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A self-consistent hybrid model connects empirical and optical models for fast, non-destructive inline characterization of thin, porous silicon layers 一个自一致的混合模型连接经验和光学模型快速,非破坏性的在线表征薄,多孔硅层
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2022035
Alexandra Wörnhör, M. Demant, H. Vahlman, S. Rein
Epitaxially-grown wafers on top of sintered porous silicon are a material-efficient wafer production process, that is now being launched into mass production. This production process makes the material-expensive sawing procedure obsolete since the wafer can be easily detached from its seed substrate. With high-throughput inline production processes, fast and reliable evaluation processes are crucial. The quality of the porous layers plays an important role regarding a successful detachment. Therefore, we present a fast and non-destructive investigation algorithm of thin, porous silicon layers. We predict the layer parameters directly from inline reflectance data by using a convolutional neural network (CNN), which is inspired by a comprehensive optical modelling approach from literature. There, a numerical fitting approach on reflection curves calculated with a physical model is performed. By adding the physical model to the CNN, we create a hybrid model, that not only predicts layer parameters, but also recalculates reflection curves. This allows a consistency check for a self-supervised network optimization. Evaluation on experimental data shows a high similarity with Scanning Electron Microscopy (SEM) measurements. Since parallel computation is possible with the CNN, 30.000 samples can be evaluated in roughly 100 ms.
在烧结多孔硅上外延生长晶圆是一种材料高效的晶圆生产工艺,目前正投入大规模生产。这种生产过程使得材料昂贵的锯切过程过时,因为晶圆片可以很容易地从它的种子基板上分离出来。在高通量的在线生产过程中,快速可靠的评估过程至关重要。多孔层的质量对成功剥离起着重要的作用。因此,我们提出了一种快速、无损的薄多孔硅层检测算法。我们使用卷积神经网络(CNN)直接从内联反射率数据预测层参数,这是受到文献中综合光学建模方法的启发。在此基础上,对物理模型计算的反射曲线进行了数值拟合。通过将物理模型添加到CNN中,我们创建了一个混合模型,该模型不仅可以预测层参数,还可以重新计算反射曲线。这允许对自监督网络优化进行一致性检查。实验数据与扫描电子显微镜(SEM)测量结果高度相似。由于CNN可以进行并行计算,因此可以在大约100毫秒内评估30,000个样本。
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引用次数: 1
Edge passivation of shingled poly-Si/SiOx passivated contacts solar cells 铺瓦式多晶硅/氧化硅钝化接触太阳能电池的边缘钝化
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023013
F. Dhainaut, R. Dabadie, B. Martel, T. Desrues, M. Albaric, O. Palais, S. Dubois, S. Harrison
This work aims at the full recovery of efficiency losses induced by shingling double-side poly-Si/SiOx passivated contacts crystalline silicon solar cells. It focuses on thermally-activated Aluminium Oxide (AlOx) layers elaborated by thermal Atomic Layer Deposition (ALD) to passivate the edges of shingled cells cut by using the innovative “45° tilt squaring approach”. The whole procedure featuring high-temperature AlOx annealing led to very low cut-related performance losses. Indeed, the efficiency and FF of the passivated shingled cells surpassed the values obtained for the as-cut shingles by 0.5%abs and 2.6%abs, respectively. Approaches for further improvements are also discussed, particularly to overcome the short-circuit current density decrease observed for passivated shingles.
