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Solvent Extraction of Zinc from a Bioleaching Solution by Modification of D2EHPA: Optimization and Thermodynamic Studies 改性D2EHPA萃取生物浸出液中的锌:优化及热力学研究
IF 0.8 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.22044/JME.2021.10324.1979
P. Tahmasebizadeh, S. Javanshir
In this work, zinc extraction from an industrial leach solution was investigated by saponified di(2-ethylhexyl)phosphoric acid (D2EHPA). The solution obtained was from a bioleaching process of a low-grade lead-zinc sulfide ore that contained 50 g/L of zinc and 6.3 g/L of iron. The selective and high Zn(II) extraction yield were obtained by modification of D2EHPA in a proposed two-step process. Firstly, a significant amount of iron (87%) was removed as sodium-jarosite via precipitation from the pregnant leaching solution (PLS) prior to zinc extraction, and secondly, the effective parameters involved in zinc extraction including the contact time, saponification degree, type of saponifier, stirring speed, pH, temperature, D2EHPA concentration, and phase ratio (A:O) were investigated. The results obtained showed that 98.4% of zinc could be extracted under the optimum conditions, i.e. 20% D2EHPA, 15% saponification degree, 650 rpm, pH 2, and an A:O ratio of 1:1 at the ambient temperature (25 ± 2 °C) during 90 s; it was 25% higher than using non-saponified D2EHPA under the same conditions. Moreover, while one theoretical step was required for the complete extraction of zinc by saponified D2EHPA, the required number of steps using D2EHPA was about three. Therefore, the advantages of the process would be two-fold: reducing the number of extraction stages and no need for neutralizing the raffinate in every extraction stage.
采用皂化二(2-乙基己基)磷酸(D2EHPA)从工业浸出液中提取锌。该溶液为含锌50 g/L、铁6.3 g/L的低品位铅锌硫化矿生物浸出液。采用二步法对D2EHPA进行改性,获得了选择性高的Zn(II)萃取率。首先,在浸锌前,通过沉淀将浸出液中的大量铁(87%)以黄钾铁矾的形式去除;其次,研究了浸锌过程中接触时间、皂化程度、皂化剂类型、搅拌速度、pH、温度、D2EHPA浓度和物相比(a:O)等参数对浸锌效果的影响。结果表明,在D2EHPA含量为20%、皂化度为15%、转速为650、pH为2、A:O比为1:1的条件下,在25±2℃环境温度下,提取时间为90 s,锌提取率可达98.4%;在相同条件下,比未皂化的D2EHPA高25%。此外,在理论上,用皂化D2EHPA完全提取锌需要一个步骤,而使用D2EHPA所需的步骤约为三个。因此,该工艺的优点是双重的:减少萃取阶段的数量,不需要在每个萃取阶段中和萃余液。
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引用次数: 5
Studying Effect of Modifying Nano-Mineral Adsorbents on Efficiency of Dye Removal from Industrial Effluents 改性纳米矿物吸附剂对工业废水脱色效果的影响研究
IF 0.8 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.22044/JME.2020.10122.1950
Azadeh Agah, Nasrin Falahati
In this research work, the potential capability of nano-clay and tonsil, as low-cost and domestic adsorbents, for the elimination of a cationic dye, (CR18) from contaminated water is investigated. The surface properties of the adsorbents are studied by means of the scanning electron microscopy (SEM) and X-ray diffraction techniques. The effects of the initial dye concentration, pH, stirring speed, contact time, and adsorbent dosage are investigated at 25 . The results obtained show that the dye adsorption data from the nano-clay and tonsil experiments fit well to the Langmuir and Freundlich isotherms, respectively. The results of dye adsorption kinetics demonstrate that the adsorption system follows a pseudo-second-order model with a satisfactory correlation value (R=99%).The adsorption thermodynamics is also studied, concluding that the adsorption process is spontaneous and physically controlled. Under the optimum conditions (pH of 7, stirring speed of 200 rpm, CR18 concentration of 30 ppm and contact time of 30 min), the adsorption capacities of the mixed adsorbents show the maximum adsorption efficiency at the tonsil:nano-clay weight ratio of 1:2.
