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Impact of the contacting scheme on I-V measurements of metallization-free silicon heterojunction solar cells 接触方式对无金属化硅异质结太阳能电池I-V测量的影响
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023009
Malte Brinkmann, F. Haase, K. Bothe, K. Bittkau, A. Lambertz, Weiyuan Duan, K. Ding, Hans-Peter Sperlich, A. Waltinger, H. Schulte‐Huxel
I‑V measurements are sensitive to the number and positioning of current and voltage sensing contacts. For busbarless solar cells, measurement setups have been developed using current collection wires and separate voltage sense contacts. Placing the latter at a defined position enables a grid resistance neglecting measurement and thus I‑V characteristics independent from the contacting system. This technique has been developed for solar cells having a finger grid and good conductivity in the direction of the fingers. The optimal position of the sense contact in case of finger-free silicon heterojunction solar cells has not yet been studied. Here, the lateral charge carrier transport occurs in a transparent conductive oxide layer resulting in a higher lateral resistance. We perform finite difference method simulations of HJT solar cells without front metallization to investigate the impact of high lateral resistances on the I-V measurement of solar cells. We show the high sensitivity on the number of used wires for contacting as well as the position of the sense contact for the voltage measurement. Using the simulations, we are able to explain the high difference of up to 7.5% in fill factor measurements of metal free solar cells with varying TCO sheet resistances between two measurement systems using different contacting setups. We propose a method to compensate for the contacting system to achieve a grid-resistance neglecting measurement with both systems allowing a reduction of the FF difference to below 1.5%.
I - V测量对电流和电压感应触点的数量和位置很敏感。对于无母线太阳能电池,已经开发了使用电流收集线和单独电压检测触点的测量装置。将后者放置在定义的位置,可以忽略测量栅格电阻,从而独立于接触系统的I - V特性。这项技术已经发展为具有手指网格和在手指方向上具有良好导电性的太阳能电池。在无指硅异质结太阳能电池中,感应接触的最佳位置尚未得到研究。在这里,横向电荷载流子传输发生在透明导电氧化层中,导致更高的横向电阻。本文采用有限差分方法模拟了未正面金属化的HJT太阳能电池,以研究高横向电阻对太阳能电池I-V测量的影响。我们展示了用于接触的电线数量的高灵敏度以及用于电压测量的感测触点的位置。通过模拟,我们能够解释在使用不同接触设置的两种测量系统之间,具有不同TCO片电阻的无金属太阳能电池的填充因子测量值高达7.5%的高差异。我们提出了一种补偿接触系统的方法,以实现两个系统的网格电阻忽略测量,从而将FF差降低到1.5%以下。
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引用次数: 0
Edge passivation of shingled poly-Si/SiOx passivated contacts solar cells 铺瓦式多晶硅/氧化硅钝化接触太阳能电池的边缘钝化
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023013
F. Dhainaut, R. Dabadie, B. Martel, T. Desrues, M. Albaric, O. Palais, S. Dubois, S. Harrison
This work aims at the full recovery of efficiency losses induced by shingling double-side poly-Si/SiOx passivated contacts crystalline silicon solar cells. It focuses on thermally-activated Aluminium Oxide (AlOx) layers elaborated by thermal Atomic Layer Deposition (ALD) to passivate the edges of shingled cells cut by using the innovative “45° tilt squaring approach”. The whole procedure featuring high-temperature AlOx annealing led to very low cut-related performance losses. Indeed, the efficiency and FF of the passivated shingled cells surpassed the values obtained for the as-cut shingles by 0.5%abs and 2.6%abs, respectively. Approaches for further improvements are also discussed, particularly to overcome the short-circuit current density decrease observed for passivated shingles.
