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Developing Self-Cleaning Photocatalytic TiO2 Nanocomposite Coatings 自清洁光催化TiO2纳米复合涂层的研制
Q4 Materials Science Pub Date : 2023-06-16 DOI: 10.4018/ijseims.324757
Jean Claude Mallia, Anthea Agius Anastasi, S. Briffa
Photocatalytic coatings with self-cleaning properties are becoming increasingly more popular due to the increased awareness of the importance of cleaning and the associated high cost of cleaning supplies and services. This research investigated self-cleaning photocatalytic polydimethylsiloxane (PDMS)/titanium dioxide (TiO2) nanocomposite coatings and focused on selecting the optimal TiO2 phase and concentration. To date, the comparison of the different TiO2 phases as a nanocomposite coating has not been sufficiently considered. PDMS/TiO2 nanocomposite coatings with three nanomaterial (NM) samples (an anatase, rutile, and mixed phase) and three concentrations of TiO2 (0.6, 1 and 3 w/v%) were prepared, applied to glass slides by dip coating, and tested with respect to hydrophobicity, surface stability, antifogging, and photocatalytic properties. It was found that a stable hydrophobic coating with the optimal photocatalyitc performance was produced with 3 w/v% anatase TiO2.
由于人们越来越意识到清洁的重要性以及清洁用品和服务的相关高成本,具有自清洁性能的光催化涂层越来越受欢迎。本研究对自清洁光催化聚二甲基硅氧烷(PDMS)/二氧化钛(TiO2)纳米复合涂层进行了研究,并重点选择了最佳的TiO2相和浓度。迄今为止,尚未充分考虑作为纳米复合涂层的不同TiO2相的比较。制备了具有三种纳米材料(NM)样品(锐钛矿、金红石和混合相)和三种浓度的TiO2(0.6、1和3w/v%)的PDMS/TiO2纳米复合涂层,通过浸涂将其应用于载玻片上,并测试了疏水性、表面稳定性、防雾和光催化性能。研究发现,用3w/v%的锐钛矿TiO2制备了具有最佳光催化性能的稳定疏水涂层。
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引用次数: 0
Microsrtructural and mechanical characterization of HVOF sprayed Ni-based alloy coating HVOF喷涂镍基合金涂层的微观结构和力学性能
Q4 Materials Science Pub Date : 2022-01-01 DOI: 10.4018/ijseims.298705
The various engineering components works under aggressive environments include the furnace parts, sliding parts in lathe machine and exhaust manifolds. Cast iron is used in these applications and important intention of this research work is to study on enhance the useful period of life.HVOF (High Velocity Oxy-fuel) sprayed Alloy-718coatings on cast iron were analysed. Coatings were characterised by field emission scanning electron microscopy (FE-SEM), Optical microscope (OM) and X-ray diffraction for its microstructural analysis. Energy dispersive spectroscopy (EDS) of the bare and coated samples was used to confirm the elemental details of the powder and the coating. Porosity measurements were taken and showed the 1.6% for Alloy-718 coating. Microhardness investigation was conducted for the Alloy-718 coating, and it was resulted as 560±20 HV. The bare material has hardness of 225±10, and there is a substantial difference of hardness found as 2.5 times higher. The fracture toughness was found to be 4.0 MPa.m1/2.
