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Effect modification by high-concentration duration in the association between particulate matters and stroke hospital admissions among hypertension patients in Beijing, China 高浓度持续时间对北京地区高血压患者颗粒物与脑卒中入院关系的影响
IF 5.1 4区 环境科学与生态学 Q1 Environmental Science Pub Date : 2023-08-15 DOI: 10.1007/s11869-023-01412-2
Zemeng Zhao, Moning Guo, Peng Tan, Xue Tian, Yuhan Zhao, Lulu Liu, Lili Luo, Hui Luo, Xiaonan Wang, Xiangtong Liu, Xiuhua Guo, Yanxia Luo

To investigate the associations between particulate matter (PM) and hospital admissions for stroke and its subtypes among hypertension patients. We proposed a new modifier named high-concentration duration (HCD). Data on daily hospital admissions, air pollution, and meteorological factors were collected from 2014 to 2018 in Beijing, China. We included all patients with hypertension who were admitted to hospitals of secondary-level and above for stroke. Time-series analysis was conducted by fitting a generalized additive model. An interaction term of daily concentration and an HCD stratum indicator were included in the model. Sex subgroup analysis was performed in four age groups to detect vulnerable populations. A total of 358,577 admissions were identified. The PM was significantly associated with stroke admissions in patients with hypertension. The maximum excess risk (ER) (%) per 10 μg/m3 increase in fine particulate matter (PM2.5) was 0.23% (95% confidence interval (CI): 0.15%, 0.31%) for overall stroke, 0.25% (95% CI: 0.16%, 0.33%) for ischemic stroke (IS). The maximum ER (%) per 10 μg/m3 increase in inhalable particle (PM10) was 0.14% (95% CI: 0.06%, 0.23%) for overall stroke, 0.15% (95% CI: 0.06%, 0.23%) for IS. For hemorrhagic stroke, significant associations were also observed among males and patients < 55 years. ER (%) in long-HCD strata was significantly larger than that in short-HCD strata. The effects of PM2.5 were significant in long-HCD strata, but insignificant in short-HCD strata. HCD might be a modifier in the association between air pollution and health effects. While controlling the daily average concentration, it is also important to reduce HCD on a given day.

研究颗粒物(PM)与高血压患者中风及其亚型入院之间的关系。我们提出了一种新的改性剂,称为高浓度持续时间(HCD)。收集了2014年至2018年中国北京每日入院人数、空气污染和气象因素的数据。我们纳入了所有因中风而入住二级及以上医院的高血压患者。通过拟合广义加性模型进行时间序列分析。模型中包括了日浓度的相互作用项和HCD地层指标。在四个年龄组中进行了性别亚组分析,以检测弱势群体。共确认358577名入院者。PM与高血压患者的卒中入院率显著相关。细颗粒物(PM2.5)每增加10微克/立方米,总体中风的最大超额风险(ER)(%)为0.23%(95%置信区间(CI):0.15%,0.31%),缺血性中风为0.25%(95%可信区间:0.16%,0.33%)。可吸入颗粒物(PM10)每增加10μg/m3,总体卒中的最大ER(%)为0.14%(95%CI:0.06%,0.23%),IS的最大ER为0.15%(95%CI:006%,.23%)。对于出血性卒中,男性和患者之间也观察到显著的相关性 <; 55岁。长HCD地层的ER(%)明显大于短HCD地层。PM2.5的影响在长HCD地层显著,而在短HCD地层不显著。HCD可能是空气污染和健康影响之间联系的一个调节剂。在控制日平均浓度的同时,减少某一天的HCD也很重要。
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引用次数: 0
The role of high humidity on extreme-temperature-related mortality in central China 高湿度对华中地区极端温度相关死亡率的影响
IF 5.1 4区 环境科学与生态学 Q1 Environmental Science Pub Date : 2023-08-14 DOI: 10.1007/s11869-023-01406-0
Peizhi Deng, Yan Li, Shenxin Li, Yuxin Feng, Donghui Jin, Yiping Yang, Yang Xie, Yao Lu, Qiuping Zhao, Hong Yuan