本研究的目的是为了完全恢复双面多晶硅/SiOx钝化触点晶体硅太阳能电池的效率损失。它专注于通过热原子层沉积(ALD)制作的热活化氧化铝(AlOx)层,通过创新的“45°倾斜方形方法”钝化瓦片电池的边缘。整个过程采用高温AlOx退火,导致非常低的切割相关性能损失。事实上,钝化的带状带状电池的效率和FF分别比未切割的带状带状电池高出0.5%和2.6%。还讨论了进一步改进的方法,特别是克服钝化瓦所观察到的短路电流密度下降。
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引用次数: 0
Insights into circular material and waste flows from c-Si PV industry c-Si光伏产业的循环材料和废物流洞察
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2022029
Peter Brailovsky, Kerstin Baumann, M. Held, A. Briem, K. Wambach, Estelle Gervais, Sina Herceg, Boris Mertvoy, S. Nold, J. Rentsch
A material flow model for the production of Bifacial Selective Emitter 60-cell p-type Cz PERC (Passivated Emitter and Rear Contacted) glass-backsheet modules with aluminium frame was built. The selected module represents mature technologies in the PV industry and their manufacturing is considered to take place in China in a production cluster with an annual module capacity of 5 GWp. In a first step, data acquisition and validation for wafer, cell and module fabs took place. The data were used to generate the reference system lifecycle inventories (LCI) and extended waste databases for the reference wafers, cells and modules. A set of potential circularity actions, such as the vertical integration of the operations and waste revalorisation strategies, had been proposed and their environmental performance and cost assessed by means of a life cycle assessment (LCA) and a total cost of ownership (TCO). Our results show that 87% of the waste can be reduced and revalorised, this represents a circular flow of raw materials of 18,756 Mg per year from a 5GWp PV module production cluster. Environmental impact reductions of 0.6–2.3% are estimated for different impact categories. We also estimate a cost reduction potential of 2.59% from total module costs.
建立了铝框架双面选择性发射极60电池p型Cz PERC(钝化发射极和后接触)玻璃背板模块的物料流模型。所选组件代表了光伏行业的成熟技术,其生产被认为是在中国的生产集群中进行的,年组件产能为5gwp。在第一步,数据采集和验证晶圆,电池和模块晶圆厂进行。这些数据用于生成参考系统生命周期清单(LCI)和参考晶圆、电池和模块的扩展废物数据库。提出了一套潜在的循环行动,例如业务的垂直整合和废物再估值战略,并通过生命周期评估(LCA)和总拥有成本(TCO)对其环境绩效和成本进行了评估。我们的研究结果表明,87%的废物可以减少并重新利用,这代表了一个5GWp光伏组件生产集群每年18756毫克的原材料循环流动。根据不同的影响类别,估计可减少0.6-2.3%的环境影响。我们还估计从总模块成本中降低2.59%的成本潜力。
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引用次数: 1
Laser-based monolithic series interconnection of two-terminal perovskite-CIGSe tandem solar cells: determination of the optimal scribe line properties 基于激光的双端钙钛矿- cigse串联太阳能电池的单片串联互连:最佳划线性能的测定
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023007
C. Schultz, G. F. Farias Basulto, Nicolas Otto, J. Dagar, A. Bartelt, R. Schlatmann, Eva Unger, B. Stegemann
To achieve a monolithic series interconnection of tandem solar cell devices consisting of a perovskite top cell and a CIGSe bottom cell, a two-terminal interconnection scheme is introduced that includes an additional, fourth patterning step, the so-called iso-cut, which separates the window layer stack between the two solar cells. The implementation of this interconnection scheme requires a process development for a total of four structuring steps, which was achieved by systematically varying the laser parameters. Based on a detailed characterization of the individual scribe line properties with respect to their scribe line depth, morphology, electrical functionality, chemical composition and their influence on adjacent and underlying layers, the optimal patterning parameters and suitable process windows were derived for each step, which is a prerequisite for a loss-free monolithic series interconnection in a tandem module.
