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2006 25th International Conference on Thermoelectrics最新文献

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Investigation of the Magnesium Silicide -- Mg2Si Films 硅化镁—Mg2Si薄膜的研究
Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331316
T. Kamilov, D.K. Kabilov, R.Kh. Kamilova, M.E. Azimov, V. Klechkovskaya, A. Orekhov, E. Suvorova
The silicides are ecologically friendly materials and they have a mechanical stability to corrosion, oxidation, decay and aggressive environments. It is known that a bulk magnesium silicide - Mg2Si demonstrates semiconductor conductivity n-type character with energy band gap Eg=0.78 eV and solid solution based on the Mg2Si-Mg2Sn have figure of merit of ZT>1 [Samsonov, et. al. 1979]. Only small part of articles has devoted to thin Mg2Si films on silicon. In this work the magnesium silicide films have been grown on silicon substrate by reactive diffusion method and their thermoelectric properties were investigated
硅化物是一种生态友好的材料,它们对腐蚀、氧化、腐烂和侵蚀环境具有机械稳定性。已知块状硅化镁- Mg2Si具有半导体导电性n型特征,能带隙Eg=0.78 eV,基于Mg2Si- mg2sn的固溶体的优点系数ZT>1 [Samsonov, et. al. 1979]。只有一小部分的文章专门研究了硅上的Mg2Si薄膜。本文采用反应扩散法在硅衬底上生长硅化镁薄膜,并对其热电性能进行了研究
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引用次数: 1
Fine Bi2Te3 wires fabricated by glass sealed melt spinning 用玻璃密封熔融纺丝制备Bi2Te3细丝
Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331361
Ichiro Shiota, H. Kohri, Munehiro Kato, I. J. Ohsugi
Applying a small size cooling system is essential to avoid thermal noise in the field of micro-electronics. Fine thermoelectric materials are required to construct the system. A glass sealed melt spinning process was attempted to fabricate the fine materials. Bi2Te 3 wires of 75 mum in diameter with oval cross section were successfully obtained. The original electrical resistivity and Seebeck coefficient of the wires were maintained after the process
在微电子领域,采用小尺寸的冷却系统是避免热噪声的必要条件。构建该系统需要优良的热电材料。尝试用玻璃密封熔融纺丝工艺制备这种优良材料。成功制备了直径为75微米、截面为椭圆形的bi2t3导线。加工后保持导线原有的电阻率和塞贝克系数
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引用次数: 4
Thermoelectric Properties of P-type Half-Heusler Compounds HfPtSn and ZrPtSn p型半heusler化合物HfPtSn和ZrPtSn的热电性能
Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331294
Y. Kimura, A. Zama, Y. Mishima
We focused on half-Heusler compounds MPtSn, where M is Hf, Zr and Ti, to seek for half-Heusler compounds which intrinsically show excellent p-type thermoelectric properties in a wide temperature range up to around 1000 K. Nearly single-phase MPtSn alloys were fabricated by directional solidification using optical floating zone melting method to evaluate thermoelectric properties as properly as possible. We have found that HfPtSn and ZrPtSn show p-type thermoelectric properties in a measured temperature range from 300 to 1100 K as it is expected from our previous work. It is interesting that HfNiSn and ZrNiSn with the same valence electrons count of 18 are well-known to show n-type thermolectric properties. HfPtSn shows quite high values of p-type thermoelectric power around 250 muV/K in low and intermediate temperature ranges, while ZrPtSn shows much smaller maximum value of about 70 muV/K. On the other hand, TiPtSn exhibits very large n-type thermoelectric power of around 500 muV/K at ambient temperatures though it decreases drastically at elevated temperatures. High electrical resistivity is a major drawback that all three MPtSn compounds have in common. HfPtSn has the lowest thermal conductivity among MPtSn though the values are relatively high. The lattice contribution is supposed to dominates the thermal conduction because of high electrical resistivity and low carrier concentration measured as 2.17 times 1025 m-3
