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Optimum site selection for oil spill response center in the Marmara Sea using the AHP-TOPSIS method 利用AHP-TOPSIS法对马尔马拉海溢油应急中心进行选址优化
IF 1.5 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-04-01 DOI: 10.24425/aep.2018.122302
B. Koseoglu, M. Buber, A. Toz
The aim of this study is to determine the optimum location for an oil spill response center in the Marmara Sea. The analytic hierarchy process (AHP) and technique for the order of preference by similarity to ideal solution (TOPSIS) method as the most preferred multi-criteria decision-making (MCDM) technique were used. The results reveal that the LOC criterion and PRA sub-criterion have the highest effects on the optimal location selection of the oil spill response center. According to the results, the most suitable location for the oil spill response center in the region is Izmit Bay Entrance. This location has been proposed for the response headquarters to manage the whole operation with the assistance of auxiliary installations in the area. In this study, only technical and operational variables are taken into account, but political and administrative criteria are excluded. Optimum site selection for oil spill response center in the Marmara Sea using the AHP-TOPSIS method 39 an integer programming model to determine the strategic response operations, which mainly aims to set optimum reaction times. Verma et al. (2013) developed a probabilistic formulation that optimizes the location and capacity of oil spill response centers. Ha (2018) performed a local pollution risk assessment based on accident probability and post-accident sensitivity using the AHP method in Korea. The studies focusing on oil spill matters are mostly concentrated in the strategic regions including straits, narrow channels, gateways and inner seas. For this reason, the Marmara Sea and the Turkish straits have always been in the focus of those studies for years. Guvenet al. (1996) performed a study dealing with the effects of oil pollution from Nassia tanker in Istanbul Strait. Otay and Yenigun (2000) simulated the weathering processes of oil spill from Volganeft-248 in Istanbul Strait. Ors (2003) and Basar (2010) used simulation technique to predict weathering processes of oil in the Marmara Sea and Istanbul Strait. Dogan and Burak (2007) aimed to determine ecological hazard level in Turkish straits and Marmara Sea considering ship originated pollution. Alpar and Unlu (2007) performed environmental risk assessment through “chemical fi ngerprint approach” after the Volganeft-248 accident. Basar et al. (2006) utilized simulation technique to fi nd risky areas for oil spillage after tanker accident at Istanbul Strait. Guven et al. (2007) aimed to determine pollution level of sediments of Turkish Straits and the Marmara Sea using sampling method between 2005 and 2007. Unlu (2007), in his study, characterized the chemical composition of the unknown oil spilled from the Haydarpasa Port through “advanced fi ngerprinting techniques and diagnostic ratio” method. Birpınar et al. (2009) tried to defi ne environmental effects of maritime traffi c on the Istanbul Strait through literature review. Bozkurtoglu (2017) used simulation technique to predict oil spill trajectory in the Istanbul
