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Fifteenth International Conference on Thermoelectrics. Proceedings ICT '96最新文献

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Precipitation study of lead and chalcogens in single crystals of PbSe-PbTe solid solution PbSe-PbTe固溶体单晶中铅、硫的析出研究
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553278
V. Kuznetsov
Lead chalcogenides and their solid solutions exhibit a retrograde solubility of lead and chalcogens that can result in the precipitation of excess components and degradation of electrical properties when this materials are used at temperatures lower then their fabrication temperature. The kinetic of precipitation of lead and chalcogens from supersaturated single crystals PbSe, PbTe, and their solid solution has been studied in this work. Single crystals were grown from vapour phase by a sublimation procedure in a vertical quartz ampoules. Sample treatment times ranged from 2 min to several hundred hours at three temperatures for both lead- and chalcogen-saturated crystals. Based on the analysis of the kinetic data the activation energy of precipitation was estimated and compared with the activation energy of diffusion of lead and chalcogens.
铅硫族化合物及其固溶体表现出铅和硫原的逆行溶解度,当这种材料在低于其制造温度的温度下使用时,可能导致过量成分的沉淀和电性能的退化。本文研究了过饱和PbSe、PbTe单晶及其固溶体中铅、硫的析出动力学。在垂直石英安瓿中,通过升华程序从气相生长单晶。样品处理时间范围从2分钟到几百小时,在三个温度下的铅和硫饱和晶体。在动力学数据分析的基础上,估算了沉淀活化能,并与铅、硫扩散活化能进行了比较。
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引用次数: 0
Deposition of (Bi,Sb)2Te3 films by magnetron co-sputtering from two targets-first results 磁控共溅射制备(Bi,Sb)2Te3薄膜
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553519
M. Stolzer, V. Bechstein, J. Meusel
Sputtered (Bi,Sb)/sub 2/Te/sub 3/ films show an excellent adhesivity on Kapton substrates and are suitable for patterning by wet etching. The known problem of strong deviation from stoichiometry in these films results from both the different sticking coefficients and the resputtering of the elements during the film growth. An oversupply of tellurium atoms is a possible and usually applied solution. A coating system was used which enables the control of direction and intensity of the particle flux from two magnetron sources separately. The targets consist of (i) stoichiometric (Bi/sub 0.25/Sb/sub 0.75/)/sub 2/Te/sub 3/ and (ii) pure tellurium. The experimental arrangement allows one to control the Te:(Bi,Sb) flux ratio R/sub F/ in a wide range. WDX analysis of the composition shows, that the films are nearly stoichiometric in the range 1.7/spl les/R/sub f//spl les/4 at substrate temperature T/sub S/=300/spl deg/C. A small deviation from stoichiometry was observed depending on the variation of T/sub S/.
溅射(Bi,Sb)/sub 2/Te/sub 3/薄膜在Kapton衬底上具有良好的粘附性,适合湿法蚀刻。已知的这些薄膜的化学计量偏差很大的问题是由于不同的粘附系数和在薄膜生长过程中元素的重溅射。碲原子供过于求是一种可能的、通常适用的解决办法。采用了一种涂层系统,可以分别控制来自两个磁控管源的粒子通量方向和强度。目标物包括(i)化学计量(Bi/sub 0.25/Sb/sub 0.75/)/sub 2/Te/sub 3/和(ii)纯碲。实验安排允许人们在很宽的范围内控制Te:(Bi,Sb)通量比R/sub F/。WDX分析表明,在衬底温度T/sub S/=300/spl℃时,薄膜在1.7/spl les/R/sub f//spl les/4范围内具有较好的化学计量性。根据T/sub S/的变化,观察到与化学计量的小偏差。
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引用次数: 7
A stove-top generator for cold areas 用于寒冷地区的炉顶发电机
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553511
A. Killander, J. Bass
This paper discusses the development and test of a prototype thermoelectric generator which is designed to use the heat of existing wood fired stoves that are typically used in the area for home heating. This generator is being developed by the Royal Institute of Technology, in Sweden, to provide small amounts of power to homes in the remote northern areas of the country which are beyond the electric grid. The paper discusses some of the aspects of the generator design, as well as the early results obtained and some of the lessons learned from the first home test site in Skerfa, Sweden, which is located near the Arctic Circle. The bismuth-telluride thermoelectric modules used in the generator are also discussed.
