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MBE Growth Of GaAs-based Pseudomorphic Lasers: Key Growth Trade-offs Between The InGaAs MQWs And The AlGaAs Cladding 基于gaas的伪晶激光器的MBE生长:InGaAs mqw和AlGaAs包层之间的关键生长权衡
Pub Date : 1994-07-06 DOI: 10.1109/LEOSST.1994.700533
E. Larkins, W. Rothemund, J. Wagner, M. Baeumier, S. Burkner, W. Benz, S. Weisser, A. Schonfelder, G. Flemig, R. Brenn, J. Fleissner, W. Jantz, J. Rosenzweig, J. Ralston
Pseudomorphic InyGal-yAs/GaAs/AlxGal.xAs MQW lasers are receiving increasing attention for shorthaul, high-speed data transmission, because they have much larger modulation bandwidths1 and smaller linewidth enhancement factors2 than GaAs/AlGaAs lasers. Although pseudomorphic InGaAs/GaAs technology is relatively young, lasers fabricated in this material system have already achieved larger direct modulation bandwidths (33 GHz at 65 mA 3, than any other material system. The key processes influencing the MBE growth of pseudomorphically strained InGaAs/GaAs/AlGaAs structures are only now being identified4p5. Thus, the growth of such structures has followed a "trial and error" approach, based on experience from the growth of GaAs/AIGaAs heterostructures. For GaAs/AlGaAs lasers, it was shown that higher substrate temperatures improved the AlGaAs quality and reduce the threshold current densities6. For pseudomorphic MQW lasers, it became necessary to grow two different ternary alloys, whose independently optimized growth parameters are quite different. As a result, it has become common practice to optimize the InyGal.yAs, GaAs and AI,Gal.,As growth parameters independently7. Such independent optimization presumes that the growth of each layer does not significantly influence the other layers a presumption which becomes questionable for the larger strains and stresses associated with the newest generation of pseudomorphic diode lasers. In this paper, we present the most recent results of our on-going investigation into the MBE growth processes of pseudomorphically strained InyGal.yAs. We present compelling evidence showing that the quality of InGaAs/GaAs MQWs in such lasers depends strongly on the growth parameters of the other epitaxial layers particularly on the AlGaAs growth temperature. This interdependence forces a complete re-evaluation of the appropriateness of I n G W G a A s growth protocols based on unstrained GaAs/AlGaAs MBE growth processes. As-grown and annealed In0.35Ga0.65As/GaAs test structures and diode lasers have been extensivel! characterized with resonant Raman scattering, photoluminescence (PL), PL microscopy (PLM) and ion channeling. We observe a gradual onset for strain relaxation through the formation of -oriented dislocations and oriented line defects. The formation and propagation of both misfit dislocations and line defects depends strongly on i) the growth temperature, ii) the substrate