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Methods for the conversion of biomass waste into value-added carbon nanomaterials: Recent progress and applications 生物质废弃物转化为增值碳纳米材料的方法:最新进展及应用
IF 29.5 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2022-09-01 DOI: 10.1016/j.pecs.2022.101023
Santosh K. Tiwari , Michał Bystrzejewski , Amrita De Adhikari , Andrzej Huczko , Nannan Wang

Herein, we deliberate the recent progress and innovative modifications which were carried out during the last ten years as commonly employed methods for the conversion of biomass and related feedstocks into carbon nanosystems. Several highlighted methods are described in individual sections comprising: the type of nanomaterial processing, experimental conditions and factors affecting the yield and the characteristics of the final product. We have reconnoitred the applicability of specific feedstocks, advantages and drawbacks of the methods used for the conversion of biomass waste. A remarkable focus has been made to explore synthesis of graphene and graphene-like porous materials (with specific surface area greater than 1000 m2 g−1) which were derived from biomass. Their prospective applications dedicated to smart materials and cutting-edge technologies are also described in each section. To maintain the readability and cover the previous stimulating works on carbon nanomaterials derived from biomass, the first section of this review recaps the present status of carbon nanomaterials derived from biomass and related precursors, chiefly for the application in electrochemical devices, catalysis, sensing, absorbent along with an ample bibliography for further reading. We believe that vast scientific data in this state-of-the-art, simple explanations with schematic diagrams and key future challenges will provide a solid platform to readers about the update in carbon materials derived from biomass waste.

在此,我们讨论了在过去十年中作为将生物质和相关原料转化为碳纳米系统的常用方法所进行的最新进展和创新修改。在个别章节中描述了几种突出的方法,包括:纳米材料加工的类型,实验条件和影响产量的因素以及最终产品的特性。我们已经调查了特定原料的适用性,用于生物质废物转化的方法的优点和缺点。一个值得注意的重点是探索合成石墨烯和石墨烯类多孔材料(比表面积大于1000 m2 g−1),这些材料来源于生物质。它们在智能材料和尖端技术方面的潜在应用也在每个部分中进行了描述。为了保持可读性,并涵盖以往关于生物质衍生碳纳米材料的令人兴奋的工作,本综述的第一部分概述了生物质衍生碳纳米材料及其相关前体的现状,主要是在电化学器件,催化,传感,吸收剂方面的应用,并提供了充足的参考书目供进一步阅读。我们相信,在这个最先进的科学数据中,简单的原理图解释和未来的关键挑战将为读者提供一个坚实的平台,让他们了解来自生物质废物的碳材料的最新进展。
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引用次数: 33
Chemical kinetics of cyclic ethers in combustion 循环醚在燃烧中的化学动力学
IF 29.5 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2022-09-01 DOI: 10.1016/j.pecs.2022.101019
Luc-Sy Tran , Olivier Herbinet , Hans-Heinrich Carstensen , Frédérique Battin-Leclerc

Cyclic Ethers (CEs) belong to a class of compounds of importance to understand the chemistry of both the engine auto-ignition of hydrocarbon fuels and the combustion of oxygenated biofuels. This article, divided in six parts, aims at systematically analyzing how up-to-date experimental and theoretical methods were applied to unveil the gas-phase oxidation chemistry of these compounds. The first part gives a brief overview on the significance of CEs as intermediates formed during alkane low-temperature oxidation summarizing its generally accepted chemical mechanism. This part also addresses the role of CEs as potential biofuels derived from lignocellulosic biomass and discusses the production methods of these molecules and their combustion performances in engine. The second part presents the different theoretical methods dedicated to calculate the electronic structure, thermochemical and kinetic data of CEs. The third part introduces the experimental methods used in studies related to CEs with a special focus on mass spectrometry and gas chromatography. The fourth part reviews the experimental and modeling studies related to CE formation during the low-temperature oxidation of linear, branched, cyclic alkanes, alkylbenzenes, olefins, and oxygenated fuels. The fifth part analyses the published work concerning the CE degradation chemistry and highlights the dominant involved reactions. To finish, the sixth part concludes and proposes future research directions.

