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Mechanochromic luminescent derivatives based on xanthenone and thioxanthenone for the fabrication of OLED devices as emitter layer 基于杂蒽酮和硫杂蒽酮的机械致变色发光衍生物制备OLED器件的发射层
Pub Date : 2023-06-09 DOI: 10.1117/12.2668347
S. Nasiri, G. Janusas
New compounds consisting of xanthenone and thioxanthenone derivatives are synthesized and the photophysical properties of the compounds are discussed in detail. The difference between singlet and triplet energies was obtained at 0.09 and 0.37 eV (at low temperature). Furthermore, the logarithm of the laser power versus the logarithm of the PL intensity showed a slope of less than 1, and the compounds exhibit thermally activated delayed fluorescence (TADF). In addition, the photoluminescence quantum yield of the spin-coated films was gained 51.83 and 41.22%, respectively. The powder X-ray diffraction of the grinded (under the force) compounds and also the PL spectrum of the compounds were shifted and the compounds were mechanochromic when the color of the compounds was changed. The ionization potential of the compounds showed (5.49 and 5.62 eV) that the compounds were well suited for using in the fabrication of OLED devices as an emitter layer. The performance of the OLEDs was investigated and the maximum brightness and external quantum efficiency were found to be 44573 cdm-2 and 12.61%, respectively.
合成了由杂蒽酮和硫杂蒽酮衍生物组成的新化合物,并详细讨论了这些化合物的光物理性质。在0.09和0.37 eV(低温下)得到了单重态和三重态的能量差。此外,激光功率的对数与PL强度的对数的斜率小于1,化合物表现出热激活的延迟荧光(TADF)。此外,自旋镀膜的光致发光量子产率分别提高了51.83%和41.22%。当化合物的颜色发生变化时,研磨后化合物的粉末x射线衍射(在外力作用下)和化合物的PL谱发生位移,化合物呈现机械变色。化合物的电离电势分别为5.49和5.62 eV,非常适合用于OLED器件的发射层制备。对oled的性能进行了研究,最大亮度为44573 cdm-2,最大外量子效率为12.61%。
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引用次数: 0
The comparative analysis of 2D photonic crystals applications based on specific modeling/simulation results 基于具体建模/仿真结果的二维光子晶体应用对比分析
Pub Date : 2023-06-09 DOI: 10.1117/12.2665488
D. Ulieru, O. Ulieru
The study of optical properties of various photonic band gap (PBGs) structures, focused on the in-plane propagation of 2D-PCs PBGs which are most applied in micro-fabrication and optical integration. These devices provide many novel and useful properties, such as lossless confinement of light mode, high-Q microcavity, linear waveguiding in low index material, low-loss bending, high efficiency resonant tunneling process to transfer energy between defects etc. The parameter interplay on the band gap formation is discussed first, then light modes in ideal bulk PCs are investigated.as finally, interaction between defects crucial to planar device designs. The comparison between the slab with air holes as with microcolumns confirmed that the surface recombination will be smaller in columns as that in air holes when assuming a constant filling factor of semiconductor. The photonic crystals in a square or hexagonal lattice as air holes on silicon on insulator (SOI) layers obtained bandgap centered on the wavelength of 1.55 μm, the spectral region for optical communications. By applications of computational methods like Finite Difference Time Domain (FDTD) could be determined the bandgap of the structure and computed transmission and reflection properties of system.
