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2022 IEEE 49th Photovoltaics Specialists Conference (PVSC)最新文献

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Understanding the Solar Cell Contacts With Atmospheric Screen-printed Copper 了解太阳能电池与大气丝网印刷铜的接触
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938719
S. Huneycutt, A. Ebong, K. Ankireddy, R. Dharmadasa, T. Druffel
Although Cu is very close to Ag in conductivity, there are still some concerns with its high diffusivity into Si. There are two Cu ions of focus; interstitial $(mathbf{cu}_{mathbf{i}}{}^{+})$ and substitutional $(mathbf{Cu}_{mathbf{s}}{}^{+})$, whereby, with regard to Si the fast-diffusing impurity is the interstitial, $mathbf{Cu_{i}}^{+}$. An isolated $mathbf{Cu_{i}}^{+}$ acts as a shallow donor, it reacts with impurities and defects to alter the electrical properties of the material. However, Cu passivates shallow acceptors, forms pairs with various impurities, including itself, and precipitates at defects. Thus, these Cu precipitates become strong electron-hole recombination centers. With regard to n-type Si, the Cu impurity precipitates much easier than in p-type Si, provided that several of the $mathbf{Cu}_{mathbf{i}}^{boldsymbol{+,}}mathbf{S}$ precipitate without trapping an electron. The diffusivity of species in the semiconductor generally depends on the time and temperature, thus, a diffusivity of $boldsymbol{7}mathbf{x}boldsymbol{10^{15}}mathbf{cm}^{boldsymbol{-3}}$ can be inferred for Cu at $boldsymbol{600}^{circ}mathbf{C}$ for 20 minutes. For the atmospheric screen-printed Cu solar cell contacts, the sintering is performed on a PERC wafer with a finger width of 83 $boldsymbol{mu} mathbf{m}$ fired at a peak a temperature of $boldsymbol{593}^{circ}mathbf{C}$ at 325 ipm for approximately 2 seconds; thus, the measured diffusion coefficient would be different. More so, since the paste consists of glass frits and Cu powder, the glass must react first with the $mathbf{SiN}_{mathbf{x}}$ to produce the molten glass which would then react with Cu. Since the reaction time is very short, the Cu will not have enough time to diffuse into the Si before cooling down and subsequent sequestration by the reformed glass. STEM will be used to understand the mechanisms which enable or disable the sequestration of Cu and the associated challenges will be discussed. Additionally, the solar cell electrical output parameters comparing the results of sequestered Cu on PERC Si wafers will be presented.
虽然Cu的电导率与Ag非常接近,但其对Si的高扩散率仍然存在一些问题。重点有两个方面;间隙$(mathbf{cu}_{mathbf{i}}{}^{+})$和代换的$(mathbf{cu}_{mathbf{s}}{}^{+})$,其中对于Si来说,快速扩散的杂质是间隙$mathbf{Cu_{i}}^{+}$。一个孤立的$mathbf{Cu_{i}}^{+}$作为一个浅供体,它与杂质和缺陷发生反应,改变材料的电学性质。然而,铜钝化浅受体,与各种杂质形成对,包括其本身,并在缺陷处沉淀。因此,这些Cu沉淀成为强电子-空穴复合中心。如果$mathbf{Cu}_{mathbf{i}}^{boldsymbol{+,}}mathbf{S}$沉淀而不捕获电子,则在n型Si中Cu杂质比在p型Si中更容易析出。半导体中物质的扩散率通常取决于时间和温度,因此,可以推断出Cu在$boldsymbol{600}^{circ}mathbf{C}$下20分钟的扩散率为$boldsymbol{7}mathbf{x}boldsymbol{10^{15}}mathbf{cm}^{boldsymbol{3}}$。对于大气丝网印刷的Cu太阳能电池触点,在指宽为83 $boldsymbol{mu} mathbf{m}$的PERC晶圆上进行烧结,在峰值温度$boldsymbol{593}^{circ}mathbf{C}$ 325 ipm下烧制约2秒;因此,测量的扩散系数会有所不同。更重要的是,由于浆料由玻璃块和铜粉组成,玻璃必须首先与$mathbf{SiN}_{mathbf{x}}$反应,产生熔融玻璃,然后与Cu反应。由于反应时间很短,Cu没有足够的时间扩散到Si中,然后冷却并随后被改造后的玻璃隔离。STEM将用于了解启用或禁用Cu封存的机制,并将讨论相关的挑战。此外,还将比较铜在PERC硅晶片上的结果,并给出太阳能电池的电输出参数。
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引用次数: 0
Accuracy of Potential High Limit Estimation for Solar Plants in the Southeast US 美国东南部太阳能发电厂潜在高限值估算的准确性
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938540
W. Hobbs, David J. Ault, V. Gevorgian, G. Saraswat
Flexible solar operation, where solar photovoltaic (PV) plants follow up- and down-regulation signals, has signifi-cant potential to improve integration of solar into power grids. To optimize operation, it is important to accurately estimate the potential maximum power output, or potential high limit (PHL), of a plant in real time during periods where output has been reduced. As the PHL cannot be directly measured while a plant is curtailed, and it is driven by highly variable weather and plant conditions, model-based estimation methods are subject to errors. An estimation method using a subset of a plant as a reference has been developed by NREL. Here, we evaluate a version of that method using data from several utility-scale plants in the Southeast US spanning up to a full year.
