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Experimental evaluation of the impact of pigment-based colored interlayers on the temperature of BIPV modules 基于色素的彩色夹层对BIPV组件温度影响的实验评估
Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023028
Markus Babin, Ingvar Haukur Jóhannsson, Michael Linde Jakobsen, Sune Thorsteinsson
While colored photovoltaics are gaining popularity in the market for building-integrated photovoltaics (BIPV), several specific properties are not accounted for in standard PV performance models. This work shows how relying on the coloration efficiency alone can lead to significant errors regarding module temperatures. By comparing measured temperature data from a test installation featuring BIPV façade elements in multiple colors, little correlation is found between total optical losses (reflection and absorption losses) and module temperature. Instead, better correlation is found with total reflectance. This is attributed to the light absorbed in the pigment-based colored layers contributing to module heating, whereas reflected light does not. This is especially relevant for colors with high lightness, such as gray or beige, for which reflection losses are dominating absorption losses. When modelling colored BIPV products, it is therefore recommended to only consider reflection losses for the irradiance contributing to module heating, while continuing to also include absorption losses for the effective irradiance used in electrical performance modelling.
虽然彩色光伏在建筑集成光伏(BIPV)市场上越来越受欢迎,但在标准的光伏性能模型中没有考虑到一些特定的性能。这项工作表明,仅依靠显色效率如何导致模块温度方面的重大错误。通过比较具有多色BIPV面板元件的测试装置的测量温度数据,发现总光学损耗(反射和吸收损耗)与模块温度之间几乎没有相关性。相反,发现与全反射的相关性更好。这是由于基于颜料的有色层吸收的光有助于模块加热,而反射光则没有。这尤其适用于高亮度的颜色,如灰色或米色,因为它们的反射损失主要是吸收损失。因此,在为彩色BIPV产品建模时,建议只考虑导致模块加热的辐照度的反射损耗,同时继续包括电气性能建模中使用的有效辐照度的吸收损耗。
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引用次数: 0
Blind PV temperature model calibration PV温度模型盲校正
Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023021
Anastasios Kladas, Bert Herteleer, Jan Cappelle
The determination of module temperature in a photovoltaic (PV) system is a crucial factor in PV modelling and the assessment of system health status. However, the scarcity of on-site temperature measurements poses a challenge, and existing PV temperature models encounter difficulties in accurately estimating temperatures in systems characterized by unique structural or locational attributes. This paper introduces a novel approach that enables the calibration of PV temperature models without relying on direct temperature measurements. Referred to as blind calibration, this method eliminates the requirement for temperature measurements, thus offering a promising solution to the aforementioned challenges. The method is validated using three datasets, demonstrating accurate PV temperature ( T PV ) estimation with mean absolute errors below 2 °C. The findings highlight the suitability of the proposed approach for various PV system types, while acknowledging limitations regarding certain system configurations.
光伏系统中组件温度的确定是光伏系统建模和系统健康状态评估的关键因素。然而,由于缺乏现场温度测量,现有PV温度模型难以准确估计具有独特结构或位置属性的系统的温度。本文介绍了一种新的方法,使PV温度模型的校准不依赖于直接的温度测量。这种方法被称为盲校准,它消除了对温度测量的要求,从而为上述挑战提供了一个有希望的解决方案。使用三个数据集验证了该方法,证明了准确的PV温度(T PV)估计,平均绝对误差低于2°C。研究结果强调了所提出的方法对各种光伏系统类型的适用性,同时承认某些系统配置的局限性。
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引用次数: 0
Assessing the long-term stability of laser enhanced contact optimization (LECO) treated PERC cells in PV modules by extended indoor and outdoor durability tests 通过扩展的室内和室外耐久性测试,评估激光增强接触优化(LECO)处理光伏组件中PERC电池的长期稳定性
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023004
Eve Krassowski, B. Jaeckel, M. Pander, D. Dassler, S. Malik
It was previously shown that the Laser Enhanced Contact Optimization (LECO) Process is a promising boost for PERC and TOPCon cell manufacturing enhancement. In this contribution, a method is developed to assess the long-term stability of industrial LECO treated PERC cells in a module compound. Therefore, extended accelerated aging tests as well as outdoor measurements were performed on modules comprising LECO treated cells as well as untreated references. It is described, how data can be evaluated to separate typical, known aging and degradation effects from presumable LECO specific effects. The results of this work show that test modules comprising LECO treated cells did not show a different behavior in the accelerated aging or degradation compared to the reference. The same conclusion was found for thermal cycling and damp heat tests, both far in excess of IEC requirements, as well as in a sequential test sequence. In addition, their outdoor performance with local and integral measurements has been evaluated. We can conclude that for the tested PERC cells, aging and degradation effects appeared, but none of them could be attributed to the LECO process. Hence, improvements in the efficiency and/or yield on cell level due to LECO can be translated to the module or even system level considering typical aging and degradation behavior, independently of a prior LECO process.
