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Polytronic 2005 - 5th International Conference on Polymers and Adhesives in Microelectronics and Photonics最新文献

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Physicochemical, electrical and stability properties of carbon black/polyesterimide thick-film resistors 碳黑/聚亚胺厚膜电阻器的物理化学、电学和稳定性
A. Dziedzic
This paper describes carbon/polyesterimide thick-film resistive composites. Polyesterimide (PEI) resin with high thermal durability served as an insulative matrix whereas medium structure carbon black (MSCB), blend of MSCB and graphite (G), and high structure carbon black (HSCB) have been used as an active phase. Chosen physicochemical investigations, standard electrical measurements (dependence of basic electrical properties on kind and content of conductive filler, curing method and curing temperature) as well as nonstandard electrical methods (1/f noise and voltage nonlinearity properties) and various stability tests have been used for complete description of MSCB/PEI, (MSCB+G)/PEI and HSCB/PEI thick-film resistor series.
介绍了碳/聚酯酰亚胺厚膜电阻复合材料。具有高热耐久性的聚亚胺(PEI)树脂作为绝缘基体,而中结构炭黑(MSCB)、MSCB与石墨(G)的共混物和高结构炭黑(HSCB)作为活性相。采用选定的物理化学研究、标准电学测量(基本电学性能与导电填料种类和含量、固化方法和固化温度的关系)、非标准电学方法(1/f噪声和电压非线性特性)和各种稳定性试验,对MSCB/PEI、(MSCB+G)/PEI和HSCB/PEI厚膜电阻器系列进行了完整的描述。
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引用次数: 2
Film Coating - Large Area Encapsulation Process for Electronics Packaging 薄膜涂层。电子封装用大面积封装工艺
K. Becker, T. Braun, M. Koch, V. Bader, R. Aschenbrenner, H. Reichl
For improved reliability of microelectronics an encapsulation of sensitive structures is crucial, this is true especially for polymer electronics, where oxygen diffusion and water vapor ingress do dramatically influence the electrical performance. For the protection of semiconducting polymers within organic LEDs a glass layer is the method of choice, providing optimized sealing except for the edge areas. Disadvantage of glass as a sealing material is its rigidity and its sensitivity against mechanical stress. For the realization of low cost applications as smart labels / RF ID tags besides barrier properties also mechanical protection is needed to ensure device functionality. This is especially true when these devices need to operate within harsh environment. Various approaches are possible to apply such barrier layers, typically CVD/PVD or spin coating are used, to yield thin, homogeneous layers of encapsulants of 1 to 5 μm thickness. For the high speed encapsulation of large areas also lamination is discussed, where multilayer films are applied using temperature and pressure, layer thickness is in the range of 5 to 30 μm. As a further technology, suited for the deposition of low viscosity liquid barrier materials, film coating processes are proposed. Focus of the technology development described is the application of homogeneous coating on large areas. Expected advantage is the contactless application at high speed on large area substrates, especially useful on substrates showing a 3D topography, as present with devices integrating heterogeneous structures as organic semiconductors (OSC), printed passives or coils.
