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Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996最新文献

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Development of p/n and n/p thick emitter InP solar cells p/n和n/p厚发射极InP太阳能电池的研制
P. Sharps, M. Timmons, S. Messenger, H. Cotal, G. Summers, P. Iles
Both n/p and p/n InP thick emitter (0.3 /spl mu/m) space solar cells with and without Ga/sub 0.5/In/sub 0.5/P windows are studied. Both polarity cells are considered for possible growth on Ge. While not achieving the high efficiencies of thin emitter InP cells, the thicker emitter cells may provide an advantage in radiation hardness. The Ga/sub 0.5/In/sub 0.5/P window has little effect on cell performance, for either polarity.
对有无Ga/sub 0.5/In/sub 0.5/ p窗口的n/p和p/n InP厚发射极(0.3 /spl mu/m)空间太阳能电池进行了研究。这两种极性的细胞都被认为可能在锗上生长。虽然不能达到薄发射极InP电池的高效率,但较厚的发射极电池可能在辐射硬度方面具有优势。对于任何极性,Ga/sub 0.5/In/sub 0.5/P窗口对电池性能几乎没有影响。
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引用次数: 2
Mars Global Surveyor (MGS) high temperature survival solar array 火星全球勘测者(MGS)高温生存太阳能电池阵列
P. Stella, R. Ross, B.S. Smith, G. Glenn, K.S. Sharmit
The MGS mission is one of the first major planetary missions conducted under the new NASA Faster, Better, Cheaper guidelines. Ironically, mission requirements make the MGS solar array one of the most challenging designs built for NASA. Not only will the array include silicon and GaAs/Ge panels, but the solar array will be used to aerobrake the spacecraft in the upper regions of the Martian atmosphere. Consequently, even though a mission to Mars is normally typified by cold temperatures, aerobraking imposes a high temperature requirement of nearly 180/spl deg/C, higher than that experienced by any previous array. The array size is tightly constrained by mass and area. Since the aerobraking occurs early in the mission, it is necessary to subsequently survive up to 20000 lower temperature thermal cycles. Furthermore, the location of a magnetometer directly on the array structure requires the minimization of circuit induced magnetic moments. This paper provides an overview of the array design and performance. In addition, the high temperature capable design and development are discussed in detail.
MGS任务是在NASA新的“更快、更好、更便宜”指导方针下进行的首批主要行星任务之一。具有讽刺意味的是,任务要求使MGS太阳能阵列成为NASA建造的最具挑战性的设计之一。该阵列不仅包括硅和砷化镓/锗板,而且太阳能阵列将用于在火星大气上层区域对航天器进行空气制动。因此,尽管火星任务通常以低温为特征,但航空制动对温度的要求接近180/spl度/C,比以往任何阵列所经历的都要高。阵列的大小受到质量和面积的严格限制。由于航空制动发生在任务的早期,因此有必要在随后的两万次低温热循环中存活下来。此外,磁力计直接放置在阵列结构上要求电路感应磁矩最小。本文概述了该阵列的设计和性能。此外,还详细讨论了耐高温性能的设计与开发。
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引用次数: 1
Manufacturing-compatible methods for the formation of Cu(In,Ga)Se/sub 2/ thin films 制备Cu(In,Ga)Se/sub /薄膜的相容方法
A. Gabor, J. Britt, A.E. Delahoy, R. Noufi, Z. Kiss
The authors have developed suitable methods of Cu(In,Ga)Se/sub 2/ thin-film formation for application in large-scale manufacturing equipment. Total-area solar cell efficiencies as high as 13.9% have been achieved on small-area cells by these methods. Large-area film thickness and V/sub OC/ uniformity data are also presented. The film formation involves sequential deposition of compound selenides, Se, and Cu. The fill factor of some devices was improved by deposition of a thin terminal In-Se layer, and surface modification by chemical treatments also improved device performance.
