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2022 IEEE 49th Photovoltaics Specialists Conference (PVSC)最新文献

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Vertical Bifacial Solar Panels as a Candidate for Solar Canal Design 垂直双面太阳能电池板作为太阳能管道设计的备选方案
Pub Date : 2022-06-05 DOI: 10.1109/pvsc48317.2022.9938769
J. Reagan, S. Kurtz
A vertical bifacial + reflector configuration is presented as a candidate for solar canal design. Simulations show output to be competitive with fixed 20° tilt systems, with South-facing vertical orientation showing 117% and 87% of annual output of South-facing 20° systems with and without a reflector, respectively. South-facing vertical orientations have better performance in non-summer months relative to other systems, resulting in a flatter seasonal curve, with useful implications for load balancing and energy storage. East- and West-facing vertical orientations outperform their fixed tilt defaults, even without a reflector, and tolerate higher DC/ AC inverter ratios than similar South-facing vertical orientations before appreciable clipping effects are seen.
一个垂直的双面+反射结构被提出作为太阳能运河设计的候选方案。模拟表明,与固定的20°倾斜系统相比,产量具有竞争力,朝南垂直方向的年产量分别为朝南20°系统年产量的117%和87%,其中有反射器和没有反射器。相对于其他系统,朝南的垂直方向在非夏季具有更好的性能,从而产生更平坦的季节曲线,对负载平衡和能量存储具有有用的含义。即使没有反射器,朝东和朝西的垂直方向也优于其固定倾斜默认值,并且在看到明显的削波效应之前,比类似的朝南垂直方向可以容忍更高的DC/ AC逆变器比率。
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引用次数: 0
Fabricating high aspect ratio front contacts for solar cells by string-printing 用串印法制造太阳能电池高纵横比前触头
Pub Date : 2022-06-05 DOI: 10.1364/pvled.2022.pvw2h.4
M. Van de Voorde, R. Saive
We are developing a method for the fabrication of high aspect ratio and high throughput solar cell front contacts, called string-printing. For this, a thread coated with silver paste approaches a silicon substrate until contact is made and then is pulled away to form high aspect ratio, ideally triangular-shaped silver contacts. Here, we describe the fabrication method and show first results. So far, we have been able to fabricate structures with an aspect ratio of 1 whereas we noticed a strong dependence on the thread diameter and the paste viscosity. Furthermore, we also suspect a dependence on the withdrawal speed of the thread. Our approach is a highly scalable, low temperature process that can boost the performance of solar cell metallization for the terawatt future.
我们正在开发一种制造高纵横比和高通量太阳能电池前触点的方法,称为串印刷。为此,一根涂有银膏的线靠近硅衬底,直到形成接触,然后被拉开,形成高宽高比,理想的三角形银接触。在这里,我们描述了制作方法并展示了初步结果。到目前为止,我们已经能够制造长宽比为1的结构,但我们注意到螺纹直径和浆料粘度对结构的依赖性很强。此外,我们还怀疑这与线程的退出速度有关。我们的方法是一种高度可扩展的低温工艺,可以为太瓦的未来提高太阳能电池金属化的性能。
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引用次数: 0
Analyzing Effects of Solar Variability and System Location on LMP Prices 太阳变率和系统位置对LMP价格的影响分析
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938680
Mesude Bayrakci-Boz, J. Ranalli
Optimal power flow has been solved to show possible effects of solar variability and location of solar systems on electricity price using the IEEE 30 Bus Test system. Different densities of simulated solar generation plants were used, with higher-density plants exhibiting higher variability of generation. The effects of different solar variability conditions tested in this study were found to be minimal on the absolute reduction in local marginal prices (LMPs), but low-density plant distributions exhibited smaller and less frequent fluctuations in the price. In some cases, solar generation was observed to reduce the LMP to zero, resulting from congestion that limited the export of electricity. We observed that lower-density generation distributions could reduce the frequency of these rapid price fluctuations. The location of solar systems within the grid can also have a significant impact on LMPs. When solar generation is installed at a high demand bus, the LMP typically decreased at both the local and neighboring buses. When the solar systems are installed at a low demand bus, the LMPs were observed to increase or decrease depending on the demand and congestion. This work highlights the importance of the effects of solar system location on LMP.
