首页 > 最新文献

Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.最新文献

英文 中文
Domain engineering of Pb[(Zn/sub 1/3/Nb/sub 2/3/)/sub 0.91/Ti/sub 0.09/]O/sub 3/ single crystals and piezoelectric related properties Pb[(Zn/sub 1/3/Nb/sub 2/3/)/sub 0.91/Ti/sub 0.09/]O/sub 3/单晶的畴工程及相关压电性能
A. Renault, H. Dammak, P. Gaucher, M. Pham Thi, G. Calvarin
The domain configuration and the electromechanical related properties have been studied in Pb[(Zn/sub 1/3/Nb/sub 2/3/)/sub 0.91/Ti/sub 0.09/]O/sub 3/ (PZN-9%PT) single crystals cut along [001] and [101~]. It was established that soft (with high d) and hard (with lower d) piezoelectric properties are respectively obtained in a multidomain and a single domain configuration. The softer piezoelectric material (d/sub 33/ = 2700 pC/N, s/sub 33//sup E/ = 180 pN/m/sup 2/, k/sub 33/ = 93%) was found in the monoclinic multidomain state after poling with a small field along [001]. Optimal poling process and electromechanical related properties of the single crystals were discussed in term of the field-temperature diagram.
研究了沿[001]和[101~]切割的Pb[(Zn/sub 1/3/Nb/sub 2/3/)/sub 0.91/Ti/sub 0.09/]O/sub 3/ (PZN-9%PT)单晶的畴结构和机电相关性能。在多域和单域结构下分别获得了高d值的软压电和低d值的硬压电。沿小电场极化后,发现较软的压电材料(d/sub 33/ = 2700 pC/N, s/sub 33//sup E/ = 180 pN/m/sup 2/, k/sub 33/ = 93%)处于单斜多畴态[001]。根据场温图讨论了最佳极化工艺和单晶的机电相关性能。
{"title":"Domain engineering of Pb[(Zn/sub 1/3/Nb/sub 2/3/)/sub 0.91/Ti/sub 0.09/]O/sub 3/ single crystals and piezoelectric related properties","authors":"A. Renault, H. Dammak, P. Gaucher, M. Pham Thi, G. Calvarin","doi":"10.1109/ISAF.2002.1195962","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195962","url":null,"abstract":"The domain configuration and the electromechanical related properties have been studied in Pb[(Zn/sub 1/3/Nb/sub 2/3/)/sub 0.91/Ti/sub 0.09/]O/sub 3/ (PZN-9%PT) single crystals cut along [001] and [101~]. It was established that soft (with high d) and hard (with lower d) piezoelectric properties are respectively obtained in a multidomain and a single domain configuration. The softer piezoelectric material (d/sub 33/ = 2700 pC/N, s/sub 33//sup E/ = 180 pN/m/sup 2/, k/sub 33/ = 93%) was found in the monoclinic multidomain state after poling with a small field along [001]. Optimal poling process and electromechanical related properties of the single crystals were discussed in term of the field-temperature diagram.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"33 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131492120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lead zirconate titanate thick films by sol-gel method for piezoelectric applications 溶胶-凝胶法制备锆钛酸铅压电厚膜
Y. Ohya, T. Tamakoshi, T. Ban, Y. Takahashi
Lead zirconate titanate (PZT) films were fabricated by a sol-gel method. The sol was prepared using Ti(O/sup i/Pr)/sub 4/, Pb(OAc)/sub 2//spl middot/3H/sub 2/O, Zr(O/sup n/Bu)/sub 4/, and diethanolamine (DEA) with a molar ratio of DEA/(Ti+Zr)=1. They were dissolved in isopropanol solvent. The concentrations of the sol were about 1.5 and 0.4 mol/L with compositions of Pb/sub x/(Ti/sub 0.5/Zr/sub 0.5/)O/sub 3/, (x = 1.1 and 1.3). The substrate used was Si wafer sputtered with Pt as an electrode. The deposition was conducted by a dip-coating procedure. After deposition and drying at 110/spl deg/C, the substrate was heated at 700/spl deg/C for 30min to crystallize perovskite phase. This coating-drying-heating cycle was repeated several times to obtain a thick PZT film. The fabricated films was about 7 /spl mu/m thick by eight depositions and consisted of the first three thin layers (90 nm each) and five to eight thick layers (1.2 /spl mu/m each). The dielectric constant of the films was about 400 and tan/spl delta/ was about 0.01 at 1 kHz. The films exhibited typical ferroelectric P-E hysteresis curve and the remanent polarization and coercive force were 29.7 /spl mu/C/cm/sup 2/ and 69.7 kV/cm, respectively. The admittance measurement of the poled thick film exhibited clear resonance and antiresonance peaks. The piezoelectric displacement was measured by a laser interferometer and the piezoelectric constant, d/sub 33/, was calculated as 430 to 550 pm/V.
