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Feasibility of coaxial deep borehole heat exchangers in southern California 加利福尼亚南部同轴深孔热交换器的可行性
IF 2.9 2区 地球科学 Q3 ENERGY & FUELS Pub Date : 2024-11-01 DOI: 10.1186/s40517-024-00319-0
Haohua Chen, Ingrid Tomac

This paper investigates the feasibility of coaxial deep borehole heat exchanger (CDBHE) applications to the University of California San Diego (UCSD) campus. By collecting different geophysical source data for various formations and well logs around the UCSD campus, a multilayered thermophysical model for the ground on the site is established. Water circulation within a closed coaxial loop system considers the geothermal energy extraction under uncertainty consideration of the unknown deeper layers heat flow gradient as coupled with the variation of pipe insulation properties, flow rates, outer pipe diameter, grout, and depths between 1 and 4 km. A finite-element framework models the Navier–Stokes fluid flow and heat transfer in the CDBHE system, validated with a field test on CDBHE from the literature. Results show that a 4-km CDBHE could produce a thermal power of 600 kW under the optimum geological conditions at the UCSD site: the water flow rate of 2.78 L/s and a ground thermal gradient of 60 ℃/km. Thermal power shares from different layers indicate that deeper formation layers contribute more to the thermal power than the shallower layers because increasing the CDBHE length from 1 to 4 km can lead to a maximum of 900% increase in thermal power and a 50% expansion in thermal plume for a CDBHE with an insulated inner pipe between the upper and lower bound heat flow bounds. An inner pipe with an insulated depth of 2 km produces only 1–6% less power than a fully insulated inner pipe for the 4-km CDBHE, and thus, a partially insulated vacuum-insulated tube (VIT)-plastic inner pipe is suggested as the best practice. Furthermore, the CDBHE thermal power increases by 5% when the grout thermal conductivity increases from 1 to 3.65 W/(K∙m), close to the formation thermal conductivity, and then maintains almost the same, and the 4-km CDBHE with flow rates of 2.78–6.94 L/s at the UCSD site can directly supply a low-temperature heating radiator system for room heating. This study suggests practical ranges for geothermal energy extraction for southern California. A CDBHE with a well-insulated inner pipe of 0.05 W/(m∙K), the thermal power of lower and upper-bound heat flow cases can vary by 60% from the mean. Finally, water as the working fluid is more efficient than CO2, doubling CDBHE's thermal power. The effects of the investigated factors provide guidelines for future geothermal resource exploitation in southern California.

本文研究了将同轴深孔热交换器(CDBHE)应用于加州大学圣地亚哥分校(UCSD)校园的可行性。通过收集加州大学圣地亚哥分校校园周围各种地层的不同地球物理源数据和测井记录,建立了该校区地面的多层热物理模型。在一个封闭的同轴环路系统中的水循环考虑了地热能源的提取,考虑了未知深层热流梯度的不确定性,以及管道隔热性能、流速、外管直径、灌浆和 1 至 4 千米深度的变化。有限元框架模拟了 CDBHE 系统中的纳维-斯托克斯流体流动和传热,并通过文献中的 CDBHE 现场测试进行了验证。结果表明,在加州大学旧金山分校的最佳地质条件下,4 千米 CDBHE 可产生 600 千瓦的热功率:水流量为 2.78 升/秒,地面热梯度为 60 ℃/千米。来自不同地层的热功率份额表明,较深地层比较浅层对热功率的贡献更大,因为将 CDBHE 长度从 1 km 增加到 4 km 最多可导致热功率增加 900%,在上下限热流边界之间带有隔热内管的 CDBHE 的热羽流扩大 50%。对于 4 千米长的 CDBHE,保温深度为 2 千米的内管所产生的功率仅比完全保温的内管低 1-6%,因此建议采用部分保温的真空保温管(VIT)-塑料内管作为最佳做法。此外,当注浆导热系数从 1 增加到 3.65 W/(K∙m)(接近地层导热系数)时,CDBHE 的热功率会增加 5%,然后几乎保持不变,在加州大学旧金山校区,4 千米 CDBHE 的流速为 2.78-6.94 L/s,可直接为室内供暖的低温暖气散热器系统供热。这项研究提出了南加州地热能源提取的实用范围。CDBHE 的内管隔热性能为 0.05 W/(m∙K),下限和上限热流情况下的热功率可与平均值相差 60%。最后,水作为工作流体比二氧化碳更有效,可将 CDBHE 的热功率提高一倍。所研究因素的影响为南加州未来的地热资源开发提供了指导。
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引用次数: 0
Controls of low injectivity caused by interaction of reservoir and clogging processes in a sedimentary geothermal aquifer (Mezőberény, Hungary) 沉积地热含水层中储层与堵塞过程相互作用导致的低注入率控制因素(匈牙利 Mezőberény)
IF 2.9 2区 地球科学 Q3 ENERGY & FUELS Pub Date : 2024-10-22 DOI: 10.1186/s40517-024-00317-2
Ábel Markó, Maren Brehme, Daniele Pedretti, Günter Zimmermann, Ernst Huenges

