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Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996最新文献

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Elimination of parasitic effects in floating junction rear surface passivation for solar cells 太阳能电池浮结后表面钝化中寄生效应的消除
C. Honsberg, S. Ghozati, A. Ebong, Y. Tang, S. Wenham
Floating junction (FJ) passivation is a relatively recent passivation scheme which has both experimentally and theoretically demonstrated superior passivation than either oxide or back surface field passivation. In addition, it is suited not only to high efficiency laboratory cells, but also to commercial solar cells. The improvement in surface passivation for commercial cells is an especially critical issue in achieving lower cost solar cells through reducing substrate thickness while simultaneously increasing efficiency. Despite the many advantages of FJ passivation, its applicability has been limited by the apparent inability to translate the excellent modelling results into actual solar cells. The objective of this paper is to present a complete analysis of FJ passivation and to demonstrate a method by which the problems with FJ passivation can be eliminated. Experimental evidence as well as theoretical modelling demonstrates that a solar cell with an optimized rear FJ is insensitive to parasitic effects.
浮结(FJ)钝化是一种相对较新的钝化方案,从实验和理论上都证明了它比氧化物钝化或后表面场钝化有更好的钝化效果。此外,它不仅适用于高效率的实验室电池,也适用于商业太阳能电池。改善商业电池的表面钝化是通过减少衬底厚度同时提高效率来实现低成本太阳能电池的一个特别关键的问题。尽管FJ钝化有许多优点,但由于明显无法将出色的建模结果转化为实际的太阳能电池,其适用性受到限制。本文的目的是对FJ钝化进行完整的分析,并展示一种消除FJ钝化问题的方法。实验证据和理论模型表明,优化后FJ的太阳能电池对寄生效应不敏感。
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引用次数: 16
Record low surface recombination velocities on low-resistivity silicon solar cell substrates 在低电阻率硅太阳能电池衬底上记录低表面复合速度
Jan Schmidt, T. Lauinger, Armin G. Aberle, R. Hezel
In this paper, the lowest ever reported effective surface recombination velocities S/sub eff/ on typical p-type low-resistivity silicon solar cell substrates are presented. We obtain this surface passivation by means of remote plasma silicon nitride films fabricated at 375/spl deg/C. On polished as well as on chemically textured silicon surfaces, the applied low-temperature passivation scheme is significantly superior to high-temperature passivation by state-of-the-art thermal oxides. On polished 1.5-/spl Omega/cm p-Si wafers, an extremely low S/sub eff/ value of 4 cm/s is obtained. Because of the enormous potential of these plasma silicon nitride films as passivation medium for the rear surface of silicon solar cells, we also investigate silicon nitride-passivated, Al grid-covered p-Si surfaces as used by us in bifacial solar cells. On such samples we measure spatially averaged S/sub eff/ values as low as 135 cm/s.
本文报道了在典型p型低阻硅太阳电池衬底上的最低有效表面复合速度S/sub /。我们通过在375/spl℃下制备的远端等离子体氮化硅薄膜获得了这种表面钝化。在抛光和化学织构的硅表面上,低温钝化方案明显优于最先进的热氧化物高温钝化方案。在抛光1.5-/spl ω /cm p-Si晶片上,获得极低的S/sub /值为4 cm/ S。由于这些等离子体氮化硅薄膜作为硅太阳能电池后表面钝化介质的巨大潜力,我们还研究了氮化硅钝化,铝栅格覆盖的p-Si表面,我们在双面太阳能电池中使用。在这些样品上,我们测量的空间平均S/sub /值低至135 cm/ S。
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引用次数: 29
Estimating and controlling chromatic aberration losses for two-junction, two-terminal devices in refractive concentrator systems 折光聚光系统中双结双端器件色差损耗的估计与控制
S. Kurtz, M. O'neill
Although previous studies have measured and calculated solar cell chromatic aberration losses and proposed methods for reducing these by modifying the optics, significant work remains to be done toward understanding how to quantify the losses and how various parameters affect this loss. This paper presents an analytical definition and calculation method for chromatic aberration losses in Ga/sub 0.5/In/sub 0.5/P/GaAs solar cells. The effects of sheet resistance of the midlayers of the cell, total irradiance, incident spectrum, cell width and diode quality factor are studied. A method for measuring the midlayer resistance in finished solar cells is also described.
