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Rapid prediction of interface morphology and oxygen transportation in crystal growth based on the response surface method 基于响应面法快速预测晶体生长过程中的界面形态和氧气运输
IF 1.7 4区 材料科学 Q3 CRYSTALLOGRAPHY Pub Date : 2024-10-12 DOI: 10.1016/j.jcrysgro.2024.127935
Dongxiu Yan , Ziyi Guo , Xue Chen , Kai Li , Jianfu Zhao , Wenrui Hu
In this paper, a two-dimensional (2D) axisymmetric model subjected to the gas shear effect and thermal Marangoni effect is developed. It is highlighted that the growth conditions of pulling rate, gas flow rate, crucible, and crystal rotation rates play important roles in determining the crystal behaviors of interface morphology and oxygen transportation during the crystal growth process. A Kriging-based response surface method (RSM) is proposed to rapidly predict the crystal growth behaviors, indicating that the outputs of interface morphology and oxygen concentration can be predicted by the corresponding input growth conditions. By global sensitivity analysis, the pulling rate is identified as the key factor in determining the interface morphology, while gas flow rate and crucible rotation rate have a greater effect on oxygen transportation. Furthermore, these two inputs with the highest sensitivities are used to construct the response surface and predict unknown oxygen transportation. When compared with the numerical simulations, the presented model proves to be an effective tool for reducing measurement time and improving accuracy in predicting crystal behaviors. Our findings provide important insights into understanding the crystal growth process under different growth conditions and inspire a data-driven method for crystal growth prediction.
本文建立了一个受气体剪切效应和热马兰戈尼效应影响的二维(2D)轴对称模型。结果表明,在晶体生长过程中,拉速、气体流速、坩埚和晶体旋转率等生长条件对晶体的界面形态和氧输送行为起着重要的决定作用。提出了一种基于克里金的响应面方法(RSM)来快速预测晶体生长行为,表明界面形态和氧浓度的输出可以通过相应的输入生长条件来预测。通过全局灵敏度分析,发现拉速是决定界面形态的关键因素,而气体流速和坩埚旋转速率对氧气输送的影响更大。此外,这两个敏感度最高的输入被用来构建响应面和预测未知的氧气输送。与数值模拟相比,所提出的模型被证明是减少测量时间和提高晶体行为预测准确性的有效工具。我们的研究结果为理解不同生长条件下的晶体生长过程提供了重要见解,并为晶体生长预测的数据驱动方法提供了灵感。
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引用次数: 0
Recent advances of rare earth orthoferrite RFeO3 magneto-optical single crystals 稀土正长铁氧体 RFeO3 磁光单晶的最新进展
IF 1.7 4区 材料科学 Q3 CRYSTALLOGRAPHY Pub Date : 2024-10-12 DOI: 10.1016/j.jcrysgro.2024.127939
Qixin Li , Jie Zhou , Jiamin Shang , Hui Shen , Leifan Li , Fei Wang , Xuanbing Shen , Tian Tian , A.M. Kalashnikova , Anhua Wu , Jiayue Xu
Currently, rare earth orthoferrites RFeO3 crystals are gaining tremendous interests, thanks to their exotic magnetic, multiferroic and magneto-optical characteristics. This family displays distinctive advantages of ultrafast response in nanoseconds and much enhanced sensitivity for magneto-optical (MO) switches and isolators. Moreover, enriched magnetic transitions and ultrafast opto-magnetic modulation have been rationally achieved, favoring ultrafast magnetic recording with much lower energy consumption. This work comprehensively summarizes the recent advances of magneto-optical RFeO3 single crystals, including the crystal growth, the regulation of magnetic properties and the tailoring of opto-magnetic interactions. The related mechanism for the modulation of magneto-optical interactions is also analyzed in details, facilitating deeper insight into the design and further exploration of RFeO3 crystals for the potential applications in the fields of novel spintronic and ultrafast magneto-optical devices.