环醚(CEs)是一类对了解碳氢燃料发动机自燃和含氧生物燃料燃烧的化学性质具有重要意义的化合物。本文分为六个部分,旨在系统地分析如何应用最新的实验和理论方法来揭示这些化合物的气相氧化化学。第一部分简要介绍了ce作为烷烃低温氧化过程中形成的中间体的意义,总结了其普遍接受的化学机理。本部分还讨论了从木质纤维素生物质中提取的ce作为潜在生物燃料的作用,并讨论了这些分子的生产方法及其在发动机中的燃烧性能。第二部分介绍了用于计算电子结构、热化学和动力学数据的不同理论方法。第三部分介绍了在研究中使用的实验方法,特别关注质谱和气相色谱法。第四部分综述了线性、支链、环烷烃、烷基苯、烯烃和含氧燃料在低温氧化过程中CE生成的实验和模型研究。第五部分对已发表的有关CE降解化学的研究进行了分析,重点介绍了主要涉及的反应。最后,第六部分对全文进行了总结,并提出了今后的研究方向。
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引用次数: 12
Fundamentals of hydrogen storage in nanoporous materials 纳米多孔材料储氢的基本原理
IF 29.5 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2022-08-26 DOI: 10.1088/2516-1083/ac8d44
Linda Zhang, M. Allendorf, R. Balderas-Xicohténcatl, D. Broom, G. Fanourgakis, G. Froudakis, T. Gennett, K. Hurst, Sanliang Ling, C. Milanese, P. Parilla, D. Pontiroli, M. Riccò, S. Shulda, V. Stavila, T. Steriotis, C. J. Webb, M. Witman, M. Hirscher
Physisorption of hydrogen in nanoporous materials offers an efficient and competitive alternative for hydrogen storage. At low temperatures (e.g. 77 K) and moderate pressures (below 100 bar) molecular H2 adsorbs reversibly, with very fast kinetics, at high density on the inner surfaces of materials such as zeolites, activated carbons and metal–organic frameworks (MOFs). This review, by experts of Task 40 ‘Energy Storage and Conversion based on Hydrogen’ of the Hydrogen Technology Collaboration Programme of the International Energy Agency, covers the fundamentals of H2 adsorption in nanoporous materials and assessment of their storage performance. The discussion includes recent work on H2 adsorption at both low temperature and high pressure, new findings on the assessment of the hydrogen storage performance of materials, the correlation of volumetric and gravimetric H2 storage capacities, usable capacity, and optimum operating temperature. The application of neutron scattering as an ideal tool for characterising H2 adsorption is summarised and state-of-the-art computational methods, such as machine learning, are considered for the discovery of new MOFs for H2 storage applications, as well as the modelling of flexible porous networks for optimised H2 delivery. The discussion focuses moreover on additional important issues, such as sustainable materials synthesis and improved reproducibility of experimental H2 adsorption isotherm data by interlaboratory exercises and reference materials.