我们将重点放在半heusler化合物MPtSn上,其中M为Hf, Zr和Ti,以寻找在高达1000 K左右的宽温度范围内具有优异p型热电性能的半heusler化合物。采用光学浮区熔融定向凝固法制备了近单相MPtSn合金,以尽可能准确地评价其热电性能。我们发现HfPtSn和ZrPtSn在300至1100 K的测量温度范围内显示p型热电性能,这与我们之前的工作预期一致。有趣的是,价电子数为18的HfNiSn和ZrNiSn都表现出n型热分子性质。HfPtSn在中低温范围内p型热电功率在250 muV/K左右表现出较高的值,而ZrPtSn表现出较小的最大值,约为70 muV/K。另一方面,TiPtSn在室温下表现出非常大的n型热电功率,约为500 μ v /K,但在高温下急剧下降。高电阻率是所有三种MPtSn化合物共同的主要缺点。在MPtSn中,HfPtSn的热导率最低,但数值相对较高。由于高电阻率和低载流子浓度(测量值为2.17 × 1025 m-3),晶格贡献被认为主导热传导
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引用次数: 6
Effective Electron Mass of ordered AgPbmSbTe2+m clarified by ab-initio calculations 用从头算法澄清了有序AgPbmSbTe2+m的有效电子质量
Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331352
W. Wunderlich
Experimental data on PbTe2-AgSbTe2-solid solutions near the metal-insulator- transition (MIT) showed controversy resulting in high [Hsu, KF, et al., 2004] or low [Kosuga, A, et al., 2005] values of the Seebeck-coefficient and could partly be explained by specimen inhomogeneties and resulting measurement difficulties [Chen, N, et al., 2005] or different ordering states [Bilc, D, et al., 2004]. The goal of this investigation is to clarify which ordering state is expected to have the higher Seebeck coefficient by estimating the effective mass from ab-initio band structure calculations, as successfully applied for Nb-doped SrTiO3 [Wunderlich, W, et al., 2006] and metallic alloys. While the effective masses for the metallic and the semiconducting compositions were less than 0.5, the effective mass near the MIT was around m*/m0 = 9 for SrNb0.2Ti0.8O2.98 [Wunderlich, W, et al., 2006]. The effective mass depends on ordering, namely on the distance of the foreign atoms. These findings give important guidelines for further improvement of this advanced thermoelectric material
pbte2 - agsbte2 -固体溶液在金属-绝缘体-过渡(MIT)附近的实验数据显示了争议,导致塞贝克系数的值很高[Hsu, KF, etal ., 2004]或很低[Kosuga, A, etal ., 2005],这可以部分解释为试样的不均匀性和由此导致的测量困难[Chen, N, etal ., 2005]或不同的有序状态[Bilc, D, etal ., 2004]。本研究的目的是通过从ab-initio波段结构计算中估计有效质量来澄清哪种有序态有望具有更高的塞贝克系数,该计算已成功应用于nb掺杂SrTiO3 [Wunderlich, W, etal ., 2006]和金属合金。虽然金属和半导体成分的有效质量小于0.5,但SrNb0.2Ti0.8O2.98在MIT附近的有效质量约为m*/m0 = 9 [Wunderlich, W, etal ., 2006]。有效质量取决于有序度,即取决于外来原子的距离。这些发现为进一步改进这种先进的热电材料提供了重要的指导
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引用次数: 0
Effects of oxide additive on thermoelectricity of FeSi2 氧化物添加剂对FeSi2热电性能的影响
Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331240
S. Sugihara, K. Morikawa, Y. Igarashi, K. Nishiyama
Thermoelectricity has been hot issue in these days, because of environmental problems and energy sources deficit. Moreover, material development for thermoelectricity is now busy in oxide and metal or alloy, basically. However, conclusive materials with good performance have not yet been found in application basis. We have studied oxide-added beta-FeSi2 for these years. Iron disilicide is well known and utilized in relatively higher temperature. In this report, we indicated our successful improvement of performance of beta-FeSi2 added with Ta2O5 showing the figure of merit almost 0.3 times 10-3/K This was obtained by reducing thermal conductivity and electrical resistivity (a half of standard FeSi2)
由于环境问题和能源短缺,热电已成为当前研究的热点。此外,目前热电材料的开发主要集中在氧化物和金属或合金方面。但在应用基础上还没有找到性能良好的结论性材料。这些年来,我们一直在研究添加氧化物的β - fesi2。二硅化铁是众所周知的,在相对较高的温度下使用。在这篇报告中,我们指出我们成功地改善了加入Ta2O5的β -FeSi2的性能,其优值几乎是10-3/K的0.3倍,这是通过降低导热系数和电阻率(标准FeSi2的一半)获得的。
