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Porosity Development and Modification in Al-Si Alloys: Effect of P and Sr Al-Si合金孔隙发育与变质:P和Sr的影响
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000435
J. Campbell, M. Tiryakioğlu
The benefits of Sr additions to Al–Si alloys to modify the eutectic are often impaired by the development of porosity, sometimes to the degree that benefits are negated. Experimental reports are reviewed in this paper, suggesting an explanation in terms of the oxide population in the melt. The unmodified silicon particles are nucleated by AlP, which has in turn nucleated on oxide bifilms. The oxide bifilms, which are essentially cracks, are straightened by the crystalline growth of Si particles, leading to increased crack size and consequently reduced mechanical properties. The addition of Sr improves properties by suppressing the formation of Si on bifilms and thereby preventing the straightening of the pre-existing cracks. Si is now forced to precipitate at a lower temperature as a coral-like eutectic. Unfortunately, the bifilms are now freed (the primary Si particles no longer exist to grow around and sequester the bifilms), remaining in suspension in the liquid metal, allowing them to act to block interdendritic flow and aid the initiation of the formation of pores, countering the benefits of the improved structure.
在Al-Si合金中添加Sr来改善共晶的好处经常被孔隙的发展所削弱,有时甚至被抵消。本文对实验报告进行了回顾,并从熔体中的氧化物种群的角度提出了一种解释。未修饰的硅颗粒被AlP成核,AlP又在氧化膜上成核。氧化膜(本质上是裂纹)被Si颗粒的结晶生长拉直,导致裂纹尺寸增大,从而降低了机械性能。添加Sr可以抑制薄膜上Si的形成,从而防止原有裂纹的矫直,从而改善性能。硅现在被迫在较低的温度下以珊瑚状共晶析出。不幸的是,双膜现在被释放了(原生硅颗粒不再存在,不再生长和隔离双膜),悬浮在液态金属中,使它们能够阻止枝晶间流动,帮助孔隙的形成,抵消了改进结构的好处。
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引用次数: 0
Designing with Aluminum Alloys 铝合金设计
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000404
Nack J. Kim
This article provides an overview of designing with aluminum alloys. Specific topics included in this review include: alloy designations, heat treatment of aluminum alloys, strengthening mechanisms, properties of aluminum alloys, Al-Li alloys, powder metallurgy of aluminum alloys, cast aluminum alloys, and temper designations. In addition, many reference tables are provided.
本文介绍了铝合金设计的概况。具体内容包括:合金名称、铝合金热处理、强化机制、铝合金性能、铝锂合金、铝合金粉末冶金、铸造铝合金和回火名称。此外,还提供了许多参考表。
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引用次数: 2
Friction Stir Processing: Effect on Microstructure and Mechanical Properties in Cast Aluminum Alloys 搅拌摩擦加工对铸铝合金组织和力学性能的影响
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000347
M. Tiryakioğlu, N. Netto
Microstructural and mechanical data from the literature of friction stir processed (FSPed) cast aluminum alloys were reanalyzed. Results indicated that friction stir processing (FSP) produced more homogeneous microstructures, with finer eutectic Si particles, grains, and intermetallics. However, a relationship between microstructural measures and process parameters could not be established. Regardless of the resultant microstructure, structural casting defects, i.e., pores and oxide films, were reduced in size or completely eliminated after FSP. Consequently, ductility and fatigue life were drastically improved by FSP. Quality index analysis showed that some FSPed specimens have a higher structural quality than aerospace and premium quality castings, and can be used to determine the intrinsic properties of cast aluminum alloys.
对搅拌摩擦处理(FSPed)铸铝合金的显微组织和力学数据进行了重新分析。结果表明,搅拌摩擦处理(FSP)产生了更均匀的组织,具有更细的共晶Si颗粒、晶粒和金属间化合物。然而,显微组织测量和工艺参数之间的关系无法建立。无论由此产生的微观结构如何,FSP后,结构性铸造缺陷(即气孔和氧化膜)的尺寸减小或完全消除。因此,FSP可显著提高材料的塑性和疲劳寿命。质量指标分析表明,某些FSPed试样的组织质量高于航空铸件和优质铸件,可用于确定铸铝合金的内在性能。
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引用次数: 3
Welding Technology: Gas Chromatography in 焊接技术:气相色谱法
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000444
R. Probst, K. Splitt
It is important to understand the effect of the protective gas atmosphere on the welding process to relate qualitatively the chemical composition of the welding atmosphere to the quality of the weld produced. Of particular interest are the reactions occurring within the gas phase of the arc welding process. This article presents the results conducted on the gaseous atmosphere with the aid of gas chromatography. The objective of this work was to obtain an overall understanding of the quantitative interaction of the welding atmosphere and liquid metal, and to improve the quality of the weld metal produced by specific metallurgical and technological means.