本研究的目的是为了完全恢复双面多晶硅/SiOx钝化触点晶体硅太阳能电池的效率损失。它专注于通过热原子层沉积(ALD)制作的热活化氧化铝(AlOx)层,通过创新的“45°倾斜方形方法”钝化瓦片电池的边缘。整个过程采用高温AlOx退火,导致非常低的切割相关性能损失。事实上,钝化的带状带状电池的效率和FF分别比未切割的带状带状电池高出0.5%和2.6%。还讨论了进一步改进的方法,特别是克服钝化瓦所观察到的短路电流密度下降。
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引用次数: 0
Insights into circular material and waste flows from c-Si PV industry c-Si光伏产业的循环材料和废物流洞察
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2022029
Peter Brailovsky, Kerstin Baumann, M. Held, A. Briem, K. Wambach, Estelle Gervais, Sina Herceg, Boris Mertvoy, S. Nold, J. Rentsch
A material flow model for the production of Bifacial Selective Emitter 60-cell p-type Cz PERC (Passivated Emitter and Rear Contacted) glass-backsheet modules with aluminium frame was built. The selected module represents mature technologies in the PV industry and their manufacturing is considered to take place in China in a production cluster with an annual module capacity of 5 GWp. In a first step, data acquisition and validation for wafer, cell and module fabs took place. The data were used to generate the reference system lifecycle inventories (LCI) and extended waste databases for the reference wafers, cells and modules. A set of potential circularity actions, such as the vertical integration of the operations and waste revalorisation strategies, had been proposed and their environmental performance and cost assessed by means of a life cycle assessment (LCA) and a total cost of ownership (TCO). Our results show that 87% of the waste can be reduced and revalorised, this represents a circular flow of raw materials of 18,756 Mg per year from a 5GWp PV module production cluster. Environmental impact reductions of 0.6–2.3% are estimated for different impact categories. We also estimate a cost reduction potential of 2.59% from total module costs.
建立了铝框架双面选择性发射极60电池p型Cz PERC(钝化发射极和后接触)玻璃背板模块的物料流模型。所选组件代表了光伏行业的成熟技术,其生产被认为是在中国的生产集群中进行的,年组件产能为5gwp。在第一步,数据采集和验证晶圆,电池和模块晶圆厂进行。这些数据用于生成参考系统生命周期清单(LCI)和参考晶圆、电池和模块的扩展废物数据库。提出了一套潜在的循环行动,例如业务的垂直整合和废物再估值战略,并通过生命周期评估(LCA)和总拥有成本(TCO)对其环境绩效和成本进行了评估。我们的研究结果表明,87%的废物可以减少并重新利用,这代表了一个5GWp光伏组件生产集群每年18756毫克的原材料循环流动。根据不同的影响类别,估计可减少0.6-2.3%的环境影响。我们还估计从总模块成本中降低2.59%的成本潜力。
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引用次数: 1
Laser-based monolithic series interconnection of two-terminal perovskite-CIGSe tandem solar cells: determination of the optimal scribe line properties 基于激光的双端钙钛矿- cigse串联太阳能电池的单片串联互连:最佳划线性能的测定
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023007
C. Schultz, G. F. Farias Basulto, Nicolas Otto, J. Dagar, A. Bartelt, R. Schlatmann, Eva Unger, B. Stegemann
To achieve a monolithic series interconnection of tandem solar cell devices consisting of a perovskite top cell and a CIGSe bottom cell, a two-terminal interconnection scheme is introduced that includes an additional, fourth patterning step, the so-called iso-cut, which separates the window layer stack between the two solar cells. The implementation of this interconnection scheme requires a process development for a total of four structuring steps, which was achieved by systematically varying the laser parameters. Based on a detailed characterization of the individual scribe line properties with respect to their scribe line depth, morphology, electrical functionality, chemical composition and their influence on adjacent and underlying layers, the optimal patterning parameters and suitable process windows were derived for each step, which is a prerequisite for a loss-free monolithic series interconnection in a tandem module.
