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Indentation : techniques expérimentales et modélisation multiéchelle 压痕:实验技术和多尺度建模
IF 0.9 Q4 Materials Science Pub Date : 2019-01-01 DOI: 10.1051/MATTECH/2019005
Anne Habraken, A. Mertens, V. Vitry, Marie-Stéphane Colla, E. Bourhis
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引用次数: 2
Étude de l’effet du temps de traitement alcalin de fibres palmier sur le comportement mécanique des matériaux à base d’argile rouge de la région de M’sila 棕榈纤维碱性处理时间对M’sila地区红粘土基材料力学性能的影响研究
IF 0.9 Q4 Materials Science Pub Date : 2019-01-01 DOI: 10.1051/mattech/2019031
Zainate Koadri, Azzedine Benyahia, Nadir Deghfel, K. Belmokre, B. Nouibat, Ali Redjem
Ce travail s’inscrit dans le développement de matériaux locaux, telle que la fibre végétale (fibre de palmier) et l’argile rouge du sud Algérien, largement utilisées dans la préparation des briques, comme matériaux de construction rurale. Les fibres végétales possèdent des propriétés très intéressantes, elles sont : renouvelables, biodégradables et le rapport coût/légèreté faible. Leurs propriétés mécaniques sont très importantes. Cependant, le problème prédominant dans ce type de matériaux composites est la faible adhésion de l’interface matrice-fibre, attribuée probablement, à la nature de la surface et au caractère hydrophobe des fibres naturelles, conduisant ainsi, à des propriétés mécaniques faibles pour le composite envisagé. Le but de cette étude consiste à traiter la fibre de palmier par une solution basique d’hydroxyde de sodium (NaOH 4 % [m/v]) durant des périodes variables : 3, 7, 24 et 48 heures, afin d’améliorer l’adhésion interfaciale. Les résultats obtenus à partir des essais réalisés sur le composite renforcé par les fibres de palmier traitées durant 7 h ont montré une nette augmentation quant à la résistance, à la flexion et à la compression ; cette croissance est respectivement de l’ordre de 57 et 60 %, comparativement au composite renforcé par les fibres non traitées. On peut déduire que les fibres de palmier peuvent être considérées comme l’un des matériaux appropriés pour le renforcement de l’argile.
这项工作是当地材料开发的一部分,如植物纤维(棕榈纤维)和阿尔及利亚南部的红粘土,广泛用于准备砖,作为农村建筑材料。植物纤维具有非常有趣的特性,它们是:可再生、可生物降解和低成本/轻比。它们的力学性能非常重要。然而,这类复合材料的主要问题是母纤维界面的低附着力,这可能是由于天然纤维的表面性质和疏水特性,从而导致所考虑的复合材料的机械性能较差。本研究的目的是用氢氧化钠碱性溶液(4% NaOH [w /v])对棕榈纤维进行不同时间的处理:3、7、24和48小时,以提高界面附着力。对棕榈纤维增强复合材料进行7小时处理的试验结果表明,其强度、弯曲和压缩性能均有显著提高;与未经处理的纤维增强复合材料相比,这一增长率分别为57%和60%。可以推断,棕榈纤维可以被认为是一种合适的粘土加固材料。
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引用次数: 1
Contraintes résiduelles et comportement mécanique de revêtements nickel-bore 镍硼涂层的残余应力和力学行为
IF 0.9 Q4 Materials Science Pub Date : 2019-01-01 DOI: 10.1051/MATTECH/2019016
A. Montagne, V. Vitry, Luiza Bonin, Muhammad Zeeshan Mughal, M. Sebastiani, Edoardo Bemporad, A. Iost, Mariana Henriette Staia
Deux revêtements à base nickel obtenus par des bains réducteurs, l’un brut et l’autre ayant subi un traitement thermique sont étudiés. L’essai d’indentation a été mis en œuvre pour caractériser la dureté et le module de Young de ces dépôts. Les résultats montrent une bonne homogénéité des propriétés mécaniques dans l’épaisseur du revêtement, alors que le traitement thermique a eu pour effet d’augmenter sa dureté et son module de façon significative. Les contraintes résiduelles dans les revêtements sont étudiées par la méthode du micro anneau incrémental. Les contraintes calculées sont faibles, dispersées et ne semblent pas dépendre du traitement thermique. En l’absence de contraintes résiduelles avant et après traitement thermique, les variations de propriétés mécaniques ont été attribuées à la modification microstructurale du revêtement et à la précipitation de phases dures.
