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Hardening and Stabilization of Volumetric Properties in Aspen and Poplar Wood with Cardanol 腰果酚对杨木和杨木体积性能的硬化和稳定作用
IF 0.2 Pub Date : 2023-06-10 DOI: 10.37482/0536-1036-2023-3-155-161
V. Shamaev, O. Shishlov
Aspen and poplar are the least required types of wood in the Russian Federation, whose stock is continually expanding. Such wood can be used as a substitute for valuable hardwood, but in this case the strength must be almost doubled while achieving stability in shape and size. Treatment with acetic anhydride, polyvinyl alcohol, polyethylene glycol, or hydrothermal care are the most common methods for maintaining the volumetric stability of the wood. Treatment with phenol- and urea-formaldehyde monomers, oligomers, and resins is typically done for strength improvement. The stabilization of the dimensional parameters is especially critical for pressed wood, which has 8 times greater swelling in water than raw wood. Cardanol was chosen as a modifier. It can be derived from cashew nutshell liquid or synthesized. The established technique for impregnating wood with cardanol includes 2–3 % acetic acid, followed by heat treatment at 140–150 °С for 6–8 hours. During this process, cardanol polymerizes with components of the lignocarbohydrate complex of the wood, which does not only improve its characteristics but also provides form and size stability in an environment with changeable humidity. A Mettler Toledo DSC 823e/700 differential scanning calorimeter was used to examine the kinetics. Heat fluxes were measured in 30 µl sealed steel crucibles that could sustain steam pressure up to 15 MPa. At a heating rate of 10 °C/min, the heat flow curve showed an exothermic peak with a maximum temperature of 150.7 °C. Aspen wood with 15 % cardanol content has a compressive strength along the fibers of 69 MPa, a volume swelling limit of 2.6 %, and a moisture absorption limit of 18 %. The ultimate water absorption and ultimate volumetric swelling of wood impregnated with cardanol are comparable to the relevant indications of the modified wood brands Accoja, Belmadur, and Thermowood. For citation: Shamaev V.A., Shishlov O.F. Hardening and Stabilization of Volumetric Properties in Aspen and Poplar Wood with Cardanol. Lesnoy Zhurnal = Russian Forestry Journal, 2023, no. 3, pp. 155–161. (In Russ.). https://doi.org/10.37482/0536-1036-2023-3-155-161
白杨和白杨是俄罗斯联邦最不需要的木材类型,其储量正在不断扩大。这种木材可以作为贵重硬木的替代品,但在这种情况下,强度必须几乎翻倍,同时保持形状和尺寸的稳定。用乙酸酐、聚乙烯醇、聚乙二醇或水热处理是保持木材体积稳定性的最常用方法。用苯酚和脲醛单体、低聚物和树脂处理通常是为了提高强度。尺寸参数的稳定对压制木材尤其重要,因为压制木材在水中的膨胀比原始木材大8倍。选择腰果酚作为改性剂。它可以从腰果液中提取,也可以人工合成。用腰果酚浸渍木材的既定技术包括2 - 3%的乙酸,然后在140-150°С下加热6-8小时。在这个过程中,腰果酚与木材的木质碳水化合物复合物的组分聚合,这不仅改善了其特性,而且在湿度变化的环境中提供了形状和尺寸的稳定性。采用Mettler Toledo DSC 823e/700差示扫描量热仪对反应动力学进行了研究。热通量在30µl密封钢坩埚中测量,坩埚可以承受高达15 MPa的蒸汽压力。在升温速率为10℃/min时,热流曲线出现放热峰,最高温度为150.7℃。腰果酚含量为15%的杨木沿纤维抗压强度为69 MPa,体积膨胀极限为2.6%,吸湿极限为18%。用腰果酚浸渍的木材的最终吸水率和最终体积膨胀率与改性木材品牌Accoja、Belmadur和Thermowood的相关指标相当。引用本文:Shamaev v.a., Shishlov O.F.。腰果酚对杨木和杨木体积性能的硬化和稳定作用。俄罗斯林业杂志,2023年第1期。3,第155-161页。(俄国人)。https://doi.org/10.37482/0536-1036-2023-3-155-161
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引用次数: 0
Surface Treatment of Cardboard with Plant and Bacterial Derived Nanocellulose Suspensions 植物和细菌来源的纳米纤维素悬浮液对纸板表面的处理
IF 0.2 Pub Date : 2023-06-10 DOI: 10.37482/0536-1036-2023-3-162-172
Еvgeniy А. Toptunov, Yuliya V. Sevastyanova, Ksenia Vashukova
This study investigates powdered cellulose materials, particularly nanocellulose derived from plant and bacterial sources. The nanocellulose was generated by hydrolyzing bleached sulphate softwood and hardwood pulp samples with strong acids. The original materials are present in the product lines of leading Russian pulp and paper companies. The bacterial cellulose was produced under laboratory conditions from Medusomyces gisevii. The dimensional parameters of the nanocellulose samples were evaluated using electron microscopy, and the degree of polymerization was measured by determining the viscosity of the cellulose solutions in cadoxene. The bleached softwood pulp had a nanocellulose particle length of 80–200 nm, a particle diameter of 80–100 nm, and a degree of polymerization of 60. The bleached