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EFFECT OF NOZZLE CONFIGURATION ON PERFORMANCE OF A SPRAY DRYER 喷嘴配置对喷雾干燥机性能的影响
Q3 Engineering Pub Date : 2024-01-03 DOI: 10.59957/jctm.v59.i1.2024.14
Ashraf Ali Basheer, Singh Sunil Kumar
In this work, hydrodynamics and drying characteristics of spray dryer is numerically investigated using computational fluid dynamics (CFD) using Euler-Lagrangian (EL) approach. The gas phase is modelled as the continuous phase and solid particle as the dispersed phase. The turbulence in the gas phase is predicted using RNG version of k-ε model. As air flow pattern influences the time spent by particle in drying chamber, the spatial variation of air velocity and its circulation rate is quantified. Accordingly, optimum conditions for drying the feed slurry are determined. Further, five different outlet pipe locations are chosen and the optimum location is identified which supports the highest evaporation rate. To improve the product quality, conventional nozzle is modified and particle impact positions are analyzed. The particles impact positions on the dryer’s surface are found to be minimum for the proposed nozzle configuration and it improves the final product quality.
本研究采用欧拉-拉格朗日(EL)方法,利用计算流体动力学(CFD)对喷雾干燥机的流体动力学和干燥特性进行了数值研究。气相被模拟为连续相,固体颗粒被模拟为分散相。气相中的湍流是使用 RNG 版本的 k-ε 模型预测的。由于气流模式会影响颗粒在干燥室中的停留时间,因此对气流速度及其循环速率的空间变化进行了量化。因此,确定了进料浆干燥的最佳条件。此外,还选择了五个不同的出口管道位置,并确定了支持最高蒸发率的最佳位置。为了提高产品质量,对传统的喷嘴进行了改进,并对颗粒的撞击位置进行了分析。结果发现,在拟议的喷嘴配置中,颗粒在干燥器表面的撞击位置最小,从而提高了最终产品质量。
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引用次数: 0
MODELLING THE EVOLUTION OF CASTING DEFECT CLOSURE BY RADIAL SHEAR ROLLING 通过径向剪切轧制模拟铸造缺陷闭合的演变过程
Q3 Engineering Pub Date : 2024-01-03 DOI: 10.59957/jctm.v59.i1.2024.23
F.E. Popov, N. Lutchenko, Alexandr Panichkin, S. Lezhnev, E. Panin, Leonid Vinogradov, A. Arbuz
This paper studies the behavior of a transverse through defect in an ingot during complex vortex flow of metal deformed by the radial shift rolling (RSR) method. The aim of the work was to investigate the applicability of the RSR method for the deformation treatment of oxide-dispersed strengthened steel (ODS-steel) ingots into a final semi-finished product. Vortex flow of metal promotes dispersion of alloying solid oxides and refinement of steel structure. However, the question of development or closure of possible casting defects of ODS-steel ingot remains open. For this purpose, an ODS-steel ingot with a through-hole modelling the defect was rolled according to the assumed process scheme. Also, to visualize the evolution of the defect in more detail during the rolling process, a simulation of thesame defect development in an aluminum bar has been performed in 2 mm steps. The results of both rolls showed good correlation. Based on many cross-sections of the experimental bars, detailed 3D models of the defect evolution were built. An average reduction of 50 % in defect volume was found. Welding of the outer areas occurs immediately, but the central areas remain unclosed, stretching proportionally with the drawing of the rod during rolling. For this reason, RSR cannot be used with large cavity defects in the axial zone, but this method is guaranteed to weld surface defects even at low reductions.
