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Electrochemistry under Microscope: Observing the Diffusion Layer and Measuring Diffusion Coefficient 显微镜下的电化学:观察扩散层和测量扩散系数
IF 3 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-12 DOI: 10.1021/acs.jchemed.3c00584
Lida Khalafi*, Nastaran Nikzad, Asayiel Alhajeri, Brandon Bacon, Karla Alvarado and Mohammad Rafiee*, 

The area near the electrode surface is called the diffusion layer, and to understand electrochemistry, it is crucial that students have a knowledge of the phenomena occurring at the diffusion layer. Here, we present a demonstration and activity to visualize and analyze the expansion of a micrometer-sized diffusion layer. The electrode process involves distinct color changes of acid–base indicators in response to electrochemically generated hydroxide ion (OH), from water electrolysis in a homemade thin-layer electrochemical cell. A kid’s optical microscope equipped with a digital eyepiece camera was used to observe and record the formation and expansion of the diffusion layer. Analyzing the time-dependent changes in the colorful diffusion layer enables students to derive the diffusion coefficient (D) of electrochemically generated OH. The imaging tool presented in this activity aids in the explicit visualization and interpretation of electrode reactions and provides an excellent opportunity to discuss concentration profiles near the electrode, diffusion layer, and diffusion coefficient.

电极表面附近的区域被称为扩散层,为了理解电化学,学生了解扩散层发生的现象至关重要。在这里,我们展示了一个演示和活动,以可视化和分析微米大小的扩散层的膨胀。电极过程涉及酸碱指示剂的不同颜色变化,以响应自制薄层电化学电池中电解水产生的电化学生成的氢氧根离子(OH–)。使用配备数字目镜相机的儿童光学显微镜观察和记录扩散层的形成和扩展。通过分析彩色扩散层的时间依赖性变化,学生可以推导出电化学产生的OH–的扩散系数(D)。该活动中提供的成像工具有助于电极反应的显式可视化和解释,并为讨论电极附近的浓度分布、扩散层和扩散系数提供了极好的机会。
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引用次数: 0
Using Pictograms to Depict Analytical Techniques in an Instrumental Analysis Course 在仪器分析课程中使用象形图描述分析技术
IF 3 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-12 DOI: 10.1021/acs.jchemed.3c00388
Deon T. Miles*, 

Students in a typical instrumental analysis course may learn more than 30 analytical techniques. There are more than 150 components associated with the instrumentation that they learn. To help students organize this large amount of information, we classified these components into four categories: sources, samples, discriminators, and detectors. In this work, color-coded pictograms are used to help students identify components associated with a particular instrumental technique. For example, a UV–visible spectrophotometer can be depicted by using four color-coded pictograms. Pictograms were created for instrumentation on each of the following topics: spectroscopy, electrochemistry, chromatography, elemental analysis, surface analysis, and thermal analysis. Methods to incorporate these pictograms into the instrumental analysis course and assess their effectiveness are provided.

一门典型的工具分析课程的学生可能会学习30多种分析技术。有150多个组件与他们学习的仪器相关。为了帮助学生组织这些大量的信息,我们将这些成分分为四类:来源、样本、鉴别器和检测器。在这项工作中,使用颜色编码的象形图来帮助学生识别与特定仪器技术相关的组件。例如,紫外线-可见光分光光度计可以通过使用四种颜色编码的象形图来描述。为以下每个主题的仪器创建了象形图:光谱、电化学、色谱、元素分析、表面分析和热分析。提供了将这些象形图纳入仪器分析课程并评估其有效性的方法。
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引用次数: 0
Virtual Special Issue Call for Papers: Investigating the Uses and Impacts of Generative Artificial Intelligence in Chemistry Education 虚拟特刊征文:研究生成式人工智能在化学教育中的应用和影响
IF 3 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-12 DOI: 10.1021/acs.jchemed.3c00829
Elizabeth Yuriev, Donald J. Wink and Thomas A. Holme*, 

The Journal of Chemical Education announces a call for papers for an upcoming virtual special issue on studies about the emerging applications of generative artificial intelligence (AI). Predictions abound about the expected impacts of this new technology, and as increasing numbers of chemistry educators consider ways to incorporate it in their classrooms, the need for scholarly investigations grows. The virtual special issue will collect reports on such work and seek to establish early baselines of understanding the potential presented by tools such as ChatGPT and others. The timing for the collection’s release is designed to gather information by August 2024 to help instructors contemplating use of these tools by the start of the 2024–2025 academic year in North America.