作者开发了适合大规模制造设备应用的Cu(In,Ga)Se/sub 2/薄膜形成方法。通过这些方法,小面积太阳能电池的总面积效率高达13.9%。大面积薄膜厚度和V/亚OC/均匀性数据也给出了。薄膜的形成涉及化合物硒化物、硒和铜的连续沉积。通过沉积薄的终端In-Se层可以提高器件的填充系数,通过化学处理的表面改性也可以提高器件的性能。
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引用次数: 2
Development of PV receivers for space line-focus concentrator modules 空间线聚焦聚光模块用光伏接收器的研制
V. Andreev, V. Lantratov, V. Larionov, V. Rumyantsev, M. Shvarts
A practical design has been developed for string-type PV receivers intended to operate in space application line-focus concentrator modules. MOCVD grown AlGaAs/GaAs solar cells are used in these receivers as the main elements whereas Zn-diffused GaSb solar cells are used in tandem to improve total efficiency. Secondary cylindrical lenses operating similar to a "large scale prismatic cover" and transforming a focal light line into separated spots are introduced on the surfaces of solar cells. Efficiency 18.3% (AM0, 15 Suns, RT) has been measured on the receiver 72 mm long constructed from twelve series-connected AlGaAs/GaAs solar cells.
已经开发了一种实用的设计,用于在空间应用线聚焦集中器模块中操作的串型PV接收器。这些接收器采用MOCVD生长的AlGaAs/GaAs太阳能电池作为主要元件,而锌扩散的GaSb太阳能电池则串联使用以提高总效率。二次圆柱形透镜的工作原理类似于“大型棱镜罩”,并在太阳能电池的表面上引入了将焦点光线转换成分离点的方法。在由12个串联的AlGaAs/GaAs太阳能电池组成的72mm长的接收器上,测量到了18.3% (AM0, 15太阳,RT)的效率。
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引用次数: 1
Indoor and outdoor testing of space concentrator AlGaAs/GaAs photovoltaic modules with Fresnel lenses 菲涅耳透镜空间聚光AlGaAs/GaAs光伏组件的室内和室外测试
V. Grilikhes, V. Rumyantsev, M. Shvarts
The use of a high-efficiency space concentrator photovoltaic (PV) modules requires a development of the testing methods and a measuring equipment for their laboratory inspection. In this case it is necessary to take into account the specific behaviour of module elements under operating conditions as well as interaction between optical and electrogenerating parts. The aim of this work is to develop the laboratory (indoor) testing procedure for concentrator PV modules, to predict their characteristics during the space flight experiment, to apply the developed methods to the lens concentrator PV modules and to check indoor results in preliminary terrestrial (outdoor) experiment.
使用高效空间聚光光伏(PV)模块需要开发测试方法和测量设备进行实验室检测。在这种情况下,有必要考虑模块元件在操作条件下的具体行为以及光学和发电部件之间的相互作用。本工作的目的是制定聚光光伏组件的实验室(室内)测试程序,预测其在空间飞行实验中的特性,将所开发的方法应用于透镜聚光光伏组件,并在地面(室外)初步实验中检查室内结果。
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引用次数: 8
Development of the GaAs solar cell for space application 空间应用砷化镓太阳能电池的研究进展
Chen Mingbo, Zhang Zhongwei
To meet the requirements of space power use, the authors developed a new multiwafer LPE technique. This technique applied a squeezing multiwafer graphite boat, with 50 wafers (2.3/spl times/2.3 cm/sup 2/) or 20 wafers (2.3/spl times/ 4.3 cm/sup 2/) produced at each epitaxial growth. They focused on the control technique for the epitaxial layers' parameters. Experimental results demonstrated that epitaxial growth at low temperature could produce ideal GaAs solar cells with good repeatability. To date, the efficiencies of GaAs solar cells prepared by this technique have reached 18.6% (2/spl times/2 cm/sup 2/, AMO) and 18.39% (2/spl times/4 cm/sup 2/, AMO), respectively. Average efficiency of the cells prepared in a small lot is 17.5% (AMO), and all the samples were qualified in space environment simulation tests.