quality, iii) the total number of QWs. iv) the thickness of the QW barrier layers, and v) the impurity (e.g dopant) concentration in these barriers. Ion channeling measurements and annealing studies reveal increasing structural instability of the MQW structures as the number of QWs increases. The formation of misfit dislocations and line defects ispreceded by the incorporation of as yet unidentified point defects. Resonant Raman measurements (Fig. 1) show an increase in the intensity of 1-LO phonon scattering from the GaAs barriers with increas
假象InyGal-yAs /砷化镓/ AlxGal。与GaAs/AlGaAs激光器相比,xAs MQW激光器具有更大的调制带宽1和更小的线宽增强因子2,因此在短距离、高速数据传输方面受到越来越多的关注。虽然假晶InGaAs/GaAs技术相对较年轻,但在这种材料系统中制造的激光器已经实现了比任何其他材料系统更大的直接调制带宽(65 mA 3时33 GHz)。影响假晶应变InGaAs/GaAs/AlGaAs结构MBE生长的关键过程现在才被确定[5]。因此,基于GaAs/AIGaAs异质结构的生长经验,这种结构的生长遵循了“试错”的方法。对于GaAs/AlGaAs激光器,研究表明,较高的衬底温度改善了AlGaAs质量,降低了阈值电流密度6。对于伪晶MQW激光器,必须生长两种不同的三元合金,其独立优化的生长参数差异很大。因此,优化InyGal已成为一种常见的做法。是的,GaAs和AI,Gal。,为独立的生长参数。这种独立的优化假设每一层的生长不会显著影响其他层,这一假设对于与最新一代伪晶二极管激光器相关的更大应变和应力变得值得怀疑。在本文中,我们介绍了我们正在进行的关于假晶应变InyGal.yAs的MBE生长过程的最新研究结果。我们提供了令人信服的证据表明,在这种激光器中,InGaAs/GaAs MQWs的质量在很大程度上取决于其他外延层的生长参数,特别是AlGaAs的生长温度。这种相互依赖关系迫使我们对基于非约束GaAs/AlGaAs MBE生长过程的gwa / gaa生长方案中的I的适当性进行彻底的重新评估。生长和退火In0.35Ga0.65As/GaAs测试结构和二极管激光器已得到广泛应用!通过共振拉曼散射、光致发光(PL)、PL显微镜(PLM)和离子通道表征。我们观察到,通过取向位错和取向线缺陷的形成,应变松弛逐渐开始。错配位错和线缺陷的形成和扩展在很大程度上取决于i)生长温度,ii)衬底质量,iii)量子阱的总数。iv)量子阱势垒层的厚度,v)这些势垒中的杂质(如掺杂)浓度。离子通道测量和退火研究表明,随着量子阱数量的增加,量子阱结构的结构不稳定性也在增加。错配位错和线缺陷的形成是由尚未识别的点缺陷的合并引起的。共振拉曼测量(图1)显示,随着量子阱数量的增加,GaAs势垒的1- lo声子散射强度增加,这归因于点缺陷密度的增加。-100 k以上。温度相关的PL测量(图2)显示,随着量子阱数量的增加,PL强度下降得更快。因此,这些新的应变诱导点缺陷可能是活跃的非辐射复合中心。随着应变松弛极限的接近,这些缺陷变得越来越重要,我们怀疑这些点缺陷也可能在促进错配位错和线缺陷的形核和扩展中起作用。这些点缺陷的性质目前正在深入研究,并将进行讨论。高速InCaAsGaAs激光器有源区的优化需要高应力InGaAs/Gais MQWs,接近失配应变松弛极限5。减少上述点缺陷的集中。AlGaAs包层的生长温度必须降低到远低于最佳AIGaAs生长温度。先前的研究表明,与三元AlGaAs合金相比,使用GaAs/AIAs短周期超晶格(SPSL)伪合金生长的GaAs/AlGaAs MQW激光器的发光效率提高,界面粗糙度降低,杂质掺入减少7。SPSL假合金在MBE生长参数中具有足够的灵活性,可以在大幅降低的温度下生长高质量的激光器。我们提出了In0.35Gao的结果。65As/GaAs 4 QW激光器(图3),其SPSL AI0,8Ga0,2As包层在700°C或620°C下生长。在620°C下生长AlGaAs包层的激光器的阈值电流密度小-3倍(图4)。内部量子效率从60%提高到70%。我们将较低的阈值电流和增加的内部量子效率归因于MQW区域中点缺陷浓度的急剧下降。脊激光器(3x100pm2)也由这些结构制造。
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引用次数: 0
Growth And Properties Of GaN Produced By ECR-MBE ECR-MBE制备氮化镓的生长与性能研究
Pub Date : 1994-07-06 DOI: 10.1109/LEOSST.1994.700546
T. D. Mousakas
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引用次数: 0
CMOS 2 X 8 Photoreceiver Array For Free Space Holographically Interconnected Counter 用于自由空间全息互连计数器的CMOS 2 × 8光电接收器阵列
Pub Date : 1994-07-06 DOI: 10.1109/LEOSST.1994.700475
C. Mao, L. Ji, D. McKnight, R. Feuerstein, J. Neff
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引用次数: 0
Tunable Lasers For Photonic Integrated Circuits 用于光子集成电路的可调谐激光器
Pub Date : 1994-07-06 DOI: 10.1109/LEOSST.1994.700421
L. Coldren, V. Jayaraman