The evidence of non-optimum ambient temperature and humidity-related mortality is widely reported. However, the joint effects of high humidity and extreme temperatures on mortality remain to understand. We collected mortality data and meteorological variables for 91 counties in central China, from 2017 to 2020. A traditional time-series model with a distributed lag non-linear model was first employed to estimate the location-specific associations between extreme temperatures or high humidity and extreme temperatures and mortality. Then, we conducted a meta-analysis to pool the county-specific estimated effect values. A total of 1,196,916 non-accidental deaths occurred during the study period. Extreme heat increased non-accidental mortality with a relative risk (RR) of 1.071 ((95% confidence interval (CI):1.022, 1.121), while extreme cold worsened the risk of stroke mortality by 2.817 (95 CI%: 1.084, 7.321). For the effect of extreme cold, high humidity increased the RR of 3.908 (95 CI%: 2.721, 5.612) in non-accidental mortality and the effect was strongest in stroke with 5.320 (95 CI%: 3.395 vs 8.338). Under the joint effect of extreme cold and high humidity, there is a lagged association with the mortality risks peaked at 12d for non-accidental mortality. High humidity significantly enhances the risk of extreme cold-related non-accidental mortality, especially regarding stroke. Our findings will assist in the development of preparedness and prevention strategies in Hunan Province and even throughout China to reduce the immediate weather-related impacts.

非最佳环境温度和湿度相关死亡率的证据被广泛报道。然而,高湿度和极端温度对死亡率的共同影响仍有待了解。我们收集了2017年至2020年中国中部91个县的死亡率数据和气象变量。首先采用具有分布式滞后非线性模型的传统时间序列模型来估计极端温度或高湿度与极端温度和死亡率之间的特定位置关联。然后,我们进行了一项荟萃分析,以汇集特定县的估计效果值。研究期间共发生1196916例非意外死亡。极端高温增加了非意外死亡率,相对风险(RR)为1.071((95%置信区间(CI):1.022,1.121),而极端寒冷使中风死亡率风险恶化了2.817(95%可信区间:1.084,7.321),高湿度使非意外死亡率的RR增加了3.908(95%CI%:2.721,5.612),中风的影响最大,为5.320(95%CI%:3.395vs 8.338)。在极端寒冷和高湿度的共同作用下,与非意外死亡率在12d达到峰值的死亡风险存在滞后关系。高湿度会显著增加与极寒相关的非意外死亡风险,尤其是中风。我们的研究结果将有助于湖南省乃至中国各地制定防范策略,以减少与天气相关的直接影响。
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引用次数: 0
Magnetotropism: a tropic response of Candida guillemondii by the effect of the oscillating magnetic field of extremely low frequency 向磁性:guillemondii念珠菌在极低频振荡磁场作用下的一种热带反应
IF 5.1 4区 环境科学与生态学 Q1 Environmental Science Pub Date : 2023-08-14 DOI: 10.1007/s11869-023-01408-y
Matilde Anaya, Erasmo Gámez-Espinosa, Sofía Borrego, Eduardo Barbará

Extremely low frequency oscillating magnetic field (OMF-ELF) can stimulate the growth of pathogenic fungi. This work aims to assess the tropic response of a dimorphic pathogenic strain Candida guilliermondii by the effect of OMF-ELF. The pathogenic strain C. guilliermondii was isolated from an indoor environment and a brewing strain Saccharomyces cerevisiae was used as a positive control. OMF-ELF of 3 mT of 60 Hz for 2 h was applied to the cultures of both strains. After treatment, images were taken every 30 min for 24 h using Digital Image Processing (DIP) to determine the superficial growth rate of both strains and the length of the pseudohyphae, and the tropic response of C. guilliermondii. However, C. guilliermondii showed a tropic response depending on the OMF-ELF applied growing 3 to 60 times faster than the control strain, with a maximum value of 1.27 μm2/min between 1.5 and 2.5 h. C. guillermondii is resistant to OMF-ELF, a factor that stimulated its superficial growth rate and the elongation of its pseudohyphae, facilitated its cellular dimorphism, and oriented its ramifications to increase reproduction. This increase constitutes a risk to human health indoor environments where there is microbiological and electromagnetic contamination. Due to the use of DIP in real time with an adapted microculture technique, this is the first study to analyze “in vivo” magnetotropism of C. guilliermondii, as indicative of its invasive behavior for a possible infestation to humans exposed to this type of non-ionizing radiation in an indoor environment.