hardwood pulp had a particle length of 80–150 nm, a particle diameter of 70–100 nm, and a degree of polymerization of 50. The bacterial nanocellulose had a particle length of 120–250 nm, a particle diameter of 70–120 nm, and a degree of polymerization of 110. Suspensions of various concentrations (from 1 to 10 %) were prepared from nanocellulose samples, which were subsequently used as reinforcing additives in cardboard samples. The additive was applied to the surface in one or two layers. Additives of nanocellulose preparations reduced the breaking length (from 9.6 to 40.4 %) along with an increase in cardboard density (from 6.3 to 23.8 %), tensile rigidity (from 14.0 to 25.0 %) and bursting strength (up to 31.9 %). The best results were obtained by applying a nanocellulose suspension of bleached softwood pulp to the board surface in two layers: a 9.6 % decrease in breaking length was observed with an increase in density of 23.8 %, tensile rigidity of 25.0 %, and bursting resistance of 31.9 % relative to the control sample. Therefore, the study showed the possibility of using nanocellulose suspensions derived from plants and bacterial sources by acid hydrolysis for the surface treatment of cardboard. For citation: Toptunov Е.А., Sevastyanova Yu.V., Vashukova K.S. Surface Treatment of Cardboard with Plant and Bacterial Derived Nanocellulose Suspensions. Lesnoy Zhurnal = Russian Forestry Journal, 2023, no. 3, pp. 162–172. (In Russ.). https://doi.org/10.37482/0536-1036-2023-3-162-172
本研究研究了粉末状纤维素材料,特别是来源于植物和细菌的纳米纤维素。采用强酸水解漂白过的硫酸盐软木浆和硬木纸浆制备纳米纤维素。原始材料存在于俄罗斯领先的纸浆和造纸公司的产品线中。在实验室条件下,以吉色美杜氏菌为原料制备细菌纤维素。利用电子显微镜对纳米纤维素样品的尺寸参数进行了评价,并通过测定纤维素溶液在卡多辛中的粘度来测定聚合度。漂白后的针叶木浆纳米纤维素颗粒长度为80 ~ 200 nm,粒径为80 ~ 100 nm,聚合度为60。漂白后的硬木纸浆颗粒长度为80 ~ 150 nm,粒径为70 ~ 100 nm,聚合度为50。细菌纳米纤维素的颗粒长度为120 ~ 250 nm,粒径为70 ~ 120 nm,聚合度为110。从纳米纤维素样品中制备不同浓度的悬浮液(从1%到10%),随后将其用作纸板样品中的增强添加剂。添加剂分一层或两层涂在表面。纳米纤维素制剂的添加剂减少了断裂长度(从9.6%到40.4%),同时增加了纸板密度(从6.3%到23.8%),拉伸刚度(从14.0%到25.0%)和破裂强度(高达31.9%)。将漂白后的软木纸浆纳米纤维素悬浮液分两层涂在纸板表面,效果最佳:与对照样品相比,断裂长度减少9.6%,密度增加23.8%,拉伸刚度提高25.0%,抗破裂能力提高31.9%。因此,该研究表明,通过酸水解从植物和细菌来源提取的纳米纤维素悬浮液用于纸板表面处理的可能性。引用:Toptunov Е.А。, Sevastyanova Yu.V。,陈国华。植物和细菌源纳米纤维素悬浮液对纸板表面处理的研究。俄罗斯林业杂志,2023年第1期。3,第162-172页。(俄国人)。https://doi.org/10.37482/0536-1036-2023-3-162-172
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引用次数: 0
Application of Reinforced Soil Foundations in the Construction of Wooden Bridge Abutments Along Logging Road 加筋土基础在伐木路木桥桥台施工中的应用
IF 0.2 Pub Date : 2023-06-10 DOI: 10.37482/0536-1036-2023-3-113-125
V. Kleveko, A. Burgonutdinov, Yulia K. Litsinger, O. Burmistrova
Wooden bridges have been used quite frequently on logging roads, regardless of their low durability and weak fire resistance. The preference is determined by the application of local materials in the construction and reparation, thus reducing the cost of the structure. However, the standard construction of the wooden bridge demands large amounts of conditioned draining bulk materials to support the cones, stone materials, or reinforced concrete slabs to protect against soil erosion. Besides, pile foundations are used on soft ground, involving heavy construction machinery. Reinforced soil foundations don’t have disadvantages of this kind. The application of innovative mounds for coastal support may reduce construction costs and increase operational capability. The purpose of the study is to estimate the potential of reinforced soil foundations in the construction of wooden bridge abutments. The results of the calculation for an abutment using reinforced support are presented. The calculations were performed for the standard loads A11, N11, and a forwarder. Additional research was performed to determine the parameters for the forwarder. According to the results, a mark of the forwarder with the maximum load on the abutment was identified. The maximum applied force was exerted by the load H11, and the minimum was A11. The stress from the timber truck Iveco-AMT 633920 (6×6) significantly exceeded the characteristic load A11, yet it was slightly lower compared to H11. The calculations for the abutment were done using the finite element method of the Plaxis 2D software. The parameters were limited to two groups of states. The