为了实现由钙钛矿顶部电池和CIGSe底部电池组成的串联太阳能电池器件的单片串联互连,引入了一种双端互连方案,该方案包括额外的第四个图像化步骤,即所谓的等切,它将两个太阳能电池之间的窗口层堆栈分开。这种互连方案的实现需要一个总共四个结构步骤的工艺开发,这是通过系统地改变激光参数来实现的。基于对单个划线线深度、形态、电气功能、化学成分及其对相邻层和下层的影响的详细表征,推导出每个步骤的最佳图案参数和合适的工艺窗口,这是在串联模块中实现无损耗单片串联互连的先决条件。
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引用次数: 0
How cool is floating PV? A state-of-the-art review of floating PV's potential gain and computational fluid dynamics modeling to find its root cause 浮动PV有多酷?浮式光伏的潜在增益和计算流体动力学建模的最新进展,以找到其根本原因
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023015
Gofran Chowdhury, M. Haggag, J. Poortmans
The noticeable rise in electricity demand, environmental concerns, and the intense land burden has led to installing PV systems on water bodies to create floating photovoltaic (FPV). Of all market niches, FPV is the one developing the fastest. Along with some of its well-documented merits comes a claim that FPV modules operate at a lower temperature than their ground-mounted counterparts (GPVs). This claim is essential due to the performance loss of PV modules at high operating temperatures. Some literature claims that FPVs are so well-cooled that they maintain around 10% higher efficiencies. However, this cooling is poorly quantified, and the root cause remains unclear in the industry. In this paper, an extensive review of all the latest published literature and white paper advertisements was analyzed. The gains in energy yield coming from different root causes range from 0.11% to 31.29%! This proves the point of lack of clarity of potential gain of FPV. The paper then analyses four possible explanations for this cooling effect and its root causes. The FPV performance parameters are isolated and systematically investigated through physics-based finite element modeling. The impacts of wind velocity, wind direction, water temperature, relative humidity, air temperature, proximity to water, tilt angle, and others are evaluated and explained. The outcomes dictate that FPV is cooled largely through wind convection. But the increase in efficiency is below the anticipated values, ranging from 0.5% to 3%.
电力需求的显著增长、环境问题和土地负担的增加,导致在水体上安装光伏系统,以制造浮动光伏(FPV)。在所有细分市场中,FPV是发展最快的一个。除了一些有充分证据证明的优点外,还有一种说法,即FPV模块的工作温度比地面安装的同类组件(gpv)要低。由于光伏组件在高温下的性能损失,这一主张是必不可少的。一些文献声称,fpv的冷却效果非常好,可以使效率提高10%左右。然而,这种降温的量化很差,其根本原因在业内仍不清楚。在本文中,广泛回顾了所有最新发表的文献和白皮书广告进行了分析。来自不同根本原因的能源产量收益从0.11%到31.29%不等!这证明了FPV的潜在增益不够清晰。然后,本文分析了这种降温效应的四种可能解释及其根本原因。通过基于物理的有限元建模,分离和系统地研究了FPV的性能参数。对风速、风向、水温、相对湿度、空气温度、靠近水、倾斜角度等因素的影响进行了评估和解释。结果表明,FPV主要通过风对流冷却。但是,效率的提高低于预期值,从0.5%到3%不等。
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引用次数: 1
Power dense thermophotovoltaic cells 功率密集的热光伏电池
Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023019
Alexander P. Kirk
Class-leading 2-junction (2J) thermophotovoltaic (TPV) cells have been developed with thermophotovoltaic efficiency exceeding 40%. However, these devices have sub-optimal power density because the subcell bandgaps are not matched to the emitter spectrum. Although efficiency is important, power density is also an important metric to gauge TPV cell performance; the greater the power density, the less total area of TPV cells that are needed to satisfy a given power generation target. To quantify the relevance of power density, spectrum-matched 1.04/0.78/0.62/0.48/0.36 eV 5-junction (5J) TPV cells have the potential to be 3.5 times more power dense than state-of-the-art, yet spectrum-mismatched, 1.4/1.2 eV 2J TPV cells when irradiated by a 2400 °C emitter. The proposed 5J TPV cells also have the potential to exceed 40% standard power conversion efficiency.
