首页 > 最新文献

Progress in Energy and Combustion Science最新文献

英文 中文
Norman Chigier (1933 – 2022) Norman Chigier(1933–2022)
IF 29.5 1区 工程技术 Q1 Chemical Engineering Pub Date : 2022-11-01 DOI: 10.1016/j.pecs.2022.101041
Hai Wang , Christof Schulz
{"title":"Norman Chigier (1933 – 2022)","authors":"Hai Wang , Christof Schulz","doi":"10.1016/j.pecs.2022.101041","DOIUrl":"https://doi.org/10.1016/j.pecs.2022.101041","url":null,"abstract":"","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":null,"pages":null},"PeriodicalIF":29.5,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"3137478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tire pyrolysis char: Processes, properties, upgrading and applications 轮胎热解炭:工艺、性能、改造及应用
IF 29.5 1区 工程技术 Q1 Chemical Engineering Pub Date : 2022-11-01 DOI: 10.1016/j.pecs.2022.101022
Ningbo Gao , Fengchao Wang , Cui Quan , Laura Santamaria , Gartzen Lopez , Paul T. Williams

Waste tires are solid wastes with large annual output and with the potential for great harm to the environment. The pyrolysis of waste tires can recycle energy and produce reusable products. Although there are many reviews in the literature in regard to the pyrolysis characteristics of waste tires, no one paper focuses on reviewing and summarizing the tire char. This paper critically appraises the achievements of earlier reports and literature and assesses the current state-of-the-art for the production and application of tire char from waste tires. Initially, the thermal decomposition behavior of different tire rubbers is discussed and compared where it is shown that the different components of waste tire rubber have different thermal degradation characteristics. The influencing factors on the yield and quality of tire char are discussed and assessed in terms of different pyrolysis reactors and technologies, tire type and composition, and a range of pyrolysis process conditions. The composition of the waste tire and pyrolysis conditions are the main factors affecting the distribution of pyrolysis products. Pyrolysis technology and reactor equipment also have an effect on the distribution of pyrolysis products. The physical and chemical structural characteristics of tire char are critically reviewed in detail, including a comparison of the fundamental differences with commercial carbon black and modified tire char (physical activation and chemical activation). Finally, high-value application fields and developmental prospects of tire char are summarized. Through extensive literature review, a novel development was that tire char could be used as a source of graphene. The economic analysis of the various tire char applications should be one of the main research directions in the future. The keynote of this review is to promote intensification of waste tire recycling and treatment so that more tire char can be obtained from waste tire pyrolysis and thereby be reused in different applications to obtain more value.

废旧轮胎是年产值较大的固体废物,对环境的潜在危害较大。废轮胎热解可以回收能源,生产可重复使用的产品。虽然文献中有很多关于废轮胎热解特性的综述,但没有一篇论文对轮胎炭进行综述和总结。本文批判性地评价了早期报告和文献的成就,并评估了当前从废轮胎中生产和应用轮胎炭的最新技术。首先,对不同轮胎橡胶的热分解行为进行了讨论和比较,表明不同成分的废轮胎橡胶具有不同的热降解特性。从不同的热解反应器和工艺、轮胎类型和成分、热解工艺条件等方面,对影响轮胎炭产率和质量的因素进行了探讨和评价。废轮胎的组成和热解条件是影响热解产物分布的主要因素。热解工艺和反应器设备对热解产物的分布也有影响。详细介绍了轮胎炭的物理和化学结构特征,包括与商业炭黑和改性轮胎炭(物理活化和化学活化)的根本区别的比较。最后,总结了轮胎炭的高价值应用领域和发展前景。通过大量的文献回顾,一个新的发展是轮胎炭可以作为石墨烯的来源。对各种轮胎炭应用的经济性分析应是今后的主要研究方向之一。本文综述的主旨是促进废轮胎回收和处理的集约化,以便从废轮胎热解中获得更多的轮胎炭,从而在不同的应用中重复利用,获得更多的价值。
{"title":"Tire pyrolysis char: Processes, properties, upgrading and applications","authors":"Ningbo Gao ,&nbsp;Fengchao Wang ,&nbsp;Cui Quan ,&nbsp;Laura Santamaria ,&nbsp;Gartzen Lopez ,&nbsp;Paul T. Williams","doi":"10.1016/j.pecs.2022.101022","DOIUrl":"https://doi.org/10.1016/j.pecs.2022.101022","url":null,"abstract":"<div><p>Waste tires are solid wastes with large annual output and with the potential for great harm to the environment. The pyrolysis of waste tires can recycle energy and produce reusable products. Although there are many reviews in the literature in regard to the pyrolysis characteristics of waste tires, no one paper focuses on reviewing and summarizing the tire char. This paper critically appraises the achievements of earlier reports and literature and assesses the current state-of-the-art for the production and application of tire char from waste tires. Initially, the thermal decomposition behavior of different tire rubbers is discussed and compared where it is shown that the different components of waste tire rubber have different thermal degradation characteristics. The influencing factors on the yield and quality of tire char are discussed and assessed in terms of different pyrolysis reactors and technologies, tire type and composition, and a range of pyrolysis process conditions. The composition of the waste tire and pyrolysis conditions are the main factors affecting the distribution of pyrolysis products. Pyrolysis technology and reactor equipment also have an effect on the distribution of pyrolysis products. The physical and chemical structural characteristics of tire char are critically reviewed in detail, including a comparison of the fundamental differences with commercial carbon black and modified tire char (physical activation and chemical activation). Finally, high-value application fields and developmental prospects of tire char are summarized. Through extensive literature review, a novel development was that tire char could be used as a source of graphene. The economic analysis of the various tire char applications should be one of the main research directions in the future. The keynote of this review is to promote intensification of waste tire recycling and treatment so that more tire char can be obtained from waste tire pyrolysis and thereby be reused in different applications to obtain more value.</p></div>","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":null,"pages":null},"PeriodicalIF":29.5,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1867848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 38