calculations contained the external and internal stability factors along with the vertical and horizontal displacements of the reinforced structure. The external stability coefficient for the first loading scheme was 2.14; for the second loading scheme, it was 1.44. They exceed the permitted limit that is 1.375. In general, the results demonstrated that the reinforced soil abutment totally meets the requirements of the regulatory documents. For citation: Burgonutdinov A.M., Burmistrova O.N., Kleveko V.I., Litsinger Yu.K. Application of Reinforced Soil Foundations in the Construction of Wooden Bridge Abutments Along Logging Road. Lesnoy Zhurnal = Russian Forestry Journal, 2023, no. 3, pp. 113–125. (In Russ.). https://doi.org/10.37482/0536-1036-2023-3-113-125
尽管木桥耐久性低,耐火性弱,但在伐木道路上经常使用木桥。这种偏好是由在建造和修复中使用当地材料决定的,从而降低了结构的成本。然而,木桥的标准建造需要大量的条件排水散装材料来支撑锥体,石材或钢筋混凝土板来防止土壤侵蚀。此外,在软土地基上采用桩基础,涉及重型施工机械。加筋土基础没有这类缺点。应用创新土墩进行海岸支护,可以降低建设成本,提高作战能力。本研究的目的是评估加筋土基础在木桥桥台建设中的潜力。给出了采用加固支撑的桥台的计算结果。计算是针对A11、N11和货代的标准载荷进行的。进行了额外的研究以确定货运代理的参数。根据结果,在桥台上确定了最大载重货代的标志。最大载荷H11,最小载荷A11。木材卡车Iveco-AMT 633920 (6×6)的应力显著超过特征荷载A11,但略低于H11。采用Plaxis 2D有限元软件对基台进行有限元计算。参数仅限于两组状态。计算中包含了外稳定因子和内稳定因子以及加筋结构的竖向和水平位移。第一加载方案的外稳定系数为2.14;对于第二个加载方案,它是1.44。它们超过了允许的上限1.375。总体而言,结果表明加筋土桥台完全符合规范性文件的要求。引证:Burgonutdinov a.m., Burmistrova O.N, Kleveko V.I, Litsinger Yu.K。加筋土基础在伐木路木桥桥台施工中的应用。俄罗斯林业杂志,2023年第1期。3,第113-125页。(俄国人)。https://doi.org/10.37482/0536-1036-2023-3-113-125
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引用次数: 0
Intraspecific Diversity of Pinus sylvestris L. in Provenance Trials of the Central Russian Forest-Steppe Area 俄罗斯中部森林草原区种源试验中西尔维斯松种内多样性研究
IF 0.2 Pub Date : 2023-06-10 DOI: 10.37482/0536-1036-2023-3-84-98
T. Galdina, Alexey I. Chernodubov, Maria I. Mikhailova
The provenance trials of Scots pine (Pinus sylvestris L.) in the Central Russian forest-steppe area were established by M.M. Veresen in 1959. They have become a natural laboratory for genetic and environmental research in order to solve the practical issues of forest seed zoning. The study of the intraspecific diversity of the provenance trials makes it possible to distinguish patterns in the formation of species with various origins under the influence of different ecological, genetic, and climatic conditions. This article presents the results of a multi-year research project. This allows us to state with full responsibility the strong influence of environmental and genetic factors on the characteristics of growth, resistance, trunk productivity, and reproductive capacity of Scots pine in new growing conditions. The generative parts of the study objects were also examined by morphometric indicators. The changes were revealed in seed production, size, cone coloring, color and weight of 1000 pieces of seeds, seed release, seed fullness, germinative energy, and absolute germination. Genetic factors, which are programmed by ancestry, define the constancy of the difference in size and color of cones and seeds. In addition, genetic factors, along with the weather conditions of a new location, regulate reproductive ability. It was noted that Scots pine with different geographical origins enters the flowering phase at different times. The northern trees are 5–7 days earlier than locals; the southern trees are 5 days later. They were studied in the climate of the Voronezh region. The variability in the characteristics of the generative organs of Scots pine is also affected by its place of birth. The size and weight of the cone are directly related to the geographic latitude. The length and weight of the cone increase with movement from north to south. There is no strict relationship between the release of the seeds during free pollination and the place of origin since the study objects were surrounded by various pollinators. The weight of 1000 seeds changes with the same regularity as in natural stands of pine: it increases with the geographical latitude of the origin. Consequently, under the influence of new growing conditions, Scots pine is strongly affected by its genetic factors that determine the stability, trunk productivity, and reproductive capacity of the species. For citation: Galdina T.E., Chernodubov A.I., Mikhailova M.I. Intraspecific Diversity of Pinus sylvestris L. in Provenance Trials of the Central Russian Forest-Steppe Area. Lesnoy Zhurnal = Russian Forestry Journal, 2023, no. 3, pp. 84–98. (In Russ.). https://doi.org/10.37482/0536-1036-2023-3-84-98