将焊接气氛的化学成分与焊缝质量定性地联系起来,了解保护气体气氛对焊接过程的影响是很重要的。特别令人感兴趣的是电弧焊过程中气相内发生的反应。本文介绍了用气相色谱法对气体气氛进行分析的结果。这项工作的目的是全面了解焊接气氛和液态金属的定量相互作用,并通过特定的冶金和技术手段提高焊接金属的质量。
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引用次数: 0
Metallurgy of Quenching Aluminum Alloys 淬火铝合金冶金
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000468
R. Shuey, M. Tiryakioğlu
The present authors have collaborated since 2000 on revitalizing and extending the technology for metallurgical aspects of quenching heat-treatable aluminum alloys, which had been developed by Dr. James T. Staley, Sr. starting with Ref. [] and continued until his retirement from Alcoa three decades later. Our objective in this chapter is a concise and current overview of what came before us and what we have added. For this we have surveyed the open literature as well as Alcoa files going back into the 1940’s, excluding any details that might still be considered proprietary. We suppose our reader to be soundly grounded in metallurgical engineering, but not necessarily with any knowledge specific to aluminum. We have excluded the topic of quench-aging, the combination of quenching and aging into a continuous process, as a substantive survey would be heavy in proprietary concepts and sophisticated metallurgy. We have also excluded thermal and mechanical aspects of quenching aluminum alloys, as well as equipment and quenchants used in fabrication of aluminum products. On these topics much of the information presented elsewhere in this volume, is generally applicable to aluminum. We conclude with our views on what has been established, how to use it, and where to go next with the techniques pioneered by our mutual mentor, Dr. James T. Staley.
自2000年以来,本文作者一直致力于振兴和扩展淬火热处理铝合金冶金方面的技术,该技术是由James T. Staley, sr博士开发的,从参考文献[]开始,一直持续到三十年后他从美国铝业公司退休。我们在本章的目标是对我们之前的内容和我们所添加的内容进行简要和当前的概述。为此,我们调查了开放文献以及美国铝业公司的文件,这些文件可以追溯到20世纪40年代,排除了任何可能仍然被认为是专有的细节。我们假定我们的读者在冶金工程方面有扎实的基础,但不一定具有任何特定于铝的知识。我们已经排除了淬火时效的主题,淬火和时效结合成一个连续的过程,因为实质性的调查将是专有概念和复杂的冶金。我们还排除了淬火铝合金的热和机械方面,以及铝制品制造中使用的设备和淬火剂。关于这些主题,本卷其他地方提供的许多信息通常适用于铝。我们总结了我们对已经建立的,如何使用它,以及我们共同导师詹姆斯·t·斯特利博士开创的技术下一步走向的看法。
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引用次数: 0
Anodic Oxides: Applications and Trends in Nanofabrication 阳极氧化物:在纳米制造中的应用和趋势
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000304
W. Stępniowski
Anodic aluminum oxide (AAO) is one of the most frequently fabricated materials with the use of electrochemical techniques. In this article, current trends in aluminum anodizing are reviewed, including anodizing in novel electrolytes, anodizing in electrolytes with various additives, and fabrication of 3D nanostructures using pulse anodizing, leading to the formation of distributed Bragg reflectors. Applications of AAO in the field of nanofabrication are also reviewed with the use of milestone and the most current research.