本文研究了通过径向偏移轧制(RSR)方法变形的金属在复杂涡流过程中钢锭中横向贯穿缺陷的行为。这项工作的目的是研究 RSR 方法是否适用于将氧化物分散强化钢(ODS-钢)钢锭变形处理成最终半成品。金属涡流可促进合金固体氧化物的分散和钢结构的细化。然而,ODS 钢锭可能存在的铸造缺陷的发展或消除问题仍未解决。为此,我们根据假定的工艺方案轧制了一块带有通孔的 ODS 钢锭。此外,为了更详细地观察缺陷在轧制过程中的演变,还以 2 毫米为单位模拟了铝棒中相同缺陷的发展。两种轧制结果显示出良好的相关性。根据实验棒材的许多横截面,建立了详细的缺陷演变三维模型。结果发现,缺陷体积平均减少了 50%。外部区域立即发生焊接,但中心区域仍未封闭,在轧制过程中随着棒材的拉伸成比例地伸长。因此,RSR 不能用于处理轴向区域的大空腔缺陷,但这种方法可以保证焊接表面缺陷,即使缺陷减少量较低。
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引用次数: 0
RESEARCH OF INJECTION METHODS FOR Y2O3 NANOPARTICLES INTO NICKEL- FREE STAINLESS STEEL DURING INDUCTION VACUUM REMELTING 感应真空重熔过程中向无镍不锈钢中注入 y2o3 纳米粒子的方法研究
Q3 Engineering Pub Date : 2024-01-03 DOI: 10.59957/jctm.v59.i1.2024.20
Alexandr Panichkin, F.E. Popov, N. Lutchenko, Askhat Beldeubayev, Ivan Samokhvalov, Alexandr Arbuz
Investigation of the possibility of obtaining an oxide-dispersed strengthening steel alloy based on 5 different ways of fine-dispersed strengthening particles Y2O3 injection into the liquid phase of steel Fe-13Cr (wt. %) in a vacuum. For this purpose, were conducted 5 series of experiments with different conditions and regimes. 2 series of 5 melts were carried out to evaluate the possibility of mechanical injection of yttrium oxide in the melt with different entry conditions. 3 series of 5 melts were conducted to evaluate the possibility of oxidation of metallic yttrium in the melt with the formation of yttrium oxide particles. Either melt residence or residual pressure in the furnace chamber was varied in different series. The results of ingot analysis on XRF, ICP-AES, and EDS showed that significant amounts of yttrium oxide were not injected. The method with oxidation of metallic yttrium in the melt from the reduction ofspecially added iron oxide with a concentration of 0.0552 ppm showed the best result.
基于 5 种不同的细分散强化粒子 Y2O3 在真空中注入钢 Fe-13Cr(重量百分比)液相的方法,研究获得氧化物分散强化钢合金的可能性。为此,进行了 5 次不同条件和制度的系列实验。2 个系列共 5 次熔炼,以评估在不同进入条件下在熔体中机械注入氧化钇的可能性。进行了 3 个系列 5 次熔化实验,以评估金属钇在熔体中氧化并形成氧化钇颗粒的可能性。在不同的系列中,熔体停留时间或炉腔中的残余压力均有所不同。钢锭的 XRF、ICP-AES 和 EDS 分析结果表明,没有注入大量的氧化钇。熔液中金属钇被氧化的方法是通过还原特别添加的氧化铁(浓度为 0.0552 ppm)来实现的,结果最好。
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引用次数: 0
ТOLERANCE TO FREEZE-DRYING CONDITIONS OF Lactobacillus delbrueckii subsp. bulgaricus STRAINS AFTER ACIDIC EXPOSE 酸性暴露后德尔布鲁贝克乳杆菌保加利亚亚种菌株对冷冻干燥条件的耐受性
Q3 Engineering Pub Date : 2024-01-03 DOI: 10.59957/jctm.v59.i1.2024.3
Ivo Ganchev
The goal of this work was to investigate the effect of fermentation pH and time on the acid tolerance, glycolytic activity, and survival during freeze drying of L. delbrueckii subsp. bulgaricus WDCM 00102 strains during cultivation in the medium, based on pretreated biomass of Spirulina platensis. During the study, when the fermentation process is carried out at a constant pH, a higher value of glycolytic activity is established in the cells of the probiotic culture, which decreases when the pH is lowered. The survival rate of cells of L. delbrueckii subsp. bulgaricus WDCM 00102 after lyophilization shows similar values after cultivation for 25 and 37 h (p < 0.05), while the opposite dependence is established in experiments related to changes in the pH of the cultivation medium. pH and fermentation time significantly influence the glycolytic activity of L. delbrueckii subsp. bulgaricus WDCM 00102 and on the resistance of its cells to acid stress and lyophilization conditions.