为了实现由钙钛矿顶部电池和CIGSe底部电池组成的串联太阳能电池器件的单片串联互连,引入了一种双端互连方案,该方案包括额外的第四个图像化步骤,即所谓的等切,它将两个太阳能电池之间的窗口层堆栈分开。这种互连方案的实现需要一个总共四个结构步骤的工艺开发,这是通过系统地改变激光参数来实现的。基于对单个划线线深度、形态、电气功能、化学成分及其对相邻层和下层的影响的详细表征,推导出每个步骤的最佳图案参数和合适的工艺窗口,这是在串联模块中实现无损耗单片串联互连的先决条件。
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引用次数: 0
How cool is floating PV? A state-of-the-art review of floating PV's potential gain and computational fluid dynamics modeling to find its root cause 浮动PV有多酷?浮式光伏的潜在增益和计算流体动力学建模的最新进展,以找到其根本原因
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023015
Gofran Chowdhury, M. Haggag, J. Poortmans
The noticeable rise in electricity demand, environmental concerns, and the intense land burden has led to installing PV systems on water bodies to create floating photovoltaic (FPV). Of all market niches, FPV is the one developing the fastest. Along with some of its well-documented merits comes a claim that FPV modules operate at a lower temperature than their ground-mounted counterparts (GPVs). This claim is essential due to the performance loss of PV modules at high operating temperatures. Some literature claims that FPVs are so well-cooled that they maintain around 10% higher efficiencies. However, this cooling is poorly quantified, and the root cause remains unclear in the industry. In this paper, an extensive review of all the latest published literature and white paper advertisements was analyzed. The gains in energy yield coming from different root causes range from 0.11% to 31.29%! This proves the point of lack of clarity of potential gain of FPV. The paper then analyses four possible explanations for this cooling effect and its root causes. The FPV performance parameters are isolated and systematically investigated through physics-based finite element modeling. The impacts of wind velocity, wind direction, water temperature, relative humidity, air temperature, proximity to water, tilt angle, and others are evaluated and explained. The outcomes dictate that FPV is cooled largely through wind convection. But the increase in efficiency is below the anticipated values, ranging from 0.5% to 3%.
电力需求的显著增长、环境问题和土地负担的增加,导致在水体上安装光伏系统,以制造浮动光伏(FPV)。在所有细分市场中,FPV是发展最快的一个。除了一些有充分证据证明的优点外,还有一种说法,即FPV模块的工作温度比地面安装的同类组件(gpv)要低。由于光伏组件在高温下的性能损失,这一主张是必不可少的。一些文献声称,fpv的冷却效果非常好,可以使效率提高10%左右。然而,这种降温的量化很差,其根本原因在业内仍不清楚。在本文中,广泛回顾了所有最新发表的文献和白皮书广告进行了分析。来自不同根本原因的能源产量收益从0.11%到31.29%不等!这证明了FPV的潜在增益不够清晰。然后,本文分析了这种降温效应的四种可能解释及其根本原因。通过基于物理的有限元建模,分离和系统地研究了FPV的性能参数。对风速、风向、水温、相对湿度、空气温度、靠近水、倾斜角度等因素的影响进行了评估和解释。结果表明,FPV主要通过风对流冷却。但是,效率的提高低于预期值,从0.5%到3%不等。
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引用次数: 1
Power dense thermophotovoltaic cells 功率密集的热光伏电池
Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023019
Alexander P. Kirk
Class-leading 2-junction (2J) thermophotovoltaic (TPV) cells have been developed with thermophotovoltaic efficiency exceeding 40%. However, these devices have sub-optimal power density because the subcell bandgaps are not matched to the emitter spectrum. Although efficiency is important, power density is also an important metric to gauge TPV cell performance; the greater the power density, the less total area of TPV cells that are needed to satisfy a given power generation target. To quantify the relevance of power density, spectrum-matched 1.04/0.78/0.62/0.48/0.36 eV 5-junction (5J) TPV cells have the potential to be 3.5 times more power dense than state-of-the-art, yet spectrum-mismatched, 1.4/1.2 eV 2J TPV cells when irradiated by a 2400 °C emitter. The proposed 5J TPV cells also have the potential to exceed 40% standard power conversion efficiency.