氢在纳米孔材料中的物理吸附为氢的储存提供了一种高效和有竞争力的替代方案。在低温(例如77 K)和中压(低于100 bar)下,分子H2以非常快的动力学以高密度在沸石、活性炭和金属有机框架(mof)等材料的内表面进行可逆吸附。本综述由国际能源署氢技术合作计划任务40“基于氢的储能和转换”的专家撰写,涵盖了纳米多孔材料中H2吸附的基本原理及其存储性能的评估。讨论包括低温和高压下氢气吸附的最新研究成果、材料储氢性能评估的新发现、体积和重量储氢容量、可用容量和最佳操作温度的相关性。总结了中子散射作为表征H2吸附的理想工具的应用,并考虑了最先进的计算方法,如机器学习,用于发现用于H2存储应用的新型mof,以及用于优化H2输送的柔性多孔网络的建模。讨论还集中在其他重要问题上,例如可持续材料合成和通过实验室间练习和参考材料提高H2吸附等温线实验数据的可重复性。
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引用次数: 9
Complexities in the energy-transport co-transformation 能源运输共转化的复杂性
IF 29.5 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2022-08-25 DOI: 10.1088/2516-1083/ac88b1
David Daniels, S. Yeh
Managing the transformation to a global low-carbon energy sector is challenging. Long-lived assets, large capital projects, and long lead times require multi-decadal transition plans. Of course, the end state of the energy system depends on the evolution of demands from energy-consuming sectors. This can perhaps best be illustrated in the changing relationship between energy supply and transportation energy demand. As the transport sector substitutes low-carbon fuels, including electricity, for fossil fuels, the locations of energy production and distribution supply chains are likely to shift. With different production processes for these fuels and different efficiencies of the vehicles that consume them, the energy intensity of transport is going to be different. Moreover, as transport begins to rely more on direct electrification, the temporal coupling of energy supply and transportation demand will tighten dramatically. While this coupling will provide some opportunities, such as vehicle-to-grid services, it will also present challenges to existing markets and traditional grid management strategies. Thus, effective management of the global energy transition requires a sensitivity to the simultaneous co-transformation in transportation. The papers in this collection illustrate the breadth of impacts on the energy sector from different ways the transport sector could plausibly evolve in a low-carbon future. Exactly how the transportation transformation will unfold remains to be seen, and it may evolve differently, and over different timelines, in different regions. Nevertheless, despite the
管理向全球低碳能源部门的转型具有挑战性。长期资产、大型资本项目和较长的交付周期需要几十年的过渡计划。当然,能源系统的最终状态取决于能源消费部门需求的演变。能源供应和运输能源需求之间不断变化的关系也许最能说明这一点。随着交通运输部门用包括电力在内的低碳燃料取代化石燃料,能源生产和分销供应链的位置可能会发生变化。由于这些燃料的生产过程不同,使用它们的车辆的效率也不同,交通运输的能源强度也会有所不同。此外,随着交通运输开始更多地依赖于直接电气化,能源供应和交通运输需求的时间耦合将急剧收紧。虽然这种耦合将提供一些机会,例如车辆到电网服务,但它也将对现有市场和传统电网管理策略提出挑战。因此,对全球能源转型的有效管理需要对交通运输的同步共同转型具有敏感性。本文集中的论文阐述了交通运输部门在低碳未来发展的不同方式对能源部门的广泛影响。交通运输转型究竟会如何展开还有待观察,它可能会在不同的时间线、不同的地区以不同的方式发展。然而,尽管
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引用次数: 1
Non-destructive examination (NDE) methods for dynamic subsea cables for offshore renewable energy 海上可再生能源动力海底电缆的无损检测方法
IF 29.5 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2022-08-25 DOI: 10.1088/2516-1083/ac8ccb
R. Nicholls-Lee, P. Thies, J. Dulieu‐Barton, G. Ólafsson, Rolf Hughes, A. Hernandez Arroyo, G. Xu, N. Cartlidge
Offshore renewable energy installations are moving into more challenging environments where fixed foundations are not economically viable, forcing the development of floating platforms. Subsea cables are critical for transfer of the power generated back to shore. The electrical capabilities of subsea cables are well understood; however, the structural capabilities are not, subsea power cable failures accounting for a significant proportion of insurance claims. Cables are challenging to repair, with specific vessels and good weather windows required, therefore making operations very costly. A good understanding of the internal structure of a subsea cable, and interaction between the layers, is integral to the development of robust and reliable, high voltage, dynamic, subsea cables. A requirement therefore exists for non-destructive examination (NDE) of live subsea cables to determine locations, and identify the causes, of faults and classify their type. An NDE framework such as this would assist in planning operations and reduce the risk and cost inherent to delivering offshore power. Improved understanding of subsea cable failure modes and mechanisms could also be achieved through us of NDE during onshore, dry, experimental testing. Three currently available NDE methods are considered, developed for use in other disciplines, for the purpose of structural monitoring of subsea power cables during onshore evaluation testing. The NDE methods were: (a) thermography, (b) eddy current testing (ECT), (c) spread spectrum time domain reflectometry (SSTDR). The methods are assessed with regards to the information that could be obtained from both a static and oscillating cable in pilot physical tests. The results of the testing were promising, with cable motions and interlayer movements being detected by all techniques to various degrees.