各种工程部件在恶劣的环境中工作,包括熔炉部件、车床中的滑动部件和排气歧管。铸铁被用于这些应用,本研究工作的重要目的是研究如何提高使用寿命。分析了高速氧燃料HVOF在铸铁表面喷涂718合金涂层的性能。通过场发射扫描电子显微镜(FE-SEM)、光学显微镜(OM)和X射线衍射对涂层的微观结构进行了表征。使用裸样品和涂层样品的能量色散光谱(EDS)来确认粉末和涂层的元素细节。进行孔隙率测量,结果显示Alloy-718涂层的孔隙率为1.6%。对合金718涂层进行了显微硬度研究,结果为560±20HV。裸露材料的硬度为225±10,硬度相差2.5倍。断裂韧性为4.0 MPa.m1/2。
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引用次数: 1
Effect of Carbonization of Orange Peel Particulate-Reinforced Polymer Composites 橘皮颗粒增强聚合物复合材料的碳化作用
Q4 Materials Science Pub Date : 2022-01-01 DOI: 10.4018/ijseims.295097
P. Naik, Smitirupa Pradhan, S. K. Acharya, P. Sahoo
Carbon black is the most promising filler material in polymer industries for fabrication of composite materials because of its unique properties and strength. In the present study, carbon black particles are developed from orange peel particulates (OPP) by pyrolysis approach at different carbonization temperatures (400oC, 600oC and 800oC). The raw and carbon black OPP materials are used as reinforcement to fabricate epoxy composites that are evaluated for mechanical and morphological properties following ASTM standard. Proximate analysis reveals that the amount of carbon content increases significantly (up to 74.42 % at 800°C) due to the carbonization. Tensile and flexural strength increase with increasing carbonization temperature and maximum value is observed in case of 800°C. SEM observations indicate good interfacial bonding between filler and matrix materials. Weight of the composite is reduced due to carbonization of raw material. TGA study of carbon black material reveals that the thermal stability increases with increase in carbonization temperature.
炭黑具有独特的性能和强度,是聚合物工业中最有前途的复合材料填充材料。在本研究中,炭黑颗粒是由陈皮颗粒(OPP)在不同碳化温度(400℃、600℃和800℃)下通过热解方法形成的。原料和炭黑OPP材料被用作增强材料,以制造环氧复合材料,该复合材料根据ASTM标准进行机械和形态性能评估。近似分析表明,由于碳化,碳含量显著增加(在800°C时高达74.42%)。拉伸和弯曲强度随着碳化温度的升高而增加,在800°C的情况下观察到最大值。SEM观察结果表明填料和基体材料之间具有良好的界面结合。由于原料的碳化,复合材料的重量减少。对炭黑材料的TGA研究表明,随着炭化温度的升高,炭黑材料的热稳定性增强。
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引用次数: 0
Investigation of mechanical & tribological properties of LM6 – fly ash metal matrix composites LM6 -粉煤灰金属基复合材料力学与摩擦学性能研究
Q4 Materials Science Pub Date : 2022-01-01 DOI: 10.4018/ijseims.302235
Composite materials assume a significant part in auto, aviation, marine and defense applications due to its unique properties. Aluminum alloys have certain advantages than other alloys. In this paper the composite material comprises of Aluminum Alloy LM6 and fly ash (150 – 175 μm) has been picked as lattice and supporting materials individually. Magnesium is added to lessen the surface pressure and evades the dismissal of the particles from the melts. Liquid state processing through Stir casting procedure was adopted for fabrication of mmc into necessary shape and size according to the ASTM principles by energetically mixing at consistent speed and time. The fly ash with various syntheses (2%, 4%, 6%) were added with LM6 combination. XRD, EDAX were used to examine the structural analysis of MMC and optical microscopy & SEM were used to investigate the microstructure on MMC. Wear test also carried out on MMC to ascertain the wear rate and cof of different MMCs. There is substantial improvement of mechanical properties like tensile strength, micro hardness & density of the composite.