极低频振荡磁场(OMF-ELF)可以刺激病原真菌的生长。本研究旨在通过OMF-ELF的作用来评估一株二态致病菌株吉列蒙地念珠菌的热带反应。从室内环境中分离出致病菌株C. guilliermondii,并以酿酒菌株酿酒酵母作为阳性对照。用60hz、3mt的OMF-ELF培养2 h。处理后,采用数字图像处理(DIP)技术,每30 min拍摄一张图像,连续拍摄24 h,测定两菌株的表面生长速率和假菌丝长度,以及吉列蒙地弓形虫的热带反应。然而,对OMF-ELF的影响,吉勒蒙地菌的生长速度比对照快3 ~ 60倍,在1.5 ~ 2.5 h之间的生长最大值为1.27 μm2/min。吉勒蒙地菌对OMF-ELF的抗性可以刺激其表面生长速度和假菌丝的伸长,促进其细胞二态性,并使其分枝定向繁殖。这种增加对人体健康构成威胁——室内环境中存在微生物和电磁污染。由于实时使用DIP和适应的微培养技术,这是第一个分析C. guilliermondii“体内”向磁性的研究,表明其入侵行为可能对暴露于室内环境中这种类型的非电离辐射的人类造成侵害。
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引用次数: 0
Dynamic changes in the characteristics of fine particles and their oxidative potential in the city of Taj (Agra, India): the untold story of fireworks display 泰姬陵(印度阿格拉)细颗粒物特征及其氧化潜能的动态变化:烟花表演的不为人知的故事
IF 5.1 4区 环境科学与生态学 Q1 Environmental Science Pub Date : 2023-08-11 DOI: 10.1007/s11869-023-01402-4
Isha Goyal, Puneet Kumar Verma, Kandikonda Maharaj Kumari, Anita Lakhani

The dithiothreitol (DTT) assay was used to investigate the oxidative potential (OP) of atmospheric fine particles (PM2.5) during fireworks (Diwali) at Agra, India. The 12-h mean PM2.5 was reported to be 263 ±151 μg m−3 during the study period. Increased levels of gaseous pollutants (NOx, SO2, CO, and O3) and metals Ba, Pb, Cu, Fe, Mg, K, Al, and Mn were also observed during fireworks. The results showed that the typical diurnal pattern of trace gases was observed, except their overall concentrations remained elevated during peak hours of the fireworks activity. The highest value of OP of PM was detected on the next morning of Diwali, with a volume-based DTT value (OPv) of 1.4 nmol min−1 m−3 and a mass-based DTT value (OPm) of 11.8 pmol min−1 μg−1, implying higher PM-related DTT activity due to fireworks. A positive association was found between redox-active metals like Cr, Cu, Ni, and V and DTT activity which could be due to the ability of these metals to catalyze reactive oxygen species (ROS) generation in ambient air. Ba and Se concentrations in the particulate matter, which are key components of firecrackers, were likewise highly linked to DTT activity. During the daytime, ozone levels were strongly correlated (r2 = 0.9) with OPv activity; this may be due to photochemical processes which may lead to the formation of tropospheric O3. Elements C, O, Al, Si, S, K, and Ba were found to be the most prevalent in elemental mappings, which suggests that fireworks may have contributed to their abundance. A comparison of the daily OPv activity and hazard index (HI) suggests that the HI may be a poor metric for measuring the health impacts of PM exposure on human health.