Metal single atom doped 2D materials for photocatalysis: current status and future perspectives 金属单原子掺杂二维光催化材料:现状与展望
IF 29.5 1区 工程技术 Q1 Chemical Engineering Pub Date : 2022-10-31 DOI: 10.1088/2516-1083/ac9eff
F. Wahid, Sajjad Ali, Pir Muhammad Ismail, F. Raziq, Sharafat Ali, Jiabao Yi, Liang Qiao
With the increase of energy crisis and greenhouse effect, the development of new photocatalytic systems with efficient solar-driven fuels/chemicals production is of great practical and scientific importance. In this scenario, single atom photocatalytic (SAP) systems are considered a significant breakthrough in the development of heterogeneous photocatalysis due to their superior catalytic efficiency, large surface area, and high atomic utilization. SAPs are consisting of isolated single atoms (SAs) distributed on/or coordinated with surface atoms of a suitable support. The anchoring of SAs on 2D substrates endows the developed SAPs with excellent properties, including high loading, uniform coordination, high light harvesting capability, and enhanced photocatalytic activities. Recently, many 2D substrates, including carbon materials, MXenes, and transition metal chalcogenides, have been used to anchor metal SAs for different photocatalytic applications. This review systematically discusses SAPs and the confining of metal SAs on 2D supports. Moreover, this review highlights the recent advances of SAPs for energy conversion, the existing challenges, and future perspectives. We expect that this review will offer some ideas for the future discovery of novel photocatalytic systems.
随着能源危机和温室效应的加剧,开发新型光催化系统以高效地生产太阳能燃料/化学品具有重要的现实意义和科学意义。在这种情况下,单原子光催化(SAP)系统由于其优越的催化效率、大表面积和高原子利用率而被认为是多相光催化发展的重大突破。sap是由孤立的单原子(SAs)组成的,它们分布在/或与合适载体的表面原子配位。将SAs锚定在二维基底上,使所开发的sap具有优异的性能,包括高负载、均匀配位、高光收集能力和光催化活性增强。最近,许多2D衬底,包括碳材料、MXenes和过渡金属硫族化合物,已被用于锚定金属sa,用于不同的光催化应用。本文系统地讨论了SAPs和金属SAs在二维支架上的限制。此外,本文还重点介绍了SAPs用于能量转换的最新进展、存在的挑战和未来的展望。我们希望本文的综述能够为未来发现新的光催化体系提供一些思路。
{"title":"Metal single atom doped 2D materials for photocatalysis: current status and future perspectives","authors":"F. Wahid, Sajjad Ali, Pir Muhammad Ismail, F. Raziq, Sharafat Ali, Jiabao Yi, Liang Qiao","doi":"10.1088/2516-1083/ac9eff","DOIUrl":"https://doi.org/10.1088/2516-1083/ac9eff","url":null,"abstract":"With the increase of energy crisis and greenhouse effect, the development of new photocatalytic systems with efficient solar-driven fuels/chemicals production is of great practical and scientific importance. In this scenario, single atom photocatalytic (SAP) systems are considered a significant breakthrough in the development of heterogeneous photocatalysis due to their superior catalytic efficiency, large surface area, and high atomic utilization. SAPs are consisting of isolated single atoms (SAs) distributed on/or coordinated with surface atoms of a suitable support. The anchoring of SAs on 2D substrates endows the developed SAPs with excellent properties, including high loading, uniform coordination, high light harvesting capability, and enhanced photocatalytic activities. Recently, many 2D substrates, including carbon materials, MXenes, and transition metal chalcogenides, have been used to anchor metal SAs for different photocatalytic applications. This review systematically discusses SAPs and the confining of metal SAs on 2D supports. Moreover, this review highlights the recent advances of SAPs for energy conversion, the existing challenges, and future perspectives. We expect that this review will offer some ideas for the future discovery of novel photocatalytic systems.","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":null,"pages":null},"PeriodicalIF":29.5,"publicationDate":"2022-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80303062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Outdoor luminescence imaging of field-deployed PV modules 野外部署光伏组件的室外发光成像
IF 29.5 1区 工程技术 Q1 Chemical Engineering Pub Date : 2022-10-13 DOI: 10.1088/2516-1083/ac9a33
O. Kunz, Jan Schlipf, Andreas Fladung, Y. S. Khoo, K. Bedrich, T. Trupke, Z. Hameiri
Solar photovoltaic (PV) installations have increased exponentially over the last decade and are now at a stage where they provide humanity with the greatest opportunity to mitigate accelerating climate change. For the continued growth and success of PV energy the reliable inspection of solar power plants is an important requirement. This ensures the installations are of high quality, safe to operate, and produce the maximum possible power for the longest possible plant life. Outdoor luminescence imaging of field-deployed PV modules provides module image data with unparalleled fidelity and is therefore the gold standard for assessing the quality, defect types, and degradation state of field-deployed PV modules. Several luminescence imaging methods have been developed and some of them are already routinely used to inspect solar power plants. The preferred luminescence inspection method to be used depends on the required image resolution, the defect types that need to be identified, cost, inspection throughput, technological readiness, and other factors. Due to the rich and detailed information provided by luminescence imaging measurements and modern image analysis methods, luminescence imaging is becoming an increasingly important tool for PV module quality assurance in PV power plants. Outdoor luminescence imaging can make valuable contributions to the commissioning, operation, and assessment of solar power plants prior to a change of ownership or after severe weather events. Another increasingly important use of these technologies is the cost-effective end-of-life assessment of solar modules to enable a sustainable circular economy.