之前的研究表明,激光增强接触优化(LECO)工艺是PERC和TOPCon电池制造增强的一个有希望的推动因素。在本贡献中,开发了一种方法来评估模块化合物中工业LECO处理的PERC电池的长期稳定性。因此,对包括LECO处理细胞和未处理参考细胞的模块进行了延长加速老化试验和室外测量。它描述了如何评估数据,以区分典型的,已知的老化和降解效应从假定的LECO特异性效应。这项工作的结果表明,与参考相比,包含LECO处理细胞的测试模块在加速老化或降解方面没有表现出不同的行为。在热循环和湿热试验中也发现了同样的结论,两者都远远超出了IEC的要求,并且在连续的测试序列中也是如此。此外,通过局部和整体测量对其室外性能进行了评估。我们可以得出结论,对于测试的PERC电池,出现了老化和降解效应,但这些效应都不能归因于LECO过程。因此,考虑到典型的老化和降解行为,LECO在电池水平上的效率和/或产量的提高可以转化为模块甚至系统水平,而不依赖于先前的LECO工艺。
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引用次数: 0
Analysis of the degradation of amorphous silicon mini-modules under a severe sequential UV/DH test 非晶硅微型组件在严格的连续UV/DH测试下的降解分析
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2023-01-01 DOI: 10.1051/epjpv/2023014
Julia Vincent, Venkata Ramana Posa, Ali Khouzam, P. Logerais, Mustapha El Yaakoubi, A. Labouret
This study presents the results of severe accelerated tests carried out on four encapsulated amorphous silicon (a-Si) mini-modules. All the a-Si mini-modules were exposed to a 85 °C and 85% relative humidity damp heat (DH) prolonged treatment for 5000 h representing five times the duration specified by the IEC 61215 standard for qualification tests. For two of the four mini-modules, the DH test was preceded by a severe UV preconditioning, by applying 30 times the dose of 15 kWh/m2 at a temperature of 50 °C as prescribed by the IEC 61215 standard, in order to enhance the degradation during the following DH test and to reduce the overall testing time. I–V curves were plotted with a time step of 100 h under standard test conditions (STC) using a class A solar simulator and a source meter in order to monitor the degradation throughout both the tests. A visual inspection with photographic capturing was also performed at each stage to detect the apparent defects. Corrosion observed after 2000 h owing to the ingress of humidity is explained here by two possible infiltration paths in the layers of the mini-modules. Delamination occurred after 5000 h for the PV mini-modules which underwent the extended DH test. After 5000 h of damp heat testing, the degradation of the maximal power (Pmax) was found to be slightly accelerated for the a-Si mini-modules that were previously exposed to a severe UV preconditioning, with a value reaching 80% of its initial value, whereas, for the others only subjected to the prolonged DH test, the maximal power remained above 80% of its initial value. In all cases, the mini-modules seemed highly reliable with no failure after 5000 h of accelerated testing, and, based on an equivalent time of 20 years for 1000 h of accelerated test, they would exhibit a limited degradation rate of 0.2%/year in outdoor field conditions.