Prior to 1991, the most advanced tunable semiconductor laser was the “Distributed Bragg Reflector” or DBR laser. DBR lasers employ a cavity design which constrains the fractional wavelength tuning Ahlh to be no more than the achievable fractional index change Aplp in a semiconductor waveguide. The maximum fractional index shift is just under 1 %, resulting in maximum tuning ranges around 10 nm at 1.5 microns (pm). Since 1991, however, three different cavity geometries have been demonstrated, with much wider tuning ranges. Figure 1 shows the Y-cavity geometry [ 11, versions of which have demonstrated on the order of 50 nm tuning [ 1,2]. Figure 2 shows the grating-assisted co-directional coupler laser (GACC) [3], which has also demonstrated more than 50 nm tuning. Lastly, Fig. 3 shows the sampled grating DBR laser, which we describe in more detail below. The sampled grating laser was first proposed by us in 1990 [4], and demonstrated in 1991 [5]. As shown in Fig. 3, the device relies on two DBR gratings modulated by an on-off sampling function, resulting in periodic reflection spectra. The periods of the two mirrors are slightly mismatched, and lasing occurs where two mirror maxima are aligned. Tuning one mirror relative to the other causes the alignment position to shift to adjacent maxima, resulting in wide-range “vernier effect” tuning. Inducing identical index changes in both mirrors allows coverage between mirror maxima. Figures 4,5, and 6 show our most recent sampled grating DBR results [6]. Figure 4 shows 73 nm tuning with 62 nm continuous wave range. Figure 5 shows light-current properties. Figure 6 shows some continuous-wave spectra, indicating very large suppression of spurious mirror resonances. The sampled grating DBR laser has also been implemented using periodically chirped gratings. This approach has also resulted in very impressive results, with tuning ranges of up to 100 nm demonstrated [7].
在1991年之前,最先进的可调谐半导体激光器是“分布式布拉格反射器”或DBR激光器。DBR激光器采用腔体设计,限制分数波长调谐Ahlh不超过半导体波导中可实现的分数折射率变化appp。最大分数指数位移略低于1%,导致在1.5微米(pm)的最大调谐范围约为10纳米。然而,自1991年以来,已经证明了三种不同的腔几何形状,具有更宽的调谐范围。图1显示了y型腔的几何形状[11],其版本已被证明在50 nm调谐量级[1,2]。图2显示了光栅辅助共向耦合器激光器(GACC)[3],它也显示了超过50 nm的调谐。最后,图3显示了采样光栅DBR激光器,我们将在下面更详细地描述。我们于1990年首次提出了采样光栅激光器,并于1991年进行了演示。如图3所示,该器件依靠开关采样函数调制的两个DBR光栅,产生周期反射光谱。两个反射镜的周期稍微不匹配,激光发生在两个反射镜的最大值对齐的地方。调优一个镜像相对于另一个镜像会导致对齐位置移动到相邻的最大值,从而导致大范围的“游标效果”调优。在两个镜像中诱导相同的索引变化允许在镜像最大值之间覆盖。图4、5和6显示了我们最近采样的光栅DBR结果[6]。图4显示了73 nm调谐,62 nm连续波范围。图5显示了光电流特性。图6显示了一些连续波谱,表明对杂散镜像共振的抑制非常大。采用周期性啁啾光栅实现了采样光栅DBR激光器。这种方法也产生了非常令人印象深刻的结果,调谐范围高达100纳米。
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引用次数: 1
Periodically Induced Mode Shift In Vertical Cavity Fabry Perot Etalons Grown By Molecular Beam Epitaxy 分子束外延生长的垂直腔法布里佩罗标准子的周期性诱导模移
Pub Date : 1994-07-06 DOI: 10.1109/LEOSST.1994.700553
L. Eng, K. Toh, C. Chang-Hasnain, K. Bacher, J. Harris