研究了两种用还原浴获得的镍基涂层,一种是未加工的,另一种是热处理的。采用压痕试验来表征这些沉积物的硬度和杨氏模量。结果表明,涂层的力学性能在厚度上具有良好的均匀性,而热处理显著提高了涂层的硬度和模量。采用增量微环法研究了涂层中的残余应力。计算的应力很小,分散,似乎不依赖于热处理。在热处理前后没有残余应力的情况下,力学性能的变化归因于涂层的微观组织变化和硬相的析出。
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引用次数: 0
Synthesis, performance and growth mechanism of silver nanoparticle coated SERS fiber probe 纳米银涂层SERS纤维探针的合成、性能及生长机理
IF 0.9 Q4 Materials Science Pub Date : 2019-01-01 DOI: 10.1051/MATTECH/2018061
Mengmei Geng, Yuting Long, Tongqing Liu, Zijuan Du, Hong Li, Zirui Liu, Yahong Xie
Surface-enhanced Raman Scattering (SERS) fiber probe provides abundant interaction area between light and materials, permits detection within limited space and is especially useful for remote or in situ detection. A silver decorated SERS fiber optic probe was prepared by hydrothermal method. This method manages to accomplish the growth of silver nanoparticles and its adherence on fiber optic tip within one step, simplifying the synthetic procedure. The effects of reaction time on phase composition, surface plasmon resonance property and morphology were investigated by X-ray diffraction analysis (XRD), ultraviolet-visible absorption spectrum (UV-VIS absorption spectrum) and scanning electron microscope (SEM). The results showed that when reaction time is prolonged from 4–8 hours at 180 °C, crystals size and size distribution of silver nanoparticles increase. Furthermore, the morphology, crystal size and distribution density of silver nanoparticles evolve along with reaction time. A growth mechanism based on two factors, equilibrium between nucleation and growth, and the existence of PVP, is hypothesized. The SERS fiber probe can detect rhodamin 6G (R6G) at the concentration of 10−6 M. This SERS fiber probe exhibits promising potential in organic dye and pesticide residue detection.
表面增强拉曼散射(SERS)光纤探头提供了丰富的光与材料之间的相互作用区域,允许在有限的空间内进行检测,特别适用于远程或原位检测。采用水热法制备了银装饰SERS光纤探针。该方法在一步之内完成了银纳米颗粒的生长及其在光纤尖端的附着,简化了合成过程。采用x射线衍射分析(XRD)、紫外-可见吸收光谱(UV-VIS吸收光谱)和扫描电子显微镜(SEM)研究了反应时间对相组成、表面等离子体共振特性和形貌的影响。结果表明:在180℃下,反应时间从4 ~ 8 h延长,银纳米颗粒的晶粒尺寸和粒径分布增大;此外,银纳米粒子的形貌、晶粒尺寸和分布密度随反应时间的变化而变化。提出了一种基于成核与生长平衡和PVP存在两种因素的生长机制。SERS光纤探头可以检测到浓度为10 ~ 6 M的罗丹明6G (R6G)。该SERS纤维探针在有机染料和农药残留检测中具有广阔的应用前景。
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引用次数: 0
An estimation of the amount of dissipated alloy elements in special steel from automobile recycling 汽车回收特殊钢中合金元素耗散量的估算
IF 0.9 Q4 Materials Science Pub Date : 2019-01-01 DOI: 10.1051/MATTECH/2019007
Zhengyang Zhang, K. Takeyama, H. Ohno, K. Matsubae, K. Nakajima, T. Nagasaka
According to the concept of a circular economy, further promotion of reuse and recycling might aid in closing the loop. However, material recycling may cause various types of material losses due to thermodynamic limitations and product complexity. In this study, we focused on automobile engines and their reuse, with the aim of quantifying the amount of dissipated steel alloy and its constituent elements (nickel and chromium) from the engine recycling process. We also elaborated upon their dissipation paths by using the MaTrace model [S. Nakamura, et al., MaTrace: Tracing the fate of materials over time and across products in open-loop recycling, Environ. Sci. Technol. 48, 7207 (2014)]. We evaluated the impact mitigation of material dissipation and the effects of reuse on the extension of product service life. We found that 22% of steel, 21% of nickel, and 63% of chromium was dissipated in total after 50 years; typically, nickel dissipates during the recovery process while chromium does so during the refinery process. Although the impacts on the reduction of material losses remained nearly the same after replacing 40 of 100% material recycling to parts reuse, greater possibilities could be achieved with respect to the service life extension of products when compared with 100% recycling.