目前,稀土正铁氧体 RFeO3 晶体因其奇特的磁性、多铁性和磁光学特性而备受关注。该系列具有纳秒级超快响应的独特优势,可大大提高磁光(MO)开关和隔离器的灵敏度。此外,还合理地实现了丰富的磁跃迁和超快光磁调制,有利于以更低的能耗实现超快磁记录。这项研究全面总结了 RFeO3 单晶的磁光最新进展,包括晶体生长、磁性调控和光磁相互作用的定制。此外,还详细分析了调制磁光相互作用的相关机制,有助于深入了解 RFeO3 晶体的设计和进一步探索其在新型自旋电子和超快磁光器件领域的潜在应用。
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引用次数: 0
A novel feathery nanoporous magnesium synthesized by ethanol vapor assisted physical vapor deposition 乙醇蒸汽辅助物理气相沉积合成的新型羽毛状纳米多孔镁
IF 1.7 4区 材料科学 Q3 CRYSTALLOGRAPHY Pub Date : 2024-10-11 DOI: 10.1016/j.jcrysgro.2024.127944
Han Wang , Xiping Song , Jingru Liu , Li You
Nanoporous magnesium exhibits outstanding performance in hydrogen absorption and desorption, rendering it a promising candidate for hydrogen storage applications. Nevertheless, there is limited discussion on the preparation method and growth mechanism of nano-porous magnesium. In this paper, a novel nanoporous magnesium material characterized by a feathery morphology was successfully synthesized at 823 K for 2 h under a vacuum pressure of 3 Pa, assisted by ethanol vapor through the physical vapor deposition method. The ethanol vapor was identified as the crucial factor in the synthesis of the feathery nanoporous magnesium. A vacancy-assisted formation mechanism is proposed to elucidate the creation of feathery nanoporous magnesium, whereby the ethanol vapor occupies specific positions within the magnesium vapor, resulting in the formation of nano and submicron pores.
纳米多孔镁在氢吸收和解吸方面表现出卓越的性能,使其成为氢储存应用的理想候选材料。然而,关于纳米多孔镁的制备方法和生长机理的讨论还很有限。本文通过物理气相沉积法,在乙醇蒸汽的辅助下,于 823 K、3 Pa 真空压力下 2 小时成功合成了一种新型纳米多孔镁材料,其特征为羽毛状形貌。乙醇蒸汽被认为是合成羽毛状纳米多孔镁的关键因素。乙醇蒸气占据了镁蒸气中的特定位置,从而形成了纳米和亚微米孔隙。
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引用次数: 0
Oxygen evolution reaction of tellurium-incorporated nickel-iron layered double hydroxide microcrystals 掺入碲的镍铁层状双氢氧化物微晶的氧进化反应
IF 1.7 4区 材料科学 Q3 CRYSTALLOGRAPHY Pub Date : 2024-10-11 DOI: 10.1016/j.jcrysgro.2024.127918
Kyoungwon Cho , Hyun Cho , Jeong Ho Ryu
Transition-metal-based layered double hydroxide (LDH) crystals have generated substantial interest as highly efficient oxygen evolution reaction (OER) catalysts because of their abundance, low cost, environmental friendliness, and favourable adsorption/desorption energies for intermittent reactants. However, the application of LDH crystals as high-performance electrocatalysts is frequently hindered by their sluggish electronic transport kinetics resulting from their intrinsically low conductivity. Herein, we report the effects of incorporating metalloids into transition metal LDH crystals on their electrocatalytic activity. In this study, tellurium (Te) incorporated NiFe (xTe-NiFe) LDH microcrystal, where x  = 0.2, 0.4, 0.6 and 0.8, were grown on three-dimensional porous nickel foam using a facile solvothermal method. The electrocatalytic OER properties were analyzed using linear sweep voltammetry and electrochemical impedance spectroscopy. The amount of Te was found to play a crucial role in improving the catalytic activity of NiFe LDH. The optimum amount of Te (x) introduced into NiFe LDH was examined with respect to the OER performance.
