Journal of Industrial and Engineering Chemistry最新文献

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Sustainable synthesis of functional zeolites from waste OLED powder for heavy metal adsorption and barium immobilization 废OLED粉末可持续合成功能沸石用于重金属吸附和钡固定化

IF 6.1 3区工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of Industrial and Engineering Chemistry

Pub Date : 2025-11-12 DOI: 10.1016/j.jiec.2025.11.020

Min-Chang Kang, Goeun Jun, Geun U Ryu, Sukhoon Pyo

引用次数: 0

Modeling arrhenius kinetics in CNT aerogel synthesis via FC-CVD using a CFD–machine learning hybrid framework 利用cfd -机器学习混合框架模拟FC-CVD碳纳米管气凝胶合成中的arrhenius动力学

IF 6.1 3区工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of Industrial and Engineering Chemistry

Pub Date : 2025-11-11 DOI: 10.1016/j.jiec.2025.11.019

Jiho You, Sook Young Moon, Bonchan Koo, Seung-Yeol Jeon

引用次数: 0

Recycling of Li and transition metals from spent lithium-ion batteries cathodes by sequential formic acid and deep eutectic solvent leaching 从废锂离子电池阴极中回收锂和过渡金属的顺序甲酸和深度共熔溶剂浸出

IF 6.1 3区工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of Industrial and Engineering Chemistry

Pub Date : 2025-11-10 DOI: 10.1016/j.jiec.2025.11.004

Huijuan Guo, Keyu Chen, Jun Wang, Khomidov Fakhriddin Gafurovich, Kadyrova Zulayho Raimovna, Linqiang Mao

引用次数: 0

Fabrication of polypyrrole/nanofibrillated cellulose/safranin sponge-like aerogels for enhanced conductivity and chromium ions adsorption capacity 聚吡咯/纳米纤化纤维素/红花色素海绵状气凝胶的制备，增强其电导率和铬离子吸附能力

IF 6.1 3区工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of Industrial and Engineering Chemistry

Pub Date : 2025-11-09 DOI: 10.1016/j.jiec.2025.11.010

Islam M. Minisy, Zuzana Morávková, Oumayma Taboubi, Jiřina Hromádková, Miloslav Lhotka, Jana Houdkova, Oleksandr Romanyuk, Patrycja Bober

引用次数: 0

γ-Oryzanol selective purification from rice bran oils by tunable properties CO2-expanded ethyl lactate: a molecular dynamics simulation study 利用可调性质从米糠油中选择性提纯γ-谷丙醇co2膨胀乳酸乙酯：分子动力学模拟研究

IF 6.1 3区工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of Industrial and Engineering Chemistry

Pub Date : 2025-11-08 DOI: 10.1016/j.jiec.2025.11.001

Guoxiao Cai, Chang Yi Kong

引用次数: 0

Flexible MIL-53(Al)/Biochar composite for enhanced norfloxacin Removal: Synergistic effects and adsorption mechanisms 柔性MIL-53(Al)/生物炭复合材料增强诺氟沙星去除：协同效应和吸附机理

IF 5.9 3区工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of Industrial and Engineering Chemistry

Pub Date : 2025-11-03 DOI: 10.1016/j.jiec.2025.11.002

Pisit Phayutcharoenkun , Samson B. Akindoye , Rajendran Chandran , Anh N. Phan , Long T. Duong , Amornchai Arpornwichanop , Phuet Prasertcharoensuk

The presence of antibiotic contaminants, particularly norfloxacin (NRFX) in aquatic environments poses a significant threat to ecosystems and public health, due to their persistence, bioaccumulation, and contribution to antimicrobial resistance. In this study, a novel MIL-53(Al)/biochar composite was synthesized and applied for NRFX removal from wastewater. The synthesized composite exhibited a high surface area (806 m²/g) and mesopore structure, promoting to improved dispersion and adsorption efficiency. Under optimal conditions (20 mg/L NRFX, 40 mg/L adsorbent, 30 °C, 120 min), the composite achieved a maximum adsorption capacity of 357 mg/g, surpassing most reported antibiotic sorbents (< 250 mg/g). The superior performance was attributed to the synergistic integration of MIL-53(Al) flexible “wine-rack” framework with the oxygen-functionalized, mesoporous carbon matrix of bamboo-derived biochar, facilitating multiple adsorption mechanisms, including electrostatic attraction, hydrogen bonding, π–π interactions, and pore-filling effects. These findings highlight the potential of MIL-53(Al)/BC as a cost‑effective, sustainable, and high‑performance adsorbent with strong potential for real-world remediation of antibiotic-contaminated wastewater under diverse environmental conditions.

抗生素污染物，特别是诺氟沙星（NRFX）在水生环境中的存在，由于其持久性、生物蓄积性和对抗菌素耐药性的贡献，对生态系统和公众健康构成重大威胁。本研究合成了一种新型MIL-53(Al)/生物炭复合材料，并将其应用于废水中NRFX的去除。合成的复合材料具有较高的比表面积（806 m2/g）和介孔结构，促进了分散和吸附效率的提高。在最佳条件下（20 mg/L NRFX， 40 mg/L吸附剂，30°C, 120 min），该复合材料的最大吸附量为357 mg/g，超过了大多数报道的抗生素吸附剂（250 mg/g）。MIL-53（Al）柔性“酒架”框架与竹源生物炭的氧功能化介孔碳基质协同集成，促进了多种吸附机制，包括静电吸引、氢键、π -π相互作用和孔隙填充效应。这些发现突出了MIL-53(Al)/BC作为一种具有成本效益，可持续发展和高性能的吸附剂的潜力，具有在各种环境条件下修复抗生素污染废水的强大潜力。

