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Multifunctional Biomimetic Paper: High-strength, Fire-resistant, and Self-cleaning ASF/HAPNW Composite Inspired by Bird-nest Architecture 多功能仿生纸:高强度,耐火,自清洁的ASF/HAPNW复合材料,灵感来自鸟巢建筑
IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2025-12-20 DOI: 10.1007/s10443-025-10422-5
Jingxiao Guo, Zhen Hong, Guoyu Zhu, Ruochen Liu, Yongcun Ma, Jilin Xu, Zuozhu Yin, Yidan Luo, Chan Xie, Mingshan Xue

Traditional cellulose-based paper suffers from inherent flammability, hydrophilicity, and oxidative degradation. These limitations cause irreversible damage, including yellowing, moisture absorption, and structural decay, during long-term archival storage. To address these challenges, a biomimetic strategy inspired by the hierarchical architecture of bird-nest (interwoven branches, grass, and mud) is proposed to engineer a multifunctional composite paper. By integrating aluminum silicate fibers (ASF) as load-bearing “branches”, ultralong hydroxyapatite nanowires (HAPNW) as flexible “grass”, and an inorganic adhesive(aluminum oxide sol) as binding “mud”, a nest-like network is constructed to synergistically enhance mechanical robustness, flame resistance, and environmental stability. Unlike pure HAPNW paper with limited tensile strength (25 MPa), the optimized composite (30% ASF) achieves a remarkable strength of 62 MPa and modulus of 9 GPa, attributed to stress redistribution via interfacial fiber entanglement and inorganic binder-mediated cohesion. Further hydrophobic modification confers superhydrophobicity and self-cleaning capabilities, while retaining writeability comparable to conventional paper. Crucially, the composite exhibits non-combustibility under direct flame exposure (700°C, 60 s) and exceptional thermal stability (84% residual mass at 800°C), outperforming commercial counterparts. This work pioneers a biomimetic paradigm for designing high-performance archival materials, offering a sustainable solution to reconcile mechanical durability, fire safety, and environmental resilience in paper-based preservation technologies.

传统的纤维素基纸具有固有的可燃性、亲水性和氧化降解性。这些限制造成不可逆的损害,包括发黄,吸湿和结构腐烂,在长期的档案储存。为了应对这些挑战,我们提出了一种仿生策略,灵感来自于鸟窝的分层结构(交织的树枝、草和泥),以设计一种多功能复合纸。通过硅酸铝纤维(ASF)作为承重“树枝”,超长羟基磷灰石纳米线(HAPNW)作为柔性“草”,无机粘合剂(氧化铝溶胶)作为结合“泥”,构建了一个类似巢的网络,协同增强了机械坚固性、阻燃性和环境稳定性。与纯HAPNW纸的极限拉伸强度(25 MPa)不同,优化后的复合材料(30% ASF)的强度达到了62 MPa,模量达到了9 GPa,这是由于界面纤维缠结和无机粘合剂介导的内聚引起的应力重分布。进一步的疏水改性赋予超疏水性和自清洁能力,同时保持与传统纸张相当的可书写性。至关重要的是,该复合材料在直接火焰暴露(700°C, 60秒)下表现出不燃性,并且具有优异的热稳定性(800°C时残余质量为84%),优于商业同类材料。这项工作开创了设计高性能档案材料的仿生范例,提供了一种可持续的解决方案,以协调纸质保存技术的机械耐久性、防火安全性和环境弹性。
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引用次数: 0
Experimental Investigation on the Strain Rate Dependence of Continuous Carbon fibre-reinforced PA6 Under four-point Flexural Loading 四点弯曲加载下连续碳纤维增强PA6应变速率相关性试验研究
IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2025-12-20 DOI: 10.1007/s10443-025-10390-w
Johann Jung, Michael Schmiedt, Robert Schneider, Wolfgang Rimkus, Iman Taha

Carbon fibre-reinforced thermoplastics used in structural applications, such as crash-relevant parts, are typically subjected to different strain rate conditions. This requires a deep understanding of their structural behaviour under these conditions. To date, there is limited data on their strain rate dependent behaviour. In this study, four-point flexure tests are used to determine the longitudinal flexural properties and failure behaviour of unidirectional carbon fibre-reinforced polyamide 6 (CF-PA6) material as a function of the applied strain rate. A universal testing machine and a drop tower test setup with two different drop heights were used to investigate the behaviour in quasi-static (1.3 × 10− 4 1/s) to medium strain rates (7 1/s). Flexural modulus, flexural strength and fracture strain were determined for all strain rates applied, and the fracture morphology was analysed using microscopic images and high-speed camera recordings. Further, Weibull analysis was performed on the flexural strength. The experimental investigation of the flexural properties showed no significant strain rate effect and no trend was observed in the Weibull parameters. Irrespective of the strain rate applied, all specimens tested exhibited a comparable fracture morphology due to a similar failure process of initial compressive failure followed by tensile failure.