Two dimensional multiple wavelength vertical cavity surface emitting laser (VCSEL) arrays are promising for ultrahigh capacity optical networks using wavelength division multiplexing (WDM). The emission wavelength of a VCSEL is determined by the laser cavity round trip phase condition, which can be varied across the array by varying the thickness of either the cavity or the dielectric mirror layers. In prior work, a 2D VCSEL array emitting 140 distinct wavelengths was reported [ 13 using a spatially tapered mirror layer in the VCSEL caused by the inherent beam flux gradient in a Molecluar Beam Epitaxy (MBE) system. In this work, we demonstrate an induced lateral variation in cavity thickness of a GaAs/AlAs Fabry Perot resonator. By indium bonding the substrate to patterned backing wafers we induce a lateral surface temperature gradient on the substrate, thereby altering the GaAs desorption rate across the wafer during the growth of the cavity. Above substrate temperatures of 640 C, the GaAs growth rate is a strongly decreasing function of temperature [2]. Previously, Goodhue et. al. achieved substrate surface temperature differences of 30 50 C by mounting the substrates, using indium, to molybdenum blocks machined with 1 mm deep grooves and a 10 mm period [3]. They observed a near 3 fold decrease in GaAs growth rate in the high temperature regions of the wafer. In our work we have used indium to selectively bond the GaAs substrate to GaAs wafers which have patterns ranging from 2 to 8 mm. The advantage of this technique is that we can define the patterns lithographically. We then grow passive Fabry Perot cavities consisting of AlAs/GaAs Bragg mirror stacks centered at 950 nm, 10.5 pairs on the bottom and 8 on the top, and a 300 nm thick GaAs cavity. The calculated cavity mode of this structure is 980 nm. Both mirrors are grown at a substrate temperature of 600 C and the cavity is grown at approximately 700 C. A schematic of this technique is shown in Figure 1. We expect the mirrors to be uniform since they are grown below the gallium desorption temperature. The cavity, however, will have a thickness variation across the wafer due to the induced surface temperature difference in a regime in which significant gallium desorption occurs. We characterize the material by measuring reflectivity spectra across the wafer, and mapping the Fabry Perot wavelength. The spatial resolution of the measurement is 100 pm. Figure 2 shows the measured cavity mode position perpendicular to the direction of a single 8 mm wide pattern. We see that the effect of the indium bonded central portion was a higher surface temperature, resulting in a decrease in cavity mode wavelength of 7 nm over a distance of 3 mm. In Figure 3, we plot the measured reflectivity spectra for x = 18, 19, 20 , 21 mm in Figure 2. We see that although the cavity mode shifts significantly here, the stop band of the reflectance stays nearly constant. In Figure 4 we show the cavity mode along one dir