对各种光子带隙(PBGs)结构的光学特性进行了研究,重点研究了在微加工和光学集成中应用最广泛的二维光子带隙(2D-PCs)的平面内传播。这些器件提供了许多新颖和有用的特性,如光模式的无损限制、高q微腔、低折射率材料的线性波导、低损耗弯曲、在缺陷之间传递能量的高效谐振隧道过程等。首先讨论了各参数对带隙形成的影响,然后研究了理想块状光子晶体中的光模式。最后,缺陷之间的相互作用对平面器件设计至关重要。将带气孔的板坯与微柱的板坯进行比较,证实了当半导体填充系数一定时,柱中的表面复合比带气孔的表面复合要小。在绝缘体硅(SOI)层上以方形或六角形晶格为空穴的光子晶体获得了以1.55 μm波长为中心的带隙,这是光通信的光谱区域。应用时域有限差分(FDTD)等计算方法可以确定结构的带隙,并计算出系统的透射和反射特性。
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引用次数: 0
Visible photomobile response of azobenzene-based polymer/carbon black films 偶氮苯基聚合物/炭黑薄膜的可见光光迁移响应
Pub Date : 2023-06-09 DOI: 10.1117/12.2666618
Anna De Girolamo Del Mauro, F. Loffredo, F. Villani, M. F. Caso, T. Fasolino, A. Vestri, D. Sagnelli, Amalia D'Avino, L. Petti, G. Nenna
In this work, we developed and characterized composites prepared by dispersing conductive carbon black (CB) at different concentrations in an azobenzene-based photomobile polymer (azo-PMP) matrix. This polymer can move under UV-blue light because its azobenzene moieties undergo a reversible photoisomerization from trans to cis configuration and this nanoscopic structural movement induces a macroscopic movement in the film. We studied the possibility to modify the photomobile properties of azo-PMP by introducing different concentrations of CB (from 0wt.% up to 1wt.%) and we investigated morphology, optical properties and photomobile behaviour at different wavelengths. Optical analysis by polarized light shows that the films with CB concentrations up to 0.1wt.% are quite homogeneous and still present birefringence properties. Photoresponsivity measurements at wavelengths in the range 457-747nm were studied to investigate how the presence of the CB affects the photomobile response inside and outside the absorption spectral region of azo-polymers. Choosing appropriately the CB concentration, we demonstrated that it is possible to enlarge the usable spectral bandwidth of the samples in visible region towards the visible and near infrared spectral region.
在这项工作中,我们开发并表征了在偶氮苯基光电聚合物(azo-PMP)基质中分散不同浓度的导电炭黑(CB)制备的复合材料。这种聚合物可以在紫外蓝光下移动,因为它的偶氮苯部分经历了从反式到顺式的可逆光异构化,这种纳米级的结构运动引起了薄膜中的宏观运动。我们研究了通过引入不同浓度的CB(从0wt开始)来修饰偶氮- pmp的光电迁移性能的可能性。%至1wt.%),我们研究了不同波长下的形貌、光学性质和光电迁移行为。偏振光光学分析表明,CB浓度可达0.1wt。%相当均匀,仍然呈现双折射性质。研究了波长457-747nm范围内的光响应性测量,以研究CB的存在如何影响偶氮聚合物吸收光谱区域内外的光移动响应。选择适当的CB浓度,我们证明了在可见光区向可见光和近红外区扩大样品的可用光谱带宽是可能的。
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引用次数: 0
Real time pulse characterization for a terawatt laser facility 太瓦激光设备的实时脉冲特性
Pub Date : 2023-06-09 DOI: 10.1117/12.2673119
Yousuf Hemani, M. Galimberti, K. Koch, H. Panuganti, Davide Bleiner
The technique of chirped pulse amplification has conveniently enabled the development of Joule-class laser facilities delivering terawatt levels of power with a single shot beam on target. In powerful systems like these, beam metrology for pulse charaterization is crucial for maintaining a high level of confidence in generating high intensity laser shots. Optical diagnostics for monitoring beam features such as spectra, beam profile, energy and also measuring dispersion and the compressed pulse duration are necessary. Spatio-temporal couplings such as angular dispersion caused by the presence of chromatic aberrations can distort the pulse energy and duration on target and affect laser matter interactions. A pulsefront- tilt (PFT) diagnostic utilizing a diffractive optic for determining angular dispersion and misalignment at shorter bandwidths is designed and implemented for our laser facility, along-with a homemade single shot auto-correlator for measuring pulse duration after the grating compressor. For real-time monitoring of the laser facility, a smart dashboard protocol using openBIS ELN (Electronics Lab Notebook) is administered to enable regular and uninterrupted saving of raw data which is integrated into the local dashboard for visualization and data analysis.
