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Pyrolysis Kinetic Modelling of Wheat Straw from the Pannonian Region 潘诺尼亚地区小麦秸秆热解动力学模型
IF 0.7 Q3 Energy Pub Date : 2016-04-03 DOI: 10.1155/2016/9534063
I. Pešenjanski, B. Miljković, Marija Vičević
The pyrolysis/devolatilization is a basic step of thermochemical processes and requires fundamental characterization. In this paper, the kinetic model of pyrolysis is specified as a one-step global reaction. This type of reaction is used to describe the thermal degradation of wheat straw samples by measuring rates of mass loss of solid matter at a linear increase in temperature. The mentioned experiments were carried out using a derivatograph in an open-air environment. The influence of different factors was investigated, such as particle size, humidity levels, and the heating rate in the kinetics of devolatilization. As the measured values of mass loss and temperature functions transform in Arrhenius coordinates, the results are shown in the form of saddle curves. Such characteristics cannot be approximated with one equation in the form of Arrhenius law. For use in numerical applications, transformed functions can be approximated by linear regression for three separate intervals. Analysis of measurement resulting in granulation and moisture content variations shows that these factors have no significant influence. Tests of heating rate variations confirm the significance of this impact, especially in warmer regions. The influence of this factor should be more precisely investigated as a general variable, which should be the topic of further experiments.
热解/脱挥发是热化学过程的一个基本步骤,需要基本的表征。本文将热解动力学模型确定为一步全局反应。这种类型的反应是用来描述小麦秸秆样品的热降解,通过测量固体物质的质量损失率在线性增加的温度。上述实验是在露天环境中用衍生仪进行的。考察了不同粒径、湿度、加热速率等因素对脱挥发动力学的影响。当质量损失函数和温度函数的测量值在Arrhenius坐标系中变换时,结果以鞍形曲线的形式表示。这样的特征不能用阿伦尼乌斯定律形式的一个方程来近似。在数值应用中,变换后的函数可以用线性回归对三个独立的区间进行近似。对测量结果造粒和含水率变化的分析表明,这些因素没有显著的影响。对升温速率变化的测试证实了这种影响的重要性,特别是在较温暖的地区。这一因素的影响应该作为一个一般变量进行更精确的研究,这应该是进一步实验的主题。
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引用次数: 10
Ignition by Hot Transient Jets in Confined Mixtures of Gaseous Fuels and Air 热瞬态射流在气体燃料和空气的密闭混合物中的点火
IF 0.7 Q3 Energy Pub Date : 2016-03-27 DOI: 10.1155/2016/9565839
Abdullah Karimi, M. Nalim
Ignition of a combustible mixture by a transient jet of hot reactive gas is important for safety of mines, prechamber ignition in IC engines, detonation initiation, and novel constant-volume combustors. The present work is a numerical study of the hot jet ignition process in a long constant-volume combustor (CVC) that represents a wave rotor channel. The hot jet of combustion products from a prechamber is injected through a converging nozzle into the main CVC chamber containing a premixed fuel-air mixture. Combustion in a two-dimensional analogue of the CVC chamber is modeled using a global reaction mechanism, a skeletal mechanism, or a detailed reaction mechanism for three hydrocarbon fuels: methane, propane, and ethylene. Turbulence is modeled using the two-equation SST -ω model, and each reaction rate is limited by the local turbulent mixing timescale. Hybrid turbulent-kinetic schemes using some skeletal reaction mechanisms and detailed mechanisms are good predictors of the experimental data. Shock wave traverse of the reaction zone is seen to significantly increase the overall reaction rate, likely due to compression heating, as well as baroclinic vorticity generation that stirs and mixes reactants and increases flame area. Less easily ignitable methane mixture is found to show slower initial reaction and greater dependence on shock interaction than propane and ethylene.