二维多波长垂直腔面发射激光器(VCSEL)阵列在采用波分复用(WDM)的超高容量光网络中具有广阔的应用前景。VCSEL的发射波长由激光腔的往返相位条件决定,可以通过改变腔或介电镜层的厚度来改变整个阵列的发射波长。在先前的研究中,利用分子束外延(MBE)系统中固有的光束通量梯度引起的VCSEL空间锥形反射层,报道了一个发射140个不同波长的二维VCSEL阵列[13]。在这项工作中,我们证明了GaAs/AlAs法布里佩罗谐振腔厚度的诱导横向变化。通过将衬底与图案衬底结合,我们在衬底上诱导了横向表面温度梯度,从而改变了在腔生长过程中整个晶圆上GaAs的解吸速率。在衬底温度为640℃以上,GaAs生长速率随温度[2]呈强烈的递减函数。以前,Goodhue等人通过使用铟将衬底安装到加工有1毫米深凹槽和10毫米周期[3]的钼块上,实现了衬底表面温差30 - 50摄氏度。他们观察到,在晶圆片的高温区域,砷化镓的生长速率降低了近3倍。在我们的工作中,我们使用铟选择性地将GaAs衬底粘合到具有2至8毫米图案的GaAs晶圆上。这种技术的优点是我们可以用光刻技术来定义图案。然后,我们生长了由以950 nm为中心,底部10.5对,顶部8对的AlAs/GaAs Bragg镜堆栈和300 nm厚的GaAs腔组成的被动Fabry Perot空腔。计算出该结构的腔模为980 nm。两个反射镜都在600℃的衬底温度下生长,而腔体的生长温度约为700℃。该技术的示意图如图1所示。我们期望镜子是均匀的,因为它们生长在镓解吸温度以下。然而,由于在显着的镓解吸发生的情况下诱导的表面温差,腔将在晶圆上有厚度变化。我们通过测量整个晶圆的反射率光谱来表征材料,并绘制法布里珀罗波长。测量的空间分辨率为100pm。图2显示了垂直于单个8mm宽图案方向的测量腔模位置。我们看到,铟键合的中心部分的影响是更高的表面温度,导致在3mm的距离上腔模波长减少了7 nm。在图3中,我们绘制了图2中x = 18,19,20,21 mm处的测量反射率光谱。我们看到,尽管腔模式在这里发生了明显的变化,但反射的阻带几乎保持不变。在图4中,我们显示了不同晶圆沿一个方向的空腔模式,该晶圆安装在具有3毫米图案的背面。再一次,我们看到在3毫米周期之后8纳米的显著变化。然而,随着图案尺寸的减小,我们注意到较大的不均匀性,这是由于难以与铟键进行良好的热接触。我们已经证明了在MBE生长的GaAs /AlAs Fabry Perot垂直腔中跨越1.5 mm的8nm腔模位移。这些结果对多波长VCSEL阵列的研制具有重要意义。在镓解吸温度以上生长空腔和空间映射空腔模式的技术也可以用作研究衬底温度均匀性的工具,因为测量对小于1%的空腔厚度变化很敏感。
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引用次数: 4
LAN Interconnection Based On A Cross-connected Multi-wavelength Layer 基于交叉连接多波长层的局域网互连
Pub Date : 1994-07-06 DOI: 10.1109/LEOSST.1994.700505
G. Khoe, H. Boom, E. Put
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引用次数: 3
Experimental Implementation Of A Cellular High Capacity Photonic Transport Network 蜂窝高容量光子传输网络的实验实现
Pub Date : 1994-07-06 DOI: 10.1109/LEOSST.1994.700493
L. Berthelon, C. Coeurjolly, P. Perrier, O. Gautheron, A. Noury, V. Havard
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引用次数: 0
1 X 18 Array Of Low Voltage, Asymmetric Fabry-Perot Modulators For Gigabit Data Transmission Applications 用于千兆数据传输应用的1 × 18低电压非对称法布里-珀罗调制器阵列
Pub Date : 1994-07-06 DOI: 10.1109/LEOSST.1994.700446
G. B. Thompson, G. Robinson, J. Scott, C. Mahon, F. Peters, B. Thibeault, L. Coldren
Asymmetric Fabry-Perot modulators (AFPMs) possess many qualities which make them excellent candidates for use in smart pixel applications [l]. They inherently operate in a surface normal configuration and are polarization independent. Devices have been designed to achieve low insertion loss, high contrast ratio, low voltage operation and high electrical bandwidth [2-31. Recently, we have extended this work in the direction of packaged arrays with low voltage (0-5V) and high bandwidth (10 GHz) operation. The design includes intracavity contacts for low series resistance and coplanar transmission lines on a semi-insulating substrate for impedance matching. The package includes standard microwave (SMA) connectors and a planar microlens array. The AFPM consists of a multiple quantum well (MQW) p-i-n diode between two DBR mirrors of unequal reflectivity which form a resonant