Journal of Industrial and Engineering Chemistry最新文献

{"title":"Progressive innovations in essential oil and their inlaid air filters for bioaerosol control: A review on future outlook","authors":"Sharmin Mst Akter ,&nbsp;Hari Krishnan Yogesh ,&nbsp;Kavitha Govindarajan ,&nbsp;Balkew Zewge Hailemeskel ,&nbsp;Bezuayehu Tadesse Negussie ,&nbsp;Asfaw Negash ,&nbsp;Shohel Mahmud ,&nbsp;Rashika Rajasekhar Kavitha ,&nbsp;Kinjal J. Shah ,&nbsp;Parasuraman Vijayarohini ,&nbsp;Woo Ram Lee ,&nbsp;Seung do Kim","doi":"10.1016/j.jiec.2025.01.002","DOIUrl":"10.1016/j.jiec.2025.01.002","url":null,"abstract":"<div><div>Post-COVID-19 pandemic, for the betterment of human health, developing antimicrobial air filters using generally recognized as safe (GRAS) materials is of interest to reduce indoor bioaerosols and airborne pathogens. Essential oil (EO)-incorporated air filters have a standard momentous attention due to their sustainability and non-toxicity. EOs are biocompatible, environmentally friendly, cost-effective, and nature-derived materials. They have a broad spectrum of antibacterial mechanisms that prevent the bacteria from developing resistance. EO-incorporated air filters are alternatives to existing ultraviolet (UV), plasma, and ozone-based air filters that effectively disinfect pathogens without releasing toxic byproducts into the atmosphere. This review focuses on recent advances in EO-integrated air filters and corresponding air-purification systems, followed by the chemical properties of EOs, antimicrobial mechanisms, pathogen inhibition capacities, encapsulation techniques, and related legislation.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 255-270"},"PeriodicalIF":5.9,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigation of electrode material and applied current density in molten carbonate electrolysis","authors":"Anafi Nur’aini ,&nbsp;Emma Laasonen ,&nbsp;Vesa Ruuskanen ,&nbsp;Tuomas Koiranen ,&nbsp;Pertti Kauranen ,&nbsp;Jero Ahola","doi":"10.1016/j.jiec.2024.12.073","DOIUrl":"10.1016/j.jiec.2024.12.073","url":null,"abstract":"<div><div>Molten carbonate electrolysis is a technology that can convert CO₂ into valuable solid carbon and oxygen gas. Different materials of electrode pairs are considered in molten carbonate electrolysis, including a titanium cathode and a titanium anode (Ti–Ti), a titanium cathode and a nickel anode (Ti–Ni), a titanium cathode and an Alloy X anode (Ti–Ax), a nickel cathode and a titanium anode (Ni–Ti), and an Alloy X cathode and a titanium anode (Ax–Ti). The electrode pairs are assessed based on their electrolysis performance and characteristics of carbon, which are analyzed using scanning electron microscope (SEM), x-ray diffraction (XRD), and energy dispersive spectroscopy (EDS). The results show that the Ti–Ni pair exhibits the most stable potential performance, the highest Faraday and voltage efficiency, the lowest specific electrical energy consumption, and the fastest carbon deposition rate. Moreover, regardless of the anode, the use of titanium as a cathode results in a spherical onion-like shape, while Alloy X as a cathode produces an amorphous structure with some tubular form.</div><div>Based on these results, the effect of the applied current density for the Ti–Ni electrode pair is investigated. The applied current density of 0.1<!--> <!-->A<!--> <!-->cm⁻² shows the highest Faraday efficiency of 67.4% and voltage efficiency of 52.3%. It also has the lowest specific electrical energy consumption for a solid carbon product of 25.9<!--> <!-->kW<!--> <!-->h<!--> <!-->kg⁻¹. The fastest carbon deposition rate is 0.027<!--> <!-->g<!--> <!-->cm⁻² <!-->h⁻¹, which is obtained by applying a current density of 0.4<!--> <!-->A<!--> <!-->cm⁻². The morphology of carbon produced with the applied current density between 0.1 and 0.4<!--> <!-->A<!--> <!-->cm⁻² shows a dominant spherical-like onion shape with a larger diameter at a higher applied current density. Furthermore, some tubular forms are found as a result of the applied current densities of 0.2<!--> <!-->A<!--> <!-->cm⁻² and 0.3<!--> <!-->A<!--> <!-->cm⁻². Plate shapes are also observed, yet only as a result of the applied current density of 0.4<!--> <!-->A<!--> <!-->cm⁻². This finding suggests that the applied current density affects the diameter of the carbon particles, but does not significantly change the morphology.