采用溶胶-凝胶法制备锆钛酸铅(PZT)薄膜。以Ti(O/sup i/Pr)/sub - 4/、Pb(OAc)/sub - 2//spl middot/3H/sub - 2/O、Zr(O/sup n/Bu)/sub - 4/和二乙醇胺(DEA)为原料制备溶胶,DEA/(Ti+Zr)的摩尔比为1。将它们溶解在异丙醇溶剂中。土壤中Pb/sub x/(Ti/sub 0.5/Zr/sub 0.5/)O/sub 3/ (x = 1.1和1.3)的浓度分别为1.5和0.4 mol/L。衬底为硅晶片溅射,电极为铂。该沉积是通过浸渍涂层程序进行的。基底在110/spl℃下沉积干燥后,在700/spl℃下加热30min使钙钛矿相结晶。这种涂覆-干燥-加热循环重复几次,以获得厚的PZT膜。通过8次沉积制备的薄膜厚度约为7 /spl mu/m,由前3层薄层(每层90 nm)和5至8层厚层(每层1.2 /spl mu/m)组成。在1 kHz时,薄膜的介电常数约为400,tan/spl δ /约为0.01。薄膜表现出典型的铁电P-E迟滞曲线,剩余极化和矫顽力分别为29.7 /spl mu/C/cm/sup 2/和69.7 kV/cm。极化厚膜的导纳测量显示出明显的共振峰和反共振峰。用激光干涉仪测量压电位移,计算压电常数d/sub 33/为430 ~ 550 pm/V。
{"title":"Lead zirconate titanate thick films by sol-gel method for piezoelectric applications","authors":"Y. Ohya, T. Tamakoshi, T. Ban, Y. Takahashi","doi":"10.1109/ISAF.2002.1195969","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195969","url":null,"abstract":"Lead zirconate titanate (PZT) films were fabricated by a sol-gel method. The sol was prepared using Ti(O/sup i/Pr)/sub 4/, Pb(OAc)/sub 2//spl middot/3H/sub 2/O, Zr(O/sup n/Bu)/sub 4/, and diethanolamine (DEA) with a molar ratio of DEA/(Ti+Zr)=1. They were dissolved in isopropanol solvent. The concentrations of the sol were about 1.5 and 0.4 mol/L with compositions of Pb/sub x/(Ti/sub 0.5/Zr/sub 0.5/)O/sub 3/, (x = 1.1 and 1.3). The substrate used was Si wafer sputtered with Pt as an electrode. The deposition was conducted by a dip-coating procedure. After deposition and drying at 110/spl deg/C, the substrate was heated at 700/spl deg/C for 30min to crystallize perovskite phase. This coating-drying-heating cycle was repeated several times to obtain a thick PZT film. The fabricated films was about 7 /spl mu/m thick by eight depositions and consisted of the first three thin layers (90 nm each) and five to eight thick layers (1.2 /spl mu/m each). The dielectric constant of the films was about 400 and tan/spl delta/ was about 0.01 at 1 kHz. The films exhibited typical ferroelectric P-E hysteresis curve and the remanent polarization and coercive force were 29.7 /spl mu/C/cm/sup 2/ and 69.7 kV/cm, respectively. The admittance measurement of the poled thick film exhibited clear resonance and antiresonance peaks. The piezoelectric displacement was measured by a laser interferometer and the piezoelectric constant, d/sub 33/, was calculated as 430 to 550 pm/V.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"113 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133410141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Low-temperature preparation of ferroelectric Ba/sub 2/NaNb/sub 5/O/sub 15/ thin films by pulsed laser deposition 脉冲激光沉积法低温制备Ba/ sub2 /NaNb/ sub5 /O/ sub15 /铁电薄膜