过渡金属基层状双氢氧化物(LDH)晶体作为高效氧进化反应(OER)催化剂,因其数量多、成本低、环境友好以及对间歇性反应物的吸附/解吸能量有利而引起了人们的极大兴趣。然而,LDH 晶体作为高性能电催化剂的应用常常受到其固有的低电导率导致的电子传输动力学迟缓的阻碍。在此,我们报告了在过渡金属 LDH 晶体中加入金属元素对其电催化活性的影响。在这项研究中,我们采用简便的溶热法在三维多孔泡沫镍上生长了碲(Te)掺杂镍铁(xTe-NiFe)的 LDH 微晶,其中 x = 0.2、0.4、0.6 和 0.8。利用线性扫频伏安法和电化学阻抗谱分析了其电催化 OER 特性。研究发现,Te 的含量对提高镍铁合金 LDH 的催化活性起着至关重要的作用。研究了引入 NiFe LDH 的 Te (x) 的最佳量对 OER 性能的影响。
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引用次数: 0
Periodic dimple lines on the surface of the grain-boundary free (100) Si thin films grown by the continuous-wave laser crystallization 连续波激光结晶法生长的无晶界 (100) 硅薄膜表面的周期性凹痕线
IF 1.7 4区 材料科学 Q3 CRYSTALLOGRAPHY Pub Date : 2024-10-11 DOI: 10.1016/j.jcrysgro.2024.127934
Satoshi Takayama , Nobuo Sasaki , Yukiharu Uraoka
Periodic dimple lines have been found by the atomic-force-microscopy on the surface of the grain-boundary free (100) Si films obtained by the continuous-wave laser crystallization. The dimple lines are straight and run parallel each other to the scan direction regularly at a period of ∼3.1 μm. The depth of the dimple lines is 3∼5 nm (peak-to-valley). The internal angle of the dimple lines is ∼179.4°. These dimple lines originate from hyperfine sub-boundaries with a boundary energy of 2.4 × 10−6 J/cm2, a rotation angle θ of ∼0.061°, and a dislocation spacing of ∼0.36 μm.
通过连续波激光结晶技术获得的无晶界(100)硅薄膜表面的原子力显微镜发现了周期性凹痕线。这些凹痕线是直线,以 ∼3.1 μm 的周期有规律地平行于扫描方向。凹痕线的深度为 3 ∼ 5 nm(峰-谷)。酒窝线的内角为 ∼179.4°。这些酒窝线源自超精细子边界,边界能量为 2.4 × 10-6 J/cm2,旋转角 θ 为 ∼ 0.061°,位错间距为 ∼ 0.36 μm。
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引用次数: 0
Influence of bottom supporting columns and cooling rate on the surface shape characteristics of sapphire substrates 底部支撑柱和冷却速度对蓝宝石基底表面形状特征的影响
IF 1.7 4区 材料科学 Q3 CRYSTALLOGRAPHY Pub Date : 2024-10-10 DOI: 10.1016/j.jcrysgro.2024.127933
Xiaobo Dai , Hao Li , Yang Zhang
The manufacturing process of sapphire substrates involves several key steps, including epitaxy, annealing, cutting, and processing. Among these, epitaxy and annealing are particularly crucial. The temperature variances along both the longitudinal and transverse axes within the furnace during the crystallization process play a significant role in determining the crystallization rate and internal structure of sapphire crystals. Furthermore, annealing sapphire serves to alleviate internal stress, enhance crystal structure, optimize physical properties, improve optoelectronic characteristics, enhance surface quality, and increase overall yield. This step is paramount in enhancing the performance and application value of sapphire materials. In order to investigate and optimize the effects of different thermal conductivities of support columns at the base and various annealing procedures on the surface characteristics of sapphire substrates, thereby improving product quality, this study conducted research by utilizing support columns made of different materials and carefully controlling the cooling rate parameters for sapphire. The findings revealed that using graphite as the base support column for the crystal furnace can reduce both the longitudinal and transverse temperature gradients within the furnace, consequently promoting crystal growth and enhancing the quality of sapphire ingots. Additionally, sapphire chips annealed using the rapid one-step annealing program exhibited the highest average warpage and bending rate variation, reaching 2.0 μm, and the average dislocation density was half that of conventionally produced chips, at 108.89 pits/cm2.