本研究介绍了在四个封装的非晶硅(a-Si)微型模块上进行的严重加速测试的结果。所有a- si微型模块暴露在85°C和85%相对湿度的湿热(DH)下,长时间处理5000小时,是IEC 61215标准规定的合格测试时间的五倍。对于四个迷你模块中的两个,在进行DH测试之前进行了严格的紫外线预处理,按照IEC 61215标准的规定,在50°C的温度下施加30倍于15 kWh/m2的剂量,以便在接下来的DH测试中增强降解并减少总体测试时间。在标准测试条件(STC)下,使用a类太阳模拟器和源计绘制时间步长为100 h的I-V曲线,以便监测整个测试过程中的退化情况。在每个阶段还进行了摄影捕捉的视觉检查,以检测明显的缺陷。在2000 h后观察到的由于湿度进入的腐蚀,这里用微型模块层中的两种可能的渗透路径来解释。经过扩展DH测试的PV微型组件在5000 h后发生分层。经过5000 h的湿热测试,发现先前暴露于严重紫外线预处理的a- si微型模块的最大功率(Pmax)的退化略有加速,达到其初始值的80%,而对于其他仅经过长时间DH测试的a- si微型模块,最大功率仍保持在其初始值的80%以上。在所有情况下,迷你模块在5000小时的加速测试后似乎高度可靠,没有出现故障,并且,基于20年的等效时间,1000小时的加速测试,它们在室外现场条件下将表现出0.2%/年的有限降解率。
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引用次数: 0
Ultra-lightweight and flexible inverted metamorphic four junction solar cells for space applications 用于空间应用的超轻柔性倒变质四结太阳能电池
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022024
Malte Klitzke, J. Schön, R. H. van Leest, G. Bissels, E. Vlieg, M. Schachtner, F. Dimroth, D. Lackner
In this work an inverted metamorphic four junction (IMM4J) solar cell with 30.9% conversion efficiency in beginning of life conditions under the AM0 (1367 W/m2) spectrum is presented. Additionally, our newest improved IMM3J cell, consisting of Ga0.51In0.49P/GaAs/Ga0.73In0.27As subcells, with 30.6% efficiency is also shown. The IMM4J solar cells consist of Al0.05Ga0.46In0.49P/Al0.14Ga0.86As/Ga0.89In0.11As/Ga0.73In0.27As subcells and are epitaxially grown by metal organic vapor phase epitaxy (MOVPE) on a GaAs substrate. These IMM solar cells achieve power-to-mass ratios of 3 W/g or more, which is more than three times higher than standard germanium based triple or four junction space solar cells. The losses in comparison to the simulated near-term potential efficiency of 33.8% for the IMM4J are analyzed in detail. Furthermore, the irradiation behavior for 1 MeV electron fluences of 1 × 1014 e−/cm2 and 2.5 × 1014 e−/cm2 for the IMM4J cells was investigated. A roadmap to further develop this concept towards an IMM5J with a realistic begin of life (BOL) efficiency potential of 35.9% under AM0 is presented.
本文介绍了一种倒置变质四结(IMM4J)太阳能电池,在AM0 (1367 W/m2)光谱下,在寿命开始条件下转换效率为30.9%。此外,我们最新的改进的IMM3J电池,由Ga0.51In0.49P/GaAs/Ga0.73In0.27As亚电池组成,效率为30.6%。IMM4J太阳能电池由Al0.05Ga0.46In0.49P/Al0.14Ga0.86As/Ga0.89In0.11As/Ga0.73In0.27As亚电池组成,采用金属有机气相外延(MOVPE)技术在GaAs衬底上外延生长。这些IMM太阳能电池的功率质量比达到3w /g或更高,比标准的锗基三结或四结空间太阳能电池高出三倍多。与模拟的IMM4J的33.8%的近期潜在效率相比,详细分析了损失。此外,研究了1 MeV、1 × 1014 e−/cm2和2.5 × 1014 e−/cm2对IMM4J细胞的辐照行为。提出了进一步将这一概念发展为在AM0条件下具有35.9%的实际寿命开始(BOL)效率潜力的IMM5J的路线图。
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引用次数: 1
Surface photovoltage characterisation of metal halide perovskite on crystalline silicon using Kelvin probe force microscopy and metal-insulator-semiconductor configuration 利用开尔文探针力显微镜和金属绝缘体-半导体结构表征晶体硅上金属卤化物钙钛矿的表面光电压
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022016
Aleksandra Bojar, D. Regaldo, J. Alvarez, D. Alamarguy, V. Donchev, S. Georgiev, P. Schulz, J. Kleider
In this study we analysed halide perovskite films deposited directly on crystalline silicon by means of two set-ups using different operating modes of the surface photovoltage (SPV) methods, i.e., the Kelvin probe force microscopy (KPFM) and the metal-insulator-semiconductor (MIS) technique. The KPFM allowed to visualize surface potential distribution on a microscale while MIS technique allowed to study SPV spectral dependence. We studied wavelength dependent SPV of these samples, which allowed us to effectively vary the probe depth in the sample and discern the contribution from each interface to the overall effect measured under white light illumination. Depending on where the photocarriers are generated, different SPV signals are observed: at the perovskite/Si interface, the signal depends on Si doping type, while at the surface the SPV is always negative indicating downward surface band bending. This is confirmed by analysing SPV phase measured in the AC MIS mode. In addition, distinction between slow and fast processes contributing to measured SPV was possible. It has been observed, that with decreasing the illumination wavelength, the processes causing SPV become slower, which can indicate that high energy photons not only generate electronic photocarriers but can also induce chemical changes with creation of defects or ionic species that also modify the measured SPV.