Low injectivity is often experienced in geothermal doublets installed in sandstone reservoirs. This even led to a shutdown of the Mezőberény (Hungary) geothermal site. An on-site campaign was carried out in January 2021 to prepare a stimulation aiming to enhance the transmissivity of the sedimentary reservoir and the near-wellbore zone of this site. Previous studies have concluded that insufficient injectivity may be linked to a high skin effect in the near well-bore zone and pore clogging in combination with the low net sandstone content of the fluvio-deltaic reservoir. A chemical soft stimulation based on the injection of hydrochloric acid (HCl) was successfully used to unclog and recover the well injectivity. Despite such empirical evidence, the geochemical mechanisms leading to both, detrimental formation of clogging and the HCl-driven transmissivity restoration, have not yet been elucidated. This work presents the results of a novel analysis aiming at (a) predicting the dominant type of clogging forming in the near-well bore zone; (b) quantifying the drop in hydraulic conductivity as clogging occurs; and (c) supporting the optimization of the HCl dosage during the chemical soft stimulation. The study is supported by new experimental datasets never presented before from the Mezőberény site and a geochemical model set-up simulating the main mechanisms involved in the clogging and unclogging processes. It is concluded that the biofilm formation was the dominant, while the precipitation of calcite and amorphous ferrihydrite—later reduced to magnetite by microbes—was the secondary clogging mechanism: In the long-term (yearly scale) simulating the hydraulic conductivity showed a decline with forming scales; therefore, biofilm was presumably responsible for the experienced rapid (1 month) clogging. When modelling the chemical stimulation, the estimated amount of precipitated minerals was dissolved already with 2.5 mol of HCl per liter of water (~ 10 m/m%). Therefore, the 20 m/m% of HCl chosen during the field campaign might had a beneficial effect dissolving the potentially higher amount of scaling and/or the carbonate minerals of the matrix near the wellbore. Overall, it is concluded that the chemical and the microbial analyses together with the geochemical model were critical to tailor the remediation attempts and to propose further development or reconstruction of the surface system before going into operation to prevent recurrent impairments. Our findings highlight the importance of interactions of various clogging mechanisms with each other as well as with the reservoir processes and provide approaches to tackle the issue of injectivity drop by characterizing and quantifying their effects.