1959年,M.M. Veresen在俄罗斯中部森林草原地区建立了苏格兰松(Pinus sylvestris L.)的种源试验。它们已成为遗传和环境研究的天然实验室,以解决森林种子分区的实际问题。种源试验种内多样性的研究,使我们能够在不同的生态、遗传和气候条件的影响下,区分不同起源物种的形成模式。这篇文章介绍了一个多年研究项目的结果。这使我们能够完全负责地说明环境和遗传因素对新生长条件下苏格兰松的生长特性、抗性、树干生产力和繁殖能力的强烈影响。研究对象的生成部分也通过形态计量指标进行了检查。在种子产量、种子大小、球果颜色、1000粒种子的颜色和重量、种子释放量、种子饱满度、发芽力和绝对发芽率等方面都发生了变化。遗传因素是由祖先设定的,决定了球果和种子的大小和颜色差异的稳定性。此外,遗传因素以及新地点的天气条件也会调节繁殖能力。人们注意到,不同地理来源的苏格兰松在不同的时间进入花期。北方的树木比当地早5-7天;南方的树晚5天。他们在沃罗涅日地区的气候中进行了研究。苏格兰松生殖器官特征的可变性也受其出生地的影响。圆锥体的大小和重量与地理纬度直接相关。圆锥体的长度和重量随着从北向南的运动而增加。由于研究对象周围有各种传粉媒介,因此在自由传粉过程中种子的释放与原产地之间没有严格的关系。1000粒种子的重量变化规律与天然松林相同:随着原产地地理纬度的增加而增加。因此,在新的生长条件的影响下,苏格兰松受到其遗传因素的强烈影响,遗传因素决定了物种的稳定性、树干生产力和繁殖能力。引用本文:Galdina t.e., Chernodubov a.i., Mikhailova M.I.。俄罗斯中部森林草原地区种源试验中松的种内多样性。俄罗斯林业杂志,2023年第1期。3,第84-98页。(俄国人)。https://doi.org/10.37482/0536-1036-2023-3-84-98
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引用次数: 0
Mathematical Estimation of Information Reliability Regarding Forest Fires 森林火灾信息可靠性的数学估计
IF 0.2 Pub Date : 2023-06-10 DOI: 10.37482/0536-1036-2023-3-21-34
R. Kotelnikov
The rapid development of digital technologies, especially methods for processing a large amount of information, offers vast opportunities for obtaining new algorithms for supporting management decisions, including the prevention of forest fires. Therefore, the requirements for data accuracy on fire hazards in forests and forest fires considerably increase. Even though the remote sensing of the Earth from space is a potential method for acquiring information independent of the human factor, it still has several technical limitations that hinder total automation. Therefore, it is important to provide а comprehensive control over the information coming from the forest fire departments. Besides, the long-term fire risk prognoses must consider retrospective statistics and cyclical weather conditions. This requires the creation of methods for evaluating the reliability of the initial data. An analysis of the records on the number of forest fires that happened in the Russian Federation from 1969 to 2020 revealed that the distribution of the values in a large sampling set is close to lognormal, which is the author’s fundamental principle. The few deviations on the right side of the distribution indirectly support the hypothesis that, in the provided information, the large forest fires in each case were presented as smaller, fragmented events. This is also consistent with the fact that such information usually occurs when the forest fire situation is complex and has many burning locations. An analysis of the records on the forest fires extinguished within one day identified a characteristic deviation, which indirectly supports the assumption that the data was probably distorted to improve recording. In such a situation, the deviation from the pattern corresponds to low combustibility and completely loses its meaning in the conditions of a severe forest fire situation with many burning areas. The authors have formed a ranking of the regions according to the validity of the archival records on the forest fires using the correspondence of the statistical data to the lognormal distribution. The proposed method can become one of the elements of a risk-oriented approach for planning control and supervisory measures in forestry policy. For citation: Kotelnikov R.V., Martynyuk A.A. Mathematical Estimation of Information Reliability Regarding Forest Fires. Lesnoy Zhurnal = Russian Forestry Journal, 2023, no. 3, pp. 21–34. (In Russ.). https://doi.org/10.37482/0536-1036-2023-3-21-34
数字技术的快速发展,特别是处理大量信息的方法,为获得支持管理决策(包括预防森林火灾)的新算法提供了巨大的机会。因此,对森林火险和森林火灾数据准确性的要求大大提高。尽管从太空对地球进行遥感是一种独立于人为因素获取信息的潜在方法,但它仍有若干技术限制,阻碍了全面自动化。因此,对来自森林消防部门的信息进行全面控制是很重要的。此外,长期的火灾风险预测必须考虑回顾性统计数据和周期性天气条件。这就需要创建评估初始数据可靠性的方法。通过对俄罗斯联邦1969 - 2020年发生的森林火灾数量记录的分析发现,在大样本集中,数值的分布接近对数正态分布,这是作者的基本原则。分布右侧的少数偏差间接支持了这样一种假设,即在所提供的信息中,每种情况下的大型森林火灾都被视为较小的、分散的事件。这也符合这样一个事实,即这种信息通常发生在森林火灾情况复杂且有许多燃烧地点的情况下。对一天内扑灭的森林火灾记录的分析发现了一个特征偏差,这间接支持了数据可能被扭曲以改进记录的假设。在这种情况下,偏离模式对应于低可燃性,在燃烧区域多的严重森林火灾情况下完全失去意义。利用统计数据与对数正态分布的对应关系,根据森林火灾档案记录的有效性,形成了区域排序。所建议的方法可以成为林业政策中规划、控制和监督措施的面向风险方法的要素之一。引用本文:Kotelnikov r.v., Martynyuk A.A.。森林火灾信息可靠性的数学估计。俄罗斯林业杂志,2023年第1期。3,第21-34页。(俄国人)。https://doi.org/10.37482/0536-1036-2023-3-21-34