根据循环经济的概念,进一步促进再利用和再循环可能有助于闭合循环。然而,由于热力学的限制和产品的复杂性,材料回收可能会造成各种类型的材料损失。在本研究中,我们将重点放在汽车发动机及其再利用上,旨在量化发动机回收过程中耗散的钢合金及其组成元素(镍和铬)的数量。我们还利用MaTrace模型详细阐述了它们的耗散路径[S]。Nakamura等人。, MaTrace:在开环回收中追踪材料随时间和产品的命运,Environ。科学。工程技术学报,2014,37(2)。我们评估了材料耗散的影响缓解和重复使用对延长产品使用寿命的影响。我们发现,在50年后,22%的钢、21%的镍和63%的铬总共消散了;通常,镍在回收过程中消散,而铬在精炼过程中消散。虽然在将100%材料回收的40%替换为零件再利用后,对减少材料损失的影响几乎保持不变,但与100%回收相比,在延长产品使用寿命方面可以实现更大的可能性。
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引用次数: 4
Optimisation des propriétés mécaniques de matériaux polymériques par les mélanges et effet bénéfique du vieillissement thermique 通过共混优化聚合物材料的力学性能和热老化的有益作用
IF 0.9 Q4 Materials Science Pub Date : 2019-01-01 DOI: 10.1051/mattech/2020001
F. Djeddi, M. Mohellebi, A. Ouibrahim
On cherche ici les propriétés mécaniques optimales de matériaux polymériques par mélangeage mécanique de deux polypropylènes et leur amélioration sous l’effet du vieillissement thermique. Ces mélanges de polypropylène homopolymère (PPH) et de polypropylène copolymère (PPC) sont élaborés sans additif ni compatibilisant. Leurs températures de fusion et leurs indices de fluidité sont déterminés par caractérisation physico-chimique. Les valeurs trouvées suggèrent l’injection comme procédé d’élaboration. Les caractérisations chimique et mécanique ont mis en évidence d’une part, la miscibilité des deux polymères et, d’autre part, des propriétés mécaniques intéressantes des deux polymères. Le PPH présente une bonne résistance à la traction avec un grand allongement à la rupture, mais une faible résistance aux chocs. Le PPC manifeste une bonne résistance aux chocs avec une faible contrainte limite élastique et un faible allongement à la rupture. L’introduction de 30 % de PPC dans la matrice PPH conduit, relativement au PPH, à accroître de 94 % la résistance aux chocs pour une diminution de 6 % seulement de la contrainte limite élastique et du module d’élasticité, l’allongement à la rupture restant égal à celui du PPH. Le vieillissement thermique accéléré améliore la rigidité et la contrainte limite élastique, mais diminue la résilience et l’allongement à la rupture.