这项工作的目的是研究发酵 pH 值和时间对保加利亚酵母亚种 WDCM 00102 菌株在培养基中冷冻干燥期间的耐酸性、糖酵解活性和存活率的影响。在研究过程中,当发酵过程在恒定的 pH 值下进行时,益生菌培养物细胞中的糖酵解活性值较高,而当 pH 值降低时,糖酵解活性就会降低。L. delbrueckii subsp. bulgaricus WDCM 00102 细胞冻干后的存活率在培养 25 小时和 37 小时后显示出相似的值(p < 0.05),而在与培养基 pH 值变化相关的实验中则显示出相反的依赖性。 pH 值和发酵时间对 L. delbrueckii subsp. bulgaricus WDCM 00102 的糖酵解活性及其细胞对酸胁迫和冻干条件的抵抗力有显著影响。
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引用次数: 0
OPTIMIZING STABILITY OF WET CHEMISTRY OXIDE PASSIVATION OF Si (111) AND Si (100) 优化 Si (111) 和 Si (100) 的湿化学氧化物透过稳定性
Q3 Engineering Pub Date : 2024-01-03 DOI: 10.59957/jctm.v59.i2.2024.15
Abhinav Deep Pakki, R. K. Sharma, Neda Neykova, Petko Mandjukov, Jakub Holovský
Numerous parameters are regulated in the wet chemical oxidation process for TOPCon/POLO solar cell technology to improve silicon oxide passivation (SiO2). Understanding the electronic properties, particularly the lifetime of the carriers and their thickness, requires knowledge of the properties of the surface of crystalline silicon (c-Si), which is subjected to native oxide etching, followed by wet chemical oxidation, such as nitric acid or hot water oxidation and various hydrogenation methods. The results of these processes are tracked with lifetime measurement equipment, and spectral ellipsometry is used to measure the thickness of the oxide layer by using the single-sided polished wafers with surface orientation (1 1 1). In addition to the actual values, their time stability is also tracked.Before the hydrogenation step was introduced, the wafers’ lifetime was approximately 0.001 ms, which is less than the bulk lifetime; with the hydrogenation, the lifetime increased by more than an order of magnitude for a relatively long time with no difference between (1 1 1) and (1 0 0) wafers indicating that hydrogenation of the Si/SiO2 interface is performed.
在 TOPCon/POLO 太阳能电池技术的湿化学氧化过程中,有许多参数需要调节,以改善硅氧化物钝化(SiO2)。要了解电子特性,特别是载流子的寿命及其厚度,就必须了解晶体硅(c-Si)表面的特性,晶体硅表面要经过原生氧化物蚀刻,然后进行湿化学氧化,如硝酸或热水氧化以及各种氢化方法。使用寿命测量设备跟踪这些过程的结果,并使用光谱椭偏仪测量表面取向的单面抛光晶片的氧化层厚度(1 1 1)。在引入氢化步骤之前,晶片的寿命约为 0.001 毫秒,小于整体寿命;氢化后,寿命在相对较长的时间内增加了一个数量级以上,(1 1 1) 和 (1 0 0) 晶片之间没有差异,这表明 Si/SiO2 界面进行了氢化。
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引用次数: 0
INFLUENCE OF Nb2O5 AND B2O3 ON THE PHOTOCATALYTIC AND ANTIBACTERIAL ACTIVITY OF SOL-GEL DERIVED TiO2 NANOPОWDERS Nb2O5 和 B2O3 对溶胶-凝胶法制备的 TiO2 纳米氧化物光催化和抗菌活性的影响
Q3 Engineering Pub Date : 2024-01-03 DOI: 10.59957/jctm.v59.i2.2024.12
A. Bachvarova-Nedelcheva, R. Iordanova, Nelly Georgieva, Veronica Nemska, Tsvetelina Foteva, A. Stoyanova
TiO2 based powders containing B2O3 and Nb2O5 were obtained through an aqueous sol-gel method. The as prepared gels were step wisely heated in the temperature range 200°C - 500°C and subsequently characterized by XRD, IR and UV-Vis analysis. The TiO2 (anatase) is the single crystalline phase which has been detected up to 500°C. Photocatalytic tests showed that the investigated samples possess photocatalytic activity toward Malachite green organic dye and TiO2/Nb2O5 exhibited higher photocatalytic activity than TiO2/B2O3 sample. The compositions exhibited good antimicrobial activity against E. coli NBIMCC K12 407 and Bacillus subtilis NBIMCC 3562.