本研究的目的是确定马尔马拉海溢油响应中心的最佳位置。采用层次分析法(AHP)和TOPSIS法作为最优多准则决策(MCDM)技术。结果表明,LOC准则和PRA子准则对溢油应急中心的最优选址影响最大。根据研究结果,该地区最适合设立溢油应急中心的地点是伊兹米特湾入口。这个地点已被提议作为应急总部,以便在该地区辅助设施的协助下管理整个行动。在这项研究中,只考虑到技术和业务变量,但排除了政治和行政标准。采用AHP-TOPSIS方法,利用整数规划模型确定马尔马拉海溢油应急响应中心的最佳选址策略,其主要目的是设定最佳反应时间。Verma等人(2013)开发了一种概率公式,可以优化溢油响应中心的位置和能力。Ha(2018)在韩国使用AHP方法进行了基于事故概率和事故后敏感性的当地污染风险评估。针对溢油问题的研究多集中在海峡、狭窄航道、门户、内海等战略区域。因此,马尔马拉海和土耳其海峡多年来一直是这些研究的重点。Guvenet al.(1996)进行了一项关于伊斯坦布尔海峡Nassia油轮油污影响的研究。Otay和Yenigun(2000)模拟了伊斯坦布尔海峡Volganeft-248溢油的风化过程。Ors(2003)和Basar(2010)利用模拟技术预测了马尔马拉海和伊斯坦布尔海峡石油的风化过程。Dogan和Burak(2007)考虑船舶污染,旨在确定土耳其海峡和马尔马拉海的生态危害水平。Alpar和Unlu(2007)在Volganeft-248事故后通过“化学指纹法”进行了环境风险评估。Basar et al.(2006)利用模拟技术在伊斯坦布尔海峡寻找油轮事故后的溢油危险区域。Guven et al.(2007)在2005年至2007年期间采用采样法测定了土耳其海峡和马尔马拉海沉积物的污染水平。Unlu(2007)在他的研究中,通过“先进的指纹技术和诊断比率”方法表征了Haydarpasa港泄漏的未知石油的化学成分。Birpınar等人(2009)试图通过文献综述来界定海上交通对伊斯坦布尔海峡的环境影响。Bozkurtoglu(2017)使用模拟技术预测了伊斯坦布尔海峡的溢油轨迹。文献中有许多科学研究用多准则决策方法模型寻求解决设施选址问题的方法。Yap et al.(2017)和Hong and Xiaohua(2011)利用AHP方法设置应急物流中心的最优位置。在多准则决策问题的求解中,AHP和TOPSIS已被许多研究综合运用。文献表明,AHP-TOPSIS方法是首选,特别是在填埋场选址问题的解决方案方面(Beskese等人2015,Soltanalizadeh等人2014,ertugrand Karakasoglu 2008, Hanine等人2016,Yari等人2013,Kharat等人2016,Hanine等人2017)。此外,Gumusay et al.(2016)和Coskun(2016)进行了旨在确定住宅区和码头建筑工地最佳位置的研究。综上所述,虽然文献中已经有很多关于紧急情况下的选址研究,但溢油应急中心的最佳选址问题是一个值得关注的问题。材料和方法本研究的目的是使用AHP-TOPSIS方法确定马尔马拉海溢油响应中心的最佳位置。为此,首先查阅相关文献,然后征求专家意见。采用层次分析法计算各参数的权重。然后,考虑每个备选方案的排名,使用TOPSIS方法。最后,通过案例研究进行了假设研究,以寻找马尔马拉海溢油响应中心的最佳位置。本研究的评价流程如图1所示。图1所示。建议的研究模型来源:由作者创建。40 B. Koseoglu, M. Buber, A.C. Toz从图中可以理解,首先,确定了决策问题和研究地点,在确定了研究地点之后,确定了石油泄漏响应中心的备选地点。 然后,通过文献综述和专家意见得出响应地点的评价标准。利用所提供的数据进行了层次分析法,并计算了权重比。最后进行TOPSIS,计算各备选方案的排名。AHP算法AHP方法的目的是通过将给定的一组选项的相关优先级放在一个尺度上,以考虑决策者的个人判断和该过程中选择的比较一致性,确保以最有效的方式完成决策过程。这种方法支持基于决策者的知识和经验的判断。AHP在多标准环境中提供了一种简单有效的解决方案,它考虑到所有因素以及组织可数因素和不可数因素的系统方法(Saaty和Vargas, 1982)。层次分析法的步骤解释如下(Saaty 1980);步骤1:在第一阶段,建立解释主要研究问题的层次结构。层次结构应该包括顶部的主要目标和底部的备选目标。正确确定影响端点的标准数量并对每个标准进行详细描述是很重要的,这样就可以一致地、合乎逻辑地进行两两比较。层次分析法的标准层次结构如图2所示。步骤2:在建立层次模型后,构建两两比较决策矩阵,在每个因素的基础上对备选方案进行评价,确定因素本身的重要程度。
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引用次数: 11
Encapsulation of halloysite with sodium alginate and application in the adsorption of copper from rainwater 海藻酸钠包埋高岭土及其在雨水中铜吸附中的应用
IF 1.5 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-04-01 DOI: 10.24425/aep.2022.140546
Anna Marszałek
by-products (Li et al. 2020). Currently, new sorption materials have been found for water purification that are readily available, economical and environmentally friendly. Clay materials are one of the cheap and natural adsorbents (Zhao et al. 2021). The use of natural clay minerals as adsorbents is widely used due to their high efficiency, relatively low operating costs and the possibility of recycling and regeneration (Derafa Garmia et al. 2018). Encapsulation has many advantages. One of them is the immobilization of the fine adsorbent powder. Adsorption with finely powdered material causes problems in recovering fine clay particles from the water, which additionally increases the turbidity of the water. Therefore, encapsulation of halloysite with sodium alginate polymer can be proposed as a solution to avoid these problems. Adsorbents should have good sorption capacity for heavy metals and appropriate porosity ensuring their removal (Pawar et al. 2020). As part of this study, laboratory-scale experiments were carried out to assess the effectiveness of the use of composite capsules based on halloysite and sodium alginate for the adsorption of copper
副产品(Li et al. 2020)。目前,人们已经发现了易于获得、经济环保的新型水净化吸附材料。粘土材料是廉价的天然吸附剂之一(Zhao et al. 2021)。天然粘土矿物作为吸附剂因其效率高、运行成本相对较低、可回收再生而被广泛使用(Derafa Garmia et al. 2018)。封装有很多优点。其中之一是细吸附粉的固定化。细粉状材料的吸附会导致从水中回收细粘土颗粒的问题,这又增加了水的浊度。因此,可以提出用海藻酸钠聚合物包封高岭土作为避免这些问题的解决方案。吸附剂应具有良好的重金属吸附能力和适当的孔隙度,以确保其去除(Pawar etal . 2020)。作为本研究的一部分,进行了实验室规模的实验,以评估使用基于高岭土和海藻酸钠的复合胶囊吸附铜的有效性
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引用次数: 2
Removal of cyclohexane and ethanol from air in biotrickling filters inoculated with Candida albicans and Candida subhashii 接种白色念珠菌和苏氏念珠菌的生物滴滤器去除空气中的环己烷和乙醇
