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Fifteenth International Conference on Thermoelectrics. Proceedings ICT '96最新文献

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Electrical properties of porous oxides of alkaline-earth metals with high thermoelectric efficiency 高热电效率碱土金属多孔氧化物的电学性质
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553285
É. Sher
Electrical properties of porous oxide layers investigated with the help of specially developed methods. The electrical conductivity measurements made in the wide range of electrical fields by developed pulse method. The method of thin metallic probes and measurements of their spreading resistance in o.l. used to receive the parameters of electron gas in pores. The value of electrical conductivity of contacts between small oxide grains separated from the value of electrical conductivity through electron gas in pores at high temperatures by measurements of spreading resistance and thermoemf, and their changes in magnetic field. The results of these experiments are giving and discussed below.
用专门开发的方法研究了多孔氧化层的电学性能。采用先进的脉冲法在大范围的电场中测量电导率。本文采用薄金属探针及其在电解液中扩展电阻的测量方法来接收孔隙中电子气体的参数。通过测量扩散电阻和热电动势及其在磁场中的变化,得到了高温下小氧化颗粒之间接触的电导率值与孔隙中通过电子气体分离的电导率值。下面给出了这些实验的结果并进行了讨论。
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引用次数: 1
Thermoelectric characteristics of homologous compounds with layer structures in the ZnO-In2O3 system ZnO-In2O3体系中层状结构同源化合物的热电特性
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553286
K. Koumoto, H. Ohta, W. Seo
Thermoelectric materials with high Z's have been searched for recently among semiconducting oxide ceramics for the purpose of power generation at high temperatures in an air atmosphere. Metallic oxides consisting of non-transition metal elements which mould possibly have large band widths and high carrier mobility have been the target materials. One possible oxide group is that having In/sub 2/O/sub 3/ as a main component. In the present study, homologous compounds of (ZnO)mIn/sub 2/O/sub 3/ (m=integer) with layer structures were synthesized by reaction-sintering the powder mixtures of ZnO and In/sub 2/O/sub 3/ at 1823 K for 2 h in air. Their thermoelectric characteristics, i.e. electrical conductivity, Seebeck coefficient, and thermal conductivity were measured at 500-1000 K. Their Z depended on the composition and the microstructure.
近年来,人们在半导体氧化物陶瓷中寻找具有高Z值的热电材料,用于在空气环境中高温发电。由非过渡金属元素组成的金属氧化物可能具有较大的频带宽度和较高的载流子迁移率,已成为目标材料。一种可能的氧化基团是以In/sub - 2/O/sub - 3/为主要成分。本研究将ZnO与In/sub 2/O/sub 3/粉末混合物在空气中1823 K反应烧结2 h,合成了具有层状结构的(ZnO)mIn/sub 2/O/sub 3/ (m=整数)同源化合物。在500-1000 K下测量了它们的热电特性,即电导率、塞贝克系数和导热系数。它们的Z值取决于成分和微观结构。
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引用次数: 1
Thermoelectric properties and structures of the sintered compact of Cu:Sn:S = 8:1:4 composition Cu:Sn:S = 8:1:4成分烧结致密体的热电性能与结构
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553282
M. Hasaka, T. Morimura, T. Aki, S. Kondo
The compact of Cu:Sn:S=8:1:4 composition was prepared by sintering. The thermoelectric properties of the compact were measured as a function of temperature and annealing period. The microstructures were investigated by X-ray diffraction experiments and transmission electron microscopic observation. The compact is desirable in thermoelectric properties and thermal stability below 450 K. The compact consists of mixtures of several compound structures.