本文讨论了热电发电机原型的开发和测试,该原型设计用于利用该地区通常用于家庭供暖的现有柴火炉的热量。瑞典皇家理工学院正在开发这种发电机,为该国北部偏远地区的家庭提供少量电力,这些地区没有电网。本文讨论了发电机设计的一些方面,以及在瑞典Skerfa的第一个家庭试验场获得的早期结果和一些经验教训,该试验场位于北极圈附近。本文还讨论了用于发电机的碲化铋热电模块。
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引用次数: 78
Thermoelectric properties of Co(MxSb/sub 1-x/)3 (M=Ge, Sn, Pb) compounds Co(MxSb/sub - 1-x/)3 (M=Ge, Sn, Pb)化合物的热电性质
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553266
T. Koyanagi, T. Tsubouchi, M. Ohtani, K. Kishimoto, H. Anno, K. Matsubara
The thermoelectric properties of CoSb/sub 3/, which was doped with IV elements of Sn, Ge and Pb, were investigated in order to improve the p-type thermoelectric performance of non-doped CoSb/sub 3/. Co(M/sub x/Sb/sub 1-x/)/sub 3/ (M=Ge, Sn, Pb) compounds were prepared by hot-pressing. The solubility limit of these dopants was determined from measurements of the X-ray photoelectron spectroscopy (XPS). The solubility limit of Ge and Sn are estimated to be about 1.4 and 2.4%, respectively, while Pb hardly substitutes for Sb. The Hall measurements reveal that the maximum carrier concentrations at room temperature were 1.5/spl times/10/sup 19/ cm/sup -3/ for Ge and 2.9/spl times/10/sup 19/ cm/sup -3/ for Sn. The change in the mobility with x can be explained qualitatively by taking account of conduction of both holes and electrons in doped CoSb/sub 3/. The electrical conductivity /spl sigma/ and Seebeck coefficient S of these samples were measured in the temperature range from 300 to 800 K. The p-type conduction is achieved in the whole temperature range by introducing Ge and Sn in CoSb/sub 3/. The values of the power factor S/sup 2//spl sigma/ for Co(Sn/sub x/Sb/sub 1-x/)/sub 3/ with x=1% are of the order of 10/sup -5/W/cmK/sup 2/ and 2/spl sim/10 times as high as those of the non-doped CoSb/sub 3/ in the wide temperature range.
为了改善未掺杂CoSb/sub 3/的p型热电性能,研究了Sn、Ge和Pb等IV元素掺杂CoSb/sub 3/的热电性能。采用热压法制备Co(M/sub x/Sb/sub 1-x/)/sub 3/ (M=Ge, Sn, Pb)化合物。通过x射线光电子能谱(XPS)测定了这些掺杂剂的溶解度极限。Ge和Sn的溶解度极限分别约为1.4和2.4%,而Pb几乎不能替代Sb。霍尔测量结果表明,室温下的最大载流子浓度为Ge的1.5/spl倍/10/sup 19/ cm/sup -3/, Sn的2.9/spl倍/10/sup 19/ cm/sup -3/。迁移率随x的变化可以通过考虑掺杂CoSb/ sub3 /中空穴和电子的传导来定性地解释。在300 ~ 800 K的温度范围内测量了样品的电导率/spl σ /和塞贝克系数S。通过在CoSb/sub /中引入Ge和Sn,在整个温度范围内实现了p型导通。当x=1%时,Co(Sn/sub x/Sb/sub 1-x/)/sub 3/的功率因数S/sup 2//spl sigma/在宽温度范围内是未掺杂CoSb/sub 3/功率因数S/sup -5/W/cmK/sup 2/和2/spl sim/的10倍。
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引用次数: 4
Remarks on a possible physical sense of the value ZT = 1 for semiconductor thermoelectrics 关于半导体热电器件ZT = 1值可能的物理意义的评述
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553291
M. Vedernikov, Y. Ravich
The problem of the existence of an upper limit of thermoelectric figure of merit Z is of principal importance for thermoelectric energy conversion. It was discussed actively during the period of development of basic aspects of semiconductor thermoelectricity but was not solved. After a long time of silence it attracts attention again. C.B.Vining at ICT'92 considered the well known fact that the dimensionless parameter ZT/spl les/1 for all real thermoelectrics. He concluded that one doesn't know any physical reasons to consider this value as a specific one. Our paper indicates those rather general assumptions at which ZT/spl ap/1 for semiconductors at a qualitative evaluation. It is shown too that the dependence of ZT increase on decrease of lattice thermal conductivity is weaker for semiconductors with ZT>1 than for one with ZT<1.