二硫苏糖醇(DTT)测定法用于研究印度阿格拉烟花(排灯节)期间大气细颗粒物(PM2.5)的氧化潜能(OP)。据报道,在研究期间,12小时平均PM2.5为263±151μg m−3。烟花期间还观察到气体污染物(NOx、SO2、CO和O3)以及金属Ba、Pb、Cu、Fe、Mg、K、Al和Mn的含量增加。结果表明,除了在烟花爆竹活动的高峰时段,微量气体的总浓度保持较高外,还观察到了典型的日变化模式。排灯节的第二天早上检测到PM的最高OP值,基于体积的DTT值(OPv)为1.4 nmol min−1 m−3,基于质量的DTT数值(OPm)为11.8 pmol min−1μg−1,这意味着烟花爆竹导致PM相关的DTT活动更高。在Cr、Cu、Ni和V等氧化还原活性金属与DTT活性之间发现了正相关,这可能是由于这些金属催化环境空气中活性氧(ROS)产生的能力。颗粒物中的Ba和Se浓度是鞭炮的关键成分,同样与DTT活性高度相关。在白天,臭氧水平与OPv活动密切相关(r2=0.9);这可能是由于光化学过程导致对流层O3的形成。元素C、O、Al、Si、S、K和Ba在元素映射中最为普遍,这表明烟花可能是它们丰度的原因之一。对每日OPv活动和危害指数(HI)的比较表明,HI可能是衡量PM暴露对人类健康影响的较差指标。
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引用次数: 0
Measurement of size-segregated airborne particulate bound polycyclic aromatic hydrocarbons and health risk assessment: a case study in Aksaray atmosphere, Turkey 尺寸分离的空气颗粒结合多环芳烃的测量和健康风险评估:土耳其阿克萨雷大气的一个案例研究
IF 5.1 4区 环境科学与生态学 Q1 Environmental Science Pub Date : 2023-08-10 DOI: 10.1007/s11869-023-01401-5
Selin Yıldırım, Ebru Koçak

Polycyclic aromatic hydrocarbons (PAHs) were measured in size-segregated particulate matters (PMs) in a range of 0.43 to 10.0 μm, categorized into two as fine particles (0.43 μm < d < 2.1 μm) and coarse particles (2.1 μm < d < 10.0 μm), during summer and winter seasons in an urban atmosphere of Aksaray, Turkey. The primary purpose of this study was to investigate size distribution, temporal variation, and related health risks of PAHs. During the winter season, concentrations of PAHs in the sampling site were almost ten times higher than in summer, and approximately 85% of the PAHs belonged to the fine PM fraction. On the other hand, it was determined that the emission sources of the detected PAHs in the summer season were traffic-related emissions. The smallest particle size range (0.45–0.63 μm) consisted of the maximum PAH concentration (1.22±0.05 ng m−3) about other particle sizes during the summer season. Fluoranthene (Flt) was the main PAH species determined during winter, indicating that coal combustion is a dominant pollution source. The size distribution properties of PAHs showed similar characteristics for coarse particles, which was also the case for fine particles. In addition, as the ring number of PAHs increases, the height of the peaks decreases in the size distribution plots of coarse particles. Higher molecular weight (HMW) PAHs show higher carcinogenicity potential, mainly found in the fine PM fraction. A health risk assessment was estimated by toxicity equivalent quantity (TEQ) and inhalation cancer risk (ICR), indicating medium risk for the fine PMs and low risk for the coarse PMs.