安装在砂岩储层中的地热双层机组经常出现注入率低的问题。这甚至导致 Mezőberény(匈牙利)地热场停工。2021 年 1 月开展了一次现场活动,准备采取一种旨在提高沉积储层和该站点近井筒区域渗透率的激励措施。先前的研究得出结论,注入率不足可能与近井口区的高集肤效应和孔隙堵塞以及荧光三角洲储层的低净砂岩含量有关。以注入盐酸(HCl)为基础的化学软刺激成功地疏通并恢复了油井的注入率。尽管有这些经验证据,但导致有害堵塞形成和盐酸驱动渗透率恢复的地球化学机制尚未阐明。本研究介绍了一种新型分析方法的结果,该方法旨在:(a)预测近井孔区形成的主要堵塞类型;(b)量化堵塞发生时水力传导性的下降;以及(c)为化学软刺激过程中盐酸用量的优化提供支持。这项研究得到了 Mezőberény 油田前所未有的新实验数据集以及模拟堵塞和疏通过程主要机制的地球化学模型的支持。结果表明,生物膜的形成是主要的堵塞机制,而方解石和无定形铁水石的沉淀--后来被微生物还原成磁铁矿--则是次要的堵塞机制:在长期(年尺度)模拟中,水力传导率随着形成尺度的增加而下降;因此,生物膜可能是造成经历过的快速(1 个月)堵塞的原因。在模拟化学刺激时,每升水中 2.5 摩尔盐酸(约 10 m/m%)已溶解了估计数量的沉淀矿物质。因此,在现场试验中选择 20 m/m% 的盐酸可能会对溶解井筒附近基质中可能存在的更多结垢和/或碳酸盐矿物产生有利影响。总之,结论是化学和微生物分析以及地球化学模型对于调整修复尝试以及在投入运行前建议进一步开发或重建地表系统以防止再次发生损害至关重要。我们的研究结果强调了各种堵塞机制之间以及与储层过程之间相互作用的重要性,并提供了通过描述和量化其影响来解决注入率下降问题的方法。
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引用次数: 0
Density of pure and mixed NaCl and CaCl2 aqueous solutions at 293 K to 353 K and 0.1 MPa: an integrated comparison of analytical and numerical data 在 293 K 至 353 K 和 0.1 MPa 条件下纯 NaCl 和 CaCl2 混合水溶液的密度:分析数据与数值数据的综合比较
IF 2.9 2区 地球科学 Q3 ENERGY & FUELS Pub Date : 2024-10-19 DOI: 10.1186/s40517-024-00318-1
Ulrike Hoffert, Laurent André, Guido Blöcher, Sylvain Guignot, Arnault Lassin, Harald Milsch, Ingo Sass

This study reports on newly acquired density data of synthetically prepared pure and mixed NaCl and CaCl2 aqueous solutions that span a wide range of geothermally encountered concentrations and mixing ratios. The analytical data are provided for the temperature range of 293–353 K at ambient pressure. For the reproduction of that data, PHREESCALE was used. The predictive potential of this numerical tool regarding the density of geothermal fluids of known composition was the major target herein. As a result, the measured data are in good agreement with previous analytical studies found in the literature. Possible sources of errors are discussed in this paper. Density data of the mixed solutions at temperatures other than ambient are unique and close existing data gaps. The numerical model reproduces the newly measured and already existing density data within an error band of approximately 1%. For further use in geothermal applications, this can be considered an excellent agreement. Moreover, the model yields a direct calculation of density without the need to establish complex empirical equations of state and mixing rules. Finally, sensitivity calculations performed with a thermal–hydraulic (TH) numerical reservoir model demonstrate the required accuracy of fluid density for reliably predicting the long-term performance of deep geothermal energy systems. In terms of the productivity index and the timing of thermal breakthrough it shows that the present analytical and numerical uncertainty in density is small enough to reliably state both reservoir parameters.

本研究报告了新近获得的合成制备的纯净和混合氯化钠和氯化钙水溶液的密度数据,这些溶液的浓度和混合比在地热作用下的范围很广。提供的分析数据是在环境压力下的 293-353 K 温度范围内的数据。为了再现这些数据,使用了 PHREESCALE。该数值工具对已知成分的地热流体密度的预测潜力是本文的主要目标。因此,测量数据与之前文献中的分析研究结果非常吻合。本文讨论了可能的误差来源。非环境温度下混合溶液的密度数据是独一无二的,填补了现有数据空白。数值模型再现了新测量的和已有的密度数据,误差范围约为 1%。对于地热应用的进一步使用,这可以被视为极佳的一致性。此外,该模型可直接计算密度,而无需建立复杂的经验状态方程和混合规则。最后,利用热-水力(TH)数值储层模型进行的敏感性计算表明,流体密度的精确性是可靠预测深层地热能源系统长期性能所必需的。就生产力指数和热突破时间而言,它表明目前密度的分析和数值不确定性很小,足以可靠地说明这两个储层参数。
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引用次数: 0
Modeling unobserved geothermal structures using a physics-informed neural network with transfer learning of prior knowledge 利用具有先验知识迁移学习功能的物理信息神经网络为未观测到的地热结构建模
IF 2.9 2区 地球科学 Q3 ENERGY & FUELS Pub Date : 2024-10-08 DOI: 10.1186/s40517-024-00312-7
Akihiro Shima, Kazuya Ishitsuka, Weiren Lin, Elvar K. Bjarkason, Anna Suzuki