灵活的太阳能运行,即太阳能光伏电站跟进上下调节信号,在改善太阳能与电网的整合方面具有巨大的潜力。为了优化运行,在输出减少期间,实时准确地估计电厂的潜在最大功率输出或潜在高限(PHL)是很重要的。由于PHL不能在植物被修剪时直接测量,而且它是由高度变化的天气和植物条件驱动的,基于模型的估计方法容易出现误差。NREL开发了一种以植物子集为参考的估算方法。在这里,我们使用来自美国东南部几个公用事业规模的工厂长达一整年的数据来评估该方法的一个版本。
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引用次数: 0
Fabrication of ultrathin Ge template for growth of multijunction solar cells based on wafer-scale porous Ge 基于晶圆级多孔锗的多结太阳能电池超薄锗模板的制备
Pub Date : 2022-06-05 DOI: 10.1109/pvsc48317.2022.9938926
Tadeáš Hanuš, J. Arias‐Zapata, B. Ilahi, P. Provost, Alexandre Chapotot, A. Boucherif
Multijunction solar cells (MJSC) currently hold the highest efficiency on the market. However, their widespread in terrestrial applications is getting held back by the high devices cost. A considerable part of the cost mainly comes from the substrate materials such as Ge and GaAs making them nonviable for terrestrial application compared to much cheaper silicon-based solar cells. Consequently, the Ge based MJSC deployment is restrained to niche domains such as spatial applications. Accordingly, the development of nanostructured substrates allowing MJSC detachment and wafer reuse stands out as a promising approach to overcoming these limitations. In this work, we demonstrate the formation of homogenous edge-to-edge porous Ge (PGe) layers on an industry-standard 100 mm wafer-scale produced by bipolar electrochemical etching. The produced nanostructured substrates' properties are easily assessable by production line compatible, fast, and nondestructive techniques such as ellipsometry. The PGe layers have been found to exhibit excellent uniformity over the wafer' surface with a relative variation of 1% in porosity and 2% in thickness. Furthermore, we show that the PGe structural properties can be finely tuned to create on-demand characteristics including the suitability for epitaxial growth. Accordingly, low-temperature growth of ultrathin crystalline Ge layer on top of PGe structure is demonstrated. The fabricated structure has been shown to be compatible with III-V heterostructures growth drawing the way for wafer-scale detachable MJSC and substrate reuse.