在这项研究中,我们分析了卤化物钙钛矿薄膜直接沉积在晶体硅上,通过两种设置,使用不同的工作模式的表面光电压(SPV)方法,即开尔文探针力显微镜(KPFM)和金属绝缘体半导体(MIS)技术。KPFM允许在微观尺度上可视化表面电位分布,而MIS技术允许研究SPV光谱依赖性。我们研究了这些样品的波长相关SPV,这使我们能够有效地改变样品中的探针深度,并辨别白光照明下每个界面对整体效果的贡献。根据产生光载流子的位置不同,观察到不同的SPV信号:在钙钛矿/Si界面,信号取决于Si掺杂类型,而在表面,SPV始终为负,表明表面带向下弯曲。通过分析在交流MIS模式下测量的SPV相位证实了这一点。此外,可以区分对测量的SPV有贡献的慢速和快速过程。观察到,随着照射波长的减小,引起SPV的过程变慢,这表明高能光子不仅产生电子光载流子,而且还可以引起化学变化,产生缺陷或离子种,这些缺陷或离子种也会改变所测的SPV。
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引用次数: 2
EU PVSEC 2021: state of the art and developments for photovoltaics at the forefront EU PVSEC 2021:最前沿的光伏技术和发展
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022011
R. Kenny, J. Serra
The transition to a low carbon society will not be possible without a major shift to renewables. Up to now the world is not set for a clear downward turn in emissions because most of the energy infrastructure continues to work in a business-as-usual scenario. With its strong reduction in LCOE, PV is at the forefront of new energy technologies to be a key contributor for change. PV bene fi ts range from local energy production to large power plants. In combination with other technologies, it expands its added value not only to cities, including buildings and mobility, but also to agriculture, water desalination and hydrogen production. According to the International Energy Agen-cy, solar is now the cheapest form of electricity generation and will be the most important renewable energy in the world.
如果不大力转向可再生能源,就不可能向低碳社会过渡。到目前为止,由于大多数能源基础设施仍在按“一切照旧”的模式运行,世界的排放量还没有明显下降。凭借其强大的LCOE降低,光伏处于新能源技术的前沿,成为变革的关键贡献者。从当地能源生产到大型发电厂,光伏发电都能从中受益。与其他技术相结合,它不仅将其附加值扩展到城市(包括建筑和交通),还将其扩展到农业、海水淡化和氢气生产。根据国际能源署的数据,太阳能目前是最便宜的发电方式,并将成为世界上最重要的可再生能源。
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引用次数: 0
Revealing of InP multi-layer stacks from KPFM measurements in the dark and under illumination 在黑暗和光照条件下KPFM测量揭示InP多层叠加
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022017
Mattia da Lisca, J. P. Connolly, J. Alvarez, K. Mekhazni, N. Vaissière, J. Decobert, J. Kleider
Solar cells are complex devices, being constituted of many layers and interfaces. The study and the comprehension of the mechanisms that take place at the interfaces is crucial for efficiency improvement. This paper applies Kelvin probe force microscopy (KPFM) to study materials and interfaces with nanometer scale imaging of the surface potential in the dark and under illumination. KPFM measurements are highly sensitive to surface states and to the experimental measurement environment influencing the atomic probe operating conditions. Therefore, in order to develop a quantitative understanding of KPFM measurements, we have prepared a dedicated structured sample with alternating layers of InP:S and InP:Fe whose doping densities were determined by secondary-ion mass spectroscopy. We have performed KPFM measurements and shown that we can spatially resolve 20 nm thick InP layers, notably when performed under illumination which is well-known to reduce the surface band-bending.