蓝宝石衬底的制造过程涉及几个关键步骤,包括外延、退火、切割和加工。其中,外延和退火尤为关键。在结晶过程中,炉内纵轴和横轴的温度变化对蓝宝石晶体的结晶速度和内部结构起着重要作用。此外,蓝宝石退火还可减轻内应力、增强晶体结构、优化物理特性、改善光电特性、提高表面质量和增加总产量。这一步骤对于提高蓝宝石材料的性能和应用价值至关重要。为了研究和优化不同导热系数的基底支撑柱和各种退火程序对蓝宝石基底表面特性的影响,从而提高产品质量,本研究通过使用不同材料制成的支撑柱和仔细控制蓝宝石的冷却速率参数进行了研究。研究结果表明,使用石墨作为晶体炉的基础支撑柱,可以减少炉内的纵向和横向温度梯度,从而促进晶体生长,提高蓝宝石铸锭的质量。此外,使用一步法快速退火程序退火的蓝宝石芯片的平均翘曲和弯曲率变化最大,达到 2.0 μm,平均位错密度为传统生产芯片的一半,为 108.89 pits/cm2。
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引用次数: 0
Study of the physical nature of Mn4Si7 crystals formed by the diffusion method using an X-ray diffraction 利用 X 射线衍射法研究通过扩散法形成的 Mn4Si7 晶体的物理性质
IF 1.7 4区 材料科学 Q3 CRYSTALLOGRAPHY Pub Date : 2024-10-10 DOI: 10.1016/j.jcrysgro.2024.127932
B.D. Igamov , A.I. Kamardin , D.Kh. Nabiev , I.R. Bekpulatov , G.T. Imanova , T.S. Kamilov , A.S. Kasimov , N.E. Norbutaev
Mn4Si7 silicide crystals obtained by the diffusion method were studied using an X-ray diffractometer (XRD-6100) SHIMADZU. As a result of research, 14 peaks were identified in the Mn4Si7 crystal, corresponding to the database (COD-1530134).The size of Mn4Si7 silicide crystals (DDiff) ranged from 6.2 × 10−10 m to 9.1 × 10−8 m, the lattice tension between crystal atoms (εDiff) from 0.31 to 3.71, the dislocation density on the surface (δDiff) varied in the range from 1 × 1011 to 3.2 × 1014. It was found that the degree of crystallization of Mn4Si7 was 9.3 %, and the degree of amorphism reached 90.7 %. It has been established that the degree of crystallization of Mn4Si7 silicides is relatively low due to the fact that the Mn and Si atoms are non-stoichiometrically bonded to each other, and the degree of amorphism is high.
使用岛津 X 射线衍射仪(XRD-6100)对通过扩散法获得的 Mn4Si7 硅化物晶体进行了研究。Mn4Si7 硅化物晶体的尺寸(DDiff)范围为 6.2 × 10-10 m 至 9.1 × 10-8 m,晶体原子间的晶格张力(εDiff)范围为 0.31 至 3.71,表面位错密度(δDiff)范围为 1 × 1011 至 3.2 × 1014。研究发现,Mn4Si7 的结晶度为 9.3%,非晶度达到 90.7%。由此可以确定,由于 Mn 原子和 Si 原子之间是非共价键,因此 Mn4Si7 硅化物的结晶度相对较低,而非晶度较高。
{"title":"Study of the physical nature of Mn4Si7 crystals formed by the diffusion method using an X-ray diffraction","authors":"B.D. Igamov ,&nbsp;A.I. Kamardin ,&nbsp;D.Kh. Nabiev ,&nbsp;I.R. Bekpulatov ,&nbsp;G.T. Imanova ,&nbsp;T.S. Kamilov ,&nbsp;A.S. Kasimov ,&nbsp;N.E. Norbutaev","doi":"10.1016/j.jcrysgro.2024.127932","DOIUrl":"10.1016/j.jcrysgro.2024.127932","url":null,"abstract":"<div><div>Mn<sub>4</sub>Si<sub>7</sub> silicide crystals obtained by the diffusion method were studied using an X-ray diffractometer (XRD-6100) SHIMADZU. As a result of research, 14 peaks were identified in the Mn<sub>4</sub>Si<sub>7</sub> crystal, corresponding to the database (COD-1530134).The size of Mn<sub>4</sub>Si<sub>7</sub> silicide crystals (<em>D<sub>Diff</sub></em>) ranged from 6.2 × 10<sup>−10</sup> m to 9.1 × 10<sup>−8</sup> m, the lattice tension between crystal atoms (<em>ε<sub>Diff</sub></em>) from 0.31 to 3.71, the dislocation density on the surface (<em>δ<sub>Diff</sub></em>) varied in the range from 1 × 10<sup>11</sup> to 3.2 × 10<sup>14</sup>. It was found that the degree of crystallization of Mn<sub>4</sub>Si<sub>7</sub> was 9.3 %, and the degree of amorphism reached 90.7 %. It has been established that the degree of crystallization of Mn<sub>4</sub>Si<sub>7</sub> silicides is relatively low due to the fact that the Mn and Si atoms are non-stoichiometrically bonded to each other, and the degree of amorphism is high.</div></div>","PeriodicalId":353,"journal":{"name":"Journal of Crystal Growth","volume":"649 ","pages":"Article 127932"},"PeriodicalIF":1.7,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stress analysis and dislocation cluster generation in silicon crystal with artificial grain boundaries 带有人工晶界的硅晶体中的应力分析和位错簇生成
IF 1.7 4区 材料科学 Q3 CRYSTALLOGRAPHY Pub Date : 2024-10-10 DOI: 10.1016/j.jcrysgro.2024.127922
Haruki Tajika , Kentaro Kutsukake , Noritaka Usami
