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Investigation of Pellet-Clad Mechanical Interaction in Failed Spent PWR Fuel 失效乏燃料堆中球团包层力学相互作用研究
IF 0.6 Q4 ELECTROCHEMISTRY Pub Date : 2019-10-31 DOI: 10.14773/CST.2019.18.5.175
Y. Jung, S. Baik
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引用次数: 2
Composite PEO-Coatings as Defence Against Corrosion and Wear: A Review peo -复合涂层抗腐蚀磨损性能研究进展
IF 0.6 Q4 ELECTROCHEMISTRY Pub Date : 2019-10-31 DOI: 10.14773/CST.2019.18.5.212
S. Gnedenkov, S. Sinebryukhov, V. Sergienko, A. Gnedenkov
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引用次数: 3
Experimental Investigation and Quantum Chemical Calculations of Some (Chlorophenyl Isoxazol-5-yl) Methanol Derivatives as Inhibitors for Corrosion of Mild Steel in 1 M HCl Solution 一些(氯苯基异恶唑-5-基)甲醇衍生物在1 M HCl溶液中作为低碳钢腐蚀抑制剂的实验研究和量子化学计算
IF 0.6 Q4 ELECTROCHEMISTRY Pub Date : 2019-10-31 DOI: 10.14773/CST.2019.18.5.155
Rogayeh Sadeghzadeh, L. Ejlali, Moosa Es’haghi, H. Basharnavaz, K. Seyyedi
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引用次数: 1
Effects of NaCl Concentration and Solution Temperature on the Galvanic Corrosion Between CFRP and A516Gr.55 Carbon Steel NaCl浓度和溶液温度对CFRP与A516Gr.55碳钢电腐蚀的影响
IF 0.6 Q4 ELECTROCHEMISTRY Pub Date : 2019-08-31 DOI: 10.14773/CST.2019.18.4.129
S. Hur, Ki Tae Kim, Y. Kim
About 20 ~ 50% of typical carbon fiber reinforced plastic is lighter than metals, and CFRP has excellent properties, including low density, high strength and high corrosion resistance [1,2]. Because of these excellent properties of CFRP, composite materials which meet various regulation conditions needed in the industrial fields, have been widely used in the many industries including aircraft, transportation, ship building, and automobile etc. [3,4]. However, CFRP reveals water absorption in water immersion or high humidity environment, and water absorption occurs in an epoxy not carbon fiber, and can be facilitated by higher temperature. Since these properties can induce volume expansion inside CFRP and change the internal stress state and degrade the chemical bond between the fiber and the matrix, the mechanical properties including bond strength may be lowered [5,6]. When CFRP contacts to metallic materials, galvanic corrosion can be occur because of the potential difference between them [7,8]. Galvanic corrosion is known to occur when two dissimilar materials are jointed together. In general, the less noble material experiences accelerated corrosion [9]. Corrosion of metallic materials varies with the exposure time in the environments, and it depends upon the formation of protective passive film and microstructure [10] and the ratio of cathode and anode, corrosivity, and temperature etc. [11]. Our group has recently reported the galvanic corrosion between GECM (Graphite Epoxy Composite Materials) and aluminum/carbon steel [12-14]: In galvanic couple between aluminum and carbon steel bolt, their corrosion rates were higher than those of single specimen. In galvanic couple between GECM, aluminum, and carbon steel, corrosion behavior of carbon steel bolt and aluminum was changed due to different corrosion mechanism in tap water and chloride solutions. On the other hand, it is well known that a strong galvanic couple can be formed between CFRP and steel rivets if the joint is exposed to a corrosion environment. In general, CFRP is cathodic and performs Effects of NaCl Concentration and Solution Temperature on the Galvanic Corrosion Between CFRP and A516Gr.55 Carbon Steel
大约20~50%的典型碳纤维增强塑料比金属轻,CFRP具有优异的性能,包括低密度、高强度和高耐腐蚀性[1,2]。由于CFRP的这些优异性能,复合材料满足工业领域所需的各种调节条件,已广泛应用于飞机、交通、造船和汽车等许多行业[3,4]。然而,CFRP在浸水或高湿度环境中表现出吸水性,并且吸水发生在环氧树脂而非碳纤维中,并且可以通过更高的温度来促进。由于这些性能会导致CFRP内部的体积膨胀,改变内应力状态,降低纤维与基体之间的化学结合,因此包括结合强度在内的机械性能可能会降低[5,6]。当CFRP与金属材料接触时,由于它们之间的电势差,可能会发生电偶腐蚀[7,8]。已知当两种不同的材料连接在一起时会发生电偶腐蚀。一般来说,不太贵的材料会经历加速腐蚀[9]。金属材料的腐蚀随着暴露在环境中的时间而变化,它取决于保护性钝化膜的形成和微观结构[10]以及阴极和阳极的比例、腐蚀性和温度等[11]。我们小组最近报道了GECM(石墨-环氧复合材料)与铝/碳钢之间的电偶腐蚀[12-14]:在铝和碳钢螺栓之间的电耦中,它们的腐蚀速率高于单个试样的腐蚀速率。在GECM、铝和碳钢之间的电偶中,碳钢螺栓和铝在自来水和氯化物溶液中的腐蚀机制不同,从而改变了其腐蚀行为。另一方面,众所周知,如果接头暴露在腐蚀环境中,则CFRP和钢铆钉之间会形成强电偶。一般来说,CFRP是阴极的,并表现出NaCl浓度和溶液温度对CFRP和A516Gr.55碳钢之间的电偶腐蚀的影响