用于结构应用的碳纤维增强热塑性塑料,例如与碰撞相关的部件,通常受到不同应变速率条件的影响。这需要深入了解它们在这些条件下的结构行为。迄今为止,关于其应变速率依赖行为的数据有限。在这项研究中,四点弯曲试验用于确定单向碳纤维增强聚酰胺6 (CF-PA6)材料的纵向弯曲性能和破坏行为作为施加应变率的函数。采用通用试验机和两种不同跌落高度的跌落塔试验装置,研究了准静态(1.3 × 10−4 1/s)至中等应变速率(7 1/s)下的行为。测量了所有应变速率下的弯曲模量、弯曲强度和断裂应变,并使用显微图像和高速摄像机记录分析了断裂形态。进一步,对抗弯强度进行威布尔分析。弯曲性能试验研究表明,应变率效应不显著,威布尔参数变化趋势不明显。无论施加的应变速率如何,由于初始压缩破坏和随后的拉伸破坏的相似破坏过程,所有试样都表现出相似的断裂形态。
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引用次数: 0
Study on the Chip Formation Mechanism of Low-Density SiCp/Al Materials 低密度SiCp/Al材料切屑形成机理研究
IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2025-12-17 DOI: 10.1007/s10443-025-10416-3
Ren Man, Guo Miaoxian, Luo Shijin, Li Xia, Guo Weicheng

SiCp/Al composites, with high specific strength, low thermal expansion coefficient, and excellent wear resistance, are widely used in aerospace lightweight components. However, during machining, hard and brittle SiC particles not only accelerate tool wear but also restrict low-damage machining efficiency due to complex chip formation mechanisms and uncontrollable surface damage. Thus, focusing on low-volume-fraction SiCp/Al, this study investigates the chip formation mechanism and its impact on surface morphology, revealing how cutting parameters regulate chip morphology and surface quality to provide theoretical support for process optimization. A three-phase SiCp/Al thermo-mechanical coupling model was built, combined with 2D cutting simulations to analyse the mesoscopic mechanism of chip formation, validated via single-factor cutting experiments. Scanning electron microscopy (SEM) and image processing techniques were used to characterize chip morphology and geometric features, and the mapping relationship between cutting parameters, chip morphology, and surface damage was established. Findings show that serrated chips are easily formed during SiCp/Al cutting; the shape and distribution of SiC particles are key factors regulating chip and surface morphology, with a 6.31% error between simulation and experimental results. With increased cutting speed, chip serration intensifies; enhanced plastic flow of the aluminium matrix drives serrations to evolve into continuous shear flow, with simultaneous improvement in surface quality. As cutting depth increases, chip serration also rises; however, intensified stress concentration in the cutting zone leads to coarser serrations, along with more microcracks, particle pull-outs, and pits, causing a continuous increase in surface roughness. Optimizing cutting parameters can balance chip stability and workpiece surface integrity, providing a process basis for efficient, low-damage machining of SiCp/Al components.