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引用次数: 0
Thermoelectric properties on n-type Si80Ge20 with different Dopants 不同掺杂剂对n型Si80Ge20热电性能的影响
Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331367
Guiying Xu, Huawei Jiang, Chunyan Zhang, Xiaofeng Wu, Sitong Niu
SixGe1-x is typical thermoelectric materials used for higher temperature as thermoelectric generator. Their property is dependent on their composition. Here different dopants, including P, Ga, B, GaP, In, Sb and InSb, were used to investigate their effect on the thermoelectric properties of n type Si80Ge20 alloys. The results describe that GaP and InSb are good dopant for n type alloys. Especially p type dopants Ga and In are very good multiplex dopant as dopants GaP and InSb for n type Si80Ge20 respectively by Seebeck coefficient of n type Si80Ge20 at same time
SixGe1-x是典型的热电材料,用于高温热电发生器。它们的性质取决于它们的组成。采用P、Ga、B、GaP、In、Sb和InSb等不同掺杂剂研究了它们对n型Si80Ge20合金热电性能的影响。结果表明,GaP和InSb是n型合金的良好掺杂剂。特别是p型掺杂剂Ga和In分别作为n型Si80Ge20的掺杂剂GaP和InSb,同时具有n型Si80Ge20的塞贝克系数
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引用次数: 2
Development of flexible thermoelectric device: Improvement of device performance 柔性热电器件的发展:器件性能的提高
Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331376
Y. Iwasaki, M. Takeda
Thermoelectric (TE) device has some problems, such as low mechanical strength, high manufacturing cost, etc. We are developing flexible TE device using thin films and flexible substrates in order to overcome those problems. The purpose of this work is to fabricate and evaluate the flexible TE device. A flexible TE device consists of vapor-deposited thin films of n- and p-type TE materials between two flexible substrates. The flexible substrate is made up of a combination of polyimide and copper. This structure enables the device itself to convert temperature difference of outer surfaces (DeltaTout) into in-plane temperature difference (DeltaT in), and it can generate electricity by the p-n couples. We analyzed temperature distribution of the device by the finite element method (FEM). According to the analysis, a flexible substrate which has thinner polyimide layer (h1) and thicker copper layer (h1) is preferable to obtain larger temperature difference. We fabricated flexible TE devices containing 33 pairs of p-n couple, which is composed of chromel and constantan thin films. The device of h 1/h2 = 12 mum/70 mum generated 3.72 muW at DeltaTout = 22.7 K, while 2.40 muW was generated from the device of h1/h2 = 35 mum/25 mum at DeltaT out = 24.0 K. The performance of the flexible TE device was successfully improved as predicted by the analysis
热电(TE)器件存在机械强度低、制造成本高等问题。为了克服这些问题,我们正在开发使用薄膜和柔性基板的柔性TE器件。本工作的目的是制作和评估柔性TE器件。一种柔性TE器件由在两个柔性衬底之间的n型和p型TE材料气相沉积薄膜组成。柔性衬底是由聚酰亚胺和铜的组合而成。这种结构使器件本身能够将外表面温差(DeltaTout)转换为面内温差(deltatin),并通过p-n偶产生电能。采用有限元法对器件的温度分布进行了分析。根据分析,具有较薄的聚酰亚胺层(h1)和较厚的铜层(h1)的柔性衬底更适合获得较大的温差。我们制作了包含33对p-n偶的柔性TE器件,该器件由铬镍合金和康钽薄膜组成。h1/h2 = 12 mum/70 mum的装置在DeltaTout = 22.7 K时产生3.72 muW,而h1/h2 = 35 mum/25 mum的装置在DeltaTout = 24.0 K时产生2.40 muW。根据分析结果,柔性TE器件的性能得到了成功的改善
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引用次数: 10
Synthesis and Characterization of nanoscale Bi2Te3, Sb2Te3, PbTe and Ag2Te powders: activated Metals and soluble Tellurium sources as synthetic Tools 纳米Bi2Te3、Sb2Te3、PbTe和Ag2Te粉体的合成与表征:活性金属和可溶性碲源作为合成工具
Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331224
S. Schlecht, M. Yosef, S. Weimer