在本研究中,研究了纳米粘土和扁桃体作为低成本和家用吸附剂去除污染水中阳离子染料(CR18)的潜力。利用扫描电子显微镜(SEM)和x射线衍射技术研究了吸附剂的表面性质。考察了初始染料浓度、pH值、搅拌速度、接触时间、吸附剂用量等因素的影响。结果表明,纳米粘土和扁桃体实验的染料吸附数据分别符合Langmuir和Freundlich等温线。染料吸附动力学结果表明,吸附系统符合准二阶模型,相关系数为99%。对吸附热力学进行了研究,认为吸附过程是自发的、受物理控制的。在最佳条件下(pH = 7,搅拌速度为200 rpm, CR18浓度为30 ppm,接触时间为30 min),混合吸附剂的吸附量在扁桃体与纳米粘土的质量比为1:2时表现出最大的吸附效率。
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引用次数: 1
Chemical Characteristics of Discharges from Two Derelict Coal Mine Sites in Enugu Nigeria: Implication for Pollution and Acid Mine Drainage 尼日利亚埃努古两个废弃煤矿排放物的化学特征:对污染和酸性矿井排水的启示
IF 0.8 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.22044/JME.2020.10181.1956
Lauren Akpan, C. I. Adamu
In this study, the chemical composition of water and soils contiguous to two abandoned coal mines in southeastern Nigeria, was assessed to evaluate the impact of water flow from the mines ponds on the geoenvironment and potential for acid mine drainage (AMD). Parameters including the pH, anions and cations, and the heavy metals were measured. These were used to evaluate contamination/pollution using hybrid factors including Pollution Load Index, factors, enrichment factors, pollution load index and index of geoaccumulation. The pH range of 3.4 to 5.9 classified the water as weakly to strongly acidic, typical of AMD. The SO42– ion, which indicates pollution by mine waters, showed moderate to high concentrations. Iron, zinc lead and copper were the most abundant heavy metals. Pollution Load Index values were greater than unity which show progressive deterioration in water and sediment quality. The Enrichment Factor values of up to 1 indicated enrichment through lithogenic and anthropogenic sources. The mine dumps serve as pools that can release toxic heavy metals into the water bodies by various processes of remobilization. Based on the lithology, mineralogy, chemical concentrations and environmental factors, the study has shown that there exists a potential for the generation of AMD. The heavy metals enriched mine flow, especially iron, empty into the nearby water bodies which serve as sources of municipal water supply. Consumption of untreated water over a prolonged period from these water sources may be detrimental to health. Remedial measure and continuous monitoring are recommended for good environmental stewardship.
本研究对尼日利亚东南部两个废弃煤矿附近的水和土壤的化学成分进行了评估,以评估矿井池塘水流对地质环境的影响和酸性矿井排水(AMD)的潜力。测定了pH、阴离子、阳离子、重金属等参数。利用污染负荷指数、因子、富集因子、污染负荷指数和地质堆积指数等混合因子对污染/污染进行评价。pH值在3.4到5.9之间,属于弱酸性到强酸性,是典型的AMD。SO42 -离子浓度为中~高浓度,是矿井水污染的标志。铁、锌、铅和铜是最丰富的重金属。污染负荷指数大于1,表现为水沙质量的逐步恶化。富集因子值高达1,表明有岩源和人为源富集。矿山排土场就像一个水池,可以通过各种再活化过程将有毒重金属释放到水体中。综合岩性、矿物学、化学浓度及环境因素,认为该区存在AMD的生成潜力。富含重金属的矿流,特别是铁,排入附近的水体,成为城市供水的来源。长期饮用来自这些水源的未经处理的水可能对健康有害。建议采取补救措施和持续监测,以实现良好的环境管理。
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引用次数: 2
Measurement, Prediction, and Modeling of Bit Wear During Drilling Operations 钻井作业中钻头磨损的测量、预测和建模
IF 0.8 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.22044/JME.2020.10183.1955
M. Capik, B. Batmunkh