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引用次数: 0
Application of Ooencyrtus kuvanae Howard Against Gypsy Moth 黄卵通菌对舞毒蛾的防治应用
IF 0.2 Pub Date : 2023-06-10 DOI: 10.37482/0536-1036-2023-3-69-83
Yuliya A. Sergeeva, Sergey O. Dolmonego
The gypsy moth, Lymanria dispar, is one of the most widespread pest-insects in the Russian Federation. Anastatus japonicus Ashmead and Ooencyrtus kuvanae Howard are parasites that live on the eggs of L. dispar. They can be found in the European part of Russia, where the insects were imported from North Korea in 1988. The usage of O. kuvanae to limit the gypsy moth populations requires recognition of the release rates and effectiveness in preventing mass pest outbreaks, as well as for the evaluation of the possibility of elimination. An experimental release of O. kuvanae (237 500 specimens) was conducted in 2019 during a gypsy moth outbreak in the Orenburg region, which covered the basin of the Ural River within the territory of three forestries. The average number of clutches of O. kuvanae varied from 1 to 20 clutches per tree. The control of efficiency was made 48–52 after the release, during the incubation period of the 3ed generation of O. kuvanae. The clutches were collected and experimentally analyzed. The release rate of L. dispar ranged 82.9–90.3 % at the locations with a density of 107–268 thousand eggs/ha and did not exceed 47.3 % at the locations with a density of 3800 thousand eggs/ha. A coefficient for estimation of the optimal number of O. kuvanae specimens per 1 ha was proposed based on the proportion of the released egg parasitoids per 1 ha and the absolute number of the destroyed eggs of L. dispar. The regulation of the gypsy moth’s population by O. kuvanae should be done at the biggening of the foci formation. The usage of the entomophage in the active reproductive foci of the gypsy moth, with an infestation rate higher than 1.5 clutches per tree, cannot reduce the phytophage numbers to a harmless level. The application of O. kuvanae can be a part of an integrated system of preventive measures: chemical or biological pesticide treatments to reduce gypsy moth populations, and after initiate the release of the entomophages. For citation: Sergeeva Yu.A., Dolmonego S.O. Application of Ooencyrtus kuvanae Howard Against Gypsy Moth. Lesnoy Zhurnal = Russian Forestry Journal, 2023, no. 3, pp. 69–83. (In Russ.). https://doi.org/10.37482/0536-1036-2023-3-69-83
舞毒蛾,Lymanria dispar,是俄罗斯联邦最普遍的害虫之一。阿纳斯塔atus japonicus Ashmead和kuvanae Ooencyrtus Howard是生活在L. dispar卵上的寄生虫。在俄罗斯的欧洲部分可以找到这种昆虫,它们是1988年从朝鲜进口的。为了限制舞毒蛾的数量,需要认识到舞毒蛾的释放率和在防止大规模虫害暴发方面的有效性,以及对消灭舞毒蛾的可能性进行评估。2019年,在奥伦堡地区爆发舞毒蛾疫情期间,对库瓦纳伊蛾进行了试验性释放(237 500个标本),该地区覆盖了乌拉尔河流域,在三个林业区域内。每棵树的平均卵卵数在1 ~ 20个之间。释放后的效率控制为48-52,在3代库瓦纳伊虫的孵育期间。收集离合器并进行实验分析。密度为10.7 ~ 26.8万粒/ha的地点,异色夜蛾的释放率为82.9 ~ 90.3%,密度为380万粒/ha的地点,释放率不超过47.3%。根据每公顷释放的寄生蜂卵的比例和灭卵的绝对数量,提出了一种估算每公顷最适库瓦纳伊蚊标本数量的系数。野蛾对舞毒蛾种群的调控应在疫源地形成初期进行。在舞毒蛾的活跃繁殖点使用植噬体,侵染率高于每棵1.5只,不能使植噬体数量减少到无害水平。kuvanae的应用可以作为综合预防措施系统的一部分:化学或生物农药处理以减少舞毒蛾种群,并在启动虫媒释放后。引用:Sergeeva Yu.A。, Dolmonego s.o。kuvanae Howard对舞毒蛾的应用。俄罗斯林业杂志,2023年第1期。3,第69-83页。(俄国人)。https://doi.org/10.37482/0536-1036-2023-3-69-83
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引用次数: 0
Processing gold-bearing antimony sulfide mechanoactivated concentrate 加工含金硫化锑机械活化精矿
IF 0.2 Pub Date : 2023-04-25 DOI: 10.21440/0536-1028-2023-2-43-51
Khaetkul Rakhimov, B. Eshov, A. Kadirov, Abdulkhair Badalov