太阳能光伏(PV)装置在过去十年中呈指数级增长,现在正处于为人类提供减缓加速的气候变化的最大机会的阶段。为了光伏能源的持续发展和成功,太阳能电站的可靠检测是一个重要的要求。这确保了设备的高质量,安全运行,并在尽可能长的工厂寿命内产生尽可能大的功率。现场部署的光伏组件的户外发光成像提供了无与伦比的保真度的模块图像数据,因此是评估现场部署的光伏组件的质量、缺陷类型和退化状态的金标准。已经开发了几种发光成像方法,其中一些已经常规用于检查太阳能发电厂。要使用的首选发光检测方法取决于所需的图像分辨率、需要识别的缺陷类型、成本、检测吞吐量、技术成熟度和其他因素。由于发光成像测量和现代图像分析方法提供了丰富而详细的信息,发光成像正在成为光伏电站光伏组件质量保证的越来越重要的工具。户外发光成像可以为太阳能发电厂的调试、运行和评估做出有价值的贡献,在改变所有权之前或在恶劣天气事件之后。这些技术的另一个日益重要的用途是对太阳能组件进行具有成本效益的寿命结束评估,以实现可持续的循环经济。
{"title":"Outdoor luminescence imaging of field-deployed PV modules","authors":"O. Kunz, Jan Schlipf, Andreas Fladung, Y. S. Khoo, K. Bedrich, T. Trupke, Z. Hameiri","doi":"10.1088/2516-1083/ac9a33","DOIUrl":"https://doi.org/10.1088/2516-1083/ac9a33","url":null,"abstract":"Solar photovoltaic (PV) installations have increased exponentially over the last decade and are now at a stage where they provide humanity with the greatest opportunity to mitigate accelerating climate change. For the continued growth and success of PV energy the reliable inspection of solar power plants is an important requirement. This ensures the installations are of high quality, safe to operate, and produce the maximum possible power for the longest possible plant life. Outdoor luminescence imaging of field-deployed PV modules provides module image data with unparalleled fidelity and is therefore the gold standard for assessing the quality, defect types, and degradation state of field-deployed PV modules. Several luminescence imaging methods have been developed and some of them are already routinely used to inspect solar power plants. The preferred luminescence inspection method to be used depends on the required image resolution, the defect types that need to be identified, cost, inspection throughput, technological readiness, and other factors. Due to the rich and detailed information provided by luminescence imaging measurements and modern image analysis methods, luminescence imaging is becoming an increasingly important tool for PV module quality assurance in PV power plants. Outdoor luminescence imaging can make valuable contributions to the commissioning, operation, and assessment of solar power plants prior to a change of ownership or after severe weather events. Another increasingly important use of these technologies is the cost-effective end-of-life assessment of solar modules to enable a sustainable circular economy.","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":null,"pages":null},"PeriodicalIF":29.5,"publicationDate":"2022-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83296958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Methods for the conversion of biomass waste into value-added carbon nanomaterials: Recent progress and applications 生物质废弃物转化为增值碳纳米材料的方法:最新进展及应用
IF 29.5 1区 工程技术 Q1 Chemical Engineering Pub Date : 2022-09-01 DOI: 10.1016/j.pecs.2022.101023
Santosh K. Tiwari , Michał Bystrzejewski , Amrita De Adhikari , Andrzej Huczko , Nannan Wang

Herein, we deliberate the recent progress and innovative modifications which were carried out during the last ten years as commonly employed methods for the conversion of biomass and related feedstocks into carbon nanosystems. Several highlighted methods are described in individual sections comprising: the type of nanomaterial processing, experimental conditions and factors affecting the yield and the characteristics of the final product. We have reconnoitred the applicability of specific feedstocks, advantages and drawbacks of the methods used for the conversion of biomass waste. A remarkable focus has been made to explore synthesis of graphene and graphene-like porous materials (with specific surface area greater than 1000 m2 g−1) which were derived from biomass. Their prospective applications dedicated to smart materials and cutting-edge technologies are also described in each section. To maintain the readability and cover the previous stimulating works on carbon nanomaterials derived from biomass, the first section of this review recaps the present status of carbon nanomaterials derived from biomass and related precursors, chiefly for the application in electrochemical devices, catalysis, sensing, absorbent along with an ample bibliography for further reading. We believe that vast scientific data in this state-of-the-art, simple explanations with schematic diagrams and key future challenges will provide a solid platform to readers about the update in carbon materials derived from biomass waste.