通过水溶胶凝胶法获得了含有 B2O3 和 Nb2O5 的二氧化钛粉末。制备的凝胶在 200°C - 500°C 的温度范围内分步加热,随后通过 XRD、IR 和 UV-Vis 分析进行表征。TiO2(锐钛型)是单晶相,其检测温度高达 500°C。光催化测试表明,所研究的样品对孔雀石绿有机染料具有光催化活性,TiO2/Nb2O5 的光催化活性高于 TiO2/B2O3 样品。这些组合物对大肠杆菌 NBIMCC K12 407 和枯草杆菌 NBIMCC 3562 具有良好的抗菌活性。
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引用次数: 0
CORRELATION BETWEEN AGING TIME PERIOD OF METAL PRECURSOR SOL – PHASE COMPOSITION AND TEXTURAL PROPERTIES OF ZIRCONIA NANOPOWDERS 金属前驱体溶胶老化时间段-相组成与氧化锆纳米粉体纹理特性之间的相关性
Q3 Engineering Pub Date : 2024-01-03 DOI: 10.59957/jctm.v59.i1.2024.26
Eva Mitkova, Irina Stambolova, Daniela Stoyanova, V. Toteva, Ognian Dimitrov
This article investigates the effect of the time of aging of ZrO2 powders, obtained from zirconium butoxide sols, stabilized using complexating agents on the volume phase fractions tetragonal phase (T) and baddeleyite crystalographic phase (B), pore size distribution and pore volume. It was proved that the aging time period influences ratio between these two polymorphs of zirconia. The sample Zr3d possesses the largest content of baddeleyite phase having the greatest crystallites in comparison to another two powders. The increasing of aging period leads to a gradual increase in (101) peak intensity of T phase, while all the samples are microporous regardless of the aging time. The longest time aged sample possesses higher pore volume and higher average pore diameter than the other two powders. The physico-chemical features of the prepared ZrO2 nanosized powders could be beneficial as catalysts/photocatalysts in different catalytic reactions, corrosion inhibition particles, etc.
本文研究了从使用络合剂稳定的丁氧化锆溶胶中获得的氧化锆粉末的老化时间对四方相(T)和巴德来特晶相(B)的体积相分数、孔径分布和孔体积的影响。实验证明,老化时间会影响氧化锆这两种多晶体之间的比例。与其他两种粉末相比,Zr3d 样品中的巴德来特相含量最高,结晶也最大。随着老化时间的延长,T 相的(101)峰强度逐渐增加,而无论老化时间长短,所有样品都具有微孔。与其他两种粉末相比,老化时间最长的样品具有更高的孔体积和平均孔直径。所制备的 ZrO2 纳米粉末的物理化学特征可用作不同催化反应的催化剂/光催化剂、缓蚀剂颗粒等。
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引用次数: 0
TREATMENT OF OYSTER SHELLS AND PREPARING THEM AS AN ADSORBENT SURFACE TO TOLUIDINE BLUE DYE 处理牡蛎壳并将其用作甲苯胺蓝染料的吸附表面
Q3 Engineering Pub Date : 2024-01-03 DOI: 10.59957/jctm.v59.i1.2024.11
Ghusoon Shabaa, R. Zabibah
The presence of dyes in drainage water is one of the important problems that many seek to solve. This study included the preparation of the adsorbent surface using the oyster shells as a basis for the preparation of chitosan, which is a series of carbohydrates and saccharides, by treating them with some simple chemical reactions that grab the acetyl group (de-acetylation), which is a part of the structure of chitin. Then the basic formula of Chitosan is ready to carry positive charges, which act as magnet to attract molecules of any substance beside it. A series of assays were undertaken to assess the efficiency of the adsorption process, such as the weight of oyster shells, equilibrium time, effect of pH, initial concentration of toluidine blue dye, and particle size of the adsorbent. These experiments have shown that the equilibrium time was 120 min, the optimum weight of oyster shells was 0.1 g in 100 mL of dye solution, and the particle size was 150 μm. They also showed there is an effect of the pH on the adsorption of the dye. The adsorption isotherm was well fitted to both the Freundlich and Langmuir models.
排水中存在染料是许多人寻求解决的重要问题之一。这项研究包括以牡蛎壳为基础制备壳聚糖的吸附剂表面,壳聚糖是一系列碳水化合物和糖类,通过一些简单的化学反应处理,抓住乙酰基(脱乙酰基),乙酰基是甲壳素结构的一部分。这样,壳聚糖的基本结构就可以携带正电荷,而正电荷就像磁铁一样,可以吸引它旁边的任何物质分子。为了评估吸附过程的效率,我们进行了一系列实验,如牡蛎壳的重量、平衡时间、pH 值的影响、甲苯胺蓝染料的初始浓度和吸附剂的粒度。这些实验表明,平衡时间为 120 分钟,在 100 毫升染料溶液中牡蛎壳的最佳重量为 0.1 克,颗粒大小为 150 微米。他们还发现 pH 值对染料的吸附也有影响。吸附等温线与 Freundlich 和 Langmuir 模型都很吻合。
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引用次数: 0
CYBER-PHYSICAL SECURITY THROUGH FACIAL RECOGNITION AND SENSOR DATA ANALYSIS 通过面部识别和传感器数据分析实现网络物理安全
Q3 Engineering Pub Date : 2024-01-03 DOI: 10.59957/jctm.v59.i2.2024.27
Ivaylo Atanasov, D. Pilev
The digital age has brought tremendous opportunities for innovation and efficiency. However, it has also exposed businesses, governments, and individuals to a range of cyber threats, such as data breaches, network attacks, ransomware, malicious insiders, and identity theft. This requires the implementation of robust cybersecurity measures to safeguard sensitive information and ensure the uninterrupted operation of all critical IT systems. This paper aims to provide a facial recognition security system for cyber-physical security that incorporates a neural network and intelligent algorithms to assess the severity level of security breaches. The system also includes alarms with severity levels ranging from 1 (low severity) to 4 (critical), based on facial recognition and data from carbon dioxide and temperature sensors. In the event of a security breach, an incident response plan is presented. The proposed system is applicable to offices, workspaces, server rooms, data centers and other areas where information is stored, to enhance physical security and protect against cybersecurity threats.