热反应气体的瞬态喷射点火对矿井安全、内燃机预燃室点火、爆轰起爆和新型等体积燃烧器都具有重要意义。本文对长等容燃烧室(CVC)的热射流点火过程进行了数值研究。燃烧产物的热射流从预室通过会聚喷嘴注入含有预混燃料-空气混合物的CVC主室。燃烧在二维模拟CVC室是使用一个整体的反应机制,骨架机制,或详细的反应机制为三种碳氢化合物燃料:甲烷,丙烷和乙烯建模。湍流模型采用双方程SST -ω模型,每个反应速率受局部湍流混合时间尺度的限制。采用一些骨架反应机理和详细机理的湍流-动力学混合方案对实验数据有较好的预测作用。反应区的冲击波穿越可以显著提高整体反应速率,这可能是由于压缩加热,以及斜压涡量的产生,搅拌和混合反应物并增加火焰面积。与丙烷和乙烯相比,不易点燃的甲烷混合物表现出较慢的初始反应和更大的对激波相互作用的依赖性。
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引用次数: 3
The Effect of Injection Timings on Performance and Emissions of Compressed Natural-Gas Direct Injection Engine 喷射正时对压缩天然气直喷发动机性能和排放的影响
IF 0.7 Q3 Energy Pub Date : 2016-03-24 DOI: 10.1155/2016/6501462
Saad Aljamali, S. Abdullah, W. M. Mahmood, Y. Ali
This experimental part investigates the effect of injection timing on performance and emissions of homogenous mixture compressed natural-gas direct injection. The engine of 1.6 L capacity, 4 cylinders, spark ignition, and compression ratio of 14 was used. Performance and emission were recorded under wide-open throttle using an engine control system (Rotronics) and the portable exhaust gas analyser (Kane). The engine was tested at speed ranging from 1500 revolutions per minute (RPM) to 4000 RPM with 500 RPM increments. The engine control unit (ECU) was modified using Motec 800. The injection timings investigated were at the end of injection (EOI) 120 bTDC, 180 bTDC, 300 bTDC, and 360 bTDC. Results show high brake power, torque, and BMEP with 120 as compared with the other injection timings. At 4000 RPM the power, torque, and BMEP with 120 were 5% compared to that with 180. Furthermore, it shows low BSFC and high fuel conversion efficiency with 120. With 360, the engine produced less CO and CO2 at higher speeds.
本实验部分研究了喷射时间对均质混合压缩天然气直喷性能和排放的影响。发动机容量为1.6 L, 4缸,火花点火,压缩比为14。使用发动机控制系统(Rotronics)和便携式废气分析仪(Kane)记录了大开油门下的性能和排放。发动机测试的转速范围从每分钟1500转到每分钟4000转,每分钟增加500转。发动机控制单元(ECU)采用Motec 800进行了改进。研究的注射时间分别为:注射结束时的120、180、300和360次上止点。结果表明,与其他喷油正时相比,120喷油正时具有较高的制动功率、扭矩和BMEP。在4000转时,120转的功率、扭矩和BMEP比180转的低5%。此外,它具有低的BSFC和高的燃料转换效率(120)。在360发动机中,发动机在更高的速度下产生更少的CO和CO2。
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引用次数: 7
NOx, Soot, and Fuel Consumption Predictions under Transient Operating Cycle for Common Rail High Power Density Diesel Engines 共轨高功率密度柴油机瞬态运行周期下的氮氧化物、烟尘和燃料消耗预测
IF 0.7 Q3 Energy Pub Date : 2016-03-24 DOI: 10.1155/2016/1374768
N. Walke, M. R. Nandgaonkar, N. V. Marathe
Diesel engine is presently facing the challenge of controlling NOx and soot emissions on transient cycles, to meet stricter emission norms and to control emissions during field operations. Development of a simulation tool for NOx and soot emissions prediction on transient operating cycles has become the most important objective, which can significantly reduce the experimentation time and cost required for tuning these emissions. Hence, in this work, a 0D comprehensive predictive model has been formulated with selection and coupling of appropriate combustion and emissions models to engine cycle models. Selected combustion and emissions models are further modified to improve their prediction accuracy in the full operating zone. Responses of the combustion and emissions models have been validated for load and “start of injection” changes. Model predicted transient fuel consumption, air handling system parameters, and NOx and soot emissions are in good agreement with measured data on a turbocharged high power density common rail engine for the “nonroad transient cycle” (NRTC). It can be concluded that 0D models can be used for prediction of transient emissions on modern engines. How the formulated approach can also be extended to transient emissions prediction for other applications and fuels is also discussed.