在热电能量转换中,热电系数Z的上限是否存在是一个重要的问题。在半导体热电学基础方面的发展过程中,人们对这一问题进行了积极的讨论,但一直没有得到解决。在长时间的沉默之后,它再次引起了人们的注意。C.B.Vining在ICT'92考虑了众所周知的事实,即所有实际热电器件的无量纲参数ZT/spl小于/1。他的结论是,人们不知道任何物理上的理由来认为这个值是一个特定的值。我们的论文指出了那些相当一般的假设,在这些假设下,半导体的ZT/spl在定性评价时为/1。结果还表明,对于ZT>1的半导体,ZT的增加对晶格热导率降低的依赖性弱于ZT<1的半导体。
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引用次数: 0
Thermoelectric properties of rf-sputtered CoSb3 films rf溅射CoSb3薄膜的热电性能
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553522
H. Anno, K. Matsubara, Y. Notohara, T. Sakakibara, K. Kishimoto, T. Koyanagi
Film growth and electronic transport properties of CoSb/sub 3/ with the cubic skutterudite structure were studied. The skutterudite CoSb/sub 3/ films were successfully grown on Si(100) and quartz substrates by using a magnetron rf-sputtering. A preferential orientation growth along [310] plane occurs when the pressure of sputtering gas decreases. Polycrystalline films with the skutterudite structure are also obtained by annealing sputtered films at low temperature. Electrical conductivity of the films changes with the film growth conditions. Electronic structure of the films was investigated by X-ray photoelectron spectroscopy. Observed valence band structure agrees well with a recent band calculation. It is revealed that the valence band structure of CoSb, consists of the hybridized bands between Co d and Sb p states and a peak structure derived from localized Co d state.
研究了具有立方方角榴石结构的CoSb/ sub3 /的薄膜生长和电子输运性质。利用磁控射频溅射技术,在Si(100)和石英衬底上成功地生长出了skutudite CoSb/ sub3 /薄膜。当溅射气体压力降低时,沿[310]平面发生择优取向生长。通过对溅射膜进行低温退火,还可以得到具有角钴矿结构的多晶薄膜。薄膜的电导率随薄膜生长条件的变化而变化。用x射线光电子能谱研究了薄膜的电子结构。观察到的价带结构与最近的能带计算结果吻合得很好。结果表明,CoSb的价带结构由Co d和Sb p态的杂化带和Co d局域态衍生出的峰结构组成。
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引用次数: 6
Thermoelectric power generation systems recovering heat from combustible solid waste in Japan 日本的热电发电系统从可燃固体废物中回收热量
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553504
T. Kajikawa
The status and future prospects on the development of thermoelectric power generation systems utilizing heat from the municipal solid waste in Japan are reviewed in this paper. Two ongoing research and development programs related to this application in Japan are briefly introduced. The characteristics of heat from the solid waste processing system lead to the peculiar concept of thermoelectric power generation system. The theoretical and experimental studies including small scale onsite experiment are shown to discuss several technological problems and the guideline for the development of such systems.
本文综述了日本城市生活垃圾热能发电系统的发展现状和前景。简要介绍了日本正在进行的与该应用相关的两个研究和开发项目。固体废物处理系统的热特性导致了热电发电系统的特殊概念。通过理论和实验研究,包括小规模的现场实验,讨论了该系统的几个技术问题和发展的指导方针。
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引用次数: 19
Investigations of the properties of a thermoelectric IR-detector for low working temperature 低工作温度热电红外探测器的性能研究
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553502
R. Fettig, T. Henkel, E. Mueller
Thermoelectric IR-detectors have been developed and built to work at a temperature of 170 K in the CIRS experiment as part of the CASSINI mission to Saturn. Thermoelectric legs of p and n-type are soldered to a metallized ceramic substrate, isolated one from another. Pyramidal legs are formed by electric discharge machining (EDM). A thin gold foil is welded to the pyramides and blackened for high absorption of radiation. Characterization measurements were carried out to correlate detector properties to the preparation process. Thermoelectric behavior is described by measuring the current-voltage characteristics from liquid nitrogen up to room temperature. Materials of the composition (Bi/sub 0.4/Sb/sub 0.6/)/sub 2/Te/sub 3/ (for p type) and Bi/sub 2/(Te/sub 0.95/Se/sub 0.95/)/sub 3/ (for n-type) have been used for detector preparation. The material was doped to have maximum figure of merit at temperatures below room temperature. It has been found that the EDM process changes the properties of the thermoelectric material and that electro etching can remove degraded layers. Electro etched detectors exhibit properties which are closer to the values expected from the original material.
