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Hierarchical Interconnected NiMoN with Large Specific Surface Area and High Mechanical Strength for Efficient and Stable Alkaline Water/Seawater Hydrogen Evolution 具有大比表面积和高机械强度的分层互连NiMoN用于高效稳定的碱性水/海水析氢
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2023-06-19 DOI: 10.1007/s40820-023-01129-y
Minghui Ning, Yu Wang, Libo Wu, Lun Yang, Zhaoyang Chen, Shaowei Song, Yan Yao, Jiming Bao, Shuo Chen, Zhifeng Ren

Highlights

  • A hierarchical interconnected NiMoN (HW-NiMoN-2h) was successfully prepared based on a rational combination of hydrothermal and water bath processes.

  • HW-NiMoN-2h exhibited high hydrogen evolution reaction (HER) activity due to its large specific surface area and good stability due to its enhanced mechanical strength.

  • In 1 M KOH seawater, HW-NiMoN-2h delivered current density of 1 A cm−2 for HER at an overpotential of 130 mV and showed excellent stability over 70 h at 1 A cm−2.

基于水热法和水浴法的合理结合,成功制备了一种层叠互联NiMoN (HW-NiMoN-2h)。HW-NiMoN-2h具有较大的比表面积和较好的稳定性,具有较高的析氢活性。在1 M KOH的海水中,HW-NiMoN-2h在过电位为130 mV时为HER提供了1 A cm -2的电流密度,并在1 A cm -2下保持了70小时的优异稳定性。
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引用次数: 3
Synergistic Optimization of Buried Interface by Multifunctional Organic–Inorganic Complexes for Highly Efficient Planar Perovskite Solar Cells 高效平面钙钛矿太阳能电池中多功能有机无机配合物埋藏界面的协同优化
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2023-06-19 DOI: 10.1007/s40820-023-01130-5
Heng Liu, Zhengyu Lu, Weihai Zhang, Hongkang Zhou, Yu Xia, Yueqing Shi, Junwei Wang, Rui Chen, Haiping Xia, Hsing-Lin Wang

Highlights

  • Highly performed perovskite solar cells are achieved via introducing organic–inorganic CL–NH complex as multifunctional interfacial layer.

  • CL–NH complex not only reduces oxygen vacancies on the surface of SnO2 but also regulates film crystallization, resulting in a superior device efficiency of 23.69%.

  • The resulting device performs excellent stability with 91.5% initial power conversion efficiency retained after 500 h light illumination.

通过引入有机-无机CL-NH配合物作为多功能界面层,实现了高性能钙钛矿太阳能电池。CL-NH配合物不仅可以减少SnO2表面的氧空位,还可以调节薄膜结晶,器件效率达到23.69%。该器件具有优异的稳定性,在500 h光照后仍保持91.5%的初始功率转换效率。
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引用次数: 1
Heteroatom-Induced Accelerated Kinetics on Nickel Selenide for Highly Efficient Hydrazine-Assisted Water Splitting and Zn-Hydrazine Battery 杂原子诱导的硒化镍高效肼助水分解和锌-肼电池加速动力学
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2023-06-19 DOI: 10.1007/s40820-023-01128-z
Hao-Yu Wang, Lei Wang, Jin-Tao Ren, Wen-Wen Tian, Ming-Lei Sun, Zhong-Yong Yuan

Hydrazine-assisted water electrolysis is a promising energy conversion technology for highly efficient hydrogen production. Rational design of bifunctional electrocatalysts, which can simultaneously accelerate hydrogen evolution reaction (HER)/hydrazine oxidation reaction (HzOR) kinetics, is the key step. Herein, we demonstrate the development of ultrathin P/Fe co-doped NiSe2 nanosheets supported on modified Ni foam (P/Fe-NiSe2) synthesized through a facile electrodeposition process and subsequent heat treatment. Based on electrochemical measurements, characterizations, and density functional theory calculations, a favorable “2 + 2” reaction mechanism with a two-step HER process and a two-step HzOR step was fully proved and the specific effect of P doping on HzOR kinetics was investigated. P/Fe-NiSe2 thus yields an impressive electrocatalytic performance, delivering a high current density of 100 mA cm−2 with potentials of − 168 and 200 mV for HER and HzOR, respectively. Additionally, P/Fe-NiSe2 can work efficiently for hydrazine-assisted water electrolysis and Zn-Hydrazine (Zn-Hz) battery, making it promising for practical application.