在此,我们讨论了在过去十年中作为将生物质和相关原料转化为碳纳米系统的常用方法所进行的最新进展和创新修改。在个别章节中描述了几种突出的方法,包括:纳米材料加工的类型,实验条件和影响产量的因素以及最终产品的特性。我们已经调查了特定原料的适用性,用于生物质废物转化的方法的优点和缺点。一个值得注意的重点是探索合成石墨烯和石墨烯类多孔材料(比表面积大于1000 m2 g−1),这些材料来源于生物质。它们在智能材料和尖端技术方面的潜在应用也在每个部分中进行了描述。为了保持可读性,并涵盖以往关于生物质衍生碳纳米材料的令人兴奋的工作,本综述的第一部分概述了生物质衍生碳纳米材料及其相关前体的现状,主要是在电化学器件,催化,传感,吸收剂方面的应用,并提供了充足的参考书目供进一步阅读。我们相信,在这个最先进的科学数据中,简单的原理图解释和未来的关键挑战将为读者提供一个坚实的平台,让他们了解来自生物质废物的碳材料的最新进展。
{"title":"Methods for the conversion of biomass waste into value-added carbon nanomaterials: Recent progress and applications","authors":"Santosh K. Tiwari ,&nbsp;Michał Bystrzejewski ,&nbsp;Amrita De Adhikari ,&nbsp;Andrzej Huczko ,&nbsp;Nannan Wang","doi":"10.1016/j.pecs.2022.101023","DOIUrl":"https://doi.org/10.1016/j.pecs.2022.101023","url":null,"abstract":"<div><p>Herein, we deliberate the recent progress and innovative modifications which were carried out during the last ten years as commonly employed methods for the conversion of biomass and related feedstocks into carbon nanosystems. Several highlighted methods are described in individual sections comprising: the type of nanomaterial processing, experimental conditions and factors affecting the yield and the characteristics of the final product. We have reconnoitred the applicability of specific feedstocks, advantages and drawbacks of the methods used for the conversion of biomass waste. A remarkable focus has been made to explore synthesis of graphene and graphene-like porous materials (with specific surface area greater than 1000 m<sup>2</sup> g<sup>−1</sup>) which were derived from biomass. Their prospective applications dedicated to smart materials and cutting-edge technologies are also described in each section. To maintain the readability and cover the previous stimulating works on carbon nanomaterials derived from biomass, the first section of this review recaps the present status of carbon nanomaterials derived from biomass and related precursors, chiefly for the application in electrochemical devices, catalysis, sensing, absorbent along with an ample bibliography for further reading. We believe that vast scientific data in this state-of-the-art, simple explanations with schematic diagrams and key future challenges will provide a solid platform to readers about the update in carbon materials derived from biomass waste.</p></div>","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":null,"pages":null},"PeriodicalIF":29.5,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1634641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 33
Chemical kinetics of cyclic ethers in combustion 循环醚在燃烧中的化学动力学
IF 29.5 1区 工程技术 Q1 Chemical Engineering Pub Date : 2022-09-01 DOI: 10.1016/j.pecs.2022.101019
Luc-Sy Tran , Olivier Herbinet , Hans-Heinrich Carstensen , Frédérique Battin-Leclerc

Cyclic Ethers (CEs) belong to a class of compounds of importance to understand the chemistry of both the engine auto-ignition of hydrocarbon fuels and the combustion of oxygenated biofuels. This article, divided in six parts, aims at systematically analyzing how up-to-date experimental and theoretical methods were applied to unveil the gas-phase oxidation chemistry of these compounds. The first part gives a brief overview on the significance of CEs as intermediates formed during alkane low-temperature oxidation summarizing its generally accepted chemical mechanism. This part also addresses the role of CEs as potential biofuels derived from lignocellulosic biomass and discusses the production methods of these molecules and their combustion performances in engine. The second part presents the different theoretical methods dedicated to calculate the electronic structure, thermochemical and kinetic data of CEs. The third part introduces the experimental methods used in studies related to CEs with a special focus on mass spectrometry and gas chromatography. The fourth part reviews the experimental and modeling studies related to CE formation during the low-temperature oxidation of linear, branched, cyclic alkanes, alkylbenzenes, olefins, and oxygenated fuels. The fifth part analyses the published work concerning the CE degradation chemistry and highlights the dominant involved reactions. To finish, the sixth part concludes and proposes future research directions.