为了提高微电子器件的可靠性,敏感结构的封装是至关重要的,特别是对于聚合物电子器件,氧气扩散和水蒸气进入会极大地影响其电气性能。为了保护有机led内的半导体聚合物,玻璃层是选择的方法,除了边缘区域外,它提供了优化的密封。玻璃作为密封材料的缺点是它的刚性和对机械应力的敏感性。为了实现低成本应用,如智能标签/射频ID标签,除了屏障特性外,还需要机械保护来确保设备功能。当这些设备需要在恶劣的环境中运行时,尤其如此。有多种方法可以应用这种阻挡层,通常使用CVD/PVD或旋转涂层,以产生厚度为1至5 μm的薄而均匀的封装层。对于大面积的高速封装也讨论了层压,其中使用温度和压力施加多层薄膜,层厚在5至30 μm范围内。作为一种适合于低粘度液障材料沉积的进一步技术,提出了薄膜涂层工艺。技术发展的重点是均匀涂层在大面积上的应用。预期的优势是在大面积基板上高速非接触式应用,特别是在显示3D地形的基板上,如集成有机半导体(OSC),印刷无源或线圈等异质结构的器件。
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引用次数: 0
Study on the Fabrication Process and Reliability Performance of Contactless Smart Card Using Nonconductive Film 非接触式非导电薄膜智能卡的制备工艺及可靠性研究
Y. Ma, Y. Chan
Contactless smart cards are widely used in various applications, such as access control, transit fare payment systems, etc. In order to improve the performance and at the same time to reduce the production cost, research work on the application of new materials and the development of new processes never stops. In this study, the assembly process of contactless smart card using nonconductive adhesive film (NCF) was investigated and adjusted considering the poor performance of PET substrate used in the test in terms of its heat resistance. Pressure cooker test was then performed to further evaluate reliability performances of the card assemblies after being subjected to severe temperature and humidity conditions. The smart card assemblies underwent both mechanical and electrical characterizations during the assembly process and the reliability test. Examinations on surface morphologies and cross-sections by SEM and optical microscope were conducted to understand the failure mechanisms.
非接触式智能卡广泛应用于各种应用,如门禁、交通费用支付系统等。为了在提高性能的同时降低生产成本,对新材料应用的研究工作和新工艺的开发从未停止。本研究针对测试中使用的PET基材耐热性能较差的情况,对非接触式智能卡non - conductive adhesive film (NCF)的组装工艺进行了研究和调整。然后进行高压锅试验,进一步评估卡组件在恶劣温度和湿度条件下的可靠性性能。智能卡组件在装配过程和可靠性测试中进行了机械和电气特性测试。利用扫描电镜和光学显微镜对其表面形貌和横截面进行了检测,以了解其失效机理。
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引用次数: 0
Electrically Conductive Formulations Filled Nano Size Silver Filler for Ink-Jet Technology 用于喷墨技术的纳米银填料的导电配方
A. Moscicki, T. Sobierajski, J. Felba, Józef Kudzia, A. Arp, Wilhelm Meyer
As current studies and analyses imply, the future of modern microelectronics solutions is utterly dependent on nanotechnology within which nano size materials are more and more frequently produced and applied. This results in the unparalleled possibility of creating new, so far impossible to manufacture products as well as application technologies. Consequently, this results in a significant increase in the possibility of miniaturization of elements of electronic systems by reducing the dimensions of its elements themselves as well as increasing the density of their compaction. Polymer composites containing silver particles of single nanometers (several atoms) may be printed with the application of the Ink-Jet method in order to obtain a line or 'points' being electricity conductors or contacts in electronic assembly. The Ink-Jet printing method utilizes the percussive effect of a piezoelectric compressing capillary element within microsecond and thus resulting in sudden 'expenditure' of the dosed composition. During the very dosing process, the dosed portion is affected by acceleration of 105g, which may cause separation of elements of various specific weights from the dosed composition. Therefore, the physically best composition has the features of a specific solution in which the filler conducting electricity (silver) has the dimensions insignificantly differing from the dimensions of the binder in which it is 'suspended'. One of the crucial technical problems is the production of silver particles separated from one another and of adequately small and repetitive at defined time dimensions.