多结太阳能电池(MJSC)是目前市场上效率最高的电池。然而,它们在地面上的广泛应用受到高设备成本的阻碍。相当一部分的成本主要来自衬底材料,如锗和砷化镓,与便宜得多的硅基太阳能电池相比,它们不适合地面应用。因此,基于Ge的MJSC部署仅限于空间应用等特定领域。因此,允许MJSC分离和晶圆重复使用的纳米结构衬底的发展是克服这些限制的有前途的方法。在这项工作中,我们展示了通过双极电化学蚀刻在工业标准的100毫米晶圆尺度上形成均匀的边缘到边缘多孔锗(PGe)层。生产的纳米结构衬底的性能很容易通过生产线兼容,快速和非破坏性的技术,如椭偏测量来评估。发现PGe层在晶圆表面表现出极好的均匀性,孔隙率和厚度的相对变化为1%和2%。此外,我们表明,PGe的结构特性可以被微调,以创建按需特性,包括外延生长的适用性。在低温下,在PGe结构上生长出超薄的Ge晶层。制备的结构已被证明与III-V异质结构生长相兼容,为晶圆级可拆卸MJSC和衬底再利用开辟了道路。
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引用次数: 0
A Combined Shading and Radiation Simulation Tool for Defining Agrivoltaic Systems 用于定义农业发电系统的综合遮阳和辐射模拟工具
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938795
Haomiao Wang, Henry J. Williams, X. Bu, K. Max Zhang
Agrivoltaic systems have the potential to resolve rapidly rising global food and energy challenges by co-locating agriculture and solar photovoltaics (PV). In the United States, Massachusetts created the Solar Massachusetts Renewable Target (SMART) Program to incentivize agrivoltaic development. The program relies on a shading-only simulation tool to differentiate agrivoltaic sites from traditional solar farms. In this paper, we demonstrate that radiation must be considered along with shading to identify land suitable for agricultural activity in agrivoltaic systems. To this end, we present a combined shading and radiation simulation tool and show that percent shade does not singularly determine land available for crop growth. Thus, we recommend the SMART Program update their current method for defining agrivoltaic systems to include radiation modeling.
农业光伏系统有潜力通过将农业和太阳能光伏(PV)放在一起来解决快速增长的全球粮食和能源挑战。在美国,马萨诸塞州创建了太阳能马萨诸塞州可再生目标(SMART)计划,以激励农业光伏发展。该项目依靠仅遮阳的模拟工具来区分农业光伏电站和传统太阳能电站。在本文中,我们证明了在农业光伏系统中,必须考虑辐射和遮阳来确定适合农业活动的土地。为此,我们提出了一个综合遮阳和辐射模拟工具,并表明遮阳百分比并不能单独决定作物生长的可用土地。因此,我们建议SMART项目更新他们目前定义农业光伏系统的方法,包括辐射建模。
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引用次数: 1
Perovskite PV Design for Stable Space Operation 稳定空间运行的钙钛矿光伏设计
Pub Date : 2022-06-05 DOI: 10.1109/pvsc48317.2022.9938607
K. VanSant, Ahmad R. Kirmani, J. Patel, L. E. Mundt, D. Ostrowski, Brian M. Wieliczka, Gabriella D. Lahti, M. McGehee, L. Schelhas, J. Luther, T. Peshek, Lyndsey McMillon-Brown
Metal halide perovskites are an emerging technology area for photovoltaic (PV) space applications. The goal of our research is to design a perovskite solar cell (PSC) that can exhibit stable performance, when exposed to space-relevant stress conditions. This presentation will focus on the down-selection of both the contact layers and the encapsulation scheme for potentially space-compatible PSCs.
金属卤化物钙钛矿是光伏空间应用的新兴技术领域。我们的研究目标是设计一种钙钛矿太阳能电池(PSC),当暴露在与空间相关的应力条件下,它可以表现出稳定的性能。本演讲将重点介绍潜在空间兼容psc的接触层和封装方案的下选择。
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引用次数: 0
A Deep Learning Approach for PV Failure Mode Detection in Infrared Images: First Insights 红外图像中PV故障模式检测的深度学习方法:初步见解
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938524
Daniel Rocha, Miguel Lopes, J. Teixeira, P. Fernandes, Modesto Morais, P. Salomé
Large-scale solar power plants require cheap and quick inspections, for this unmanned aerial vehicle (UAV's) for high resolution optical and infrared imaging were introduced in the past years. While using UAV's is fast for image acquisition, image is a time-consuming process where the best of practice today is still for an expert to individually analyze each image. As such, in this work we use computer vision to accelerate this process. We performed an instance segmentation assessment using a pre-trained mask R-CNN for the segmentation of defective modules, and cells, as well as for segmentation and classification of failures. This method was chosen due its good past performance. In this work we created a database from a solar power plant consisting of 42048 modules and an expert analyzed the images. Later on, our computer algorithm results were benchmarked against the expert. Our algorithm achieved a mean average precision (mAP) in defective module segmentation mask of 72.1 % and 47.9 % in segmentation mask of failure type with an intersection over union threshold (IoU) of 0.50, without human interference. The presented preliminary results allow to assess the methodology advantages and drawbacks to increase performance and pave the way to a large-scale study.