环醚(CEs)是一类对了解碳氢燃料发动机自燃和含氧生物燃料燃烧的化学性质具有重要意义的化合物。本文分为六个部分,旨在系统地分析如何应用最新的实验和理论方法来揭示这些化合物的气相氧化化学。第一部分简要介绍了ce作为烷烃低温氧化过程中形成的中间体的意义,总结了其普遍接受的化学机理。本部分还讨论了从木质纤维素生物质中提取的ce作为潜在生物燃料的作用,并讨论了这些分子的生产方法及其在发动机中的燃烧性能。第二部分介绍了用于计算电子结构、热化学和动力学数据的不同理论方法。第三部分介绍了在研究中使用的实验方法,特别关注质谱和气相色谱法。第四部分综述了线性、支链、环烷烃、烷基苯、烯烃和含氧燃料在低温氧化过程中CE生成的实验和模型研究。第五部分对已发表的有关CE降解化学的研究进行了分析,重点介绍了主要涉及的反应。最后,第六部分对全文进行了总结,并提出了今后的研究方向。
{"title":"Chemical kinetics of cyclic ethers in combustion","authors":"Luc-Sy Tran ,&nbsp;Olivier Herbinet ,&nbsp;Hans-Heinrich Carstensen ,&nbsp;Frédérique Battin-Leclerc","doi":"10.1016/j.pecs.2022.101019","DOIUrl":"https://doi.org/10.1016/j.pecs.2022.101019","url":null,"abstract":"<div><p><span>Cyclic Ethers (CEs) belong to a class of compounds of importance to understand the chemistry of both the engine auto-ignition of hydrocarbon fuels and the combustion of oxygenated biofuels. This article, divided in six parts, aims at systematically analyzing how up-to-date experimental and theoretical methods were applied to unveil the gas-phase oxidation chemistry of these compounds</span><em>.</em><span><span> The first part gives a brief overview on the significance of CEs as intermediates formed during alkane low-temperature oxidation summarizing its generally accepted chemical mechanism. This part also addresses the role of CEs as potential biofuels derived from lignocellulosic biomass<span> and discusses the production methods of these molecules and their combustion performances in engine. The second part presents the different theoretical methods dedicated to calculate the electronic structure, thermochemical and kinetic data of CEs. The third part introduces the experimental methods used in studies related to CEs with a special focus on mass spectrometry and </span></span>gas chromatography<span>. The fourth part reviews the experimental and modeling studies related to CE formation during the low-temperature oxidation of linear, branched, cyclic alkanes, alkylbenzenes, olefins, and oxygenated fuels. The fifth part analyses the published work concerning the CE degradation chemistry and highlights the dominant involved reactions. To finish, the sixth part concludes and proposes future research directions.</span></span></p></div>","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":null,"pages":null},"PeriodicalIF":29.5,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1752267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Fundamentals of hydrogen storage in nanoporous materials 纳米多孔材料储氢的基本原理
IF 29.5 1区 工程技术 Q1 Chemical Engineering Pub Date : 2022-08-26 DOI: 10.1088/2516-1083/ac8d44
Linda Zhang, M. Allendorf, R. Balderas-Xicohténcatl, D. Broom, G. Fanourgakis, G. Froudakis, T. Gennett, K. Hurst, Sanliang Ling, C. Milanese, P. Parilla, D. Pontiroli, M. Riccò, S. Shulda, V. Stavila, T. Steriotis, C. J. Webb, M. Witman, M. Hirscher
Physisorption of hydrogen in nanoporous materials offers an efficient and competitive alternative for hydrogen storage. At low temperatures (e.g. 77 K) and moderate pressures (below 100 bar) molecular H2 adsorbs reversibly, with very fast kinetics, at high density on the inner surfaces of materials such as zeolites, activated carbons and metal–organic frameworks (MOFs). This review, by experts of Task 40 ‘Energy Storage and Conversion based on Hydrogen’ of the Hydrogen Technology Collaboration Programme of the International Energy Agency, covers the fundamentals of H2 adsorption in nanoporous materials and assessment of their storage performance. The discussion includes recent work on H2 adsorption at both low temperature and high pressure, new findings on the assessment of the hydrogen storage performance of materials, the correlation of volumetric and gravimetric H2 storage capacities, usable capacity, and optimum operating temperature. The application of neutron scattering as an ideal tool for characterising H2 adsorption is summarised and state-of-the-art computational methods, such as machine learning, are considered for the discovery of new MOFs for H2 storage applications, as well as the modelling of flexible porous networks for optimised H2 delivery. The discussion focuses moreover on additional important issues, such as sustainable materials synthesis and improved reproducibility of experimental H2 adsorption isotherm data by interlaboratory exercises and reference materials.