IF 1.5 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-04-01 DOI: 10.24425/aep.2021.136445
P. Rybarczyk, Milena Marycz, Bartosz Szulczyński, A. Brillowska-Dąbrowska, Agnieszka Rybarczyk, J. Gębicki
This paper presents investigations on the removal of cyclohexane and ethanol from air in polyurethane-packed biotrickling filters, inoculated with Candida albicans and Candida subhashii fungal species. Results on process performance together with flow cytometry analyses of the biofilm formed over packing elements are presented and discussed. The results indicate that the presence of ethanol enhances the removal efficiency of cyclohexane from air. This synergistic effect may be attributed to both co-metabolism of cyclohexane with ethanol as well as increased sorption efficiency of cyclohexane to mineral salt medium in the presence of ethanol. Maximum elimination capacities of 89 g m-3 h-1 and 36.7 g m-3 h-1 were noted for cyclohexane and ethanol, respectively, when a mixture of these compounds was treated in a biofilter inoculated with C. subhashii. Results of flow cytometry analyses after 100 days of biofiltration revealed that about 91% and 88% of cells in biofilm remained actively dividing, respectively for C. albicans and C. subhashii species, indicating their good condition and ability to utilize cyclohexane and ethanol as a carbon source. Removal of cyclohexane and ethanol from air in biotrickling fi lters inoculated with Candida albicans... 27 break the mass transfer barrier between gaseous and aqueous (i.e. biofilm) phases and the rate of their biodegradation is mainly governed by the rate of biodegradation within the biofilm. Contrary, for poorly water-soluble compounds, i.e. hydrophobic ones, the efficiency of biofiltration depends greatly on the mass transfer rate between the above mentioned phases, and thus the biofiltration efficiency is much lower than for hydrophilic compounds (Cheng et al. 2016; Gospodarek et al. 2019). Several measures may be applied to improve the biofiltration performance with respect to hydrophobic compounds, including the addition of surfactants, especially biosurfactants, application of selected microbial species, including fungi, reactor modification, selection of proper process conditions as well as co-treatment with hydrophilic compounds (Cheng et al. 2020; He et al. 2020; Miller et al. 2019; Miller et al. 2020; Rybarczyk et al. 2020, 2019b; Yang et al. 2018, 2010). In this paper, the possibility of using selected Candida fungi to simultaneously remove from air compounds with extremely different affinity to the aqueous phase was investigated. Hydrophobic cyclohexane and hydrophilic ethanol were used as model compounds. These compounds are found in post-processing gases from, e.g., paint, petroleum and food industries (Avalos Ramirez et al. 2007; Zhanga et al. 2018). Biotrickling filtration of air containing single cyclohexane or ethanol was previously investigated (Avalos Ramirez et al. 2007; Cox et al. 2001; Salamanca et al. 2017). In this paper, a mixture of cyclohexane and ethanol was subjected to biofiltration in two biotrickling filters, inoculated with Candida albicans and Candida subhashii, respecti