Deep learning has gained attention as a potentially powerful technique for modeling natural-state geothermal systems; however, its physical validity and prediction inaccuracy at extrapolation ranges are limiting. This study proposes the use of transfer learning in physics-informed neural networks to leverage prior expert knowledge at the target site and satisfy conservation laws for predicting natural-state quantities such as temperature, pressure, and permeability. A neural network pre-trained with multiple numerical datasets of natural-state geothermal systems was generated using numerical reservoir simulations based on uncertainties of the permeabilities, sizes, and locations of geological units. Observed well logs were then used for tuning by transfer learning of the network. Two synthetic datasets were examined using the proposed framework. Our results demonstrate that the use of transfer learning significantly improves the prediction accuracy in extrapolation regions with no observed wells.

深度学习作为一种对自然态地热系统进行建模的潜在强大技术,受到了广泛关注;然而,其物理有效性和外推范围的预测不准确性却受到了限制。本研究提出在物理信息神经网络中使用迁移学习,以利用目标地点的先验专家知识,并满足预测温度、压力和渗透率等自然状态量的守恒定律。根据地质单元的渗透率、大小和位置的不确定性,利用数值储层模拟生成了一个神经网络,该网络使用多个自然状态地热系统的数值数据集进行预训练。然后,通过网络的迁移学习,利用观测到的测井记录进行调整。使用所提出的框架对两个合成数据集进行了检验。结果表明,在没有观测井的外推法区域,使用迁移学习可以显著提高预测精度。
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引用次数: 0
Methods of grout quality measurement in borehole exchangers for heat pumps and their rehabilitation 热泵井孔交换器灌浆质量测量方法及其修复
IF 2.9 2区 地球科学 Q3 ENERGY & FUELS Pub Date : 2024-10-06 DOI: 10.1186/s40517-024-00313-6
Petr Nakládal, Martin Procházka, Viktor Goliáš, Jaromíra Hrdá

Methods and instrumentation for measuring grout quality in heat pump boreholes, including the measurement of groundwater flow through boreholes outside partly grouted borehole exchanger pipes, have been developed in the Czech Republic. A Semtex charge has also been developed to repair rock massifs, which reliably disconnects borehole exchanger pipes without severely harming the surrounding rock environment or buildings. The resulting hole can then be used for regrouting, thus preventing undesirable vertical water flow through the borehole.

捷克共和国开发了测量热泵钻孔灌浆质量的方法和仪器,包括测量部分灌浆钻孔交换管道外的地下水流经钻孔的情况。此外,还开发了一种用于修复岩层的 Semtex 装药,它可以可靠地断开井眼交换管道,而不会对周围的岩石环境或建筑物造成严重损害。由此产生的孔洞可用于重新灌浆,从而防止孔洞中出现不可取的垂直水流。
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引用次数: 0
Geothermal resources in Latin-America and their exploration using electromagnetic methods 拉丁美洲地热资源及其电磁勘探方法
IF 2.9 2区 地球科学 Q3 ENERGY & FUELS Pub Date : 2024-09-28 DOI: 10.1186/s40517-024-00314-5
Octavio Castillo-Reyes, Rosa María Prol-Ledesma, Fernando Corbo-Camargo, Otilio Rojas

