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Trimming the Degrees of Freedom via a K+ Flux Rectifier for Safe and Long-Life Potassium-Ion Batteries 通过K+通量整流器对安全和长寿命钾离子电池的自由度进行修剪。
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-08-18 DOI: 10.1007/s40820-023-01178-3
Xianhui Yi, Apparao M. Rao, Jiang Zhou, Bingan Lu

Highlights

  • High Coulombic efficiency of over 99% for dendrite-free K||Cu cell after 820 cycles.

  • Year-scale-cycling performance of organic PTCDI cathode over 2,100 cycles.

  • Flexible device demonstration such as fibre cell still could operate when cut into three fibre cells.

电解质中K+运动的高自由度(DOF)是理想的,因为由此产生的高离子电导率有助于改善钾离子电池,但需要高度自由和易燃的有机溶剂分子的支持,严重影响电池的安全性。在此,我们开发了一种K+通量整流器,将K离子的DOF调整到1,并改善了电化学性能。虽然离子电导率在K+通量整流器中受到损害,但PIBs的整体电化学性能得到了改善。氧化稳定性从4.0 V提高到5.9 V,枝晶的形成和有机阴极的溶解受到抑制。因此,K||K细胞连续循环超过3,700 h;K||Cu电池可稳定运行800次以上,库仑效率超过99%;K - | - |石墨电池在1500次循环后的容量保留率高达74.7%。此外,3,4,9,10-苝四羧基二亚胺有机阴极的循环次数超过2,100次,达到了年尺度的循环时间。我们制作了一个2.18 Ah的袋状电池,经过100次循环后容量没有明显的衰减。
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引用次数: 0
High-Quality Epitaxial N Doped Graphene on SiC with Tunable Interfacial Interactions via Electron/Ion Bridges for Stable Lithium-Ion Storage 高质量外延N掺杂石墨烯在SiC上的电子/离子桥可调谐界面相互作用,用于稳定锂离子存储。
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-08-18 DOI: 10.1007/s40820-023-01175-6
Changlong Sun, Xin Xu, Cenlin Gui, Fuzhou Chen, Yian Wang, Shengzhou Chen, Minhua Shao, Jiahai Wang

Highlights

  • The intimate NG@SiC heterostructure has been constructed via a direct thermal decomposition method.

  • The NG@SiC heterostructure anode delivers enhanced capacity and cycling stability both in the half-cell and in the full cell.

  • DFT analysis reveals that this NG@SiC anode possesses lower lithium-ion adsorption energy and higher charge and discharge rates.

定制sic基阳极材料中的界面相互作用对于实现更高的能量容量和更长的锂离子存储循环寿命至关重要。在本文中,通过在SiC (NG@SiC)上外延生长高质量N掺杂石墨烯(NG),实现了原子尺度的可调谐界面相互作用。这个精心设计的NG@SiC异质结展示了一个具有强烈界面相互作用的本征电场,使其成为深入了解电子/离子桥构型和原子间电子迁移机制的理想原型。密度泛函理论(DFT)分析和电化学动力学分析表明,这些有趣的电子/离子桥可以通过界面耦合化学键控制和调整界面相互作用,增强界面电荷转移动力学,防止粉化/聚集。作为概念验证研究,这种精心设计的NG@SiC阳极显示出良好的可逆容量(在0.1 a g-1下循环200次后为1197.5 mAh g-1)和循环耐久性,在10.0 a g-1下循环1000次后为447.8 mAh g-1,容量保持率为76.6%。正如预期的那样,锂离子电池(LiFePO4/C//NG@SiC)表现出优越的倍率能力和循环稳定性。这种通过外延生长方法实现的界面相互作用定制策略为传统的sic基阳极实现高性能锂离子存储提供了新的机会。
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引用次数: 0
Conformal Human–Machine Integration Using Highly Bending-Insensitive, Unpixelated, and Waterproof Epidermal Electronics Toward Metaverse 使用高度弯曲不敏感,无像素化和防水表皮电子元件的保形人机集成。
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-08-16 DOI: 10.1007/s40820-023-01176-5
Chao Wei, Wansheng Lin, Liang Wang, Zhicheng Cao, Zijian Huang, Qingliang Liao, Ziquan Guo, Yuhan Su, Yuanjin Zheng, Xinqin Liao, Zhong Chen

Highlights

  • The addressable electrical contact structure enables the multifunctional epidermal interface with an all-in-one function of sense, recognition, and transmission, which realizes high flexibility and high-precision touch detection.

  • The multifunctional epidermal interface achieves superior waterproofness and is constructed enough thin to be bent freely, which is not as rigid, bulky, and thick as common interactive electronic device.