数字时代为创新和效率带来了巨大的机遇。然而,它也使企业、政府和个人面临一系列网络威胁,如数据泄露、网络攻击、勒索软件、恶意内鬼和身份盗用。这就需要实施强有力的网络安全措施来保护敏感信息,并确保所有关键 IT 系统的不间断运行。本文旨在提供一种用于网络物理安全的面部识别安全系统,该系统结合了神经网络和智能算法来评估安全漏洞的严重程度。该系统还包括根据面部识别以及二氧化碳和温度传感器的数据发出的严重程度从 1(低严重性)到 4(严重性)不等的警报。一旦发生安全漏洞,系统将提出事故响应计划。拟议的系统适用于办公室、工作区、服务器机房、数据中心和其他存储信息的区域,以加强实体安全和防范网络安全威胁。
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引用次数: 0
CORROSION BEHAVIOR OF MILD STEEL IN SODIUM SULFATE SOLUTION IN PRESENCE OF PHOSPHATES OF DIFFERENT COMPOSITION 低碳钢在不同成分磷酸盐存在的硫酸钠溶液中的腐蚀行为
Q3 Engineering Pub Date : 2024-01-03 DOI: 10.59957/jctm.v59.i2.2024.16
A. Raimbekova, Viktoriya Kapralova, Angelina Popova, Sholpan Kubekova, Amantai Dalbanbay, Aizhan Kalenova, Bekezhan Mustahimov, Sharipa Yermekbayeva, Sharbanu Myrzabekova
Corrosion of mild steel in sodium sulfate solutions (1000 mg SO42- L-1) in the presence of various phosphateinhibitors was studied gravimetrically. Studies were performed under static conditions at room temperature. The known sodium polyphosphate inhibitor has been found to have low efficacy under these conditions. The inhibitor efficiency of its does not exceed 30.5 % at a concentration of 100 mg P2O5 L-1. It has been shown that a more effective inhibitor is calcium-manganese polyphosphate (Са, Mn)(PO3)2 obtained on the basis of manganese ore enrichment wastes of the Zhayrem deposit. The inhibitor efficiency of its already at a concentration of 20 mgP2O5 L-1 is 47.3 %. At a concentration of 100 mgP2O5 L-1, the inhibitor efficiency (Са, Mn)(PO3)2 is 96.2 %. Electrochemical tests confirmed the results of the gravimetric study. Infrared spectroscopic analysis showed that phosphate protective coatings were formed on the steel surface in solutions of sodium sulfate with additives of calcium-manganese polyphosphate.
在硫酸钠溶液(1000 毫克 SO42- L-1)中,在各种磷酸盐抑制剂的作用下,对低碳钢的腐蚀进行了重力测量研究。研究是在室温静态条件下进行的。研究发现,已知的聚磷酸钠抑制剂在这些条件下的功效较低。在 100 mg P2O5 L-1 的浓度下,其抑制效率不超过 30.5%。研究表明,更有效的抑制剂是在 Zhayrem 矿床锰矿富集废料基础上获得的钙锰聚磷酸盐 (Са,Mn)(PO3)2。当浓度为 20 mgP2O5 L-1 时,其抑制效率为 47.3%。当浓度为 100 mgP2O5 L-1 时,其抑制效率 (Са, Mn)(PO3)2 为 96.2 %。电化学测试证实了重量分析的结果。红外光谱分析显示,在含有聚磷酸钙锰添加剂的硫酸钠溶液中,钢铁表面形成了磷酸盐保护层。
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引用次数: 0
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Journal of Chemical Technology and Metallurgy
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