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Investigation on Microstructure and Compressive Strength of Brazing Porous Nickel to Copper and Stainless Steel 多孔镍与铜及不锈钢钎焊的显微组织及抗压强度研究
Q3 Materials Science Pub Date : 2023-09-25 DOI: 10.36547/ams.29.3.1863
Ramizah Rozaimay, Tuan Zaharinie Tuan Zahari, Yose Fachmi Buys, Poo Balan Ganesan, Zainul Huda, Tadashi Ariga
This paper investigates the effects of brazing temperatures on the microstructure and compressive strength for brazing porous nickel to copper and stainless steel using VZ2250 as the brazing filler metal. A high vacuum furnace is used to braze the samples. Three different brazing process parameters were set with a heating and cooling rate of 10°C/min, respectively. The characteristics of the joint interface have been investigated to evaluate the performance of the brazed samples by use of scanning electron microscope, energy-dispersive X-Ray spectroscope, X-Ray diffractometer, and Instron Universal Testing machine. The data obtained has been quantitively analyzed to confirm the diffusion of the BFM during the brazing process. It has been found that the diffusion process resulted in an increase in the rigidity of the porous Ni. The compressive strength tests for the brazed joint showed that the maximum compressive strength can be achieved for brazing at 680°C. The highest compressive strength value has been justified by quantitative analysis of the microstructural data. It has been proved that the VZ2250 BFM effectively diffused into the porous Ni at the brazing temperature of 680°C; Cu3P and Cu6Sn5 were detected at the brazed Interface 1, whereas MnNi3 phase at the brazed Interface 2.
以VZ2250为钎料,研究了钎焊温度对多孔镍与铜、不锈钢钎焊组织和抗压强度的影响。用高真空炉钎焊样品。设置3种不同的钎焊工艺参数,加热和冷却速度分别为10℃/min。采用扫描电子显微镜、能谱仪、x射线衍射仪和Instron万能试验机对钎焊试样的接头界面特征进行了研究,以评价钎焊试样的性能。对所获得的数据进行了定量分析,以证实BFM在钎焊过程中的扩散。结果表明,扩散过程使多孔Ni的硬度增加。钎焊接头抗压强度试验表明,在680℃时钎焊可达到最大抗压强度。通过显微组织数据的定量分析,确定了最高的抗压强度值。结果表明,在钎焊温度为680℃时,VZ2250 BFM能有效扩散到多孔Ni中;在钎焊界面1中检测到Cu3P和Cu6Sn5相,而在钎焊界面2中检测到MnNi3相。
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引用次数: 0
INCIDENCE OF HEAT TREATMENT ON THE CORROSIVE BEHAVIOR OF AISI 316L AUSTENITIC STAINLESS STEEL 热处理对aisi 316l奥氏体不锈钢腐蚀行为的影响
Q3 Materials Science Pub Date : 2023-09-25 DOI: 10.36547/ams.29.3.1803
Mariano Nicolás Inés, Graciela Analía Mansilla
Heat treatments of AISI 316L samples were conducted at 900°C with slow cooling in air to induce varied precipitation of chromium-rich carbide particles at grain boundaries, resulting in a microstructure susceptible to intergranular corrosion. The corrosion behavior of the material in this state was investigated in a salt spray chamber containing 5% NaCl. The temperature inside the chamber was set at 35°C, while the saturated air temperature was recorded at 47°C. Samples were periodically extracted for observation and analysis using a stereoscopic magnifying glass, optical microscope, and scanning electron microscope. The results revealed the detrimental effect of chloride ions on the corrosion behavior of these stainless steels. Metallographic examination of corroded specimens after the salt spray test confirmed that the passive layer's breakdown was responsible for the intergranular corrosion occurring along preferential paths of chromium carbides.