啁啾脉冲放大技术为焦耳级激光设备的发展提供了便利,可以用单次发射光束向目标发射太瓦级功率。在像这样的强大系统中,用于脉冲表征的光束计量对于在产生高强度激光射击时保持高水平的信心至关重要。为了监测光束的特征,如光谱、光束轮廓、能量以及测量色散和压缩脉冲持续时间,光学诊断是必要的。色差引起的角色散等时空耦合会使脉冲能量和持续时间发生畸变,从而影响激光与物质的相互作用。为我们的激光设备设计并实现了脉冲前倾斜(PFT)诊断,利用衍射光学来确定较短带宽下的角色散和不对准,以及用于测量光栅压缩器后脉冲持续时间的自制单射自相关器。为了对激光设备进行实时监控,使用openBIS ELN(电子实验室笔记本)的智能仪表板协议进行管理,以便定期和不间断地保存原始数据,这些数据集成到本地仪表板中,用于可视化和数据分析。
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引用次数: 0
Computer vision approaches for the absolute energy calibration of Bragg crystal setups Bragg晶体装置绝对能量校准的计算机视觉方法
Pub Date : 2023-06-09 DOI: 10.1117/12.2665790
Christian Grech, G. Geloni, M. Guetg
Bragg crystals are widely used in free electron lasers to diffract and isolate an extremely narrow spectral range from the initial self-amplified spontaneous emission (SASE) signal. By rotating the crystal along one of its axes, multiple reflections can be generated as per Bragg’s law. A measurement model based on Bragg’s law was established at the SASE2 beamline of the European XFEL after extensive hours of hard x-ray self-seeding (HXRSS) operation. This model characterizes the crystal’s range of motion and reflections. In this work, two computer vision techniques, the Hough transform and template matching, are implemented to identify the absolute photon energy from photon diagnostic images. By comparing the spectrometer correlation scans with the model, the actual operational energy can be determined from the measured data using these techniques, enabling accurate calibration as well as the ability to freely scan the photon energy with a self-seeded beam over a wide energy range.
Bragg晶体广泛应用于自由电子激光器中,用于衍射和隔离初始自放大自发发射(SASE)信号的极窄光谱范围。通过沿其中一个轴旋转晶体,可以根据布拉格定律产生多次反射。在欧洲XFEL的SASE2光束线上,经过长时间的硬x射线自播散(HXRSS)操作,建立了基于Bragg定律的测量模型。这个模型描述了晶体运动和反射的范围。本文采用Hough变换和模板匹配两种计算机视觉技术从光子诊断图像中识别绝对光子能量。通过将光谱仪的相关扫描与模型进行比较,可以利用这些技术从测量数据中确定实际的工作能量,从而实现精确的校准以及在宽能量范围内使用自种子光束自由扫描光子能量的能力。
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引用次数: 0
Fabrication of atomically precise, super smooth, and damage-free x-ray optics 制造原子精度,超光滑,和无损伤的x射线光学
Pub Date : 2023-06-09 DOI: 10.1117/12.2668438
P. V. Bui, Masahiko Kanaoka, M. Yabashi, Tetsuya Ishikawa, Y. Sano, K. Yamauchi
An atomically precise, super smooth, and damage-free surface is highly demanded for x-ray mirrors, multilayer optics, channel-cut crystal monochromators (CCM), and gratings. An ultra-precision optic with a figure error of several nm is crucial for single-nanometer spatial resolution, signal strength, and contrast. Moreover, sub-angstrom root-mean-square surface roughness is beneficial for high reflectivity and the lowest unwanted scattering. Additionally, a damage-free surface with no alter layer is greatly desired for CCM and grating substrates because it is essential for the high reflectivity of the CCM and the uniform etching rate of the grating’s ruling. In the manufacturing of x-ray mirrors, to obtain the desired figure error, a non-contact figuring method, such as ion beam figuring (IBF), plasma chemical vaporization machining (PCVM), or Elastic Emission Machining (EEM), is usually employed thanks to its high controllability and stability. EEM has proved the best performance in terms of achieving a low figure error and maintaining a good surface roughness. After shaping/figuring, a finishing method is usually applied to improve its surface roughness without distorting its figure error. Recently, Catalyst-Referred Etching (CARE) has realized its potential and applicability to x-ray mirror manufacturing as a finishing method. Thanks to its removal mechanism, a highly ordered surface with a root-mean-square of 0.03 nm RMS is attained. In the polishing of a CCM, because a mechanical method is usually used to polish its surface at the narrow gap, the residual mechanical damage induced a low reflectivity and low spatial resolution. PCVM with a wire electrode has recently been proposed and demonstrated its excellent performance. The damage-free surface of a CCM with a gap of less than 100µm has been successfully realized by PCVM. In this paper, recent achievements in figuring (EEM), surface finishing (CARE), and damage removal (PCVM) are presented and discussed.