K. Ohnuki, T. Higuchi, M. Takayasu, M. Sogawa, T. Tsukamoto
Ferroelectric Ba/sub 2/NaNb/sub 5/O/sub 15/ (BNN) thin films were prepared on MgO (100) substrates by pulsed laser deposition method. When the laser power density and repetition frequency were fixed at 200 mJ/cm/sup 2/ and 5 Hz, respectively, the c-axis oriented BNN thin film was obtained at substrate temperature of 650/spl deg/C. The interface between the c-axis oriented BNN thin film and MgO substrate was very smooth. The band gap of the c-axis oriented BNN thin film was about 3.1 eV, which accords to that of the BNN single crystal.
采用脉冲激光沉积法在MgO(100)衬底上制备了Ba/ sub2 /NaNb/ sub5 /O/ sub15 / (BNN)铁电薄膜。当激光功率密度和重复频率分别为200 mJ/cm/sup /和5 Hz时,衬底温度为650/spl℃,可获得C轴取向的BNN薄膜。c轴取向BNN薄膜与MgO衬底之间的界面非常光滑。c轴取向的BNN薄膜的带隙约为3.1 eV,与BNN单晶的带隙一致。
{"title":"Low-temperature preparation of ferroelectric Ba/sub 2/NaNb/sub 5/O/sub 15/ thin films by pulsed laser deposition","authors":"K. Ohnuki, T. Higuchi, M. Takayasu, M. Sogawa, T. Tsukamoto","doi":"10.1109/ISAF.2002.1195897","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195897","url":null,"abstract":"Ferroelectric Ba/sub 2/NaNb/sub 5/O/sub 15/ (BNN) thin films were prepared on MgO (100) substrates by pulsed laser deposition method. When the laser power density and repetition frequency were fixed at 200 mJ/cm/sup 2/ and 5 Hz, respectively, the c-axis oriented BNN thin film was obtained at substrate temperature of 650/spl deg/C. The interface between the c-axis oriented BNN thin film and MgO substrate was very smooth. The band gap of the c-axis oriented BNN thin film was about 3.1 eV, which accords to that of the BNN single crystal.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132709950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Direct growth of orthorhombic potassium niobate (KNbO/sub 3/) crystal from an aqueous solution 在水溶液中直接生长正交铌酸钾(KNbO/ sub3 /)晶体
R. Komatsu, K. Adachi, K. Ikeda
Ferroelectric orthorhombic potassium niobate (KNbO/sub 3/) crystal is successfully grown from an aqueous solution dissolving K/sub 2/NbO/sub 3/F as a nutrient. Although the size of each crystal is about 30 /spl mu/m or less, properties of the formed KNbO/sub 3/ crystals have been examined. The possibility of this method in the future to grow KNbO/sub 3/ crystals or thin films has also been investigated in order to apply KNbO/sub 3/ to SAW and BAW devices.