目前,柴油发动机面临着控制瞬态循环NOx和烟尘排放的挑战,以满足更严格的排放标准,并控制现场作业中的排放。开发用于瞬态运行周期的氮氧化物和烟尘排放预测的模拟工具已成为最重要的目标,这可以显着减少调整这些排放所需的实验时间和成本。因此,在本工作中,通过选择合适的燃烧和排放模型并将其耦合到发动机循环模型中,建立了一个0D综合预测模型。进一步修改选定的燃烧和排放模型,以提高其在整个操作区域的预测精度。燃烧和排放模型的响应已经验证了负载和“开始喷射”的变化。模型预测的瞬态油耗、空气处理系统参数、氮氧化物和烟尘排放与涡轮增压高功率密度共轨发动机“非道路瞬态循环”(NRTC)的实测数据吻合良好。结果表明,0D模型可用于现代发动机瞬态排放的预测。本文还讨论了如何将所制定的方法推广到其他应用和燃料的瞬态排放预测。
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引用次数: 3
Evaluation of a Semiempirical, Zero-Dimensional, Multizone Model to Predict Nitric Oxide Emissions in DI Diesel Engines’ Combustion Chamber 半经验的评估,零维,多区域模型预测一氧化氮排放在直喷式柴油发动机的燃烧室
IF 0.7 Q3 Energy Pub Date : 2016-03-16 DOI: 10.1155/2016/6202438
N. Savva, D. Hountalas
In the present study, a semiempirical, zero-dimensional multizone model, developed by the authors, is implemented on two automotive diesel engines, a heavy-duty truck engine and a light-duty passenger car engine with pilot fuel injection, for various operating conditions including variation of power/speed, EGR rate, fuel injection timing, fuel injection pressure, and boost pressure, to verify its capability for Nitric Oxide (NO) emission prediction. The model utilizes cylinder’s basic geometry and engine operating data and measured cylinder pressure to estimate the apparent combustion rate which is then discretized into burning zones according to the calculation step used. The requisite unburnt charge for the combustion in the zones is calculated using the zone equivalence ratio provided from a new empirical formula involving parameters derived from the processing of the measured cylinder pressure and typical engine operating parameters. For the calculation of NO formation, the extended Zeldovich mechanism is used. From this approach, the model is able to provide the evolution of NO formation inside each burned zone and, cumulatively, the cylinder’s NO formation history. As proven from the investigation conducted herein, the proposed model adequately predicts NO emissions and NO trends when the engine settings vary, with low computational cost. These encourage its use for engine control optimization regarding NOx abatement and real-time/model-based NOx control applications.
在本研究中,作者建立了一种半经验的零维多区域模型,对两台带有先导燃油喷射的汽车柴油发动机(重型卡车发动机和轻型乘用车发动机)在功率/转速、EGR速率、燃油喷射正时、燃油喷射压力和增压压力等不同工况进行了仿真,验证了该模型对一氧化氮(NO)排放的预测能力。该模型利用汽缸的基本几何形状和发动机运行数据以及实测汽缸压力来估计表观燃烧速率,然后根据计算步骤将表观燃烧速率离散到燃烧区域。区域燃烧所需的未燃药量由区域等效比计算得到,该公式由处理实测气缸压力和典型发动机工作参数得到的参数组成。对于NO形成的计算,使用扩展的Zeldovich机制。通过这种方法,该模型能够提供每个燃烧区域内NO地层的演化情况,并累计提供柱体NO地层的历史。本文的研究表明,该模型能够较好地预测发动机设置变化时NO排放和NO趋势,且计算成本较低。这鼓励了它在发动机控制优化方面的应用,包括氮氧化物减排和实时/基于模型的氮氧化物控制应用。
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引用次数: 2
Formation of Liquid Products at the Filtration Combustion of Solid Fuels 固体燃料过滤燃烧时液体产物的形成
IF 0.7 Q3 Energy Pub Date : 2016-03-14 DOI: 10.1155/2016/9637082
E. Salgansky, V. M. Kislov, S. V. Glazov, M. Salganskaya
Yields of liquid and gaseous products of the filtration combustion of cellulose, wood, peat, coal, and rubber have been investigated. Experiments have shown that the gasification of solid fuels in the regime with superadiabatic heating yields liquid hydrocarbons with quantity and quality, which are close to those produced using other methods, for example, by pyrolysis. But in this case no additional energy supply is needed to carry out the gasification process. The low calorific combustible gas, which forms in this process, contains a substantial quantity of carbon monoxide and hydrogen, which are components of syngas.