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"144 ","pages":"Pages 792-805"},"PeriodicalIF":5.9,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143372238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The role of emerging photoactive nanostructures in electrochemical sensor construction: Synthesis, properties, challenges, and perspectives","authors":"Ravi Kumar Yohan ,&nbsp;Mohanraj Jagannathan ,&nbsp;Gopi Sivalingam","doi":"10.1016/j.jiec.2024.12.076","DOIUrl":"10.1016/j.jiec.2024.12.076","url":null,"abstract":"<div><div>Functional characteristics with high photoactive and electroactive properties have been emerging as the subject of advanced analytical applications. Recently, significant research has been augmenting the development of photoactive nanomaterials that can be utilized for both qualitative and quantitative determination of analytes for environmental, food, and healthcare applications. This review focuses on recent advancements in photoactive nanostructures for photoelectrochemical (PEC) sensing applications, emphasizing their preparation, functionalization, and electrode construction strategies. Key developments include the rational design of photoactive materials with enhanced photoelectrochemical performances and signal-amplification techniques for improved sensitivity and selectivity. The review highlights the application of PEC sensors for detecting various analytes, such as insecticides, antibiotics, pathogens, carcinogenic compounds, and metabolic disorder markers in environmental, food, and healthcare settings. Current challenges, including material stability, selectivity, and real-world applicability, are critically discussed, along with future research directions for designing next-generation PEC sensors with superior functional properties.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 234-254"},"PeriodicalIF":5.9,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Corrigendum to “Scale-up of dehydrogenation reaction system via heterogeneous metal catalysts for the utilization of by-product glycerol from biodiesel production process” [J. Ind. Eng. Chem. 136 (2024) 211–221]","authors":"Doyeon Song ,&nbsp;Juwon Min ,&nbsp;Seung-Jun Baek ,&nbsp;In-Hyoup Song ,&nbsp;Myung-June Park ,&nbsp;Anil H. Valekar ,&nbsp;Macchindra G. Chandgude ,&nbsp;Young Kyu Hwang ,&nbsp;Kyoung-Su Ha","doi":"10.1016/j.jiec.2024.12.008","DOIUrl":"10.1016/j.jiec.2024.12.008","url":null,"abstract":"","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"144 ","pages":"Page 806"},"PeriodicalIF":5.9,"publicationDate":"2024-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143372239","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The synergistic effect of carboxymethylated cellulose nanocrystals -Polyvinyl alcohol- L Arginine in facilitated transport membranes for biogas purification","authors":"Nithin Mithra S,&nbsp;Sandeep S. Ahankari","doi":"10.1016/j.jiec.2024.12.033","DOIUrl":"10.1016/j.jiec.2024.12.033","url":null,"abstract":"<div><div>Biogas can be used as a renewable energy source to mitigate the use of conventional fuels. However, for this to happen its quality must be improved. Herein biogas purification was carried out utilising membranes with a biodegradable selective layer of carboxymethylated cellulose nanocrystals (C-CNC)/ Polyvinyl alcohol (PVA)- L Arginine nanocomposite coated over highly porous poly(ether-sulfone) (PESF) hollow fibre substrate. Facilitated transport of CO₂ aided by a mobile carrier (L-Arginine) and NaOH as carriers of CO₂ in the hydrophilic C-CNC/PVA under high relative humidity is the principle of this separation process. Concentrations varying from 0-2 wt% of C-CNC in PVA-LA were considered for the study at 90 % RH and varying feed pressures of 0.8–1 bar. CO₂ permeance and selectivity increased with the increase in C-CNC concentration till 1C-CNC/PVA-LA (1 wt% of C-CNC in PVA-LA) (6226 GPU permeance and selectivity of 19). At further higher C-CNC concentrations, a high chance of creating C-CNC-induced pathways through the selective layer could have created higher swelling, hence a reduction in CO₂ permeance (5244 GPU) and reduced selectivity (11) for 2C-CNC/PVA-LA. Overall, a synergistic effect of the hydrophilicity induced by the C-CNC in PVA along with L-Arginine and NaOH for CO₂ transport helped the attainment of biogas purification at low-pressure conditions.