SiCp/Al复合材料具有高比强度、低热膨胀系数和优异的耐磨性,广泛应用于航空航天轻量化部件。然而,在加工过程中,硬脆的SiC颗粒不仅加速了刀具的磨损,而且由于其复杂的切屑形成机制和不可控的表面损伤,限制了低损伤加工效率。因此,本研究以低体积分数SiCp/Al为研究对象,研究切屑形成机理及其对表面形貌的影响,揭示切削参数如何调节切屑形貌和表面质量,为工艺优化提供理论支持。建立SiCp/Al三相热-力耦合模型,结合二维切削模拟分析切屑形成的细观机理,并通过单因素切削实验进行验证。利用扫描电子显微镜(SEM)和图像处理技术对切屑形貌和几何特征进行表征,建立了切削参数、切屑形貌和表面损伤之间的映射关系。结果表明:SiCp/Al切削易形成锯齿状切屑;SiC颗粒的形状和分布是影响晶片和表面形貌的关键因素,模拟结果与实验结果误差为6.31%。随着切削速度的增加,切屑锯齿化加剧;增强的塑性流动的铝基体驱动锯齿演变成连续的剪切流动,同时在表面质量的改善。随着切削深度的增加,切屑锯齿度也增加;然而,切削区应力集中的加剧导致了更粗的锯齿,以及更多的微裂纹、颗粒拉出和凹坑,导致表面粗糙度不断增加。优化切削参数可以平衡切屑稳定性和工件表面完整性,为SiCp/Al部件的高效、低损伤加工提供工艺基础。
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引用次数: 0
Progressive Collapse Behaviors of Re-Entrant Honeycomb Structure Under Out-of-Plane Compression 面外压缩下再入蜂窝结构的递进破坏行为
IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2025-12-15 DOI: 10.1007/s10443-025-10392-8
Chenyang Lv, Yan Li, Fusheng Wang, Jianhua Li, Donghong Wang

Phenolic resin-impregnated aramid paper honeycombs are promising for engineering applications. However, most designs cannot provide sufficient load-bearing capacity, limiting their application as structural materials. Here, a novel re-entrant honeycomb structure is designed based on the expansion manufacturing method and 17 distinct honeycomb structures are derived from this structure using the Box-Behnken design method. Compression tests are performed on the re-entrant honeycomb to investigate its deformation mechanism and validate the finite element model. Numerical results from 17 honeycomb structures demonstrate that peak stress, plateau stress and energy absorption increase with increasing density and total side length, while decreasing with increasing angle of 1/4 unit cell. The analysis of collapse mechanisms reveal that the plastic deformation mode comprised both bending and membrane deformations. On this basis, an analytical model for predicting the mean compressive strength of honeycomb structures is developed using a simplified super folding element theory. The theoretical solution is in good agreement with the simulations. Furthermore, a multiobjective optimization method is used to efficiently optimize the structural parameters, resulting in the acquisition of optimal structural parameters that meet the load-bearing requirements. The yield strength, mean compressive strength and energy absorption of novel honeycomb are significantly higher than other popular honeycomb structures.

酚醛树脂浸渍芳纶纸蜂窝具有广阔的工程应用前景。然而,大多数设计不能提供足够的承载能力,限制了其作为结构材料的应用。本文基于膨胀制造方法设计了一种新型的可重入式蜂窝结构,并采用Box-Behnken设计方法推导出17种不同的蜂窝结构。对返回式蜂窝进行了压缩试验,研究了其变形机理,验证了有限元模型的正确性。对17个蜂窝结构的数值计算结果表明,峰值应力、平台应力和能量吸收随密度和总边长的增大而增大,随1/4单元格角的增大而减小。破坏机理分析表明,塑性变形模式包括弯曲变形和薄膜变形。在此基础上,采用简化的超折叠单元理论建立了蜂窝结构平均抗压强度的分析模型。理论解与仿真结果吻合较好。在此基础上,采用多目标优化方法对结构参数进行高效优化,获得满足承载要求的最优结构参数。新型蜂窝的屈服强度、平均抗压强度和吸能明显高于其他常用蜂窝结构。
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引用次数: 0
Hygrothermal Aging Effects on Low-Velocity Impact Resistance of 3D Orthogonal Jute/Basalt Hybrid Woven Composites 湿热老化对三维正交黄麻/玄武岩混杂编织复合材料抗低速冲击性能的影响
IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2025-12-15 DOI: 10.1007/s10443-025-10420-7
Xin Sun, Jiaxuan Wang, Yiwei Ouyang, Xiaoke Huang, Xiaonan Wang, Yiran Han, Yang Liu, Xiaozhou Gong