阳极氧化铝(AAO)是利用电化学技术制备的最常用的材料之一。本文综述了铝阳极氧化的最新研究进展,包括新型电解液阳极氧化、添加各种添加剂的电解液阳极氧化以及利用脉冲阳极氧化制备三维纳米结构,从而形成分布布拉格反射体。同时,对AAO在纳米制造领域的应用进行了综述。
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引用次数: 0
Atom Probe Characterization of Nanoscale Precipitates in Aluminum Alloys 铝合金中纳米析出物的原子探针表征
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000394
K. Hono
Atomic Probe Field Ion Microscopy (APFIM) is used to solve many critical problems related to microstructures of metallic materials such as nanostructures that are composed of nanoscale precipitates dispersed in a matrix phase. The atom probe technique provides unique information on metallic nanostructures not attainable with other analytical microscopy techniques such as Transmission Electron Microscopy (TEM). In this article the an overview of the contribution of the atom probe technique to enhance the current understanding of solute clustering and characterization of fine precipitates of aluminum alloys.
原子探针场离子显微镜(APFIM)用于解决与金属材料微观结构有关的许多关键问题,例如由分散在基体相中的纳米级沉淀物组成的纳米结构。原子探针技术提供了金属纳米结构的独特信息,这是其他分析显微镜技术如透射电子显微镜(TEM)无法获得的。本文综述了原子探针技术在提高对铝合金溶质聚类和细析出物表征的认识方面的贡献。
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引用次数: 0
Plasma Surface Treatment: Effects on Mechanical and Corrosion Protection Properties of Hybrid Sol–Gel Coatings 等离子体表面处理:对混合溶胶-凝胶涂层机械性能和防腐性能的影响
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000211
R. Subasri
Surface cleaning and activation of substrates are two critical processes that affect the mechanical and corrosion resistance properties of protective coatings when deposited on the substrates. Surface cleaning removes the contaminants, for example, grease on the substrate, and surface activation introduces active bonds on the substrate thereby increasing the surface free energy. Conventionally, surface cleaning and activation of aluminum and its alloys are carried out by a wet chemical technique. A convenient and safe alternate to the wet chemical cleaning/activation would be to use plasma for the same purpose. Plasma surface pre-treatment greatly improves adhesion of coatings deposited, which is very vital for good corrosion protection and mechanical properties such as scratch and abrasion resistance. Cold and atmospheric air plasma treatments have been the most widely studied pre-treatments for Al alloys. This article will discuss the advancements in the use of plasma treatment on Al/Al alloys and its effect on corrosion resistance and mechanical properties of coatings deposited after the surface treatment.
表面清洗和基材活化是影响基材表面防护涂层机械性能和耐腐蚀性能的两个关键过程。表面清洁去除污染物,例如基材上的油脂,表面活化在基材上引入活性键,从而增加表面自由能。传统上,铝及其合金的表面清洁和活化是通过湿化学技术进行的。一种方便和安全的替代湿式化学清洗/活化的方法是使用等离子体来达到同样的目的。等离子体表面预处理大大提高了镀层的附着力,这对于良好的防腐性能和耐划伤、耐磨性等机械性能至关重要。低温和常压空气等离子体处理是目前研究最广泛的铝合金预处理方法。本文将讨论等离子体处理Al/Al合金的研究进展及其对表面处理后镀层的耐蚀性和力学性能的影响。
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引用次数: 0
Aerospace Fasteners: Use in Structural Applications 航空航天紧固件。结构应用
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000240
G. Melhem
Aircraft components need to be selected and manufactured to adequately combat the environment, temperature, loading, compatibility, and so on. When structural materials such as aluminum alloys or fiber-reinforced polymer composites need to be joined in aircraft, the selection of fasteners, bolts, rivets, adhesives, and other methods need to be quantitatively assessed in order that the correct design for the component and joining method is identified. There is a variety of fasteners, bolts, and rivets, made using a variety of materials. Aluminum rivets are often used to join aluminum components in an aircraft. Rivets do not perform well under tension loading, but perform better in shear, thus limiting the application specifically for these purposes. Bolts are designed to clamp material together, and even though the bolt may be adequate to support a particular structure and load requirement, consideration must also be given to the modulus of elasticity and stiffness of the components that are being clamped together. Therefore, an understanding of each of the materials being clamped or joined together is necessary. Bolts manufactured from steel, for instance, have coatings applied in order to help protect them from corrosion. The use of composites translates to a reduced number of rivets and fasteners to be used. Drilling of holes into composites to insert fasteners poses many challenges because the fibers are damaged, a region of high stress concentration may be formed, and the hole is a site for the ingress of water or moisture. The insertion of aluminum fasteners or the contact of aluminum components with carbon fibers creates galvanic corrosion due to the large difference in electrical potential. Titanium alloy (Ti-6Al-4V) is a typical fastener where there is composite joining due to its better compatibility (elimination of galvanic corrosion) and increased strength properties. Substitution of rivets and fasteners for welding is also on the increase in aircraft because laser beam welding (LBW) and friction stir welding both reduce cracking, porosity, and better properties achieved due to deeper penetration, and reduce the heat-affected zone which would typically be undesirable with conventional arc welding such as metal inert gas and tungsten inert gas welding. The shear and compressive stresses are increased, and fatigue cracking, weight, and cost are also reduced as a result of LBW, including the elimination of stresses and corrosion associated with rivets and the elimination of adhesives. Dissimilar metals such as the 7000 series and the 2000 series can be joined with a filler metal compatible to both metals to mitigate galvanic corrosion.