We conducted a dislocation and stress analysis on various grain boundaries (GBs) using silicon ingots that contained artificial GBs to permit systematic comparison of experimental and analytical results. Through photoluminescence imaging, we found that the number of dislocation clusters generated around the 〈1 1 0〉-oriented GBs was significantly higher than those around the 〈1 0 0〉-oriented GBs. The stress analysis revealed that this difference is linked to the maximum shear stress around the GB. However, there were some GBs where dislocation cluster generation was not observed despite the presence of high shear stress. For most of these GBs, the direction of the maximum shear stress in the 12 slip system of silicon crystal was found to be oblique downward to the growth direction, which appears to inhibit dislocation propagation.
我们利用含有人造晶界的硅锭对各种晶界(GB)进行了位错和应力分析,以便对实验结果和分析结果进行系统比较。通过光致发光成像,我们发现在〈1 1 0〉取向晶界周围产生的位错簇数量明显高于在〈1 0 0〉取向晶界周围产生的位错簇数量。应力分析表明,这种差异与 GB 周围的最大剪应力有关。然而,尽管存在高剪切应力,但在某些 GB 上并未观察到位错簇的产生。对于大多数这些 GB,发现硅晶体 12 滑移系统中的最大剪切应力方向与生长方向呈斜向下,这似乎抑制了位错的传播。
{"title":"Stress analysis and dislocation cluster generation in silicon crystal with artificial grain boundaries","authors":"Haruki Tajika ,&nbsp;Kentaro Kutsukake ,&nbsp;Noritaka Usami","doi":"10.1016/j.jcrysgro.2024.127922","DOIUrl":"10.1016/j.jcrysgro.2024.127922","url":null,"abstract":"<div><div>We conducted a dislocation and stress analysis on various grain boundaries (GBs) using silicon ingots that contained artificial GBs to permit systematic comparison of experimental and analytical results. Through photoluminescence imaging, we found that the number of dislocation clusters generated around the 〈1<!--> <!-->1<!--> <!-->0〉-oriented GBs was significantly higher than those around the 〈1<!--> <!-->0<!--> <!-->0〉-oriented GBs. The stress analysis revealed that this difference is linked to the maximum shear stress around the GB. However, there were some GBs where dislocation cluster generation was not observed despite the presence of high shear stress. For most of these GBs, the direction of the maximum shear stress in the 12 slip system of silicon crystal was found to be oblique downward to the growth direction, which appears to inhibit dislocation propagation.</div></div>","PeriodicalId":353,"journal":{"name":"Journal of Crystal Growth","volume":"649 ","pages":"Article 127922"},"PeriodicalIF":1.7,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142442189","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Growth and characterizations of indium doped tin diselenide (InxSn1−x)Se2 crystals 掺杂铟的二硒化锡 (InxSn1-x)Se2 晶体的生长和特性分析
IF 1.7 4区 材料科学 Q3 CRYSTALLOGRAPHY Pub Date : 2024-10-10 DOI: 10.1016/j.jcrysgro.2024.127913
P.D. Patel , N.N. Prajapati , H.M. Patel , S.P. Sikligar , P.B. Patel , H.N. Desai , J.M. Dhimmar , B.P. Modi
<div><div>Nowadays, materials with narrow bandgap of transition metal dichalcogenide layered structures have attracted towards the research due to their substantial and tunable optoelectronic properties. Among the IV-VI compound semiconductor, (In<span><math><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span>Sn<span><math><msub><mrow></mrow><mrow><mn>1</mn><mo>−</mo><mi>x</mi></mrow></msub></math></span>)Se<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> is potential candidate with higher carrier mobility, sustainability and getting higher carrier concentration with doping. The (In<span><math><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span>Sn<span><math><msub><mrow></mrow><mrow><mn>1</mn><mo>−</mo><mi>x</mi></mrow></msub></math></span>)Se<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> crystal is layered type crystal grown by direct vapor transport mode within vacuum closed quartz ampoule. The chemical composition of (In<span><math><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span>Sn<span><math><msub><mrow></mrow><mrow><mn>1</mn><mo>−</mo><mi>x</mi></mrow></msub></math></span>)Se<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> grown