对于x射线反射镜、多层光学、通道切割晶体单色器(CCM)和光栅来说,高度要求原子精度、超光滑和无损伤的表面。具有数nm图形误差的超精密光学器件对于单纳米空间分辨率、信号强度和对比度至关重要。此外,亚埃的均方根表面粗糙度有利于高反射率和最低的不必要散射。此外,对于CCM和光栅基板来说,一个没有改变层的无损伤表面是非常需要的,因为它对于CCM的高反射率和光栅的均匀刻蚀率至关重要。在x射线反射镜的制造中,为了获得理想的图形误差,通常采用离子束加工(IBF)、等离子体化学汽化加工(PCVM)或弹性发射加工(EEM)等非接触加工方法,因为它们具有较高的可控性和稳定性。EEM在实现低图形误差和保持良好的表面粗糙度方面证明了最佳性能。在成形/图形化后,通常采用精加工方法来改善其表面粗糙度,而不会扭曲其图形误差。近年来,催化参考蚀刻(CARE)作为一种精加工方法已经意识到它在x射线反射镜制造中的潜力和适用性。由于其去除机制,获得了均方根RMS为0.03 nm的高度有序表面。在CCM的抛光中,由于通常采用机械方法对其表面的窄间隙进行抛光,因此残余的机械损伤导致了低反射率和低空间分辨率。最近提出了带线电极的PCVM,并证明了其优异的性能。利用PCVM技术成功实现了间隙小于100µm的CCM表面无损伤。本文介绍和讨论了近年来在成形(EEM)、表面处理(CARE)和损伤去除(PCVM)方面取得的进展。
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引用次数: 0
Adiabatic frequency converter as a custom octave-spanning dispersive element 绝热变频器作为自定义的跨倍频散元件
Pub Date : 2023-06-09 DOI: 10.1117/12.2671413
Dylan Heberle, Noah Flemens, Connor Davis, J. Moses
Dispersion management is among the most challenging aspects of the design and realization of amplified laser systems possessing octave-spanning bandwidth and good compressed pulse quality. Here we demonstrate a new type of device for octave-spanning dispersion management. We combine the paradigm of chirped quasi-phase matching (QPM) for pulse shaping during frequency conversion with the robust, efficient, octave-spanning capability of an adiabatic frequency downconversion device. The result is a simple, monolithic device that can produce an octave-spanning infrared pulse with tailored dispersion – a technique that may be especially convenient for high-energy amplifier chains employing difference frequency generation and/or parametric amplification stages. The technique can also serve as a way to produce pulses of ~10 fs duration throughout the visible to mid-infrared spectrum for hyperspectral ultrafast spectroscopy. Adiabatic frequency conversion employs a slowly changing position-dependent poling frequency in a chirped QPM device to efficiently frequency shift photons over a wide bandwidth with a linear transfer function. In this work, we show that the frequency dependent localized conversion of the process allows tailoring of the total group-delay dispersion (GDD). We have demonstrated a first device with zero GDD, allowing efficient conversion of a few-cycle near-infrared input to a near-single-cycle mid-infrared output of the same duration (~12 fs, with bandwidth spanning 2.0-4.0 microns). We present additional designs for precise custom tailoring of the frequency-dependent group delay.
色散管理是设计和实现具有八度跨度带宽和良好压缩脉冲质量的放大激光系统最具挑战性的方面之一。在这里,我们展示了一种新型的八度跨度色散管理装置。我们将啁啾准相位匹配(QPM)在频率转换过程中的脉冲整形范式与绝热频率下变频装置的鲁棒、高效、跨倍频的能力相结合。结果是一个简单的单片器件,可以产生具有定制色散的八度跨越红外脉冲-这种技术可能特别方便用于采用差频产生和/或参数放大级的高能放大器链。该技术还可以作为一种方法,在可见光到中红外光谱中产生持续时间约10秒的脉冲,用于高光谱超快光谱。绝热频率转换在啁啾QPM器件中采用缓慢变化的位置相关极点频率,以线性传递函数在宽带宽上有效地移频光子。在这项工作中,我们证明了该过程的频率相关局部转换允许裁剪总群延迟色散(GDD)。我们已经展示了一个零GDD的器件,允许将几个周期的近红外输入有效地转换为相同持续时间(~12 fs,带宽跨越2.0-4.0微米)的近单周期中红外输出。我们提出了精确定制频率相关群延迟的附加设计。
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引用次数: 0
Ultrafast dynamics in quantum matter at SwissFEL: capabilities of Furka endstation 瑞士fel量子物质的超快动力学:Furka终端的能力
Pub Date : 2023-06-09 DOI: 10.1117/12.2668886
E. Razzoli, H. Ueda, E. Paris, B. Liu, E. Skoropata, L. Patthey
Time-resolved spectroscopies have provided insights in the quest for understanding the fundamental properties of quantum materials and towards controlling their functional properties through light-matter interaction. In this regard, Free Electrons Lasers (FELs) have developed as a powerful tool to perform ultrafast x-ray spectroscopy to obtain energy and momentum-resolved information. In this contribution, we introduce the SwissFEL soft-x-ray condensed matter experimental endstation, named Furka, which is dedicated to Time-Resolved X-ray Absorption (TR-XAS), resonant X-Ray Diffraction (TR-RXRD) and Resonant Inelastic x-ray Scattering (TR-RIXS) experiments to study quantum materials. The current status of the endstation and the first results from the commissioning phase will also be discussed.