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引用次数: 0

Design of FeCoNiSmNd-co-doped porous carbon catalysts from pulverized coal for radical and non-radical peroxymonosulfate activation in organic pollutant degradation 煤粉中feconismn共掺杂多孔碳催化剂的设计及其对自由基和非自由基过氧单硫酸盐的活化降解

IF 6.1 3区工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of Industrial and Engineering Chemistry

Pub Date : 2025-11-01 DOI: 10.1016/j.jiec.2025.10.058

Zhen Wu, Lisheng Wang, Xiaohan Wang, Bin Zhao, Heliang Fan, Xueyu Tao, Ming Zheng, Yasser Vasseghian, Akbar Hojjati-Najafabadi, Litong Guo

引用次数: 0

Tailored Siloxane-Based protective coatings for flexible tactile sensors with enhanced wear resistance and compliance 为柔性触觉传感器量身定制的硅氧烷保护涂层，具有增强的耐磨性和依从性

IF 6.1 3区工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of Industrial and Engineering Chemistry

Pub Date : 2025-10-30 DOI: 10.1016/j.jiec.2025.10.056

Hee Seon Choi, Yong-Cheol Jeong

引用次数: 0

Passive vortex-driven mass transfer 被动涡驱动传质

IF 5.9 3区工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of Industrial and Engineering Chemistry

Pub Date : 2025-10-17 DOI: 10.1016/j.jiec.2025.10.018

Faisal Maqbool , Guan-Yu Lu , Ya-Yu Chiang

Parallel flow typically exhibits inefficient mixing due to viscous-dominated laminar regimes, limiting biphasic mass transfer to interfacial molecular diffusion. To overcome this fundamental constraint, we engineered a novel core-annular microextractor featuring a rectangular helical wire core. This unique passive geometry inherently induces controlled vortices directly at the liquid–liquid interface without external energy input. Multiphysics simulations revealed that specific gap widths combined with the helical topology trigger vortex formation as the aqueous phase interacts with the wire pillars, significantly disrupting the diffusion boundary layer. Fluorescent particle tracking experimentally confirmed these interface-proximal vortices, validating the simulation. Crucially, this passive vortex-driven mass transfer mechanism directly enhances interfacial renewal and mixing efficiency. In proof-of-concept extraction of acetophenone/n-heptane systems, the structurally induced vortices within the optimized gap achieved 68.18% acetophenone extraction efficiency, demonstrating how tailored microfluidic architectures can passively amplify mass transfer via localized hydrodynamic manipulation.

由于粘滞占主导地位的层流状态，平行流动通常表现出低效率的混合，限制了双相传质到界面分子扩散。为了克服这一基本限制，我们设计了一种具有矩形螺旋线芯的新型芯环微提取器。这种独特的被动几何形状固有地在液-液界面直接诱导可控涡流，而无需外部能量输入。多物理场模拟表明，当水相与线柱相互作用时，特定的间隙宽度与螺旋拓扑结构相结合会触发涡流的形成，从而显著破坏扩散边界层。荧光粒子跟踪实验证实了这些界面-近端漩涡，验证了模拟。关键是，这种被动涡驱动的传质机制直接提高了界面更新和混合效率。在对苯乙酮/正庚烷体系的概念验证中，优化间隙内的结构诱导涡提取苯乙酮的效率达到68.18%，这表明定制的微流体结构可以通过局部流体动力学操作被动地放大传质。

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引用次数: 0

Insight into the anti-corrosion performance of Red dragon fruit stem extract for copper in sulfuric acid medium 红龙果茎提取物在硫酸介质中对铜的防腐性能研究

IF 5.9 3区工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of Industrial and Engineering Chemistry

Pub Date : 2025-09-24 DOI: 10.1016/j.jiec.2025.09.040

Hui Huang , Lihao Xie , Xinhuan Chen , Wenlong Li , Riadh Marzouki

In this research, we utilized a water-based extraction technique to produce a highly potent red dragon fruit stem extract (RDFSE). We explored the means by which RDFSE inhibits corrosion on copper in an acidic sulfuric acid (H₂SO₄) setting, employing electrochemical assessments, surface analysis methodologies, and computational predictions. The electrochemical tests indicated an inhibition efficiency (IE) of over 93 % for RDFSE at 298 K with 300 mg/L, underscoring its remarkable protective capabilities for copper. These observations were supported by surface analysis outcomes, which were in harmony with the electrochemical findings. Further examination of the isotherm model confirmed that the bonding between RDFSE and copper surfaces aligns with the Langmuir adsorption. Computational analyses demonstrated that the active constituents within RDFSE possess strong anti-corrosive characteristics. For the first time, it is demonstrated that RDFSE can effectively inhibit the corrosion of copper in sulfuric acid medium.

在本研究中，我们利用水基提取技术制备了一种高效的红龙果茎提取物（RDFSE）。我们探索了RDFSE在酸性硫酸（H2SO4）环境中抑制铜腐蚀的方法，包括电化学评估、表面分析方法和计算预测。电化学测试表明，在298 K、300 mg/L的条件下，对RDFSE的抑制率（IE）超过93%，表明其对铜具有显著的保护作用。这些观察结果得到了表面分析结果的支持，这与电化学结果是一致的。对等温线模型的进一步研究证实，RDFSE与铜表面之间的键合符合Langmuir吸附。计算分析表明，RDFSE中的有效成分具有较强的防腐性能。首次证明了RDFSE能有效抑制铜在硫酸介质中的腐蚀。

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引用次数: 0

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