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"144 ","pages":"Pages 782-791"},"PeriodicalIF":5.9,"publicationDate":"2024-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143372657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electrospun PAN membrane encapsulated in PEO as a polymer electrolyte for lithium metal batteries","authors":"Waqas Ul Arifeen ,&nbsp;Bhargav Akkinepally ,&nbsp;Zain Ul Abideen ,&nbsp;Iftikhar Hussain ,&nbsp;Masoom Raza Siddiqui ,&nbsp;Shuang Li ,&nbsp;Jaesool Shim ,&nbsp;Tae Jo Ko","doi":"10.1016/j.jiec.2024.11.054","DOIUrl":"10.1016/j.jiec.2024.11.054","url":null,"abstract":"<div><div>The novel two-step fabrication method of polymer electrolyte membrane was proposed. In the first step, the polyacrylonitrile nano fibrous membrane was prepared with the help of electrospinning. In the second step, the polyethylene oxide solution was prepared along with lithium salt and plasticizers. The solution was poured on the electrospun polyacrylonitrile to get polymer electrolyte membrane in the form of PAN membrane encapsulated in PEO. The polymer electrolyte membrane was boosted by the liquid LiPF₆ before assembled in the lithium metal batteries. The polymer electrolyte membrane was compared with the commercial Celgard separator when assembled in coin cell for the application of lithium metal batteries. The polymer electrolyte membrane outperformed and exhibited a good ultimate tensile strength of 20 MPa and the better thermal stability of 97 % at 305 °C. Moreover, the polymer electrolyte membrane also exhibited excellent ionic conductivity of 1.2 mS cm⁻¹, good lithium-ion transference number of 0.57 and uniform lithium plating/stripping cycles for up to 500 cycles without internal short circuiting. The polymer electrolyte membrane represented outstanding rate capability and exhibited the good discharge capacity of 141 mA h g⁻¹ after 100 cycles at 0.5 C rate.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"142 ","pages":"Pages 746-752"},"PeriodicalIF":5.9,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143135992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"MXene mastery: Transforming supercapacitors through solid-solution innovations","authors":"Yedluri Anil Kumar ,&nbsp;Reddi Mohan Naidu Kalla ,&nbsp;Tholkappiyan Ramachandran ,&nbsp;Ahmed M. Fouda ,&nbsp;H.H. Hegazy ,&nbsp;Md Moniruzzaman ,&nbsp;Jaewoong Lee","doi":"10.1016/j.jiec.2024.11.049","DOIUrl":"10.1016/j.jiec.2024.11.049","url":null,"abstract":"<div><div>Exploring innovative materials for supercapacitors has been a focus to broaden energy storage alternatives. The distinctive properties and applications of solid-solution MXenes have garnered significant attention in this regard. This research delves into the application of solid-solution MXene materials in supercapacitor energy storage, examining aspects such as manufacturing, electrochemical behaviour, and structural characteristics. The article begins with an overview of the MXene family, highlighting its potential for energy storage, a highly sought-after quality. The solid-solution approach is particularly favoured for its ability to enhance MXenes electrochemical properties by introducing additional components. This study explores how etching, and intercalation impact the material’s structure and energy storage capabilities. Detailed analyses of the crystallographic, surface chemical, and morphological properties of solid-solution MXenes are conducted. The study emphasizes the influence of these factors on the electrochemical performance of MXene supercapacitors, stressing the importance of tailored design. The research extensively investigates the durability, electrical storage capacity, and charge retention mechanisms of these materials. Understanding the effects of dopants and intercalants on charge storage dynamics could lead to improvements in MXene electrode energy storage. The paper reviews the current advancements, challenges, and the potential of solid-solution MXenes in supercapacitors. With a careful examination of existing research and strategic selection of constituents, solid-solution MXene materials could play a crucial role in future energy storage systems, providing a valuable tool for engineers and scientists exploring renewable energy storage technologies.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 216-233"},"PeriodicalIF":5.9,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A novel fluorescent probe with a large Stokes shift targeting lysosomes and lipid droplets and its application to cellular imaging","authors":"Lin Wang ,&nbsp;Cong-Cong Li ,&nbsp;Jia-xin Cao ,&nbsp;Jian-Yong Wang","doi":"10.1016/j.jiec.2024.10.065","DOIUrl":"10.1016/j.jiec.2024.10.065","url":null,"abstract":"<div><div>Lipid droplets and lysosomes are crucial organelles that play significant roles in cellular metabolism. Therefore, studying both lipid droplets and lysosomes simultaneously holds great value. A new fluorescent probe <strong>BTD-Lyso</strong> was designed based on the principle of intramolecular charge transfer (ICT). The probe was formed with a typical D-π-A structure, and it used benzothiadiazole as the electronic acceptor and morpholine as the electronic donor. The experimental results showed that <strong>BTD-Lyso</strong> was able to detect the change of polarity in the microenvironment. Furthermore, the probe showed a large Stokes shift (300 nm), excellent selectivity, polarity sensitivity, and photostability. In addition, it could be successfully utilized in cellular imaging due to its low cytotoxicity and could target lipid droplets and lysosomes well.