研究了纤维素、木材、泥炭、煤和橡胶过滤燃烧的液体和气体产物的产率。实验表明,固体燃料在超绝热加热状态下的气化产生的液态碳氢化合物的数量和质量与使用其他方法(例如热解)产生的液态碳氢化合物接近。但在这种情况下,不需要额外的能源供应来进行气化过程。在此过程中形成的低热量可燃气体含有大量的一氧化碳和氢气,它们是合成气的组成部分。
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引用次数: 22
On Laminar Rich Premixed Polydisperse Spray Flame Propagation with Heat Loss 考虑热损失的富层流预混多分散喷雾火焰传播研究
IF 0.7 Q3 Energy Pub Date : 2016-03-02 DOI: 10.1155/2016/1069873
G. Kats, J. Greenberg
A mathematical analysis of laminar premixed spray flame propagation with heat loss is presented. The analysis makes use of a distributed approximation of the Arrhenius exponential term in the reaction rate expression and leads to an implicit expression for the laminar burning velocity dependent on the spray-related parameters for the fuel, gas-related parameters and the intensity of the heat losses. It is shown that the initial droplet load, the value of the evaporation coefficient, and the initial size distribution are the spray-related parameters which exert an influence on the onset of extinction. The combination of these parameters governs the manner in which the spray heat loss is distributed spatially and it is this feature that is the main factor, when taken together with volumetric heat loss, which determines the spray’s impact on flame propagation and extinction.
对考虑热损失的层流预混喷雾火焰传播进行了数学分析。分析利用了反应速率表达式中Arrhenius指数项的分布近似,得到了层流燃烧速度的隐式表达式,该表达式依赖于燃料的喷雾相关参数、气体相关参数和热损失强度。结果表明,雾滴初始负荷、蒸发系数值和初始粒径分布是影响消光发生的雾剂相关参数。这些参数的组合决定了喷雾热损失在空间上的分布方式,当与体积热损失一起考虑时,这一特征是决定喷雾对火焰传播和熄灭影响的主要因素。
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引用次数: 2
Comparative Numerical Study of Four Biodiesel Surrogates for Application on Diesel 0D Phenomenological Modeling 四种生物柴油替代品在柴油0D现象学建模中的应用比较数值研究
IF 0.7 Q3 Energy Pub Date : 2016-02-29 DOI: 10.1155/2016/3714913
Claude Valéry Ngayihi Abbe, R. Danwe, R. Nzengwa
To meet more stringent norms and standards concerning engine performances and emissions, engine manufacturers need to develop new technologies enhancing the nonpolluting properties of the fuels. In that sense, the testing and development of alternative fuels such as biodiesel are of great importance. Fuel testing is nowadays a matter of experimental and numerical work. Researches on diesel engine’s fuel involve the use of surrogates, for which the combustion mechanisms are well known and relatively similar to the investigated fuel. Biodiesel, due to its complex molecular configuration, is still the subject of numerous investigations in that area. This study presents the comparison of four biodiesel surrogates, methyl-butanoate, ethyl-butyrate, methyl-decanoate, and methyl-9-decenoate, in a 0D phenomenological combustion model. They were investigated for in-cylinder pressure, thermal efficiency, and emissions. Experiments were performed on a six-cylinder turbocharged DI diesel engine fuelled by methyl ester (MEB) and ethyl ester (EEB) biodiesel from wasted frying oil. Results showed that, among the four surrogates, methyl butanoate presented better results for all the studied parameters. In-cylinder pressure and thermal efficiency were predicted with good accuracy by the four surrogates. emissions were well predicted for methyl butanoate but for the other three gave approximation errors over 50%.