《化学教育杂志》(Journal of Chemical Education)宣布为即将出版的关于生成式人工智能(AI)新兴应用研究的虚拟特刊征集论文。关于这项新技术的预期影响的预测比比皆是,随着越来越多的化学教育者考虑将其纳入课堂的方法,对学术研究的需求也在增长。虚拟特刊将收集有关此类工作的报告,并寻求建立早期基线,以了解ChatGPT等工具所呈现的潜力。该系列的发布时间是为了在2024年8月之前收集信息,以帮助北美的教师在2024 - 2025学年开始时考虑使用这些工具。
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引用次数: 0
Current Chemistry Investigators (CCI): Development and Evaluation of a Scientist in a Classroom Electrochemistry Workshop 当代化学研究者(CCI):一位科学家在课堂电化学研讨会上的发展与评价
IF 3 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-12 DOI: 10.1021/acs.jchemed.3c00515
John O’Donoghue*, Natalia García Doménech, Fiona McArdle, Mary Connolly, Yvonne Lang and Niamh McGoldrick, 

Over the course of the COVID-19 pandemic, school students suffered from a reduction in opportunities to connect with higher education institutions, meet scientific role models in person, discuss scientific career options, and carry out hands-on practical laboratory activities. Current Chemistry Investigators (CCI) is a successful electrochemistry-based STEM career intervention program, developed and evaluated through a co-creation process with teachers and students. The goals of CCI are 2-fold: first, to provide school students with career advice through tangible scientific role models and, second, to provide real-world context for the fundamentals of electrochemistry through hands-on activities. Herein, the development of a novel electro-analytical workshop from concept through to delivery with over a thousand students having taken part to date is reported. Students are tasked with solving why a battery malfunctioned through quantitative and qualitative analyses of an electrolyte using conductivity meters. Student feedback is also gathered anonymously through the use of a classroom response system (also known as “clickers”). Together with feedback from teachers, a robust evaluation is presented to measure the impact of providing tangible scientific role models and the usefulness of the workshop.

在新冠肺炎大流行期间,学生与高等教育机构联系、亲自会见科学榜样、讨论科学职业选择和开展实践实验室活动的机会减少。Current Chemistry Investigators(CCI)是一个成功的基于电化学的STEM职业干预计划,通过与教师和学生的共同创建过程开发和评估。CCI的目标有两个方面:第一,通过切实可行的科学榜样为学生提供职业建议;第二,通过实践活动为电化学基础知识提供现实世界的背景。在此,报道了一个新颖的电分析研讨会的发展,从概念到交付,迄今已有1000多名学生参加。学生们的任务是通过使用电导率计对电解质进行定量和定性分析来解决电池故障的原因。学生的反馈也通过使用课堂反应系统(也称为“点击器”)匿名收集。结合教师的反馈,提出了一项强有力的评估,以衡量提供切实的科学榜样的影响和研讨会的有用性。
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引用次数: 0
Dissociation Must Be Taken into Account in Raoult’s Law 拉乌尔定律必须考虑离解
IF 3 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-11 DOI: 10.1021/acs.jchemed.3c00369
Amparo Gómez-Siurana*,  and , Sergio Menargues, 

This communication shows that although some textbooks do not discuss how to apply Raoult’s law to electrolyte solutions, we should not ignore dissociation, and the van’t Hoff factor must be considered.

这篇通讯表明,尽管一些教科书没有讨论如何将拉乌尔定律应用于电解质溶液,但我们不应该忽视离解,必须考虑范特-霍夫因子。
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引用次数: 0
Fluffy, Fluffier, and Fluffiest: Creating and Testing Biodegradable Starch Packing Peanuts 蓬松、蓬松和蓬松:可生物降解淀粉包装花生的生产和测试
IF 3 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-11 DOI: 10.1021/acs.jchemed.3c00510
Katherine R. McCance*, Ana Maria Topliceanu, Darlene Echeverria, Shana L. McAlexander, Margaret R. Blanchard and Richard A. Venditti, 

