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Fault diagnosis of air compressor set-up using decision tree based J48 classification algorithm 基于决策树J48分类算法的空压机机组故障诊断
IF 0.9 4区 工程技术 Q3 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-12-01 DOI: 10.1016/j.jer.2023.09.028
Atul Dhakar, Bhagat Singh, Pankaj Gupta
This paper describes an air compressor fault diagnosis method based on the acquisition of audio signals pertaining to seven faulty and one healthy condition. These audio signals are processed using Local Mean Decomposition (LMD) signal processing technique. Further, statistical indicators have been evaluated for feature extraction considering the decomposed signals. From different statistical indictors mean, variance, root mean square (RMS), root mean amplitude (RMA), absolute mean amplitude (AMA), kurtosis, peak to peak index, waveform index, peak index, impulse index, margin index, skewness, Shannon entropy, standard deviation, log energy entropy, log detector and CPT has been selected for decision tree based J48 classification algorithm. Decision tree based J48 classification algorithm more accurately identified healthy and faulty bearing state in an air compressor with the help of all statistical indicators. Data set consists of 360 instances having 17 attributes with 2 classes (healthy and bearing fault). Higher classification accuracy of J48 algorithm (96.66 %) has been obtained for healthy and faulty bearing conditions. LMD along with decision tree based J48 classification algorithm is quite suitable for processing and monitoring in situ fault features in air compressor set-up.
本文介绍了一种基于7故障1健康音频信号采集的空压机故障诊断方法。这些音频信号使用局部均值分解(LMD)信号处理技术进行处理。此外,考虑到分解后的信号,对特征提取的统计指标进行了评估。从不同的统计指标均值、方差、均方根(RMS)、均方根振幅(RMA)、绝对平均振幅(AMA)、峰度、峰间指数、波形指数、峰值指数、脉冲指数、裕度指数、偏度、香农熵、标准差、对数能量熵、对数检测器和CPT等选择了基于决策树的J48分类算法。基于决策树的J48分类算法借助各种统计指标更准确地识别空压机轴承的健康和故障状态。数据集由360个实例组成,具有17个属性和2类(健康和轴承故障)。J48算法对健康和故障轴承状态的分类准确率达到96.66%。LMD结合基于决策树的J48分类算法非常适合于空压机机组现场故障特征的处理和监测。
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引用次数: 0
Statistical modelling to assessing and enhancing road traffic safety in Tripoli, Libya: A systematic approach 统计模型评估和加强在的黎波里,利比亚道路交通安全:一个系统的方法
IF 0.9 4区 工程技术 Q3 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-12-01 DOI: 10.1016/j.jer.2023.09.021
Enass Al Feki , Jamel Neji
In recent years, there is gradual increase in the needs for private vehicle ownership in Libya due to the lack and poor public transportation infrastructure which results in the growth of road traffic accidents (RTAs), particularly in Tripoli. Therefore, in order to evaluate RTAs, the current study used a systematic method that looks at three variables: the driver, the vehicle, and urban conditions. Besides, in order to explore the causes and factors that contribute to RTAs in the city, the current study used multiple correspondence analysis and logistic regression analysis to examine the data of 1) drivers and 2) vehicles involved in accidents, and 3) RTAs reported between 2015 and 2019 on twelve major urban roads in Tripoli. The findings show that each of the 12 chosen routes had a severity index (SI) above 10 and that RTAs regularly happened on those roads. RTAs most commonly happened as a result of driver negligence, which included speeding, being careless, failing to give priority, using a phone while driving, and negotiating bends incorrectly. While the results of the logistic regression analysis showed that increasing the width of the road median, crosswalks, and pedestrian bridges as well as the number of lanes and traffic signs would significantly increase road traffic safety (RTS), by following the distinct RTA-related factors such as sign boards on each road. A reduction in RTA frequency in Tripoli might be achieved by enhancing driver education and risk perception (drivers should maintain a high degree of awareness, refrain from distractions, respect traffic rules, and modify their driving style to the conditions of the road as well as their own physical and mental health), as the majority of RTAs there are caused by speeding and inattention, and by improving the nation's road infrastructure. The current study helps to design the policy of creating and putting into practice a systematic approach for safer roads in Tripoli.