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 686-692"},"PeriodicalIF":5.9,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488876","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advancements in transition metal sulfide supercapacitors: A focused review on high-performance energy storage","authors":"Mohammad Shariq ,&nbsp;Dalal Alhashmialameer ,&nbsp;Hind Adawi ,&nbsp;Mazen R. Alrahili ,&nbsp;Majed Y.A. Almashnowi ,&nbsp;Ali Alzahrani ,&nbsp;Mukul Sharma ,&nbsp;Syed Kashif Ali ,&nbsp;Y. Slimani","doi":"10.1016/j.jiec.2024.11.012","DOIUrl":"10.1016/j.jiec.2024.11.012","url":null,"abstract":"<div><div>The advancement of efficient energy storage technologies has become a critical area of focus in recent years. Transition metal sulfides (TMSs), due to their superior redox properties, high electrical conductivity, and excellent theoretical capacitance, have emerged as highly promising electrode materials for next-generation supercapacitors. Through compositional and structural engineering, significant improvements have been achieved in the electrochemical performance of TMSs, including materials based on Mn, V, Co, Fe, Ni, Mo, Zn, W, and Sn. Key strategies for enhancing TMS electrodes include morphological control and composite engineering, both of which have proven instrumental in addressing fundamental challenges such as slow reaction kinetics, limited structural stability, and significant volume expansion during charge/discharge cycles. This study highlights the transformative potential of optimized TMSs, particularly when paired with advanced electrochemical catalysts, to overcome these barriers and drive the development of high-performance supercapacitors. TMS-based electrodes improve charge storage mechanisms, solving energy storage system problems and enabling future, cost-effective, and sustainable energy storage technologies. This study tackles crucial information gaps in charge storage kinetics and processes, suggesting possibilities to innovate in this field. This research concludes an in-depth exploration of the opportunities, challenges, and potential strategies for leveraging TMSs to shape the future of high-efficiency supercapacitors.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"144 ","pages":"Pages 269-291"},"PeriodicalIF":5.9,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143372323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhancing the biorefinery of brewery spent grain by deep eutectic solvent pretreatment: Optimisation of polysaccharide enrichment through a response surface methodology","authors":"M.G. Morán-Aguilar ,&nbsp;I. Costa-Trigo ,&nbsp;M. Calderón-Santoyo ,&nbsp;M.G. Aguilar-Uscanga ,&nbsp;R. Pinheiro de Souza Oliveira ,&nbsp;J.M. Domínguez","doi":"10.1016/j.jiec.2024.10.066","DOIUrl":"10.1016/j.jiec.2024.10.066","url":null,"abstract":"<div><div>One of the main challenges in biorefinery is the efficient fractionation and use of lignocellulosic biomass. In this sense, pretreatment with deep eutectic solvents (DES) is highlighted as a clean and effective separation method, due to its selective solubilisation of hemicellulose and lignin fractions while preserving cellulose. This study presents a process of the enrichment of polysaccharide content and the improvement of enzymatic digestibility using choline chloride (ChCl) and lactic acid (LA) or glycerol (Gly) in brewery spent grain (BSG) pretreatment. Additionally, it describes how improvements can be made in obtaining polysaccharide-rich material through a response surface methodology, this by means of analysing the operational conditions (temperature, reaction time, and molar ratio) using ChCl:LA. The optimised operational conditions (130 °C, 90 min, and 1:8 mol/mol) generate a 75 % enrichment of polysaccharide fraction and the removal of 77.13 %, 50.70 %, and 100 % of acid-soluble lignin, xylan, and arabinan, respectively. Moreover, the process enhances the saccharification of glucan and xylan to almost 70 % using Cellic CTec2, and to 80 % of glucan and 40 % of xylan using <em>A. niger</em> CECT 2700 enzymatic extract. This constitutes a promising approach to the fractioning of cellulose and lignin from BSG through DES pretreatment, which is unfeasible using traditional pretreatment methods.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 693-704"},"PeriodicalIF":5.9,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}