采用烧结法制备了Cu:Sn:S=8:1:4的致密体。测量了热电性能随温度和退火时间的变化。通过x射线衍射实验和透射电镜观察对其微观结构进行了研究。该紧凑型具有理想的热电性能和450 K以下的热稳定性。该致密体由几种复合结构的混合物组成。
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引用次数: 0
Thermoelectric generators in photovoltaic hybrid systems 光伏混合系统中的热电发电机
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553505
R. Kugele, W. Roth, W. Schulz, A. Steinhuser
The supply of distant electric devices that cannot be connected to the public electricity grid for reasons of cost, waiting time or due to the need of local flexibility has been a major problem. To date, the power supply of such stand-alone systems has been based mainly on battery-buffered fossil-fueled motor-generators. Apart from the consumption of limited fossil fuel reserves, the disadvantages of these systems include the creation of noise and exhaust gases, the constant need to obtain fuel and, most important, the high amount of maintenance and repairs. For these reasons, and due to the progress in regenerative energy conversion made in the last decade, battery-buffered PV power systems are used more and more often. Their advantages are high reliability and low cost of repairs. However, far away from the equator, where solar radiation is very low during the winter, large PV generators are needed to guarantee sufficient reliability. Therefore, system costs are high. Another disadvantage is that the battery lifetime in PV power systems is significantly reduced compared to its lifetime in fossil fueled systems. To avoid these disadvantages, the PV generator can be combined with fossil fueled power generators. In the medium power range, from 10 W up to several hundred W, thermoelectric generators appear to be particularly qualified because of their reliability and lifetime. In this paper, a (so called) "photovoltaic hybrid system" is compared to a purely PV power system on the basis of model calculations starting with the solar radiation situation on the Earth's surface.
由于费用、等待时间或由于需要当地的灵活性,无法连接到公共电网的远距离电力设备的供应一直是一个主要问题。迄今为止,这种独立系统的电力供应主要基于电池缓冲的化石燃料发电机。除了消耗有限的化石燃料储备外,这些系统的缺点包括产生噪音和废气,不断需要获得燃料,最重要的是,大量的维护和维修。由于这些原因,以及由于近十年来在可再生能源转换方面取得的进展,电池缓冲光伏发电系统的使用越来越频繁。它们的优点是高可靠性和低维修成本。然而,远离赤道,冬季太阳辐射非常低,需要大型光伏发电机来保证足够的可靠性。因此,系统成本很高。另一个缺点是,与化石燃料系统相比,光伏发电系统的电池寿命大大缩短。为了避免这些缺点,光伏发电机可以与化石燃料发电机结合使用。在中等功率范围内,从10w到几百W,热电发电机似乎特别合格,因为它们的可靠性和寿命。在本文中,一个(所谓的)从地球表面的太阳辐射情况出发,在模型计算的基础上,将“光伏混合系统”与单纯的光伏发电系统进行对比。
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引用次数: 15
Optimum design in thermoelectric cooling systems 热电冷却系统的优化设计
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553303
M. Yamanashi, Y. Kibayashi, F. Toyada, M. Azechi
An optimum design is investigated to maximize the coefficient of performance (COP) for a thermoelectric cooling system (TEC system) which consists of a thermoelectric cooler (TEC) and heat-exchangers at the cold side and the hot side. Optimizing a TEC in the TEC system for the maximum COP can be performed by using the balance equations of nondimensional entropy flow, when the thermal resistances of heat-exchangers for a TEC system are given and the system operates under a constant temperature difference. In these equations, the COP of the TEC system becomes a function of nondimensional thermal resistance of the cold side heat-exchanger and nondimensional entropy flow at the cold side of the TEC system. Therefore the COP of the TEC system is shown as a contour graph on these two variables. By using this graph, not only TEC design parameters for the maximum COP of the TEC system can be determined, but the degrading effect by thermal resistances of the TEC system on the COP can also be evaluated.
研究了由热电冷却器(TEC)和冷热侧换热器组成的热电冷却系统(TEC)的性能系数最大化的优化设计。当换热器的热阻已知,且系统在恒温条件下运行时,利用无量纲熵流平衡方程,可以对系统中的换热器进行优化,以获得最大COP。在这些方程中,TEC系统的COP变成了冷侧换热器的无因次热阻和TEC系统冷侧无因次熵流的函数。因此,TEC系统的COP表示为这两个变量的等值线图。利用该图不仅可以确定TEC系统最大COP的TEC设计参数,还可以评估TEC系统的热阻对COP的降解作用。
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引用次数: 9
Validation of thermoelectrics measurements. II 热电测量的验证。2
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553518
J. Sharp, E. H. Volckmann, H. Lyon, D. J. Gillespie, G. Kamm, A. Ehrlich
This paper reports the joint effort of Marlow Industries (MI) and members of the Naval Research Laboratory (NRL) to test the usefulness of a carefully constructed conventional apparatus for measurement of the thermal conductivity of thermoelectrics. The design of the NRL apparatus takes into account the listed error sources, but is especially tailored to eliminate radiative exchange. This choice is driven by the fact that the instrument is most often used to measure the thermal conductivity of metals at high temperatures. We have found that as a consequence of using insulation to prevent radiation, the apparatus is not well suited for measurement of low thermal conductivity samples, such as standard thermoelectrics. The samples used as standard materials were taken from ingots grown at MI by a commercial method. The p-type ingot was grown from a melt of Sb/sub 150/Bi/sub 50/Te/sub 291/Se/sub 9/ plus a few percent of excess Te. The n-type ingot was grown from a doped melt of Bi/sub 20/Te/sub 27/Se/sub 3/. With slight variations, these are the compositions used throughout the thermoelectrics industry.