近年来,由于缺乏和糟糕的公共交通基础设施,导致道路交通事故(rta)的增长,特别是在的黎波里,利比亚对私人车辆所有权的需求逐渐增加。因此,为了评估rta,目前的研究使用了一种系统的方法,该方法考虑了三个变量:驾驶员、车辆和城市条件。此外,为了探索导致城市rta的原因和因素,本研究采用多重对应分析和logistic回归分析,研究了2015年至2019年的黎波里12条主要城市道路上的驾驶员和事故车辆数据,以及3)报告的rta。研究结果显示,12条选定路线的严重程度指数(SI)均在10以上,并且这些道路上经常发生rta。rta最常见的原因是司机的疏忽,包括超速、粗心、没有优先考虑、开车时使用手机和转弯时不正确。logistic回归分析结果表明,增加道路中间线、人行横道和人行天桥的宽度,以及车道和交通标志的数量,可以显著提高道路交通安全(RTS),并遵循不同的rta相关因素,如每条道路上的标志。减少的黎波里RTA的频率可以通过加强驾驶员教育和风险认知来实现(驾驶员应保持高度的意识,避免分心,尊重交通规则,根据道路状况以及自己的身心健康调整驾驶风格),因为那里的大多数RTA是由超速和注意力不集中引起的,并且可以通过改善国家的道路基础设施来实现。目前的研究有助于制定政策,制定并实施的黎波里更安全道路的系统方法。
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引用次数: 0
Assessing coastal outfall impact on shallow enclosed bays water quality: Field and statistical analysis 评估海岸排放物对浅封闭海湾水质的影响:实地及统计分析
IF 0.9 4区 工程技术 Q3 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-12-01 DOI: 10.1016/j.jer.2023.09.031
Mohamad A. Alkhalidi , Sarah M. Hasan , Badreyah F. Almarshed
Shallow bays, valued for their environmental, economic, and social significance, face increasing threats from anthropogenic stressors, primarily wastewater discharge through coastal outfalls. The slow tidal currents in these bays hinder the effective dispersion of pollutants to deeper waters, exacerbating their impact. This study assesses the spatial effects of wastewater and brine discharges on Sulaibikhat Bay's water quality. The approach combines fieldwork, laboratory analysis, and statistical techniques to identify pollutant types, sources, and concentrations near outfalls, nearshore, and offshore areas. Throughout the study, high water temperatures were observed consistently, exceeding 30 °C in summer and 18.6 °C in winter near most outfalls, with a maximum deviation from the ambient water of 11.1 °C recorded in December. In addition to elevated electrical conductivity (EC) levels peaking at 60,700 μs/cm, these elevated temperatures significantly reduce dissolved oxygen levels and have been linked to fish kill events in the Bay. NH3-N, TSS, COD, BOD5, FC, and FS concentrations exceeded allowable limits in 56.4 %, 92.25 %, 40.30 %, 32.1 %, 70 %, and 63.36 % of samples, respectively, often reaching extreme levels. Also, the BOD5/COD ratios suggest the presence of non-biodegradable organic matter, mainly from industrial sewage, and the FC/FS levels implicate human and animal waste. These results indicate a mix of domestic, industrial, and commercial wastewater discharges and underscore the severe threat coastal outfalls pose to ecosystem health and water quality in Sulaibikhat Bay. Principal Component Analysis (PCA) and Cluster Analysis (CA) delineate two distinct environmental zones with varying characteristics and contamination levels, necessitating expanded monitoring. Finally, substantial field research, numerical modeling, and establishing a sustainable environmental management system are needed to protect this fragile ecosystem. Also, converting outfalls into offshore may mitigate the environmental status of the bay by enhancing pollutant dilution and dispersion.