在以K/sub - 2/NbO/sub - 3/F为营养物的水溶液中成功生长出铁电正交铌酸钾晶体。虽然每个晶体的大小约为30 /spl mu/m或更小,但所形成的KNbO/sub - 3/晶体的性质已被检查。为了将KNbO/sub - 3/应用于SAW和BAW器件,还研究了这种方法在未来生长KNbO/sub - 3/晶体或薄膜的可能性。
{"title":"Direct growth of orthorhombic potassium niobate (KNbO/sub 3/) crystal from an aqueous solution","authors":"R. Komatsu, K. Adachi, K. Ikeda","doi":"10.1109/ISAF.2002.1195957","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195957","url":null,"abstract":"Ferroelectric orthorhombic potassium niobate (KNbO/sub 3/) crystal is successfully grown from an aqueous solution dissolving K/sub 2/NbO/sub 3/F as a nutrient. Although the size of each crystal is about 30 /spl mu/m or less, properties of the formed KNbO/sub 3/ crystals have been examined. The possibility of this method in the future to grow KNbO/sub 3/ crystals or thin films has also been investigated in order to apply KNbO/sub 3/ to SAW and BAW devices.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"62 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130333560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Studies of proton irradiated 0.9PMN-0.1PT/P(VDF-TrFE) 0-3 composites 质子辐照0.9PMN-0.1PT/P(VDF-TrFE) 0-3复合材料的研究
K. H. Lam, H. Chan, C. Choy, E. Luo, I. Wilson
Polyvinylidene fluoride-trifluoroethylene [P(VDF-TrFE) 70/30 mol%] copolymer can be transformed from a ferroelectric to a relaxor material after proton irradiation. The phase transition peak broadens and shifts towards lower temperature as the measurement frequency decreases. In the present study, 0-3 composites are fabricated by incorporating 0-9Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-0.1PbTiO/sub 3/ ceramic powder into a P(VDF-TrFE) 70/30 mol% copolymer matrix. 0.9PMN-0.1PT ceramic is a relaxor ferroelectric with high dielectric permittivity. It was found that the relative permittivity of PMN-PT/P(VDF-TrFE) 0-3 composite increases with increasing ceramic volume fraction. Composites with 0.3 and 0.4 volume fraction of 0.9PMN-0.1PT were subjected to proton irradiation. With a 80 Mrad (4.76 /spl times/ 10/sup 13/ ions/cm/sup 2/) proton dosage, the relative permittivity of the 0.4 volume fraction 0-3 composites can go up to 130 near room temperature (at 1 kHz).
聚偏氟乙烯-三氟乙烯[P(VDF-TrFE) 70/30 mol%]共聚物经质子辐照后可由铁电性转变为弛豫材料。随着测量频率的降低,相变峰变宽并向较低温度方向移动。在本研究中,将0-9Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-0.1PbTiO/sub 3/陶瓷粉末掺入P(VDF-TrFE) 70/30 mol%共聚物基体中制备了0-3复合材料。0.9PMN-0.1PT陶瓷是具有高介电常数的弛豫铁电体。结果表明,PMN-PT/P(VDF-TrFE) 0-3复合材料的相对介电常数随陶瓷体积分数的增加而增大。以0.9PMN-0.1PT体积分数为0.3和0.4的复合材料进行质子辐照。当质子用量为80 Mrad (4.76 /spl倍/ 10/sup 13/ ions/cm/sup 2/)时,0.4体积分数0-3复合材料的相对介电常数在室温(1 kHz)附近可达130。
{"title":"Studies of proton irradiated 0.9PMN-0.1PT/P(VDF-TrFE) 0-3 composites","authors":"K. H. Lam, H. Chan, C. Choy, E. Luo, I. Wilson","doi":"10.1109/ISAF.2002.1195863","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195863","url":null,"abstract":"Polyvinylidene fluoride-trifluoroethylene [P(VDF-TrFE) 70/30 mol%] copolymer can be transformed from a ferroelectric to a relaxor material after proton irradiation. The phase transition peak broadens and shifts towards lower temperature as the measurement frequency decreases. In the present study, 0-3 composites are fabricated by incorporating 0-9Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-0.1PbTiO/sub 3/ ceramic powder into a P(VDF-TrFE) 70/30 mol% copolymer matrix. 0.9PMN-0.1PT ceramic is a relaxor ferroelectric with high dielectric permittivity. It was found that the relative permittivity of PMN-PT/P(VDF-TrFE) 0-3 composite increases with increasing ceramic volume fraction. Composites with 0.3 and 0.4 volume fraction of 0.9PMN-0.1PT were subjected to proton irradiation. With a 80 Mrad (4.76 /spl times/ 10/sup 13/ ions/cm/sup 2/) proton dosage, the relative permittivity of the 0.4 volume fraction 0-3 composites can go up to 130 near room temperature (at 1 kHz).","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"90 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124577405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of A-site substitution on the magnetic and dielectric behaviors of YMnO/sub 3/ based ferroelectric thin films a位取代对YMnO/ sub3 /基铁电薄膜磁性和介电行为的影响