虽然以前的研究已经测量和计算了太阳能电池色差损失,并提出了通过修改光学来减少这些损失的方法,但在了解如何量化损失以及各种参数如何影响这种损失方面仍有重要的工作要做。本文给出了Ga/sub 0.5/ in /sub 0.5/P/GaAs太阳能电池色差损耗的解析定义和计算方法。研究了电池中间层的片电阻、总辐照度、入射光谱、电池宽度和二极管质量因子等因素的影响。本文还描述了一种测量成品太阳能电池中间层电阻的方法。
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引用次数: 49
Rapid thermal processing of conventionally and electromagnetically cast 100 cm/sup 2/ multicrystalline silicon 快速热加工常规和电磁铸造100厘米/sup 2/多晶硅
S. Sivoththaman, W. Laureys, P. de Schepper, J. Nijs, R. Mertens
100 cm/sup 2/ n/sup +/pp/sup +/ solar cells have been fabricated by rapid thermal processing (RTP) on conventionally cast (CC) and electromagnetically cast (EMC) multicrystalline silicon (mc-Si). All thermal steps were carried out by fast-ramp (>30/spl deg/C/s) RTP using tungsten-halogen lamps. Emitter and BSF were simultaneously formed by RTP co-diffusion of phosphorous and boron/or aluminum (50-60 seconds) and surface passivation by rapid thermal oxidation, RTO (40-50 seconds). The all-RTP process resulted in 14.1% and 13.3% efficient cells on CC and EMC mc-Si respectively. The EMC cells, when subjected to an additional plasma hydrogen treatment, improved to give the same efficiency as the CC mc-Si cells. Systematic lifetime measurements performed on these materials show that the degradation in the EMC mc-Si is mainly due to the activated crystallographic defects, responding favourably to hydrogenation treatments but poorly to RT-gettering treatments. On the other hand, significant gettering effects are observed in CC mc-Si.
在常规铸造(CC)多晶硅(mc-Si)和电磁铸造(EMC)多晶硅(mc-Si)上,采用快速热加工(RTP)技术制备了100 cm/sup 2/ n/sup +/pp/sup +/太阳能电池。所有热步骤均采用钨卤灯快速斜坡(>30/spl°/C/s) RTP进行。通过磷和硼/铝的RTP共扩散(50-60秒)和快速热氧化(RTO)表面钝化(40-50秒)同时形成发射极和BSF。全rtp工艺在CC和EMC mc-Si上的电池效率分别为14.1%和13.3%。当EMC电池经过额外的等离子氢处理后,其效率提高到与CC mc-Si电池相同。对这些材料进行的系统寿命测量表明,EMC mc-Si的降解主要是由于活化的晶体缺陷,对加氢处理反应良好,而对rt吸光处理反应较差。另一方面,在CC mc-Si中观察到明显的吸散效应。
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引用次数: 6
Environmental testing of chemically thinned, lightweight CuInSe/sub 2/ solar cells 化学减薄,轻质CuInSe/ sub2 /太阳能电池的环境测试
N. Kim, M.A. Vemvyvelt, M. Thompson, K. Coates
Environmental test results performed with chemically thinned, lightweight CuInSe/sub 2/ (CIS) space power solar cells are presented. CIS solar cells, which were fabricated by a chemical thinning process after CIS device structures had been formed on thick substrates, produced high efficiency devices. Pyroshock/random vibration, off-angle and thermal cycling tests were conducted with test conditions matching or exceeding the requirement for the PASP Plus space flight experiment. All phases of testing were monitored and produced favorable results. Electrical performance and physical inspection confirm its viability for space power applications. Environmental test procedures as well as the test results obtained are described in detail.
介绍了化学减薄的轻质CuInSe/sub 2/ (CIS)空间动力太阳能电池的环境试验结果。在厚衬底上形成CIS器件结构后,采用化学减薄工艺制备CIS太阳能电池,生产出高效率器件。在符合或超过PASP Plus航天飞行实验要求的条件下,进行了热冲击/随机振动、偏角和热循环试验。测试的所有阶段都得到了监控,并产生了良好的结果。电气性能和物理检查证实了其空间电源应用的可行性。详细介绍了环境试验程序和试验结果。
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引用次数: 1
The design, qualification and use of bypass diode integration onto GaAs/Ge solar cells 旁路二极管集成在GaAs/Ge太阳能电池上的设计、鉴定和应用
R. Dally, J.R. Kululka, J. Schwartz
Bypass diodes are integrated onto GaAs/Ge solar cells by selectively thinning a pocket into the backside of the solar cell's germanium substrate, electrically connecting the two devices via insulated metal foil tabs (Ag, Ag/Kovar or Ag/Mo) attached by thermal compression bonding (welding) and/or soldering and bonding the 3 mm thick silicon diode chip into the germanium pocket with a standard space qualified adhesive. This efficient and synergistic method of integration maintains the modularity of the solar cell unit, minimizes active area obscuration, heat sinks the diode and eliminates the need for discrete bypass diode wiring at the solar panel level. The approach is also applicable to future high efficiency, multijunction solar cells. Qualification status, performance results and manufacturing capabilities are discussed.
将旁通二极管集成到GaAs/Ge太阳能电池上,方法是在太阳能电池的锗衬底背面选择性地减薄一个口袋,通过热压缩键合(焊接)和/或用标准空间合格粘合剂将3毫米厚的硅二极管芯片焊接到锗口袋中,通过绝缘金属箔片(Ag, Ag/Kovar或Ag/Mo)将两个器件电连接起来。这种高效和协同的集成方法保持了太阳能电池单元的模块化,最大限度地减少了活动区域的遮挡,散热二极管,并消除了在太阳能电池板一级分立旁路二极管接线的需要。该方法也适用于未来的高效率、多结太阳能电池。讨论了资质状况、性能结果和制造能力。
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引用次数: 7
Factors limiting further improvement of a-SiGe:H 限制a-SiGe进一步改善的因素:H
T. Ikeda, G. Ganguly, A. Matsuda
The authors' results suggest that under conditions where the contribution of short lifetime radicals to growth has been minimized, the factors limiting further improvement of a-SiGe:H are (a) the low mobility of the Ge related precursor and (b) loss of surface hydrogen coverage due to rapid desorption from Ge-H sites. Therefore, preparing high quality a-SiGe:H requires high temperatures for increasing the precursor mobility and high deposition rates for reducing the effective hydrogen desorption rate.