通过将两种聚丙烯机械混合,并通过热老化改善聚合物材料的力学性能,寻求聚合物材料的最佳力学性能。这些均聚聚丙烯(PPH)和共聚聚丙烯(PPC)的混合物是在没有添加剂或增容剂的情况下制备的。它们的熔化温度和流动指数是通过物理化学表征确定的。发现的值表明注入是一种制备过程。化学和力学表征一方面表明了两种聚合物的混溶性,另一方面表明了两种聚合物有趣的力学性能。PPH具有良好的抗拉强度,断裂伸长率大,但抗冲击能力低。PPC具有良好的抗冲击性能,屈服应力低,断裂伸长率低。与PPH相比,在PPH基体中加入30%的PPC可使抗冲击性能提高94%,但屈服应力和弹性模量仅降低6%,断裂伸长率与PPH相同。加速热时效提高了刚度和屈服应力,但降低了韧性和断裂伸长率。
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引用次数: 0
Retour sur les Journées Annuelles de la SF2M 2019 回顾2019年SF2M年度日
IF 0.9 Q4 Materials Science Pub Date : 2019-01-01 DOI: 10.1051/mattech/2020010
D. Quantin
Les Journées Annuelles de la SF2M 2019 se sont déroulées à Paris (Chimie Paris Tech) du 21 au 23 octobre. Plus de 150 participants ont pu assister à 50 présentations scientifiques dont 3 plénières, 1 conférence plénière sur l’histoire des matériaux et table ronde sur les carrières, organisée par le groupe « Jeunes » de la SF2M. Seize posters faisant l’objet d’un concours ont aussi été présentés. Les présentations scientifiques étaient regroupées en 3 thèmes génériques : Fabrication additive, de la fabrication de la matière première à la pièce fonctionnelle ; Ténacité et rupture brutale ; Mise en forme, microstructure et propriétés d’usage des superalliages base nickel polycristallins.
2019年SF2M年会于10月21日至23日在巴黎(Chimie Paris Tech)举行。超过150名与会者参加了由SF2M青年小组组织的50个科学报告,包括3个全体会议、1个关于材料历史的全体会议和关于职业的圆桌会议。还有16张海报参加了比赛。科学报告分为3个通用主题:增材制造,从原材料制造到功能部件;韧性和突然断裂;多晶镍基高温合金的成形、显微组织及使用性能。
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引用次数: 0
Palimpsest and heterotopia, metaphors of the Circular Economy 重写本和异托邦,循环经济的隐喻
IF 0.9 Q4 Materials Science Pub Date : 2019-01-01 DOI: 10.1051/mattech/2019026
J. Birat
Words like palimpsest or heterotopia do not belong to the working vocabulary of materials or engineering sciences: they are used in Social Sciences and Humanities (SSH). A palimpsest is a manuscript written on an older document, the text of which has been erased. Heterotopia is a young word forged by Michel Foucault in 1967 to describe a closed space, the boundaries of which mark a discontinuity in terms of behavior: a jail or a monastery are thus a heterotopia. The Circular Economy (CE) is an essential concept in the framework of the ecological transition, pulled by a series of converging economic, ecological and political drivers. It is usually described as the adoption of a circular model of production to replace the “linear model”, but also as the new buzzword to describe material efficiency, the 3-R rule, the zero-waste ideal, the concepts of lean or frugal design or their reformulation by the Ellen Macarthur Foundation, as a societal challenge and an ethical necessity. Materials producers claim that they have been practicing the Circular Economy since long before the expression was ever invented, thus à la Monsieur Jourdain, etc. The point of this paper is to describe the Circular Economy as a palimpsest and as a heterotopia and to use the metaphors, if indeed they are only metaphors, to highlight some of the less obvious features of the CE. A palimpsest is a parchment or a papyrus, which is used several times to support a series of consecutive texts. Secondary raw materials are like a palimpsest, because there are retrieved from a previous life and used again in a second life: a new artefact made from that material is like a new text written on/with this material – a metaphor also used, mutatis mutandis, in expressions like 3-D printing or laser scribing. Some interesting features of the CE pointed out by the metaphor: a the palimpsest can be used several