This study prepared three-dimensional orthogonal jute/basalt composites with varying weft mixing ratios via vacuum-assisted resin transfer molding (VARTM). The composites were subsequently immersed in distilled water at two temperatures (25 °C and 65 °C) for up to 90 days.Moisture absorption tests and low-velocity impact (LVI) tests were performed on hygrothermal-treated composites, with damage morphologies characterized using optical microscopy and scanning electron microscopy (SEM). Results showed that moisture absorption rate of composites increased with jute content. Among all specimens, the pure jute composite specimen ([7J]) showed the highest moisture absorption rate, while the pure basalt composite specimen ([7B]) demonstrated the lowest. Elevated temperature accelerated moisture diffusion and matrix degradation, while fiber arrangement also affected moisture absorption performance. Hygrothermal aging degraded LVI performance: after 90-day aging at 65 °C, peak load of the jute/basalt weft-alternating hybrid composite specimen ([4B3J]) specimens decreased by 38.01% and energy absorption reduced by 24%, attributed to matrix hydrolysis, fiber-matrix interface debonding, and microcrack propagation. Damage analysis revealed that specimens with higher jute content experienced more severe fracture and delamination, with aging exacerbating the “I”-shaped back surface damage. This study provides theoretical guidance for engineering applications of natural fiber hybrid composites in hygrothermal environments.

采用真空辅助树脂转移模塑(VARTM)法制备了不同纬混比的三维正交黄麻/玄武岩复合材料。随后将复合材料浸泡在两种温度(25°C和65°C)的蒸馏水中长达90天。对湿热处理的复合材料进行了吸湿测试和低速冲击(LVI)测试,并使用光学显微镜和扫描电子显微镜(SEM)对损伤形貌进行了表征。结果表明,复合材料吸湿率随黄麻含量的增加而增加。其中,纯黄麻复合试样([7J])吸湿率最高,纯玄武岩复合试样([7B])吸湿率最低。升高的温度加速了水分的扩散和基质的降解,而纤维排列也影响了吸湿性能。湿热老化降低了LVI性能:65℃老化90 d后,黄麻/玄武岩湿-交变混杂复合材料([4B3J])试样的峰值荷载下降了38.01%,能量吸收下降了24%,主要原因是基体水解、纤维-基体界面脱粘和微裂纹扩展。损伤分析表明,黄麻含量越高,试件断裂和脱层越严重,老化加剧了后表面的“I”形损伤。本研究为天然纤维混杂复合材料在湿热环境下的工程应用提供了理论指导。
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引用次数: 0
Impact Damage Detection on Thick Reinforced Thermoplastic Pipe Utilizing X-Ray Computed Tomography and Phased Array Ultrasonic Testing Techniques 基于x射线计算机断层扫描和相控阵超声检测技术的厚增强热塑性钢管冲击损伤检测
IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2025-12-15 DOI: 10.1007/s10443-025-10399-1
Mohd Fadzil Mohd Tahir, Andreas T. Echtermeyer

This study investigated impact damage characterization of reinforced thermoplastic pipes (RTP) using X-ray computed tomography (CT) scan and phased array ultrasonic testing (PAUT) techniques. Two types of RTP samples, namely the standard (ST) and gas-tight (GT) types, were impacted using a drop-weight tower. The X-ray CT scan revealed detailed cross-sectional views of damages, including fiber breakage, matrix degradation, and aluminum layer damage. With the implementation of time-corrected gain method in a zero-degree configuration, PAUT demonstrated damage detection capabilities comparable to the CT scan technique by employing various frequencies and focusing techniques. However, it was challenging to accurately assess the extent of damage in the GT type due to the presence of the aluminum layer. While higher-frequency PAUT transducers improved sizing accuracy for the ST type, sizing damages in the GT type remained challenging. Implementing a focusing technique revealed ultrasonic B-scan cross-sectional images of damage closely resembling those from CT scans, offering insights into through-thickness damage morphology. This research showed that the results from the ultrasonic wave-based technique were in good agreement with those from the X-ray imaging-based technique.

