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Performance Optimization of Sol-Derived C/Mullite Composites by Reducing the Sintering Shrinkage of Mullite Matrix 通过降低莫来石基体的烧结收缩率优化溶胶法 C/莫来石复合材料的性能
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-04-22 DOI: 10.1007/s10443-024-10227-y
Wei Zhang, Qingsong Ma, Kuanhong Zeng, Weiguo Mao

C/Mullite composites were fabricated through sol impregnation-drying-heating (SIDH) route using the sol with a high solid content in our previous work, and the composites showed desirable performance. However, it was found that thermal stress caused by sintering shrinkage of mullite matrix is one of the main factors leading to the performance regression of the composites. In present study, the sintering characteristic of Al2O3-SiO2 sol was modified to reduce the thermal stress caused by the sintering shrinkage of mullite matrix, optimizing the performance of the composites. The results showed that the sintering shrinkage of mullite matrix was reduced about 25% after heat treatment at 1600ºC by modifying the sintering characteristic of sol, resulting in that the thermal stress caused by sintering shrinkage of mullite matrix was reduced effectively. Therefore, the strength, modulus and fracture work of the composites were increased by about 19.4%, 24.5% and 24.9% to 318.4 MPa, 62.0 GPa and 6958 J/m2, respectively. Furthermore, thermal stability of the composites was also improved obviously in Ar and vacuum environment.

在我们之前的工作中,通过溶胶浸渍-干燥-加热(SIDH)途径,使用高固含量的溶胶制造了碳/莫来石复合材料,复合材料表现出了理想的性能。但研究发现,莫来石基体烧结收缩引起的热应力是导致复合材料性能退步的主要因素之一。本研究改变了 Al2O3-SiO2 溶胶的烧结特性,以降低莫来石基体烧结收缩引起的热应力,优化复合材料的性能。结果表明,通过改变溶胶的烧结特性,莫来石基体在 1600ºC 热处理后的烧结收缩率降低了约 25%,从而有效降低了莫来石基体烧结收缩引起的热应力。因此,复合材料的强度、模量和断裂功分别提高了约 19.4%、24.5% 和 24.9%,达到 318.4 MPa、62.0 GPa 和 6958 J/m2。此外,复合材料在氩气和真空环境下的热稳定性也得到了明显改善。
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引用次数: 0
Correction: Finite Element Analysis and Machine Learning Guided Design of Carbon Fiber Organosheet-Based Battery Enclosures for Crashworthiness 更正:有限元分析和机器学习指导下的碳纤维有机片电池外壳防撞设计
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-04-20 DOI: 10.1007/s10443-024-10228-x
Shadab Anwar Shaikh, M. F. N. Taufique, Kranthi Balusu, Shank S. Kulkarni, Forrest Hale, Jonathan Oleson, Ram Devanathan, Ayoub Soulami
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引用次数: 0
Tensile Creep Performance of PVC Flexible Composites Reinforced With Aramid Warp-Knitted Fabrics From Various Architectures 不同结构芳纶经编织物增强聚氯乙烯柔性复合材料的拉伸蠕变性能
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-04-20 DOI: 10.1007/s10443-024-10226-z
Wenya Yin, Ziyu Zhao, Lifeng Wang, Pibo Ma

This paper aims to investigate the tensile creep behavior of PVC flexible composites reinforced with various aramid warp-knitted fabrics (PCRAWF). The tensile creep test of PCRAWF was conducted and the impact of various tissue structure reinforcements on the viscoelastic behavior of PCRAWF was also discussed. Dynamic mechanical analysis (DMA) tests were conducted on PCRAWF to explore the effect of temperature on the creep strain and creep recovery properties of PCRAWF. The variation in viscoelastic properties of PCRAWF with temperature was analyzed. The decomposition behavior of aramid fibers and PVC resins in a nitrogen (N2) atmosphere was analyzed using thermogravimetric analysis (TGA). The experimental results showed that as the density of the reinforcing fabric increases, the creep strain of the corresponding PCRAWF decreases. The amount of creep strain increases as the loading force increases, and the rate of increase gradually decreases. The creep strain of PCRAWF increases as the temperature rises, and the creep recovery decreases with increasing temperature. The creep strain increases by approximately 0.4–1.6% as the temperature rises from 30 °C to 60 °C, and by about 0.2–0.6% as the temperature increases from 60 °C to 90 °C. The TGA results analyzed the thermal degradation temperatures of aramid fiber and PVC composites in N2 to reach 680 °C and 480 °C, respectively. The characterization of tensile creep behavior has significant potential for predicting the long-term performance of fabric-reinforced polyvinyl chloride flexible composites. Based on the experimental results of the creep of PCRAWF, the constitutive Kelvin-Maxwell model was used to establish the constitutive equations with the experimental data for numerical simulation.