为了满足空间电源使用的要求,作者开发了一种新的多晶片LPE技术。该技术采用挤压多晶片石墨船,每次外延生长产生50片(2.3/spl次/2.3 cm/sup 2/)或20片(2.3/spl次/ 4.3 cm/sup 2/)。重点研究了外延层参数的控制技术。实验结果表明,低温外延生长可以制备出具有良好重复性的理想的砷化镓太阳能电池。迄今为止,利用该技术制备的砷化镓太阳能电池的效率分别达到18.6% (2/spl倍/2 cm/sup 2/, AMO)和18.39% (2/spl倍/4 cm/sup 2/, AMO)。小批量制备的电池平均效率为17.5% (AMO),所有样品在空间环境模拟试验中均合格。
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引用次数: 3
Mc-Si thin film solar cells by fast CVD on low cost SSP pre-ribbons 低成本SSP预带快速CVD制备Mc-Si薄膜太阳能电池
F. Faller, N. Schillinger, A. Hurrle, C. Schetter, A. Eyer
Silicon films 40-90 /spl mu/m thick were epitaxially deposited on fast-grown mc-SSP pre-ribbons. Special attention was focused on the design of the authors' self-constructed CVD system. It is principally convertable into a conveyer-belt system for a high continuous throughput, which is needed to be economically competitive. With high deposition rates of up to 10 /spl mu/m/min, the epi-layers revealed diffusion lengths of 250 /spl mu/m on <100>-Cz substrates, 150 /spl mu/m on SILSO and 11-30 /spl mu/m on SSP pre-ribbons (all substrates highly doped). Solar cells were manufactured using the authors' standard cell process. No passivation or gettering steps were performed and no texturing was applied. Solar cell efficiencies of 12.8% on Cz, 11.1% on SILSO wafers and 6.1% on SSP were achieved.
在快速生长的mc-SSP预带上外延沉积了厚度为40-90 /spl mu/m的硅膜。重点介绍了自建CVD系统的设计。它主要是转换成一个输送带系统的高连续吞吐量,这是需要在经济上具有竞争力。随着沉积速率高达10 /spl mu/m/min,外接层在-Cz衬底上的扩散长度为250 /spl mu/m,在SILSO衬底上的扩散长度为150 /spl mu/m,在SSP预带上的扩散长度为11-30 /spl mu/m(所有衬底都高度掺杂)。太阳能电池是使用作者的标准电池工艺制造的。没有执行钝化或获取步骤,也没有应用纹理。太阳能电池在Cz上的效率为12.8%,在SILSO晶圆上的效率为11.1%,在SSP上的效率为6.1%。
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引用次数: 5
Dynamics of photoexcited carrier relaxation and recombination in CdTe/CdS thin films CdTe/CdS薄膜中光激发载流子弛豫和复合动力学
D. Levi, B. Fluegel, R. Ahrenkiel, A. Compaan, L. Woods
Efficiency-limiting defects in photovoltaic devices are readily probed by time-resolved spectroscopy. This paper presents the first direct optical measurements of the relaxation and recombination pathways of photoexcited carriers in the CdS window layer of CdTe/CdS polycrystalline thin films. We utilize the complimentary techniques of femtosecond time-resolved differential absorption (TRDA) and picosecond time-resolved photoluminescence (TRPL) to determine the relaxation and recombination mechanisms in these films. Comparison between samples with systematic variations in their CdS layers leads to several conclusions. Photoexcited holes are very rapidly captured by deep traps where they remain until recombining with electrons in shallow traps. The hole trapping states are most likely produced by tellurium substituting for sulfur in the CdS lattice. We postulate that reduction of tellurium diffusion into CdS during growth may increase the spectral response of CdTe/CdS solar cells for photon energies above 2.5 eV by reducing or eliminating these defect sites.