本文报道了马洛工业公司(MI)和海军研究实验室(NRL)成员的共同努力,以测试一种精心构造的用于测量热电材料导热性的传统仪器的有效性。NRL装置的设计考虑了列出的误差源,但特别针对消除辐射交换进行了定制。这种选择是由于该仪器最常用于测量高温下金属的导热性。我们发现,由于使用绝缘来防止辐射,该仪器不太适合测量低导热样品,如标准热电样品。作为标准材料的样品是通过商业方法从MI生长的铸锭中提取的。p型铸锭是由Sb/sub - 150/Bi/sub - 50/Te/sub - 291/Se/sub - 9/外加几个百分点的过量Te熔体生长而成的。n型铸锭是在Bi/sub 20/Te/sub 27/Se/sub 3/掺杂熔体中生长的。略有不同,这些是整个热电工业中使用的成分。
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引用次数: 0
Miniature thermoelectric generators (TEG) with catalytic heating 微型热电发电机(TEG)与催化加热
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553510
L. Anatychuk, V. Mikhailovskii, V. Konopelnyuk
Modern fuel thermoelectric generators (TEG) are widely used in the range of 10-500 W. Chemical sources of current (CSC) that do not always satisfy consumers are used at lower powers. Negative factors are large weight, cost, self-discharge amount, problems in storage and maintenance at low temperatures. CSC manufacture is power-intensive, expensive and ecologically dangerous. That is why fuel TEGs capable of competing with CSCs are of interest. The paper is devoted to fuel TEGs on liquefied gas development for 10-100 mW power ranges. Small power heat sources have been developed on the catalytic counter-flow burner base which stably operates on gas and is suitable for continuous operation on a self-sufficiency basis. The catalytic burner feature at separated fuel and air supply is spontaneous burning resumption after short breaks in fuel supply, changes in air supply and combustion products discharge. The burner's temperature can be maintained within 250-400/spl deg/C. A high efficiency promoted catalyst with service life up to 10000 hours is used in heat sources. The use of results of a series research works in this direction ensured the development of such catalytic heat sources (CHS). TEGs design was made by the computer modelling. TEGs maximum is defined by the following optimizing parameters: a collector aerodynamic drag, burner-collector distance, fuel consumption, load impedance and thermoelectric battery properties.
现代燃料热电发电机(TEG)广泛应用于10- 500w范围内。在较低功率下使用的化学电流源(CSC)并不总是让消费者满意。负面因素是重量大、成本高、自放电量大、储存和低温维护问题。CSC的制造是能源密集、昂贵且生态危险的。这就是为什么能够与csc竞争的燃料teg备受关注的原因。本文致力于10-100兆瓦功率范围内液化气开发的燃料TEGs。在催化逆流式燃烧器基座上研制了小功率热源,该热源在燃气上稳定运行,适合于自给自足的连续运行。燃料和空气分离供给时催化燃烧器的特点是燃料供给短暂中断、供气变化和燃烧产物排放后恢复自燃。燃烧器温度可保持在250-400/spl℃。热源采用高效促进催化剂,使用寿命可达10000小时。这一方向的一系列研究成果的应用保证了这种催化热源(CHS)的发展。通过计算机建模进行了TEGs的设计。TEGs的最大值由以下优化参数定义:集热器气动阻力、燃烧器-集热器距离、燃油消耗、负载阻抗和热电电池性能。
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引用次数: 0
Interacted electron and phonon thermal waves in semiconductors: application to photothermal effects 半导体中相互作用的电子和声子热波:在光热效应中的应用
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553302
G. González de la Cruz, Y. Gurevich
In this work heat transport in condensed media is examined from the theoretical point of view. We consider the heat flux at the surface of the sample as boundary condition and a fixed temperature on the other surface of the sample those boundary conditions reflect the usual experimental conditions in photoacoustic experiments. From this, we obtain explicitly the electron and phonon temperature distributions in the sample as function of both, time and position, valid for all range of the laser chopper frequency. The characterization of the thermal waves properties is discussed and some practical procedures for this purpose provide us with information about the electron and phonon thermal parameters.