本文研究了接种白色念珠菌和亚哈氏念珠菌的聚氨酯填料生物滴滤器对空气中环己烷和乙醇的去除效果。介绍并讨论了工艺性能的结果以及在填料上形成的生物膜的流式细胞术分析。结果表明,乙醇的存在提高了空气中环己烷的脱除效率。这种协同效应可能是由于环己烷与乙醇的共代谢以及在乙醇存在下环己烷对无机盐介质的吸附效率提高。当环己烷和乙醇的混合物在接种了梭菌的生物过滤器中处理时,最大的清除能力分别为89 g m-3 h-1和36.7 g m-3 h-1。生物滤过100天后的流式细胞术分析结果显示,白色念珠菌和亚哈希念珠菌的生物膜细胞仍有91%和88%的活性分裂,表明它们具有良好的条件和利用环己烷和乙醇作为碳源的能力。接种白色念珠菌生物滴滤器去除空气中环己烷和乙醇的研究打破气相和水相(即生物膜)之间的传质屏障,其生物降解速率主要由生物膜内的生物降解速率决定。相反,对于水溶性差的化合物,即疏水化合物,生物过滤的效率在很大程度上取决于上述相之间的传质速率,因此生物过滤效率远低于亲水化合物(Cheng et al. 2016;Gospodarek et al. 2019)。可以采用几种措施来改善疏水化合物的生物过滤性能,包括添加表面活性剂,特别是生物表面活性剂,应用选定的微生物物种,包括真菌,对反应器进行改造,选择适当的工艺条件以及与亲水性化合物共处理(Cheng et al. 2020;He et al. 2020;Miller et al. 2019;Miller et al. 2020;Rybarczyk et al. 2020, 2019b;Yang et al. 2018, 2010)。本文研究了选用念珠菌同时去除空气中对水相亲和性差异极大的化合物的可能性。以疏水环己烷和亲水乙醇为模型化合物。这些化合物存在于油漆、石油和食品工业的后处理气体中(Avalos Ramirez等人,2007年;Zhanga et al. 2018)。生物滴滤法过滤含有单环己烷或乙醇的空气以前进行过研究(Avalos Ramirez等人,2007;Cox et al. 2001;Salamanca et al. 2017)。本文将环己烷和乙醇的混合物分别接种白色念珠菌和subhashii念珠菌,在两个生物滴滤器中进行生物过滤。采用流式细胞术对两种生物滴滤器形成的生物膜组成进行了寄生真菌的纯度检测,并对工艺启动和稳态运行条件进行了比较。据本文作者所知,上述真菌迄今尚未用于空气净化的生物滴滤器中,寻找能够生物降解污染物的新物种,特别是疏水性微生物,是环境研究的一个重要趋势。材料与方法:采用内径0.08 m,高0.68 m的有机玻璃柱制成生物滴滤器。生物过滤器用聚氨酯泡沫盘填充(孔径PPI 10, Ultramare,波兰;单片尺寸:直径0.08米,高0.01米),工作容积为2.5 dm3。生物过滤器从底部注入混合气体,而液体则通过蠕动泵从生物反应器顶部注入。空气与环己烷和乙醇的气态混合物(POCH,波兰)是通过一个多孔烧结通过含有液体环己烷和乙醇的小瓶经过纯化和干燥的空气。使用精确的质量流量控制器(Vögtlin,瑞士)控制和调节气体流量。在整个实验过程中,气体流速为2.5 dm3 min-1,导致空床停留时间(EBRT)等于1 min。使用MPX5010dp传感器(NXP,荷兰)监测生物滴滤器填料的压降,工作范围为0至10 kPa。在整个试验过程中,最大注意压力不超过2 kPa,未观察到生物量过度生长。从进出口气流中提取含环己烷和乙醇的气体样品。 样品采集于Tedlar袋中,采用DB-WAX色谱柱(30 m × 0.53 mm × 1 μm;安捷伦科技公司,美国)和火焰电离检测器(Varian CP-3800, VarianAnalytical Instruments,美国)。氮气被用作载气。分析程序参数如下:烘箱温度:100℃;FID检测器温度:200℃,载气流量:3 cm3 min-1;分割比例:10。在启动期间(生物过滤过程的前7-10天),用缓冲蛋白胨水培养基(德国默克公司)滴注生物过滤器的填料元件。然后介绍了无机盐介质(MSM)。MSM含有溶解于1 dm3蒸馏水中的以下盐:Na2HPO4·2H2O (7.39 g)、KH2PO4 (3 g)、NaCl (0.5 g)和NH4Cl (1 g)(波兰POCH)。滴注液体溶液在引入生物过滤器(Prestige Medical, England)之前进行高压灭菌,在整个报告期间每周更换一次MSM溶液。以每小时0.5分钟的频率,以0.2 dm3 min-1的体积流量,在填料元件上喷洒滴液。在生物过滤启动之前,用聚氨酯泡沫盘制成的填料接种白色念珠菌(生物滴滤器“A”)和假丝酵母菌(生物滴滤器“B”)。使用无菌烧杯(体积为1 dm3)将真菌固定在聚氨酯圆盘上,其中放置600 cm3的Sabouraud培养基(BTL,波兰),其中含有10% (v/v)的选定真菌种接种物。这些烧杯在轨道激振器(100转/分,24°C)中搅拌。摇动24小时后,用新鲜的MSM溶液替换一半的中体积。在接下来的24小时震动后,整个介质体积被新鲜的MSM溶液所取代。然后,重复类似的程序,但按照上述两步将MSM溶液替换为Sabouraud培养基。接种时间为120 h。每天接种,取培养基样品,使用Thermo Scientific Multiskan FC分光光度计(Thermo Fisher Scientific, Finland)在波长595 nm处进行常规光密度测量。进行了两个系列的实验。在第一个系列(I)中,研究了两个生物滴滤器A和B的性能。两个生物滴滤器最初只加入环己烷,在过程的第38天,将乙醇引入气流。此外,流式细胞术分析旨在确定居住在生物过滤器填料元件的微生物种群的一般情况。在第二系列实验(II)中,研究了一种接种了苏氏弧菌的生物滴滤器。这两种真菌的选择是由于白色念珠菌的致病特性以及预期的C. subhashii在疏水挥发性有机化合物的生物滴滤中的高性能。在这个系列中,生物过滤器是由环己烷和乙醇的混合物从工艺启动。本方法旨在研究乙醇添加对28 P. Rybarczyk, M. Marycz, B. Szulczyński, A. Brillowska-Dąbrowska, A. Rybarczyk, J. Gębicki环己烷生物过滤性能的影响,并与系列i的实验进行比较。在系列II的实验中,还研究了液相(MSM)在生物过滤过程中pH的变化以及处理化合物浓度的变化。实验采用亚甲基蓝染色技术(Sigma Aldrich, USA)来评估生物膜的形成,在聚氨酯泡沫元件上含有被测真菌。采用10倍工作距离透镜的透射光学显微镜(LAB 40系列光学显微镜,OPTA-TECH,波兰)拍摄固定化真菌的照片。为了进行细胞分析,从每个工作的生物过滤器中取出单个聚氨酯圆盘。将每个圆盘置于烧杯中,悬浮于40cm3的0.01 M磷酸盐缓冲盐水溶液(PBS, pH = 7.6)中,并在超声波浴(Bandelin Sonorex,德国)中摇4次,每次摇15秒。在每一步摇动之后,将一个带圆盘的烧杯放在水冰浴中15秒。细胞悬浮液用400目尼龙
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引用次数: 6
Study of catalytic processes for biodiesel production wastewater treatment 生物柴油生产废水的催化处理研究
IF 1.5 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-04-01 DOI: 10.24425/aep.2019.127981
T. Borralho, Solange Coelho, Andreia Estrelo
The study of the possibility of removing organic compounds from wastewater originating from the biodiesel purifi cation stage by two catalytic processes, HSO5 -/transition metal and Fenton method has been presented. The source of the ion HSO5 is potassium monopersulphate (2KHSO5∙KHSO4∙K2SO4) (Oxone) that may be decomposed into radicals (OH., SO4 -., SO5 -.) by means of transition metal as Co (II). Different concentrations were used for both compounds and the combination ([Co2+] =1.00μM/[HSO5 -] =5.00×10-2 M) achieved the highest COD removal (60%) and complete decomposition of the oxidant was verifi ed for contact times of 45 min. This process has some advantages comparing to the conventional Fenton method such as the absence of the costly pH adjustment and the Fe(III) hydroxide sludge which characterize this treatment process. The Fenton process showed that the