N. Fujimura, H. Sakata, D. Ito, T. Yokota, T. Ito
Dielectric and magnetic properties of A-site substituted YMnO/sub 3/ ceramics and epitaxial films were studied. Stoichiometric polycrystalline bulk sample exhibit p-type conduction due to the existence of Mn/sup 4+/. The I-V property is well explained the Pool-Frenkel type carrier emission, and the activation energy is calculated to be 0.38 eV. The carrier density decreases by Zr doping and increases by Li or Mg doping. Although all the samples exhibit antiferromagnetic magnetization behavior against the applied magnetic field at 5 K, carrier doped samples displays parasitic ferromagnetic behavior (weak ferromagnetism). Epitaxial films show distinct ferroelectric property and also exhibit antiferromagnetism. Substituting Y with Yb enhances the ferromagnetic interaction.
研究了a位取代的YMnO/ sub3 /陶瓷和外延薄膜的介电和磁性能。由于Mn/sup 4+/的存在,化学计量多晶体样品呈现p型导电。池- frenkel型载流子发射的I-V特性得到了很好的解释,计算出活化能为0.38 eV。Zr掺杂使载流子密度减小,Li或Mg掺杂使载流子密度增大。虽然所有样品在5k时对外加磁场表现出反铁磁磁化行为,但载流子掺杂的样品表现出寄生铁磁行为(弱铁磁)。外延薄膜具有明显的铁电特性和反铁磁性。用Yb取代Y增强了铁磁相互作用。
{"title":"Effect of A-site substitution on the magnetic and dielectric behaviors of YMnO/sub 3/ based ferroelectric thin films","authors":"N. Fujimura, H. Sakata, D. Ito, T. Yokota, T. Ito","doi":"10.1109/ISAF.2002.1195909","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195909","url":null,"abstract":"Dielectric and magnetic properties of A-site substituted YMnO/sub 3/ ceramics and epitaxial films were studied. Stoichiometric polycrystalline bulk sample exhibit p-type conduction due to the existence of Mn/sup 4+/. The I-V property is well explained the Pool-Frenkel type carrier emission, and the activation energy is calculated to be 0.38 eV. The carrier density decreases by Zr doping and increases by Li or Mg doping. Although all the samples exhibit antiferromagnetic magnetization behavior against the applied magnetic field at 5 K, carrier doped samples displays parasitic ferromagnetic behavior (weak ferromagnetism). Epitaxial films show distinct ferroelectric property and also exhibit antiferromagnetism. Substituting Y with Yb enhances the ferromagnetic interaction.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"7 7","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"113980179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electromechanical characterization of thick PT and PZT films PT和PZT厚膜的机电特性
Laurent Simon, P. Gonnard, L. Lebrun
This work is focused on the electromechanical characterization of lead titanate and Pb(Zr/sub 0.52/Ti/sub 0.48/)O/sub 3/ thick films (30 - 100 /spl mu/m) screen-printed on various substrates (alumina, silicon and glass-ceramic). Measurements of permittivity and piezoelectric constant are given at low signal and as a function of the AC electric field amplitude. Measurement of the true remanent polarization on PT films is more delicate due to the existence of an internal electric field which is different according to the type of the bottom electrode. A correct value can be achieved by extrapolation. At last the elastic stiffness and the extensional thickness coupling factor k/sub t/ are evaluated by analyzing the resonance frequency spectrum of the piezoelectric film supported by a substrate. Some reasons of inaccuracy of the results are stated.