氢在纳米孔材料中的物理吸附为氢的储存提供了一种高效和有竞争力的替代方案。在低温(例如77 K)和中压(低于100 bar)下,分子H2以非常快的动力学以高密度在沸石、活性炭和金属有机框架(mof)等材料的内表面进行可逆吸附。本综述由国际能源署氢技术合作计划任务40“基于氢的储能和转换”的专家撰写,涵盖了纳米多孔材料中H2吸附的基本原理及其存储性能的评估。讨论包括低温和高压下氢气吸附的最新研究成果、材料储氢性能评估的新发现、体积和重量储氢容量、可用容量和最佳操作温度的相关性。总结了中子散射作为表征H2吸附的理想工具的应用,并考虑了最先进的计算方法,如机器学习,用于发现用于H2存储应用的新型mof,以及用于优化H2输送的柔性多孔网络的建模。讨论还集中在其他重要问题上,例如可持续材料合成和通过实验室间练习和参考材料提高H2吸附等温线实验数据的可重复性。
{"title":"Fundamentals of hydrogen storage in nanoporous materials","authors":"Linda Zhang, M. Allendorf, R. Balderas-Xicohténcatl, D. Broom, G. Fanourgakis, G. Froudakis, T. Gennett, K. Hurst, Sanliang Ling, C. Milanese, P. Parilla, D. Pontiroli, M. Riccò, S. Shulda, V. Stavila, T. Steriotis, C. J. Webb, M. Witman, M. Hirscher","doi":"10.1088/2516-1083/ac8d44","DOIUrl":"https://doi.org/10.1088/2516-1083/ac8d44","url":null,"abstract":"Physisorption of hydrogen in nanoporous materials offers an efficient and competitive alternative for hydrogen storage. At low temperatures (e.g. 77 K) and moderate pressures (below 100 bar) molecular H2 adsorbs reversibly, with very fast kinetics, at high density on the inner surfaces of materials such as zeolites, activated carbons and metal–organic frameworks (MOFs). This review, by experts of Task 40 ‘Energy Storage and Conversion based on Hydrogen’ of the Hydrogen Technology Collaboration Programme of the International Energy Agency, covers the fundamentals of H2 adsorption in nanoporous materials and assessment of their storage performance. The discussion includes recent work on H2 adsorption at both low temperature and high pressure, new findings on the assessment of the hydrogen storage performance of materials, the correlation of volumetric and gravimetric H2 storage capacities, usable capacity, and optimum operating temperature. The application of neutron scattering as an ideal tool for characterising H2 adsorption is summarised and state-of-the-art computational methods, such as machine learning, are considered for the discovery of new MOFs for H2 storage applications, as well as the modelling of flexible porous networks for optimised H2 delivery. The discussion focuses moreover on additional important issues, such as sustainable materials synthesis and improved reproducibility of experimental H2 adsorption isotherm data by interlaboratory exercises and reference materials.","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":null,"pages":null},"PeriodicalIF":29.5,"publicationDate":"2022-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73314824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Complexities in the energy-transport co-transformation 能源运输共转化的复杂性
IF 29.5 1区 工程技术 Q1 Chemical Engineering Pub Date : 2022-08-25 DOI: 10.1088/2516-1083/ac88b1
David Daniels, S. Yeh
Managing the transformation to a global low-carbon energy sector is challenging. Long-lived assets, large capital projects, and long lead times require multi-decadal transition plans. Of course, the end state of the energy system depends on the evolution of demands from energy-consuming sectors. This can perhaps best be illustrated in the changing relationship between energy supply and transportation energy demand. As the transport sector substitutes low-carbon fuels, including electricity, for fossil fuels, the locations of energy production and distribution supply chains are likely to shift. With different production processes for these fuels and different efficiencies of the vehicles that consume them, the energy intensity of transport is going to be different. Moreover, as transport begins to rely more on direct electrification, the temporal coupling of energy supply and transportation demand will tighten dramatically. While this coupling will provide some opportunities, such as vehicle-to-grid services, it will also present challenges to existing markets and traditional grid management strategies. Thus, effective management of the global energy transition requires a sensitivity to the simultaneous co-transformation in transportation. The papers in this collection illustrate the breadth of impacts on the energy sector from different ways the transport sector could plausibly evolve in a low-carbon future. Exactly how the transportation transformation will unfold remains to be seen, and it may evolve differently, and over different timelines, in different regions. Nevertheless, despite the
管理向全球低碳能源部门的转型具有挑战性。长期资产、大型资本项目和较长的交付周期需要几十年的过渡计划。当然,能源系统的最终状态取决于能源消费部门需求的演变。能源供应和运输能源需求之间不断变化的关系也许最能说明这一点。随着交通运输部门用包括电力在内的低碳燃料取代化石燃料,能源生产和分销供应链的位置可能会发生变化。由于这些燃料的生产过程不同,使用它们的车辆的效率也不同,交通运输的能源强度也会有所不同。此外,随着交通运输开始更多地依赖于直接电气化,能源供应和交通运输需求的时间耦合将急剧收紧。虽然这种耦合将提供一些机会,例如车辆到电网服务,但它也将对现有市场和传统电网管理策略提出挑战。因此,对全球能源转型的有效管理需要对交通运输的同步共同转型具有敏感性。本文集中的论文阐述了交通运输部门在低碳未来发展的不同方式对能源部门的广泛影响。交通运输转型究竟会如何展开还有待观察,它可能会在不同的时间线、不同的地区以不同的方式发展。然而,尽管
