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Overview and loss analysis of III–V single-junction and multi-junction solar cells III-V型单结和多结太阳能电池概述及损耗分析
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022020
M. Yamaguchi, F. Dimroth, N. Ekins‐Daukes, N. Kojima, Y. Ohshita
The development of high-performance solar cells offers a promising pathway toward achieving high power per unit cost for many applications. Because state-of-the-art efficiencies of single-junction solar cells are approaching the Shockley-Queisser limit, the multi-junction (MJ) solar cells are very attractive for high-efficiency solar cells. This paper reviews progress in III–V compound single-junction and MJ solar cells. In addition, analytical results for efficiency potential and non-radiative recombination and resistance losses in III–V compound single-junction and MJ solar cells are presented for further understanding and decreasing major losses in III–V compound materials and MJ solar cells. GaAs single-junction, III–V 2-junction and III–V 3-junction solar cells are shown to have potential efficiencies of 30%, 37% and 47%, respectively. Although in initial stage of developments, GaAs single-junction and III–V MJ solar cells have shown low ERE values, ERE values have been improved as a result of several technology development such as device structure and material quality developments. In the case of III–V MJ solar cells, improvements in ERE of sub-cells are shown to be necessary for further improvements in efficiencies of MJ solar cells.
高性能太阳能电池的发展为许多应用提供了一条实现高单位成本功率的有希望的途径。由于目前单结太阳能电池的效率已接近Shockley-Queisser极限,因此多结(MJ)太阳能电池对高效太阳能电池非常有吸引力。本文综述了III-V型化合物单结和MJ太阳能电池的研究进展。此外,本文还给出了III-V化合物单结和MJ太阳能电池的效率势、非辐射复合和电阻损耗的分析结果,以进一步了解和减少III-V化合物材料和MJ太阳能电池的主要损耗。结果表明,GaAs单结、III-V 2结和III-V 3结太阳能电池的潜在效率分别为30%、37%和47%。虽然在开发的初始阶段,砷化镓单结和III-V MJ太阳能电池的ERE值较低,但由于器件结构和材料质量等技术的发展,ERE值得到了改善。在III-V MJ太阳能电池的情况下,改进亚电池的ERE被证明是进一步提高MJ太阳能电池效率的必要条件。
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引用次数: 4
A study of quenching approaches to optimize ultrasonic spray coated perovskite layers scalable for PV 优化光伏可扩展超声喷涂钙钛矿层的淬火方法研究
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022008
J. Silvano, Jacopo Sala, T. Merckx, Y. Kuang, Pieter Verding, J. D’Haen, Tom Aernouts, B. Vermang, W. Deferme
Perovskite materials have gathered increased interest over the last decade. Their rapidly rising efficiency, coupled with the compatibility with solution processing and thin film technology has put perovskite solar cells (PSC) on the spotlight of photovoltaic research. On top of that, band gap tunability via composition changes makes them a perfect candidate for tandem applications, allowing for further harvest of the solar irradiation spectrum and improved power conversion efficiency (PCE). In order to convert all these advantages into large scale production and have increased dissemination in the energy generation market, perovskite fabrication must be adapted and optimized with the use of high throughput, continuous processes, such as ultrasonic spray coating (USSC). In this paper we investigate the ultrasonically spray coated perovskite layers for photovoltaic applications, with particular focus on the quenching-assisted crystallization step. Different quenching techniques are introduced to the process and compared in terms of final layer morphology and cell performance. Finally, gas quenching is used with the large-scale-compatible deposition and allows the production of perovskite solar cells with PCE >15%.