本研究的重点是钛酸铅和Pb(Zr/sub 0.52/Ti/sub 0.48/)O/sub 3/厚膜(30 - 100 /spl mu/m)丝网印刷在各种衬底(氧化铝、硅和玻璃陶瓷)上的机电特性。给出了低信号下的介电常数和压电常数随交流电场幅值的函数。由于内部电场的存在,根据底部电极的类型,内部电场的存在是不同的,因此对PT薄膜上真实剩余极化的测量更加微妙。通过外推可以得到一个正确的值。最后,通过分析衬底支撑的压电薄膜的谐振频谱,计算了其弹性刚度和拉伸厚度耦合系数k/sub t/。指出了结果不准确的一些原因。
{"title":"Electromechanical characterization of thick PT and PZT films","authors":"Laurent Simon, P. Gonnard, L. Lebrun","doi":"10.1109/ISAF.2002.1195967","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195967","url":null,"abstract":"This work is focused on the electromechanical characterization of lead titanate and Pb(Zr/sub 0.52/Ti/sub 0.48/)O/sub 3/ thick films (30 - 100 /spl mu/m) screen-printed on various substrates (alumina, silicon and glass-ceramic). Measurements of permittivity and piezoelectric constant are given at low signal and as a function of the AC electric field amplitude. Measurement of the true remanent polarization on PT films is more delicate due to the existence of an internal electric field which is different according to the type of the bottom electrode. A correct value can be achieved by extrapolation. At last the elastic stiffness and the extensional thickness coupling factor k/sub t/ are evaluated by analyzing the resonance frequency spectrum of the piezoelectric film supported by a substrate. Some reasons of inaccuracy of the results are stated.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"7 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114134034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The influence of Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/ content on the piezoelectric and dielectric properties of PMNN-PZT system near the MPB Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/含量对MPB附近PMNN-PZT体系压电和介电性能的影响
Haiyan Chen, X. Guo, Wenbiao Wu, Z. Meng
Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-Pb(Mn/sub 1/3/Nb/sub 2/3/)O/sub 3/-PbZrO/sub 3/-PbTiO/sub 3/ (PMMN-PZT) quaternary piezoelectric ceramics with the various contents of Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/ (PMN), which locate in the vicinity of the morphotropic phase boundary (MPB), were fabricated. The phase structure of the system was delineated by X-ray diffraction analysis. The piezoelectric and dielectric properties were also measured. Experimental results reveal that the MPB coexisting tetragonal and rhombohedral phases in the present system has a broad composition region from 0.10 to 0.14mol% PM. The piezoelectric coefficient and electromechanical coupling factor increase with increasing PMN and reach the maximum values at 12mol% PMN, then decrease remarkably with further PMN addition, whereas the variation of Qm with PMN addition shows the opposite trend. The dielectric constant also reaches the maximum value at 12mol% PMN. It is found that compared with the as-sintered samples, the dielectric constant of the poled samples in tetragonal phase increases, while there are contrary results in rhombohedral phase. The variation of dielectric properties reflects the transition from tetragonal phase to rhombohedral phase.