正如目前的研究和分析所暗示的那样,现代微电子解决方案的未来完全取决于纳米技术,在纳米技术中,纳米尺寸的材料越来越频繁地生产和应用。这导致了创造新产品的无与伦比的可能性,到目前为止不可能制造产品以及应用技术。因此,通过减小元件本身的尺寸以及增加其压实密度,电子系统元件小型化的可能性大大增加。含有单纳米银粒子(几个原子)的聚合物复合材料可以用喷墨方法打印,以获得作为电子组装中的电导体或触点的线或“点”。喷墨打印方法利用压电压缩毛细管元件在微秒内的冲击效应,从而导致剂量组合物的突然“消耗”。在加药过程中,加药部分受到105g加速度的影响,这可能导致不同比重的元素从加药组合物中分离出来。因此,物理上最好的组合物具有特定溶液的特征,其中导电填料(银)的尺寸与其“悬浮”的粘合剂的尺寸相差不大。关键的技术问题之一是生产彼此分离的银粒子,并在规定的时间尺度上生产足够小和重复的银粒子。
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引用次数: 38
Cu/LCP Laminated Materials for New Generation FPC 新一代FPC用Cu/LCP层压材料
K. Nanbu, K. Saijo, K. Yoshida, H. Okayama, S. Ozawa, T. Suga
As future materials for flexible printed circuits (FPCs) with high performance, we have studied copper clad lamination (CCL) materials of liquid crystal polymer (LCP) on copper (Cu) foil using a new laminating process, so called, surface activated bonding (SAB) method [1-5]. In previous report, it was found that the loss of peel strength during the heat-resistance test was improved by using copper-0.02% zirconium (Cu-Zr) alloy foil and a thicker sputter of copper-45% nickel (Cu-45Ni) or nickel-20% chromium (Ni-20Cr) alloys [5]. These improved materials showed excellent interface conductivity at high frequency and etching property. In this report, we tried to produce more improved materials with different sputtering metals and investigated various characteristics of the laminated materials such as scattering parameter (S21), etching property, and dimensional stability for the FPCs. It was clarified that the sputter metal of higher nickel content alloys prevented from the interface oxidation of the Cu-Zr alloy foil/LCP film laminated materials (Cu-Zr/LCP materials) after heat-resistance test. Especially in copper-80% nickel (Cu-80Ni)or nickel-10% chromium (Ni-10Cr) alloy, the peel strength of the laminated materials kept around 500N/m even after 144 hour heating. The S21 of micro-strip line of the laminated materials showed half attenuation when comparing with that produced by the conventional heat bonding method. It is also shown that the Cu-Zr materials produced by the SAB method (SAB material) have excellent etching property and dimensional stability.
作为未来高性能柔性印刷电路(fpc)的材料,我们利用一种新的层压工艺,即所谓的表面活化键合(SAB)方法,在铜(Cu)箔上研究了液晶聚合物(LCP)的覆铜层压(CCL)材料[1-5]。在之前的报道中发现,使用铜-0.02%锆(Cu-Zr)合金箔和更厚的铜-45%镍(Cu-45Ni)或镍-20%铬(Ni-20Cr)合金溅射可以改善耐热试验中剥离强度的损失[5]。这些改进的材料表现出优异的高频界面导电性和蚀刻性能。在本报告中,我们尝试用不同的溅射金属制备更多的改进材料,并研究了层合材料的散射参数(S21)、蚀刻性能和尺寸稳定性等特性。通过对Cu-Zr合金箔/LCP膜层合材料(Cu-Zr/LCP材料)的耐热性试验,阐明了高镍含量合金溅射金属对Cu-Zr合金箔/LCP膜层合材料界面氧化的抑制作用。特别是在铜-80%镍(Cu-80Ni)或镍-10%铬(Ni-10Cr)合金中,即使加热144小时,层合材料的剥离强度仍保持在500N/m左右。叠层材料微带线的S21与传统热粘合方法相比衰减了一半。采用SAB法制备的Cu-Zr材料(SAB材料)具有良好的蚀刻性能和尺寸稳定性。
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引用次数: 0
Reliability Testing of Polytronics Components in the Micro-Nano Region 多电子元件的微纳可靠性测试
B. Michel, R. Dudek, H. Walter
Reliability testing of polytronics components has found much attention recently, because of the growing practical importance of polytronics. There has been a growing need for a better knowledge of local materials parameters, local deformation as well stress fields. Interface crack and delamination phenomena have also moved to the focus of reliability estimations for polytronics. Creep and fatigue on the other hand can be described by means of local micro- and nanomaterials testing combined with advanced reliability and life-time concepts. The authors are going to discuss a combined experimental and simulation approach to improve the classical reliability analysis. The approach is based upon various digital image correlation (DIC) techniques, e.g. microDIC, nanoDIC and fibDIC, as well as related methods involving AFM, SEM or FIB, too.