采用x射线计算机断层扫描(CT)和相控阵超声检测(PAUT)技术研究了增强热塑性塑料管(RTP)的冲击损伤特征。两种类型的RTP样品,即标准型(ST)和气密型(GT),使用落锤塔进行冲击。x射线CT扫描显示了损伤的详细横截面图,包括纤维断裂、基体降解和铝层损伤。通过在零度配置中实现时间校正增益方法,通过使用各种频率和聚焦技术,PAUT展示了与CT扫描技术相当的损伤检测能力。然而,由于铝层的存在,很难准确评估GT型的损伤程度。虽然高频pat换能器提高了ST型的上浆精度,但GT型的上浆损伤仍然具有挑战性。采用聚焦技术,超声b扫描显示损伤的横截面图像与CT扫描的图像非常相似,从而提供了对全厚度损伤形态的见解。研究结果表明,超声成像技术与x射线成像技术的结果吻合较好。
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引用次数: 0
Influence of Equivalent Axial Stiffness on Dynamic Crushing Energy Absorption Characteristics of C-section CFRP Composite Stanchions in Sub-cargo Area of Aircraft 等效轴向刚度对飞机分货区c截面CFRP复合材料支柱动态破碎吸能特性的影响
IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2025-12-06 DOI: 10.1007/s10443-025-10410-9
Fu Liu, Xinyi Wang, Yuandi Li, Jiulian Wang, Xiong Pan, Chunyu Bai, Xulong Xi

Dynamic axial crushing tests were performed on C-section carbon fiber reinforced polymer (CFRP) composite stanchions used in sub-cargo area of aircraft to evaluate their dynamic response under high-speed axial crushing load. A numerical model based on the continuum damage mechanics (CDM) was developed, with calculated failure modes and crushing loads closely matching experimental results, validating the model’s accuracy and reliability. The influence of equivalent axial stiffness and lay-up sequence on the crushing failure modes and energy absorption characteristics of the stanchions was investigated. A mathematical relationship among the specific energy absorption (SEA), average crushing load and equivalent axial stiffness was fitted. The results showed that, compared to single lay-ups, hybrid lay-up configurations exhibited superior structural stability and energy absorption performance. In particular, lay-up configurations with higher equivalent axial stiffness significantly enhanced both the SEA and average crushing load. Furthermore, when the equivalent axial stiffness was held constant, variations in lay-up sequence had a relatively minor effect on the energy absorption characteristics. However, if the axial stiffness of the outermost plies was significantly reduced by consecutively placing 90° plies on the outermost plies, the axial stability of the stanchion deteriorated rapidly, leading to a pronounced decrease in its energy absorption performance.

对飞机分货区c截面碳纤维增强聚合物(CFRP)复合材料支柱进行了轴向动态破碎试验,以评估其在高速轴向破碎载荷下的动态响应。建立了基于连续损伤力学(CDM)的数值模型,计算的破坏模式和破碎载荷与实验结果吻合较好,验证了模型的准确性和可靠性。研究了等效轴向刚度和铺层顺序对支柱破碎破坏模式和能量吸收特性的影响。拟合了比能吸收(SEA)、平均破碎载荷和等效轴向刚度之间的数学关系。结果表明,与单一铺层相比,混合铺层具有更好的结构稳定性和吸能性能。特别是,具有较高等效轴向刚度的铺设构型显著提高了SEA和平均破碎载荷。此外,当等效轴向刚度保持不变时,铺层顺序的变化对能量吸收特性的影响相对较小。然而,如果连续在最外层层上放置90°层,显著降低最外层层的轴向刚度,则支柱的轴向稳定性迅速恶化,导致其吸能性能明显下降。
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引用次数: 0
Compressive and Flexural Properties of a Novel Arc Honeycomb Structure 一种新型弧形蜂窝结构的抗压和弯曲性能
IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2025-12-05 DOI: 10.1007/s10443-025-10380-y
Tongtong Zheng, Yuanyuan Wei, Guoqian Song, Can Tang, Wenfeng Hao

Honeycomb structures have garnered significant attention due to their outstanding mechanical properties, including high strength, high stiffness, and excellent energy absorption capabilities. This paper innovatively incorporates circular arcs and support structures based on the configuration characteristics of positive and negative Poisson’s ratio cells, designing three novel circular arc honeycomb configurations and their combination forms. Specimens were fabricated using FDM technology. Through uniaxial compression and three-point bending tests, the quasi-static compression and bending properties of these structures were systematically investigated. Finite element simulations provided in-depth insights into deformation mechanisms and stress evolution during compression. Results indicate that the negative Poisson’s ratio with arc and support structure exhibits superior compressive performance, achieving a compressive ultimate strength of 2.6 MPa and a specific energy absorption of 3815.9 J/kg. Compared to conventional honeycomb structures, the specific energy absorption value increased by 3.15 times. Finite element analysis indicates that the arc design effectively disperses stress and enables stable progressive folding. With its high specific strength (6.9 MPa·cm³/g), the negative Poisson’s ratio structure with arcs is suitable for lightweight applications. Bending test results show that the positive Poisson’s ratio arc structure exhibits the highest average crush force (249.1 N) and specific energy absorption (158.8 J/kg) due to arc-induced shear stress dispersion. Combining the three unit cells enhances the mechanical properties of individual cells, with the failure sequence of the composite structure following the strength gradient of the unit cells. This study achieves synergistic optimization of lightweighting, load-bearing, and energy-absorption performance through structural innovation combined with additive manufacturing technology. It provides valuable reference for structural design and application in aerospace, transportation, and building protection fields.