在土耳其阿克萨雷的夏季和冬季,在城市大气中测量了尺寸分离的颗粒物(PM)中的多环芳烃(PAHs),颗粒物范围为0.43至10.0μm,分为细颗粒物(0.43μm<;d<;2.1μm)和粗颗粒物(2.1μm<;d<;10.0μm)。本研究的主要目的是调查多环芳烃的大小分布、时间变化和相关的健康风险。在冬季,采样点的多环芳烃浓度几乎是夏季的十倍,大约85%的多环芳烃属于细颗粒物。另一方面,确定夏季检测到的多环芳烃的排放源是与交通有关的排放。最小粒径范围(0.45–0.63μm)由夏季其他粒径的最大PAH浓度(1.22±0.05 ng m−3)组成。荧蒽(Flt)是冬季测定的主要PAH物种,表明燃煤是主要污染源。PAHs的尺寸分布特性在粗颗粒中表现出类似的特征,细颗粒也是如此。此外,随着多环芳烃环数的增加,粗颗粒尺寸分布图中峰的高度减小。高分子量PAHs表现出更高的致癌性潜力,主要存在于细颗粒物中。健康风险评估通过毒性当量(TEQ)和吸入癌症风险(ICR)进行估计,表明细PM的中等风险和粗PM的低风险。
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引用次数: 0
Assessing air pollution exposure misclassification using high-resolution PM2.5 concentration model and human mobility data 使用高分辨率PM2.5浓度模型和人类流动性数据评估空气污染暴露的错误分类
IF 5.1 4区 环境科学与生态学 Q1 Environmental Science Pub Date : 2023-08-08 DOI: 10.1007/s11869-023-01404-2
Yougeng Lu

Due to a paucity of human movement data, the traditional method for estimating pollution exposure is static: Exposure is based on place of residence. However, local air quality varies over both time and space. This study explores exposure measurement errors associated with ignoring human mobility and its impact on exposure-health effect estimates. Using a random forest classification model, this study examines the impact of a variety of factors on potential measurement errors in personal exposure to outdoor PM2.5. Mobility data at the individual level was combined with hourly PM2.5 surfaces at the neighborhood level to estimate and compare residence-based and mobility-based exposures for 100,784 Los Angeles County residents. The results show that exposure measurement errors increase for individuals with high mobility levels. Significant sociodemographic disparities are observed across different exposure classification groups. Exposures of low-income people who have high mobility and reside in polluted neighborhoods tend to be overestimated. In contrast, exposures of high-income people living in neighborhoods with cleaner air are likely to be underestimated. The result on the exposure-health effect suggests that health risks of the socially disadvantaged after exposure to PM2.5 is likely to be underestimated due to the exposure measurement error introduced by ignoring human mobility.

由于缺乏人类活动数据,估计污染暴露的传统方法是静态的:暴露是基于居住地。然而,当地空气质量在时间和空间上都有所不同。本研究探讨了与忽视人类流动性相关的暴露测量误差及其对暴露健康影响估计的影响。本研究使用随机森林分类模型,考察了各种因素对个人暴露于室外PM2.5的潜在测量误差的影响。将个人层面的流动性数据与社区层面的每小时PM2.5表面相结合,以估计和比较100784名洛杉矶县居民基于居住和基于流动的暴露。结果表明,对于行动能力强的个体,暴露测量误差会增加。在不同的暴露分类组中观察到显著的社会人口统计学差异。高流动性和居住在污染社区的低收入人群的暴露往往被高估。相比之下,生活在空气更清洁的社区的高收入人群的暴露可能被低估了。暴露健康效应的结果表明,由于忽视人类流动性带来的暴露测量误差,社会弱势群体在暴露于PM2.5后的健康风险可能被低估。
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引用次数: 0
Recent developments in high-resolution wind field modeling in complex terrain for dispersion simulations using GRAMM-SCI 使用GRAMM-SCI进行复杂地形分散模拟的高分辨率风场建模的最新进展
IF 5.1 4区 环境科学与生态学 Q1 Environmental Science Pub Date : 2023-08-08 DOI: 10.1007/s11869-023-01403-3
Dietmar Oettl, Raphael Reifeltshammer