Introduction. The solution of important strategic objectives of the Republic of Tajikistan depends on such industries as chemical, mining, processing, and metallurgical. Their smooth functioning is provided by a developed energy and transport industry. Comprehensive mineral processing of abundant minerals located on the territory of the Republic of Tajikistan contributes to socioeconomic problems solution and to the development of new production facilities and employment, the transition from the role of a primary producer and middle-stage manufacturer to an end product producer. Methods of research. The expediency of separating antimony and precious metals before cyaniding is obvious. It can be achieved by pyrometallurgy or beneficiation methods. Distillate roasting allows to amply remove antimony from complex ores relatively poor in this metal. However, when processing raw materials rich in antimony, the risk of accretion development in furnaces creates difficulties. At a high temperature (1000–1100 °C), a large amount of gold can combine with oxides and become an oxide. Antimony can be removed by roasting with chlorination. Additional chlorinating reagent makes it possible to increase gold recovery during the subsequent cyanidation of the calcine from 75 to 95–98% compared to conventional oxidative roasting. Results and analysis. This article is the result of a series of experiments and renovations for the technologies of processing gold-bearing antimony sulfide concentrate into the final product. An effective method has been developed for chloridizing roasting of mechanoactivated precious metal containing antimony-gold concentrate with sodium chloride. The optimal roasting mode has been determined, which provides a high yield of antimony and gold compounds, which are technologically easy to process.
介绍。塔吉克斯坦共和国重要战略目标的解决取决于化学、采矿、加工和冶金等工业。发达的能源和运输业为它们的顺利运行提供了条件。塔吉克斯坦共和国境内丰富矿物的综合矿物加工有助于解决社会经济问题,发展新的生产设施和就业,从初级生产者和中期制造商的作用过渡到最终产品生产商。研究方法。在氰化前分离锑和贵金属的便利性是显而易见的。它可以通过火法冶金或选矿方法来实现。蒸馏焙烧可以从复杂矿石中充分去除锑,而锑的含量相对较低。然而,当加工富含锑的原材料时,在熔炉中产生堆积的风险会造成困难。在高温下(1000-1100℃),大量的金可以与氧化物结合,成为氧化物。锑可通过氯化焙烧除去。与传统的氧化焙烧相比,额外的氯化剂可以在焙烧后的氰化过程中提高金的回收率,从75%提高到95-98%。结果和分析。本文是对含金硫化锑精矿加工成最终产品的工艺进行了一系列试验和改造的结果。提出了一种用氯化钠氯化焙烧机械活化的含锑金贵金属精矿的有效方法。确定了最佳焙烧方式,使锑金化合物产率高,工艺简单。
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引用次数: 0
Rationale for the temperature regime of the foam separation cycle 泡沫分离循环温度状态的基本原理
IF 0.2 Pub Date : 2023-04-25 DOI: 10.21440/0536-1028-2023-2-21-31
E. Kovalenko
The research objective is to determine the optimal temperature regimes for slurry preparation and foam separation of diamond-bearing kimberlites to ensure maximum diamond recovery under high selectivity of the process. Methods of research include the electron probe X-ray spectral analysis, IR spectrophotometry, and measurement of the contact angles of a collecting agent drop on diamonds or minerals. Technological studies were carried out on the setup for foam separation. Research results. It was shown that when the feedstock of the foam separation cycle is heated to a temperature of 80–85 °C the diamonds are effectively purified from hydrophilic coatings, which leads to the restoration of their natural floatability. Through contact angles measurement, the temperature range of 30–40 °C was determined in the feedstock reagent conditioning operation. It is shown that the maximum water repellence of diamonds is achieved in this temperature range without a significant increase in the kimberlite minerals water repellence. Laboratory experiments have shown that the best foam separation results are achieved when in the conditioning operation the feedstock with flotation reagents is maintained at a temperature of 30–38 °C. The flotation studies using F-5 bunker fuel oil as base collecting agent, as well as its compounds with diesel fraction and Machchobinsky oil, determined the optimal temperature of 14–24 °C directly in the process of foam separation. After data analysis, a temperature regime was proposed and tested, which includes the foam separation feedstock heating before the operation of slurry removal and conditioning with flotation reagents up to 85 °C and the subsequent use of accumulated heat in the operations of foam separation feedstock conditioning (30 °C) with reagents and the foam separation process itself (18 °C). The prospects of the technology. The test results of the selected temperature regime for the foam separation process on a test bench show the possibility of increasing the diamonds recovery into the concentrate by 2.3–4.5% when using applied and potential collecting agents, including F-5 bunker fuel oil and compounds based on it. The developed regime is recommended for commercial development in the foam separation cycle at Alrosa processing plants.