浅海湾因其环境、经济和社会意义而受到重视,但它面临着越来越多的人为压力因素的威胁,主要是沿海排水口排放的废水。这些海湾缓慢的潮流阻碍了污染物向更深水域的有效扩散,加剧了它们的影响。本研究评估了污水和盐水排放对苏莱比哈特湾水质的空间影响。该方法结合了实地考察、实验室分析和统计技术,以确定污染物类型、来源和排放口附近、近岸和近海地区的浓度。在整个研究过程中,持续观察到高水温,在大多数出口附近夏季超过30°C,冬季超过18.6°C,与环境水的最大偏差在12月记录为11.1°C。除了电导率(EC)水平升高(峰值为60700 μs/cm)外,这些升高的温度显著降低了溶解氧水平,并与海湾中的鱼类死亡事件有关。NH3-N、TSS、COD、BOD5、FC和FS的超标比例分别为56.4%、92.25%、40.30%、32.1%、70%和63.36%,往往达到极限值。此外,BOD5/COD比值表明存在不可生物降解的有机物质,主要来自工业污水,而FC/FS水平涉及人类和动物粪便。这些结果表明了生活、工业和商业废水排放的混合,并强调了沿海排放物对苏莱比哈特湾生态系统健康和水质构成的严重威胁。主成分分析(PCA)和聚类分析(CA)描绘了两个不同的环境区域,具有不同的特征和污染水平,需要扩大监测。最后,需要大量的实地研究、数值模拟和建立可持续的环境管理系统来保护这一脆弱的生态系统。此外,将排污口转为近海,可加强污染物的稀释和扩散,从而改善海湾的环境状况。
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引用次数: 0
Thermal performance study of buildings and their corresponding scale models with identical constructions and geometrical similarity 具有相同结构和几何相似性的建筑物及其相应比例模型的热工性能研究
IF 0.9 4区 工程技术 Q3 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-12-01 DOI: 10.1016/j.jer.2023.10.022
Xiangfeng Liu , Miao Xu
Small-scale physical model testing can be applied to calibrate a computational building energy model based on the acquired reliable thermal performance data. The calibration approach using a small-scale physical model is a rigorous and cost effective means in order to do an accurate full-scale building energy simulation. It is meaningful to reveal the correlation of the thermal performance between a full-scale building and its scale model, so that the data from a small-scale model testing can be scalable to predict the performance of a full-scale building. The purpose of the research is to investigate the correlations reflecting the comparative thermal performance of a full-scale building against its scale model with identical constructions and geometrical similarity. More than ninety thousand scenarios about the typical target building zones and their corresponding scale models were generated via the parametric energy modeling and simulation approach. Then, the typical thermal performance indicator of each building zone, i.e. the zone mean air temperature (ZMAT), was obtained. The result shows that the zone mean air temperature difference between the target building and its scale model is a time dependent variable with the diurnal cycle. Compared with a fixed scale model, the bigger building causes the larger variation of zone mean air temperature difference. Furthermore, it also indicates that the zone mean air temperature difference can be approximated by a logarithmic regression function as ALn(SF/d)+B, where A and B are empirical coefficients associated with climate, building form, material and construction, as well as window-to-wall ratio. In engineering practice, the outcomes of the research are applicable for thermal performance estimation and energy model calibration of full-scale buildings, especially for a planned building with the available material and construction samples, but without the determined or reliable thermal performance data for the building.
基于获得的可靠的热性能数据,可以应用小尺度物理模型试验来校准计算建筑能量模型。为了进行精确的全尺寸建筑能量模拟,使用小尺寸物理模型的校准方法是一种严格且经济有效的方法。揭示全尺寸建筑的热工性能与其模型之间的相关性,使小尺寸模型试验的数据可以扩展到全尺寸建筑的性能预测中,具有重要的意义。本研究的目的是探讨反映全尺寸建筑与具有相同结构和几何相似性的比例模型的比较热性能的相关性。通过参数化能量建模与仿真方法,生成了典型目标建筑区域的9万多个场景及其相应的比例模型。然后,得到各建筑区域的典型热性能指标,即区域平均空气温度(ZMAT)。结果表明:目标建筑与其比例模型之间的区域平均温差是一个随日周期变化的时间变量。与固定比例尺模型相比,建筑物越大,区域平均温差变化越大。区域平均温差可以用对数回归函数近似表示为ALn(SF/d)+B,其中a和B是与气候、建筑形式、材料和构造以及窗墙比相关的经验系数。在工程实践中,研究结果适用于全尺寸建筑的热性能估算和能量模型校准,特别是对于具有可用材料和施工样品但没有确定或可靠的建筑热性能数据的规划建筑。
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引用次数: 0
Smart demand management based on economic and technical objective functions in the autonomous energy system 自主能源系统中基于经济和技术目标函数的智能需求管理
IF 0.9 4区 工程技术 Q3 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-12-01 DOI: 10.1016/j.jer.2024.02.006
María-Verónica Seminario-Morales , María-Gregoria Sánchez-Prieto , Nestor Cuba Carbajal , Manuel Enrique Chenet Zuta , Yersi-Luis Huamán-Romaní
This article introduces a novel approach to scheduling the autonomous energy system (AES) by taking into account both technical and economic considerations. To enhance the performance of the system during operation, demand management is proposed. This involves offering bid prices to consumers in order to reduce demand during emergencies. The study aims to achieve multiple objectives, including minimizing operational costs and improving voltage indices, through the use of multi-objective modeling. The Particle Swarm Optimization (PSO) algorithm is employed to optimize this multi-objective problem. The fuzzy max-min method is then applied to obtain the desired optimal solution from the set of non-dominated solutions. To demonstrate the effectiveness and validity of the proposed strategy, two case studies are conducted on the 33 bus IEEE test system. The participation of demand management by consumers leads to improving operational costs and voltage indices by 6.12%% and 20% in comparison with non-participation of the consumers.
