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Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996最新文献

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Dynamics of photoexcited carrier relaxation and recombination in CdTe/CdS thin films CdTe/CdS薄膜中光激发载流子弛豫和复合动力学
D. Levi, B. Fluegel, R. Ahrenkiel, A. Compaan, L. Woods
Efficiency-limiting defects in photovoltaic devices are readily probed by time-resolved spectroscopy. This paper presents the first direct optical measurements of the relaxation and recombination pathways of photoexcited carriers in the CdS window layer of CdTe/CdS polycrystalline thin films. We utilize the complimentary techniques of femtosecond time-resolved differential absorption (TRDA) and picosecond time-resolved photoluminescence (TRPL) to determine the relaxation and recombination mechanisms in these films. Comparison between samples with systematic variations in their CdS layers leads to several conclusions. Photoexcited holes are very rapidly captured by deep traps where they remain until recombining with electrons in shallow traps. The hole trapping states are most likely produced by tellurium substituting for sulfur in the CdS lattice. We postulate that reduction of tellurium diffusion into CdS during growth may increase the spectral response of CdTe/CdS solar cells for photon energies above 2.5 eV by reducing or eliminating these defect sites.
光伏器件中的效率限制缺陷很容易用时间分辨光谱来探测。本文首次对CdTe/CdS多晶薄膜CdS窗口层中光激发载流子的弛豫和复合路径进行了直接光学测量。我们利用飞秒时间分辨微分吸收(TRDA)和皮秒时间分辨光致发光(TRPL)互补技术来确定这些薄膜的弛豫和复合机制。对cd层有系统变化的样品进行比较可以得出几个结论。光激发态的空穴很快被深阱捕获,在浅阱中与电子重新结合。空穴捕获态很可能是由碲取代CdS晶格中的硫而产生的。我们假设在生长过程中碲扩散到CdS中的减少可能会通过减少或消除这些缺陷位点来增加CdTe/CdS太阳能电池对2.5 eV以上光子能量的光谱响应。
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引用次数: 1
Development of PV receivers for space line-focus concentrator modules 空间线聚焦聚光模块用光伏接收器的研制
V. Andreev, V. Lantratov, V. Larionov, V. Rumyantsev, M. Shvarts
A practical design has been developed for string-type PV receivers intended to operate in space application line-focus concentrator modules. MOCVD grown AlGaAs/GaAs solar cells are used in these receivers as the main elements whereas Zn-diffused GaSb solar cells are used in tandem to improve total efficiency. Secondary cylindrical lenses operating similar to a "large scale prismatic cover" and transforming a focal light line into separated spots are introduced on the surfaces of solar cells. Efficiency 18.3% (AM0, 15 Suns, RT) has been measured on the receiver 72 mm long constructed from twelve series-connected AlGaAs/GaAs solar cells.
已经开发了一种实用的设计,用于在空间应用线聚焦集中器模块中操作的串型PV接收器。这些接收器采用MOCVD生长的AlGaAs/GaAs太阳能电池作为主要元件,而锌扩散的GaSb太阳能电池则串联使用以提高总效率。二次圆柱形透镜的工作原理类似于“大型棱镜罩”,并在太阳能电池的表面上引入了将焦点光线转换成分离点的方法。在由12个串联的AlGaAs/GaAs太阳能电池组成的72mm长的接收器上,测量到了18.3% (AM0, 15太阳,RT)的效率。
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引用次数: 1
Development of the GaAs solar cell for space application 空间应用砷化镓太阳能电池的研究进展
Chen Mingbo, Zhang Zhongwei
To meet the requirements of space power use, the authors developed a new multiwafer LPE technique. This technique applied a squeezing multiwafer graphite boat, with 50 wafers (2.3/spl times/2.3 cm/sup 2/) or 20 wafers (2.3/spl times/ 4.3 cm/sup 2/) produced at each epitaxial growth. They focused on the control technique for the epitaxial layers' parameters. Experimental results demonstrated that epitaxial growth at low temperature could produce ideal GaAs solar cells with good repeatability. To date, the efficiencies of GaAs solar cells prepared by this technique have reached 18.6% (2/spl times/2 cm/sup 2/, AMO) and 18.39% (2/spl times/4 cm/sup 2/, AMO), respectively. Average efficiency of the cells prepared in a small lot is 17.5% (AMO), and all the samples were qualified in space environment simulation tests.