crystals have been confirmed by Energy Dispersive X-ray analysis. Also it showed that as grown (In<span><math><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span>Sn<span><math><msub><mrow></mrow><mrow><mn>1</mn><mo>−</mo><mi>x</mi></mrow></msub></math></span>)Se<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> crystals to be near the stochiometric rich with Se. The structure analysis by X-ray diffraction of as grown (In<span><math><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span>Sn<span><math><msub><mrow></mrow><mrow><mn>1</mn><mo>−</mo><mi>x</mi></mrow></msub></math></span>)Se<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> crystal confirmed by hexagonal structure having lattice parameters: <span><math><mrow><mi>a</mi><mo>=</mo><mi>b</mi><mo>=</mo><mn>3</mn><mo>.</mo><mn>81</mn><mspace></mspace><mstyle><mi>Å</mi></mstyle><mo>,</mo></mrow></math></span> c = <span><math><mrow><mn>6</mn><mo>.</mo><mn>14</mn><mspace></mspace><mstyle><mi>Å</mi></mstyle></mrow></math></span>, and <span><math><mrow><mi>α</mi><mo>=</mo><mi>β</mi><mo>=</mo><mn>9</mn><msup><mrow><mn>0</mn></mrow><mrow><mo>∘</mo></mrow></msup></mrow></math></span>, <span><math><mrow><mi>γ</mi><mo>=</mo><mn>12</mn><msup><mrow><mn>0</mn></mrow><mrow><mo>∘</mo></mrow></msup></mrow></math></span> for x = 0. Optical parameters of layered crystals were characterized with optical absorption spectra within the wavelength range of 400 nm to 1100 nm. The thermal analysis of crystals have been performed by recording thermo gravimetric curve. The kinetic parameters, thermal activation energies evaluated by Broido method, Coast-Redfern method, Horowitz-Metzger method. The variat
如今,过渡金属二掺杂层状结构的窄带隙材料因其巨大的可调光电特性而备受研究关注。在 IV-VI 族化合物半导体中,(InxSn1-x)Se2 具有更高的载流子迁移率和可持续性,并可通过掺杂获得更高的载流子浓度,是一种潜在的候选材料。(InxSn1-x)Se2 晶体是在真空密闭石英安瓿瓶中通过直接气相传输模式生长的层状晶体。能量色散 X 射线分析证实了生长出的 (InxSn1-x)Se2 晶体的化学成分。研究还表明,生长出来的(InxSn1-x)Se2 晶体接近于富含硒的稳态计量晶体。通过 X 射线衍射分析,生长出的 (InxSn1-x)Se2 晶体的结构被证实为六边形结构,其晶格参数为:a=b=3.81 Å,c=6.14 Å,x = 0 时,α=β=90∘,γ=120∘。通过记录热重曲线对晶体进行了热分析。用 Broido 法、Coast-Redfern 法和 Horowitz-Metzger 法评估了动力学参数和热活化能。电阻随温度的变化表明,(InxSn1-x)Se2 晶体具有负温度系数的半导体行为。此外,随着(InxSn1-x)Se2 晶体中铟掺杂浓度的增加,活化能也有所降低。此外,还评估了晶体在 100 mw/cm2 光照强度下的光响应参数。
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Among the IV-VI compound semiconductor, (In&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;x&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;Sn&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mi&gt;x&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;)Se&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; is potential candidate with higher carrier mobility, sustainability and getting higher carrier concentration with doping. The (In&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;x&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;Sn&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mi&gt;x&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;)Se&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; crystal is layered type crystal grown by direct vapor transport mode within vacuum closed quartz ampoule. The chemical composition of (In&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;x&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;Sn&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mi&gt;x&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;)Se&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; grown crystals have been confirmed by Energy Dispersive X-ray analysis. Also it showed that as grown (In&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;x&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;Sn&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mi&gt;x&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;)Se&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; crystals to be near the