  • The bending-insensitive characteristic facilitates accurate and stable human–machine interactions, which provides a key foundation for intelligent prostheses and super-soft robots.

高效和灵活的交互需要将人类的意图精确地转化为计算机可识别的信号,这对元宇宙的突破性发展至关重要。交互式电子器件面临着实现高精度、稳定的触摸检测但刚性大、体积大、厚度大或实现高柔性穿戴但失去精度的共同困境。在这里,我们构建了高度弯曲不敏感、无像素化和防水的表皮界面(BUW表皮界面),并展示了它们在保形人机集成中的交互应用。基于可寻址电触点结构的BUW表皮界面具有高精度、稳定的触摸检测、高灵活性、快速响应时间、优异的稳定性和多功能的“剪切-粘贴”特性。无论是平的还是弯曲的,BUW表皮界面都可以与人体皮肤共形连接,实现实时、舒适和不受约束的交互。本研究为表皮电子学的功能复合和结构设计策略的发展提供了新的技术途径,并可能进一步扩大人机交互向超宇宙的发展。
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引用次数: 0
Maximizing Terahertz Energy Absorption with MXene Absorber 最大化太赫兹能量吸收与MXene吸收器。
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-08-12 DOI: 10.1007/s40820-023-01167-6
Xinliang Li, Hao Luo

Achieving high absorption in broad terahertz bands has long been challenging for terahertz electromagnetic wave absorbers. Recently in Nature Photonics, Xiao et al. reported the high absorption approaching the theoretical upper limit across the whole terahertz band of MXene-based terahertz absorbers and, on this basis, constructed an applicable, updated alternating current impedance matching model.

Graphical Abstract

对太赫兹电磁波吸收器来说,在太赫兹宽波段实现高吸收一直是一个挑战。最近在Nature Photonics上,Xiao等人报道了基于mxene的太赫兹吸收器在整个太赫兹波段的高吸收接近理论上限,并在此基础上构建了一个适用的、更新的交流阻抗匹配模型。
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引用次数: 0
Bioorthogonal Engineered Virus-Like Nanoparticles for Efficient Gene Therapy 用于有效基因治疗的生物正交工程病毒样纳米颗粒。
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-08-12 DOI: 10.1007/s40820-023-01153-y
Chun-Jie Bao, Jia-Lun Duan, Ying Xie, Xin-Ping Feng, Wei Cui, Song-Yue Chen, Pei-Shan Li, Yi-Xuan Liu, Jin-Ling Wang, Gui-Ling Wang, Wan-Liang Lu
AbstractSection Highlights
  • A virus-like nanoparticle (reBiosome) was developed via site-specific codon mutation for displaying unnatural amino acid (Azi) on virus envelope protein at a rational site, followed by conjugating weak acid-responsive polyethylene glycol polymer on Azi via bioorthogonal chemistry.

  • The reBiosome exhibited reduced virus-like immunogenicity, prolonged blood circulation and enhanced delivery to weakly acidic disease foci.

  • The reBiosome enabled efficient delivery of gene editing and gene silencing system, demonstrating remarkable therapeutic efficacy in breast cancer and arthritis, respectively.

基因疗法为人类主要疾病提供了潜在的变革性策略。然而,基因治疗的关键挑战之一是开发一种有效的策略,将基因传递到特定的组织中。在这里,我们报道了一种新的病毒样纳米颗粒,生物正交工程病毒样重组生物体(reBiosome),用于癌症和炎症性疾病的有效基因治疗。突变型病毒样生物小体(mBiosome)首先通过位点特异性密码子突变,将4-叠氮多-l -苯丙氨酸显示在水泡性口炎病毒糖蛋白上,然后通过生物正交化学将弱酸反应亲水性聚合物点击到mBiosome上,制备出突变型病毒样生物小体。结果表明,reBiosome具有降低病毒样免疫原性、延长血液循环时间和提高基因传递到弱酸性病灶(如肿瘤和关节炎组织)的效率。此外,reBiosome分别通过提供基因编辑和沉默系统,在乳腺癌和关节炎中显示出强大的治疗效果。总之,本研究为癌症和炎症性疾病的基因治疗提供了一个通用、安全、有效的平台。
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引用次数: 0
Swift Assembly of Adaptive Thermocell Arrays for Device-Level Healable and Energy-Autonomous Motion Sensors 用于设备级可修复和能量自主运动传感器的自适应热电池阵列的快速组装。
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-08-11 DOI: 10.1007/s40820-023-01170-x
Xin Lu, Daibin Xie, Kaihua Zhu, Shouhao Wei, Ziwei Mo, Chunyu Du, Lirong Liang, Guangming Chen, Zhuoxin Liu

Highlights

  • The MXene-boosted rapid gelling expedites the assembly of flexible thermocell arrays, overcoming the typical constraint of complicated device fabrication processes.