本文旨在研究用各种芳纶经编织物(PCRAWF)增强的聚氯乙烯柔性复合材料的拉伸蠕变行为。本文对 PCRAWF 进行了拉伸蠕变试验,并讨论了各种组织结构增强材料对 PCRAWF 粘弹行为的影响。对 PCRAWF 进行了动态力学分析(DMA)测试,以探讨温度对 PCRAWF 的蠕变应变和蠕变恢复特性的影响。分析了 PCRAWF 的粘弹性能随温度的变化。使用热重分析法(TGA)分析了芳纶纤维和聚氯乙烯树脂在氮气(N2)环境中的分解行为。实验结果表明,随着增强织物密度的增加,相应 PCRAWF 的蠕变应变降低。蠕变应变的量随着加载力的增加而增加,增加的速度逐渐减小。PCRAWF 的蠕变应变随温度升高而增大,蠕变恢复随温度升高而减小。温度从 30 °C 升至 60 °C 时,蠕变应变增加约 0.4-1.6%;温度从 60 °C 升至 90 °C 时,蠕变应变增加约 0.2-0.6%。TGA 结果分析了芳纶纤维和聚氯乙烯复合材料在 N2 中的热降解温度,分别达到 680 ℃ 和 480 ℃。拉伸蠕变行为的表征对于预测织物增强聚氯乙烯柔性复合材料的长期性能具有重要潜力。在 PCRAWF 蠕变实验结果的基础上,采用 Kelvin-Maxwell 构成模型建立了与实验数据相关的构成方程,并进行了数值模拟。
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引用次数: 0
Enhancing the Robustness of Hybrid Metal-Composite Connections Through 3D Printed Micro Penetrative Anchors 通过 3D 打印微型穿透性锚固件增强金属-复合材料混合连接的坚固性
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-04-13 DOI: 10.1007/s10443-024-10224-1
Luca Raimondi, Luca Tomesani, Andrea Zucchelli

This work proposes a novel solution for manufacturing hybrid metal-composite joints, in which different pin shapes are evaluated for their capability to penetrate long carbon fiber epoxy composites successfully and for the mechanical behavior determined by each configuration. On the metal side, pins are manufactured by Laser Powder Bed Fusion (LPBF), downsizing the currently adopted solutions and, at the same time, developing new blocking features aimed at enhancing the mechanical properties of the joint. The different configurations were evaluated in two distinct experiments: the first to evaluate the induced defects in the composite substrate and the second to characterize the mechanical behavior of the joint. It emerges that smaller pins produce much less damage and misalignments in the composite structure with respect to the conventional pin solution, whereas the new “blocking features” configurations consistently increase maximum pullout load and energy with respect to the conventional pin solution, with the same level of fiber damage.

这项研究提出了一种制造金属-复合材料混合接头的新型解决方案,其中对不同形状的销钉进行了评估,以确定它们能否成功穿透长碳纤维环氧复合材料,以及每种配置所决定的机械性能。在金属方面,销钉是通过激光粉末床熔融(LPBF)制造的,缩小了目前采用的解决方案的尺寸,同时还开发了新的阻塞功能,旨在提高接头的机械性能。在两项不同的实验中对不同的配置进行了评估:第一项实验评估了复合材料基材中的诱导缺陷,第二项实验确定了接头的机械性能。结果表明,与传统的销钉解决方案相比,较小的销钉在复合材料结构中产生的损坏和错位要少得多,而与传统的销钉解决方案相比,在纤维损坏程度相同的情况下,新的 "阻塞特征 "配置持续增加了最大拉拔载荷和能量。
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引用次数: 0
The Relationship Between the Extent of Indentation and Impact Damage in Carbon-Fibre Reinforced-Plastic Composites after a Low-Velocity Impact 低速冲击后碳纤维增强塑料复合材料的压痕程度与冲击损伤之间的关系
IF 2.3 4区 材料科学 Q2 Materials Science Pub Date : 2024-04-03 DOI: 10.1007/s10443-024-10223-2
R. A. Brooks, J. Liu, Z. E. C. Hall, A. M. Joesbury, L. T. Harper, H. Liu, A. J. Kinloch, J. P. Dear