stochiometric rich with Se. The structure analysis by X-ray diffraction of as grown (In&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;x&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;Sn&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mi&gt;x&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;)Se&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; crystal confirmed by hexagonal structure having lattice parameters: &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;a&lt;/mi&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mi&gt;b&lt;/mi&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;3&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;81&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mstyle&gt;&lt;mi&gt;Å&lt;/mi&gt;&lt;/mstyle&gt;&lt;mo&gt;,&lt;/mo&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; c = &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mn&gt;6&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;14&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mstyle&gt;&lt;mi&gt;Å&lt;/mi&gt;&lt;/mstyle&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, and &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;α&lt;/mi&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mi&gt;β&lt;/mi&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;9&lt;/mn&gt;&lt;msup&gt;&lt;mrow&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mo&gt;∘&lt;/mo&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;γ&lt;/mi&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;12&lt;/mn&gt;&lt;msup&gt;&lt;mrow&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mo&gt;∘&lt;/mo&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; for x = 0. Optical parameters of layered crystals were characterized with optical absorption spectra within the wavelength range of 400 nm to 1100 nm. The thermal analysis of crystals have been performed by recording thermo gravimetric curve. The kinetic parameters, thermal activation energies evaluated by Broido method, Coast-Redfern method, Horowitz-Metzger method. The variat","PeriodicalId":353,"journal":{"name":"Journal of Crystal Growth","volume":"649 ","pages":"Article 127913"},"PeriodicalIF":1.7,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142535709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Laser-driven synthesis of functional materials for advanced energy applications: A short review 激光驱动的先进能源应用功能材料合成:简评
IF 1.7 4区 材料科学 Q3 CRYSTALLOGRAPHY Pub Date : 2024-10-09 DOI: 10.1016/j.jcrysgro.2024.127925
Eunseo Lee, Younghee So, Sungwook Mhin
Since the initial exploration of synthesis possibilities at a liquid–solid interface through pulsed laser irradiation of iron in water, the pulsed laser ablation in liquid media (PLAL) process has garnered significant attention for constructing various nanostructures due to its simple, ultrafast, and clean methodology that avoids byproduct formation. Recent advances in functionalized heterostructures via the PLAL process suggest a broad range of applications for energy- conversion systems, including water splitting and energy harvesting. This review surveys recent advancements in PLAL for energy applications, with a specific focus on its applications in oxygen evolution reaction (OER) electrocatalysts and energy harvesting devices. The review discusses the synthesis mechanisms, advantages, challenges, and future research directions of PLAL, aiming to provide a comprehensive understanding of its potential and limitations.
自最初探索通过脉冲激光照射水中的铁在液固界面合成的可能性以来,液体介质中的脉冲激光烧蚀(PLAL)工艺因其简单、超快、清洁且避免副产品形成的方法,在构建各种纳米结构方面获得了极大的关注。通过 PLAL 工艺构建功能化异质结构的最新进展表明,该工艺可广泛应用于能量转换系统,包括水分离和能量收集。本综述探讨了 PLAL 在能源应用方面的最新进展,特别关注其在氧进化反应(OER)电催化剂和能量收集装置中的应用。综述讨论了 PLAL 的合成机制、优势、挑战和未来研究方向,旨在提供对其潜力和局限性的全面了解。
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引用次数: 0
期刊
Journal of Crystal Growth
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