  • The hydrogel electrolyte can sustain stable thermoelectrochemical performance under various challenging conditions, including large, repeated, and sustained deformations, and multiple cut-healing cycles.

  • The as-assembled thermocell array exhibits device-level self-healing capability and high adaptability to human body, efficiently harvesting low-grade heat for wearable applications.

可穿戴技术的发展促进了对自适应、自我修复和能源自主的能源设备的需求。本研究通过引入一种mxene推进的水凝胶电解质,创新地解决了这一挑战,该电解质加速了柔性热电池(TEC)阵列的组装过程,从而绕过了典型可穿戴电子产品的复杂制造。我们的发现强调了水凝胶电解质在大量变形和重复自愈循环下优越的热电化学性能。所得的水凝胶基TEC在ΔT温度为20 K的条件下,当拉伸到500%,循环1000次时,其最大功率输出为1032.1 nW,相当于其初始状态的80%;同时,在ΔT 20 K条件下,即使经过60次切割愈合循环,其仍能维持1179.1 nW,约为初始状态的92%。组装后的TEC阵列具有设备级自修复能力和对人体的高适应性。它很容易应用于基于触摸的加密通信,其中不同的电压信号可以转换为字母;它也被用作自供电传感器,用于现场监测各种复杂的人体动作。快速组装方法,结合TEC设备的多功能,为未来可穿戴电子产品的发展铺平了道路,目标是健身监测和人机界面。
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引用次数: 0
Competitive Redox Chemistries in Vanadium Niobium Oxide for Ultrafast and Durable Lithium Storage 钒铌氧化物的竞争氧化还原化学用于超快和持久的锂存储。
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-08-10 DOI: 10.1007/s40820-023-01172-9
Xiaobo Ding, Jianhao Lin, Huiying Huang, Bote Zhao, Xunhui Xiong

Highlights

  • The over-reduction from Nb5+ to Nb3+ in the lithiation process have been demonstrated to be the critical reason for the capacity decay of Nb2O5 for the first time.

  • A novel competitive redox strategy has been proposed to suppress the over-reduction of Nb5+ to Nb3+, which can be achieved by the incorporation of vanadium to form a new rutile VNbO4 anode.

  • The performance of VNbO4 anode designed in this study stands among the best in cycle stability.

五氧化二铌(Nb2O5)阳极以其优异的倍率性能和高安全性在大功率锂离子电池中得到越来越多的关注。然而,Nb2O5阳极经改性后循环稳定性较差,其机理尚不明确,制约了其实际应用。本文首次证明了Nb5+的过还原是导致容量损失的关键原因。此外,研究了一种有效的竞争性氧化还原策略,解决了Nb2O5容量快速衰减的问题,该策略可以通过掺入钒形成新的金红石型VNbO4阳极来实现。VNbO4中高度可逆的V3+/V2+氧化还原对可以有效抑制Nb5+的过度还原。此外,电子从V3+向Nb5+的迁移可以大大提高VNbO4的本征电子导电性。结果表明,VNbO4阳极在0.1 a g-1下可提供206.1 mAh g-1的高容量,并且在1.0 a g-1下循环2000次后保持93.4%的显着循环性能。此外,组装的锂离子电容器在5.8 kW kg-1下具有44 Wh kg-1的高能量密度。总之,我们的工作为超快速和耐用阳极的设计提供了新的见解。
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引用次数: 0
Highly Selective Electrocatalytic CuEDTA Reduction by MoS2 Nanosheets for Efficient Pollutant Removal and Simultaneous Electric Power Output 二硫化钼纳米片高选择性电催化CuEDTA还原高效污染物去除和同步电力输出。
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-08-09 DOI: 10.1007/s40820-023-01166-7
Hehe Qin, Xinru Liu, Xiangyun Liu, Hongying Zhao, Shun Mao

Highlights

  • Highly efficient CuEDTA removal by an electrolyzer with MoS2 nanosheet cathode.

  • Higher removal rate and Faraday efficiency compared with other widely reported electrocatalytic technologies.

  • CuEDTA/Zn primary battery is constructed for the first time to realize CuEDTA removal and synchronous power generation.