复合材料由于其独特的性能,在汽车、航空、海洋和国防应用中发挥着重要作用。铝合金比其他合金具有某些优点。本文选用LM6铝合金和粉煤灰(150–175μm)复合材料分别作为格栅和支撑材料。添加镁是为了减轻表面压力,避免熔体中颗粒的排出。根据ASTM原理,采用搅拌铸造的液态工艺,以一致的速度和时间大力搅拌,将mmc制成必要的形状和尺寸。将LM6组合加入到不同合成方法(2%、4%、6%)的粉煤灰中。用XRD、EDAX对MMC进行了结构分析,用光学显微镜和扫描电镜研究了MMC的微观结构。还对MMC进行了磨损试验,以确定不同MMC的磨损率和cof。复合材料的拉伸强度、显微硬度和密度等力学性能有了显著提高。
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引用次数: 0
Effect of Yield Strength on the Static and Dynamic Behaviours of Cylindrical Contact 屈服强度对圆柱接触静动态特性的影响
Q4 Materials Science Pub Date : 2022-01-01 DOI: 10.4018/ijseims.304806
Tamonash Jana, A. Mitra, P. Sahoo
The present paper considers the influence of yield strength on static and dynamic behaviour of cylindrical contact interface. The semi-cylinder is assumed to be in plane stress condition. A quasi-static analysis is executed by means of finite element (FE) software package ANSYS 18.2 to obtain several contact parameters. A key parameter, quantifying nonlinearity for the single-asperity cylindrical contact system is educed from the interference-contact force plot. The dynamic characteristics of the cylindrical contact interface is investigated by utilizing this parameter. In order to investigate the same, the contact interface is represented by a single degree of freedom spring-mass-damper system and the analysis is carried out for free-undamped as well as forced-damped vibration. It is found that, with higher Young’s modulus, the dynamic contact system becomes more nonlinear in nature. It is found that, with lower value of yield strength, the dynamic contact system becomes more nonlinear in nature. Moreover, the contact system is found to possess hardening type of nonlinearity.
本文考虑了屈服强度对圆柱接触界面静态和动态特性的影响。假设半圆柱体处于平面应力状态。利用有限元软件包ANSYS 18.2进行准静态分析,以获得几个接触参数。从干涉接触力图中导出了单凸柱面接触系统的一个关键参数,即量化非线性。利用该参数对圆柱接触界面的动力学特性进行了研究。为了研究这一点,接触界面由单自由度弹簧-质量阻尼器系统表示,并对自由无阻尼和强迫阻尼振动进行了分析。研究发现,随着杨氏模量的增加,动态接触系统在本质上变得更加非线性。研究发现,随着屈服强度值的降低,动态接触系统在本质上变得更加非线性。此外,发现接触系统具有硬化型非线性。
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引用次数: 0
Influence of temperature and applied load on adhesion and abrasion wear characteristics of Ti6Al4V alloy 温度和载荷对Ti6Al4V合金粘着磨损特性的影响
Q4 Materials Science Pub Date : 2022-01-01 DOI: 10.4018/ijseims.302234
Over the last decade, research on high-temperature tribological characteristics of Ti6Al4V alloy has been gathered significant interest due to their sustainable properties in high-temperature applications. Adhesion and abrasion have been identified as the most prevalent wear mechanism in the tribological system operated under high temperatures. Hence, the present study aimed to investigate the high-temperature wear behavior of titanium alloys under a vacuum environment and various operating conditions in order to explore the formation of no-oxide tribo layers and the governing wear mechanisms. The transition of materials from both the worn surfaces (Pin and Disc) has been demonstrated. The microstructural characteristics of the worn surfaces and cross-sections revealed the formation of no-oxide tribo-layers which significantly influenced the wear rates as well as governed wear mechanisms. Due to the formation of no-oxide layers, the coefficient of friction was observed to increase with increasing the temperature and load.
近十年来,由于Ti6Al4V合金在高温应用中的持续性能,对其高温摩擦学特性的研究引起了人们的极大兴趣。在高温下工作的摩擦系统中,粘着和磨损是最普遍的磨损机制。因此,本研究旨在研究钛合金在真空环境和不同操作条件下的高温磨损行为,以探索无氧化物摩擦层的形成及其控制磨损机制。材料的过渡从两个磨损表面(销和盘)已被证明。磨损表面和横截面的显微组织特征表明无氧化物摩擦层的形成对磨损速率和磨损机理有显著影响。由于无氧化层的形成,摩擦系数随温度和载荷的增加而增加。
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引用次数: 0
On the Development of an Automated Adaptive Polishing System 自动自适应抛光系统的研制
Q4 Materials Science Pub Date : 2022-01-01 DOI: 10.4018/ijseims.313668
A. Baraati, D. Afonso, Ricardo Guincho
The emerge of Industrial 4.0 revolution and influences to production, information, and communication technologies have made manufacturers capable of reaching higher performance in the last decade. Making smart operations has been set as a top strategy of manufacturing societies, and machinery industry as an integral part of production has been highlighted develop. Aerospace, automotive, metals, glass, and plastics industries have been pioneers to improve, optimize, and develop automated polishing as a final operation of surface finishing process considering of KPIs: quality, time, cost, and safety. In this review, after mentioning the state of the art of last relevant papers, some clues for future research will be presented.