大型太阳能发电厂需要廉价和快速的检查,用于高分辨率光学和红外成像的无人机(UAV)在过去几年被引入。虽然使用无人机可以快速获取图像,但图像是一个耗时的过程,目前的最佳实践仍然是由专家单独分析每张图像。因此,在这项工作中,我们使用计算机视觉来加速这一过程。我们使用预训练的掩模R-CNN进行了实例分割评估,以分割有缺陷的模块和细胞,以及分割和分类故障。由于该方法过去表现良好,因此选择了该方法。在这项工作中,我们创建了一个由42048个模块组成的太阳能发电厂的数据库,并由专家分析了这些图像。后来,我们的计算机算法结果与专家进行了基准测试。该算法在不受人为干扰的情况下,缺陷模块分割掩码的平均精度(mAP)为72.1%,故障类型分割掩码的平均精度(mAP)为47.9%,交集超过联合阈值(IoU)为0.50。提出的初步结果允许评估方法的优点和缺点,以提高性能,并为大规模研究铺平道路。
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引用次数: 2
Complex Refractive Index and Complex Dielectric Function Modeling of Film Stack in Perovskite Solar Cells using Spectroscopic Ellipsometry 钙钛矿太阳能电池薄膜堆复折射率和复介电函数的椭偏光谱建模
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938816
Maria Fernanda Villa Bracamonte, J. R. M. Bojorquez, A. Ayón
We report a comprehensive single layer modeling approach to investigate the complex refractive index of ITO, PEDOT:PSS, MAPbI3 perovskite film stack deposited on a glass substrate. The optical constants such as refractive index and extinction coefficient as well as the complex dielectric function are studied by spectroscopy ellipsometry, We propose that spectroscopic ellipsometry characterization can be used at the different stages of the fabrication process of each layer to study the mechanisms that impact the final performance of a photovoltaic device.
我们报告了一种综合的单层建模方法来研究沉积在玻璃衬底上的ITO, PEDOT:PSS, MAPbI3钙钛矿薄膜堆栈的复折射率。利用椭偏光谱法研究了光电器件的折射率、消光系数等光学常数以及复介电函数,提出了在光电器件制造过程的不同阶段采用椭偏光谱法进行表征,以研究影响光电器件最终性能的机制。
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引用次数: 0
Feeder Open-Phase Detection by Smart Inverters 智能逆变器馈线断相检测
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938797
Yiwei Ma, Xiaojie Shi, A. Huque, R. Bründlinger, Ron Ablinger
Inadvertent open phase condition is a concern for distributed energy resources (DER) integration, due to the unregulated voltage on the opened phase. Although IEEE 1547–2018 standard mandates DER to detect and trip for open phase condition at its reference point of applicability (RPA), it may be challenging for DER to detect a feeder (high side of interconnection transformer) open phase condition. This paper presents an improved feeder open phase detection (OPD) method that only utilizes the solar photovoltaic (PV) or energy storage inverter's onboard resources. Controller hardware-in-the-loop (CHIL) results are shown to demonstrate the effectiveness of the proposed OPD algorithm. It is found that the OPD method can successfully detect a feeder open phase condition for $Delta/mathbf{Yg}$, YgNg, and $Delta/Delta$ transformer, but not with $mathbf{Yg}/Delta$ transformer.