combination of [H2O2] =2.00M/[Fe 2+] = 0.70 M was the best and archived COD removal of 80%. The treatments studied in this research have achieved high COD removal, but the wastewater from the biodiesel purifi cation stage presents very high parametric values of Chemical Oxygen Demand (667,000 mgO2/L), so the fi nal COD concentration reached is still above the emission limit of discharge in surface water, according the Portuguese Law (Decree-Law 236/98). However, both treatments have proved to be feasible techniques for the pre-oxidation of the wastewater under study and can be considered as a suitable pre-treatment for this type of wastewaters. A rough economic analysis of both processes was, also, made. Archives vol 45 no 2 a4 srodki.indd 66 2019-05-09 14:53:01 Study of catalytic processes for biodiesel production wastewater treatment 67 2012, Chi et al. 2016, Wang and Chu 2012) thereby providing mechanisms for reaction with some advantages comparing to hydroxyl radicals (Hu and Long 2016, Oh et al. 2016). Oxone can also be decomposed into radicals by means of transition metals, such as Co (II), Ru (II) and Mn (II) (Rivas et al. 2012), according Eqs.1, 2 and 3: HSO5 + M n+ → SO4 .+M(n+1) + + OH(Eq. 1) HSO5 + M n+ → SO4 +M(n+1) + + OH. (Eq. 2) HSO5 + M n+ → SO5 +M(n+1) + + H+ (Eq. 3) M = Co (II), Ru (II) or Mn (II) Co (II) has been reported as one of the most effective metal catalysts for the activation of HSO5 promoting a radical sulphate complex mechanism (Rivas et al. 2012, Sun et al. 2009). So, the main objective of this study was to evaluate the performance of two catalytic treatments based in advanced oxidation processes; the traditional Fenton process and the emerging treatment that uses the compound monopersulphate (HSO5 -) on the removal of wastewater COD from the biodiesel purifi cation stage. Several combinations of the amounts of oxidant/catalyst have been investigated and optimum conditions assessed. Materials and methods Materials and chemical reagents Table 1 summarises the physicochemical characteristics of the biodiesel wastewater used, provided by PRIO (Prio Energy Co). T
研究了HSO5 -/过渡金属法和Fenton法两种催化工艺去除生物柴油净化废水中有机物的可能性。离子HSO5的来源是一过硫酸钾(2KHSO5∙KHSO4∙K2SO4) (Oxone),可能被分解成自由基(OH)。, so4 -。两种化合物使用不同的浓度([Co2+] =1.00μM/[HSO5 -] =5.00×10-2 M),达到了最高的COD去除率(60%),并且在接触时间为45分钟的情况下证实了氧化剂的完全分解。与传统的Fenton法相比,该工艺具有一些优点,例如没有昂贵的pH调整和Fe(III)氢氧化物污泥,这是该处理过程的特征。Fenton工艺结果表明,[H2O2] =2.00M/[fe2 +] = 0.70 M的组合效果最佳,COD去除率达80%。本研究所研究的处理方法均取得了较高的COD去除率,但生物柴油净化阶段废水的化学需氧量参数值非常高(667,000 mgO2/L),因此最终达到的COD浓度仍高于葡萄牙法律(法令236/98)规定的地表水排放限值。然而,这两种处理方法已被证明是对所研究的废水进行预氧化的可行技术,可以被认为是这类废水的合适预处理方法。对这两种过程也作了粗略的经济分析。档案卷45第2卷a4。生物柴油生产废水的催化工艺研究67 2012,Chi et al. 2016, Wang and Chu 2012),从而提供了与羟基自由基相比具有一定优势的反应机制(Hu and Long 2016, Oh et al. 2016)。氧酮也可以通过过渡金属,如Co (II)、Ru (II)和Mn (II)分解为自由基(Rivas etal . 2012),根据公式1、2和3:HSO5 +M n+→SO4 .+M(n+1) + + OH(Eq。1) HSO5 +M n+→SO4 +M(n+1) + + OH。(Eq. 2) HSO5 +M n+→SO5 +M(n+1) + + H+ (Eq. 3) M = Co (II), Ru (II)或Mn (II) Co (II)被报道为激活HSO5最有效的金属催化剂之一,促进了自由基硫酸盐络合机制(Rivas etal . 2012, Sun etal . 2009)。因此,本研究的主要目的是评估两种基于高级氧化工艺的催化处理的性能;传统的Fenton工艺和新兴的复合过硫酸盐(HSO5 -)处理生物柴油净化阶段的废水COD。研究了几种氧化剂/催化剂用量的组合,并评估了最佳条件。材料和方法材料和化学试剂表1总结了使用的生物柴油废水的物理化学特性,由PRIO (PRIO Energy Co .)提供。本工作所用试剂为:硫酸,H2SO4, 95-98%, (Panreac);超纯水,Mili-Q。电阻率10 MΩ cm;氢氧化钠,NaOH, 98% (Panreac);碘酸钾KIO3 (Panreac);碘化钾,KI, 99.0-100.5% (Panreac);钼酸铵,(NH4)2MoO4∙4H2O, 93.1-101.0% (Panreac);Oxone, 2KHSO5∙KHSO4∙K2SO4, 99.9%, (Sigma Aldrich);硫酸钴,CoSO4∙7H2O, (Sigma Aldrich);硫代硫酸钠Na2S2O3, 98-102%, (Panreac);盐酸HCl, 36% (Panreac);氯化钡,BaCl2∙H2O (Panreac);过氧化氢,H2O2, 30% w/w, (Scharlab);硫酸铁,FeSO4∙7H2O, (Sigma Aldrich);重铬酸钾K2Cr2O7 (Panreac)和硝酸银AgNO3 (Panreac)。所用试剂均为分析级试剂。