对AISI 316L试样进行900℃空气缓慢冷却热处理,在晶界处析出不同形式的富铬碳化物颗粒,形成易发生晶间腐蚀的显微组织。在含5% NaCl的盐雾室中研究了这种状态下材料的腐蚀行为。室内温度设定为35℃,饱和空气温度记录为47℃。定期抽取样品,用立体放大镜、光学显微镜、扫描电镜观察分析。结果表明氯离子对这些不锈钢的腐蚀行为有不利影响。盐雾试验后腐蚀试样的金相检查证实,钝化层的击穿是导致沿碳化铬优先路径发生晶间腐蚀的原因。
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引用次数: 0
Characterization of Hot Deformation behavior for Ultra-High Strength (UHS) Steel containing Tungsten 超高强度(UHS)含钨钢热变形行为的表征
Q3 Materials Science Pub Date : 2023-09-25 DOI: 10.36547/ams.29.3.1835
Taher El-Bitar, Maha ElMeligy, Wojciech Borek, Saad Ebied
The steel alloy of the current study contains 0.3% carbon with different amounts of Cr, and Mo, in addition to W. Single simulation hits were designed as isothermal passes for compressive hot deformation up to 0.5 true strain. Each simulation compressive pass was carried out at temperatures, 1050, 950, 850 and 750 oC, with strain rates 0.1 and 1.0 sec-1. A numerical computational model is used for formulation of the alloy hot flow behavior at the specified conditions. The model considers inseparable strain hardening mechanism and dynamic softening phenomenon. It is noticed that high deformation temperature lowers the flow stress value (σf), while the increase of the strain rate raises it. The flow curves reveal initial high strain hardening phenomena in combination with low dynamic softening features. With the increase of strain, the dynamic softening, becomes dominant, and the flow stress gradually drops until a relatively stable stress level. Predicted flow curves were then constructed and compared with their counterpart experimental flow curves. The predicted flow curves are typically matching the counterpart experimental ones.
本研究的钢合金除含有w外,还含有0.3%的碳和不同数量的Cr、Mo,并将单次模拟命中设计为等温孔道,用于高达0.5真应变的压缩热变形。在1050、950、850和750℃的温度下,应变速率分别为0.1和1.0 sec-1。采用数值计算模型对合金在特定条件下的热流行为进行了数值模拟。该模型考虑了不可分割的应变硬化机制和动态软化现象。高变形温度使流变应力值(σf)降低,而应变速率的增大使流变应力值升高。流动曲线表现出初始高应变硬化现象和低动态软化特征。随着应变的增加,动态软化成为主导,流动应力逐渐下降,直到一个相对稳定的应力水平。然后构建预测流动曲线,并与相应的实验流动曲线进行比较。预测的流动曲线通常与对应的实验曲线相匹配。
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引用次数: 0
EXPERIMENTAL DETERMINATION OF THE DRAW BEAD COEFFICIENT OF FRICTION OF CuZn SHEETS IN SHEET METAL FORMING PROCESSES 金属板成形过程中锌板拉延头摩擦系数的实验测定
Q3 Materials Science Pub Date : 2023-09-25 DOI: 10.36547/ams.29.3.1780
Tomasz Trzepieciński, Valmir Dias Luiz, Marcin Szpunar
In sheet metal forming, draw beads are used to limit the flow of sheet metal in specific areas of the stamping die. The value of the coefficient of friction at the draw bead determines achievement of the desired resistance to sheet displacement. This article presents the results of experimental tests for determining the coefficient of friction on a draw bead using a specially developed tribotester. The test material consisted of CuZn37, CuZn30 and CuZn10 brass sheets in various states of hardening. Investigations were carried out with different roughness of the countersamples and sliding speeds. In addition, the tests were carried out under conditions of dry friction and lubrication of the sheet surface with LAN-46 machine oil. The relationships between the process parameters and the value of the coefficient of friction were analysed using the analysis of variance. It was found that the coefficient of friction decreases with increasing mean roughness of the countersamples. Lubrication reduced friction by about 6.2-29.8% depending on the grade of the tested sheet and the sliding speed.