为了满足有关发动机性能和排放的更严格的规范和标准,发动机制造商需要开发新技术来提高燃料的无污染性能。从这个意义上说,测试和开发生物柴油等替代燃料是非常重要的。目前燃料测试是一个实验和数值工作的问题。柴油机燃料的研究涉及到使用替代燃料,这些替代燃料的燃烧机制是众所周知的,并且与所研究的燃料相对相似。生物柴油由于其复杂的分子结构,仍然是该领域众多研究的主题。本研究比较了四种生物柴油替代物,丁酸甲酯、丁酸乙酯、癸酸甲酯和9-癸酸甲酯,在0 -d现象燃烧模型中。他们的缸内压力,热效率和排放进行了调查。以废弃煎炸油制备的甲酯(MEB)和乙酯(EEB)生物柴油为燃料,在一台六缸涡轮增压直喷式柴油机上进行了试验。结果表明,在4种替代物中,丁酸甲酯对所有研究参数的效果都较好。四种替代方法均能较好地预测缸内压力和热效率。丁酸甲酯的排放量预测得很好,但其他三种的近似误差超过50%。
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引用次数: 4
Real Costs Assessment of Solar-Hydrogen and Some Fossil Fuels by means of a Combustion Analysis 基于燃烧分析的太阳能-氢和一些化石燃料的实际成本评估
IF 0.7 Q3 Energy Pub Date : 2016-02-03 DOI: 10.1155/2016/6527510
G. Nicoletti, R. Bruno, N. Arcuri, Gerardo Nicoletti
In order to compare solar-hydrogen and the most used fossil fuels, the evaluation of the “external” costs related to their use is required. These costs involve the environmental damage produced by the combustion reactions, the health problems caused by air pollution, the damage to land from fuel mining, and the environmental degradation linked to the global warming, the acid rains, and the water pollution. For each fuel, the global cost is determined as sum of the market price and of the correspondent external costs. In order to obtain a quantitative comparison, the quality of the different combustion reactions and the efficiency of the technologies employed in the specific application sector have to be considered adequately. At this purpose, an entropic index that considers the degree of irreversibility produced during the combustion process and the degradation of surroundings is introduced. Additionally, an environmental index that measures the pollutants released during the combustions is proposed. The combination of these indexes and the efficiency of the several technologies employed in four energy sectors have allowed the evaluation of the total costs, highlighting an economic scenario from which the real advantages concerning the exploitation of different energy carrier are determined.
为了比较太阳能氢燃料和最常用的化石燃料,需要评估与它们的使用有关的“外部”成本。这些成本包括燃烧反应造成的环境破坏、空气污染造成的健康问题、燃料开采对土地的破坏以及与全球变暖、酸雨和水污染有关的环境退化。对于每种燃料,全球成本由市场价格和相应的外部成本之和确定。为了获得定量比较,必须充分考虑不同燃烧反应的质量和特定应用领域所采用的技术的效率。为此,引入了考虑燃烧过程和环境退化过程中产生的不可逆性程度的熵指数。此外,还提出了一种测量燃烧过程中释放的污染物的环境指标。将这些指数和四个能源部门所采用的几种技术的效率结合起来,可以对总成本进行评价,突出了一种经济情景,从中可以确定利用不同能源载体的真正优势。
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引用次数: 5
Review of Sensing Methodologies for Estimation of Combustion Metrics 燃烧度量估计的传感方法综述
IF 0.7 Q3 Energy Pub Date : 2016-01-28 DOI: 10.1155/2016/8593523
Libin Jia, J. Naber, J. Blough
For reduction of engine-out emissions and improvement of fuel economy, closed-loop control of the combustion process has been explored and documented by many researchers. In the closed-loop control, the engine control parameters are optimized according to the estimated instantaneous combustion metrics provided by the combustion sensing process. Combustion sensing process is primarily composed of two aspects: combustion response signal acquisition and response signal processing. As a number of different signals have been employed as the response signal and the signal processing techniques can be different, this paper did a review work concerning the two aspects: combustion response signals and signal processing techniques. In-cylinder pressure signal was not investigated as one of the response signals in this paper since it has been studied and documented in many publications and also due to its high cost and inconvenience in the application.
为了减少发动机排放和提高燃油经济性,燃烧过程的闭环控制已经被许多研究者探索和记录。在闭环控制中,根据燃烧感知过程提供的估计的瞬时燃烧指标对发动机控制参数进行优化。燃烧传感过程主要由燃烧响应信号采集和响应信号处理两个方面组成。由于采用了多种不同的信号作为响应信号,信号处理技术也不尽相同,本文从燃烧响应信号和信号处理技术两方面进行了综述。由于缸内压力信号已经在许多出版物中进行了研究和记录,并且由于其成本高且应用不便,因此本文没有将其作为响应信号之一进行研究。
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引用次数: 12
期刊
Journal of Combustion
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