作者的研究结果表明,在短寿命自由基对生长的贡献最小化的条件下,限制a- sige:H进一步改善的因素是(a) Ge相关前驱体的低迁移率和(b)由于Ge-H位点的快速解吸而导致表面氢覆盖的损失。因此,制备高质量的a-SiGe:H需要较高的温度来提高前驱体的迁移率,需要较高的沉积速率来降低有效的氢解吸率。
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引用次数: 0
Initial results for the silicon monolithically interconnected solar cell product 硅单片互连太阳能电池产品的初步结果
K. Shreve, L. C. Dinetta, J. Cotter, J. Bower, T. R. Ruffins, A. Barnett
This technology is based on AstroPower's electrostatic bonding and silicon solar cell processing techniques. Electrostatic bonding allows silicon wafers to be permanently attached to a thermally matched glass superstrate and processed to form the monolithically interconnected devices. These devices can be tailored for space and terrestrial applications. The costs of the monolithic interconnection compare favorably to labor intensive, conventionally strung solar cell arrays. Voltage and current outputs can be varied without varying the number of fabrication steps. Prototypes have demonstrated efficiencies greater than 11%. The monolithic approach has a number of inherent advantages for space and terrestrial photovoltaic products.
这项技术是基于AstroPower的静电键合和硅太阳能电池加工技术。静电键合允许硅片永久附着在热匹配的玻璃上,并加工形成单片互连器件。这些设备可以为空间和地面应用量身定制。单片互连的成本比劳动密集型,传统的串联太阳能电池阵列有利。电压和电流输出可以在不改变制造步骤数量的情况下变化。原型机的效率超过11%。单片方法对空间和地面光伏产品具有许多固有的优势。
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引用次数: 7
22.3% efficient silicon solar cell module 22.3%效率硅太阳能电池组件
J.-H. Zhao, A. Wang, E. Abbaspour-Sani, F. Yun, M. Green, D. King
This paper reports a recent result of 22.3% solar cell module efficiency independently confirmed at Sandia National Laboratories. This is the highest confirmed module efficiency for a module of this size achieved by solar cells made on any material. Modified double layer antireflection coated PERL (passivated emitter, rear locally-diffused) solar cells of 23% efficiency are used in this module. This double layer coating, together with the redesigned solar cell structure and a shingled encapsulation technique, considerably contributed to this efficiency improvement.
这篇论文报道了桑迪亚国家实验室独立证实的22.3%太阳能电池组件效率的最新结果。这是由任何材料制成的太阳能电池实现的这种尺寸的模块的最高确认模块效率。改进的双层抗反射涂层PERL(钝化发射极,后部局部扩散)太阳能电池的效率为23%。这种双层涂层,再加上重新设计的太阳能电池结构和瓦片封装技术,大大提高了效率。
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引用次数: 9
The SCARLET light concentrating solar array 猩红聚光太阳能阵列
D. Allen, P. Jones, D. Murphy, M. Piszczor
In recent years, spacecraft power levels have continued to grow, accelerating the evolution towards higher efficiency photovoltaic devices. Light concentrating arrays enable the cost-effective implementation of recently developed high-efficiency solar cells while providing high array efficiency, protection from space radiation effects and plasma interaction minimization for high voltage arrays. The line-focus concentrator concept delivers two added advantages: (1) low-cost mass production of the lens material; and (2) relaxation of precise array tracking requirements to only a single axis. New array designs emphasize lightweight, high stiffness, stow-ability, and ease of manufacture and assembly. In this paper, the authors address the current status of the SCARLET (solar concentrator array with refractive linear element technology) concentrator program with special emphasis on cost and mass performance trade-offs versus cell type and Sun tracking capability.
近年来,航天器功率水平持续增长,加速了向更高效率光伏器件的演变。光集中阵列使最近开发的高效太阳能电池具有成本效益,同时提供高阵列效率,保护空间辐射效应和最大限度地减少高压阵列的等离子体相互作用。线聚焦聚光器的概念提供了两个额外的优势:(1)低成本的透镜材料的批量生产;(2)将精确的阵列跟踪要求放宽到只有一个轴。新的阵列设计强调轻量化,高刚度,可装载性,易于制造和组装。在本文中,作者讨论了SCARLET(采用折光线性元件技术的太阳能聚光器阵列)聚光器计划的现状,特别强调了成本和质量性能与电池类型和太阳跟踪能力的权衡。
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引用次数: 56
期刊
Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996
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