为了满足空间电源使用的要求,作者开发了一种新的多晶片LPE技术。该技术采用挤压多晶片石墨船,每次外延生长产生50片(2.3/spl次/2.3 cm/sup 2/)或20片(2.3/spl次/ 4.3 cm/sup 2/)。重点研究了外延层参数的控制技术。实验结果表明,低温外延生长可以制备出具有良好重复性的理想的砷化镓太阳能电池。迄今为止,利用该技术制备的砷化镓太阳能电池的效率分别达到18.6% (2/spl倍/2 cm/sup 2/, AMO)和18.39% (2/spl倍/4 cm/sup 2/, AMO)。小批量制备的电池平均效率为17.5% (AMO),所有样品在空间环境模拟试验中均合格。
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引用次数: 3
Rapid thermal processing of conventionally and electromagnetically cast 100 cm/sup 2/ multicrystalline silicon 快速热加工常规和电磁铸造100厘米/sup 2/多晶硅
S. Sivoththaman, W. Laureys, P. de Schepper, J. Nijs, R. Mertens
100 cm/sup 2/ n/sup +/pp/sup +/ solar cells have been fabricated by rapid thermal processing (RTP) on conventionally cast (CC) and electromagnetically cast (EMC) multicrystalline silicon (mc-Si). All thermal steps were carried out by fast-ramp (>30/spl deg/C/s) RTP using tungsten-halogen lamps. Emitter and BSF were simultaneously formed by RTP co-diffusion of phosphorous and boron/or aluminum (50-60 seconds) and surface passivation by rapid thermal oxidation, RTO (40-50 seconds). The all-RTP process resulted in 14.1% and 13.3% efficient cells on CC and EMC mc-Si respectively. The EMC cells, when subjected to an additional plasma hydrogen treatment, improved to give the same efficiency as the CC mc-Si cells. Systematic lifetime measurements performed on these materials show that the degradation in the EMC mc-Si is mainly due to the activated crystallographic defects, responding favourably to hydrogenation treatments but poorly to RT-gettering treatments. On the other hand, significant gettering effects are observed in CC mc-Si.
在常规铸造(CC)多晶硅(mc-Si)和电磁铸造(EMC)多晶硅(mc-Si)上,采用快速热加工(RTP)技术制备了100 cm/sup 2/ n/sup +/pp/sup +/太阳能电池。所有热步骤均采用钨卤灯快速斜坡(>30/spl°/C/s) RTP进行。通过磷和硼/铝的RTP共扩散(50-60秒)和快速热氧化(RTO)表面钝化(40-50秒)同时形成发射极和BSF。全rtp工艺在CC和EMC mc-Si上的电池效率分别为14.1%和13.3%。当EMC电池经过额外的等离子氢处理后,其效率提高到与CC mc-Si电池相同。对这些材料进行的系统寿命测量表明,EMC mc-Si的降解主要是由于活化的晶体缺陷,对加氢处理反应良好,而对rt吸光处理反应较差。另一方面,在CC mc-Si中观察到明显的吸散效应。
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引用次数: 6
Estimating and controlling chromatic aberration losses for two-junction, two-terminal devices in refractive concentrator systems 折光聚光系统中双结双端器件色差损耗的估计与控制
S. Kurtz, M. O'neill
Although previous studies have measured and calculated solar cell chromatic aberration losses and proposed methods for reducing these by modifying the optics, significant work remains to be done toward understanding how to quantify the losses and how various parameters affect this loss. This paper presents an analytical definition and calculation method for chromatic aberration losses in Ga/sub 0.5/In/sub 0.5/P/GaAs solar cells. The effects of sheet resistance of the midlayers of the cell, total irradiance, incident spectrum, cell width and diode quality factor are studied. A method for measuring the midlayer resistance in finished solar cells is also described.