海上可再生能源设施正进入更具挑战性的环境,在这些环境中,固定基础在经济上不可行,迫使浮式平台的发展。海底电缆对于将产生的电力传输回岸上至关重要。海底电缆的电气性能已经得到了很好的了解;然而,结构能力却不是,海底电力电缆故障占保险索赔的很大比例。电缆的修复具有挑战性,需要特定的船只和良好的天气窗口,因此作业成本非常高。了解海底电缆的内部结构以及各层之间的相互作用,对于开发坚固可靠、高电压、动态的海底电缆至关重要。因此,需要对海底电缆进行无损检测(NDE),以确定故障位置、确定故障原因并对故障类型进行分类。这样的NDE框架将有助于规划运营,降低海上电力输送的风险和成本。通过在陆上、干式和实验测试中使用NDE技术,可以更好地了解海底电缆的失效模式和机制。本文考虑了三种目前可用的无损检测方法,它们被开发用于其他学科,用于陆上评估测试期间海底电力电缆的结构监测。无损检测方法有:(a)热像仪,(b)涡流检测(ECT), (c)扩频时域反射(SSTDR)。根据在试验物理试验中从静态和振荡电缆中获得的信息,对这些方法进行了评估。测试结果令人鼓舞,所有技术都能在不同程度上检测到电缆运动和层间运动。
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引用次数: 1
UK perspective research landscape for offshore renewable energy and its role in delivering Net Zero 英国海上可再生能源的研究前景及其在实现净零排放中的作用
IF 29.5 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2022-08-23 DOI: 10.1088/2516-1083/ac8c19
D. Greaves, S. Jin, P. Wong, David White, H. Jeffrey, B. Scott, Ross Wigg
This paper sets out the role of offshore renewable energy (ORE) in UK targets for Net Zero greenhouse gas emissions by 2050 and provides a review of the research challenges that face the sector as it grows to meet these targets. The research challenges are set out in a Research Landscape that was established by the ORE Supergen Hub following extensive consultation with the ORE community. The challenges are divided into eight themes, each challenge is described, and current progress is summarised. The progress of the ORE sector in recent years has seen huge cost reductions, which have encouraged the great ambition for the sector seen in UK Government targets. However, in order to meet these critical targets and achieve Net Zero, further innovations and novel technologies will be needed and at pace, driven forward by new research and innovation. The strategy of the Supergen ORE Hub in framing the research and innovation activities within a community-developed research landscape and working together across disciplines and with close collaboration between academia and industry is a necessary component in achieving the ambition of sustainable energy generation.
本文阐述了海上可再生能源(ORE)在英国2050年净零温室气体排放目标中的作用,并回顾了该行业在实现这些目标的过程中所面临的研究挑战。在与ORE社区广泛协商后,ORE Supergen Hub建立了一个研究景观,其中列出了研究挑战。挑战分为八个主题,对每个挑战进行了描述,并总结了当前的进展。近年来,矿石行业的进步已经看到了巨大的成本降低,这鼓励了英国政府对该行业的雄心壮志。然而,为了达到这些关键目标并实现净零排放,将需要进一步的创新和新技术,并在新的研究和创新的推动下向前发展。Supergen ORE Hub的战略是在社区发展的研究环境中制定研究和创新活动,并在学术界和工业界之间开展跨学科合作和密切合作,这是实现可持续能源生产雄心的必要组成部分。
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引用次数: 2
Accelerated aging tests vs field performance of PV modules 加速老化试验与光伏组件的现场性能
IF 29.5 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2022-08-11 DOI: 10.1088/2516-1083/ac890a
K. Weiß, E. Klimm, I. Kaaya
The solar conversion market with photovoltaic (PV) systems has experienced and is experiencing an enormous growth worldwide and—according to the agreed goals of many countries to protect the climate—will further grow over the coming decades. Investments related to PV became an important financial product with the special feature of very long contract durations. A typical setting is an operation of more than 20 years, during which the generation of electricity and also revenues are expected. Sometimes Power Purchase Agreements with durations of up to 50 years have been reported. Taking these long operational times into account, quality, durability, reliability, and degradation rates become a crucial topic for the investment and for all stakeholders. PV modules are the dominating components in this regard since they prevail the investment and—due to their sheer quantity—are in most cases hard to replace if a system has PV module immanent issues. Accelerated ageing tests are in general used to ensure the