研究目的是确定含金刚石金伯利岩浆液制备和泡沫分离的最佳温度制度,以确保在高选择性的过程中最大限度地回收钻石。研究方法包括电子探针x射线光谱分析,红外分光光度法,以及收集剂滴在钻石或矿物上的接触角的测量。对泡沫分离装置进行了工艺研究。研究的结果。结果表明,当泡沫分离循环的原料加热到80-85℃时,金刚石的亲水性涂层被有效地纯化,从而恢复了金刚石的自然可浮性。通过接触角测量,确定了原料药剂调理操作的温度范围为30 ~ 40℃。结果表明,在此温度范围内,钻石的防水性达到最大,而金伯利岩矿物的防水性没有显著增加。室内实验表明,在调质操作中,含浮选药剂的原料温度保持在30 ~ 38℃时,泡沫分离效果最好。采用F-5船用燃料油作为基础捕收剂,并与柴油馏分和马乔比斯基油混合浮选,确定了泡沫分离过程的最佳温度为14 ~ 24℃。经过数据分析,提出并测试了一个温度体系,其中包括泡沫分离原料在浆液去除和浮选试剂调理操作之前加热至85°C,以及随后在泡沫分离原料调理(30°C)和泡沫分离过程本身(18°C)操作中积累的热量的使用。该技术的前景。在试验台上对泡沫分离过程所选择的温度范围进行的测试结果表明,使用现有和潜在的捕收剂,包括F-5船用燃料油及其化合物,有可能使钻石在精矿中的回收率提高2.3-4.5%。已开发的制度被推荐用于阿尔罗莎加工厂泡沫分离循环的商业开发。
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引用次数: 0
Studying electrical parameters of contact and contactless polarization of particles under the electrochemical treatment of mineral suspensions 研究了矿物悬浮液在电化学处理下颗粒的接触极化和非接触极化的电参数
IF 0.2 Pub Date : 2023-04-25 DOI: 10.21440/0536-1028-2023-2-9-20
I. Morozov, A. Valtseva
Introduction. Electrochemical treatment of mineral suspensions is used in electrochemical conditioning of flotation pulp and electrochemical dissolution of minerals and metals in the processes of gold-bearing products electrochemical chlorination. Research objective is to develop and implement the procedures for determining the values of the liquid phase resistance, contact resistance under contact polarization, and ion discharge energy loss resistance under contactless polarization of the electrically conductive part. Methods of research. Equivalent circuits of electrochemical processes have been built for various electrochemical cells. Circuits for various polarizations of electrically conductive particles are established. A formula is proposed for calculating the electrically conductive particle resistance through the electrical resistivity of a unit of volume. A procedure has been developed for calculating the liquid phase resistance through the resistance increment under changing distance between the electrodes. The contact area and pressure influence on the value of the contact resistance is studied through the contact of pyrite and chalcopyrite with an iron electrode. Results. When studying the electrical resistivity of the liquid phase, it was found that increased distance between the current-carrying electrodes leads to an equivalent increase in the liquid phase resistance. It has been established that increased pressure and contact area between the contacting particles and the current-carrying electrode results in decreased contact resistance. The contact resistance between the particle and the electrode in the electrolyte solution is much less than the contact resistance under dry surfaces contact. This phenomenon is explained by electrons tunneling through the electrolyte film. The obtained experimental data on the determination of the liquid phase resistance, contact resistance and ion discharge energy loss resistance make it possible to mathematically describe the processes of electrochemical chlorination under a large number of particles in the pulp. Conclusions and scope of results. Procedures have been developed and specific data have been obtained on the liquid phase resistance, contact resistance, and ion discharge resistance. They can be used for practical application when implementing electrochemical technologies for mineral suspensions treatment.