本文从理论的角度研究了凝聚态介质中的热传递。我们考虑样品表面的热流密度作为边界条件,样品另一表面的温度固定,这些边界条件反映了光声实验中通常的实验条件。由此,我们明确地得到了样品中电子和声子温度随时间和位置的函数分布,该分布在激光斩波频率的所有范围内都有效。讨论了热波性质的表征,并为此目的提供了一些实用的程序,为我们提供了有关电子和声子热参数的信息。
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引用次数: 0
Application of bismuth-telluride thermoelectrics in driving DNA amplification and sequencing reactions 碲化铋热电材料在驱动DNA扩增和测序反应中的应用
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553312
J. Hansen, M. Nussbaum
Recently, a new application for low-temperature thermoelectric modules has emerged in the fields of biology and medicine. Laboratory instruments that thermally cycle small biological samples for purposes of DNA amplification are now common in research laboratories throughout the world, and instruments based upon several different technologies have been developed. Market forces are increasing showing that thermoelectrics are very well suited to this task, but several hurdles must first be overcome in order to build a quality instrument. Chief among these is the need to build modules optimized for thermal cycling. Data are presented here to document a particularly rugged design of module that works well in this demanding application.
近年来,低温热电模块在生物和医学领域出现了新的应用。用于DNA扩增目的的小生物样品热循环的实验室仪器现在在世界各地的研究实验室中很常见,并且基于几种不同技术的仪器已经开发出来。越来越多的市场力量表明,热电非常适合这项任务,但为了制造出高质量的仪器,必须首先克服几个障碍。其中最主要的是需要构建针对热循环进行优化的模块。这里提供的数据记录了一个特别坚固的模块设计,在这个苛刻的应用程序中工作得很好。
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引用次数: 24
Crystal growth of narrow gap semiconductors for thermoelectric applications 热电应用窄间隙半导体的晶体生长
Pub Date : 1996-03-26 DOI: 10.1109/ICT.1996.553281
C. Kloc, K. Fess, W. Kaefer, K. Friemelt, H. Riazi-Nejad, M. Wendl, E. Bucher
Recently, there has been a growing interest in small integrated cooling units. This prompted us to establish a screening program for the search of new efficient thermoelectric materials requiring the optimization of figure of merit. Preparation and crystal growth experiments on possible thermoelectric compounds: TiNiSn, ZrNiSn, CoSb/sub 3/, SrAs/sub 3/, /spl beta/-FeSi/sub 2/, FeSi, NiS, La/sub 3/Cu/sub 3/Sb/sub 4/, Ce/sub 3/Cu/sub 3/Sb/sub 4/, Gd/sub 3/Cu/sub 3/Sb/sub 4/ are presented. Single crystals of congruently melting compounds were obtained by the Czochralski or Bridgman techniques. The peritectic decomposing compounds were prepared by flux-growth. Low defect crystals were obtained by vapor transport. Whenever it was possible, more than one technique was studied for the preparation of the same compound. Transport properties and thermoelectric properties were measured and discussed.
最近,人们对小型集成冷却装置的兴趣越来越大。这促使我们建立了一个筛选程序,以寻找新的高效热电材料,需要优化的品质系数。介绍了可能的热电化合物TiNiSn、ZrNiSn、CoSb/sub 3/、SrAs/sub 3/、/spl beta/-FeSi/sub 2/、FeSi、NiS、La/sub 3/Cu/sub 3/Sb/sub 4/、Ce/sub 3/Cu/sub 3/Sb/sub 4/、Gd/sub 3/Cu/sub 3/Sb/sub 4/的制备及晶体生长实验。用Czochralski或Bridgman方法获得了完全熔融化合物的单晶。采用通量生长法制备了包晶分解化合物。通过气相输运得到低缺陷晶体。只要有可能,就研究多种技术来制备同一化合物。对其输运性质和热电性质进行了测量和讨论。
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引用次数: 13
期刊
Fifteenth International Conference on Thermoelectrics. Proceedings ICT '96
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