分析方法采用pH、电导率、氧化还原电位、浊度、化学需氧量(COD)、油脂和氯化物等理化参数对样品进行表征。根据标准化水和废水方法(APHA 2012)进行表征。pH和氧化还原电位分别用pH - Metron 654电位器和WTW - Inolab电位器测定,电导率用电导率仪法测定,浊度用WTW Turb.550浊度仪测定。硫酸盐的测定采用Thermo - Heraeus k114型炉。在两种催化处理(HSO5 -/Co2+和Fenton法)中,测试了氧酮和过氧化氢的浓度,并使用碘量法监测了其随反应时间的变化。这种方法是在样品中加入过量的碘化物,用硫代硫酸钠溶液滴定。因此,取5 mL样品,加入10 mL H2SO4, 2.0 N, 25 mL KI (20 g/L)和几滴饱和钼酸铵溶液作为催化剂。所发生的反应为:HSO5 + 2I+ 2H+→I2 + H2O + HSO4(式。 4) H2O2 + 2I + 2H+→I2 + H2O + OH (Eq. 5)然后用硫代硫酸钠滴定,之前用KIO3测量,所需浓度为:C = (VS2O3 2∙CS2O3 2-)/2∙Vsample (Eq. 6),其中VS2O3 2为滴定中消耗的硫代硫酸盐体积,CS2O3 2为所用硫代硫酸盐溶液的浓度,Vsample为样品体积。处理结束时,通过COD测定进行有机物降解(APHA 2012)。硫酸盐用重量法测定(APHA 2012),氯化物用莫尔法测定(APHA 2012)。两项实验均采用不连续方式进行,取300 mL废水,以250 rpm的恒定转速搅拌,以避免浓度梯度。实验开始于表1。根据第236/98号法令(葡萄牙立法),生物柴油废水的物理化学特性和地表水中废水排放的各自排放限值(LEV)
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引用次数: 0
A study on aerobic lipid substrate elimination by microbial consortium 微生物联合体消除好氧脂质底物的研究
IF 1.5 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-04-01 DOI: 10.24425/aep.2020.134539
Witold Nocoń, Anna Węgrzyn, Mieczysław Metzger
: The purpose of this study was to validate the applicability of specialized microbial consortium for the degradation of lipids in wastewater. An experimental model of the process is proposed that enables prediction of the required batch length. This model can be used for supervision of the process and to control cycles of the batch reactor. The study involved 4 reactors with microbial consortium obtained by inoculation from a commercially available biopreparate. Each reactor was fed a diff erent load of lipid containing substrate. The biodiversity, settling characteristics and COD reductions were measured. The biodiversity of the microbial consortium changed within a range of ±15% depending on lipids concentration, as shown by the Shannon index and increasing amount of β-proteobacteria. Higher concentrations of lipids increased the biodiversity suggesting higher growth of microorganisms capable of utilizing lipids as energy and carbon source by producing lipid hydrolyzing enzymes. High lipid concentrations degrade the settling capabilities of the biomass. Higher lipid concentrations (0.5–2.0 [g
本研究的目的是验证专门的微生物联合体在降解废水中脂质的适用性。提出了该工艺的实验模型,可以预测所需的批长度。该模型可用于间歇反应器的过程监督和循环控制。该研究涉及4个反应器,通过接种从市售生物制剂中获得的微生物联合体。每个反应器喂入不同负荷的含脂底物。测定了生物多样性、沉降特性和COD减少量。微生物群落的生物多样性随脂质浓度的变化在±15%的范围内变化,如香农指数和β-变形菌数量的增加所示。较高的脂质浓度增加了生物多样性,表明能够通过产生脂质水解酶来利用脂质作为能量和碳源的微生物的生长速度更快。高脂质浓度降低了生物质的沉降能力。较高的脂质浓度(0.5-2.0 [g])
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引用次数: 1
Fecal sludge management: Insights from selected cities in Sub-Saharan Africa 粪便污泥管理:来自撒哈拉以南非洲选定城市的见解
IF 1.5 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-04-01 DOI: 10.24425/aep.2019.127984
E. A. Odey, B. O. Abo, A. Giwa, Zifu Li
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引用次数: 4
First report on implementation of response surface methodology for the biodegradation of textile industrial effluents by Coniophora puteana IEBL-1 响应面法在纺织工业废水生物降解中的应用研究
IF 1.5 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-04-01 DOI: 10.24425/aep.2019.130241
R. T. Mahmood, M. Asad, M. Asgher, Tayyaba Zainab, M. Zafar, S. H. Hadri, I. Ali, Nasib Zaman, F. H. Wattoo