介绍。矿物悬浮液的电化学处理主要用于浮选矿浆的电化学调理和含金产品电化学氯化过程中矿物和金属的电化学溶解。研究目的是制定并实现导电部分的液相电阻、接触极化下的接触电阻和非接触极化下离子放电能量损失电阻的测定程序。研究方法。已经为各种电化学电池建立了电化学过程的等效电路。建立了导电粒子的各种极化电路。提出了用单位体积的电阻率计算导电粒子电阻的公式。本文提出了一种通过电极间距变化时的电阻增量来计算液相电阻的方法。通过铁电极接触黄铁矿和黄铜矿,研究了接触面积和压力对接触电阻值的影响。结果。在研究液相电阻率时,发现载流电极之间距离的增加会导致液相电阻的等效增加。已经确定,接触颗粒与载流电极之间的压力和接触面积的增加会导致接触电阻的降低。在电解质溶液中,颗粒与电极之间的接触电阻远小于干燥表面接触下的接触电阻。这种现象可以用电子穿隧穿过电解质薄膜来解释。所得的测定液相电阻、接触电阻和离子放电能量损失电阻的实验数据,使得用数学方法描述纸浆中大量颗粒情况下的电化学氯化过程成为可能。结论和结果范围。已经制定了程序,并获得了有关液相电阻、接触电阻和离子放电电阻的具体数据。它们可用于实际应用时实施电化学技术的矿物悬浮液处理。
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引用次数: 0
Geophysical research of underground hydraulic structures, old Glubochinsky water tunnel case study 地下水工构筑物地球物理研究,老格洛博钦斯基水洞实例研究
IF 0.2 Pub Date : 2023-04-25 DOI: 10.21440/0536-1028-2023-2-87-95
V. Davydov, V. Gorshkov, A. Vdovin
Research objective is to study the features of geophysical fields and parameters in the area of the artificial underground water tunnel and estimate the capabilities of geophysical methods of identifying hidden underground industrial facilities. Methods of research. Measurements of self-potential signals (SP) were carried out using nonpolarizing electrodes and an electrical exploration receiver. The magnetic exploration was carried out by a proton magnetometer. Electrotomography was carried out using multielectrode electrical survey equipment with a Schlumberger symmetrical scheme of surveys. The microseismic background was recorded using an autonomous seismic station. The georadar survey was carried out using the SIR-3000 ground penetrating radar and antennas with the frequencies of 100 MHz and 270 MHz. Results. Based on the survey results, graphs of magnetic and self-potential fields, electrotomographic and microseismic sections, and radarogram were built on the research profile. The research has shown different levels of the magnetic field and the SP in the area of volcanic rocks and dikes of gabbro-dolerites occurrence. A significant increase in microseismic noise was observed with an increase in the weathering crust thickness. A local decrease in the SP potential, abnormally high values of specific electrical resistivity and intensive reflections of radio waves from the tunnel top were recorded above the underground water tunnel. Conclusions. Qualitative and quantitative geophysical characteristics were obtained in the area of the old underground water tunnel. The research showed different levels of the magnetic field and spontaneous polarization potentials in the occurrence area of rocks of different composition. A significant increase in microseismic noise was recorded with an increase in the weathering crust thickness. Geophysical signs of the boundaries between geological structures and artificial underground objects are revealed. The exact position and depth of the old underground tunnel of Glubochinsky hydraulic structures was determined.
研究目的是研究人工地下水隧洞区域的地球物理场特征和参数,评价地球物理方法识别地下隐伏工业设施的能力。研究方法。采用非极化电极和电探测接收机对自电位信号进行测量。磁探测是用质子磁强计进行的。采用斯伦贝谢对称测量方案的多电极电测量设备进行电层析成像。微地震背景是用自主地震台站记录的。地质雷达调查使用SIR-3000型探地雷达和频率分别为100兆赫和270兆赫的天线进行。结果。根据调查结果,建立了研究剖面的磁场图、自势场图、电断层图、微地震剖面和射线图。研究表明,在火山岩区和辉长榴辉岩脉区存在不同程度的磁场和SP。微震噪声随风化壳厚度的增加而显著增加。地下水隧道上方局部电位下降,比电阻率异常高,隧道顶部无线电波反射强烈。结论。获得了旧地下水隧洞区域的定性和定量地球物理特征。研究表明,不同成分岩石的赋存区具有不同的磁场强度和自发极化电位。微震噪声随风化壳厚度的增加而显著增加。揭示了地质构造与地下人工物体边界的地球物理标志。确定了格洛博钦斯基水工建筑物旧地下隧道的确切位置和深度。
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引用次数: 0
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Lesnoy Zhurnal-Forestry Journal
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