作为卡西尼号土星任务的一部分,在CIRS实验中,热电红外探测器已经被开发和建造,可以在170 K的温度下工作。p型和n型热电腿焊接在金属化陶瓷衬底上,彼此隔离。锥体腿是用电火花加工成形的。金字塔上焊接了一层薄薄的金箔,并将其涂黑,以提高辐射的吸收。进行了表征测量,以将探测器的性质与制备过程相关联。热电行为是通过测量从液氮到室温的电流电压特性来描述的。用Bi/sub 0.4/Sb/sub 0.6/)/sub 2/Te/sub 3/ (p型)和Bi/sub 2/(Te/sub 0.95/Se/sub 0.95/)/sub 3/ (n型)组成的材料制备探测器。在低于室温的温度下,该材料被掺杂到具有最大的性能值。研究发现,电火花加工改变了热电材料的性能,电蚀刻可以去除退化层。电蚀刻探测器的性能更接近于原始材料的预期值。
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引用次数: 0
Thermoelectric power in disordered mixed crystals 无序混合晶体中的热电功率
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553299
P. Lin-Chung, A. Rajagopal
In disordered mixed crystals the effect of alloy scattering is known to be of significant importance in comparison with that of lattice scattering in the consideration of electrical and thermal transport properties. In this work we consider the thermoelectric power in such isotropically disordered mixed crystals. We derive the energy current density operator for a combined electron and vibrating ions of the lattice system with the electron-lattice interaction term included. In this preliminary report, the relative importance of electrons and lattice vibrations to the thermoelectric power is discussed. The coherent potential approximation may be used to obtain the thermoelectric power of the disordered mixed crystal as function of the concentration. Our operator formulation is in coordinate space which besides containing previous formulations for metals and alloys as special cases, admits of the coherent-potential approximation methods to be applied as well.
在无序混合晶体中,合金散射的影响在考虑电和热输运性质方面比晶格散射的影响更为重要。在这项工作中,我们考虑了这种各向同性无序混合晶体的热电功率。我们导出了包含电子-晶格相互作用项的晶格系统中电子和振动离子组合的能量电流密度算符。在这个初步报告中,讨论了电子和晶格振动对热电功率的相对重要性。用相干势近似可以得到无序混合晶体的热电功率随浓度的变化。我们的算符公式是在坐标空间中,除了包含先前的金属和合金的公式作为特殊情况外,还允许应用相干势近似方法。
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引用次数: 0
Bi-Sb alloys: an update 铋锑合金:最新进展
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553246
B. Lenoir, A. Dauscher, X. Devaux, R. Martin-Lopez, Y. Ravich, H. Scherrer, S. Scherrer
This paper is devoted to a survey of the principal studies performed on Bi-Sb thermoelectric materials over the last forty years. Bi-Sb alloys are still the best n-type materials for refrigeration at low temperatures nowadays. After a brief introduction of their physical characteristics (crystallography and band structure), the elaboration, characterization and transport properties (thermoelectric and galvanomagnetic) of the Bi-Sb alloys will be presented. The results obtained on bulk materials, in single crystalline and polycrystalline forms, and thin films will be discussed.
本文对近四十年来铋锑热电材料的主要研究进行了综述。目前,铋锑合金仍是低温制冷的最佳n型材料。在简要介绍了铋锑合金的物理特性(晶体学和能带结构)之后,介绍了铋锑合金的细化、表征和输运特性(热电和磁)。在块状材料,单晶和多晶形式,以及薄膜上得到的结果将被讨论。
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引用次数: 26
期刊
Fifteenth International Conference on Thermoelectrics. Proceedings ICT '96
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