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引用次数: 0
Effect of electron beam irradiation on estrogens removal from treated wastewater 电子束辐照对废水中雌激素去除的影响
IF 0.9 4区 工程技术 Q3 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-12-01 DOI: 10.1016/j.jer.2023.09.013
Abdallah Abusam , Talat Saeed , Adel Al-Haddad , Rashed Al-Yaseen
In order to remove micro pollutants such as estrogens efficiently from wastewater, it is often recommended that conventional wastewater treatment plants (WWTP) be retrofitted with an advanced oxidation process (AOP) for post-treatment purposes. This study examined the effects of electron beam (EB) absorbed dose on the removal of estrogens from biologically treated wastewater. Known concentrations of E1, E2, E3 and EE2 (0.2, 0.5, 5.0 and 10 µg/l) were spiked into samples obtained from a municipal wastewater plant, which were then irradiated with EB doses of 0.2, 2.0, 5.0 and 10.0 kGy. Levels of estrogen after irradiation were analyzed using the liquid-chromatography mass-spectrometry (LC-MS). According to the results obtained, the concentration of estrogens decreased steadily with an increasing absorbed dose up to 2 kGy. However, there was no significant increase in estrogen removal at EB doses above 2 kGy. It is estimated that the removals of the different types of estrogen are ranged from 86 % to 99 %. E2 was found to be the fastest estrogen to be degraded, followed by E3, EE2, and E1.
为了有效地去除废水中的微污染物,如雌激素,通常建议对传统的废水处理厂(WWTP)进行改造,采用高级氧化工艺(AOP)进行后处理。研究了电子束吸收剂量对生物处理废水中雌激素去除的影响。将已知浓度的E1, E2, E3和EE2(0.2, 0.5, 5.0和10µg/l)加入到从城市污水厂获得的样品中,然后用0.2,2.0,5.0和10.0 kGy的EB剂量照射。采用液相色谱-质谱法(LC-MS)分析辐照后雌激素水平。根据所获得的结果,雌激素浓度随着吸收剂量的增加而稳定下降,直至2 kGy。然而,当EB剂量超过2 kGy时,雌激素去除量没有显著增加。据估计,不同类型雌激素的去除率在86%到99%之间。E2是降解最快的雌激素,其次是E3、EE2和E1。
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引用次数: 0
Operation of the stand-alone electrical system based on optimal energy management 基于最优能量管理的单机电力系统运行
IF 0.9 4区 工程技术 Q3 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-12-01 DOI: 10.1016/j.jer.2023.10.020
R. Sivaraman , Biju Theruvil Sayed , Oriza Candra , Rosario Mireya Romero-Parra , Iskandar Muda , Mohaimen Al-Thamir , Ibrahim H. Al-Kharsan
This paper focuses on optimizing the energy of a stand-alone energy grid by incorporating energy storages and demand side participation. The increasing popularity of energy storage systems and demand side participation is mainly attributed to their advantages, such as the ease of distribution in electrical networks and operational flexibility during critical periods. The main objective functions of the model involve optimizing the stand-alone electrical grid by maximizing efficiency and minimizing energy costs. The efficiency is modelled by energy not supplied. The costs of energy consumption are represented by the fuel costs consumed by resources. To encourage consumers to reduce their demand during peak times, an incentive approach is suggested for their participation. Additionally, a hydrogen storage system is operated in the stand-alone energy grid to enhance the primary objectives. The particle swarm optimization (PSO) algorithm is utilized to optimize energy usage and solve objective functions. Numerical simulations are conducted in two case studies to validate and demonstrate the effectiveness of energy optimization when incorporating storage system and consumers. The case studies based on non-participation and participation of the storage system and consumers in the energy management are implemented. With participation of the storage system and consumers, efficiency and energy costs are improved by 3% and 29.8% than non-participation of them.