制备了Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-Pb(Mn/sub 1/3/Nb/sub 2/3/)O/sub 3/-PbZrO/sub 3/-PbTiO/sub 3/ (PMMN-PZT)含量不同的Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/ (PMN)的四元压电陶瓷,其分布在亲晶相边界(MPB)附近。通过x射线衍射分析确定了体系的相结构。测试了材料的压电和介电性能。实验结果表明,该体系中四边形和菱形相共存的MPB在0.10 ~ 0.14mol% PM范围内具有较宽的组成范围。压电系数和机电耦合系数随PMN的增加而增大,在PMN添加量为12mol%时达到最大值,然后随着PMN添加量的增加而显著减小,而Qm随PMN添加量的变化趋势相反。介电常数在12mol% PMN时也达到最大值。结果表明,与烧结试样相比,正方相极化试样的介电常数增大,而菱形相极化试样的介电常数增大。介电性能的变化反映了从四方相到菱形相的转变。
{"title":"The influence of Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/ content on the piezoelectric and dielectric properties of PMNN-PZT system near the MPB","authors":"Haiyan Chen, X. Guo, Wenbiao Wu, Z. Meng","doi":"10.1109/ISAF.2002.1195948","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195948","url":null,"abstract":"Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-Pb(Mn/sub 1/3/Nb/sub 2/3/)O/sub 3/-PbZrO/sub 3/-PbTiO/sub 3/ (PMMN-PZT) quaternary piezoelectric ceramics with the various contents of Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/ (PMN), which locate in the vicinity of the morphotropic phase boundary (MPB), were fabricated. The phase structure of the system was delineated by X-ray diffraction analysis. The piezoelectric and dielectric properties were also measured. Experimental results reveal that the MPB coexisting tetragonal and rhombohedral phases in the present system has a broad composition region from 0.10 to 0.14mol% PM. The piezoelectric coefficient and electromechanical coupling factor increase with increasing PMN and reach the maximum values at 12mol% PMN, then decrease remarkably with further PMN addition, whereas the variation of Qm with PMN addition shows the opposite trend. The dielectric constant also reaches the maximum value at 12mol% PMN. It is found that compared with the as-sintered samples, the dielectric constant of the poled samples in tetragonal phase increases, while there are contrary results in rhombohedral phase. The variation of dielectric properties reflects the transition from tetragonal phase to rhombohedral phase.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"13 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124472234","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dielectric properties of lead barium zirconate titanate-based relaxors for power electronics applications 电力电子用锆钛酸铅钡基弛豫器的介电性能
M. Pan, R. Rayne, B. Bender
In this study, we examined the effects of niobium oxide and lanthanum oxide dopants on the dielectric properties of a lead barium zirconate titanate (PBZT) relaxor material. Specifically, our goal was to maximize PBZT's dielectric constant (>6000) while maintaining its stability under DC electric field for filter capacitor applications. Our results showed that the Nb addition did not have a significant effect on the dielectric behavior of PBZT, except the 1% Nb addition which increased the PBZT's dielectric constant by 17%. The cause of the increase is speculated in this article. On the other hand, the La addition caused a monotonic decrease of dielectric constant and a significant shift of the dielectric peaks toward low temperature.
在这项研究中,我们研究了氧化铌和氧化镧掺杂对锆钛酸铅钡弛豫材料介电性能的影响。具体来说,我们的目标是最大化PBZT的介电常数(>6000),同时保持其在直流电场下的稳定性,用于滤波电容器应用。结果表明,Nb的加入对PBZT的介电常数没有显著影响,但添加1%的Nb使PBZT的介电常数增加了17%。这篇文章推测了增加的原因。另一方面,La的加入引起了介电常数的单调降低和介电峰向低温方向的显著移动。
{"title":"Dielectric properties of lead barium zirconate titanate-based relaxors for power electronics applications","authors":"M. Pan, R. Rayne, B. Bender","doi":"10.1109/ISAF.2002.1195918","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195918","url":null,"abstract":"In this study, we examined the effects of niobium oxide and lanthanum oxide dopants on the dielectric properties of a lead barium zirconate titanate (PBZT) relaxor material. Specifically, our goal was to maximize PBZT's dielectric constant (>6000) while maintaining its stability under DC electric field for filter capacitor applications. Our results showed that the Nb addition did not have a significant effect on the dielectric behavior of PBZT, except the 1% Nb addition which increased the PBZT's dielectric constant by 17%. The cause of the increase is speculated in this article. On the other hand, the La addition caused a monotonic decrease of dielectric constant and a significant shift of the dielectric peaks toward low temperature.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"66 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124655681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A 35 MHz linear ultrasonic array for medical imaging 用于医学成像的35 MHz线性超声阵列