Modelling wear of drill bits can increase the efficiency in the drilling operations. Related to the subject, it is aimed to investigate the wear mechanism of drill bits. Wear in drill bits is influenced by many factors related to the drilling and rock properties. The type and intensity of wear are dependent on several complicated factors that are required to be considered in anticipating the rate of wear in the field and laboratory conditions. The laboratory tests have been performed in order to specify the relationships between the bit wear rate and the physico-mechanical properties, drillability, abrasive properties, and brittleness of rocks. Statistical analysis has been used to obtain equations for estimating the bit wear rate based on the rock properties. In this work, an ensemble technique is used to estimate the confidence interval and the prediction intervals for the regression models. This paper summaries the rock properties and bit wear mechanism, and argues the options to determine the bit wear rate. The test models indicate that the rock properties can give an idea of bit wear. They also show a good correlation between the bit wear rates. Also some models are developed to represent the wear quantification, and an approach is suggested in order to estimate the bit wear rate. The results obtained from studying the developed models provide a good agreement with the performance evaluation of an efficient drilling, which provide an indirect evaluation of drill bit wear rate during a drilling process, which can help to reduce the specific energy consumption and lower costs for the exchange of drill bits.
对钻头磨损进行建模可以提高钻井作业效率。与本课题相关,旨在研究钻头的磨损机理。影响钻头磨损的因素与钻进和岩石性质有关。磨损的类型和强度取决于在现场和实验室条件下预测磨损率时需要考虑的几个复杂因素。为了确定钻头磨损率与岩石物理力学性能、可钻性、磨蚀性能和脆性之间的关系,进行了实验室测试。利用统计分析方法,得到了基于岩石性质的钻头磨损率估算方程。在这项工作中,使用集成技术来估计回归模型的置信区间和预测区间。本文总结了岩石性质和钻头磨损机理,讨论了确定钻头磨损率的方法。试验模型表明,岩石的性质可以反映钻头的磨损情况。它们还显示了钻头磨损率之间的良好相关性。建立了钻头磨损量化模型,并提出了一种估算钻头磨损率的方法。所建模型的研究结果与高效钻井的性能评价结果吻合较好,可对钻井过程中钻头磨损率进行间接评价,有助于降低钻头的比能耗,降低钻头的更换成本。
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引用次数: 1
Applying a Technical-Economic Approach to Calculate a Suitable Panel Width for Longwall Mining Method 应用技术经济方法计算长壁采矿法适宜盘面宽度
IF 0.8 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.22044/JME.2020.9552.1870
S. Aghababaei, H. Jalalifar, A. Hosseini
Providing an approach to calculate a suitable panel width for the longwall mining method is considered considering both the technical and economic factors. Based on the investigations carried out, a technical-economic model is proposed to calculate a suitable panel width. The proposed model is a combination of the rock engineering system-based model and the technical relationships to estimate the expected actual face advance rate of the longwall panel and also the economic relationships to determine the operational costs. Applying the technical conditions to the presented model is conducted by the vulnerability index of the advancing operation, which considers the face advance rate as the main important factor that controls the operational costs of the longwall face. The performance evaluation of the presented model is possible by the recordable field data, which is one of its advantages. This process is carried out by a case study, and the results obtained indicate that the developed approach can provide an applicable tool to calculate a suitable panel width.