: The current study was aimed to evaluate the industrial ef fl uents biodegradation potential of an indigenous microorganism which reduced water pollution caused by these ef fl uents. In the present study biodegradation of three textile industrial ef fl uents was performed with locally isolated brown rot fungi named Coniophora puteana IEBL-1. Response Surface Methodology (RSM) was employed under Box Bhenken Design (BBD) for the optimization of physical and nutritional parameters for maximum biodegradation. Quality of treated ef fl uents was checked by study of BOD, COD and analysis through HPLC. Three ligninolytic enzymes named lignin peroxidase, manganese peroxidase and laccase were also studied during the biodegradation process. The results showed that there was more than 85% biodegradation achieved for all three ef fl uents with decrease in Biological Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) below the recommended values for industrial ef fl uent i.e. 80 mg/L for BOD and 220 mg/L for COD after optimization of nutritional parameters in the second stage. Analysis of samples through HPLC revealed the formation of less toxic diphenylamine, 3-methyldiphenylamine and N-methylaniline after treatment. The ligninolytic enzymes assays con fi rmed the role of lignin peroxidase (LiP), manganese peroxidase
本研究旨在评价一种本地微生物对工业废水的生物降解潜力,以减少工业废水对水体的污染。利用当地分离的褐腐菌(Coniophora puteana iebl1)对3种纺织工业废水进行了生物降解研究。在Box henken设计(BBD)下,采用响应面法(RSM)优化物理和营养参数,以实现最大限度的生物降解。通过生化需氧量(BOD)、化学需氧量(COD)测定和高效液相色谱(HPLC)分析,对处理后的出水质量进行了检验。对木质素降解酶木质素过氧化物酶、锰过氧化物酶和漆酶进行了研究。结果表明:经第二阶段营养参数优化后,3种出水均达到85%以上的生物降解效果,生物需氧量(BOD)和化学需氧量(COD)均低于工业出水推荐值(BOD为80 mg/L, COD为220 mg/L)。经HPLC分析,样品经处理后形成毒性较小的二苯胺、3-甲基二苯胺和n -甲基苯胺。木质素分解酶测定证实了木质素过氧化物酶(LiP)、锰过氧化物酶的作用
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引用次数: 2
The beneficial role of indigenous arbuscular mycorrhizal fungi in phytoremediation of wetland plants and tolerance to metal stress 乡土丛枝菌根真菌在湿地植物修复和金属胁迫耐受中的有益作用
IF 1.5 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-04-01 DOI: 10.24425/AEP.2019.125916
W. Sidhoum, Z. Fortas
The potential of fi ve plants namely Atriplex halimus L., A. canescens (Pursh) Nutt., Suaeda fruticosa (Forssk. ex J.F. Gmel.), Marrubium vulgare L. and Dittrichia viscosa (L.) Greuter from two selected wetlands in northwest Algeria subjected to house and industrial effl uents were examined to assess their arbuscular mycorrhizal fungal (AMF) diversity and colonization, as well as to determine their tolerance and ability in accumulating metallic trace elements (MTEs). The purpose was to investigate whether, or not, these fungi are related to metallic uptake. Arbuscular mycorrhizal association was observed in all plant species, since the dual association between AMF and dark septate endophytes (DSE) was found in roots of 80% plants species. Hence, the decreasing trend of metal accumulation in most plant organs was Zn>Cu>Pb, and the most effi cient species were M. vulgare> S. fruticosa> A. canescens> D. viscosa> A. halimus. The bioaccumulator factors exceeded the critical value (1.0) and the transport factors indicated that all these species were phytoremediators. Pearson correlation showed that Cd bioaccumulation and translocation were inhibited by AMF infection; meanwhile Zn, Pb and Cd accumulation were affected by AMF spore density and species richness, DSE frequency, pH, AMF and plant host. Native halophytes showed a multi-metallic resistance capacity in polluted wetlands. M. vulgare was the most effi cient in metal accumulation and the best host for mycorrhizal fungi. AMF played a major role in metal accumulation and translocation. 104 W. Sidhoum, Z. Fortas for soil remediation engineer to establish a novel ecosystem in polluted soils (Yang et al. 2014). As reported by (Wójcik et al. 2015), the communities of the indigenous metallophyte of abandoned metalliferous waste sites are considered as an important source of species, seed banks and gene pools for the environmental phytotechnologies. Two strategies are probably used by plants in order to use to transact with high metal concentrations in the rhizosphere: exclusion (avoidance) mechanisms, where the uptake and/or root-to-shoot