The rather complex terrain in Austria requires that wind fields with sub-kilometer resolutions have to be generated prior to any kind of dispersion modeling due to the large demand on computation times required by non-hydrostatic prognostic mesoscale models. Proper modeling of highly resolved flows in Alpine regions is still a matter of research, and no harmonized methodology is available at the moment. In order to harmonize the meteorological input for dispersion modeling at the regional level, authorities in Austria aim at providing so-called wind-field libraries for a certain reference year for all stakeholders involved in air quality assessments for regulatory purposes. The region of Styria was the first to establish such a library using the prognostic, non-hydrostatic mesoscale model GRAMM with a horizontal resolution of 300 m in 2015. Over the years, attempts have been made for improving the quality of the wind fields. One of the most challenging issues is the interaction between synoptic-scale flows and local thermally driven winds. In this work, the newly developed mesoscale model GRAMM-SCI is presented, which is driven by ERA5 reanalysis data. Especially, novel nudging techniques allow for nesting and dynamic downscaling wind fields with a horizontal resolution of 100–200 m. Moreover, a methodology called “match-to-observation” (MTO) is presented, which greatly improves the final quality of wind fields. For the first time, a wind-field library for the reference year 2017 has been generated for Styria with this new approach.

奥地利相当复杂的地形要求,由于非静水预测中尺度模型对计算时间的巨大需求,必须在任何类型的分散建模之前生成分辨率为千米以下的风场。高山地区高分辨率流量的适当建模仍然是一个研究问题,目前还没有统一的方法。为了协调区域一级分散建模的气象输入,奥地利当局旨在为参与空气质量评估的所有利益相关者提供特定参考年的所谓风场库,以达到监管目的。2015年,施蒂利亚地区率先使用水平分辨率为300米的预测性非静水中尺度模式GRAMM建立了这样一个库。多年来,人们一直在努力提高风场的质量。最具挑战性的问题之一是天气尺度流和局部热驱动风之间的相互作用。在这项工作中,提出了新发展的中尺度模式GRAMM-SCI,它是由ERA5再分析数据驱动的。特别是,新的微调技术允许嵌套和动态缩小水平分辨率为100–200米的风场。此外,提出了一种称为“与观测匹配”(MTO)的方法,大大提高了风场的最终质量。采用这种新方法,首次为施蒂利亚州生成了2017参考年的风场库。
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引用次数: 1
Respiratory deposition dose of PM2.5 and PM10 during night and day periods at an urban environment 城市环境中PM2.5和PM10夜间和日间的呼吸沉积剂量
IF 5.1 4区 环境科学与生态学 Q1 Environmental Science Pub Date : 2023-08-08 DOI: 10.1007/s11869-023-01405-1
Yago Alonso Cipoli, Leonardo Furst, Manuel Feliciano, Célia Alves

Inhalation of particulate matter (PM) has been extensively associated with the worsening and onset of cardiorespiratory diseases, being responsible for millions of deaths annually. Assessment of PM deposition in the human respiratory tract is critical to better understand the health risks from environmental exposure of vulnerable age groups. In this study, PM2.5 and PM10 day-night monitoring campaigns during the cold season were carried out in Bragança, Portugal. The multiple-path particle dosimetry (MPPD) model was used to quantify total and regional depositions in the human respiratory tract for four different age groups: infant (3 months), child (9 years), adult (21 years) and elderly (65 years). The results showed that concentrations for both PM fractions were higher during the night, a period marked by the burning of biomass for residential heating. Regional deposition fractions (DF) for PM2.5 were in the ranges 17–38% (head), 4–14% (tracheobronchial) and 20–28% (pulmonary), while for PM10 were 24–67% (head), 4–27% (tracheobronchial) and 12–22% (pulmonary). Children and the elderly were found to be the most vulnerable groups to PM deposition, especially for the TB and H regions, respectively. The lifetime cancer and non-cancer risks associated with exposure to PM2.5 exceeded the recommended limits, especially for children <10 years old. These findings provide useful information to alert authorities to the need to take action to reduce the pollution burden and protect the health, in particular of those most susceptible.