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引用次数: 0
Variables of Electrolytic Nickel Plating for RPV Cladding Repair RPV熔覆修复中电解镀镍的变量
IF 0.6 Q4 ELECTROCHEMISTRY Pub Date : 2019-08-31 DOI: 10.14773/cst.2019.18.4.148
Min-Su Kim, S. Hwang, Dongjun Kim, Dong-Bok Lee
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引用次数: 0
Corrosion Prediction of Metallic Cultural Heritage Assets by EIS 金属文化遗产资产腐蚀的EIS预测
IF 0.6 Q4 ELECTROCHEMISTRY Pub Date : 2019-08-31 DOI: 10.14773/CST.2019.18.4.121
E. Angelini, S. Grassini, M. Parvis, F. Zucchi
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引用次数: 3
Analysis on Formation of Corrosion Products in Secondary Steam-Water System of Nuclear Power Plant, 원자력발전소 2차측 습증기계통 주요지점별 부식 발생현황 분석 分析核电站二次测湿蒸汽系统各主要地点腐蚀情况
IF 0.6 Q4 ELECTROCHEMISTRY Pub Date : 2019-08-31 DOI: 10.14773/CST.2019.18.4.138
Kyunghee Lee, H. Han, Sung-Kyu Shin, K. Sung, Y. Rhee, 이경희, 한호석, 신성용, 성기방, 이영우
Pipes and components of the secondary system in the pressurized water reactor (PWR) are mainly comprised of manufactured carbon steel. Thus, the generated carbon steel corrosion products are transported into the steam generator and deposited, thereby deteriorating the integrity of the steam generator. Environmental condition in the secondary system of the PWRs differs across different locations. So, the corrosion rate and types of corrosion products depend on specific locations in the secondary system. In this study, the quantity and chemical compositions of corrosion products generated in various locations that vary in different temperatures and chemistry conditions were investigated. As a result of evaluating the PWR “Unit A” that is in current operation, the amount of corrosion products generated in the section of high temperature feedwater system was identified as the largest source in the secondary system. Major components of corrosion products were iron oxides such as magnetite, hematite, and lepidocrocite.
压水堆二次系统的管道和部件主要由制造的碳钢组成。因此,产生的碳钢腐蚀产物被输送到蒸汽发生器中并沉积,从而使蒸汽发生器的完整性恶化。PWR二次系统的环境条件因位置不同而不同。因此,腐蚀速率和腐蚀产物的类型取决于二次系统中的特定位置。在这项研究中,研究了在不同温度和化学条件下,在不同位置产生的腐蚀产物的数量和化学成分。评估当前运行的压水堆“a机组”的结果是,高温给水系统部分产生的腐蚀产物数量被确定为二次系统中的最大来源。腐蚀产物的主要成分是氧化铁,如磁铁矿、赤铁矿和鳞片细晶岩。
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引用次数: 0
Comparing Resistances to Pitting Corrosion of Additive Manufactured Ti-6Al-4V Alloys in NaCl and NaBr Aqueous Solutions, NaCl과 NaBr수용액에서 적층가공으로 제조된 Ti-6Al-4V 합금의 공식 저항성 비교 Comparing Resistances to Pitting Corrosion of Additive Manufactured Ti-6Al-4V Alloys in NaCl and NaBr Aqueous Solutions, NaCl与NaBr水溶液中经过层压加工制造的Ti-6Al-4V合金的正式电阻性比较
IF 0.6 Q4 ELECTROCHEMISTRY Pub Date : 2019-06-30 DOI: 10.14773/CST.2019.18.3.110
D. Seo, Jae-Bong Lee, 서동일, 이재봉
Resistances to pitting corrosion of additive manufactured (AM) Ti-6Al-4V alloys in 0.6 M NaBr and 0.6 M NaCl aqueous solutions were compared using micro-droplet cell techniques. With respect to the pitting corrosion resistance, this study focused on two different types of halide anions in aqueous solutions, i.e. Br - and Cl - . The differences between Br - and Cl - halide anions for breakdown on passive films of AM Ti-6Al-4V alloy were explained using Langmuir adsorption model with their equilibrium adsorption coefficients. The results of the analysis showed that the lower resistance to pitting potential of AM Ti-6Al-4V alloy in Br - aqueous solution was attributed to the higher equilibrium adsorption coefficient of Br - . In addition, micro-electrochemical test results showed that the pitting corrosion resistance of dark grains in additive manufactured Ti-6Al-4V alloy was lower as compared to that of bright grains due to the larger volume of α ' phase that caused the susceptibility to pit initiation.