领先的2结(2J)热光伏(TPV)电池已经开发出来,热光伏效率超过40%。然而,由于子单元带隙与发射频谱不匹配,这些器件具有次优功率密度。虽然效率很重要,但功率密度也是衡量冠脉光伏电池性能的重要指标;功率密度越大,满足给定发电目标所需的TPV电池总面积就越小。为了量化功率密度的相关性,光谱匹配的1.04/0.78/0.62/0.48/0.36 eV 5结(5J) TPV电池在2400°C发射器照射时,其功率密度可能是目前最先进的功率密度的3.5倍,但光谱不匹配的1.4/1.2 eV 2J TPV电池。提出的5J TPV电池也有可能超过40%的标准功率转换效率。
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引用次数: 0
Benchmark of eight commercial solutions for deterministic intra-day solar forecast 确定日内太阳预报的八个商业解决方案的基准
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023006
J. Lehmann, Christian Koessler, Lina Ruiz Gomez, Stijn Scheerlinck
Continuous increase of the production of photovoltaic energy requires precise forecasting to ensure grid stability. This paper presents a detailed benchmark of eight commercial forecasting solutions for intra-day solar forecasts. The comparison was carried out on a period of six months, from November to May 2021, on seven different PV plants located in different countries of the northern hemisphere. Performance evaluation metrics MAE, RMSE and MBE are used in order to analyze the forecasting precision. It is shown that forecasting solar power remains challenging, as shown by the important dispersion between the actors that we have observed.
光伏发电量的持续增长需要精确的预测来保证电网的稳定。本文介绍了八种日间太阳预报商业方案的详细基准。从2021年11月到5月,对位于北半球不同国家的七个不同的光伏电站进行了为期六个月的比较。运用MAE、RMSE和MBE等绩效评价指标对预测精度进行分析。研究表明,预测太阳能发电仍然具有挑战性,正如我们所观察到的因素之间的重要分散所表明的那样。
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引用次数: 0
Long-term PV system modelling and degradation using neural networks 使用神经网络的长期光伏系统建模和退化
Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023018
Gerardo Guerra, Pau Mercade-Ruiz, Gaetana Anamiati, Lars Landberg
The power production of photovoltaic plants can be affected throughout its operational lifetime by multiple losses and degradation mechanisms. Although long-term degradation has been widely studied, most methodologies assume a specific degradation behaviour and require detailed metadata. This paper presents a methodology for the calculation of long-term degradation of a photovoltaic plant based on neural networks. The goal of the neural network is to model the photovoltaic plant's power production as a function of environmental conditions and time elapsed since the plant started operating. A big advantage of this method with respect to others is that it is completely data-driven, requires no additional information, and makes no assumptions related to degradation behaviour. Results show that the model can derive a long-term degradation trend without overfitting to shorter-term effects or abrupt changes in year-to-year operation.
光伏电站在其整个运行寿命期内会受到多种损耗和退化机制的影响。虽然长期退化已被广泛研究,但大多数方法都假定有特定的退化行为,并且需要详细的元数据。提出了一种基于神经网络的光伏电站长期退化计算方法。神经网络的目标是将光伏电站的发电量建模为环境条件和电站开始运行后经过的时间的函数。与其他方法相比,这种方法的一大优点是它完全是数据驱动的,不需要额外的信息,也不做与退化行为相关的假设。结果表明,该模型可以得出长期的退化趋势,而不会过度拟合短期效应或年际运行的突变。
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引用次数: 0
Investigation of III-V GaP solar cell on silicon substrate 硅衬底III-V型GaP太阳能电池的研究
Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023020
Soline Boyer-Richard, Fei Fan, Alexandre Beck, Christophe Levallois, Karine Tavernier, Tony Rohel, Rozenn Bernard, Antoine Létoublon, Charles Cornet, Olivier Durand
The best solar conversion efficiencies have been reached thanks to multijunction solar based on III-V semiconductors on GaAs or Ge substrates. While displaying high conversion efficiencies, these solar cells suffer from the high cost of such substrates. To benefit from both the low cost and technological maturity of silicon cells, III-V tandem cells on silicon seem a good compromise to overpass the theoretical efficiency limit of the Si single cells. To study the GaP/Si interface effect on the solar cell characteristic, a GaP n-i-p solar cell has been grown on silicon substrate. Two types of electrical contacts configurations have been processed: a top-top configuration in which the current does not see the GaP/Si interface and the top-bottom configuration where the electric current crosses the interface. A comparison of dark I-V, I-V under solar illumination, and EQE measurements on both configurations is performed. The top-bottom contacts configuration shows an EQE a little bit lower than the top-top contact one, likely due to lower carrier diffusion length or recombination at the lower interface. However, the result on the EQE of the top-bottom configuration is encouraging for the future development of the GaP-based/Si tandem solar cells, and any other tandem cell on silicon using GaP as an intermediate selective contact.