工业4.0革命的出现及其对生产、信息和通信技术的影响使制造商能够在过去十年中达到更高的性能。智能运营被确立为制造业社会的最高战略,机械工业作为生产的重要组成部分得到了突出发展。航空航天、汽车、金属、玻璃和塑料行业一直是改进、优化和开发自动化抛光的先驱,并将其作为考虑到质量、时间、成本和安全等关键绩效指标(kpi)的表面处理过程的最终操作。在本文的回顾中,在提及最近相关论文的研究现状后,将提出一些未来研究的线索。
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引用次数: 0
Prediction of Surface Roughness During Dry Sliding Wear 干滑动磨损过程中表面粗糙度的预测
Q4 Materials Science Pub Date : 2022-01-01 DOI: 10.4018/ijseims.2022010104
B. Lal, Abhijit Dey, Mohamamd Farooq Wani
Due to the relatively low strength and poor wear resistance of unalloyed titanium and its good mechanical properties, corrosion resistance, and biocompatibility. Ti6Al4V has been extensively used in various type of application including aerospace, biomedical and offshore industries. The goal of this research is to enhance the surface properties of the high strength alloys are examine such as Ti6Al4V pin sliding against Al2O3disc, due to the various surfaces roughness parameters. The COF and the wear rate were found to be lower at higher applied load due to higher frictional heating leading to thermal oxidation and thereby formation of several mm thick tribo-layers on the worn surfaces. Characterization of the tribological sample was performed using a scanning electron microscope (SEM) equipped with energy dispersive X-ray analysis (EDAX) to ensure that the wear pattern and debris morphologies of the Ti6Al4V and alumina disks were distinct, suggesting a surface roughness value determined by 3D profilometer at various load and sliding speed of 0.01ms-1.
由于非合金钛的强度相对较低,耐磨性较差,且具有良好的机械性能、耐腐蚀性和生物相容性。Ti6Al4V已被广泛应用于各种类型的应用,包括航空航天、生物医学和海上工业。本研究的目的是提高高强度合金的表面性能,如Ti6Al4V销在Al2O3disc上滑动,这是由于不同的表面粗糙度参数。发现在较高的施加载荷下,由于较高的摩擦加热导致热氧化,从而在磨损表面上形成几毫米厚的摩擦层,COF和磨损率较低。使用配备有能量色散X射线分析(EDAX)的扫描电子显微镜(SEM)对摩擦学样品进行表征,以确保Ti6Al4V和氧化铝盘的磨损模式和碎片形态不同,表明在不同载荷和滑动速度下,通过3D轮廓仪测得的表面粗糙度值为0.01ms-1。
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引用次数: 0
Role of Reinforcement Particle Size and Its Dispersion on Room Temperature Dry Sliding Wear of AA7075/TiB2 Composites 增强颗粒尺寸及其分散性对AA7075/TiB2复合材料室温干滑动磨损的影响
Q4 Materials Science Pub Date : 2022-01-01 DOI: 10.4018/ijseims.2022010102
V. V. Meti, G. Raju, I. G. Siddhalingeshwar, V. Gaitonde
Aluminum alloy based metal matrix composites (AMCs) are widely accepted material in the aerospace, automotive, military, and defence applications due to lightweight and high strength. For tribological applications, high-performance wear-resistant materials like AMCs are the candidate materials. In this investigation, AA7075 based composites with different size TiB2 particles were fabricated using in-situ and ultrasound casting techniques (UST). The AMCs were tested using pin-on-disc tribo tester and the effects of different sized TiB2 particles on wear resistance of AA7075/TiB2 composites have been investigated. The wear resistance of AA7075/TiB2 composite fabricated using UST is found to significantly improve when compared to base alloy and also in-situ composite due to refinement in the particle size, reduced the agglomeration, and improved the distribution of TiB2 particles. The test results also revealed the existence of a mixture of mechanically mixed Al–Zn–Fe intermetallic alloy and oxides of these elements.
