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ATMOSPHERIC CORROSION BEHAVIOR OF HOT-DIP GALVANIZED AND CONTINUOUS GALVANIZED STEEL 热镀锌和连续镀锌钢的大气腐蚀行为
IF 1 Q3 Materials Science Pub Date : 2022-09-24 DOI: 10.36547/ams.28.3.1526
G. Sığırcık, Ömer Yıldırım, T. Tüken
Five years of outdoor atmospheric corrosion tests of hot dip galvanized steel samples were performed, for products of continuous galvanizing and after fabrication batch galvanizing processes. For the purpose of comparison between corrosion performances of these two different galvanizing process products, an industrial coastal area (Gemlik-Bursa/TURKEY) was chosen for outdoor testing, which fits into C4 type corrosive atmosphere definition, according to ISO 9223. Samples were studied in laboratory with accelerated salt spray exposure test and electrochemical methods. Corrosion products formed on exposed samples and cross section of coatings are analyzed by SEM. Lead is observed to change the corrosion characteristics of the coatings with change in constituents of environments. In saline electrolytes, alloying of lead is found to accelerate corrosion rate. This metal deposits as cluster on top layer of the galvanized coatings and acts as strong cathodes with respect to the zinc and accelerates the corrosion rate. It was determined that differences in dip and continuous galvanization processes cause dramatic differences in the elemental composition, morphology and regional hardness values of coatings. In the comparison of corrosion resistance, lower performance of the dip galvanized coating, although it is much thicker, has been shown due to the differences mentioned above.
对连续镀锌和批量镀锌产品进行了5年的室外大气腐蚀试验。为了比较这两种不同镀锌工艺产品的腐蚀性能,选择了一个工业沿海地区(gemlikk - bursa /TURKEY)进行室外测试,该地区符合ISO 9223的C4型腐蚀性大气定义。采用加速盐雾暴露试验和电化学方法对样品进行了室内研究。利用扫描电镜分析了裸露试样和涂层截面上形成的腐蚀产物。观察到铅会随着环境成分的变化而改变镀层的腐蚀特性。在含盐电解质中,发现铅的合金化会加速腐蚀速率。这种金属以簇状沉积在镀锌涂层的顶层,作为锌的强阴极,加速了腐蚀速度。结果表明,浸镀锌和连续镀锌工艺的不同会导致镀层元素组成、形貌和区域硬度值的显著差异。在耐腐蚀性能的比较中,由于上述差异,浸镀锌涂层虽然厚得多,但性能较低。
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引用次数: 0
THERMO-MECHANICAL AND MICROSTRUCTURAL INVESTIGATIONS OF AA 6061/GNPS WELDED JOINTS DEVELOPED BY CONTINUOUS DRIVE FRICTION WELDING 连续驱动摩擦焊AA 6061/GNPS焊接接头的热机械和微观组织研究
IF 1 Q3 Materials Science Pub Date : 2022-09-24 DOI: 10.36547/ams.28.3.1573
M. Tashkandi, M. Gamil
The paper provides a novel technique for merging graphene nanoplatelets (GNPs) within aluminium matrix (AA 6061) by continuous drive friction welding (CDFW). The welding processes were done at 1400 rpm and 2000 rpm rotational speeds with two different frictional loads 2000 N and 2500 N for 5 sec and 7 sec welding times. The welded joints were subjected to tensile and hardness tests. The heating-cooling cycles through the welding process were monitored. The microstructure investigation was performed using optical and scanning electron microscopes (SEM). The effect of welding conditions on the ultimate tensile strength (UTS) results of AA 6061 and AA 6061/GNPs were completely studied in details. There is no big detectable variation in the mean hardness values due to the GNPs addition. The best welding conditions for achieving the highest mechanical properties were defined. The presence of GNPs in the welded joints results in lower heating at the welded joint at the same welding conditions. Finer grain structure and homogeneous distribution for the GNPs within the welding zone were observed.