cavity. In the zero-bias, low absorption state, the reflectivity is high (typically > 50%). Applying an electric field across the p-i-n diode increases the cavity absorption via the quantum confined Stark effect (QCSE), decreasing the effective back mirror reflectivity to match that of the front mirror and nulling out the reflected signal. The device design parameters include the front mirror reflectivity, the number of quantum wells, the quantum well and barrier thicknesses and compositions, thickness of the contact regions, operating voltage swing and the operating wavelength. Since the QCSE can be treated as an instantaneous process on picosecond time scales, the modulation speed is limited in practice only by the speed with which the field applied across the MQW region can be modulated. Quantum well material (1 OOA GaAs wells with 45A A10.3Ga0.7As barriers) was characterized in terms of absorption as a function of wavelength for different applied voltages (or equivalently, electric fields) using photocurrent measurements. Using this data, a modulator was designed to have €3 dB insertion loss and >lo GHz bandwidth (with a 50Q parallel termination resistor) for a 4V modulation swing and operate at a wavelength of about 853 nm to be compatible with GaAs QW laser sources. Typical DC characteristics are shown in Figure 1. Growth non-uniformity across the array adversely affects performance. We fabricated a I x 18 array of AFPMs with a 250 pm pitch. We observed approximately a 1 nm variation in the optimum wavelength of operation across the array. This translates into a maximum insertion loss of 4 dB and minimum contrast ratio of 8 dB across the entire array for a fixed wavelength of operation. Location and orientation of an array on the wafer in addition to the optical bandwidth of the device determine these values and so improvements are possible i n the future. Microwave measurements were performed using an HP85 1 OC network analyzer. The transmission line and device were characterized by measuring S i 1 at a bias of 2V. The equivalent circuit model is shown in the inset of Figur
非对称法布里-珀罗调制器(afpm)具有许多特性,使其成为智能像素应用的优秀候选者[l]。它们固有地以表面法向结构工作,并且与极化无关。器件被设计为实现低插入损耗、高对比度、低电压操作和高电带宽[2-31]。最近,我们在低电压(0-5V)和高带宽(10 GHz)操作的封装阵列方向上扩展了这项工作。该设计包括用于低串联电阻的腔内触点和用于阻抗匹配的半绝缘衬底上的共面传输线。该封装包括标准微波(SMA)连接器和一个平面微透镜阵列。AFPM由两个反射率不等的DBR反射镜之间的多量子阱(MQW) p-i-n二极管组成,形成谐振腔。在零偏、低吸收状态下,反射率高(一般> 50%)。在p-i-n二极管上施加电场,通过量子受限斯塔克效应(QCSE)增加腔吸收,降低后视镜的有效反射率以匹配前镜的反射率,并使反射信号为零。器件设计参数包括前镜反射率、量子阱数量、量子阱和势垒厚度和组成、接触区厚度、工作电压摆动和工作波长。由于QCSE可以被视为皮秒时间尺度上的瞬时过程,因此在实践中,调制速度仅受跨MQW区域应用的场可以调制的速度的限制。利用光电流测量对量子阱材料(1 OOA GaAs阱和45A a10.1 ga0.7 as势垒)在不同施加电压(或电场)下的吸收与波长的关系进行了表征。利用这些数据,我们设计了一个调制器,该调制器在4V调制摆幅下具有€3db插入损耗和>lo GHz带宽(带有50Q并联端接电阻),工作波长约为853 nm,与GaAs QW激光源兼容。典型的直流特性如图1所示。整个阵列的生长不均匀性会对性能产生不利影响。我们制作了一个I x 18阵列的afpm与250 pm的间距。我们观察到在整个阵列的最佳操作波长上大约有1nm的变化。对于固定波长的操作,这意味着整个阵列的最大插入损耗为4 dB,最小对比度为8 dB。