从技术和经济两方面考虑,为长壁采矿法提供一种合适的底板宽度计算方法。在此基础上,提出了一个技术经济模型来计算合适的面板宽度。该模型结合了基于岩石工程系统的模型和预测长壁板实际掘进速度的技术关系,以及确定作业成本的经济关系。将该模型的技术条件应用于超前作业脆弱性指标,将工作面超前速度作为控制长壁工作面作业成本的主要重要因素。该模型的优点之一是可以利用可记录的现场数据对模型进行性能评价。通过实例分析,结果表明该方法可以为计算合适的面板宽度提供一种实用的工具。
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引用次数: 2
Experimental Investigation of Usability of Construction Waste as Aggregate 建筑垃圾集料可用性试验研究
IF 0.8 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.22044/JME.2021.10309.1976
Gokhan Kulekci, A. Yılmaz, M. Çullu
DOI:10.22044/jme.2021.10309.1976 The aim of this work is to obtain recycled aggregate (RA) from construction debris in order to reduce the rapid consumption of aggregate resources and the environmental impact of these resources. In order to fulfill this aim, the density, porosity, Schmidt hardness test, uniaxial compression resistance, carbonation depth, and ultrasonic pwave velocity experiments were conducted on different construction debris transported by trucks from 9 different points in Turkey. In addition, the debris samples taken were broken down to the size of the aggregate and subjected to the tests of density, porosity, moisture content, freeze-thaw, and impact resistance. As a result of the conducted experiments, the lowest mass loss as a result of freezing-thawing was in GRA with 9.36%, the highest mass loss was in ORA with 22.58%, the highest ORA average aggregate impact strength index was 21.27%, and the lowest TRA aggregate impact strength index was found to be 18.26%. İt was determined that most of the physical properties of RA obtained from the construction wreckage was within the limit values specified in the literature and that the recycled aggregates could be used instead of natural aggregate. With this work and these results, RA obtained could be used in many areas such as concrete aggregate in the construction sector, underground filling in mining, filling material in gunned concrete, and filling materials on highways. Keywords
这项工作的目的是从建筑碎片中获得再生骨料(RA),以减少骨料资源的快速消耗和这些资源对环境的影响。为了实现这一目标,对土耳其9个不同地点卡车运输的不同建筑碎片进行了密度、孔隙率、施密特硬度试验、单轴抗压性、碳化深度和超声波波速实验。此外,采集的碎片样品被分解成骨料的大小,并进行密度、孔隙率、含水率、冻融和抗冲击性测试。结果表明,冻融后的质量损失最小的是GRA,为9.36%,质量损失最大的是ORA,为22.58%,ORA平均骨料冲击强度指数最高为21.27%,TRA骨料冲击强度指数最低为18.26%。İt经确定,从建筑残骸中获得的RA的大部分物理特性都在文献中规定的极限值内,并且可以使用再生骨料代替天然骨料。通过这项工作和这些结果,所获得的RA可用于许多领域,如建筑部门的混凝土骨料,采矿的地下填充,喷枪混凝土的填充材料和高速公路的填充材料。关键字
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引用次数: 5
Quantifying Roof Falling Potential based on CMRR Method by Incorporating DEMATEL-MABAC Method; A Case Study 结合DEMATEL-MABAC方法的CMRR法定量顶板落势案例研究
IF 0.8 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.22044/JME.2020.9878.1911
S. Mohammadi, M. Babaeian, M. Ataei, K. Ghanbari
This work incorporates the DEMATEL-MABAC method for quantifying the potential of roof fall in coal mines by means of the coal mine roof rating (CMRR) parameters. For this purpose, considering the roof weighting interval as a quantitative criterion for the stability of the roof, the immediate roof falling potential was quantified and ranked in 15 stopes of Eastern Alborz Coal Mines Company. In this regard, on the basis of the experts’ judgments, the fuzzy DEMATEL method was used for designation weights of the parameters, and the MABAC method was incorporated to quantify and rank the stopes (alternatives). “UCS of roof” and “joint spacing” in the immediate roof were found to be the most important parameters that controlled roof falling in stopes; and “joint persistence” was also found to be a quite significant parameter. Finding confirms that overall strength of rood rock mass plays a main role in the falling potential. Comparison of the coefficients of determination (R2) between the weighting interval and proposed model with that and original CMRR indicated more than 15% increase, which represented that the new proposed model was more accurate to quantify roof quality. The findings of this work show that using this combined method and specializing the CMRR method for a given mine geo-condition to assess the quality of the roof and its potential of collapse possesses a higher performance when compared with the original CMRR method.
本文采用DEMATEL-MABAC方法,利用煤矿顶板额定值(CMRR)参数对煤矿顶板落顶势进行量化。为此,将顶板压重间隔作为顶板稳定性的定量判据,对东奥尔博斯煤矿公司15个采场的顶板直接冒落势进行了量化排序。为此,在专家判断的基础上,采用模糊DEMATEL法确定各参数的权重,并结合MABAC法对采场(备选方案)进行量化排序。结果表明,直接顶板的“顶板UCS”和“节理间距”是控制采场顶板冒落的最重要参数;“关节持续性”也是一个非常重要的参数。研究结果证实了巷道岩体的综合强度对落势起主要作用。将权重区间和模型的决定系数R2与原CMRR的决定系数R2进行比较,结果表明,新模型对顶板质量的量化精度提高了15%以上。研究结果表明,将该方法与特定矿山地质条件下的CMRR方法相结合,对顶板质量及其坍塌潜力进行评估,与原有的CMRR方法相比,具有更高的性能。
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引用次数: 2
Study of Rock Pillar Failure Consisting of Non-Persistent Joint using Experimental Test and Fracture Analysis Code in Two Dimensions 基于试验试验和二维断裂分析程序的非持久节理矿柱破坏研究
IF 0.8 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.22044/JME.2020.10266.1968
V. Sarfarazi, H. Javid, Kaveh Asgari
The experimental and numerical methods were used to investigate the effects of joint number and joint angle on the failure behaviour of rock pillars under a uniaxial compressive test. The gypsum samples with dimensions of 200 mm × 200 mm × 50 mm were prepared. The compressive strength of the intact sample was 7.2 MPa. The imbeded joint was placed inside the specimen. The joint length was 6 cm in a constant joint length. There were several numbers of cracks including one, two, and three cracks. In the experimental tests, the angles of the diagonal plane with respect to the horizontal axis were 0, 30, 60, and 90 degrees. The axial load was applied to the model with a rate of 0.01 mm/s. In the fracture analysis code, the angles of the diagonal plane with respect to the horizontal axis were 0, 15, 30, 45, 60, 75, and 90 degrees. A constant axial load of 135 MPa was applied to the model. The results obtained showed that the failure process was mostly dependent on the angle and number of the non-persistent joint. The compressive strength of the samples was dependent on the fracture pattern and the failure mechanism of the discontinuities. It was shown that the tensile cracks were developed whithin the model. The strength of the specimens increased by increasing both the joint angle and joint number. The joint angle of 45°  KI had the maximum quantity. The stress intensity factor was decreased by increasing the joint number. The failure pattern and failure strength were analogous in both methods, i.e. the experimental testing and the numerical simulation methods.
采用试验与数值相结合的方法,研究了单轴压缩试验中节理数目和节理角度对岩柱破坏行为的影响。制备了尺寸为200 mm × 200 mm × 50 mm的石膏样品。完整试样的抗压强度为7.2 MPa。将嵌入关节置于试件内部。在固定关节长度下,关节长度为6cm。有几条裂缝,包括一条、两条和三条裂缝。在实验测试中,对角线平面相对于水平轴的角度分别为0度、30度、60度和90度。轴向载荷以0.01 mm/s的速率作用于模型。在断裂分析规范中,对角线平面相对于水平轴的角度分别为0、15、30、45、60、75和90度。模型施加恒定轴向载荷135 MPa。结果表明,破坏过程主要取决于非持久节理的角度和数量。试样的抗压强度取决于断裂模式和不连续面破坏机制。结果表明,模型内部出现了拉伸裂纹。随着节理角度和节理数目的增加,试件的强度有所提高。关节角为45°KI时数量最多。随着接头数目的增加,应力强度因子减小。两种方法的破坏模式和破坏强度相似,即试验测试和数值模拟方法。
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引用次数: 1
Probabilistic Prediction of Acid Mine Drainage Generation Risk Based on Pyrite Oxidation Process in Coal Washery Rejects - A Case Study 基于选煤厂废渣黄铁矿氧化过程的酸性矿井水生成风险概率预测——以黄铁矿氧化废渣为例
IF 0.8 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.22044/JME.2020.9609.1873
F. Hadadi, B. J. Shokri, Masoud Zare Naghadehi, F. D. Ardejani