近年来,由于多电子元件在实际应用中的重要性日益提高,多电子元件的可靠性测试受到越来越多的关注。人们越来越需要更好地了解局部材料参数、局部变形以及应力场。界面裂纹和分层现象也成为多电子可靠性估计的焦点。另一方面,蠕变和疲劳可以通过局部微纳米材料试验与先进的可靠性和寿命概念相结合来描述。作者将讨论一种实验与仿真相结合的方法来改进经典的可靠性分析。该方法是基于各种数字图像相关(DIC)技术,如微DIC、纳米DIC和fibDIC,以及涉及AFM、SEM或FIB的相关方法。
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引用次数: 3
Sol-gel materials for opto(electronic) applications 光电应用的溶胶-凝胶材料
K. Maruszewski
Conventional glass preparation requires melting of precursors at high temperatures, rapid cooling and subsequent vitrification of the glassy material. This procedure highly restricts choice of substances which can be entrapped in the glass products. Basically only metal oxides and some inorganic salts can survive such drastic conditions avoiding thermal decomposition. Furthermore, the way in which conventional glass is produced makes thin films preparation extremely cumbersome and the only method of preparation of porous classical glasses requires etching or partial dissolving (e.g. Vycor® glass). On the other hand glass and glassy materials possess several useful features for e.g. optical applications such as transparency, homogeneity, mechanical sturdiness, high refractive index etc. An alternative approach to glass and glass-like materials production is offered by the sol-gel technology. The process itself is known for more than a century, but it has gained a new importance in the last two decades after pioneering results of Dislich. He and other researchers improved the chemistry of the process so much that it is now possible to obtain samples in days (or even hours — in case of thin films) rather than months (or years) like in the case of the early samples. The sol-gel technique is based on hydrolysis of liquid precursors and formation of colloidal sols. The precursors are usually organosilicates (e.g. TEOS — tetraethoxysilane) giving silicate sol-gel materials. However, the method is not restricted to the silica compounds — for example precursors based on Ti, Zr, V etc.
传统的玻璃制备需要在高温下熔化前驱体,快速冷却并随后玻璃化材料的玻璃化。这一程序严格限制了玻璃制品中可能夹带的物质的选择。基本上,只有金属氧化物和一些无机盐能在如此极端的条件下生存,避免热分解。此外,传统玻璃的生产方式使得薄膜制备非常繁琐,制备多孔经典玻璃的唯一方法需要蚀刻或部分溶解(例如Vycor®玻璃)。另一方面,玻璃和玻璃材料具有一些有用的特性,例如光学应用,如透明度,均匀性,机械坚固性,高折射率等。溶胶-凝胶技术为玻璃和类玻璃材料的生产提供了另一种方法。这个过程本身已经有一个多世纪的历史了,但在过去的二十年里,在迪利希的开创性成果之后,它获得了新的重要性。他和其他研究人员极大地改进了这一过程的化学性质,现在可以在几天(甚至几小时——如果是薄膜)内获得样品,而不是像早期的样品那样几个月(或几年)。溶胶-凝胶技术是基于液体前体的水解和胶体溶胶的形成。前驱体通常是有机硅酸盐(如TEOS -四乙氧基硅烷),形成硅酸盐溶胶-凝胶材料。然而,该方法并不局限于二氧化硅化合物-例如基于Ti, Zr, V等的前驱体。
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引用次数: 1
Reduced Amount of Conductive Ink with Gridded Printed Antennas 减少网格印刷天线的导电油墨量
J. Sidén, T. Olsson, A. Koptioug, Hans-Erik Nilsson
It becomes more and more common to print tag antennas using electrically conductive ink for mass-produced Radio Frequency IDentification (RFID) tags. Electrical properties of the ink are mostly determined by conductive (e.g. silver) particles mixed into the ink solution. Since silver is relatively expensive it is desirable to minimize the amount of ink used per antenna. This paper illustrates how the printed conductor area of the antenna can be reduced by applying a grid pattern to an existing antenna geometry and to what extent the gridding can be performed without significantly degrading of the antenna electrical properties. Two common antenna structures are used as an example. It is also shown that by slightly modifying the original antenna geometry it is possible to even further reduce the amount of used ink.