J. Cannata, T. Shrout, K. Shung
Ultrasound backscatter microscope (UBM) imaging systems operating above 20 MHz are capable of achieving the axial and lateral resolutions needed for applications in ophthalmology and dermatology. Unfortunately these systems rely upon mechanically scanned single element transducers and suffer from a fixed focus, low frame rate and cumbersome scanning hardware. High frequency arrays are therefore desirable for several reasons, including the ability to dynamically focus the sound beam, increase frame rates and clinical convenience. This study investigates the design tradeoffs involved in the development of a high frequency (35 MHz) 64-element linear array. This array was designed primarily for human eye and skin imaging, and features monolithic elements mechanically diced out of a fine grain high density PZT-5H ceramic. Array elements were spaced with a 50 /spl mu/m pitch, interconnected via a flexible circuit and matched to the 50 /spl Omega/ system electronics via a 85 /spl Omega/ transmission line coaxial cable. Several prototype arrays were constructed with promising results. An average center frequency of 34 MHz with a -6 dB bandwidth of at least 45% per element was achieved. The maximum combined electrical and acoustical crosstalk for nearest and next nearest elements was less than -29 dB, and the average 40 dB pulse length was 105 ns.
工作在20兆赫以上的超声后向散射显微镜(UBM)成像系统能够实现眼科和皮肤病学应用所需的轴向和横向分辨率。不幸的是,这些系统依赖于机械扫描的单元件传感器,并且受到固定焦点,低帧率和笨重的扫描硬件的影响。因此,出于几个原因,高频阵列是可取的,包括动态聚焦声束的能力,提高帧率和临床便利性。本研究探讨了开发高频(35 MHz) 64元线性阵列所涉及的设计权衡。该阵列主要是为人眼和皮肤成像而设计的,其特点是采用细颗粒高密度PZT-5H陶瓷机械切割而成的单片元件。阵列元件间距为50 /spl μ /m,通过柔性电路互连,并通过85 /spl ω /传输线同轴电缆与50 /spl ω /系统电子设备匹配。构建了几个原型阵列,并取得了令人满意的结果。平均中心频率为34 MHz,每个元件的-6 dB带宽至少为45%。最近和次最近元件的最大电声串扰小于-29 dB,平均40 dB脉冲长度为105 ns。
{"title":"A 35 MHz linear ultrasonic array for medical imaging","authors":"J. Cannata, T. Shrout, K. Shung","doi":"10.1109/ISAF.2002.1195939","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195939","url":null,"abstract":"Ultrasound backscatter microscope (UBM) imaging systems operating above 20 MHz are capable of achieving the axial and lateral resolutions needed for applications in ophthalmology and dermatology. Unfortunately these systems rely upon mechanically scanned single element transducers and suffer from a fixed focus, low frame rate and cumbersome scanning hardware. High frequency arrays are therefore desirable for several reasons, including the ability to dynamically focus the sound beam, increase frame rates and clinical convenience. This study investigates the design tradeoffs involved in the development of a high frequency (35 MHz) 64-element linear array. This array was designed primarily for human eye and skin imaging, and features monolithic elements mechanically diced out of a fine grain high density PZT-5H ceramic. Array elements were spaced with a 50 /spl mu/m pitch, interconnected via a flexible circuit and matched to the 50 /spl Omega/ system electronics via a 85 /spl Omega/ transmission line coaxial cable. Several prototype arrays were constructed with promising results. An average center frequency of 34 MHz with a -6 dB bandwidth of at least 45% per element was achieved. The maximum combined electrical and acoustical crosstalk for nearest and next nearest elements was less than -29 dB, and the average 40 dB pulse length was 105 ns.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129753343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
期刊
Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1