The present paper investigates the low-velocity impact behaviour of carbon-fibre reinforced-plastic (CFRP) composite panels and the damage incurred when they are subjected to a single impact. The relationship between the depth of permanent surface indentation that results and the associated area of interlaminar delamination damage is investigated for two different thicknesses of composite panels. In particular, the delamination damage area increases with impact energy for both thicknesses of composite panel that were studied. Likewise, the indentation depth also increases with increasing impact energy, again for both thicknesses of CFRP panels. It is shown that the indentation depth, at the centre of the indentation, may be used to provide an indication of the extent of delamination damage within the CFRP panel after impact. Indeed, from plotting the indentation depth versus the interlaminar delamination normalised by the thickness of the panel area there is shown to be a unique ‘master’ relationship, with a positive intercept indicating that the indentation damage seems to result before delamination damage initiates. Thus, for both thicknesses of CFRP panels, it is suggested that the indentation process is a precursor to interlaminar delamination damage.

本文研究了碳纤维增强塑料(CFRP)复合材料板的低速冲击行为以及在受到单次冲击时产生的损伤。针对两种不同厚度的复合板,研究了造成的永久性表面压痕深度与相关层间分层损伤面积之间的关系。特别是,对于所研究的两种厚度的复合板,分层损伤面积都会随着冲击能量的增加而增大。同样,对于两种厚度的 CFRP 面板,压痕深度也随着冲击能量的增加而增加。研究表明,压痕中心的压痕深度可用于指示 CFRP 面板在受到冲击后的分层损坏程度。事实上,通过绘制压痕深度与层间分层的关系曲线(以板材厚度为标准),可以发现两者之间存在一种独特的 "主 "关系,正截距表明压痕损坏似乎在分层损坏开始之前就已产生。因此,对于两种厚度的 CFRP 面板而言,压痕过程都是层间分层损坏的前兆。
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引用次数: 0
Finite Element Analysis and Machine Learning Guided Design of Carbon Fiber Organosheet-Based Battery Enclosures for Crashworthiness 有限元分析和机器学习指导下的碳纤维有机板电池外壳防撞设计
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-04-01 DOI: 10.1007/s10443-024-10218-z
Shadab Anwar Shaikh, M. F. N. Taufique, Kranthi Balusu, Shank S. Kulkarni, Forrest Hale, Jonathan Oleson, Ram Devanathan, Ayoub Soulami

Carbon fiber composite can be a potential candidate for replacing metal-based battery enclosures of current electric vehicles (E.V.s) owing to its better strength-to-weight ratio and corrosion resistance. However, the strength of carbon fiber-based structures depends on several parameters that should be carefully chosen. In this work, we implemented high throughput finite element analysis (FEA) based thermoforming simulation to virtually manufacture the battery enclosure using different design and processing parameters. Subsequently, we performed virtual crash simulations to mimic a side pole crash to evaluate the crashworthiness of the battery enclosures. This high throughput crash simulation dataset was utilized to build predictive models to understand the crashworthiness of an unknown set. Our machine learning (ML) models showed excellent performance (R2 > 0.97) in predicting the crashworthiness metrics, i.e., crush load efficiency, absorbed energy, intrusion, and maximum deceleration during a crash. We believe that this FEA-ML work framework will be helpful in down select process parameters for carbon fiber-based component design and can be transferrable to other manufacturing technologies.

摘要 由于碳纤维复合材料具有更好的强度重量比和耐腐蚀性,因此有可能取代目前电动汽车(E.V.s)的金属电池外壳。然而,碳纤维基结构的强度取决于几个参数,需要仔细选择。在这项工作中,我们实施了基于高通量有限元分析(FEA)的热成型模拟,利用不同的设计和加工参数虚拟制造电池外壳。随后,我们进行了虚拟碰撞模拟,模拟侧杆碰撞,以评估电池外壳的耐撞性。我们利用这一高通量碰撞模拟数据集建立预测模型,以了解未知组件的耐撞性。我们的机器学习(ML)模型在预测耐撞性指标(即碰撞负载效率、吸收能量、侵入和碰撞过程中的最大减速度)方面表现出色(R2 > 0.97)。我们相信,这一有限元分析-线性回归工作框架将有助于碳纤维部件设计的工艺参数选择,并可应用于其他制造技术。
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引用次数: 0
Retained Hygrothermal State Compression Damage Behavior Investigation of Carbon Fiber Reinforced Composites 碳纤维增强复合材料的滞留热态压缩损伤行为研究
IF 2.3 4区 材料科学 Q2 Materials Science Pub Date : 2024-04-01 DOI: 10.1007/s10443-024-10225-0
Haodong Huo, Jingchao Wei, Yong Cao, Wenzhi Wang, Zhihua Wang