{"title":"Complexities in the energy-transport co-transformation","authors":"David Daniels, S. Yeh","doi":"10.1088/2516-1083/ac88b1","DOIUrl":"https://doi.org/10.1088/2516-1083/ac88b1","url":null,"abstract":"Managing the transformation to a global low-carbon energy sector is challenging. Long-lived assets, large capital projects, and long lead times require multi-decadal transition plans. Of course, the end state of the energy system depends on the evolution of demands from energy-consuming sectors. This can perhaps best be illustrated in the changing relationship between energy supply and transportation energy demand. As the transport sector substitutes low-carbon fuels, including electricity, for fossil fuels, the locations of energy production and distribution supply chains are likely to shift. With different production processes for these fuels and different efficiencies of the vehicles that consume them, the energy intensity of transport is going to be different. Moreover, as transport begins to rely more on direct electrification, the temporal coupling of energy supply and transportation demand will tighten dramatically. While this coupling will provide some opportunities, such as vehicle-to-grid services, it will also present challenges to existing markets and traditional grid management strategies. Thus, effective management of the global energy transition requires a sensitivity to the simultaneous co-transformation in transportation. The papers in this collection illustrate the breadth of impacts on the energy sector from different ways the transport sector could plausibly evolve in a low-carbon future. Exactly how the transportation transformation will unfold remains to be seen, and it may evolve differently, and over different timelines, in different regions. Nevertheless, despite the","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":null,"pages":null},"PeriodicalIF":29.5,"publicationDate":"2022-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90449166","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Non-destructive examination (NDE) methods for dynamic subsea cables for offshore renewable energy 海上可再生能源动力海底电缆的无损检测方法
IF 29.5 1区 工程技术 Q1 Chemical Engineering Pub Date : 2022-08-25 DOI: 10.1088/2516-1083/ac8ccb
R. Nicholls-Lee, P. Thies, J. Dulieu‐Barton, G. Ólafsson, Rolf Hughes, A. Hernandez Arroyo, G. Xu, N. Cartlidge
Offshore renewable energy installations are moving into more challenging environments where fixed foundations are not economically viable, forcing the development of floating platforms. Subsea cables are critical for transfer of the power generated back to shore. The electrical capabilities of subsea cables are well understood; however, the structural capabilities are not, subsea power cable failures accounting for a significant proportion of insurance claims. Cables are challenging to repair, with specific vessels and good weather windows required, therefore making operations very costly. A good understanding of the internal structure of a subsea cable, and interaction between the layers, is integral to the development of robust and reliable, high voltage, dynamic, subsea cables. A requirement therefore exists for non-destructive examination (NDE) of live subsea cables to determine locations, and identify the causes, of faults and classify their type. An NDE framework such as this would assist in planning operations and reduce the risk and cost inherent to delivering offshore power. Improved understanding of subsea cable failure modes and mechanisms could also be achieved through us of NDE during onshore, dry, experimental testing. Three currently available NDE methods are considered, developed for use in other disciplines, for the purpose of structural monitoring of subsea power cables during onshore evaluation testing. The NDE methods were: (a) thermography, (b) eddy current testing (ECT), (c) spread spectrum time domain reflectometry (SSTDR). The methods are assessed with regards to the information that could be obtained from both a static and oscillating cable in pilot physical tests. The results of the testing were promising, with cable motions and interlayer movements being detected by all techniques to various degrees.
海上可再生能源设施正进入更具挑战性的环境,在这些环境中,固定基础在经济上不可行,迫使浮式平台的发展。海底电缆对于将产生的电力传输回岸上至关重要。海底电缆的电气性能已经得到了很好的了解;然而,结构能力却不是,海底电力电缆故障占保险索赔的很大比例。电缆的修复具有挑战性,需要特定的船只和良好的天气窗口,因此作业成本非常高。了解海底电缆的内部结构以及各层之间的相互作用,对于开发坚固可靠、高电压、动态的海底电缆至关重要。因此,需要对海底电缆进行无损检测(NDE),以确定故障位置、确定故障原因并对故障类型进行分类。这样的NDE框架将有助于规划运营,降低海上电力输送的风险和成本。通过在陆上、干式和实验测试中使用NDE技术,可以更好地了解海底电缆的失效模式和机制。本文考虑了三种目前可用的无损检测方法,它们被开发用于其他学科,用于陆上评估测试期间海底电力电缆的结构监测。无损检测方法有:(a)热像仪,(b)涡流检测(ECT), (c)扩频时域反射(SSTDR)。根据在试验物理试验中从静态和振荡电缆中获得的信息,对这些方法进行了评估。测试结果令人鼓舞,所有技术都能在不同程度上检测到电缆运动和层间运动。
{"title":"Non-destructive examination (NDE) methods for dynamic subsea cables for offshore renewable energy","authors":"R. Nicholls-Lee, P. Thies, J. Dulieu‐Barton, G. Ólafsson, Rolf Hughes, A. Hernandez Arroyo, G. Xu, N. Cartlidge","doi":"10.1088/2516-1083/ac8ccb","DOIUrl":"https://doi.org/10.1088/2516-1083/ac8ccb","url":null,"abstract":"Offshore renewable energy installations are moving into more challenging environments where fixed foundations are not economically viable, forcing the development of floating platforms. Subsea cables are critical for transfer of the power generated back to shore. The electrical capabilities of subsea cables are well understood; however, the structural capabilities are not, subsea power cable failures accounting for a significant proportion of insurance claims. Cables are challenging to repair, with specific