吸入颗粒物(PM)与心肺疾病的恶化和发作密切相关,每年造成数百万人死亡。评估PM在人类呼吸道中的沉积对于更好地了解弱势年龄组暴露在环境中的健康风险至关重要。在这项研究中,在葡萄牙布拉干萨开展了寒冷季节PM2.5和PM10昼夜监测活动。多路粒子剂量测定(MPPD)模型用于量化四个不同年龄组(婴儿(3个月)、儿童(9岁)、成人(21岁)和老年人(65岁)在人类呼吸道中的总沉积和区域沉积。结果表明,两种PM组分的浓度在夜间都较高,这一时期的特点是燃烧生物质用于住宅供暖。PM2.5的区域沉积分数(DF)范围为17–38%(头部)、4–14%(气管支气管)和20–28%(肺部),而PM10的区域沉积百分比为24–67%(头部),4–27%(气管支气管和12–22%(肺部)。儿童和老年人被发现是最容易受到PM沉积的群体,尤其是在结核病和H地区。与暴露于PM2.5相关的终身癌症和非癌症风险超过了推荐限值,尤其是儿童<;10岁。这些发现提供了有用的信息,提醒当局有必要采取行动减轻污染负担,保护健康,特别是那些最易受感染的人的健康。
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引用次数: 0
A review on the formation and remediations of polychlorinated dibenzo p-dioxins and dibenzo-furans (PCDD/Fs) during thermal processes with a focus on MSW process 热处理过程中多氯二苯并对二恶英和二苯并呋喃(PCDD/Fs)的形成和修复研究进展——以城市生活垃圾处理为重点
IF 5.1 4区 环境科学与生态学 Q1 Environmental Science Pub Date : 2023-08-07 DOI: 10.1007/s11869-023-01394-1
Nomathemba Themba, Linda L. Sibali, Tlou B. Chokwe

Polychlorinated dibenzo-p-dioxins and dibenzo-furans (PCDD/Fs) are notorious pollutants classified as persistent organic pollutants (POPs), which even at trace levels can bio-accumulate in the environment and have negative effects on organisms. Due to their adverse health effects, countries around the globe have introduced stringent emission standards to reduce the formation of PCDD/Fs. Using data in the literature over the past two decades (2001 to 2023), this review discussed the PCDD/F emissions from incineration facilities, E-waste recycling, iron sintering, secondary metal smelting plants, and crematories. But the review only focused on pollutants and remediation strategies from the incineration processes. There are two heterogeneous mechanism pathways that lead to the formation of PCDD/Fs, firstly, the De novo phase, using macromolecules of carbon or polycyclic aromatic hydrocarbons to begin the synthesis, and secondly, the condensation reaction beginning with the rearrangement of the molecular structure of the precursor compound. On the remediation strategies, adsorption injections were the most preferred method; however, recent studies reported other strategies such as catalytic filtration systems, an electron beam system, and good combustion practices. This review concluded that a lot has been done to manage and prevent PCDD/F formation efficiently to the level which no longer poses a hazard to human health and the environment.

多氯二苯并对二恶英和二苯并呋喃是臭名昭著的持久性有机污染物,即使在微量水平下也会在环境中生物积累,对生物体产生负面影响。由于其对健康的不利影响,全球各国都制定了严格的排放标准,以减少多氯二苯并呋喃的形成。利用过去二十年(2001年至2023年)的文献数据,本综述讨论了焚烧设施、电子废物回收、铁烧结、二次金属冶炼厂和火葬场的多氯二苯并呋喃排放。但该审查只关注焚烧过程中的污染物和补救策略。导致PCDD/Fs形成的多相机理途径有两种,首先是从头相,使用碳或多环芳烃的大分子开始合成,其次是缩合反应,始于前体化合物的分子结构重排。在修复策略上,吸附注射是最优选的方法;然而,最近的研究报告了其他策略,如催化过滤系统、电子束系统和良好的燃烧实践。这项审查得出的结论是,在有效管理和防止多氯二苯并呋喃的形成方面已经做了很多工作,达到了不再对人类健康和环境构成危害的水平。
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引用次数: 0
Air and soil concentrations of persistent organic pollutants in Bursa (Türkiye) and Yurimaguas (Peru): air-soil exchange and gas-phase flux 布尔萨(土耳其)和尤里马瓜斯(秘鲁)持久性有机污染物的空气和土壤浓度:空气-土壤交换和气相通量
IF 5.1 4区 环境科学与生态学 Q1 Environmental Science Pub Date : 2023-08-07 DOI: 10.1007/s11869-023-01400-6
Fatma Esen, Daniel Alejandro Cordova Del Aguila, Mehmet Ferhat Sari