飞机部件的选择和制造需要充分考虑环境、温度、载荷、兼容性等因素。当飞机上需要连接铝合金或纤维增强聚合物复合材料等结构材料时,需要对紧固件、螺栓、铆钉、粘合剂和其他方法的选择进行定量评估,以便确定正确的部件设计和连接方法。有各种各样的紧固件、螺栓和铆钉,使用各种材料制成。铝铆钉常用于连接飞机上的铝部件。铆钉在拉伸载荷下表现不佳,但在剪切载荷下表现较好,因此限制了专门用于这些目的的应用。螺栓的设计是为了将材料夹紧在一起,即使螺栓可能足以支持特定的结构和负载要求,也必须考虑到被夹紧在一起的部件的弹性模量和刚度。因此,了解夹紧或连接在一起的每种材料是必要的。例如,用钢制造的螺栓涂上涂层以防止腐蚀。复合材料的使用可以减少铆钉和紧固件的使用。在复合材料上钻孔以插入紧固件带来了许多挑战,因为纤维会被破坏,可能形成高应力集中区域,并且孔是水或湿气进入的场所。铝紧固件的插入或铝部件与碳纤维的接触,由于电势差大,会产生电偶腐蚀。钛合金(Ti-6Al-4V)是一种典型的紧固件,因为它具有更好的相容性(消除电偶腐蚀)和更高的强度性能。在飞机上,用铆钉和紧固件代替焊接也在增加,因为激光束焊接(LBW)和搅拌摩擦焊接都减少了裂纹、气孔和更好的性能,这是由于更深的渗透,并且减少了传统电弧焊(如金属惰性气体和钨惰性气体焊接)通常不希望出现的热影响区。由于LBW,剪切和压缩应力增加,疲劳开裂,重量和成本也减少了,包括消除了与铆钉相关的应力和腐蚀以及消除了粘合剂。不同的金属,如7000系列和2000系列,可以与两种金属兼容的填充金属连接,以减轻电偶腐蚀。
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引用次数: 7
Strength and Intergranular Corrosion of Aluminum Alloys: Effect of Cooling Rate 铝合金的强度与晶间腐蚀:冷却速率的影响
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000221
Patrícia Mariane Kavalco, L. Canale, G. Totten
Although cooling rate and strength correlations for a wide range of quenching conditions are routinely discussed, cooling time–temperature data are shown less often. However, intergranular corrosion is also cooling rate and pathway dependent, but such data correlation is much less likely to be encountered, especially by commercial quenchant suppliers. Even cooling rate data, strength, intergranular corrosion, and either residual stress or distortion correlations are more rarely reported together. This entry discusses the mechanism of intergranular corrosion and provides an illustrative example of the dependence of intergranular corrosion on the cooling rate.
虽然冷却速率和强度在大范围淬火条件下的相关性经常被讨论,但冷却时间-温度数据很少被显示。然而,晶间腐蚀也依赖于冷却速率和路径,但这种数据相关性不太可能遇到,特别是商业淬火剂供应商。甚至冷却速率数据、强度、晶间腐蚀和残余应力或变形相关性也很少一起报道。本条目讨论了晶间腐蚀的机理,并提供了晶间腐蚀对冷却速率的依赖性的说明性示例。
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引用次数: 0
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Encyclopedia of Aluminum and Its Alloys
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