由于基于GaAs或Ge衬底的III-V半导体的多结太阳能已经达到了最佳的太阳能转换效率。在显示高转换效率的同时,这些太阳能电池受到这种基板的高成本的影响。为了从硅电池的低成本和技术成熟度中获益,硅上的III-V串联电池似乎是一个很好的妥协,以超越硅单电池的理论效率极限。为了研究GaP/Si界面对太阳电池特性的影响,在硅衬底上生长了一种GaP n-i-p太阳电池。已经处理了两种类型的电触点配置:一种是自上而下的配置,其中电流看不到GaP/Si接口,另一种是自上而下的配置,其中电流穿过接口。比较了暗I-V,太阳照射下的I-V,以及两种配置下的EQE测量结果。上下触点结构的EQE略低于上下触点结构,这可能是由于载流子扩散长度较短或下界面处的复合所致。然而,自上而下结构的EQE结果对于基于GaP的/Si串联太阳能电池的未来发展,以及使用GaP作为中间选择性接触的硅上的任何其他串联电池都是令人鼓舞的。
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引用次数: 0
Simulation of the irradiance and yield calculation of bifacial PV systems in the USA and Germany by combining ray tracing and view factor model 结合光线追踪和视场因子模型对美国和德国双面光伏系统的辐照度和产率进行模拟
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023003
Eva-Maria Grommes, Felix Schemann, Frederik Klag, Sebastian Nows, U. Blieske
Compared to conventional photovoltaic (PV), there are more influencing factors in bifacial photovoltaics to be considered to calculate incoming irradiance and energy yield. Accurate models to investigate the influences of the elevation, the albedo of the ground, the shading conditions between the PV rows and many other rear-side related factors are required. This paper combines the ray tracing (RT) and view factor (VF) models to calculate the irradiance with a subsequent electrical yield calculation using the one-diode model. To verify the results of the developed open-source simulation program BifacialSimu, accurate data from a plant in Golden, USA (single-axis tracked) and a commercially operated plant in Germany (fixed-tilt) are used. Through comparisons to the actual data, it can be concluded that a combination of RT and VF models seems to be valid for longer simulation periods with several months since the relative errors balance out. The RT-only simulation accurately reproduces the precise hourly radiation and electrical yield pattern. Still, a continuous positive deviation was found, which does not even out over long periods and is thus less accurate than the VF/RT combination. A simulation for a single month with RT can take several hours. Thus, the best simulation mode results according to user requirements.
与传统光伏(PV)相比,双面光伏在计算入射辐照度和产能时需要考虑更多的影响因素。需要精确的模型来研究海拔、地面反照率、PV排之间的遮阳条件和许多其他后方相关因素的影响。本文结合射线追踪(RT)和视场因子(VF)模型来计算辐照度,并使用单二极管模型计算随后的电产率。为了验证开发的开源模拟程序BifacialSimu的结果,使用了来自美国Golden工厂(单轴跟踪)和德国商业运营工厂(固定倾斜)的准确数据。通过与实际数据的比较,可以得出结论,RT和VF模型的组合在较长的模拟周期内似乎是有效的,因为相对误差抵消了几个月。RT-only模拟准确地再现了精确的每小时辐射和电产出模式。尽管如此,仍然发现了一个连续的正偏差,在很长一段时间内不均匀,因此不如VF/RT组合准确。使用RT进行一个月的模拟可能需要几个小时。因此,最佳的仿真模式结果可根据用户要求而定。
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引用次数: 1
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EPJ Photovoltaics
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