本文提出了一种通过连续驱动摩擦焊接(CDFW)将石墨烯纳米片(GNP)融合在铝基体(AA 6061)中的新技术。焊接过程在1400rpm和2000rpm的转速下进行,两种不同的摩擦载荷分别为2000N和2500N,焊接时间分别为5秒和7秒。对焊接接头进行了拉伸和硬度测试。对焊接过程中的加热-冷却循环进行了监测。使用光学显微镜和扫描电子显微镜(SEM)进行微观结构研究。详细研究了焊接条件对AA6061和AA6061/GNP极限抗拉强度(UTS)结果的影响。由于添加了GNP,平均硬度值没有大的可检测变化。确定了实现最高机械性能的最佳焊接条件。在相同的焊接条件下,焊接接头中GNP的存在导致焊接接头处的加热较低。观察到GNP在焊接区内具有更细的晶粒结构和均匀分布。
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引用次数: 0
CONTROL OF THE PROCESSES OF PHASE FORMATION OF CARBIDE COMPONENTS IN NICKEL-BASED SUPERALLOYS 镍基高温合金中碳化物组分相形成过程的控制
IF 1 Q3 Materials Science Pub Date : 2022-06-22 DOI: 10.36547/ams.28.2.1506
A. Glotka, V. Ol’shanetskii
The mathematical dependences of thermodynamic processes of precipitation of carbide phases are determined, and a practical study of the structure and distribution of chemical elements is carried out. Regularities were established for the effect of the chemical composition of the alloy on the morphology and type of carbides. It is shown that, depending on the introduced chemical elements in the system, the types of carbides and their chemical composition can change, which leads to a decrease in the processes of crack formation in the material. The established dependencies for the multicomponent system Ni-22.5Cr-19Co-1.9Al-3.7Ti-2W-1.4Ta-1Nb-0.15C make it possible to determine the chemical composition of carbides from the chemical composition of the alloy. The evaluation of the results obtained by the calculation method and experimental data was carried out, the analysis of the results gave good convergence and can be recommended for industrial use.
确定了碳化物相析出热力学过程的数学依赖性,并对化学元素的结构和分布进行了实际研究。建立了合金化学成分对碳化物形态和类型影响的规律。研究表明,根据系统中引入的化学元素,碳化物的类型及其化学成分会发生变化,从而减少材料中裂纹形成的过程。建立的多组分体系Ni-22.5Cr-19Co-1.9Al-3.7Ti-2W-1.4Ta-1Nb-0.15C的依赖性使得从合金的化学成分确定碳化物的化学成分成为可能。对计算方法得到的结果和实验数据进行了评价,结果分析具有良好的收敛性,可推荐工业应用。
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引用次数: 1
SOLID STATE DIFFUSION BONDING OF X70 STEEL TO DUPLEX STAINLESS STEEL X70钢与双相不锈钢的固态扩散连接
IF 1 Q3 Materials Science Pub Date : 2022-06-22 DOI: 10.36547/ams.28.2.1504
Z. Boumerzoug, Lamia Baghdadi, F. Brisset, D. Solas, T. Baudin
This paper deals with the solid state diffusion bonding of X70 steel to duplex stainless steel. Microstructure and mechanical properties of the welded dissimilar steels were investigated. Optical microscopy, Electron Backscatter Diffraction, energy dispersive spectrometry, Vickers hardness measurements, and X-Ray Diffraction were the main techniques of characterization. Microtructural variation was observed in the X70 steel side compared to duplex stainless steel. The diffusion coefficient of iron, chromium, and nickel across the interface X70 steel/duplex stainless steel was also measured. The diffusion coefficient of iron and chromium is higher than that of nickel. The Vickers microhardness profile across the bond joint showed an abrupt decrease in hardness from duplex stainless steel to X70 steel. In addition, a dynamic recrystallisation reaction was observed close to the interface in the X70 steel side.