quality of PV components. These tests are partly standardized, for PV mainly by the International Electrotechnical Commission IEC and related national committees. These standards are used for type approval testing or safety testing, which can also address legal issues. Accelerated ageing tests are also adapted to specific needs and for example used for quality assurance (QA) of manufacturers or service life prediction (SLP) by manufacturers or research institutes. All the efforts are taken to gain more knowledge about the behavior of PV modules in operation and thus the accelerated tests have to be related to normal operation. Since PV is used around the globe, the conditions vary significantly depending on the location of installation, from dry and sunny deserts to mountain climates to tropical or maritime climates. In addition, the type of installation has severe influence on the operational conditions of PV modules i.e. mounted on a roof, roof integrated, open rack—or even in upcoming applications like floating PV. The papers attempt is to give an overview on the state of the art of accelerated testing and field performance analysis of PV modules with focus on the developments over the last five to ten years. Developments are described and the status is analyzed regarding the significance of tests including the latest developments and open scientific gaps related to the envisaged correlation of accelerated tests with field performance. In the end the reader is enabled to differentiate between reliability testing and service life prediction. The understanding for a comprehensive approach of reliability testing including field evaluation data will be developed.
具有光伏(PV)系统的太阳能转换市场在世界范围内经历了并正在经历巨大的增长,并且根据许多国家保护气候的商定目标,在未来几十年将进一步增长。光伏相关投资以其超长的合约期限成为一种重要的金融产品。一个典型的环境是一个超过20年的运行,在此期间,发电和收入都是预期的。有时有长达50年的电力购买协议的报道。考虑到这些较长的运行时间,质量、耐用性、可靠性和退化率成为投资和所有利益相关者的关键话题。光伏组件是这方面的主要组件,因为它们在投资中占上风,而且由于它们的绝对数量,在大多数情况下,如果系统有光伏组件内部问题,它们很难被替换。加速老化试验通常用于确保光伏组件的质量。这些测试部分标准化,主要由国际电工委员会IEC和相关国家委员会进行。这些标准用于型式认可测试或安全测试,也可以解决法律问题。加速老化试验也适用于特定需求,例如用于制造商的质量保证(QA)或制造商或研究机构的使用寿命预测(SLP)。所有的努力都是为了更多地了解光伏组件在运行中的行为,因此加速试验必须与正常运行有关。由于光伏发电在全球范围内使用,因此根据安装位置的不同,从干燥和阳光充足的沙漠到山地气候,再到热带或海洋性气候,条件差异很大。此外,安装类型对光伏组件的运行条件有严重影响,例如安装在屋顶上、屋顶集成、开放式机架上,甚至在即将到来的应用中,如浮动光伏。本文试图对光伏组件的加速测试和现场性能分析的现状进行概述,重点关注过去五到十年的发展。介绍了试验的重要性方面的发展情况,并分析了试验的现状,包括与设想的加速试验与实地性能的相关性有关的最新发展和尚未解决的科学差距。最后,读者能够区分可靠性测试和使用寿命预测。将开发包括现场评估数据在内的可靠性测试综合方法的理解。
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引用次数: 2
Infrared imaging of photovoltaic modules: a review of the state of the art and future challenges facing gigawatt photovoltaic power stations 光伏组件的红外成像:回顾吉瓦光伏电站的技术现状和未来面临的挑战
IF 29.5 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2022-08-11 DOI: 10.1088/2516-1083/ac890b
C. Buerhop, Lukas Bommes, Jan Schlipf, Tobias Pickel, Andreas Fladung, I. M. Peters
Thermography is a frequently used and appreciated method to detect underperforming Photovoltaic modules in solar power stations. With the review, we give insights on two aspects: (a) are the developed measurement strategies highly efficient (about 1 module s−1) to derive timely answers from the images for operators of multi-Mega Warr peak power stations, and (b) do Photovoltaic stakeholders get answers on the relevance of thermal anomalies for further decisions. Following these questions, the influence of measurement conditions, image and data collection, image evaluation as well as image assessment are discussed. From the literature it is clear that automated image acquisition with manned and unmanned aircrafts allow to capture more than 1 module s−1. This makes it possible to achieve almost identical