In this paper, we investigate a probabilistic approach in order to predict how acid mine drainage is generated within coal waste particles in NE Iran. For this, a database is built based on the previous studies that have investigated the pyrite oxidation process within the oldest abandoned pile during the last decade. According to the available data, the remaining pyrite fraction is considered as the output data, while the depth of the waste, concentration of bicarbonate, and oxygen fraction are the input parameters. Then the best probability distribution functions are determined on each one of the input parameters based on a Monte Carlo simulation. Also the best relationships between the input data and the output data are presented regarding the statistical regression analyses. Afterward, the best probability distribution functions of the input parameters are inserted into the linear statistical relationships to find the probability distribution function of the output data. The results obtained reveal that the values of the remaining pyrite fraction are between 0.764% and 1.811% at a probability level of 90%. Moreover, the sensitivity analysis carried out by applying the tornado diagram shows that the pile depth has, by far, the most critical factors affecting the pyrite remaining
在本文中,我们研究了一种概率方法,以预测伊朗东北部煤矸石颗粒中酸性矿井排水是如何产生的。为此,基于过去十年来对最古老的废弃堆中黄铁矿氧化过程的研究,建立了一个数据库。根据现有数据,以残余黄铁矿分数为输出数据,以废石深度、碳酸氢盐浓度、氧分数为输入参数。然后在蒙特卡罗模拟的基础上确定每个输入参数的最佳概率分布函数。在统计回归分析中,给出了输入数据与输出数据之间的最佳关系。然后,将输入参数的最佳概率分布函数插入到线性统计关系中,求出输出数据的概率分布函数。结果表明,在90%的概率水平上,黄铁矿残余分数在0.764% ~ 1.811%之间。应用龙卷风图进行敏感性分析表明,桩深是影响黄铁矿残留的最关键因素
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引用次数: 6
Facies Quality Zoning in Shale Gas by Deep Learning Method 基于深度学习方法的页岩气相质量分区研究
IF 0.8 Q3 MINING & MINERAL PROCESSING Pub Date : 2021-01-01 DOI: 10.22044/JME.2021.10366.1983
Y. A. Nezhad, A. Moradzadeh
One of the most essential factors involved in unconventional gas reserves for drilling and production is a suitable quality facies determination. The direct core and geochemical analyses are the most common methods used for studying this quality. Due to the lack of this data and the high cost, the researchers have recently resorted to the indirect methods that use the common data of the reservoir (including petro-physical logs and seismic data). One of the major problems in using these methods is that the complexities of these reproducible repositories cannot be accurately modeled. In this work, the quality of facies in shale gas is zoned using the deep learning technique. The applied method is long short-term memory (LSTM) neural network. In this scheme, the features required for zoning are automatically extracted and used to model the reservoir complexities properly. The results of this work show that zoning is done with an appropriate accuracy (86%) using the LSTM neural network, while it is 78% for a conventional intelligent MLP network. This specifies the superior accuracy of the deep learning method.
确定适合钻井和生产的非常规天然气储量最重要的因素之一是确定合适的质量相。直接岩心法和地球化学分析是研究该质量最常用的方法。由于这些数据的缺乏和高成本,研究人员最近采用了间接方法,即使用储层的常用数据(包括岩石物理测井和地震数据)。使用这些方法的一个主要问题是,这些可重复存储库的复杂性无法精确建模。在这项工作中,使用深度学习技术对页岩气的相质量进行了分区。应用的方法是长短期记忆(LSTM)神经网络。在该方案中,自动提取分区所需的特征,并将其用于油藏复杂性建模。这项工作的结果表明,使用LSTM神经网络以适当的精度(86%)完成分区,而传统智能MLP网络的分区精度为78%。这说明了深度学习方法的优越准确性。
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引用次数: 1
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