光伏器件中的效率限制缺陷很容易用时间分辨光谱来探测。本文首次对CdTe/CdS多晶薄膜CdS窗口层中光激发载流子的弛豫和复合路径进行了直接光学测量。我们利用飞秒时间分辨微分吸收(TRDA)和皮秒时间分辨光致发光(TRPL)互补技术来确定这些薄膜的弛豫和复合机制。对cd层有系统变化的样品进行比较可以得出几个结论。光激发态的空穴很快被深阱捕获,在浅阱中与电子重新结合。空穴捕获态很可能是由碲取代CdS晶格中的硫而产生的。我们假设在生长过程中碲扩散到CdS中的减少可能会通过减少或消除这些缺陷位点来增加CdTe/CdS太阳能电池对2.5 eV以上光子能量的光谱响应。
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引用次数: 1
Record high 18.6% efficient solar cell on HEM multicrystalline material 在HEM多晶材料上创造了18.6%的太阳能电池效率
A. Rohatgi, S. Narasimha, S. Kamra, P. Doshi, C. Khattak, K. Emery, H. Field
Solar cells with efficiencies as high as 18.6% (1 cm/sup 2/ area) have been achieved by a process which involves impurity gettering and effective back surface passivation on 0.65 /spl Omega/-cm multicrystalline silicon (mc-Si) grown by the heat exchanger method (HEM). This represents the highest reported solar cell efficiency on mc-Si to date. PCD analysis revealed that the bulk lifetime (/spl tau//sub b/) in HEM samples after phosphorus gettering can be as high as 135 /spl mu/s. This increases the impact of the back surface recombination velocity (S/sub b/) on the solar cell performance. By incorporating a deeper aluminum BSF, the S/sub b/ for solar cells in this study was lowered from 10000 cm/s to 2000 cm/s on HEM mc-Si. This combination of high /spl tau//sub b/ and moderately low S/sub b/ resulted in the record high efficiency mc-Si solar cell. Model calculations indicate that lowering S/sub b/ further can raise the efficiency of untextured HEM mc-Si solar cells above 19.0%, thus closing the efficiency gap between good quality, untextured single crystal and mc-Si solar cells.
在热交换器法(HEM)生长的0.65 /spl Omega/-cm多晶硅(mc-Si)上,通过杂质捕集和有效的背表面钝化工艺,获得了效率高达18.6% (1 cm/sup 2/面积)的太阳能电池。这代表了迄今为止mc-Si上报道的最高太阳能电池效率。PCD分析表明,吸磷后HEM样品的体积寿命(/spl tau//sub b/)可高达135 /spl mu/s。这增加了后表面复合速度(S/sub b/)对太阳能电池性能的影响。通过加入更深的铝BSF,本研究中太阳能电池的S/sub / b/在HEM mc-Si上从10000 cm/ S降低到2000 cm/ S。这种高/spl τ //sub b/和中等低S/sub b/的组合导致了创纪录的高效率mc-Si太阳能电池。模型计算表明,进一步降低S/sub b/可以使无纹理HEM mc-Si太阳电池的效率提高到19.0%以上,从而缩小了质量好的无纹理单晶与mc-Si太阳电池的效率差距。
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引用次数: 40
200 /spl mu/m thick encapsulated amorphous silicon solar cells 200 /spl亩/米厚封装非晶硅太阳能电池
B. Crone, A. Payne, S. Wagner
A 200 /spl mu/m thick fully glass-encapsulated a-Si:H solar cell is demonstrated. The cell structure is 75 /spl mu/m glass foil superstrate/a-Si,N:H diffusion barrier/specular ZnO:Al/a-Si:H pin solar cell/Al. The solar cell is encapsulated with 50 /spl mu/m ethylene vinyl acetate (EVA) and another 75 /spl mu/m glass foil. The current-voltage characteristics of a 0.24 cm/sup 2/ cell measured under AM1.5 (100 mW/cm/sup 2/) light give V/sub OC/=0.83 V, J/sub SC/=11.1 mA/cm/sup 2/, and FF=0.61, for an initial efficiency of 5.6%.
展示了一种200 /spl亩/米厚的全玻璃封装的A - si:H太阳能电池。电池结构为75 /spl mu/m玻璃箔上覆层/a-Si,N:H扩散阻挡层/镜面ZnO:Al/a-Si:H引脚太阳能电池/Al。太阳能电池用50 /磅/米的醋酸乙烯酯(EVA)和另外75 /磅/米的玻璃箔封装。在AM1.5 (100 mW/cm/sup 2/)光下测量的0.24 cm/sup 2/电池的电流-电压特性为V/sub OC/=0.83 V, J/sub SC/=11.1 mA/cm/sup 2/, FF=0.61,初始效率为5.6%。
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引用次数: 1
期刊
Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996
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