measurement conditions for the modules; however, it is documented to what extent the increase in speed is achieved at the expense of image resolution. Many image processing tools based on machine learning (ML) have been developed and show the potential for analysis of infrared (IR) images and defect classification. There are different approaches to evaluating IR anomalies in terms of impact on performance, yield or degradation, of individual modules or modules in a string configuration. It is clear that the problem is very complex and multi-layered. On the one hand, information on the electrical interconnection is necessary, and on the other hand, there is a lack of sufficient and suitable data sets to adapt existing computer vision tools to Photovolatics. This is where we see the greatest need for action and further development to increase the expressiveness of IR images for PV stakeholder. We conclude with recommendations to improve the outcome of IR-images and encourage the generation of suitable public data sets of IR-footage for the development of ML tools.
热成像技术是一种常用的检测太阳能电站中性能不佳的光伏组件的方法。通过回顾,我们给出了两个方面的见解:(a)开发的测量策略是否高效(约1个模块s−1),以便为多兆瓦峰值电站的运营商从图像中及时获得答案,以及(b)光伏利益相关者是否获得热异常相关性的答案,以便进一步决策。针对这些问题,讨论了测量条件、图像和数据采集、图像评价和图像评价的影响。从文献中可以清楚地看出,有人驾驶和无人驾驶飞机的自动图像采集允许捕获超过1个模块s - 1。这使得可以实现几乎相同的测量条件的模块;然而,在何种程度上,速度的提高是以牺牲图像分辨率为代价的。许多基于机器学习(ML)的图像处理工具已经被开发出来,并显示出红外(IR)图像分析和缺陷分类的潜力。根据对单个模块或管柱配置中的模块的性能、产量或退化的影响,有不同的方法来评估IR异常。很明显,这个问题是非常复杂和多层次的。一方面,关于电气互连的信息是必要的,另一方面,缺乏足够和合适的数据集来使现有的计算机视觉工具适应光伏。这是我们认为最需要采取行动和进一步发展的地方,以提高光伏利益相关者的红外图像的表现力。最后,我们提出了改善红外图像结果的建议,并鼓励为ML工具的开发生成合适的红外镜头公共数据集。
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引用次数: 11
Development of electrochemical reactors for CO2 electroreduction—the viability of an electrochemical CO2 plant in Brazil CO2电还原电化学反应器的开发——巴西CO2电化学装置的可行性
IF 29.5 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2022-08-09 DOI: 10.1088/2516-1083/ac8865
J. Nogueira, Igor Franca Pereira, P. Amaral, C. R. Miranda, J. Meneghini, Thiago Lopes
Our global economy based on burning fossil fuels reached a turning point in the 2020s as problems arising from climate change are becoming increasingly evident. An important strategy to decrease anthropogenic CO2 emission relies on carbon capture and storage (CCS). However, the challenges associated with long-term storage of CO2 in the gas phase highlight the need for a viable Chemical Fixation of CO2. In this scenario, electrochemistry gains prominence since electricity from renewable sources can provide the electrons needed for CO2 electroreduction. The main drawback is the high stability of CO2, the most oxidized form of carbon. Our intention in this Perspective is to give a concise overview of CO2 electroreduction, focusing on why working in the gas phase may help overcome mass transport limitations due to the low solubility of CO2 and how the chemical environment can affect selectivity and activity. We also explore a carbon-emission analysis applied to a CO2 electrochemical system. To do so, we assumed a Brazilian scenario, that is, the carbon footprint associated with electricity generation in the country. Since Brazil relies on more renewable energy sources, an electrochemical reactor that converts CO2 to oxalate with a conversion efficiency (CE) of 20% is enough to result in CO2 abatement, that is, an oxalate production with a negative carbon footprint. Compared with the United States of America, such a system would need to operate at higher CE, 50%, to produce similar results. These results evidence how intricate the implementation of an electrochemical plant is with the carbon footprint of the electricity source.