使用微滴池技术比较了添加剂制造的(AM)Ti-6Al-4V合金在0.6M NaBr和0.6M NaCl水溶液中的耐点蚀性。关于耐点蚀性,本研究重点研究了水溶液中两种不同类型的卤化物阴离子,即Br-和Cl-。利用Langmuir吸附模型及其平衡吸附系数,解释了Br-和Cl-卤化物阴离子在AM Ti-6Al-4V合金钝化膜上击穿的差异。分析结果表明,AM Ti-6Al-4V合金在Br-水溶液中耐点蚀电位较低的原因是Br-的平衡吸附系数较高。此外,微观电化学测试结果表明,与亮晶粒相比,添加剂制造的Ti-6Al-4V合金中暗晶粒的耐点蚀性能较低,这是由于较大体积的α相导致了点蚀的敏感性。
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引用次数: 2
Micro-scale Observation of Corrosion of Hot-Dip Aluminized 11% Cr Stainless Steel 热浸镀铝11% Cr不锈钢腐蚀的微观观察
IF 0.6 Q4 ELECTROCHEMISTRY Pub Date : 2019-06-30 DOI: 10.14773/CST.2019.18.3.73
Min-Seung Cho, Choong-Nyeon Park, Chan‐Jin Park
Hot-dip aluminized coating has been widely used to protect steel substrate against corrosion. In this study, the corrosion behavior of hot-dip aluminized type 409L (11% Cr) stainless steel (SS) was investigated using macro- and micro-scale polarization tests. An Al-Fe-Si alloy layer that was formed due to inter-diffusion of alloying elements between Al coating and SS substrate was observed between Al coating and 409L SS substrate. In both macro- and micro-scale polarization tests, the corrosion potential ( E corr ) of the 409L SS substrate was much nobler than that of the Al coating and alloy layer. E corr of the alloy layer was between that of Al coating and 409L SS substrate. This indicates that the alloy layer can act as a buffer between the more active Al coating and the nobler SS substrate for pit growth in aluminized SS. The presence of the alloy layer appears to be helpful in hindering pitting corrosion of aluminized SS.
热浸镀铝涂层广泛应用于钢基体的防腐。采用宏观和微观极化试验研究了热浸镀铝409L (11% Cr)不锈钢(SS)的腐蚀行为。在Al涂层与409L SS衬底之间观察到合金元素在Al涂层与SS衬底之间相互扩散形成Al- fe - si合金层。在宏观和微观极化测试中,409L SS基板的腐蚀电位(E - corr)明显高于Al涂层和合金层。合金层的E角介于Al涂层和409L SS衬底之间。这表明合金层可以作为更活跃的Al涂层和更高尚的SS衬底之间的缓冲层,以促进镀铝SS的点蚀生长。合金层的存在似乎有助于阻止镀铝SS的点蚀。
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引用次数: 0
Critical Influence of Rivet Head Height on Corrosion Performance of CFRP/Aluminum Self-Piercing Riveted Joints 铆钉头高度对CFRP/铝自穿铆接腐蚀性能的临界影响
IF 0.6 Q4 ELECTROCHEMISTRY Pub Date : 2019-06-30 DOI: 10.14773/CST.2019.18.3.92
A. Karim, Jin-Hee Bae, D. Kam, Cheolhee Kim, Yeong-do Park
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引用次数: 4
期刊
Corrosion Science and Technology-Korea
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