times, like a material can be recycled several times; the concept of the palimpsest posits that the parchment is somehow more important than the text that is written on it, therefore a material is more important than the goods that are made of it; the palimpsest was used before the invention of paper and, similarly, the Circular Economy was the standard model before mass production of cheap consumer goods imposed the so-called “linear model”; a palimpsest keeps a fragmented memory of the past, in the same way as recycled material maintains a link to its past lives, through its composition in tramp elements. Examples of heterotopia are a prison or a cemetery. The Circular Economy defines a space where a particular material/element exists in its various avatars, impersonations and reincarnations and this may tentatively be worked out as a heterotopia. This is a more complex endeavor than discussing the palimpsest metaphor, but a potentially more fruitful one. Foucault has provided criteria defining heterotopia which can help us explore the analogy: particularly the point that such a space i
像“重写本”或“异质乌托邦”这样的词不属于材料科学或工程科学的工作词汇:它们用于社会科学和人文科学(SSH)。重写本是写在旧文件上的手稿,其文本已被擦掉。异托邦(Heterotopia)是米歇尔·福柯(Michel Foucault)在1967年创造的一个年轻词,用来描述一个封闭的空间,其边界标志着行为的不连续性:因此,监狱或修道院是一个异托邦。循环经济(CE)是生态转型框架中的一个重要概念,受到一系列经济、生态和政治因素的共同推动。它通常被描述为采用循环生产模式来取代“线性模式”,但也作为描述材料效率的新流行语,3-R规则,零浪费理想,精益或节俭设计的概念或由艾伦麦克阿瑟基金会重新制定的概念,作为社会挑战和道德必要性。材料生产商声称,早在循环经济这个词被发明出来之前,他们就已经在实践循环经济了,例如,《Jourdain先生》等。本文的重点是将循环经济描述为一个重写本和一个异托邦,并使用隐喻,如果它们确实只是隐喻的话,以突出行政长官的一些不太明显的特征。重写本是一种羊皮纸或纸莎草,它被多次使用来支持一系列连续的文本。二手原材料就像一本重写本,因为它们是从前世中提取出来的,并在第二世中再次使用:用这种材料制成的新人工制品就像用这种材料写的新文本——在进行必要的修改后,这个隐喻也被用在3d打印或激光划线等表达中。这个比喻指出了CE的一些有趣的特征:a重写本可以多次使用,就像一种材料可以多次回收一样;重写本的概念假定羊皮纸在某种程度上比写在上面的文字更重要,因此一种材料比由它制成的商品更重要;在纸发明之前,人们就使用了重写本;同样,在廉价消费品的大规模生产强加所谓的“线性模式”之前,循环经济是标准模式;重写本保留了对过去的碎片记忆,就像回收材料通过其流浪元素的组成来保持与过去生活的联系一样。异托邦的例子是监狱或墓地。循环经济定义了一个空间,在这个空间中,特定的材料/元素以其各种化身、模仿和转世存在,这可能暂时被设计成一个异托邦。这是一个比讨论改写本比喻更复杂的努力,但可能更有成果。福柯提供了定义异托邦的标准,可以帮助我们探索这个类比:特别是这样一个空间要么是幻觉的空间,要么是完美的空间。这种分析是原创的,因为它将材料和SSH概念混合在一起,从而符合SAM会议所关注的材料与社会之间的前沿探索。
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引用次数: 3
Towards a sustainable material use in the automotive industry: Life Cycle Costing and socio-technical approach to material use 迈向可持续的材料使用在汽车工业:生命周期成本和社会技术方法的材料使用
IF 0.9 Q4 Materials Science Pub Date : 2019-01-01 DOI: 10.1051/mattech/2019027
N. Iken, Stéphane Morel, Franck Aggeri
The purpose of the article is twofold. We first present a Life Cycle Costing methodology applied at different scales to compare between design options in terms of materials use: in an automobile vehicle part, a whole vehicle, and a car manufacturer’s portfolio. The Life Cycle Costs consider costs for different stakeholders, including environmental damage costs (supported by the civil society), fuel expenses (supported by the customer) and materials costs (supported by the car manufacturer). The second objective of the article is to bring a management and socio-technical vision to the issue of material use in the automobile industry, in order to challenge the idea that all decisions regarding material use depend on purely technical and economic criteria. Through a qualitative research, we investigated the barriers to material efficiency and integrating the environmental criterion in decision making from a French car manufacturer’s perspective. Within the same company, we also collected material experts’ feedbacks on the LCC tool developed in the first Part, both in terms of methodology and potential integration in decision-making.