肼辅助水电解是一种很有前途的高效制氢能量转换技术。合理设计能同时加速析氢反应(HER)/肼氧化反应(HzOR)动力学的双功能电催化剂是关键步骤。在此,我们展示了超薄P/Fe共掺杂NiSe2纳米片的发展,支持改性Ni泡沫(P/Fe-NiSe2)通过简单的电沉积工艺和随后的热处理合成。基于电化学测量、表征和密度泛函理论计算,充分证明了两步HER和两步HzOR反应的良好“2 + 2”反应机理,并研究了P掺杂对HzOR动力学的具体影响。P/ fe - nis2因此产生了令人印象深刻的电催化性能,为HER和HzOR提供了100 mA cm - 2的高电流密度,分别为- 168和200 mV。此外,P/ fe - nis2可以有效地用于肼辅助电解和锌-肼(Zn-Hz)电池,具有实际应用前景。
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引用次数: 7
A Bilayer High-Temperature Dielectric Film with Superior Breakdown Strength and Energy Storage Density 一种具有优异击穿强度和储能密度的双层高温介质薄膜
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2023-06-08 DOI: 10.1007/s40820-023-01121-6
Jiang-Bo Ping, Qi-Kun Feng, Yong-Xin Zhang, Xin-Jie Wang, Lei Huang, Shao-Long Zhong, Zhi-Min Dang

Highlights

  • A bilayer dielectric film is prepared via coating boron nitride nanosheets (BNNSs) by solution casting on the surface of polyethylene terephthalate (PET) film.

  • The BNNS layer acts as the efficient barrier layer to suppress the charge injection, thereby making the surface-modified PET films exhibit excellent breakdown strength and electrostatic energy storage performance.

  • The surface coating methods are accessible and suitable for large-scale roll-to-roll process production of dielectric films.

在聚对苯二甲酸乙二醇酯(PET)薄膜表面采用溶液浇铸法制备了氮化硼纳米片(BNNSs)双层介质薄膜。BNNS层作为有效的阻挡层抑制电荷注入,从而使表面改性PET薄膜具有优异的击穿强度和静电储能性能。表面涂覆方法易于获得,适合大规模卷对卷工艺生产介质薄膜。
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引用次数: 6
Novel Bilayer-Shelled N, O-Doped Hollow Porous Carbon Microspheres as High Performance Anode for Potassium-Ion Hybrid Capacitors 新型双壳氮氧掺杂空心多孔碳微球作为钾离子杂化电容器的高性能阳极
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2023-06-07 DOI: 10.1007/s40820-023-01113-6
Zhen Pan, Yong Qian, Yang Li, Xiaoning Xie, Ning Lin, Yitai Qian

Highlights

  • Proposing a one-step pyrolysis strategy to fabricate a novel bilayer-shelled N, O-doped hollow porous carbon microspheres (NOHPC) anode.

  • The optimized NOHPC anode displays a high K-storage capacity of 325.9 mAh g−1 at 0.1 A g−1 and excellent rate performance (201.1 mAh g−1 at 5 A g−1 after 6000 cycles).

  • The assembled NOHPC//hollow porous activated carbon microspheres (HPAC) potassium ion hybrid capacitors deliver a high energy density of 90.1 Wh kg−1 at a power density of 939.6 W kg−1 even over 6000 cycles.

提出了一步热解制备新型双壳层氮氧掺杂中空多孔碳微球(NOHPC)阳极的方法。优化后的NOHPC阳极在0.1 ag−1时具有325.9 mAh g−1的高k存储容量和优异的倍率性能(在6000次循环后,在5 ag−1时具有201.1 mAh g−1)。组装的NOHPC//空心多孔活性炭微球(HPAC)钾离子混合电容器在超过6000次循环的功率密度为939.6 W kg - 1时,其能量密度高达90.1 Wh kg - 1。
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引用次数: 3
Tetris-Style Stacking Process to Tailor the Orientation of Carbon Fiber Scaffolds for Efficient Heat Dissipation 俄罗斯方块式堆叠工艺,以调整碳纤维支架的方向,以实现高效散热
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2023-06-07 DOI: 10.1007/s40820-023-01119-0
Shida Han, Yuan Ji, Qi Zhang, Hong Wu, Shaoyun Guo, Jianhui Qiu, Fengshun Zhang

Highlights

  • Carbon fiber (CF) scaffolds with horizontally aligned, diagonally aligned and vertically aligned structure were fabricated via magnetic field-assisted Tetris-style stacking and carbonization process.

  • The obtained CF scaffolds/ polydimethylsiloxane composites showed ultrahigh thermal conductivity (above 40 W m−1 K−1) in the fiber alignment direction.