vessels and good weather windows required, therefore making operations very costly. A good understanding of the internal structure of a subsea cable, and interaction between the layers, is integral to the development of robust and reliable, high voltage, dynamic, subsea cables. A requirement therefore exists for non-destructive examination (NDE) of live subsea cables to determine locations, and identify the causes, of faults and classify their type. An NDE framework such as this would assist in planning operations and reduce the risk and cost inherent to delivering offshore power. Improved understanding of subsea cable failure modes and mechanisms could also be achieved through us of NDE during onshore, dry, experimental testing. Three currently available NDE methods are considered, developed for use in other disciplines, for the purpose of structural monitoring of subsea power cables during onshore evaluation testing. The NDE methods were: (a) thermography, (b) eddy current testing (ECT), (c) spread spectrum time domain reflectometry (SSTDR). The methods are assessed with regards to the information that could be obtained from both a static and oscillating cable in pilot physical tests. The results of the testing were promising, with cable motions and interlayer movements being detected by all techniques to various degrees.","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":null,"pages":null},"PeriodicalIF":29.5,"publicationDate":"2022-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81517213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
UK perspective research landscape for offshore renewable energy and its role in delivering Net Zero 英国海上可再生能源的研究前景及其在实现净零排放中的作用
IF 29.5 1区 工程技术 Q1 Chemical Engineering Pub Date : 2022-08-23 DOI: 10.1088/2516-1083/ac8c19
D. Greaves, S. Jin, P. Wong, David White, H. Jeffrey, B. Scott, Ross Wigg
This paper sets out the role of offshore renewable energy (ORE) in UK targets for Net Zero greenhouse gas emissions by 2050 and provides a review of the research challenges that face the sector as it grows to meet these targets. The research challenges are set out in a Research Landscape that was established by the ORE Supergen Hub following extensive consultation with the ORE community. The challenges are divided into eight themes, each challenge is described, and current progress is summarised. The progress of the ORE sector in recent years has seen huge cost reductions, which have encouraged the great ambition for the sector seen in UK Government targets. However, in order to meet these critical targets and achieve Net Zero, further innovations and novel technologies will be needed and at pace, driven forward by new research and innovation. The strategy of the Supergen ORE Hub in framing the research and innovation activities within a community-developed research landscape and working together across disciplines and with close collaboration between academia and industry is a necessary component in achieving the ambition of sustainable energy generation.
本文阐述了海上可再生能源(ORE)在英国2050年净零温室气体排放目标中的作用,并回顾了该行业在实现这些目标的过程中所面临的研究挑战。在与ORE社区广泛协商后,ORE Supergen Hub建立了一个研究景观,其中列出了研究挑战。挑战分为八个主题,对每个挑战进行了描述,并总结了当前的进展。近年来,矿石行业的进步已经看到了巨大的成本降低,这鼓励了英国政府对该行业的雄心壮志。然而,为了达到这些关键目标并实现净零排放,将需要进一步的创新和新技术,并在新的研究和创新的推动下向前发展。Supergen ORE Hub的战略是在社区发展的研究环境中制定研究和创新活动,并在学术界和工业界之间开展跨学科合作和密切合作,这是实现可持续能源生产雄心的必要组成部分。
{"title":"UK perspective research landscape for offshore renewable energy and its role in delivering Net Zero","authors":"D. Greaves, S. Jin, P. Wong, David White, H. Jeffrey, B. Scott, Ross Wigg","doi":"10.1088/2516-1083/ac8c19","DOIUrl":"https://doi.org/10.1088/2516-1083/ac8c19","url":null,"abstract":"This paper sets out the role of offshore renewable energy (ORE) in UK targets for Net Zero greenhouse gas emissions by 2050 and provides a review of the research challenges that face the sector as it grows to meet these targets. The research challenges are set out in a Research Landscape that was established by the ORE Supergen Hub following extensive consultation with the ORE community. The challenges are divided into eight themes, each challenge is described, and current progress is summarised. The progress of the ORE sector in recent years has seen huge cost reductions, which have encouraged the great ambition for the sector seen in UK Government targets. However, in order to meet these critical targets and achieve Net Zero, further innovations and novel technologies will be needed and at pace, driven forward by new research and innovation. The strategy of the Supergen ORE Hub in framing the research and innovation activities within a community-developed research landscape and working together across disciplines and with close collaboration between academia and industry is a necessary component in achieving the ambition of sustainable energy generation.","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":null,"pages":null},"PeriodicalIF":29.5,"publicationDate":"2022-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77880693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
期刊
Progress in Energy and Combustion Science
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1