The global priority for sustainable societies drives the transition to green energy, with geothermal power as a promising alternative. Latin-American countries benefit from the active volcanism along the Pacific Rim, which fuels their significant geothermal potential. Geothermal electricity production in the region is steadily growing and currently represents approximately (11%) of global output (16 GW). This paper provides details on the installed capacity of electrical generation in the most geothermally significant Latin-American countries, as well as the estimated potential production from existing prospects in the region. We also discuss the multiple challenges that limit the widespread development and exploitation of this valuable resource in Latin-America. As México stands as the top electricity producer in the region and ranks sixth worldwide, we offer an overview of its geothermal potential, the use of electromagnetic imaging technologies to enhance Mexican geothermal resource exploration, and the challenges and limitations associated with traditional exploration techniques. Additionally, we present recent case studies on the combined use of these technologies in México, highlighting best practices and lessons learned. The paper identifies open questions and outlines future research directions, particularly in México, to unlock the geothermal potential of the entire region.

全球对可持续发展社会的重视推动了向绿色能源的过渡,而地热发电是一种前景广阔的替代能源。拉丁美洲国家受益于太平洋沿岸的活火山活动,这激发了其巨大的地热潜力。该地区的地热发电量正在稳步增长,目前约占全球发电量(16 GW)的 11%。本文详细介绍了地热发电量最大的拉美国家的发电装机容量,以及该地区现有勘探区的估计潜在发电量。我们还讨论了限制拉丁美洲广泛开发利用这一宝贵资源的多重挑战。墨西哥是该地区最大的发电国,在全球排名第六,因此我们概述了墨西哥的地热潜力、利用电磁成像技术加强墨西哥地热资源勘探的情况,以及传统勘探技术面临的挑战和局限性。此外,我们还介绍了最近在墨西哥综合利用这些技术的案例研究,重点介绍了最佳实践和经验教训。本文指出了一些开放性问题,并概述了未来的研究方向,特别是在墨西哥,以发掘整个地区的地热潜力。
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引用次数: 0
Repurposing idle wells in the North German Basin as deep borehole heat exchangers 将北德意志盆地的闲置水井重新用作深井热交换器
IF 2.9 2区 地球科学 Q3 ENERGY & FUELS Pub Date : 2024-09-28 DOI: 10.1186/s40517-024-00315-4
Nora Koltzer, Johannes Schoenherr, Maximilian Sporleder, Jan Niederau, Florian Wellmann

This study investigates the feasibility to repurpose wells from gas production for geothermal closed-loop application in the North German Basin (NGB). The objective for this research topic is to extend the value-added chain of idle wells by re-completion as coaxial deep borehole heat exchangers as an efficient way to produce green energy without drilling new wells by saving the carbon emission and costs of building a new geothermal well. With numerical models of two typical geological settings of the NGB and two different completion schemes, it is possible to simulate the thermal performance over a lifetime of 30 years. The calculated heat extraction rates range from 200 to 400 kW, with maximum values of up to 600 kW. Sensitivity analyses demonstrate that re-completion depth and injection temperature are the most sensitive parameters of thermal output determination. The heat demand around the boreholes is mapped, and heat generation costs are calculated with heating network simulations. The initial production costs for heat are comparable to other renewable energy resources like biomass and competitive against gas prices in 2022. This study highlights available geothermal resources’ environmental and economic potential in already installed wells. The application has almost no geological and no drilling risks and may be installed at any idle well location.

本研究调查了在北德盆地(NGB)将天然气生产井重新用于地热闭环应用的可行性。该研究课题的目标是通过重新完井作为同轴深井热交换器来延长闲置井的增值链,从而节省碳排放和建造新地热井的成本,作为一种不钻新井而生产绿色能源的有效方法。利用 NGB 两种典型地质环境的数值模型和两种不同的完井方案,可以模拟 30 年使用寿命内的热性能。计算得出的热提取率为 200 至 400 千瓦,最大值可达 600 千瓦。敏感性分析表明,再完井深度和注入温度是确定热输出的最敏感参数。绘制了钻孔周围的热需求图,并通过供热网络模拟计算了制热成本。热量的初始生产成本与生物质能等其他可再生能源相当,与 2022 年的天然气价格相比具有竞争力。这项研究强调了已安装水井中可用地热资源的环境和经济潜力。该应用几乎没有地质风险和钻井风险,可安装在任何闲置的井位。
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引用次数: 0
Determination of thermal properties of grouting materials for borehole heat exchangers (BHE) 测定井眼热交换器(BHE)灌浆材料的热性能
IF 2.9 2区 地球科学 Q3 ENERGY & FUELS Pub Date : 2024-09-28 DOI: 10.1186/s40517-024-00316-3
Anna Albers, Petra Huttenloch, Roman Zorn, Hagen Steger, Philipp Blum