本文的重点是通过结合储能和需求侧参与来优化独立电网的能量。储能系统和需求方参与的日益普及主要归功于它们的优势,例如易于在电网中分配和关键时期的操作灵活性。该模型的主要目标函数包括通过最大化效率和最小化能源成本来优化独立电网。效率是通过不提供的能量来模拟的。能源消耗的成本由资源消耗的燃料成本表示。为了鼓励消费者在高峰时段减少用电需求,我们建议采用一种激励方法来鼓励他们参与。此外,氢存储系统在独立的能源网中运行,以增强主要目标。利用粒子群算法对能量利用进行优化,求解目标函数。在两个案例中进行了数值模拟,以验证和展示在结合存储系统和消费者时能量优化的有效性。对基于储能系统和用户参与能源管理的不参与和参与进行了案例研究。在储能系统和消费者参与的情况下,效率和能源成本分别比不参与的情况下提高3%和29.8%。
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引用次数: 0
COVID-19 and the construction sector: Impacts and an agenda for post-pandemic policy in the context of Kuwait COVID-19 与建筑部门:对科威特的影响和流行病后政策议程
IF 0.9 4区 工程技术 Q3 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-12-01 DOI: 10.1016/j.jer.2023.11.017
Mohamed Salem , Richard Kirkham , Ruqaya Al-Sabah , Samara Chebli

Purpose

Amidst the global upheaval, Kuwait's construction industry confronts unique challenges, serving as a microcosm for pandemic-induced disruptions examined in this study. This research offers a pivotal analysis of COVID-19's disruptive impact on Kuwait's construction projects, enriched with comparative global insights to bolster industry adaptability and recovery strategies.

Design/methodology/approach

A mixed-method approach involving a systematic literature review and 17 semi-structured in-depth interviews with construction experts, including contractors and suppliers from construction industry in Kuwait.

Findings

The findings showed that during the COVID-19 pandemic, construction projects faced numerous challenges, including government-imposed lockdowns, increased safety measures, and a fear of infection among workers, leading to delays and increased overhead costs. Post-pandemic recovery strategies highlighted in the interviews include strict adherence to health guidelines, visa extensions for laborers, additional hiring, and embracing digital transformation to enhance productivity. However, the high costs of technology and a need for more skilled personnel have hindered digital adoption in the construction industry.

Practical implications

Practical implications for moving forward emphasize government financial support and incentives to aid the construction sector's recovery and advancement in the post-pandemic economy. Government institutions and stakeholders developed and executed a number of approaches and measures to successfully address the effects of the COVID-19 epidemic on the Kuwaiti construction sector.

Originality/value

This paper contributes to a paucity in evidence on the impact of pre and post COVID-19 pandemic in the context of the Kuwaiti construction sector. The study used a mixed method research using systematic literature review and qualitative study. This is the first study that qualitatively investigate the effect of the pandemic on construction projects in Kuwait.