This paper establishes a composite material damage analysis strategy that retains the hygrothermal state to investigate the damage behavior and mechanical performance characteristics of composite materials in hygrothermal environments. Initially, mass diffusion and heat conduction are equivalently considered, and a hygrothermal state predefined model is developed using a combination of sequential and fully coupled approaches. Then the hygrothermal stress field is extracted as the initial state of the compression process, and a compression progressive damage analysis is conducted using the VUMAT subroutine. Additionally, the accelerated hygrothermal aging experiments are conducted to investigate moisture absorption behavior and moisture diffusion coefficients. Then the quasi-static compression tests are carried out on the specimens before and after aging, with failure processes recorded using Digital Image Correlation (DIC). Experimental and simulation results reveal that hygrothermal conditions lead to matrix cracking and debonding from the fiber surface, generating an uneven stress field internally. This results in earlier occurrence and increased severity of delamination during the compression process. The dominant failure modes include wedge splitting and longitudinal cracking. The compressive strength, failure strain, and elastic modulus of the specimens decrease after aging. The analysis strategy developed in this paper effectively reflects the hygrothermal state during compression, aligning more closely with the actual physical processes.

本文建立了一种保留湿热状态的复合材料损伤分析策略,以研究复合材料在湿热环境下的损伤行为和机械性能特征。首先,等效考虑质量扩散和热传导,并采用顺序和完全耦合相结合的方法建立湿热状态预定义模型。然后提取湿热应力场作为压缩过程的初始状态,并使用 VUMAT 子程序进行压缩渐进损伤分析。此外,还进行了加速湿热老化实验,以研究吸湿行为和湿气扩散系数。然后对老化前后的试样进行准静态压缩试验,并使用数字图像相关技术(DIC)记录破坏过程。实验和模拟结果表明,湿热条件会导致基体开裂和与纤维表面脱粘,从而在内部产生不均匀的应力场。这导致在压缩过程中更早出现分层现象,并增加了分层的严重程度。主要的破坏模式包括楔形劈裂和纵向开裂。试样的抗压强度、破坏应变和弹性模量在老化后都会降低。本文开发的分析策略有效地反映了压缩过程中的湿热状态,更加贴近实际物理过程。
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引用次数: 0
Investigating the Effects of Contact Area and Chamfering on the Failure Behavior of Plain Woven Composite-Metal T-joints 研究接触面积和倒角对平纹编织复合材料-金属 T 型接头失效行为的影响
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-03-20 DOI: 10.1007/s10443-024-10220-5
Qi Zhang, Zhangjie Yu, Deng’an Cai, Guangming Zhou

This paper experimentally and numerically investigates the failure behavior of plain woven composite-metal connection structures (T-joints) under loads in different directions. According to the direction of load application, it can be divided into TX specimens and TZ specimens. Wherein, TX and TZ are subjected to the tensile load parallel and perpendicular to the composite panel, respectively. Test results show significant differences in the ultimate load, failure modes and strain distribution among different specimens. Increasing the contact area between the lower block and the composite panel and adding round to the contact part between the metal part and the composite panel can improve the load-carrying capacity of the T-joints. The multiscale simulation is conducted to study the failure process of T-joints. Micro-scale and meso-scale models are established to obtain the mechanical properties of the plain woven composite, and the error between the simulated results and the experimental data is less than 10%. Progressive damage analysis is then done by using the macro-scale model. The simulated failure load and damage process of T-joints are consistent with the test results. The information and proposed multiscale analysis method on the failure behavior of T-joints are useful for the optimal design of similar structures.

摘要 本文通过实验和数值计算研究了平织复合材料-金属连接结构(T 型接头)在不同方向荷载作用下的破坏行为。根据施加载荷的方向,可分为 TX 试样和 TZ 试样。其中,TX 和 TZ 分别承受平行于复合板和垂直于复合板的拉伸载荷。试验结果表明,不同试样的极限载荷、破坏模式和应变分布存在明显差异。增大下块与复合材料面板的接触面积以及在金属部分与复合材料面板的接触部分增加圆形,可以提高 T 型接头的承载能力。为研究 T 型接头的失效过程,进行了多尺度模拟。通过建立微观尺度和中观尺度模型来获得平织复合材料的力学性能,模拟结果与实验数据的误差小于 10%。然后利用宏观尺度模型进行渐进损伤分析。T 型接头的模拟破坏载荷和破坏过程与试验结果一致。有关 T 型接头破坏行为的信息和所提出的多尺度分析方法有助于类似结构的优化设计。
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引用次数: 0
Effect of Bricks-and-Mortar Architecture on Fracture Behavior of SiCp/Al Composite: A Finite Element Analysis 砖臼结构对 SiCp/Al 复合材料断裂行为的影响:有限元分析
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-03-19 DOI: 10.1007/s10443-024-10221-4
Xiang Gao, Xiaonan Lu, Xuexi Zhang, Mingfang Qian, Aibin Li, Huan Wang, Cheng Liu, Bowen Gong, Wenting Ouyang, Hua-Xin Peng