As e-commerce increases, the demand for packaging materials and the potential for generating waste and negative environmental impacts also rise. Packing peanuts are a type of plastic packaging material that are used to protect goods during the shipping process. Petroleum-based plastics are common packaging materials due to their low cost, light weight, and versatility. Traditional packing peanuts are made of polystyrene, which is not biodegradable and contributes to landfill waste. Starch-based packing peanuts are biobased and a more sustainable alternative. This article describes the implementation and assessment of a hands-on laboratory activity appropriate for high school students (ages 14 to 18). In the lab, students create cornstarch-based packing peanuts with different properties and carry out follow-up experiments to test the peanuts’ performance. This article includes observations and student data that were collected from implementation in four science classes predominantly at rural high schools in a Southeastern state in the U.S. This lab can be adapted to chemistry, environmental science, and physical science classes to augment lessons on topics such as polymers, polarity, bonding, and renewable and nonrenewable resources.

随着电子商务的增加,对包装材料的需求以及产生废物和负面环境影响的可能性也在增加。包装花生是一种塑料包装材料,用于在运输过程中保护货物。石油基塑料由于其低成本、轻重量和多功能性而成为常见的包装材料。传统包装花生是由聚苯乙烯制成的,聚苯乙烯不可生物降解,会造成垃圾填埋。淀粉包装花生是以生物为基础的,是一种更可持续的替代品。本文介绍了适用于高中生(14至18岁)的动手实验室活动的实施和评估。在实验室里,学生们制作出具有不同性能的玉米淀粉包装花生,并进行后续实验来测试花生的性能。这篇文章包括在美国东南部一个州的农村高中的四个科学班中收集的观察结果和学生数据。该实验室可以适应化学、环境科学和物理科学课程,以增加聚合物、极性、键合以及可再生和不可再生资源等主题的课程。
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引用次数: 0
Lighting Up for Learning─Fluorescence Analysis of Microplastic Particles by Secondary School Students Using Nile Red 点亮学习灯─用尼罗红对中学生微塑料颗粒的荧光分析
IF 3 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-11 DOI: 10.1021/acs.jchemed.3c00370
Alina Majcen, Sebastian Tassoti and Philipp Spitzer*, 

Microplastics have been detected in most ecosystems around the world. They affect the environment and organisms in it, including humans and possibly their health. Hence, the analysis of microplastic occurrence in the environment is highly relevant. However, there are only a few practical and easy-to-implement methods published for school use, and therefore, microplastics still receive little attention in the classroom. This review presents an approach for separation and detection of microplastic particles in sediment with secondary school students based on methods used in current research. After sieving and density separation, the fluorescence marker Nile Red is used to selectively stain microplastic particles. Subsequently, the particles can be detected using a DIY low-cost fluorescence photobox. It offers an opportunity to address the problems associated with microplastics in a school context and can be used as an example for further discussion.

在世界各地的大多数生态系统中都检测到了微塑料。它们会影响环境和其中的生物,包括人类,可能还会影响他们的健康。因此,分析微塑料在环境中的存在具有高度相关性。然而,只有少数实用且易于实施的方法可供学校使用,因此,微塑料在课堂上仍然很少受到关注。这篇综述提出了一种基于当前研究方法的中学生沉积物中微塑料颗粒的分离和检测方法。在筛选和密度分离后,使用荧光标记尼罗红对微塑料颗粒进行选择性染色。随后,可以使用DIY低成本荧光照相盒来检测颗粒。它提供了一个在学校环境中解决与微塑料相关问题的机会,可以作为进一步讨论的例子。
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引用次数: 0
Spectroscopy Data for Undergraduate Teaching 光谱学数据在本科教学中的应用
IF 3 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-11 DOI: 10.1021/acs.jchemed.3c00046
Scott E. Van Bramer*,  and , Loyd D. Bastin, 

This paper describes a data set of IR, MS, H-1 NMR, C-13 NMR, DEPT, and 2D NMR spectra designed for undergraduate teaching. The data files are provided as MestReNova documents containing all the available spectra for each of the 251 different compounds in the data set. The spectral data in these files can be processed, manipulated, copied, and pasted as needed by faculty to support teaching organic chemistry and instrumental analysis and for specialized courses in spectroscopy and organic synthesis. The compounds in the database were selected to provide examples for interpreting spectra and unknowns for teaching interpretation and to support teaching synthesis mechanisms. Additional MestReNova documents are provided to demonstrate how the data can be used for a variety of common undergraduate course topics─introducing IR, MS interpretation, NMR interpretation, data processing, and spectroscopy unknowns for students.