钙钛矿材料在过去十年中引起了越来越多的兴趣。钙钛矿太阳能电池(PSC)效率的迅速提高,加上与溶液加工和薄膜技术的兼容性,使其成为光伏研究的焦点。最重要的是,通过成分变化的带隙可调性使它们成为串联应用的完美候选者,允许进一步收集太阳辐射光谱并提高功率转换效率(PCE)。为了将所有这些优势转化为大规模生产,并在能源生产市场上增加传播,钙钛矿制造必须适应和优化使用高通量,连续工艺,如超声波喷涂(USSC)。在本文中,我们研究了用于光伏应用的超声喷涂钙钛矿层,特别关注了淬火辅助结晶步骤。介绍了不同的淬火工艺,并在最终层形貌和电池性能方面进行了比较。最后,气淬与大规模相容沉积一起使用,并允许生产PCE >15%的钙钛矿太阳能电池。
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引用次数: 2
Stable reverse bias or integrated bypass diode in HIP‑MWT+ solar cells 稳定的反向偏压或集成旁路二极管在HIP‑MWT+太阳能电池
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2021016
T. Schweigstill, A. Spribille, J. D. Huyeng, Florian Clement, Stefan W. Glunz
The Metal Wrap Through+ (HIP-MWT+) solar cell is based on the PERC concept but features two additional electrical contacts, namely the Schottky contact between p-type Si bulk and Ag n-contact and the metal-insulator-semiconductor (MIS) contact on the rear side of the cell below the n-contact pads. To prevent thermal hotspots under reverse bias, both contacts shall either restrict current flow or allow a homogenous current flow at low voltage. In this work we present both options. First the stable reverse bias characteristics up to −15 V with a MIS contact using industrially manufactured SiON passivation and second, an integrated by-pass diode using AlOX as insulator in the passivation stack allowing current flows at approximately Vrev = –3.5 V depending on the chosen screen-print paste. The examined Schottky contacts break down at around Vrev = –2.5 V. Reverse bias testing of the cells reveals a solid performance of the cells under reverse bias and an average conversion efficiency of η = 21.2% (AlOX) and η = 20.7% (SiON), respectively.
金属包裹穿透+ (HIP-MWT+)太阳能电池基于PERC概念,但具有两个额外的电触点,即p型硅体和Ag - n-触点之间的Schottky触点和n-触点垫下方电池背面的金属-绝缘体-半导体(MIS)触点。为了防止反向偏置下的热热点,两个触点要么限制电流流动,要么在低电压下允许均匀电流流动。在这项工作中,我们提出了这两种选择。首先,稳定的反向偏置特性高达- 15 V,使用工业制造的SiON钝化MIS触点;其次,在钝化堆栈中使用AlOX作为绝缘体的集成旁路二极管,根据所选择的网印膏,允许电流在大约Vrev = -3.5 V流过。所检查的肖特基触点在Vrev = -2.5 V左右击穿。反偏置测试表明,电池在反偏置下性能良好,平均转化效率分别为η = 21.2% (AlOX)和η = 20.7% (SiON)。
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引用次数: 0
Detection of microcracks and dark spots in monocrystalline PERC cells using photoluminescene imaging and YOLO-based CNN with spatial pyramid pooling 利用光致发光成像和基于yolo的CNN空间金字塔池检测单晶PERC细胞中的微裂纹和黑点
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022025
Amran Binomairah, Azizi Abdullah, B. Khoo, Z. Mahdavipour, T. W. Teo, Nor Shahirah Mohd Noor, Mohd Zaid Abdullah
Two common defects encountered during manufacturing of crystalline silicon solar cells are microcrack and dark spot or dark region. The microcrack in particular is a major threat to module performance since it is responsible for most PV failures and other types of damage in the field. On the other hand, dark region in which one cell or part of the cell appears darker under UV illumination is mainly responsible for PV reduced efficiency, and eventually lost of performance. Therefore, one key challenge for solar cell manufacturers is to remove defective cells from further processing. Recently, few researchers have investigated deep learning as an alternative approach for defect detection in solar cell manufacturing. The results are quite encouraging. This paper evaluates the convolutional neural network based on heavy-weighted You Only Look Once (YOLO) version 4 or YOLOv4 and the tiny version of this algorithm referred here as Tiny-YOLOv4. Experimental results suggest that the multi-class YOLOv4 is the best model in term of mean average precision (mAP) and prediction time, averaging at 98.8% and 62.9 ms respectively. Meanwhile an improved Tiny-YOLOv4 with Spatial Pyramid Pooling scheme resulted in mAP of 91.0% and runtime of 28.2 ms. Even though the tiny-weighted YOLOv4 performs slightly lower compared to its heavy-weighted counterpart, however the runtime of the former is 2.2 order much faster than the later.