利用IEEE 30总线测试系统求解了最优潮流,以显示太阳能变化和太阳能系统位置对电价的可能影响。采用不同密度的模拟太阳能发电厂,密度越大,发电量变异性越大。本研究中测试的不同太阳变率条件对当地边际价格(LMPs)的绝对降低的影响很小,但低密度植物分布的价格波动较小且不太频繁。在某些情况下,太阳能发电被观察到将LMP降低到零,这是由于阻塞限制了电力出口。我们观察到,较低密度的发电分布可以减少这些快速价格波动的频率。太阳能系统在电网中的位置也会对lmp产生重大影响。当在高需求公交车上安装太阳能发电时,本地和邻近公交车的LMP通常都会下降。当太阳能系统安装在低需求总线上时,观察到lmp根据需求和拥堵情况增加或减少。这项工作强调了太阳系位置对LMP影响的重要性。
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引用次数: 0
Superior Performance of Two-Phase Triple Halide Inorganic Perovskites 两相三卤化物无机钙钛矿的优越性能
Pub Date : 2022-06-05 DOI: 10.1109/pvsc48317.2022.9938691
Deniz N. Cakan, Rishi E. Kumar, Connor J Dolan, Moses Kodur, Yanqi Luo, Tao Zhou, Z. Cai, Barry Lai, Martin Holt, D. Fenning
Inorganic halide perovskites are attractive for achieving the wide bandgap optimal for a high-efficiency perovskite-perovskite tandem photovoltaic based on today’ Pb-Sn low bandgap compositions. However, they have suffered from lower photoluminescent quantum yield relative to hybrid compositions and phase instability. To improve upon metastable CsPbI3, we explore triple-halide alloying of minor amounts of Br and Cl with I. In agreement with previous reports for hybrid analogues, we observe a chlorine solubility limit in the majority iodine-bromine all-inorganic perovskite lattice. Past this solubility limit we observe the perovskite forming a split phase of iodine-bromine-rich and bromine-chlorine-rich clusters. Interestingly, these dual-phase thin films show superior and long lasting PL-intensity under 40-sun equivalent 633 nm laser intensity, which hints at possible synergistic effects of this chemical heterogeneity. We leverage multi-modal synchrotron microscopy and correlative spectroscopic micro-photoluminescence (µPL) on all-inorganic triple halide perovskites CsPbX3 (X-site: I/Br/Cl) films to elucidate mechanisms for superior performance in the face of phase segregation. The results suggest that a greater focus on harnessing the flexibility of the inorganic perovskite material system holds promise to retrace the outstanding performance and stability gains made in hybrid analogues.
无机卤化物钙钛矿在实现高效钙钛矿-钙钛矿串联光伏的最佳宽带隙方面具有吸引力,该光伏基于当今的Pb-Sn低带隙成分。然而,相对于杂化成分和相不稳定性,它们的光致发光量子产率较低。为了改善亚稳态CsPbI3,我们探索了少量的Br和Cl与i的三卤化物合金化。与先前的杂化类似物的报道一致,我们观察到氯在大多数碘溴全无机钙钛矿晶格中的溶解度限制。超过这个溶解度限制,我们观察到钙钛矿形成富碘-溴和富溴-氯簇的分裂相。有趣的是,这些双相薄膜在40太阳等效的633 nm激光强度下表现出优异且持久的pl强度,这暗示了这种化学非均质性可能的协同效应。我们利用多模态同步显微镜和相关的光谱微光致发光(µPL)对全无机三卤化物钙钛矿CsPbX3 (x -位:I/Br/Cl)薄膜进行了研究,以阐明在面对相偏析时优越性能的机制。结果表明,更多地关注利用无机钙钛矿材料系统的灵活性,有望重现混合类似物的卓越性能和稳定性。
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引用次数: 0
Life Cycle Assessment of High-Efficiency Si Solar Modules 高效硅太阳能组件的生命周期评估
Pub Date : 2022-06-05 DOI: 10.1109/pvsc48317.2022.9938679
Estefania Papaioannou, Pritpal Singh, Ross Lee