Thermal properties of grouting materials for borehole heat exchangers (BHE) are currently analysed with varying measurement methods and analysis procedures, resulting in difficulties when comparing values of different studies. This study therefore provides the first comprehensive investigation of different analysis procedures by systematically comparing the influence of the measurement method and the sample preparation on the determination of the thermal conductivity and the volumetric heat capacity. Seven dissimilar grouting materials with varying water–solid ratios (W/S) and compositions are analysed. The thermal conductivities of the materials range between 0.9 and 1.8 W m−1 K−1 (transient plane source method, TPS). The volumetric heat capacities range between 3.01 and 3.63 MJ m−3 K−1 (differential scanning calorimetry, DSC). From the findings of this study, a standardised analysis of grouting materials is provided which suggests mixing of the grouting material at a high mixing speed and sample curing under water for 28 days at room temperature. The benefits of calculating the volumetric heat capacities of grouting materials from the specific heat capacities of dry samples measured with the DSC, the water content and the bulk density are demonstrated. Furthermore, an estimation procedure of volumetric heat capacity from the W/S and suspension density with an uncertainty of smaller ± 5% is provided. Finally, this study contributes to consistency and comparability between existing and future studies on the thermal properties of grouting materials.

目前,用于井眼热交换器(BHE)的灌浆材料的热性能分析采用的测量方法和分析程序各不相同,导致在比较不同研究的数值时存在困难。因此,本研究通过系统比较测量方法和样品制备对热导率和体积热容测定的影响,首次对不同分析程序进行了全面调查。研究分析了七种水固比(W/S)和成分各不相同的灌浆材料。材料的导热系数介于 0.9 和 1.8 W m-1 K-1 之间(瞬态平面源方法,TPS)。体积热容介于 3.01 和 3.63 MJ m-3 K-1 之间(差示扫描量热法,DSC)。根据这项研究的结果,对灌浆材料进行了标准化分析,建议以较高的搅拌速度混合灌浆材料,并在室温下将样品在水中固化 28 天。根据 DSC 测量的干样比热容、含水量和体积密度计算灌浆材料体积热容的好处也得到了证实。此外,还提供了一种根据 W/S 和悬浮密度估算体积热容的程序,其不确定性小于 ±5%。最后,这项研究有助于提高现有和未来有关灌浆材料热性能研究的一致性和可比性。
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引用次数: 0
Chemical and isotopic constraints on fluid origin and genesis of geothermal systems in the Tingri-Tangra Yumco rift, southern Tibetan Plateau 青藏高原南部定日-唐古拉玉错裂谷流体起源和地热系统成因的化学和同位素制约因素
IF 2.9 2区 地球科学 Q3 ENERGY & FUELS Pub Date : 2024-09-03 DOI: 10.1186/s40517-024-00311-8
Wei Liu, Maoliang Zhang, Yi Liu, Lifeng Cui, Yuji Sano, Sheng Xu