领先的2结(2J)热光伏(TPV)电池已经开发出来,热光伏效率超过40%。然而,由于子单元带隙与发射频谱不匹配,这些器件具有次优功率密度。虽然效率很重要,但功率密度也是衡量冠脉光伏电池性能的重要指标;功率密度越大,满足给定发电目标所需的TPV电池总面积就越小。为了量化功率密度的相关性,光谱匹配的1.04/0.78/0.62/0.48/0.36 eV 5结(5J) TPV电池在2400°C发射器照射时,其功率密度可能是目前最先进的功率密度的3.5倍,但光谱不匹配的1.4/1.2 eV 2J TPV电池。提出的5J TPV电池也有可能超过40%的标准功率转换效率。
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引用次数: 0
Benchmark of eight commercial solutions for deterministic intra-day solar forecast 确定日内太阳预报的八个商业解决方案的基准
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023006
J. Lehmann, Christian Koessler, Lina Ruiz Gomez, Stijn Scheerlinck
Continuous increase of the production of photovoltaic energy requires precise forecasting to ensure grid stability. This paper presents a detailed benchmark of eight commercial forecasting solutions for intra-day solar forecasts. The comparison was carried out on a period of six months, from November to May 2021, on seven different PV plants located in different countries of the northern hemisphere. Performance evaluation metrics MAE, RMSE and MBE are used in order to analyze the forecasting precision. It is shown that forecasting solar power remains challenging, as shown by the important dispersion between the actors that we have observed.
光伏发电量的持续增长需要精确的预测来保证电网的稳定。本文介绍了八种日间太阳预报商业方案的详细基准。从2021年11月到5月,对位于北半球不同国家的七个不同的光伏电站进行了为期六个月的比较。运用MAE、RMSE和MBE等绩效评价指标对预测精度进行分析。研究表明,预测太阳能发电仍然具有挑战性,正如我们所观察到的因素之间的重要分散所表明的那样。
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引用次数: 0
Long-term PV system modelling and degradation using neural networks 使用神经网络的长期光伏系统建模和退化
Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023018
Gerardo Guerra, Pau Mercade-Ruiz, Gaetana Anamiati, Lars Landberg
The power production of photovoltaic plants can be affected throughout its operational lifetime by multiple losses and degradation mechanisms. Although long-term degradation has been widely studied, most methodologies assume a specific degradation behaviour and require detailed metadata. This paper presents a methodology for the calculation of long-term degradation of a photovoltaic plant based on neural networks. The goal of the neural network is to model the photovoltaic plant's power production as a function of environmental conditions and time elapsed since the plant started operating. A big advantage of this method with respect to others is that it is completely data-driven, requires no additional information, and makes no assumptions related to degradation behaviour. Results show that the model can derive a long-term degradation trend without overfitting to shorter-term effects or abrupt changes in year-to-year operation.
光伏电站在其整个运行寿命期内会受到多种损耗和退化机制的影响。虽然长期退化已被广泛研究,但大多数方法都假定有特定的退化行为,并且需要详细的元数据。提出了一种基于神经网络的光伏电站长期退化计算方法。神经网络的目标是将光伏电站的发电量建模为环境条件和电站开始运行后经过的时间的函数。与其他方法相比,这种方法的一大优点是它完全是数据驱动的,不需要额外的信息,也不做与退化行为相关的假设。结果表明,该模型可以得出长期的退化趋势,而不会过度拟合短期效应或年际运行的突变。
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引用次数: 0
Investigation of III-V GaP solar cell on silicon substrate 硅衬底III-V型GaP太阳能电池的研究
Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023020
Soline Boyer-Richard, Fei Fan, Alexandre Beck, Christophe Levallois, Karine Tavernier, Tony Rohel, Rozenn Bernard, Antoine Létoublon, Charles Cornet, Olivier Durand
The best solar conversion efficiencies have been reached thanks to multijunction solar based on III-V semiconductors on GaAs or Ge substrates. While displaying high conversion efficiencies, these solar cells suffer from the high cost of such substrates. To benefit from both the low cost and technological maturity of silicon cells, III-V tandem cells on silicon seem a good compromise to overpass the theoretical efficiency limit of the Si single cells. To study the GaP/Si interface effect on the solar cell characteristic, a GaP n-i-p solar cell has been grown on silicon substrate. Two types of electrical contacts configurations have been processed: a top-top configuration in which the current does not see the GaP/Si interface and the top-bottom configuration where the electric current crosses the interface. A comparison of dark I-V, I-V under solar illumination, and EQE measurements on both configurations is performed. The top-bottom contacts configuration shows an EQE a little bit lower than the top-top contact one, likely due to lower carrier diffusion length or recombination at the lower interface. However, the result on the EQE of the top-bottom configuration is encouraging for the future development of the GaP-based/Si tandem solar cells, and any other tandem cell on silicon using GaP as an intermediate selective contact.