时间分辨光谱为理解量子材料的基本特性和通过光-物质相互作用控制其功能特性提供了见解。在这方面,自由电子激光器(FELs)已经发展成为一种强大的工具来执行超快x射线光谱,以获得能量和动量分辨信息。在这篇文章中,我们介绍了瑞士自由电子实验室软x射线凝聚态物质实验终端Furka,该终端致力于时间分辨x射线吸收(TR-XAS),共振x射线衍射(TR-RXRD)和共振非弹性x射线散射(TR-RIXS)实验来研究量子材料。还将讨论终端站的当前状态和调试阶段的初步结果。
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引用次数: 0
Liquid jet target system for laser-plasma interactions at kHz repetition rate 重复频率为kHz的激光等离子体相互作用液体喷射靶系统
Pub Date : 2023-06-09 DOI: 10.1117/12.2665607
Nina Gamaiunova, M. Tryus, F. Grepl, A. Velyhan, S. Stanček, V. Kantarelou, G. Cirrone, D. Margarone, L. Giuffrida, T. Chagovets
We have developed a compact liquid target setup that produces a continuous ø50 µm cylindrical water jet, capable of operating at high vacuum. It has been tested with a commercial ultrashort-pulse laser in a series of proof-of-principle laser-driven ion acceleration and x-ray generation experiments at repetition rates up to 1 kHz. In optimized conditions, measurements by the time-of-flight (TOF) method have demonstrated a proton signal cut-off energy of 179±9 keV. The laser-generated x-ray emission was characterized in the range 2-36 keV and used as excitation for x-ray fluorescence spectroscopy (XRF) measurements.
我们开发了一种紧凑的液体靶装置,可产生连续的ø50 μ m圆柱形水射流,能够在高真空下运行。它已经在商业超短脉冲激光器上进行了一系列原理验证的激光驱动离子加速和x射线生成实验,重复率高达1khz。在优化的条件下,通过飞行时间(TOF)方法的测量表明,质子信号截止能量为179±9 keV。激光产生的x射线辐射在2- 36kev范围内被表征,并用作x射线荧光光谱(XRF)测量的激发。
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引用次数: 0
Seeding at SwissFEL 在瑞士fel播种
Pub Date : 2023-06-09 DOI: 10.1117/12.2666463
S. Reiche
SwissFEL at the Paul Scherrer Institute is a free-electron laser facility providing hard and soft x-rays, based on the SASE principle. In addition, the soft x-ray beamline Athos is currently extended for electron beam manipulation with external lasers, aiming to provide seeding capabilities based on the two-stage echo-enabled harmonic generation (EEHG) scheme. Completion of the installation is foreseen in spring 2023. We present the initial results on the single-stage operation for ESASE and mode-locked lasing and give an outlook on the expected performance for seeding down to 1 nm.
位于Paul Scherrer研究所的SwissFEL是一个基于SASE原理的自由电子激光设备,提供硬x射线和软x射线。此外,软x射线光束线Athos目前正在扩展,用于外部激光器的电子束操作,旨在提供基于两级回声激活谐波产生(EEHG)方案的播散能力。预计将于2023年春季完成安装。我们介绍了ESASE和锁模激光单级操作的初步结果,并展望了播种至1nm的预期性能。
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引用次数: 0
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Optics + Optoelectronics
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