在晶硅太阳能电池的制造过程中,常见的两种缺陷是微裂纹和暗斑。微裂纹是组件性能的主要威胁,因为它是导致大多数PV故障和现场其他类型损坏的原因。另一方面,在紫外线照射下,一个或部分电池变暗的暗区是光伏效率降低,最终丧失性能的主要原因。因此,太阳能电池制造商面临的一个关键挑战是在进一步加工中去除有缺陷的电池。最近,很少有研究人员将深度学习作为太阳能电池制造中缺陷检测的替代方法。结果相当令人鼓舞。本文评估了基于权重You Only Look Once (YOLO) version 4或YOLOv4的卷积神经网络,以及该算法的微型版本tiny -YOLOv4。实验结果表明,在平均精度(mAP)和预测时间方面,多类YOLOv4是最好的模型,平均精度分别为98.8%和62.9 ms。采用空间金字塔池方案的改进Tiny-YOLOv4的mAP值为91.0%,运行时间为28.2 ms。尽管小权重的YOLOv4的性能略低于大权重的YOLOv4,但是前者的运行时间比后者快2.2个数量级。
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引用次数: 1
A fully coupled opto-electro-thermal model to investigate silicon solar cells under real operating conditions 研究硅太阳能电池在实际工作条件下的完全耦合光电热模型
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022018
Jérémy Dumoulin, E. Drouard, M. Amara
In this work, a fully coupled opto-electro-thermal model for crystalline silicon solar cells is presented. Based on a detailed set of material properties, the developed model allows us to predict and analyse the solar cell behaviour under real operating conditions in a standalone framework. The results show the potential of our model to study the influence of the cell design on its real operating performance, thus giving a new opportunity for silicon solar cell optimisation. Specifically, the doping level is found to impact both the operating temperature and the temperature coefficient, showing that two cells with the same power conversion efficiency in standard test conditions can have a very different efficiency under real operating conditions. We also demonstrate the model capability to assess in detail the influence of environmental conditions, such as the solar spectrum, which also impacts the temperature coefficient. As the latter is not required by our material-based approach but is a simulation output, this work opens the way to more reliable outdoor prediction. Moreover, the various perspectives and challenges associated with the proposed detailed multiphysics simulation of solar cells are discussed, providing important guidelines for future studies.
本文建立了晶体硅太阳能电池的全耦合光电模型。基于一组详细的材料特性,开发的模型使我们能够在独立的框架中预测和分析太阳能电池在实际操作条件下的行为。结果表明,我们的模型在研究电池设计对其实际工作性能的影响方面具有潜力,从而为硅太阳能电池的优化提供了新的机会。具体来说,我们发现掺杂水平对工作温度和温度系数都有影响,这表明在标准测试条件下具有相同功率转换效率的两个电池在实际工作条件下的效率可能相差很大。我们还证明了模型能够详细评估环境条件的影响,例如太阳光谱,这也会影响温度系数。由于后者不是我们基于材料的方法所需要的,而是模拟输出,因此这项工作为更可靠的室外预测开辟了道路。此外,还讨论了与所提出的太阳能电池详细多物理场模拟相关的各种观点和挑战,为未来的研究提供了重要的指导。
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引用次数: 0
Digitalization as a driver for supporting PV deployment and cost reduction 数字化是支持光伏部署和降低成本的驱动因素
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2021013
E. Saretta, P. Bonomo, Willy Maeder, V. K. Nguyen, F. Frontini
Digitalization is providing advantages to all sectors around the world and it can be of relevance also for the photovoltaic (PV) sector. As an example, the current value chain of the European PV sector is often characterized by analogue and fragmented processes that should be overcame to support greater PV deployment. The adoption of a more open and collaborative digital-based approach characterized by data-sharing among different stakeholders and more integrated information thread from the design till O&M can provide direct benefits in optimizing the PV process, increasing performances, and reducing of costs. Therefore, a novel PV Information Management (PIM) approach has been drawn within the European H2020 project “SuperPV”. In accordance with PIM objectives, a workflow for seamlessly transferring data along main PV work-stages has been developed, as well as new digital features to specifically address collaborative approach in the PV sector such as: (i) advanced functionalities introduced in the existing BIMSolar® software for improving the simultaneous design, performance simulation and cost assessment of medium and large PV systems, (ii) a proof-of-concept for aggregating all relevant information into a Digital Twin platform aimed at setting the ground for post-construction management and lifecycle assessment of the whole PV system.