在分布式能源集成中,由于开相上的电压不稳定,引起了非故意开相状态的问题。尽管IEEE 1547-2018标准要求DER在其参考适用点(RPA)检测和跳闸开相状态,但DER检测馈线(互连变压器高侧)开相状态可能具有挑战性。提出了一种仅利用太阳能光伏或储能逆变器板载资源的馈线开相检测方法。控制器硬件在环(CHIL)实验结果验证了所提OPD算法的有效性。结果表明,对于$Delta/mathbf{Yg}$、YgNg和$Delta/Delta$变压器,OPD方法可以成功地检测馈线断相情况,而对于$mathbf{Yg}/Delta$变压器则不能。
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引用次数: 0
Barriers to Solar Photovoltaic (PV) Adoption on a National Scale in the United States 美国全国范围内采用太阳能光伏(PV)的障碍
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938533
Casey R. Corrado, E. Holt, L. Schambach
The U.S. Government is facing immense pressure to reduce carbon emissions and shift towards renewable energy sources due to the pressing issue of climate change. Solar Photovoltaic (PV) technology, when implemented at the levels of residential, commercial businesses, and government agencies, has the potential to slow the rate of global warming, one step in addressing the climate crisis. Solar PVs provide an alternative to fossil fuels, with both lower carbon emissions and cost. The falling price of solar energy has made solar PVs increasingly cost effective compared to traditional, non-renewable energy sources. There are, however, a myriad of technological, environmental, political, economic, and social hurdles that prevent wider-spread solar adoption. While several solar-focused government policies and incentives have already been put in place, the government lacks a full understanding of the constraint space preventing widespread solar adoption. Identifying these barriers is a crucial step in developing effective and impactful plans and policy to expedite nation-wide implementation. This work evaluates current barriers to solar PV adoption within the U.S. and provides potential mitigation steps to address them. A list of recommendations for the U.S. federal government are also provided.
由于气候变化的紧迫问题,美国政府面临着减少碳排放和转向可再生能源的巨大压力。太阳能光伏(PV)技术,当在住宅、商业企业和政府机构层面实施时,有可能减缓全球变暖的速度,这是解决气候危机的一步。太阳能光伏提供了化石燃料的替代品,其碳排放和成本都较低。与传统的不可再生能源相比,太阳能价格的下降使得太阳能光伏发电越来越具有成本效益。然而,有无数的技术、环境、政治、经济和社会障碍阻碍了太阳能的广泛采用。虽然一些以太阳能为重点的政府政策和激励措施已经到位,但政府对阻碍太阳能广泛采用的限制空间缺乏充分的了解。确定这些障碍是制定有效和有影响力的计划和政策以加快在全国范围内实施的关键步骤。这项工作评估了目前在美国采用太阳能光伏的障碍,并提供了潜在的缓解措施来解决这些问题。本文还为美国联邦政府提供了一系列建议。
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引用次数: 0
Ultra-Thin and Lightweight CdS/CdTe Solar Cell Fabricated on Ceramic Substrate for Space Applications 用于空间应用的陶瓷基板超薄轻质CdS/CdTe太阳能电池
Pub Date : 2022-06-05 DOI: 10.1109/PVSC48317.2022.9938514
Manoj K. Jamarkattel, A. Phillips, Geethika K. Liyanage, Fadhil K. Alfadhili, Ebin Bastola, V. Plotnikov, A. Compaan, R. Ellingson, M. Heben
Ultra-thin and light weight cadmium telluride (CdTe) solar cells were fabricated on 20-micron thick yttria-stabilized zirconia (3YSZ) substrate in superstrate configuration. Optimization of CdCl2 treatment and copper diffusion were done to enhance the preformation of the device. Due to high reflectance off the substrate surface, anti -reflecting layer was deposited on the front of the device to reduce the reflectance which increase current density. Here, we present ultra-thin and light weight CdS/CdTe solar cells with conversion efficiency of 11.2 % and specific power> 6 kW/kg. This could make CdTe based solar cells applicable for space applications.
在20微米厚的氧化钇稳定氧化锆(3YSZ)衬底上制备了超薄轻质碲化镉(CdTe)太阳能电池。通过优化CdCl2处理工艺和铜扩散工艺来提高器件的预成型性能。由于衬底表面的高反射率,在器件的前部沉积增透层以降低反射率,从而增加电流密度。在这里,我们展示了超薄轻质的CdS/CdTe太阳能电池,其转换效率为11.2%,比功率> 6 kW/kg。这可能使基于碲化镉的太阳能电池适用于太空应用。
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引用次数: 1
期刊
2022 IEEE 49th Photovoltaics Specialists Conference (PVSC)
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