除了器件的光带宽外,晶圆上阵列的位置和方向决定了这些值,因此未来可能会有所改进。微波测量使用hp851oc网络分析仪进行。在2V的偏置下测量s1对传输线和器件进行了表征。等效电路模型如图2插图所示。并联RC等效电路表示电阻率较高的欧姆触点。串联RC等效电路值与直径为40 pm、本质区厚度为0.47 pm的器件的期望值非常吻合。调制器反射的光被聚焦到多模光纤中,经25 GHz探测器转换成电信号。在频谱分析仪测量之前,用两个18db, 20ghz的微波增益级对信号进行放大。利用Microwave Spice对s11模型进行了S ~ I测量的模拟。模拟和实验数据吻合较好,如图2所示。3db带宽约为4ghz。当在仿真中加入一个50R端接电阻时,可获得7.3 GHz的3db带宽。将该器件集成到千兆光数据传输试验台,并对其误码率(BER)性能进行了1 Gbit/s的评估。误码率曲线如图3所示。由于热噪声(NEP = 1 pW光学)的影响,接收灵敏度限制在-19 dBm,误码率为10-9。
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引用次数: 1
Fabrication Of Multiple Wavelength Vertical-cavity Surface-emitting Laser Array Using Flip-chip Bonding 利用倒装键合技术制备多波长垂直腔面发射激光器阵列
Pub Date : 1994-07-06 DOI: 10.1109/LEOSST.1994.700461
I. Ogura, M. Kajita, S. Kawai, K. Kasahara
Two-dimensionally integrated multiple wavelength arrays using VCSELs or VCSEL-based optical functional device arrays such as V S W s are expected to provide a wider-bandwidth and improved functionality, such as wavelength addressing.') A multiple wavelength VCSEL array, grown with a specific thickness grading, can provide fixed wavelength separation.2) To fully utilize the advantages of the multiple wavelength scheme, a more flexible fabrication technique is needed for providing the arrays with the desired wavelength separation or distribution, such as periodic distribution.
使用VCSEL或基于VCSEL的光学功能器件阵列(如VCSEL)的二维集成多波长阵列有望提供更宽的带宽和改进的功能,如波长寻址。)具有特定厚度分级的多波长VCSEL阵列可以提供固定的波长分离。为了使阵列具有所需的波长分离或分布(如周期性分布),需要一种更灵活的制造技术。
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引用次数: 0
Gaseous Source Epitaxy Technologies For Wide Bandgap II-VI Semiconductors 宽禁带II-VI半导体的气源外延技术
Pub Date : 1994-07-06 DOI: 10.1109/LEOSST.1994.700548
L. Kolodziejski
Substantial progress in recent years by the solid source molecular beam epitaxy (MBE) community has demonstrated the feasibility of the (Zn,Mg)(S,Se) material system for realizing laser diodes operating in the green to blue spectral region. For the Zn-chalcogenide quaternary, all of the constituent elements have very high vapor pressures, and require the regulation of thermal effusion ovens operating at low temperatures (-100-300"C), thus creating a difficulty in reproducibility of the 11-VI alloy composition and emission wavelength. Gaseous source epitaxy technologies [metalorganic (MOMBE) and gas source molecular beam epitaxy (GSMBE)] address these difficulties by employing mass flow controllers to regulate the flux of hydride and metalorganic gas sources. The ultrahigh vacuum environment of MOMBWGSMBE enables implementation of a nitrogen plasma source, which is necessary for p-type doping by the incorporation of nitrogen acceptors into the 11-VI material system. In this paper, the application of the gaseous source epitaxial growth approaches to the fabrication of wide bandgap 11-VI materials and heterostructures will be summarized. In addition, the use of photo-assisted epitaxy, which enables in situ modification of surface chemical reactions, has provided a significant growth rate enhancement, as well as a growth rate retardation, and is dependent on the species present at the growth front. (An electron beam incident to the surface has also been found to simulate the photo-assisted epitaxy effect by creating a significant growth rate enhancement.) To expand the range of lattice constants available for the heteroepitaxy of ZnSe-based heterostructures, the epitaxial growth of ZnSe onto novel 111-V epitaxial layers containing (In,Ga)P is also under intense investigation; the initial characterization of this new IIVyIII-V heterostructure will be described. Utilizing gas source molecular beam epitaxy, ZnSe has been grown using a hydride compound for the source of the high vapor pressure anion species. Nand p-type doping has been investigated using a nitrogen plasma cell for acceptor species of nitrogen and a solid ZnC12 source for donor species of chlorine, respectively. The use of hydride compounds, however, raises the issue of hydrogen incorporation and the possibility that hydrogen may electrically passivate donors or acceptors. High quality ZnSe:Cl has been grown with atomic c1 concentrations approaching lo2' as indicated by secondary ion mass spectrometry (SIMS). At incorporation levels greater than lo2' ~ m ~ , an appreciable decrease in the growth rate has been observed. The sharp transition to a negligible growth rate is atmbuted to the Occurrence of a surface chemical reaction originating from C1 and H which are present in the GSMBE environment. For C1 concentrations as high as 4 ~ 1 0 ' ~ the films exhibited high crystalline quality, as indicated by photoluminescence originating from a single intense donor-bound excitonic transition. In
近年来固体源分子束外延(MBE)领域取得的重大进展证明了(Zn,Mg)(S,Se)材料体系实现绿色到蓝色光谱区域激光二极管工作的可行性。对于硫族锌四元化合物,所有组成元素都具有非常高的蒸汽压,并且需要在低温(-100-300”C)下调节热渗出炉,从而造成11-VI合金成分和发射波长的重现性困难。气体源外延技术[金属有机(MOMBE)和气体源分子束外延(GSMBE)]通过使用质量流量控制器来调节氢化物和金属有机气体源的通量来解决这些困难。MOMBWGSMBE的超高真空环境可以实现氮等离子体源,这是将氮受体掺入11-VI材料体系中进行p型掺杂所必需的。本文综述了气源外延生长方法在制备宽禁带11-VI材料和异质结构中的应用。此外,光辅助外延的使用,使表面化学反应的原位修饰,提供了一个显着的生长速度提高,以及生长速度减慢,这取决于存在于生长前沿的物种。(入射到表面的电子束也被发现通过产生显著的生长速率增强来模拟光辅助外延效应。)为了扩大ZnSe基异质结构外延的晶格常数范围,ZnSe在含有(In,Ga)P的新型111-V外延层上的外延生长也得到了深入的研究;本文将描述这种新的iivii - ii - v异质结构的初步表征。利用气源分子束外延,利用氢化物化合物作为高蒸汽压阴离子源生长ZnSe。采用氮质浆电池和固体ZnC12源分别对氮的受体和氯的供体进行了Nand p型掺杂研究。然而,氢化物的使用引发了氢掺入的问题,以及氢可能电钝化供体或受体的可能性。二级离子质谱(SIMS)表明,高质量的ZnSe:Cl在c1原子浓度接近lo2'的情况下生长。当掺入量大于2′~ m ~时,观察到生长速率明显下降。由于GSMBE环境中存在由C1和H引起的表面化学反应的发生,生长速率急剧转变为可忽略不计。当C1浓度高达4 ~ 10′~时,薄膜表现出较高的晶体质量,这表明由单一强烈的供体结合激子跃迁引起的光致发光。在ZnSe:Cl的情况下,H存在于ZnSe层中,但似乎没有对n型薄膜的电学性能产生不利影响。利用电容-电压(C-V)谱图和霍尔效应测量对ZnSe:Cl层进行电学表征,得到的电子浓度值与SIMS得到的电子浓度值较为接近。氮掺杂p型ZnSe中氢的掺入有明显的差异
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Proceedings of IEE/LEOS Summer Topical Meetings: Integrated Optoelectronics
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