A Life Cycle Assessment (LCA) is an analytical framework that quantifies the environmental impacts associated with the lifecycle stages of a product. This LCA compares the impacts of 1 kWh of electricity (functional unit) produced by two different hypothetical solar modules: a standard PERC crystalline silicon module and a luminescent solar concentrator (LSC)/PERC tandem module. An LSC-PERC tandem device contains luminescent materials that absorb incoming light with a wide frequency range and re-emits the energy as light in a narrow wavelength range that can be absorbed by silicon, increasing the module power conversion efficiency from 20% to 24%. This ‘cradle to grave’ LCA includes the following life stages: materials acquisition and module fabrication in China, transport to the hypothetical installation site in New Jersey, installation, use, electricity generated, maintenance, disassembly, and end of life. The results indicate that the tandem module will have less overall environmental impacts per unit of electricity generated than the PERC module. The carbon footprint calculated for the PERC module is 31.3 g CO2 eq/kWh, compared with 18.0 g CO2 eq/kWh for the Tandem module. Other impact categories analyzed include ozone depletion, smog, acidification, eutrophication, and human health effects. Several Sustainable Product Innovation (SPI) improvements were proposed and evaluated, including a reduction in the thickness of the silicon cells, replacement of virgin aluminum with recycled aluminum in the frames, removal of antimony in the formulation of the LSC device, and transfer of manufacturing from China to the USA. These SPIs further reduced the environmental impacts in the tandem modules and are reported on in this paper.
生命周期评估(LCA)是一个分析框架,用于量化与产品生命周期阶段相关的环境影响。本LCA比较了两种不同的假设太阳能组件:标准PERC晶体硅模块和发光太阳能聚光器(LSC)/PERC串联模块产生的1千瓦时电力(功能单位)的影响。LSC-PERC串联器件包含的发光材料可以吸收宽频率范围的入射光,并将能量以可被硅吸收的窄波长范围内的光的形式重新发射,将模块的功率转换效率从20%提高到24%。这种“从摇篮到坟墓”的生命周期分析包括以下生命阶段:在中国获取材料和模块制造,运输到新泽西州的假想安装地点,安装,使用,发电,维护,拆卸,以及生命周期结束。结果表明,串联模块比PERC模块产生的每单位电力对整体环境的影响要小。PERC模块的碳足迹为31.3 g CO2当量/kWh,而Tandem模块的碳足迹为18.0 g CO2当量/kWh。分析的其他影响类别包括臭氧消耗、烟雾、酸化、富营养化和对人类健康的影响。提出并评估了几项可持续产品创新(SPI)改进,包括减少硅电池的厚度,在框架中用再生铝代替原铝,在LSC设备的配方中去除锑,以及将制造从中国转移到美国。这些spi进一步减少了串联模块对环境的影响,并在本文中进行了报道。
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引用次数: 0
Study of ALD-grown Tin Oxide as an Electron Selective Layer for NIP Perovskite-Based Solar Cells ald生长氧化锡作为NIP钙钛矿基太阳能电池电子选择层的研究
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938962
Félix-Louis Gayot, E. Bruhat, M. Manceau, E. de Vito, D. Mariolle, Stephanc Cros
This work presents a comparative study between tin(IV) oxide $(mathbf{SnO_{2}})$ thin films deposited either by solution process or by Atomic Layer Deposition (ALD) for an application as an electron selective layer in perovskite/silicon tandem solar cells. This study is motivated by the usually lower performances of solar cells using electron selective layer (ESL) made of ALD-grown $mathbf{SnO_{2}}$ compared to ones using a solution-processed ESL. Chemical, electrical, optical and topographical properties of each type of film were investigated. In an attempt to link thin film properties to device characteristics single-junction perovskite solar cells and perovskite/silicon tandem solar cells