在钣金成形中,拉伸珠用于限制冲压模具特定区域内钣金的流动。拉伸头处的摩擦系数决定了板料位移阻力的实现。本文介绍了用专门研制的摩擦试验机测定拉延头摩擦系数的试验结果。试验材料由不同硬化状态的CuZn37、CuZn30和CuZn10黄铜片组成。在不同的反样粗糙度和滑动速度下进行了研究。此外,还在干摩擦和用LAN-46机油润滑板料表面的条件下进行了试验。采用方差分析法分析了工艺参数与摩擦系数之间的关系。结果表明,摩擦系数随反样平均粗糙度的增大而减小。根据被测薄片的等级和滑动速度的不同,润滑减少了约6.2-29.8%的摩擦。
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引用次数: 0
MICROSTRUCTURE EVOLUTION AND HARDNESS IMPROVEMENT OF GRAY CAST IRON BY ADDITION OF FeSiMg FOLLOWED BY FLAME HARDENING PROCESS 添加FeSiMg后火焰硬化灰铸铁的显微组织演变及硬度的提高
Q3 Materials Science Pub Date : 2023-09-25 DOI: 10.36547/ams.29.3.1794
Agung Setyo Darmawan, Agus Dwi Anggono, Agus Yulianto, Bambang Waluyo Febriantoko, None Masyrukan
The addition of magnesium alloy elements followed by a flame-hardening process will change the phase configuration in gray cast iron. This study aims to investigate changes in microstructure and hardness due to these two processes. The addition of magnesium is conducted by adding FeSiMg as a carrier for magnesium. Metallographic examination to observe changes in microstructure was carried out using a Scanning Electron Microscope (SEM) and Energy-Dispersive X-ray Spectroscopy (EDS). The formed phase is examined by X-Ray Diffraction testing. The hardness test was carried out using the Vickers technique on the surface of the gray cast iron, the nodular cast iron, and the flame-hardened nodular cast iron. Whilst for flame-hardened nodular cast iron, the Vickers technique was also conducted on a cross-section. The addition of the FeSiMg compound changed flake graphite into spherical graphite with increased hardness from 130 VHN to 313.22 VHN. The flame-hardening process in nodular cast iron results in the formation of a martensite phase and the disappearance of graphite on the surface of the material. The hardness on the surface of the material due to the flame-hardening process increased by 82.4% compared to the substrate.
加入镁合金元素后进行火焰硬化处理将改变灰口铸铁的相结构。本研究旨在研究这两种工艺对合金显微组织和硬度的影响。镁的添加是通过添加FeSiMg作为镁的载体进行的。利用扫描电子显微镜(SEM)和能量色散x射线能谱仪(EDS)进行金相检查,观察微观结构的变化。形成的相用x射线衍射测试来检验。采用维氏法对灰口铸铁、球墨铸铁和火焰淬硬球墨铸铁的表面进行了硬度测试。而对于火焰硬化球墨铸铁,维氏技术也在横截面上进行。FeSiMg化合物的加入使片状石墨变成球形石墨,硬度从130 VHN提高到313.22 VHN。球墨铸铁的火焰硬化过程导致马氏体相的形成和材料表面石墨的消失。经火焰硬化处理后,材料表面硬度较基体提高了82.4%。
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引用次数: 0
PREDICTION OF HARDNESS, FLEXURAL STRENGTH, AND FRACTURE TOUGHNESS OF ZRO2 BASED CERAMICS USING ENSEMBLE LEARNING ALGORITHMS 用集成学习算法预测ZRO2基陶瓷的硬度、弯曲强度和断裂韧性
IF 1 Q3 Materials Science Pub Date : 2023-06-20 DOI: 10.36547/ams.29.2.1819
V. Kulyk, I. Izonin, V. Vavrukh, R. Tkachenko, Z. Duriagina, B. Vasyliv, M. Kováčová
Flexural strength, hardness, and fracture toughness are the basic mechanical properties of ceramic materials. Manufacturers widely use this set of properties to ensure the durability of ceramic products. However, many factors, such as chemical and phase compositions, sintering temperature, average grain size, density, and others, affect these properties, making it challenging to estimate corresponding reliability parameters correctly. Experimental examination of the impact of these factors on the mechanical properties of ceramics is a rather time-consuming and resource-consuming procedure. This work aims to predict the mechanical properties of zirconia ceramics using machine learning tools. The authors have created an experimental database for predicting the hardness, flexural strength, and fracture toughness of ZrO2-based ceramics based on chemical composition, phase composition, microstructural features, and sintering temperature on the mechanical properties of zirconia ceramics. The authors compare compared the effectiveness of using different machine learning algorithms and have found a high accuracy of the predicted values of each of the three mechanical properties using boosting ensemble methods. Also they  developed a stacked ensemble of machine learning methods to improve the accuracy of determining the hardness property prediction task. We obtained the increase in accuracy of more than 10% (R2) using our approach.