Numerous geothermal systems are hosted by extensional rifts that transect the Himalayas and Lhasa block in the Himalayan–Tibetan orogen. However, the relationships between hydrogeological processes and geothermal fluid circulation in different tectonic units remain unclear. Here, we report an integrated dataset of chemical and isotopic compositions (including major and trace elements, δD, δ18O, and 87Sr/86Sr) of thermal spring water from the Tingri-Tangra Yumco rift to assess their origins and circulation processes. δ18O (− 21.3 to − 17.0‰) and δD (− 166 to − 135‰) values of thermal springs indicate dominant recharge of meteoric waters from areas with elevation of > 6000 m and minor addition of magmatic fluids. Meteoric water could infiltrate to depths of about 1700–2900 m along the faults, whereby it is influenced by geothermal gradient and/or conductive heat transfer of magmatic fluids. The thermal spring waters are mainly Na-HCO3 type and are controlled by dissolution of silicate and carbonate minerals and mixing with deep fluids. The results of chemical and multicomponent geothermometers indicate reservoir temperatures of 115 − 195 ℃, corresponding to a convection heat flux of 3.96 × 105 J/s to 1.78 × 107 J/s from geothermal systems, which are comparable to that of the low-enthalpy geothermal systems in southern Italy. Geochemical modeling is conducted to assess the water–mineral equilibria in the reservoir. Trace elements and 87Sr/86Sr data suggest spatially variable controlling factors for the rift-related geothermal systems: (1) interaction with granitoid and carbonate in the Himalayas; (2) cold groundwater mixing with that leaching from granite and volcanic rocks in the Lhasa block; (3) the input of vapors from magmatic degassing. The geochemistry of thermal springs associated with extensional rift is largely induced by the interaction between fluid and different reservoir rocks in the Himalayas and Lhasa block. Based on these findings, a genetic model is proposed for exploration and development of geothermal resources in the Tingri-Tangra Yumco rift.

喜马拉雅-西藏造山带中横贯喜马拉雅山脉和拉萨地块的伸展裂谷孕育了众多地热系统。然而,不同构造单元中的水文地质过程与地热流体循环之间的关系仍不清楚。在此,我们报告了定日-唐古拉玉科断裂温泉水的化学成分和同位素组成(包括主要元素和微量元素、δD、δ18O和87Sr/86Sr)的综合数据集,以评估其起源和循环过程。温泉的δ18O(- 21.3 至 - 17.0‰)和δD(- 166 至 - 135‰)值表明,来自海拔 > 6000 米地区的陨石水是主要补给水源,岩浆流体是次要补给水源。流星水可沿断层渗透到约 1700-2900 米深处,受到地热梯度和/或岩浆流体传导热量的影响。温泉水主要是 Na-HCO3 类型,受硅酸盐和碳酸盐矿物溶解以及与深层流体混合的控制。化学和多组分地温仪的结果表明,储层温度为 115 - 195 ℃,相当于地热系统 3.96 × 105 J/s 至 1.78 × 107 J/s 的对流热通量,与意大利南部的低焓地热系统相当。为评估储层中的水-矿物平衡,进行了地球化学建模。痕量元素和 87Sr/86Sr 数据表明,与断裂有关的地热系统的控制因素在空间上是可变的:(1) 与喜马拉雅山花岗岩和碳酸盐岩的相互作用;(2) 冷地下水与拉萨地块花岗岩和火山岩沥滤的地下水混合;(3) 岩浆脱气产生的蒸汽输入。与伸展裂谷相关的温泉地球化学主要是由喜马拉雅山和拉萨地块的流体与不同储层岩石之间的相互作用引起的。根据这些发现,提出了定日-唐古拉玉科断裂地热资源勘探和开发的遗传模型。
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引用次数: 0
Hydrogeochemical and microbial characterization of a Middle Triassic carbonate aquifer (Muschelkalk) in Berlin and geochemical simulation of its use as a high-temperature aquifer thermal energy storage 柏林中三叠统碳酸盐含水层(Muschelkalk)的水文地质化学和微生物特征及其作为高温含水层热能储存的地球化学模拟
IF 2.9 2区 地球科学 Q3 ENERGY & FUELS Pub Date : 2024-08-28 DOI: 10.1186/s40517-024-00309-2
Lioba Virchow, Christian Siever-Wenzlaff, Guido Blöcher, Armando Alibrandi, Jens Kallmeyer, Martin Zimmer, Thomas Wiersberg, Christoph Thielke, Anja Schleicher, Simona Regenspurg