本文介绍了为本科生教学设计的IR、MS、H-1 NMR、C-13 NMR、DEPT和2D NMR光谱数据集。数据文件以MestNova文件的形式提供,该文件包含数据集中251种不同化合物中每种化合物的所有可用光谱。这些文件中的光谱数据可以根据教师的需要进行处理、操作、复制和粘贴,以支持有机化学和仪器分析的教学,以及光谱学和有机合成的专业课程。选择数据库中的化合物是为了提供用于解释光谱的实例和用于教学解释的未知物,并支持教学合成机制。提供了额外的MestNova文件,以演示如何将数据用于各种常见的本科生课程主题─为学生介绍IR、MS解释、NMR解释、数据处理和光谱未知。
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引用次数: 0
The Digital Task Navigator as a Scaffold for Supporting Higher Education Students while Solving Tasks in Organic Chemistry 数字任务导航器作为支持高等教育学生解决有机化学任务的支架
IF 3 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-08 DOI: 10.1021/acs.jchemed.2c00518
David Keller,  and , Jolanda Hermanns*, 

Scaffolds can be seen as a suitable tool to support students’ learning chemistry. Digital task navigators, written scaffolds that support students in solving tasks in organic chemistry, were developed, used, and evaluated for this study. A paper task navigator was further developed into a digital task navigator, which included links to explanations of special terms that were unknown to the students. The students could use the links to find these explanations if they needed them. Four newly designed digital task navigators were evaluated using questionnaires. The students rated this newly developed digital scaffold quite highly. Students who used the links to the explanations felt that these were also helpful. The results of the students’ ratings can be used to design additional digital task navigators for other topics as well as to develop this scaffold further.

支架可以被视为支持学生学习化学的合适工具。本研究开发、使用和评估了数字任务导航器,这是一种支持学生解决有机化学任务的书面支架。纸质任务导航器被进一步发展为数字任务导航器,其中包括学生不知道的特殊术语解释的链接。如果需要的话,学生们可以使用这些链接找到这些解释。使用问卷对四个新设计的数字任务导航器进行了评估。学生们对这个新开发的数字脚手架给予了很高的评价。使用解释链接的学生认为这些链接也很有帮助。学生的评分结果可用于为其他主题设计额外的数字任务导航器,并进一步开发该支架。
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引用次数: 0
How to Identify–with as Little as One Question–Students Who Are Likely to Struggle in Undergraduate Organic Chemistry 如何识别——只需一个问题——可能在本科有机化学中挣扎的学生
IF 3 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-08 DOI: 10.1021/acs.jchemed.3c00344
Charles E. Jakobsche*, 

Our goal as educators should be to help our students become well positioned to achieve future success. To develop effective strategies for accomplishing this objective, we must first understand the root causes of success. Thus, to best serve undergraduate students who are taking organic chemistry courses, we must understand the attributes that most significantly enable students to be successful in these courses. The current work evaluates an assessment of undergraduate students’ abilities to answer simple general chemistry questions on the first day of an organic chemistry course. The results show that this assessment, as well as some but not all of its component questions, have high ability to predict student outcomes in an organic chemistry 1 course. This type of assessment can provide a tool for instructors to easily identify high-risk students right at the beginning of the semester. The results of this study also identify some particular prerequisite knowledge and skills that are especially important for positioning students to succeed in organic chemistry courses.

作为教育工作者,我们的目标应该是帮助我们的学生做好准备,在未来取得成功。为了制定实现这一目标的有效战略,我们必须首先了解成功的根本原因。因此,为了更好地为正在学习有机化学课程的本科生服务,我们必须了解最能使学生在这些课程中取得成功的特质。目前的工作评估了本科生在有机化学课程第一天回答简单普通化学问题的能力。结果表明,该评估以及部分但不是全部的组成问题,具有很高的预测有机化学1课程学生成绩的能力。这种类型的评估可以为教师提供一种工具,在学期开始时轻松识别高风险学生。这项研究的结果还确定了一些特定的先决条件知识和技能,这些知识和技能对定位学生在有机化学课程中取得成功尤为重要。
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引用次数: 0
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Journal of Chemical Education
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