随着气候变化带来的问题日益明显,以化石燃料为基础的全球经济在本世纪20年代迎来了一个转折点。减少人为二氧化碳排放的一项重要战略依赖于碳捕获与封存(CCS)。然而,在气相中长期储存二氧化碳的挑战突出了对二氧化碳可行的化学固定的需求。在这种情况下,电化学变得重要,因为来自可再生能源的电力可以提供二氧化碳电还原所需的电子。主要的缺点是二氧化碳的稳定性高,二氧化碳是碳的最氧化形式。我们的目的是简要概述CO2电还原,重点是为什么在气相中工作可能有助于克服由于CO2的低溶解度而导致的质量传输限制,以及化学环境如何影响选择性和活性。我们还探讨了应用于二氧化碳电化学系统的碳排放分析。为此,我们假设了巴西的情况,即该国与发电相关的碳足迹。由于巴西依赖更多的可再生能源,一个将二氧化碳转化为草酸盐的电化学反应器,其转化效率(CE)为20%,足以实现二氧化碳减排,即产生负碳足迹的草酸盐。与美国相比,这样的系统需要在更高的CE(50%)下运行,才能产生类似的结果。这些结果证明了电化学工厂的实施与电力来源的碳足迹是多么复杂。
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引用次数: 0
Improving future travel demand projections: a pathway with an open science interdisciplinary approach 改进未来旅游需求预测:采用开放科学跨学科方法的途径
IF 29.5 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2022-08-03 DOI: 10.1088/2516-1083/ac86b5
S. Yeh, J. Gil, P. Kyle, P. Kishimoto, Pierpaolo Cazzola, Matteo Craglia, O. Edelenbosch, Panagiotis Fragkos, L. Fulton, Yuan Liao, Luis Martinez, D. McCollum, Joshua Miller, R. Pereira, J. Teter
Transport accounts for 24% of global CO2 emissions from fossil fuels. Governments face challenges in developing feasible and equitable mitigation strategies to reduce energy consumption and manage the transition to low-carbon transport systems. To meet the local and global transport emission reduction targets, policymakers need more realistic/sophisticated future projections of transport demand to better understand the speed and depth of the actions required to mitigate greenhouse gas emissions. In this paper, we argue that the lack of access to high-quality data on the current and historical travel demand and interdisciplinary research hinders transport planning and sustainable transitions toward low-carbon transport futures. We call for a greater interdisciplinary collaboration agenda across open data, data science, behaviour modelling, and policy analysis. These advancemets can reduce some of the major uncertainties and contribute to evidence-based solutions toward improving the sustainability performance of future transport systems. The paper also points to some needed efforts and directions to provide robust insights to policymakers. We provide examples of how these efforts could benefit from the International Transport Energy Modeling Open Data project and open science interdisciplinary collaborations.
交通运输占全球化石燃料二氧化碳排放量的24%。各国政府在制定可行和公平的缓解战略以减少能源消耗和管理向低碳运输系统的过渡方面面临挑战。为了实现地方和全球交通减排目标,政策制定者需要对未来交通需求进行更现实/更复杂的预测,以更好地了解减少温室气体排放所需行动的速度和深度。在本文中,我们认为缺乏当前和历史旅行需求的高质量数据以及跨学科研究阻碍了交通规划和向低碳交通未来的可持续过渡。我们呼吁在开放数据、数据科学、行为建模和政策分析方面开展更大的跨学科合作议程。这些进展可以减少一些主要的不确定性,并有助于为改善未来交通系统的可持续性绩效提供基于证据的解决方案。本文还指出了一些必要的努力和方向,以便为政策制定者提供有力的见解。我们提供了这些努力如何从国际运输能源建模开放数据项目和开放科学跨学科合作中受益的例子。
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引用次数: 4
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Progress in Energy and Combustion Science
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