由于基于GaAs或Ge衬底的III-V半导体的多结太阳能已经达到了最佳的太阳能转换效率。在显示高转换效率的同时,这些太阳能电池受到这种基板的高成本的影响。为了从硅电池的低成本和技术成熟度中获益,硅上的III-V串联电池似乎是一个很好的妥协,以超越硅单电池的理论效率极限。为了研究GaP/Si界面对太阳电池特性的影响,在硅衬底上生长了一种GaP n-i-p太阳电池。已经处理了两种类型的电触点配置:一种是自上而下的配置,其中电流看不到GaP/Si接口,另一种是自上而下的配置,其中电流穿过接口。比较了暗I-V,太阳照射下的I-V,以及两种配置下的EQE测量结果。上下触点结构的EQE略低于上下触点结构,这可能是由于载流子扩散长度较短或下界面处的复合所致。然而,自上而下结构的EQE结果对于基于GaP的/Si串联太阳能电池的未来发展,以及使用GaP作为中间选择性接触的硅上的任何其他串联电池都是令人鼓舞的。
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引用次数: 0
Architecture of symmetrical bifacial perovskite/Si/perovskite PV modules and LCOE comparison in bifacial applications 对称双面钙钛矿/硅/钙钛矿光伏组件的结构及双面应用中的LCOE比较
Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023025
Amaury Martin, Pierre-Philippe Grand, Matthew Hull, Jean Rousset, Lars Oberbeck
Perovskite on silicon tandem technologies offer a promising way to overcome the efficiency limit of single-junction crystalline silicon modules and are therefore widely studied. Besides the cost reduction potential of using tandem modules in utility-scale PV plants, the application of bifacial PV modules offers additional opportunities to reduce costs by increasing the energy yield. However, the bifaciality factor of tandem PV modules using bifacial crystalline silicon solar cells is typically lower than that of single-junction bifacial modules, considering the asymmetric architecture of the module with higher front-side than rear-side efficiency. In this study, we assess a symmetrical bifacial triple-junction perovskite/silicon/perovskite PV module architecture which allows for a significant improvement of the PV module rear side efficiency. Cost of ownership, energy yield and levelized cost of energy modeling show the superior performance of such modules compared to crystalline silicon and perovskite/silicon tandem modules specifically in vertical mounting applications that are used e.g.in AgriPV or noise protection PV walls on highways.
钙钛矿在硅上的串联技术为克服单结晶体硅组件的效率限制提供了一条有希望的途径,因此得到了广泛的研究。除了在公用事业规模的光伏电站中使用串联模块降低成本的潜力之外,双面光伏模块的应用还提供了通过增加能源产量来降低成本的额外机会。然而,采用双面晶硅太阳能电池的串联光伏组件的双面性系数通常低于单结双面组件,考虑到组件的不对称结构,前部效率高于后部效率。在本研究中,我们评估了一种对称的双面三结钙钛矿/硅/钙钛矿光伏组件架构,该架构可以显著提高光伏组件的后侧效率。与晶体硅和钙钛矿/硅串联模块相比,拥有成本、能源产量和能源建模的平均化成本显示出这些模块的优越性能,特别是在垂直安装应用中,例如在AgriPV或高速公路上的隔音光伏墙中使用。
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引用次数: 0
期刊
EPJ Photovoltaics
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