本文研究了X70钢与双相不锈钢的固态扩散连接。研究了焊接异种钢的组织和力学性能。光学显微镜、电子背散射衍射、能量色散光谱、维氏硬度测量和X射线衍射是表征的主要技术。与双相不锈钢相比,在X70钢侧观察到微观结构变化。还测量了铁、铬和镍在X70钢/双相不锈钢界面上的扩散系数。铁和铬的扩散系数高于镍。从双相不锈钢到X70钢,整个接头的维氏显微硬度分布显示硬度急剧下降。此外,在X70钢侧的界面附近观察到动态再结晶反应。
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引用次数: 2
PROPERTIES OF Al-Zn-Mg-Cu ALLOY WHEN MODIFIED BY La, Ce, AND THERMAL-MECHANICAL La、Ce和热机械改性Al-Zn-Mg-Cu合金的性能
IF 1 Q3 Materials Science Pub Date : 2022-06-22 DOI: 10.36547/ams.28.2.1424
D. Nguyen, T. Bui, A. Vu, Manh-Thang Sai, M. K. Pham, Duc-Huy Tran
The influence of La, Ce elements and thermal-mechanical treatment on microstructure and mechanical properties of Al-Zn-Mg-Cu alloy are presented in this study. According to the results, when the alloy was added to the La, Ce elements, after casting, the grain size of samples was around 40-50µm compared to that of without about 65µm; and then these impurity samples attained 30µm after homogeneous mixture the grain sizes. After the cold deformation process, the distance between plates is 10µm. This homogenization process contributes to increasing the ductility of the studied alloy. In addition, the EDS lines study shows that after the combination of the deformation and heat treatment, the uniformation of elements mainly focuses on the boundary and in the grain. After recrystallization annealing, the grain size is around 10 µm with the modification sample. Further, as a result of ability deformation from the tensile test, these results demonstrate that the tensile test obtained 140 % when adding La, Ce contents into the alloy combined with thermal-mechanical treatment. The combined use of La; Ce and thermal-mechanical treatment have increased the ductility of Al-Zn-Mg-Cu alloy. The combination of modification and thermal-mechanical treatment has created a small grain size for the studied alloy.
研究了La、Ce元素及热机械处理对Al-Zn-Mg-Cu合金组织和力学性能的影响。根据结果,当合金在铸造后添加到La、Ce元素中时,样品的晶粒尺寸约为40-50µm,而不添加约65µm;然后这些杂质样品在均匀混合晶粒尺寸后达到30µm。冷变形过程后,板之间的距离为10µm。这种均匀化过程有助于提高所研究合金的延展性。此外,EDS谱线研究表明,变形和热处理相结合后,元素的均匀化主要集中在边界和晶粒中。再结晶退火后,改性样品的晶粒尺寸约为10µm。此外,作为拉伸试验的能力变形的结果,这些结果表明,当将La、Ce含量添加到合金中并结合热机械处理时,拉伸试验获得140%。La的组合使用;Ce和热机械处理提高了Al-Zn-Mg-Cu合金的延展性。改性和热机械处理的结合为所研究的合金创造了小的晶粒尺寸。
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引用次数: 0
Bonding of Interface Bimetal Aluminum-Bronze for Bimetal Bushing Produced by Solid Liquid Method 固液法双金属衬套双金属铝青铜界面的粘接
IF 1 Q3 Materials Science Pub Date : 2022-06-22 DOI: 10.36547/ams.28.2.1253
L. Setyana, N. Santoso, Bambang Suharnadi, Benidiktus Tulung Prayoga, Wiyadi Wiyadi
Bimetal is a combination of two dissimilar metals that form a metallurgical bond. The manufacture of bimetallic bushing by centrifugal casting has not been widely developed. There is still no recommendation for optimum temperature used in the manufacture. The aim of this research was to determine the first frozen layer temperature of the aluminum when bronze was poured to produce a well-integrated bond interface. The materials used were aluminum and bronze. Molten metal was pouring into the mold alternately. First, aluminum was poured into the mold. Then, bronze was poured gradually to form a bushing aluminum-bronze bimetallic. The temperature variations of the first frozen layer of aluminum were 27º C, 350º C, 400º C, and 450º C when bronze poured. The molten metal was poured with the filling speed of about 0.2 kg/s into a rotating sand mold. The rotational speed of the mold was 350 rpm. The result shows that the bond interface’s width increases as the first frozen layer aluminum temperature increases. As a result, interface wear and hardness are increased compared to the base metal. Hence, centrifugal casting with the first frozen layer aluminum was 450ºC recommended for aluminum-bronze bimetal bushing applications.