蜂窝结构因其优异的机械性能,包括高强度、高刚度和出色的能量吸收能力而受到广泛关注。本文根据正、负泊松比单元的构型特点,创新性地将圆弧与支撑结构结合,设计了三种新颖的圆弧蜂窝构型及其组合形式。采用FDM技术制作标本。通过单轴压缩和三点弯曲试验,系统地研究了这些结构的准静态压缩和弯曲性能。有限元模拟提供了深入了解压缩过程中的变形机制和应力演化。结果表明,采用负泊松比的圆弧和支撑结构具有较好的抗压性能,其抗压极限强度为2.6 MPa,比能吸收为3815.9 J/kg。与传统蜂窝结构相比,比能吸收值提高了3.15倍。有限元分析表明,弧形设计有效地分散了应力,实现了稳定的渐进式折叠。具有弧的负泊松比结构具有较高的比强度(6.9 MPa·cm³/g),适用于轻量化应用。弯曲试验结果表明,正泊松比电弧结构由于电弧引起的剪切应力分散,具有最高的平均压溃力(249.1 N)和比能吸收(158.8 J/kg)。三个单元格的结合提高了单个单元格的力学性能,复合结构的破坏顺序遵循单元格的强度梯度。本研究通过结构创新与增材制造技术相结合,实现了轻量化、承载和吸能性能的协同优化。为航空航天、交通运输、建筑防护等领域的结构设计和应用提供了有价值的参考。
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引用次数: 0
Shear Strength Enhancement of Injection-Molded Metal-Polymer Composite Joints Using Z-Pins Manufactured Through Fused Filament Fabrication 用熔丝制造的z销提高注射成型金属-聚合物复合材料接头的抗剪强度
IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2025-12-04 DOI: 10.1007/s10443-025-10381-x
Run Chen, Xin Lv, Qixin Zhao, Mengjia Li, Yuan Zhao, Sisi Wang, Shiju E, Linlin Wang

This work examines the joining performance of metal-polymer composite single-lap joints (SLJs) enhanced with 316 L stainless steel Z-pins manufactured through fused filament fabrication (FFF). The Z-pin arrays and steel substrates were co-printed using FFF, and then subjected to debinding and sintering processes. The resulting structure was subsequently combined with polyphenylene sulfide (PPS) through an injection molding direct joining (IMDJ) process to create durable 316 L-PPS composite SLJs. The results show that incorporating FFF-fabricated Z-pins significantly enhance the joining performance of metal-polymer SLJs. A detailed investigation into the effects of pinning density and Z-pin alignment on polymer melt behavior and joint performance revealed that higher pinning densities and vertically aligned Z-pins (90° angle) resulted in superior joint strength. This configuration enhanced PPS melt flow, minimized interfacial defects, and achieved the highest shear strength—improving by up to 113.1% compared to unreinforced joints. The improved mechanical response is primarily due to the Z-pins’ ability to dissipate energy through mechanisms such as interfacial sliding and localized deformation, which hinder crack initiation and growth. This study presents a distinctive strategy for engineering metal-polymer composite joints, enabling the fabrication of multifunctional hybrid structures with enhanced performance.