在批量生产的射频识别(RFID)标签中,使用导电油墨打印标签天线越来越普遍。油墨的电性能主要是由混合在油墨溶液中的导电颗粒(如银)决定的。由于银是相对昂贵的,因此最好尽量减少每个天线所用的墨水量。本文说明了如何通过将网格图案应用于现有天线几何形状来减少天线的印刷导体面积,以及在不显着降低天线电性能的情况下可以执行网格的程度。以两种常见的天线结构为例。还表明,通过稍微修改原始天线几何形状,可以进一步减少墨水的使用量。
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引用次数: 38
The effect of aging process on the parameters of a thin film optoelectronic NAND logical gate 老化过程对薄膜光电NAND逻辑门参数的影响
Z. Porada
An optoelectronic logical gate NAND composed of thin film photoconductive (PC) and electroluminescent (EL) elements. In the system was supplied with sinusoidal voltage with equal values of amplitude and frequency. The input signals were two rectangular light pulses, illuminating the respective photoconductive elements, and the output signal was the luminance of the electro-luminescent cell. The process of natural aging, which caused changes in parameters of PC elements, influenced also the changes in characteristics of the system composed of these elements. For EL element subjected to aging in normal conditions without applied voltage, the luminance of the light was lower by about 20% than for element immediately after their preparation. A variation of the parameters of PC and EL elements by the aging process caused then a decrease of the signal on the output of NAND gate and also an increase in the lag of the output signal in relation to the input signal.
一种由薄膜光导(PC)和电致发光(EL)元件组成的光电逻辑门NAND。系统由幅值和频率相等的正弦电压供电。输入信号为两个矩形光脉冲,分别照亮各自的光导元件,输出信号为电致发光电池的亮度。自然老化过程引起PC元件参数的变化,也影响了由这些元件组成的系统特性的变化。在无外加电压的正常条件下老化的EL元件,其发光亮度比刚制备后的元件低20%左右。老化过程导致PC和EL元件参数的变化,导致NAND门输出信号减小,输出信号相对于输入信号的滞后增大。
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引用次数: 0
A simple method to simulate polymer field-effect transistors 一种模拟聚合物场效应晶体管的简单方法
H. Qiu, R. Meixner, H. Goebel, W. Klix, R. Stenzel
The paper describes a simple method for simulating organic field-effect transistors. In contrast to so far developed models, which require modifications of the source code of the simulator, we propose a model which uses a gate voltage dependent charge carrier mobility. This approach can be implemented in conventional drift-diffusion device simulator. The verification of this method was performed with "bottom contact"(BOC) polymer field-effect transistors and the device simulator "SIMBA" [1]. The simulation results are in good agreement with the measurements.
本文介绍了一种简单的模拟有机场效应晶体管的方法。与迄今为止开发的需要修改模拟器源代码的模型相反,我们提出了一个使用栅极电压依赖电荷载流子迁移率的模型。该方法可以在传统的漂移扩散装置模拟器中实现。用“底部接触”(BOC)聚合物场效应晶体管和器件模拟器“SIMBA”[1]对该方法进行了验证。仿真结果与实测结果吻合较好。
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引用次数: 1
期刊
Polytronic 2005 - 5th International Conference on Polymers and Adhesives in Microelectronics and Photonics
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