虽然以前的研究已经测量和计算了太阳能电池色差损失,并提出了通过修改光学来减少这些损失的方法,但在了解如何量化损失以及各种参数如何影响这种损失方面仍有重要的工作要做。本文给出了Ga/sub 0.5/ in /sub 0.5/P/GaAs太阳能电池色差损耗的解析定义和计算方法。研究了电池中间层的片电阻、总辐照度、入射光谱、电池宽度和二极管质量因子等因素的影响。本文还描述了一种测量成品太阳能电池中间层电阻的方法。
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引用次数: 49
Development of a low cost integrated 15 kW AC solar tracking subarray for grid connected PV power system applications 用于并网光伏发电系统的低成本集成15kw交流太阳能跟踪子阵列的开发
M. Stern, R. West
The Utility Power Group has reduced the installation cost of grid connected photovoltaic power systems through a two step approach of integrating and packaging all sub-array power conversion and control functions within a single factory produced enclosure and utilizing large area factory assembled photovoltaic panels. A modular 15 kW AC single axis solar tracking sub-array was designed to meet the requirements of Article 690 of the 1996 National Electrical Code and eight prototype sub-arrays are under construction in Sacramento, California for the Sacramento Municipal Utility District. This paper presents general design information and describes the cost savings associated with the utilization of an integrated approach to PV system cost reduction.
公用事业电力集团通过两步方法降低了并网光伏发电系统的安装成本,即在一个工厂生产的外壳内集成和包装所有子阵列电源转换和控制功能,并利用工厂组装的大面积光伏板。模块化的15千瓦交流单轴太阳能跟踪子阵列设计满足1996年国家电气规范第690条的要求,8个原型子阵列正在加利福尼亚州萨克拉门托萨克拉门托市政公用事业区建设中。这篇论文提出了一般的设计信息,并描述了与利用光伏系统成本降低的综合方法相关的成本节约。
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引用次数: 10
Manufacturing-compatible methods for the formation of Cu(In,Ga)Se/sub 2/ thin films 制备Cu(In,Ga)Se/sub /薄膜的相容方法
A. Gabor, J. Britt, A.E. Delahoy, R. Noufi, Z. Kiss
The authors have developed suitable methods of Cu(In,Ga)Se/sub 2/ thin-film formation for application in large-scale manufacturing equipment. Total-area solar cell efficiencies as high as 13.9% have been achieved on small-area cells by these methods. Large-area film thickness and V/sub OC/ uniformity data are also presented. The film formation involves sequential deposition of compound selenides, Se, and Cu. The fill factor of some devices was improved by deposition of a thin terminal In-Se layer, and surface modification by chemical treatments also improved device performance.
作者开发了适合大规模制造设备应用的Cu(In,Ga)Se/sub 2/薄膜形成方法。通过这些方法,小面积太阳能电池的总面积效率高达13.9%。大面积薄膜厚度和V/亚OC/均匀性数据也给出了。薄膜的形成涉及化合物硒化物、硒和铜的连续沉积。通过沉积薄的终端In-Se层可以提高器件的填充系数,通过化学处理的表面改性也可以提高器件的性能。
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引用次数: 2
GaAs- and InAlGaAs-based concentrator-type cells for conversion of power transmitted by optical fibers 基于GaAs和inalgaas的聚光器型电池,用于转换光纤传输的能量
A. Fahrenbruch, L. Lopez-Otero, J.G. Werthern, Ta C. Wu
A novel application for high intensity GaAs-based solar cells is conversion of monochromatic light transmitted by fiber optics into electrical power for remote sensors. At present, the efficiencies of these devices are as high as 58%, and the systems can deliver 0.5 W electrical at distances of /spl ap/1 km. A typical OMCVD grown, six sector GaAs-based device, with an illuminated portion 0.15 cm in diameter, produces V/sub OC/=6.7 V, J/sub SC/=8.15 A/cm/sup 2/, and an efficiency of 55% under 820 nm illumination of 250 mW. Also reported are modeling and characterization of In/sub x/Al/sub y/Ga/sub 1-x-y/As devices for operation at 1320 nm, to examine the tradeoffs between increased fiber transmission, larger currents and lower voltages, relative to GaAs.