数字化正在为世界各地的所有行业提供优势,它也可以与光伏(PV)行业相关。例如,目前欧洲光伏行业的价值链通常以模拟和分散的过程为特征,应该克服这些过程以支持更大的光伏部署。采用更加开放和协作的基于数字的方法,其特点是不同利益相关者之间的数据共享,以及从设计到运维的更集成的信息线程,可以为优化光伏工艺、提高性能和降低成本提供直接好处。因此,在欧洲H2020项目“超级光伏”中提出了一种新的光伏信息管理(PIM)方法。根据PIM的目标,已经开发了一个在主要光伏工作阶段无缝传输数据的工作流程,以及专门解决光伏行业协作方法的新数字功能,例如:(i)现有BIMSolar®软件中引入的先进功能,用于改进大中型光伏系统的同步设计、性能模拟和成本评估;(ii)将所有相关信息聚合到数字孪生平台中的概念验证,旨在为整个光伏系统的施工后管理和生命周期评估奠定基础。
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引用次数: 4
DLTS investigations on CIGS solar cells from an inline co-evaporation system with RbF post-deposition treatment 基于RbF后沉积处理的在线共蒸发系统对CIGS太阳能电池的DLTS研究
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022003
Tim Helder, A. Kanevce, A. Bauer, Mario Zinßer, S. Paetel, T. Friedlmeier, M. Powalla
In this study, Deep Level Transient Spectroscopy (DLTS) measurements have been performed on Cu(In,Ga)Se2 (CIGS) solar cells from an inline co-evaporation system. The focus of this investigation is directed on the effect of rubidium-fluoride (RbF)-post-deposition treatment (PDT) on the defects in the CIGS absorber layer. Different traps can be identified and their properties are calculated. Herein, different methods of evaluations have been used to verify the results. Specifically, one minority trap around 400 meV was found to show a significant reduction of the trap density due to the alkali treatment. In contrast, a majority trap at approximately 600 meV is unaffected.
在这项研究中,对Cu(In,Ga)Se2 (CIGS)太阳能电池进行了深能级瞬态光谱(DLTS)测量。研究了氟化铷(RbF)沉积后处理(PDT)对CIGS吸收层缺陷的影响。可以识别不同的圈闭并计算其性质。本文采用了不同的评价方法来验证结果。具体来说,发现一个400 meV左右的少数陷阱由于碱处理而显着降低了陷阱密度。相比之下,大约600 meV的多数阱不受影响。
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引用次数: 4
Fluorination and chlorination effects on the charge transport properties of the IDIC non-fullerene acceptor: an ab-initio investigation 氟化和氯化对IDIC非富勒烯受体电荷输运性质的影响:从头算研究
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022012
M. Andrea, Konstantinos Kordos, E. Lidorikis, Dimitrios P. Papageorgiou
Fused-ring electron acceptors end-capped with electron withdrawing groups have contributed to the ever-increasing power conversion efficiency of organic solar cells. Adding π-extensions and halogenating the end groups are two popular strategies to boost performance even further. In this work, a typical non-fullerene acceptor molecule, IDIC, is used as a model system for investigating the impact of the halogenation approach at the molecular level. The two end groups are substituted by fluorinated and chlorinated counterparts and their electronic and optical properties are systematically probed using ab-initio calculations. In gas phase, halogenation lowers the HOMO and LUMO energy levels and narrows the energy gap, especially for the chlorinated compound. Moreover, chlorinated IDIC exhibits the largest redshift and the smallest reorganization energy. Finally, crystal structures of the three compounds are constructed, revealing an improved transfer integral and transfer rate for the halogenated variants. Specifically, the chlorination strategy leads to an increase of 60% in transfer rate, compared to halogen-free IDIC.