双金属是两种不同金属的结合,形成冶金结合。用离心铸造的方法制造双金属套管还没有得到广泛的发展。对于制造中使用的最佳温度仍然没有建议。本研究的目的是确定浇注青铜以产生良好集成的粘结界面时铝的第一个冻结层温度。使用的材料是铝和青铜。熔化的金属交替地倒入模具中。首先,将铝倒入模具中。然后,逐渐浇注青铜以形成衬套铝青铜双金属。浇注青铜时,第一层铝冻结层的温度变化为27ºC、350ºC、400ºC和450ºC。将熔融金属以约0.2kg/s的填充速度倒入旋转砂模中。模具的旋转速度为350rpm。结果表明,随着第一凝固层铝温度的升高,界面宽度增大。结果,与基底金属相比,界面磨损和硬度增加。因此,对于铝青铜双金属套管应用,建议使用450ºC的第一个凝固层铝离心铸造。
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引用次数: 0
AN APPROACH TOWARD PREDICTION OF SM-CO ALLOY’S MAXIMUM ENERGY PRODUCT USING FEATURE BAGGING TECHNIQUE 基于特征套袋技术的sm-co合金最大能积预测方法
IF 1 Q3 Materials Science Pub Date : 2022-06-22 DOI: 10.36547/ams.28.2.1462
V. Kulyk
The work aims to solve the problem of predicting magnetic properties on the example of Sm-Co alloy using artificial intelligence. In particular, the authors solved the Sm-Co alloys maximum energy product prediction task using the feature bagging technique. To implement this approach, we have chosen the Random Forest algorithm, which efficiently processes short data sets by reducing variance and, as a result, reducing the impact/avoidance of overfitting. Experimental modelling was based on a short set of data (190 observations) collected by the authors with many independent attributes. As a result, it has been experimentally established that the studied machine learning method provides a high value of the coefficient of determination - 0.78 when solving Sm-Co alloy’s maximum energy product prediction task. Furthermore, by comparing with other ensemble methods from different classes, the highest accuracy of the researched process is established based on various performance indicators.
本工作旨在解决以Sm-Co合金为例的人工智能磁性能预测问题。利用特征套袋技术解决了Sm-Co合金最大能积预测问题。为了实现这种方法,我们选择了随机森林算法,该算法通过减少方差有效地处理短数据集,从而减少了过度拟合的影响/避免。实验模型是基于作者收集的具有许多独立属性的一组短数据(190个观测值)。实验结果表明,所研究的机器学习方法在解决Sm-Co合金最大能积预测任务时提供了较高的决定系数值- 0.78。此外,通过比较不同类别的集成方法,基于各种性能指标确定了所研究过程的最高精度。
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引用次数: 0
STUDY ON DEEP DRAWING BEHAVIOR OF THE INTERSTITIAL FREE STEEL IN CORRELATION WITH THE MICROSTRUCTURE 无间隙钢的深冲行为与组织的相关性研究
IF 1 Q3 Materials Science Pub Date : 2022-06-22 DOI: 10.36547/ams.28.2.1416
E. Brandaleze, M. Romanyuk
The objective of this paper was to present results obtained about the behaviour of the IF steel associated with high deformation. To evaluate the deep drawing aptitude, samples were subjected to tensile test, n and r values determination, hole expansion and Erichsen tests. The results were correlated with a microstructural study. Through thermodynamic simulation, the phase transformation temperature (Tg®a) and the precipitates formation were estimated. The Tg®a value was also determined by dilatometry test. The failure of the material during deep drawing or stamping process is evidenced through the formation of cracks in areas with critical angles changes. It was relevant to understand the mechanisms of fracture nucleation and propagation of the IF steel. A fractography study was carried out and was possible to verify the presence of cavitation mechanism as results of the superplastic flow at high deformation conditions, promoting necking and fracture after a high plastic deformation achieved.
本文的目的是介绍有关IF钢与高变形相关的行为的结果。为了评估深冲能力,对样品进行拉伸试验、n和r值测定、孔膨胀和Erichsen试验。结果与微观结构研究相关。通过热力学模拟,估计了相变温度(Tg®a)和沉淀物的形成。Tg®a值也通过膨胀计测试确定。材料在拉深或冲压过程中的失效是通过在临界角度变化的区域形成裂纹来证明的。这与理解IF钢的断裂成核和扩展机制有关。进行了断口形貌研究,并有可能验证空化机制的存在,这是高变形条件下超塑性流动的结果,在实现高塑性变形后促进颈缩和断裂。
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引用次数: 0
THE INFLUENCE OF ANNEALING TEMPERATURE ON THE MAGNETIC PROPERTIES OF CRYO-ROLLED NON-ORIENTED ELECTRICAL STEEL 退火温度对冷轧无取向电工钢磁性能的影响
IF 1 Q3 Materials Science Pub Date : 2022-06-22 DOI: 10.36547/ams.28.2.1471
T. Kvačkaj, I. Demjan, Peter D. Bella, R. Kočiško, P. Petroušek, Alica Fedoriková, J. Bidulská, Miloslav Lupták, P. Jandačka, Marcela Lascsáková
The paper is focused on a comparison of the magnetic properties of the non-oriented isotropic electrical steel containing 3.5% Si. The material was processed by conventional ambient temperature rolling and progressive rolling at the cryogenic conditions at liquid nitrogen. Deformations of the samples in both thermal conditions were in the interval εÎ<5;35>[%]. Subsequently, the samples were heat treated at temperatures TÎ<900;1100> [°C]. Measuring of the magnetic properties was carried out in an alternating magnetic field at frequencies f= 50; 100; 150 Hz. At a frequency of 50 Hz were achieved smallest magnetic losses and therefore further measurements were made at a given frequency. Followed measurements of the magnetic induction were conducted at different intensities of the magnetic field. EBSD analyses were performed to obtain the IPF maps on which the resulting structure was evaluated after processing of the material. The specific magnetic losses were compared to different processing methods. The best magnetic properties defined as by minimal values of core loses were reached after samples rolled at cryogenic temperature followed by subsequently annealed. Also, higher proportion of cubic texture was archived after rolling at cryogenic temperature with compared to samples processed at ambient   temperature.