这篇文章的目的是双重的。我们首先提出了一种应用于不同尺度的生命周期成本计算方法,以比较材料使用方面的设计选项:汽车部件、整车和汽车制造商的产品组合。生命周期成本考虑不同利益相关者的成本,包括环境破坏成本(由民间社会支持)、燃料费用(由客户支持)和材料成本(由汽车制造商支持)。本文的第二个目标是为汽车工业的材料使用问题带来管理和社会技术的愿景,以挑战所有关于材料使用的决定取决于纯粹的技术和经济标准的想法。通过定性研究,我们从一家法国汽车制造商的角度考察了材料效率和环境标准在决策中的整合障碍。在同一家公司内,我们还收集了材料专家对第一部分中开发的LCC工具的反馈,包括方法论和决策中的潜在集成。
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引用次数: 2
Fundamentals for the development of impact categories for the application of LCA in space − space debris 为在空间中应用LCA制定影响类别的基本原则-空间碎片
IF 0.9 Q4 Materials Science Pub Date : 2019-01-01 DOI: 10.1051/MATTECH/2019011
N. Ko, Raed Bouslama, T. Betten, Simon Pfeuffer
The measurable environmental impacts associated with space travel are still relatively low, compared to the total anthropogenic emissions. Yet, its significance will increase with a general increase in space travel. State-of-the-art assessments of space systems are limited to a cradle-to-launch scope and need to be extended to cover the whole life cycle. Previous work established that Life Cycle Assessment is a suitable tool to cover these additional impacts, with the impacts of space debris being identified as the most relevant at the moment. First, the work by Maury et al. on orbital scarcity, developing impact pathways of space debris as an impact on resource depletion, is discussed. Afterwards, this study takes an anthropocentric view and impact pathways of space debris as an impact on human health are developed. The two different areas of damage by space debris in space by collision and during the re-entry were identified and discussed separately. The chosen impact category for both damage categories is disability-adjusted life years (DALY). Calculation approaches for the physical damage caused in space and during re-entry are developed. To calculate the impacts of toxic and radioactive substances that are emitted or produced by collision or re-entry further research is needed. The work of Maury et al. complements the indicators, developed in this study. Yet, not all of the impacts of space debris are completely covered and need to be studied further. Nevertheless, as a next step towards integrating the impacts of space debris a practical implementation assessing changes to orbital scarcity and potential impacts on human health by space debris is considered as feasible and important.
与人为排放总量相比,与太空旅行相关的可测量环境影响仍然相对较低。然而,它的重要性将随着太空旅行的普遍增加而增加。对空间系统的最新评估仅限于从摇篮到发射的范围,需要扩大到包括整个生命周期。先前的工作确定,生命周期评估是涵盖这些额外影响的合适工具,目前确定空间碎片的影响是最相关的。首先,讨论了Maury等人在轨道稀缺性方面的工作,即发展空间碎片对资源枯竭的影响途径。随后,本研究采取以人类为中心的观点,并制定了空间碎片对人类健康影响的影响途径。分别确定并讨论了空间碎片在空间中因碰撞和在重返大气层时造成的两个不同领域的损害。两个损害类别所选择的影响类别是残疾调整生命年(DALY)。提出了空间和再入过程中物理损伤的计算方法。为了计算因碰撞或再入而排放或产生的有毒和放射性物质的影响,需要进一步的研究。Maury等人的工作补充了本研究中制定的指标。然而,并非所有空间碎片的影响都被完全覆盖,需要进一步研究。然而,作为整合空间碎片影响的下一步,评估轨道稀缺性的变化和空间碎片对人类健康的潜在影响的实际实施被认为是可行和重要的。
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引用次数: 1
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