端部有吸电子基团的熔环电子受体对有机太阳能电池不断提高的功率转换效率做出了贡献。添加π扩展和端基卤化是进一步提高性能的两种常用策略。在这项工作中,一个典型的非富勒烯受体分子IDIC被用作一个模型系统,在分子水平上研究卤化方法的影响。两个端基被氟化和氯化基团取代,它们的电子和光学性质用从头算系统地探讨。在气相中,卤代化降低了HOMO和LUMO能级,缩小了能隙,尤其是氯代化合物。氯化的IDIC表现出最大的红移和最小的重组能。最后,构建了这三种化合物的晶体结构,揭示了卤化变体的转移积分和转移速率的提高。具体来说,与无卤IDIC相比,氯化策略导致转移率提高了60%。
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引用次数: 0
Quantifying the performance gain of 100 cm2 bifacial four terminal perovskite-Si tandem modules 量化100cm2双面四端钙钛矿-硅串联模块的性能增益
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022006
P. Manshanden, G. Coletti, Victor Rosca, M. Jansen, Koen de Groot, Gertjan J. de Graaff, M. Creatore, L. Šimurka, M. Najafi, V. Zardetto, Ilkar Dogan, H. Fledderus, S. Veenstra
Improving the performance of solar modules requires the implementation of both spectral and directional irradiance optimization. The performance of bifacial four-terminal tandem minimodules with a 100 cm2 area is reported, both indoor and outdoor measurements. We demonstrate a 24.5 mW/cm2 (bifacial irradiance 200 W/m2) bifacial tandem power density, measured according to a tandem adapted IEC60904-1-2 protocol, which constitutes a 3 mW/cm2 gain with respect to monofacial use. In addition, we show that in outdoor measurements bifacial four terminal tandems outperform identical monofacial four terminal tandems by 26% on average, depending on incident angle, injection level and temperature, in a 10% albedo environment. The average gain is higher for outdoor performance than for indoor performance, due to variations in relative rear irradiance.
提高太阳能组件的性能需要实现光谱和定向辐照度的优化。报道了面积为100 cm2的双面四端串联微型模块的室内和室外测量性能。我们展示了24.5 mW/cm2(双面辐照度200 W/m2)双面串联功率密度,根据串联适应的IEC60904-1-2协议进行测量,相对于单面使用,它构成了3 mW/cm2的增益。此外,在室外测量中,在10%反照率的环境中,根据入射角、注入水平和温度的不同,双面四端串联比相同的单面四端串联平均高出26%。由于相对后方辐照度的变化,室外性能的平均增益高于室内性能。
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引用次数: 0
Impact of handling defects towards SHJ cell parameters 处理缺陷对SHJ电池参数的影响
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022009
A. Fischer, I. V. Vulcanean, S. Pingel, A. Moldovan, J. Rentsch
Within this paper, a systematic approach will be presented to specify the influence of defects caused by vacuum grippers onto silicon heterojunction solar cell parameters. The study focuses on the comparison between handling-induced defects originating from handling on the emitter or non-emitter side, and the comparison of handling-induced defects originating from handling before and after plasma enhanced chemical vapor deposition. The analysis was carried out by means of J–V measurements on manufactured silicon heterojunction solar cells and by means of suns photoluminescence imaging measurements on solar cell precursors. It is shown that local insufficient passivated regions caused by handling before passivation not only cause a local electrical defect at the point of handling, but also affect a large area around the insufficient passivated region. This had a significant negative effect on fill factor, short-circuit current, open circuit voltage and efficiency, which was found to be more severe for wafers handled on the non-emitter side.
在本文中,将提出一种系统的方法来确定真空夹具引起的缺陷对硅异质结太阳能电池参数的影响。研究重点比较了在发射极侧和非发射极侧处理产生的处理缺陷,以及等离子体增强化学气相沉积前后处理产生的处理缺陷。通过对人造硅异质结太阳能电池的J-V测量和对太阳能电池前驱体的太阳光致发光成像测量进行了分析。结果表明,钝化前处理造成的局部钝化不足区域,不仅会在处理点造成局部电缺陷,而且会影响到钝化不足区域周围的大面积区域。这对填充系数、短路电流、开路电压和效率有显著的负面影响,对于在非发射极侧处理的晶圆来说,这种影响更为严重。
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引用次数: 1
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EPJ Photovoltaics
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