本文对含3.5% Si的无取向各向同性电工钢的磁性能进行了比较。采用常规常温轧制和液氮低温条件下的连续轧制两种方法对材料进行了加工。两种热条件下试样的变形量在εÎ[%]区间内。随后,样品在TÎ[°C]温度下进行热处理。在频率为f= 50的交变磁场中进行磁性测量;100;150赫兹。在50赫兹的频率下实现了最小的磁损失,因此在给定的频率下进行了进一步的测量。随后在不同强度的磁场下进行了磁感应强度的测量。进行EBSD分析以获得IPF图,在此图上对材料处理后的所得结构进行评估。比较了不同加工方法的比磁损耗。样品经低温轧制后再退火后,磁性能达到最佳,即磁芯损耗最小。此外,与常温下处理的样品相比,低温轧制后的样品中立方织构的比例更高。
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引用次数: 2
Performance Evaluation of Coconut Oil Based Cutting Fluid with Biodegradable Additives on Cylindrical Turning of AISI 1040 Carbon Steel 添加可生物降解添加剂的椰子油基切削液在AISI 1040碳钢圆柱车削中的性能评价
IF 1 Q3 Materials Science Pub Date : 2022-03-15 DOI: 10.36547/ams.28.1.1256
S. Adedayo, Bright Omoshola, P. Omoniyi
This article analyzed the effect of coconut oil-based cutting fluid with emulsion properties of 5%. The cutting fluid was evaluated by comparing it with conventional cutting fluid (Petroleum Based). Machining temperature at the tool-workpiece interface was measured during straight turning operation on CNC machine at various cutting speeds, depths of cut, and fixed feed rate of 7.5 mm/min for 15 minutes. The Response Surface Methodology (RSM) was also used to determine the machining parameters' effect on each cutting fluid's temperature at the tool-workpiece interface. It was observed that the developed coconut cutting fluid outperformed the other cutting fluids as a coolant at all experimented speeds, with a maximum temperature of 63.5 °C at the working zone as against 90.6 °C observed for conventional cutting fluid and 163.8 °C for dry turning. The viscosity values obtained from the developed cutting fluid between 40 °C and 100 °C show the tendency of the developed cutting fluid to maintain its lubricity at a higher temperature. Depth of cut was also observed to have a significant effect on the temperature at the tool-workpiece interface.
本文分析了乳化性能为5%的椰子油基切削液的切削效果。通过与常规切削液(石油基)的比较,对该切削液进行了评价。测量了数控机床在不同切削速度、切削深度、固定进给速度为7.5 mm/min、加工时间为15 min的直车削过程中,刀-工件界面的加工温度。利用响应面法(RSM)确定了加工参数对刀-工件界面各切削液温度的影响。据观察,在所有实验速度下,开发的椰子切削液作为冷却剂的性能优于其他切削液,在工作区域的最高温度为63.5°C,而传统切削液的最高温度为90.6°C,干车削的最高温度为163.8°C。在40 ~ 100℃范围内得到的切削液粘度值表明,切削液在较高温度下仍有保持润滑的趋势。切削深度对刀具-工件界面温度也有显著影响。
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引用次数: 1
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Acta Metallurgica Slovaca
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