本研究考察了金属-聚合物复合材料单搭接接头(slj)的连接性能,该接头是通过熔融长丝制造(FFF)制造的316l不锈钢z形销增强的。采用FFF共印Z-pin阵列和钢基板,然后进行脱脂和烧结工艺。随后,通过注射成型直接连接(IMDJ)工艺将所得结构与聚苯硫醚(PPS)结合,制成耐用的316 L-PPS复合slj。结果表明,加入fff制备的z -pin可以显著提高金属-聚合物slj的连接性能。详细研究了钉接密度和z销排列对聚合物熔体行为和接头性能的影响,发现较高的钉接密度和垂直排列的z销(90°角)可以提高接头强度。这种结构增强了PPS熔体流动,最大限度地减少了界面缺陷,与未增强的接头相比,抗剪强度提高了113.1%。改善的力学响应主要是由于z销能够通过界面滑动和局部变形等机制耗散能量,从而阻碍裂纹的萌生和扩展。本研究提出了一种独特的工程金属-聚合物复合连接策略,使多功能混合结构的制造具有更高的性能。
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引用次数: 0
Design and Characterization of Spiderweb-Inspired CF/Nylon Composite Honeycombs for Enhanced Energy Absorption 基于蜘蛛网的碳纤维/尼龙复合材料蜂窝的设计与性能研究
IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2025-12-02 DOI: 10.1007/s10443-025-10411-8
Yongsheng Li, Cheng Shen, Qi Wu, Jinling Gao, Han Meng, Tian Jian Lu

Conventional honeycomb structures face problems of local buckling, brittle fracture, and insufficient energy absorption efficiency under out-of-plane compression. To address these limitations, this study investigates a bio-inspired spiderweb-like honeycomb structure using 3D-printed short carbon fiber reinforced nylon composite. Specimens of spiderweb-like and conventional hexagonal honeycomb structures were fabricated via fused deposition modeling technology. Through quasi-static compression tests and finite element simulation, deformation modes and energy absorption characteristics of different honeycomb structures were comparatively analyzed. Results demonstrate that the spiderweb-type honeycomb structure achieves significant improvements in load-bearing capacity and energy absorption efficiency through hierarchical collapse mechanisms and coordinated deformation of multiple plastic hinges. Compared to conventional hexagonal honeycombs with equivalent wall thickness, the spiderweb structure exhibits 221% greater load bearing capacity and 94% higher specific energy absorption. When compared to conventional hexagonal honeycomb structures with the same area density, the spiderweb honeycomb shows a specific energy absorption increase of about 35% and a total energy absorption increase of 93.9%. Additionally, parametric studies reveal that hierarchical design parameters r (the ratio of the side lengths of the inner and outer honeycomb layers) in the spiderweb structure plays an important role in the distribution of plastic hinges and plateau stress. When r is in the range of 0.4 to 0.6, the structure achieves uniform stress distribution and maintains high load-bearing capacity through anti-symmetric buckling and progressive folding deformation. However, when r = 1 or r < 0.4, the structure undergoes global buckling or brittle fracture, leading to a decrease in energy absorption performance. This work develops a design framework for bio-inspired hierarchical composites with tailored energy absorption performance, demonstrating specific parameter configurations that achieve superior energy absorption for aerospace and automotive applications.

传统蜂窝结构在面外压缩作用下存在局部屈曲、脆性断裂、吸能效率不足等问题。为了解决这些限制,本研究利用3d打印短碳纤维增强尼龙复合材料研究了一种仿生蜘蛛网状蜂窝结构。采用熔融沉积建模技术制备了蛛网状和常规六边形蜂窝结构的样品。通过准静态压缩试验和有限元模拟,对比分析了不同蜂窝结构的变形模式和能量吸收特性。结果表明,网状蜂窝结构通过分层坍塌机制和多个塑性铰的协同变形实现了承载能力和吸能效率的显著提高。与同等壁厚的传统六边形蜂窝结构相比,蛛网结构的承载能力提高了221%,比能吸收提高了94%。与相同面积密度的常规六边形蜂窝结构相比,网状蜂窝的比能吸收提高约35%,总能吸收提高93.9%。此外,参数化研究表明,蛛网结构的分层设计参数r(内外蜂窝层边长之比)对塑性铰和平台应力的分布有重要影响。当r在0.4 ~ 0.6范围内时,结构通过反对称屈曲和渐进式折叠变形实现应力分布均匀,并保持较高的承载能力。但当r = 1或r <; 0.4时,结构发生整体屈曲或脆性断裂,吸能性能下降。这项工作为生物启发的分层复合材料开发了一个设计框架,具有定制的能量吸收性能,展示了特定的参数配置,可为航空航天和汽车应用实现卓越的能量吸收。
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Applied Composite Materials
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