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引用次数: 0
Effect of pore forming agents on the properties and performance of the supported liquid membrane for levulinic acid separation 孔隙形成剂对用于分离乙酰丙酸的支撑液体膜的性质和性能的影响
IF 0.9 4区 工程技术 Q3 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-12-01 DOI: 10.1016/j.jer.2024.01.003
Vikneswary Rajendaren, Syed M. Saufi, M.A.K.M. Zahari
The porosity of the membrane support plays a crucial role in the performance and efficiency of the supported liquid membrane (SLM) process. The formation of pores and the membrane porosity value can be improved by adding a pore-forming agent in the dope solution during membrane manufacturing. The objective of this study is to investigate the effect of pore-forming additives such as polyethyleneglycol (PEG) 200, PEG 20,000, lithium chloride, Tween-80, and polyvinyl pyrrolidone (PVP 10,000) on the polyethersulfone (PES) membrane properties and their performance in the separation of levulinic acid (LA) using the SLM method. The morphology, contact angle, porosity, and tensile strength of the membrane were evaluated. Among the pore-forming agents tested, PEG 200 emerged as the most effective in inducing a sponge-like structural wall in the PES membrane. It achieved a remarkable porosity level of 87.1%, displaying contact angles of 81.2° and 98° at the top and bottom surfaces, respectively, as well as a high tensile strength of 1032.88 kPa. The membrane achieved the highest extraction of 8.92 g/L LA in the SLM process using a 10 g/L LA aqueous feed solution.
{"title":"Effect of pore forming agents on the properties and performance of the supported liquid membrane for levulinic acid separation","authors":"Vikneswary Rajendaren,&nbsp;Syed M. Saufi,&nbsp;M.A.K.M. Zahari","doi":"10.1016/j.jer.2024.01.003","DOIUrl":"10.1016/j.jer.2024.01.003","url":null,"abstract":"<div><div>The porosity of the membrane support plays a crucial role in the performance and efficiency of the supported liquid membrane (SLM) process. The formation of pores and the membrane porosity value can be improved by adding a pore-forming agent in the dope solution during membrane manufacturing. The objective of this study is to investigate the effect of pore-forming additives such as polyethyleneglycol (PEG) 200, PEG 20,000, lithium chloride, Tween-80, and polyvinyl pyrrolidone (PVP 10,000) on the polyethersulfone (PES) membrane properties and their performance in the separation of levulinic acid (LA) using the SLM method. The morphology, contact angle, porosity, and tensile strength of the membrane were evaluated. Among the pore-forming agents tested, PEG 200 emerged as the most effective in inducing a sponge-like structural wall in the PES membrane. It achieved a remarkable porosity level of 87.1%, displaying contact angles of 81.2° and 98° at the top and bottom surfaces, respectively, as well as a high tensile strength of 1032.88 kPa. The membrane achieved the highest extraction of 8.92 g/L LA in the SLM process using a 10 g/L LA aqueous feed solution.</div></div>","PeriodicalId":48803,"journal":{"name":"Journal of Engineering Research","volume":"12 4","pages":"Pages 616-620"},"PeriodicalIF":0.9,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139393977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
True order determination of sonochemical degradation kinetics of organic contaminants in water using the half-lives method 利用半衰期法对水中有机污染物的声化学降解动力学进行真序测定
IF 0.9 4区 工程技术 Q3 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-12-01 DOI: 10.1016/j.jer.2024.01.015
Maher Alrashed, Oualid Hamdaoui
In the literature, the modeling of the sonolytic decomposition kinetics of organic contaminants in water has been carried out using the pseudo-first and pseudo-second order equations. The results obtained with this method are totally biased because it requires the assumption of the order of the degradation reaction, which is a real limitation, and the sonochemical oxidation mechanism is a very complex phenomenon that cannot be described by such simple models. In this paper, for the first time, the true order of the sonochemical degradation kinetics of organic pollutants in aqueous solutions at various initial substrate concentrations was determined using the half-lives method combined with the general rate law model, i.e., the pseudo-nth order equation. Linear and nonlinear regression techniques were used to determine the order of the sonolytic destruction reaction. The half-life technique for the general rate law model can adequately describe the experimental results of the sono-destruction of the investigated pollutants. For rhodamine B and naphthol blue black, the sono-destruction mechanism for both contaminants does not change as the initial contaminant concentration varies over the range examined, while for 4-isopropylphenol and furosemide, the sono-destruction mechanism changes as the initial substrate concentration varies. A fractional order of the sonolytic destruction reaction was determined for all the pollutants tested. These fractional orders of sono-destruction reactions indicate the complex nature and behavior of the reactions, often involving multiple steps or mechanisms. They also reveal a more complex interaction between pollutant concentration and sonolytic destruction rate. In a word, the method developed in this paper should be used to determine the real order of the sono-oxidation reaction of nonvolatile organic pollutants in aqueous phase.
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引用次数: 0
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Journal of Engineering Research
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