高强度gaas基太阳能电池的一种新应用是将光纤传输的单色光转换为远程传感器的电能。目前,这些设备的效率高达58%,系统可以在/spl /1公里的距离上提供0.5 W的电。典型的OMCVD生长的六扇区gaas器件,其照明部分直径为0.15 cm,在820 nm 250 mW的照明下产生V/sub OC/=6.7 V, J/sub SC/=8.15 A/cm/sup 2/,效率为55%。此外,还报道了用于1320nm工作的In/sub x/Al/sub y/Ga/sub 1-x-y/As器件的建模和表征,以研究相对于GaAs而言,增加光纤传输、更大电流和更低电压之间的权衡。
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引用次数: 28
Solar electric power for a better tomorrow 为了太阳能电力的美好明天
A. Barnett
The promise of solar electricity based on the photovoltaic (PV) effect is well known, but these systems are not common all over the world. Consumers in the USA are well-known for their attraction to new technology, but PV power systems are still not appearing on roof-tops in the US. The reason may be that grid-connected roof top systems are too difficult to acquire, too difficult to integrate with the grid, too difficult to measure the energy produced and too expensive. The author argues that it is essential that PV power systems are made user-friendly, while reducing the component and system costs. Elegant PV technology must be reduced to practical systems that can be used by the average person everywhere. Choosing the right problem will help achieve the promise of photovoltaics. This paper describes a methodology to choose the right problems as an approach to PV development. Solar cell and PV power system examples are presented.
基于光伏(PV)效应的太阳能发电的前景是众所周知的,但这些系统在世界各地并不常见。美国消费者对新技术的吸引力是出了名的,但光伏发电系统仍然没有出现在美国的屋顶上。原因可能是,与电网相连的屋顶系统太难获得,太难与电网整合,太难测量产生的能量,而且太昂贵。作者认为,在降低组件和系统成本的同时,光伏发电系统的用户友好性是至关重要的。优雅的光伏技术必须被简化为实用的系统,可以被普通人随处使用。选择正确的问题将有助于实现光伏的承诺。本文描述了一种选择正确问题作为光伏开发方法的方法。给出了太阳能电池和光伏发电系统的实例。
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引用次数: 15
Initial results for the silicon monolithically interconnected solar cell product 硅单片互连太阳能电池产品的初步结果
K. Shreve, L. C. Dinetta, J. Cotter, J. Bower, T. R. Ruffins, A. Barnett
This technology is based on AstroPower's electrostatic bonding and silicon solar cell processing techniques. Electrostatic bonding allows silicon wafers to be permanently attached to a thermally matched glass superstrate and processed to form the monolithically interconnected devices. These devices can be tailored for space and terrestrial applications. The costs of the monolithic interconnection compare favorably to labor intensive, conventionally strung solar cell arrays. Voltage and current outputs can be varied without varying the number of fabrication steps. Prototypes have demonstrated efficiencies greater than 11%. The monolithic approach has a number of inherent advantages for space and terrestrial photovoltaic products.
这项技术是基于AstroPower的静电键合和硅太阳能电池加工技术。静电键合允许硅片永久附着在热匹配的玻璃上,并加工形成单片互连器件。这些设备可以为空间和地面应用量身定制。单片互连的成本比劳动密集型,传统的串联太阳能电池阵列有利。电压和电流输出可以在不改变制造步骤数量的情况下变化。原型机的效率超过11%。单片方法对空间和地面光伏产品具有许多固有的优势。
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引用次数: 7
期刊
Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996
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