  • Fibers with different alignment direction can be combined by multiple stacking and carbonization process, allowing for the efficient heat transfer along customized paths.

采用磁场辅助的俄罗斯方块式堆砌碳化工艺制备了水平排列、对角排列和垂直排列结构的碳纤维支架。所得的CF支架/聚二甲基硅氧烷复合材料在纤维取向方向上具有超高的导热系数(> 40 W m−1 K−1)。不同排列方向的纤维可以通过多次堆叠和碳化工艺组合在一起,从而实现沿定制路径的高效传热。
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引用次数: 1
Tailoring Food Biopolymers into Biogels for Regenerative Wound Healing and Versatile Skin Bioelectronics 将食品生物聚合物剪裁成生物凝胶,用于再生伤口愈合和多用途皮肤生物电子学
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2023-06-07 DOI: 10.1007/s40820-023-01099-1
Qiankun Zeng, Qiwen Peng, Fangbing Wang, Guoyue Shi, Hossam Haick, Min Zhang

Highlights

  • This food biopolymer-based biogel unites the challenging needs of elastic yet injectable wound dressing and skin bioelectronics in a single platform.

  • This is the first demonstration of a hydrogel dressing that satisfies both deep and superficial wounds, and for the accelerated healing of diabetic wounds.

  • Biogel-based flexible skin bioelectronic can serve as a “fever indicator” and monitoring human activities and tiny electrophysiological signals, providing important clinical information for the rehabilitation training of the wounded.

这种基于食品生物聚合物的生物凝胶将弹性可注射伤口敷料和皮肤生物电子学的挑战性需求结合在一个平台上。这是一种水凝胶敷料的首次演示,它既能满足深层伤口,也能满足浅表伤口,并能加速糖尿病伤口的愈合。基于生物凝胶的柔性皮肤生物电子可以作为“发热指示器”,监测人体活动和微小的电生理信号,为伤员的康复训练提供重要的临床信息。
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引用次数: 1
Boosting Interfacial Polarization Through Heterointerface Engineering in MXene/Graphene Intercalated-Based Microspheres for Electromagnetic Wave Absorption 利用异质界面工程增强MXene/石墨烯插层微球电磁波吸收的界面极化
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2023-06-07 DOI: 10.1007/s40820-023-01123-4
Ge Wang, Changfeng Li, Diana Estevez, Peng Xu, Mengyue Peng, Huijie Wei, Faxiang Qin

Multi-layer 2D material assemblies provide a great number of interfaces beneficial for electromagnetic wave absorption. However, avoiding agglomeration and achieving layer-by-layer ordered intercalation remain challenging. Here, 3D reduced graphene oxide (rGO)/MXene/TiO2/Fe2C lightweight porous microspheres with periodical intercalated structures and pronounced interfacial effects were constructed by spray-freeze-drying and microwave irradiation based on the Maxwell–Wagner effect. Such approach reinforced interfacial effects via defects introduction, porous skeleton, multi-layer assembly and multi-component system, leading to synergistic loss mechanisms. The abundant 2D/2D/0D/0D intercalated heterojunctions in the microspheres provide a high density of polarization charges while generating abundant polarization sites, resulting in boosted interfacial polarization, which is verified by CST Microwave Studio simulations. By precisely tuning the 2D nanosheets intercalation in the heterostructures, both the polarization loss and impedance matching improve significantly. At a low filler loading of 5 wt%, the polarization loss rate exceeds 70%, and a minimum reflection loss (RLmin) of −67.4 dB can be achieved. Moreover, radar cross-section simulations further confirm the attenuation ability of the optimized porous microspheres. These results not only provide novel insights into understanding and enhancing interfacial effects, but also constitute an attractive platform for implementing heterointerface engineering based on customized 2D hierarchical architectures.

多层二维材料组合提供了大量有利于电磁波吸收的界面。然而,避免团聚和实现逐层有序嵌入仍然是一个挑战。利用麦克斯韦-瓦格纳效应,采用喷雾冷冻干燥和微波辐照法制备了具有周期性插层结构和明显界面效应的3D还原氧化石墨烯/MXene/TiO2/Fe2C轻量多孔微球。该方法通过引入缺陷、多孔骨架、多层组装和多组分体系增强界面效应,导致协同损失机制。微球中丰富的2D/2D/0D/0D插层异质结提供了高密度的极化电荷,同时产生了丰富的极化位点,从而增强了界面极化,CST Microwave Studio模拟验证了这一点。通过对二维纳米片在异质结构中的嵌入进行精确调整,极化损耗和阻抗匹配都得到了显著改善。当填充量为5 wt%时,极化损耗率超过70%,最小反射损耗(RLmin)为- 67.4 dB。此外,雷达截面模拟进一步证实了优化后多孔微球的衰减能力。这些结果不仅为理解和增强界面效应提供了新的见解,而且为实现基于定制二维层次结构的异质界面工程提供了一个有吸引力的平台。
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引用次数: 4
Fundamental Perspectives on the Electrochemical Water Applications of Metal–Organic Frameworks 金属-有机骨架在电化学水处理中的应用
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2023-06-07 DOI: 10.1007/s40820-023-01124-3
Xiang He