乙二胺四乙酸铜(CuEDTA)是一种典型的难降解重金属络合污染物,电催化还原是一种在温和条件下运行的环保型方法。然而,CuEDTA的选择性还原仍然是阴极过程中的一大挑战。在这项工作中,我们报道了一种MoS2纳米片/石墨毡(GF)阴极,在- 0.65 V vs SCE(饱和甘汞电极)下,对CuEDTA的平均法拉第效率为29.6%,比去除率(SRR)为0.042 mol/cm2/h,这两者都远高于通常报道的基于电氧化技术的去除系统。此外,还展示了一种具有锌阳极和MoS2/GF阴极的CuEDTA/Zn电池的概念验证,该电池具有同时去除CuEDTA和能量输出的双重功能。本研究是重金属配合物电催化还原和CuEDTA/Zn电池的先驱研究之一,为开发高效的电催化还原系统用于污染控制和能源输出提供了新的见解。
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引用次数: 0
Advances in Mn-Based Electrode Materials for Aqueous Sodium-Ion Batteries 水性钠离子电池用锰基电极材料的研究进展。
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-08-09 DOI: 10.1007/s40820-023-01162-x
Changsheng Ding, Zhang Chen, Chuanxiang Cao, Yu Liu, Yanfeng Gao

Highlights

  • Mn-based electrode materials, including oxides, Prussian blue analogues and polyanion compounds, are introduced systematically for aqueous sodium-ion batteries.

  • The composition, crystal structure, morphology and electrochemical performance of Mn-based electrode materials are reviewed.

  • The improvement methods of electrochemical performance, such as electrolyte optimization, element doping or substitution, morphology optimization and carbon modification, are discussed.

水性钠离子电池由于其丰富的钠资源、低成本、水性电解质的本质安全性和生态友好性,在大规模储能应用中引起了广泛关注。水性钠离子电池的电化学性能受电极材料和电解质性能的影响。在各种电极材料中,Mn基电极材料以其丰富的Mn、低成本、无毒、环保和有趣的电化学性能而备受关注。具有窄电化学窗口的水性电解质也影响Mn基电极材料的电化学性能。在这篇综述中,我们从阴极材料和阳极材料两个方面系统地介绍了用于水性钠离子电池的锰基电极材料,并对其最新发展进行了全面的概述。这些Mn基材料包括氧化物、普鲁士蓝类似物和聚阴离子化合物。综述和讨论了锰基电极材料的组成、晶体结构、形貌和电化学性能。重点介绍了基于电解质优化、元素掺杂或取代、形貌优化和碳改性的改进方法。并对锰基电极材料的发展前景进行了展望。我们认为这篇综述对探索和应用锰基电极材料在水性钠离子电池中具有重要意义。
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引用次数: 0
Multifunctional MXene/C Aerogels for Enhanced Microwave Absorption and Thermal Insulation 增强微波吸收和隔热的多功能MXene/C气凝胶。
IF 26.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-08-09 DOI: 10.1007/s40820-023-01158-7
Fushuo Wu, Peiying Hu, Feiyue Hu, Zhihua Tian, Jingwen Tang, Peigen Zhang, Long Pan, Michel W. Barsoum, Longzhu Cai, ZhengMing Sun

Highlights

  • Curving 2D MXene into 1D nanofibers can effectively stop the restacking of MXene flakes, and then the nanofibers are used to construct a lightweight and multifunctional MXene/C aerogel.

  • The MXene/C aerogels achieved an RLmin of − 53.02 dB and EAB of 5.3 GHz. The radar cross-sectional reduction value of MXene/C aerogels can reach 12.02 dB m2.

  • Integrating multiple functions such as thermal insulation, sensing, and microwave absorption into one material—MXene/C aerogel.

二维过渡金属碳化物和氮化物(MXene)已成为微波吸收(MA)材料的有前途的候选者。但也存在阻抗匹配差、自堆叠倾向高、密度大等缺点。为了解决这些问题,MXene纳米片被整合到聚丙烯腈(PAN)纳米纤维中,随后通过PAN碳化组装成三维(3D)网络结构,得到MXene/C气凝胶。三维网络有效地扩展了微电流传输路径,从而增强了电磁波的导电损耗。此外,气凝胶丰富的孔隙结构显著改善了阻抗匹配,同时有效降低了mxene基吸收剂的密度。EM参数分析表明,MXene/C气凝胶的最小反射损耗(RLmin)值为- 53.02 dB (f = 4.44 GHz, t = 3.8 mm),有效吸收带宽(EAB)为5.3 GHz (t = 2.4 mm, 7.44 ~ 12.72 GHz)。通过雷达截面(RCS)模拟对MXene/C气凝胶的雷达隐身效果进行了评估,结果表明,MXene/C气凝胶覆盖的完美电导体的最大RCS降低值达到12.02 dB m2。除了MA性能外,MXene/C气凝胶也表现出良好的保温性能,5mm厚的气凝胶在82℃下可以产生超过30℃的温度梯度。该研究为创建轻质、高效、多功能的mxene基MA材料提供了一种可行的设计方法。
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引用次数: 0
期刊
Nano-Micro Letters
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