弯曲强度、硬度和断裂韧性是陶瓷材料的基本力学性能。制造商广泛使用这套性能来确保陶瓷产品的耐用性。然而,许多因素,如化学成分和相组成、烧结温度、平均晶粒度、密度等,都会影响这些性能,因此正确估计相应的可靠性参数具有挑战性。实验研究这些因素对陶瓷力学性能的影响是一个相当耗时和耗费资源的过程。本工作旨在使用机器学习工具预测氧化锆陶瓷的力学性能。作者创建了一个实验数据库,用于根据化学成分、相组成、微观结构特征和烧结温度对氧化锆陶瓷力学性能的影响来预测ZrO2基陶瓷的硬度、弯曲强度和断裂韧性。作者比较了使用不同机器学习算法的有效性,并发现使用boosting集成方法对三种机械特性的预测值都有很高的准确性。他们还开发了一套堆叠的机器学习方法,以提高确定硬度特性预测任务的准确性。使用我们的方法,我们获得了超过10%(R2)的准确性提高。
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引用次数: 0
Effect of (Al, Zn, Cu, and Sr) doping on structural, optical and electrical properties of sprayed SnO2 thin films (Al, Zn, Cu, Sr)掺杂对喷涂SnO2薄膜结构、光学和电学性能的影响
IF 1 Q3 Materials Science Pub Date : 2023-06-20 DOI: 10.36547/ams.29.2.1730
Imene Saoula, Chahinez Siad, Khedidja Djedidi, N. Allag, A. Chala
Tin dioxide thin films deposited onto a glass substrate were prepared by spray pyrolysis technique, and then doped with different elements which are: Al, Zn, Cu, and Sr by electroplating method, these elements were chosen for their different atomic radii. XRD illustrate that all the films were polycrystalline with a tetragonal rutile structure and a strong preferred orientation of (200) plane. Uv-vis spectrophotometer specters showed that the highest average transmittance of Al/SnO2 film was about 86.77% in the visible region and the Sr/SnO2 film had the highest band gap of 3.95 eV. From the MEB images, the morphological characteristics improved when the SnO2 thin films doped with Al and Zn but the opposite happened when it doped with Cu and Sr. The four-point probe showed that the best sample was for Al/SnO2 because it had the highest electrical conductivity around 692.306 (Ω.cm) -1.