铝合金基金属基复合材料(AMCs)由于重量轻、强度高,在航空航天、汽车、军事和国防应用中被广泛接受。对于摩擦学应用,高性能耐磨材料如amc是候选材料。采用原位铸造和超声铸造技术制备了不同尺寸TiB2颗粒的AA7075基复合材料。采用针盘式摩擦试验机对复合材料进行了测试,研究了不同尺寸TiB2颗粒对AA7075/TiB2复合材料耐磨性能的影响。与基体合金和原位复合材料相比,UST制备的AA7075/TiB2复合材料的耐磨性得到了显著提高,这是由于晶粒尺寸的细化,减少了团聚,改善了TiB2颗粒的分布。试验结果还揭示了机械混合的Al-Zn-Fe金属间合金及其氧化物的存在。
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引用次数: 0
Effect of Coating Bath Parameters on Properties of Electroless Nickel-Boron Alloy Coatings 镀液参数对化学镀镍硼合金镀层性能的影响
Q4 Materials Science Pub Date : 2022-01-01 DOI: 10.4018/ijseims.2022010101
Electroless nickel-boron binary coatings were obtained with various bath compositions to investigate the effect of bath parameters on tribological and mechanical behaviours of the coating. Characterisation of the coating for surface morphology and phase structure is done using Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD), respectively, whereas tribological behaviour of coatings is evaluated on a pin-on-disc tribo-tester. Elastic modulus and surface hardness of coatings have been obtained using nano-indentation technique, while the scratch behaviour of the coatings has been determined using micro-scratch test. Corrosion resistance of coatings is also determined. It is observed that surface roughness of the coatings increased with increase in sodium borohydride concentration but decreased slightly with increase in nickel chloride concentration. Friction and wear characteristics are found to increase with surface roughness which occurs due to increased boron content. Surface hardness and scratch hardness are also seen to vary with coating bath parameters.
制备了不同镀液组成的镍硼二元化学镀层,研究了镀液参数对镀层摩擦学和力学性能的影响。分别使用扫描电子显微镜(SEM)和X射线衍射(XRD)对涂层的表面形态和相结构进行表征,而在销-盘摩擦测试仪上评估涂层的摩擦学行为。用纳米压痕技术获得了涂层的弹性模量和表面硬度,并用微划痕试验测定了涂层的划痕行为。还测定了涂层的耐腐蚀性。观察到涂层的表面粗糙度随着硼氢化钠浓度的增加而增加,但随着氯化镍浓度的增加略有下降。发现摩擦和磨损特性随着表面粗糙度的增加而增加,这是由于硼含量的增加而发生的。表面硬度和划痕硬度也随着涂层浴参数的变化而变化。
{"title":"Effect of Coating Bath Parameters on Properties of Electroless Nickel-Boron Alloy Coatings","authors":"","doi":"10.4018/ijseims.2022010101","DOIUrl":"https://doi.org/10.4018/ijseims.2022010101","url":null,"abstract":"Electroless nickel-boron binary coatings were obtained with various bath compositions to investigate the effect of bath parameters on tribological and mechanical behaviours of the coating. Characterisation of the coating for surface morphology and phase structure is done using Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD), respectively, whereas tribological behaviour of coatings is evaluated on a pin-on-disc tribo-tester. Elastic modulus and surface hardness of coatings have been obtained using nano-indentation technique, while the scratch behaviour of the coatings has been determined using micro-scratch test. Corrosion resistance of coatings is also determined. It is observed that surface roughness of the coatings increased with increase in sodium borohydride concentration but decreased slightly with increase in nickel chloride concentration. Friction and wear characteristics are found to increase with surface roughness which occurs due to increased boron content. Surface hardness and scratch hardness are also seen to vary with coating bath parameters.","PeriodicalId":37123,"journal":{"name":"International Journal of Surface Engineering and Interdisciplinary Materials Science","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42805931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
期刊
International Journal of Surface Engineering and Interdisciplinary Materials Science
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