transport of metals are restricted, phytostabilization process (reduction of the mobility, bioavailability and/or toxicity of pollutants in the rhizosphere), or in contrast, sequestration of MTE contaminants by plant roots, and then translocation to their aerial parts internally. Here, the aim of phytoextraction or phytoaccumulation is to increase the accumulation of metal in plant tissues, and thus the mechanisms of internal tolerance could be important (Padmavathiamma and Li 2007). The AMF are ubiquitous soil inhabitants associated symbiotically with most plants roots, and constitute a major component of the soil microbial biomass. They promote the penetration of nutrients in ecosystems, enhance plant establishment and growth, soil aggregation, and mineral uptake (Luginbuehl and Oldroyd 2017). In view of above background, the present study was aimed at to 1) determin
对每个根系,用光学显微镜(Olympus CX22)检测50个长度约为1 cm的根片段的AMF定植。根据Trouvelot et al.(1986)的描述,对菌根发育进行了评估,并表示为菌根频率(F%,被菌根感染的根皮质百分比),菌根强度(根皮质被菌根化的数量,它指的是整个根系(M%)或仅指菌根部分(M%)),整个根系或定植根片段的丛枝丰富度(A%)。在其他内生菌(DSE定殖或其他真菌内生菌)的情况下,频率
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引用次数: 12
Mercury content in refuse-derived fuels 垃圾衍生燃料中的汞含量
IF 1.5 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-04-01 DOI: 10.24425/122304
W. Hryb, P. Matyasik
is a non--pro fi t association, founded in 2001 by European companies producing recovered fuels. ERFO was established to develop the concept of Solid Recovered Fuel (SRF). SRFs are solid fuels prepared from non-hazardous waste to be utilized for energy recovery in incineration or co-incineration plants and meeting the classi fi cation and speci fi cation requirements laid down in the EN15359 European standard. ERFO’s main aim is to promote the production and use of recovered fuels, and especially SRF, in Europe. To that aim, ERFO supports standardization of SRF and participates in research projects. Abstract: The paper presents the results of testing the mercury content in fuels derived from different types of waste. Legal and technical issues related to preventing mercury from getting into the environment are taken into account with respect to refuse-derived fuels used in cement plants. The mercury content in refuse-derived fuels is usually smaller compared to conventional fossil fuels such as coal. For this reason, the requirement imposed on the fuel suppliers that it must not exceed the limit of 0.3 ppm (in dry matter (DM)) seems over-restrictive and unjusti fi ed. The paper presents the sources of mercury contamination of waste with attention drawn to the signi fi cance of selective waste collection and the need to educate the public in this area. Presented are results of the testing of the mercury content in waste types characterized by a great variation of the parameter depending on the origin of the waste combustible
是一个非营利性协会,由生产再生燃料的欧洲公司于2001年成立。ERFO的成立是为了发展固体回收燃料(SRF)的概念。srf是由无害废物制备的固体燃料,用于焚烧或共焚烧厂的能量回收,符合EN15359欧洲标准中规定的分类和规格要求。ERFO的主要目标是促进欧洲回收燃料的生产和使用,特别是SRF。为此,ERFO支持SRF的标准化并参与研究项目。摘要:本文介绍了不同类型废弃物燃料中汞含量的检测结果。就水泥厂使用的垃圾衍生燃料而言,考虑到与防止汞进入环境有关的法律和技术问题。与煤炭等传统化石燃料相比,垃圾衍生燃料中的汞含量通常较低。因此,对燃料供应商施加的不得超过0.3 ppm(干物质)限制的要求似乎过于严格和不合理。本文介绍了废物中汞污染的来源,并注意到选择性废物收集的重要性以及在这方面教育公众的必要性。本文介绍了对各种废物中汞含量的测试结果,这些废物的参数根据可燃废物的来源而有很大变化
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引用次数: 4
Concepts of energy use of municipal solid waste 城市固体废物能源利用的概念
IF 1.5 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-04-01 DOI: 10.24425/aep.2021.137279
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引用次数: 2
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Archives of Environmental Protection
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