采用喷雾热解技术在玻璃基板上制备了二氧化锡薄膜,并根据不同的原子半径选择不同的Al、Zn、Cu和Sr元素进行电镀。XRD分析结果表明,所有薄膜均为多晶,具有四边形金红石结构,具有较强的(200)面择优取向。紫外-可见分光光度计光谱显示,Al/SnO2薄膜在可见光区的平均透过率最高,约为86.77%,Sr/SnO2薄膜的带隙最高,为3.95 eV。从MEB图像来看,掺杂Al和Zn的SnO2薄膜的形貌特征得到改善,而掺杂Cu和sr的SnO2薄膜的形貌特征则相反。四点式探针表明,Al/SnO2薄膜的电导率最高,约为692.306 (Ω.cm) -1。
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引用次数: 0
MODELLING THE PROCESS OF OXIDISING IMPURITIES IN A METAL BATH USING COHERENT NOZZLES 用相干喷嘴模拟金属浴中杂质氧化过程
IF 1 Q3 Materials Science Pub Date : 2023-06-20 DOI: 10.36547/ams.29.2.1733
T. Golub, L. Molchanov, S. Semykin, A. Koveria
The main task of the oxygen-converter process is to produce a liquid metal semi-product with specified properties. It is directly related to the optimization of the blowing mode and devices responsible for the process and technical and economic parameters of melting. The effectiveness of the organization of the process of introducing oxygen into the melt, and, accordingly, assimilation by the metal bath basically depends on the design of the lance nozzles. In electrometallurgy, coherent nozzles are used to improve bath mixing performance and activate processes (a central nozzle for supplying oxygen and a peripheral one surrounding it for supplying gas as a fuel that forms an enveloping flame). Therefore, the authors conducted a study of the influence of coherent top nozzles on the oxidation of impurities in the metal bath under the conditions of the use for the oxygen-converter process (with oxygen supplied to both parts of the nozzle). A high-temperature simulation of the oxidation process of Si from hot metal was carried out by using a Cu-Zn melt (1%) when comparing blowing through a nozzle of a coherent type with a peripheral part of 75% and a conventional nozzle of the equivalent diameter.
氧气转炉工艺的主要任务是生产具有特定性能的液态金属半成品。它直接关系到吹制方式和设备的优化,负责熔炼的工艺和技术经济参数。将氧气引入熔体的过程组织的有效性,以及相应地通过金属浴的同化,基本上取决于喷枪喷嘴的设计。在电冶金中,相干喷嘴用于提高熔池混合性能和激活工艺(一个用于供应氧气的中心喷嘴和一个围绕它的外围喷嘴,用于供应气体作为形成包围火焰的燃料)。因此,作者研究了在氧气转换器工艺的使用条件下(向喷嘴的两个部分供应氧气),相干顶部喷嘴对金属浴中杂质氧化的影响。通过使用Cu-Zn熔体(1%)对Si从热金属的氧化过程进行高温模拟,当比较通过具有75%周边部分的相干型喷嘴和等效直径的传统喷嘴的吹送时。
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引用次数: 0
EFFECT OF ULTRAFAST HEATING ON AISI 304 AUSTENITIC STAINLESS STEEL 超快速加热对aisi304奥氏体不锈钢的影响
IF 1 Q3 Materials Science Pub Date : 2023-06-20 DOI: 10.36547/ams.29.2.1833
B. R. Rodriguez vargas, L. Albini, Giulia Tiracorrendo, Riccardo Massi, G. Stornelli, A. Di schino
This study explores the effects of ultrafast heating on AISI 304 austenitic stainless steel. The research shows that ultrafast heating can lead to fine-grained mixed microstructures in steel, making it a potential alternative for modifying microstructure in stainless steel. The study demonstrates that a minimum temperature of 980 °C is required to achieve a fully recrystallized microstructure. The results also suggest that a lower temperature can result in a finer recrystallized grain size compared to higher temperature results. The study provides valuable insights into the impact of ultrafast heating on the microstructural constituents, recrystallization temperatures, and mechanical properties of investigated steel.
本研究探讨了超快速加热对AISI 304奥氏体不锈钢的影响。研究表明,超快加热可以在钢中产生细粒度的混合微观组织,使其成为改变不锈钢微观组织的潜在替代品。研究表明,实现完全再结晶的微观结构需要980°C的最低温度。结果还表明,与较高的温度结果相比,较低的温度可以导致更细的再结晶晶粒尺寸。该研究为超快加热对所研究钢的微观结构成分、再结晶温度和机械性能的影响提供了有价值的见解。
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引用次数: 2
Obituary of Ing. Juraj Lapin, DrSc. Juraj Lapin博士的讣告。
IF 1 Q3 Materials Science Pub Date : 2023-06-20 DOI: 10.36547/ams.29.2.1849
M. Nosko
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引用次数: 0
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Acta Metallurgica Slovaca
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