were fabricated. Despite the high-quality conductivity and optical properties of ALD-grown $mathbf{SnO_{2}}$, perovskite-based solar cells employing such film showed limited performances. Characterization of perovskite films properties grown on both type of $mathbf{SnO_{2}}$ did not rise significant differences and tend to indicate some hindering factors at the ALD-grown $mathbf{SnO_{2}}$ interface with perovskite. Specifically, a larger workfunction for ALD-grown $mathbf{SnO_{2}}$ may create a potential barrier for electron extraction at perovskite interface
本文介绍了通过溶液法和原子层沉积法(ALD)沉积作为钙钛矿/硅串联太阳能电池电子选择层的锡(IV)氧化物$(mathbf{SnO_{2}})$薄膜的比较研究。这项研究的动机是,与使用溶液处理的ESL相比,使用由ald生长的$mathbf{SnO_{2}}$制成的电子选择层(ESL)的太阳能电池通常性能较低。研究了各类型薄膜的化学、电学、光学和形貌等性能。为了将薄膜性能与器件特性联系起来,制备了单结钙钛矿太阳能电池和钙钛矿/硅串联太阳能电池。尽管ald生长的$mathbf{SnO_{2}}$具有高质量的导电性和光学性能,但使用这种薄膜的钙钛矿基太阳能电池表现出有限的性能。在两种类型的$mathbf{SnO_{2}}$上生长的钙钛矿薄膜性能表征没有显著差异,并且倾向于表明在ald生长的$mathbf{SnO_{2}}$与钙钛矿界面上存在一些阻碍因素。具体来说,ald生成的$mathbf{SnO_{2}}$更大的工作函数可能会在钙钛矿界面上产生电子提取的潜在屏障
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引用次数: 0
Passivating Surface Iodide Defects Slows the CsPbI3 Phase Transformation 钝化表面碘化物缺陷减缓了CsPbI3相变
Pub Date : 2022-06-05 DOI: 10.1109/pvsc48317.2022.9938665
Jeffrey A. Christians, Jonathan Outen, Rory M Campagna, Zachery R Wylie, Peter Ruffolo
Efforts to improve halide perovskite solar cell stability require detailed understanding of all of the various degradation modes that can occur in a device. One degradation mode of note is the perovskite to nonperovskite phase transition. In this work, we demonstrate a simple method to track the kinetics of this in CsPbI3 thin films. We demonstrate that this phase transition is first order with respect to atmospheric water. Moreover, we show the ability to decrease the phase transition rate from 7.5×10–3 s−1 to 1.4×10–3 s−1 by surface iodide treatment of the films. This insight will help the design of more robust perovskite films and continued understanding of this phase transformation will likely be important for efforts aimed at extrapolating accelerated lifetime tests.
为了提高卤化物钙钛矿太阳能电池的稳定性,需要详细了解器件中可能发生的所有各种降解模式。一个值得注意的降解模式是钙钛矿到非钙钛矿的相变。在这项工作中,我们展示了一种简单的方法来跟踪CsPbI3薄膜中的动力学。我们证明了这种相变对于大气中的水是一级的。此外,我们还证明了通过表面碘化物处理薄膜可以降低从7.5×10-3 s−1到1.4×10-3 s−1的相变速率。这一发现将有助于设计更坚固的钙钛矿薄膜,对这种相变的持续理解可能对旨在推断加速寿命测试的努力很重要。
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引用次数: 1
A Model to Predict Daily Snow Albedo Change Over Time 预测每日积雪反照率随时间变化的模型
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938897
C. Pike, D. Riley, L. Burnham
As solar photovoltaic technology is deployed in snowier and more northern locations and bifacial module use continues to increase, ground albedo from snow plays a significant role in the energy output of these systems. Accurately knowing the ground albedo allows for more accurate production models. Here we use multiple years of measured snow and albedo data from 6 locations to develop a snow albedo change model that uses time and temperature as the major inputs.