The geological formation of the Muschelkalk is widespread in the center of the North German Basin (NGB) and is increasingly attracting interest for application of geothermal energy extraction or high-temperature aquifer thermal energy storage (HT-ATES). This study investigates the Middle Triassic “Rüdersdorfer Schaumkalk”, which was the former injection horizon of the natural gas storage facility in Berlin, Germany. For the first time, detailed chemical and microbiological analyses of formation water of this Lower Muschelkalk limestone formation were conducted and hydrogeochemically characterized. In addition, a hydrogeochemical model was developed to quantify the potential reactions during HT-ATES focusing on calcite dissolution and precipitation. The main objectives of this study are: (1) to determine the origin of the water from the three wells targeting the Muschelkalk aquifer, (2) to understand changes in hydrochemistry after system operation, and (3) to evaluate the long-term sustainability of a potential HT-ATES system with increasing temperature. The target formation is encountered by several wells at about 525 m below the surface with an average thickness of 30 m. Two hydraulic lifting tests including physical, chemical, and microbial groundwater as well as gas monitoring were carried out. In addition, several downhole samples of formation fluid were collected from the aquifer at in situ pressure and temperature conditions. Fluid analysis of the saline formation water indicate a seawater origin within the Muschelkalk with subsequent evaporation and various water–rock interactions with anhydrite/gypsum, dolomite, and calcite. With a salinity of 130 g/L, dominated by Na–Cl, a slightly acidic pH between 6 and 7, and a low gas content of 3%, the formation water fits to other saline deep formation waters of the NGB. Gas concentrations and microbial communities like sulfate-reducing bacteria and methanogenic archaea in the produced water indicate several geochemical alterations and microbial processes like corrosion and the forming of biogenic methane. Geochemical simulations of calcite equilibrium over 10 HT-ATES cycles indicated a pronounced propensity for calcite precipitation up to 31 mg/kgw, within the heat exchanger. At the same time, these models predicted a significant potential for calcite dissolution, with rates up to 21 mg/kgw, in both the cold and hot reservoirs. The results from the carbonate aquifer characterized in this study can be transferred to other sites in the NGB affected by salt tectonics and have provided information on the microbiological-chemical processes to be expected during the initial use of old wells.

北德盆地(NGB)中心广泛分布着马舍克尔克(Muschelkalk)地质构造,它在地热能源提取或高温含水层热能储存(HT-ATES)方面的应用正日益引起人们的兴趣。本研究调查了中三叠统 "Rüdersdorfer Schaumkalk",它曾是德国柏林天然气储存设施的注入层。该研究首次对这一下穆谢尔克尔克石灰岩地层的地层水进行了详细的化学和微生物分析,并对其进行了水文地质化学鉴定。此外,还开发了一个水文地球化学模型,用于量化 HT-ATES 期间的潜在反应,重点是方解石溶解和沉淀。本研究的主要目标是(1) 确定以 Muschelkalk 含水层为目标的三口井的水源,(2) 了解系统运行后的水文化学变化,(3) 评估潜在 HT-ATES 系统随着温度升高的长期可持续性。目标地层位于地表下约 525 米处,平均厚度为 30 米。此外,还在原地压力和温度条件下从含水层采集了若干地层流体的井下样本。对含盐地层水的流体分析表明,含盐地层水来源于穆斯切尔克岩层中的海水,随后被蒸发,并与无水石膏/石膏、白云石和方解石发生了各种水岩相互作用。地层水的盐度为 130 克/升,主要成分为 Na-Cl,pH 值在 6 到 7 之间,呈微酸性,气体含量较低,仅为 3%,与 NGB 的其他含盐深层地层水相吻合。产水中的气体浓度和微生物群落(如硫酸盐还原菌和产甲烷古细菌)表明存在一些地球化学变化和微生物过程,如腐蚀和形成生物甲烷。对 10 个 HT-ATES 循环进行的方解石平衡地球化学模拟表明,热交换器内的方解石沉淀倾向明显,最高可达 31 mg/kgw。同时,这些模型还预测了方解石溶解的巨大潜力,在冷储层和热储层中的溶解速率最高可达 21 毫克/千克湿重。本研究对碳酸盐含水层进行了特征描述,其结果可用于受盐类构造影响的 NGB 其他地点,并提供了有关老井初始使用期间预期微生物化学过程的信息。
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Geothermal Energy
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