太阳能电池是一种复杂的器件,由许多层和界面组成。研究和理解在界面处发生的机制对于提高效率至关重要。本文应用开尔文探针力显微镜(KPFM)对材料和界面进行了研究,并在黑暗和光照下对其表面电位进行了纳米级成像。KPFM测量对表面状态和影响原子探针工作条件的实验测量环境高度敏感。因此,为了对KPFM测量进行定量理解,我们制备了一个专用的结构样品,其中InP:S和InP:Fe交替层,其掺杂密度由二次离子质谱测定。我们已经进行了KPFM测量,并表明我们可以在空间上分辨20nm厚的InP层,特别是在众所周知可以减少表面带弯曲的照明下进行。
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引用次数: 1
Analysis of the operation of PV strings at the MPP closest to the nominal MPP voltage instead of the global MPP based on measured current–voltage curves 根据测量的电流-电压曲线,分析PV串在最接近标称MPP电压的MPP处的运行情况,而不是在全局MPP处
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022001
K. Lappalainen, S. Valkealahti
Under non-uniform operating conditions, photovoltaic (PV) generators may have several maximum power points (MPP) and voltage of the global MPP (GMPP) may vary quickly over a wide voltage range which may cause problems for tracking of the GMPP. Since highly varying GMPP voltage causes fluctuation of the inverter reference voltage, it would be beneficial to operate the PV system in a more predictable and straightforward manner by keeping the operating point of the inverter all the time close to the nominal MPP voltage. This article presents an experimental study of a scenario in which the MPP closest to the nominal MPP voltage (CMPP) is always the operating point instead of the GMPP. The analysis was based on 1,296,000 measured current–voltage curves of three different PV strings located at Tampere, Finland. 12 days of full-time measurements were analysed for each of the studied strings consisting of 6, 17 and 23 series-connected NAPS NP190GK PV modules. Furthermore, the effects of inverter sizing on the operating point behaviour of the strings were studied. The results show that the wide operating voltage range of the GMPP can be significantly reduced by operating at the CMPP at a cost of negligible energy losses. Energy losses due to power curtailment were much larger than energy losses due to operation at the CMPP instead of the GMPP.
在非均匀工况下,光伏发电机组可能有多个最大功率点(MPP),全局最大功率点(GMPP)的电压可能在较宽的电压范围内变化很快,这可能会给GMPP的跟踪带来问题。由于GMPP电压的剧烈变化会引起逆变器参考电压的波动,因此将逆变器的工作点始终保持在标称MPP电压附近,有利于光伏系统的运行更加可预测和直接。本文提出了一种实验研究方案,其中最接近MPP标称电压(CMPP)的MPP始终是工作点,而不是GMPP。该分析基于位于芬兰坦佩雷的三个不同PV串的1,296,000个测量的电流-电压曲线,对每个研究串(包括6个,17个和23个串联的nap NP190GK光伏模块)进行了12天的全职测量分析。此外,还研究了逆变器尺寸对串工作点行为的影响。结果表明,在CMPP下工作可以显著减小GMPP的宽工作电压范围,而能量损失可以忽略不计。由于停电造成的能量损失远远大于在CMPP而不是GMPP运行所造成的能量损失。
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引用次数: 3
Electroluminescence analysis of silicon interdigitated back contact solar cells with a front surface selective band offset barrier 具有前表面选择性带偏移势垒的硅互指背接触太阳能电池的电致发光分析
IF 2.5 Q3 PHYSICS, APPLIED Pub Date : 2022-01-01 DOI: 10.1051/epjpv/2022015
Koffi F. Ahanogbe, J. Alvarez, A. Jaffré, J. P. Connolly, M. Gueunier‐Farret, E. Fourmond, Seif El-Whibi, A. Fave, P. Carroy, Z. Djebbour, J. Kleider
Electroluminescence allows rapid characterization of an entire photovoltaic solar cell and visualization of defects at the micrometer scale. Here we focus on the optoelectronic properties of silicon interdigitated back contact cells characterized by electroluminescence. The spatially resolved electroluminescence helps us control the quality of interdigitated back contact structures used in silicon bottom subcells in a three-terminal tandem perovskite on silicon solar cell. Local variations in minority carrier diffusion length, surface recombination velocity and, the impact of resistive and optical losses were analyzed by electroluminescence mapping. In addition, we quantify the radiative saturation current density and the radiative open circuit voltage using the electroluminescence spectrum of the cell. This step allows us to accurately assess the performance limits induced in the device due to the non-radiative recombination.
电致发光可以快速表征整个光伏太阳能电池,并在微米尺度上可视化缺陷。本文主要研究了以电致发光为特征的硅交叉指背接触电池的光电性能。空间分辨电致发光有助于控制三端串联钙钛矿硅基太阳能电池硅底亚电池中使用的交叉背接触结构的质量。通过电致发光作图分析了少数载流子扩散长度、表面复合速度以及电阻损耗和光学损耗的局部变化。此外,我们还利用电池的电致发光光谱量化了辐射饱和电流密度和辐射开路电压。这一步使我们能够准确地评估由于非辐射重组而在器件中引起的性能限制。
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引用次数: 0
期刊
EPJ Photovoltaics
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