随着太阳能光伏技术在多雪地区和更北部地区的部署以及双面组件的使用不断增加,地面积雪反照率在这些系统的能量输出中起着重要作用。准确地了解地面反照率可以获得更精确的生产模型。在这里,我们使用来自6个地点的多年积雪和反照率数据来开发一个以时间和温度为主要输入的积雪反照率变化模型。
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引用次数: 0
Results of Environmental-Based PV Soiling Models after Extreme Dust Events: The Case of Saharan Dust Intrusions in Southern Spain 极端沙尘事件后基于环境的PV污染模型的结果:以西班牙南部撒哈拉沙尘入侵为例
Pub Date : 2022-06-05 DOI: 10.1109/pvsc48317.2022.9938938
J. G. Bessa, Álvaro F. Solas, F. A. Cruz, E. Fernández, L. Micheli
Soiling is a major issue that greatly determines the operation and maintenance cost of PV systems. The occurrence of extreme dust events in sites where typically the losses due to soiling are not high can significantly alter the cleaning schedule. In this work, two different environmental-based models are applied to estimate the soiling losses that two recent Saharan dust intrusions caused in a location in southern Spain. During the first one, a peak of PM10 equal to 904 μg/m was reached, and it became the most intense dust event registered in 10 years for both its intensity and its length, as it lasted almost three days. Due to these two factors that led to very low irradiance values during the episode, no measurements from a soiling station installed in the site were available. Therefore, the only approach to quantify the impact of this event was through environmental-based soiling extraction models. The results of these models showed both relatively high differences between them and a strong dependence with the cleaning threshold value. These issues are expected to impact the decision-making about the cleaning of PV modules. For example, non-negligible differences were found when considering a cleaning threshold of 1 mm/day or a cleaning threshold of 10 mm/day. In the first case, only 1 day with significant soiling losses (8.3% using Coello' model) is detected; whereas in the second case, the PV modules are supposed to be notably soiled (losses >=3D 8.3%) during 5 days.
污染是决定光伏系统运行和维护成本的主要问题。在通常因污染造成的损失不高的地点发生极端粉尘事件可以显著改变清洁计划。在这项工作中,应用了两种不同的基于环境的模型来估计最近两次撒哈拉沙尘入侵在西班牙南部某地造成的污染损失。第一次持续了近3天,PM10峰值达到904 μg/m,无论从强度还是时间上看,都是10年来最严重的沙尘事件。由于这两个因素导致事件期间的辐照度值非常低,因此没有从现场安装的污染站获得测量数据。因此,量化这一事件影响的唯一方法是通过基于环境的污染提取模型。这些模型的结果表明,它们之间存在较大的差异,并且与清洗阈值有很强的依赖性。这些问题预计将影响光伏组件清洁的决策。例如,当考虑1毫米/天的清洁阈值或10毫米/天的清洁阈值时,发现了不可忽略的差异。在第一种情况下,仅检测到1天的严重污染损失(使用Coello模型为8.3%);而在第二种情况下,光伏组件应该在5天内被明显污染(损失>=3D 8.3%)。
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引用次数: 0
Investigation of lead-free 2D/3D mixed-dimensional tin perovskite solar cell embedded with plasmonic metal nanoparticles 等离子体金属纳米粒子嵌套二维/三维混合锡钙钛矿太阳能电池的研究
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938955
Atanu Purkayastha, Manoranjan Minz, R. Sonkar, A. T. Mallajosyula
In this work, various metal nanoparticles have been used to improve the efficiency of a single layer 2D/3D mixed-dimensional hybrid tin perovskite solar cell, exploiting the surface plasmon effect. Silvaco TCAD and Lumerical FDTD software have been used for this study. As a first step, the thickness of perovskite layer, without the presence of any nanoparticles, has been optimized using experimentally determined optical constants. It has been found that the best possible efficiency of 14.13% is obtained at 180 nm. At this thickness, the size and position of metal nanoparticles in the perovskite layer have been varied. With spherical silver nanoparticles of 15 nm radius placed at the electron transport layer interface, the light absorption has been significantly enhanced for wavelengths between 450–600 nm and above 800 nm. Owing to this, the maximum possible photocurrent density improved by 7% to 29.64 $mathbf{mA}.mathbf{cm}^{-2}$.
在这项工作中,利用表面等离子体效应,利用各种金属纳米颗粒来提高单层二维/三维混合维混合锡钙钛矿太阳能电池的效率。本研究使用了Silvaco TCAD和Lumerical FDTD软件。作为第一步,在没有任何纳米颗粒存在的情况下,钙钛矿层的厚度已经通过实验确定的光学常数进行了优化。结果表明,在180 nm处效率最高,为14.13%。在此厚度下,金属纳米颗粒在钙钛矿层中的大小和位置发生了变化。在电子传递层界面处放置半径为15 nm的球形银纳米粒子,在450 ~ 600 nm和800 nm以上的波长范围内,银纳米粒子的光吸收显著增强。因此,最大可能光电流密度提高了7%,达到29.64 $mathbf{mA}.mathbf{cm}^{-2}$。
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引用次数: 0
期刊
2022 IEEE 49th Photovoltaics Specialists Conference (PVSC)
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