The study of persistent organic pollutants (POPs) in different environments has helped to understand the behavior and distribution of these pollutants worldwide. Many developed and developing countries have extensive data on the presence of these pollutants, especially in ambient air and soil. However, the simultaneous measurement of air and soil is less frequent, despite offering the opportunity to characterize air-soil exchange. Moreover, such measurements in upper-middle-income countries such as Turkey are very limited and null in Peru. Both countries also offer unique opportunities to characterize the air-soil exchange since Peru has a semi-arid subtropical desert climate and Turkey has a Mediterranean climate. Therefore, the aim of this study is to determine the simultaneous POP concentrations (polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and organochlorine pesticides (OCPs)) in ambient air and soil in Turkey and Peru and to reveal the POP exchange between air and soil and flux amounts in the gas phase. POP concentrations in ambient air were measured higher at sampling points in Turkey, while POPs in soil were measured similarly in both countries. Also, the air-soil fugacity fractions indicated net volatilization for low molecular weight PAH and PCB congeners, but net deposition for high molecular weight congeners; equilibrium states were found for medium molecular weight congeners. Fugacity fractions did not change with their molecular weights for OCPs. It has been determined that soil acts as a “secondary source” for low molecular weight PAH and PBC congeners in the atmosphere, while the atmosphere acts as a “sink” for high molecular weight PAH and PCB congeners in the soil. Finally, cancer risk calculations for adults and children have been made, both via inhalation of atmospheric POPs and uptake of POPs from the soil. According to the calculations, no health risks were found for both air and soil for adults and children.

对不同环境中持久性有机污染物的研究有助于了解这些污染物在全球范围内的行为和分布。许多发达国家和发展中国家都有关于这些污染物存在的大量数据,特别是在环境空气和土壤中。然而,尽管提供了表征空气-土壤交换的机会,但同时测量空气和土壤的频率较低。此外,在土耳其等中上收入国家,这种衡量标准非常有限,在秘鲁是无效的。由于秘鲁属于半干旱亚热带沙漠气候,土耳其属于地中海气候,两国也为描述空气-土壤交换提供了独特的机会。因此,本研究的目的是确定土耳其和秘鲁环境空气和土壤中同时存在的POP浓度(多环芳烃(PAHs)、多氯联苯(PCBs)和有机氯农药(OCPs)),并揭示空气和土壤之间的POP交换和气相通量。在土耳其的采样点测得的环境空气中持久性有机污染物浓度较高,而在这两个国家测得的土壤中持久性污染物浓度相似。此外,空气-土壤逸度分数表明,低分子量PAH和多氯联苯同源物为净挥发,但高分子量同源物为纯沉积;发现了中等分子量同源物的平衡态。对于OCP,逸度分数不随其分子量而变化。已经确定,土壤是大气中低分子量多环芳烃和多氯联苯同源物的“二次来源”,而大气是土壤中高分子量多环芳烃或多氯联苯同源物“汇”。最后,通过吸入大气中的持久性有机污染物和从土壤中吸收持久性有机化合物,对成人和儿童进行了癌症风险计算。根据计算,成人和儿童的空气和土壤都没有健康风险。
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Air Quality Atmosphere and Health
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