The metal-matrix composites (MMCs) with biomimetic bricks-and-mortar architectures have been experimentally demonstrated to exhibit excellent strength-ductility match. Here, biomimetic bricks-and-mortar architecture mimicking masonry bonds was introduced in numerical models. By translating perpendicular layers on stack bond model, 1/2 running and running bond models were established. The results reveal that elongation of running bond model is the highest (4.77%), which is ∼ 1.5 times as that of stack type model. The strength of these models is similar (330 ± 1 MPa). However, it is the trade-off between load bearing capacity and fracture of SiC particles. In the stack bond model, over a small junction layer area led to a relatively straight crack path and thus lower elongation. On the contrary, running bond model shows a zigzag main crack. So, the main crack deflects frequently with high energy consumption. Furthermore, crack deflection into matrix cell increases propagation resistance, leading to the highest elongation in the running bond model. Therefore, the biomimetic bricks-and-mortar architecture delays and deflects main crack propagation. These findings have significant implication for the architecture design of advanced composite materials.

实验证明,具有仿生砖-砂浆结构的金属基复合材料(MMC)具有优异的强度-电导率匹配性能。在此,我们在数值模型中引入了模拟砖石结构的仿生砖石结构。通过在叠层粘结模型上平移垂直层,建立了 1/2 运行和运行粘结模型。结果表明,流水粘结模型的伸长率最高(4.77%),是叠合模型的 1.5 倍。这些模型的强度相似(330 ± 1 兆帕)。然而,这需要在承载能力和碳化硅颗粒断裂之间做出权衡。在堆栈结合模型中,在较小的接合层面积上,裂纹路径相对较直,因此伸长率较低。相反,运行结合模型则显示出 "之 "字形主裂纹。因此,主裂纹偏转频繁,能量消耗高。此外,裂纹偏转到基质细胞中会增加传播阻力,从而导致运行粘结模型的伸长率最高。因此,仿生砖-砂浆结构延迟并偏转了主裂纹的扩展。这些发现对先进复合材料的结构设计具有重要意义。
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引用次数: 0
Design, Manufacture, and Cryogenic Testing of a Linerless Composite Tank for Liquid Hydrogen 无衬里液氢复合罐的设计、制造和低温测试
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-03-18 DOI: 10.1007/s10443-024-10219-y
Robin Olsson, Christopher Cameron, Florence Moreau, Erik Marklund, Matthias Merzkirch, Jocke Pettersson

This paper describes design, manufacture, and testing of a linerless composite vessel for liquid hydrogen, having 0.3 m diameter and 0.9 m length. The vessel consists of a composite cylinder manufactured by wet filament winding of thin-ply composite bands, bonded to titanium end caps produced by additive manufacturing. The aim was to demonstrate the linerless design concept with a thin-ply composite for the cylinder. The investigation is limited to the internal pressure vessel, while real cryogenic tanks also involve an outer vessel containing vacuum for thermal insulation. Thermal stresses dominate during normal operation (4 bar) and the layup was selected for equal hoop strains in the composite cylinder and end caps during filling with liquid hydrogen. Two vessels were tested in 20 cycles, by filling and emptying with liquid nitrogen to 4 bar, without signs of damage or leakage. Subsequently, one vessel was tested until burst at almost 30 bar.

摘要 本文介绍了一个直径 0.3 米、长度 0.9 米的无内衬液氢复合容器的设计、制造和测试。该容器由一个复合材料圆筒组成,圆筒通过湿法缠绕薄层复合材料带制造而成,并与增材制造的钛合金端盖粘接在一起。其目的是展示使用薄层复合材料制造圆筒的无衬垫设计理念。调查仅限于内部压力容器,而真正的低温罐还包括一个用于隔热的真空外容器。在正常运行期间(4 巴),热应力占主导地位,在充填液氢时,复合材料筒体和端盖的环向应变相等,因此选择了这种铺层方式。对两个容器进行了 20 次循环测试,即充入和排空液氮至 4 巴,未发现损坏或泄漏迹象。随后,一个容器在接近 30 巴的压力下测试至爆裂。
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引用次数: 0
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Applied Composite Materials
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