Binary tellurides such as PbTe or Bi2Te3 represent one of the fundamental classes of thermoelectrics. Thus, the development of new routes for the preparation of these compounds as nanoscale powders is an important challenge. In this context, we investigated the use of activated metals and soluble tellurium sources such as diphenyltelluride or the tellurolates of hard transition metal cations as versatile tool box system for the synthesis of these powders. Using solvochemically activated lead, bismuth or antimony, their respective tellurides PbTe, Bi2Te3 and Sb2 Te3 could be obtained in a reaction with Ph2Te2 following the same experimental protocol in all cases. The preparation of an Ag2Te nanopowder required a different synthetic approach as elemental silver does not react with Ph 2Te2. Following the principle of hard and soft acids and bases, silver acetate and zinc tellurolate Zn(TePh)2middotTMEDA [Jun, Y, 2001] were reacted to form nanoparticles of Ag2Te from intermediately formed silver tellurolate
像PbTe或Bi2Te3这样的二元碲化物代表了热电物质的基本类别之一。因此,开发将这些化合物制备成纳米级粉末的新途径是一个重要的挑战。在这种情况下,我们研究了使用活性金属和可溶性碲源,如二苯基碲化物或硬过渡金属阳离子的碲酸盐作为合成这些粉末的多功能工具箱体系。采用溶剂化学活化的铅、铋或锑,可与Ph2Te2反应得到PbTe、Bi2Te3和sb2te3三种不同的碲化物,实验方法相同。制备Ag2Te纳米粉末需要不同的合成方法,因为元素银不与Ph 2Te2反应。根据软硬酸碱的原理,醋酸银与碲酸锌Zn(TePh)2middotTMEDA [Jun, Y, 2001]反应,中间生成的碲酸银生成Ag2Te纳米颗粒
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引用次数: 1
Effect of the Yb substitutions on the thermoelectric properties of CaMnO3 Yb取代对CaMnO3热电性能的影响
Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331291
D. Flahaut, R. Funahashi, K. Lee, H. Ohta, K. Koumoto
Ca1-xYbxMnO3 (x = 0-0.5) samples were prepared via solid state reaction in air. Electrical and thermoelectric properties have been investigated up to 1000 K. The measurements reveal that the resistivity values are strongly affected by the charge carrier content and the octahedral distortion. The lowest rho reaches 3 mOmegamiddotcm for x = 0.15. Whereas the Seebeck coefficient depends only on the charge carrier concentration, the thermal conductivity of Ca1-xYbxMnO3 is mainly governed by the mass difference between the Yb and Ca cations. The best ZT value, ZT = 0.2, is obtained for x = 0.05 at 1000 K and demonstrates the good potentialities of these oxides as high temperature thermoelectric material
在空气中通过固相反应制备Ca1-xYbxMnO3 (x = 0-0.5)样品。电学和热电性质已经研究了高达1000 K。测量结果表明,电阻率值受载流子含量和八面体畸变的影响较大。当x = 0.15时,最小的rho达到3 m。塞贝克系数仅与载流子浓度有关,而Ca1-xYbxMnO3的热导率主要受Yb和Ca阳离子质量差的影响。在1000 K温度下,当x = 0.05时ZT值最高,为0.2,显示了这些氧化物作为高温热电材料的良好潜力
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引用次数: 8
A new concept of reducing nitrogen oxides emissions in a combustion engine -- combination of ceramic oxygen conductors and thermoelectric materials 减少内燃机中氮氧化物排放的新概念——陶瓷氧导体和热电材料的结合
Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331239
K. Wojciechowski, M. Bučko, J. Obła̧kowski, P. Fuć, J. Merkisz
The subject of this work is to present a new concept of reducing NOx emissions in a combustion engine based on full elimination of nitrogen from a supply system. The use of the oxygen separator (oxygen pump), composed of the ceramic ionic conductor, together with an electrical supply system based on thermoelectric materials that utilizes exhaust heat is the main assumption of the proposed solution. The paper focuses on analyzing several possibilities for the practical application of the idea suggested
这项工作的主题是提出一种基于从供应系统中完全消除氮的减少内燃机中NOx排放的新概念。使用由陶瓷离子导体组成的氧气分离器(氧气泵)以及基于热电材料的利用废气热的供电系统是所提出的解决方案的主要假设。本文着重分析了这一思想实际应用的几种可能性
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引用次数: 1
期刊
2006 25th International Conference on Thermoelectrics
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