Metal–organic frameworks (MOFs), a family of highly porous materials possessing huge surface areas and feasible chemical tunability, are emerging as critical functional materials to solve the growing challenges associated with energy–water systems, such as water scarcity issues. In this contribution, the roles of MOFs are highlighted in electrochemical-based water applications (i.e., reactions, sensing, and separations), where MOF-based functional materials exhibit outstanding performances in detecting/removing pollutants, recovering resources, and harvesting energies from different water sources. Compared with the pristine MOFs, the efficiency and/or selectivity can be further enhanced via rational structural modulation of MOFs (e.g., partial metal substitution) or integration of MOFs with other functional materials (e.g., metal clusters and reduced graphene oxide). Several key factors/properties that affect the performances of MOF-based materials are also reviewed, including electronic structures, nanoconfined effects, stability, conductivity, and atomic structures. The advancement in the fundamental understanding of these key factors is expected to shed light on the functioning mechanisms of MOFs (e.g., charge transfer pathways and guest–host interactions), which will subsequently accelerate the integration of precisely designed MOFs into electrochemical architectures to achieve highly effective water remediation with optimized selectivity and long-term stability.

金属有机框架(mof)是一类具有巨大表面积和可行的化学可调性的高多孔材料,正在成为解决与能源-水系统相关的日益增长的挑战的关键功能材料,例如水资源短缺问题。在这篇文章中,mof在基于电化学的水应用(即反应,传感和分离)中的作用得到了强调,其中mof基功能材料在检测/去除污染物,回收资源和从不同水源收集能量方面表现出出色的性能。与原始mof相比,通过合理的结构调制(例如,部分金属取代)或与其他功能材料(例如,金属团簇和还原氧化石墨烯)集成mof,可以进一步提高效率和/或选择性。综述了影响mof基材料性能的几个关键因素/性质,包括电子结构、纳米限制效应、稳定性、电导率和原子结构。对这些关键因素的基本理解的进展有望揭示mof的功能机制(例如电荷转移途径和主客体相互作用),这将随后加速将精确设计的mof集成到电化学结构中,以实现具有优化选择性和长期稳定性的高效水修复。
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引用次数: 3
Outstanding Humidity Chemiresistors Based on Imine-Linked Covalent Organic Framework Films for Human Respiration Monitoring 基于亚胺共价有机骨架膜的人体呼吸监测用杰出湿度化学电阻
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2023-06-07 DOI: 10.1007/s40820-023-01107-4
Xiyu Chen, Lingwei Kong, Jaafar Abdul-Aziz Mehrez, Chao Fan, Wenjing Quan, Yongwei Zhang, Min Zeng, Jianhua Yang, Nantao Hu, Yanjie Su, Hao Wei, Zhi Yang

Highlights

  • Imine groups in covalent organic framework (COF) films act as dual-active sites for humidity sensing, inducing an intrinsic enhanced mechanism of reversible protonated tautomerism via water molecule-induced hydrogen bonding.

  • The cis-ketoimine reciprocal isomerization induces a stretching vibration effect for the ordered conjugated conductive frame of COF films, realizing fast response, wide range, and high sensitivity characteristics for humidity detection.

  • Resistance changes of COF film-based sensors keep a strong linear relationship with low-range relative humidity, reflecting the quantitative sensing mechanism at the molecular level.

共价有机框架(COF)膜中的亚胺基团作为湿度传感的双活性位点,通过水分子诱导的氢键诱导可逆质子化互变异构的内在增强机制。顺式酮亚胺互反异构化对COF薄膜的有序共轭导电框架产生拉伸振动效应,实现了快速响应、宽范围、高灵敏度的湿度检测特性。COF薄膜传感器的电阻变化与低量程相对湿度呈较强的线性关系,反映了分子水平上的定量传感机制。
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引用次数: 3
期刊
Nano-Micro Letters
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