首页 > 最新文献

Asia-Pacific Journal of Chemical Engineering最新文献

英文 中文
Enhancing coal slime processing: Investigating the efficacy of sodium dodecyl sulfonate in the adsorption on kaolinite surfaces 加强煤泥加工:研究十二烷基磺酸钠在高岭石表面的吸附效果
IF 1.4 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-04-04 DOI: 10.1002/apj.3074
Fangqin Lu, Lingyun Liu, Chuilei Kong, Hongyu Zhao

Addressing the issue of processing fine kaolinite and quartz particles in coal slime, this study utilized molecular simulation and Density Functional Theory (DFT) to investigate the chelate adsorption characteristics of sodium dodecyl sulfate (SDS) on kaolinite surfaces. As a major clay mineral component in coal slime, kaolinite reduces coal's calorific value but holds potential for industrial and agricultural applications. The research identified distinct interactions between SDS and the tetrahedral SiO layer and octahedral AlO layer of kaolinite, in contrast to quartz, which contains only the tetrahedral SiO layer. This difference is crucial for the effective separation of kaolinite from quartz. The study focused on analyzing SDS adsorption on the (001) and (00-1) planes of kaolinite. The findings revealed strong adsorption of SDS on kaolinite surfaces, especially on the (001) plane, evidenced by significant charge transfer indicating efficient chelation. This effect results from the interaction of SDS's electron-donating atoms (such as S and O) with the metal atoms on the surface of kaolinite. Adsorption strength was quantified through adsorption energy calculations, showing a stronger interaction on the (001) surface. Experimental validations, including single mineral flotation experiments and infrared spectroscopic analysis, further corroborated the simulation outcomes. These tests demonstrated improved flotation recovery of kaolinite in the presence of SDS and with reduced particle size. Infrared analysis revealed that SDS selectively and strongly adsorbs on kaolinite surfaces, as indicated by diminished hydroxyl group stretching vibrations in the FTIR spectrum and changes in absorption peaks related to inorganic vibrations and sulfonic acid groups. The study demonstrates that SDS can selectively and effectively adsorb onto kaolinite surfaces, particularly on the (001) plane, facilitating the efficient extraction of fine kaolinite from coal slime. This research holds significant potential for enhancing the utilization of resources from coal slime in the coal industry, offering both economic and environmental benefits.

针对煤泥中细小高岭石和石英颗粒的加工问题,本研究利用分子模拟和密度泛函理论(DFT)研究了十二烷基硫酸钠(SDS)在高岭石表面的螯合吸附特性。作为煤泥中的一种主要粘土矿物成分,高岭石降低了煤的热值,但在工业和农业应用方面却具有潜力。研究发现,SDS 与高岭石的四面体 SiO 层和八面体 AlO 层之间有明显的相互作用,而石英只含有四面体 SiO 层。这种差异对于有效分离高岭石和石英至关重要。研究重点分析了 SDS 在高岭石 (001) 和 (00-1) 平面上的吸附情况。研究结果表明,SDS 在高岭石表面,尤其是在(001)平面上有很强的吸附作用,电荷转移明显,表明其具有高效的螯合作用。这种效应是 SDS 的电子捐赠原子(如 S 和 O)与高岭石表面的金属原子相互作用的结果。通过吸附能计算对吸附强度进行了量化,结果表明(001)表面的吸附作用更强。实验验证(包括单矿物浮选实验和红外光谱分析)进一步证实了模拟结果。这些测试表明,在 SDS 的存在下,高岭石的浮选回收率有所提高,粒度也有所减小。红外分析表明,傅立叶变换红外光谱中羟基伸缩振动减弱,与无机振动和磺酸基团相关的吸收峰发生变化,这表明 SDS 可选择性地强烈吸附在高岭石表面。这项研究表明,SDS 可以选择性地有效吸附在高岭石表面,尤其是 (001) 平面上,从而促进从煤泥中高效提取细高岭石。这项研究为提高煤炭工业对煤泥资源的利用提供了巨大潜力,同时带来了经济和环境效益。
{"title":"Enhancing coal slime processing: Investigating the efficacy of sodium dodecyl sulfonate in the adsorption on kaolinite surfaces","authors":"Fangqin Lu,&nbsp;Lingyun Liu,&nbsp;Chuilei Kong,&nbsp;Hongyu Zhao","doi":"10.1002/apj.3074","DOIUrl":"10.1002/apj.3074","url":null,"abstract":"<p>Addressing the issue of processing fine kaolinite and quartz particles in coal slime, this study utilized molecular simulation and Density Functional Theory (DFT) to investigate the chelate adsorption characteristics of sodium dodecyl sulfate (SDS) on kaolinite surfaces. As a major clay mineral component in coal slime, kaolinite reduces coal's calorific value but holds potential for industrial and agricultural applications. The research identified distinct interactions between SDS and the tetrahedral <span></span>Si<span></span>O layer and octahedral <span></span>Al<span></span>O layer of kaolinite, in contrast to quartz, which contains only the tetrahedral <span></span>Si<span></span>O layer. This difference is crucial for the effective separation of kaolinite from quartz. The study focused on analyzing SDS adsorption on the (001) and (00-1) planes of kaolinite. The findings revealed strong adsorption of SDS on kaolinite surfaces, especially on the (001) plane, evidenced by significant charge transfer indicating efficient chelation. This effect results from the interaction of SDS's electron-donating atoms (such as S and O) with the metal atoms on the surface of kaolinite. Adsorption strength was quantified through adsorption energy calculations, showing a stronger interaction on the (001) surface. Experimental validations, including single mineral flotation experiments and infrared spectroscopic analysis, further corroborated the simulation outcomes. These tests demonstrated improved flotation recovery of kaolinite in the presence of SDS and with reduced particle size. Infrared analysis revealed that SDS selectively and strongly adsorbs on kaolinite surfaces, as indicated by diminished hydroxyl group stretching vibrations in the FTIR spectrum and changes in absorption peaks related to inorganic vibrations and sulfonic acid groups. The study demonstrates that SDS can selectively and effectively adsorb onto kaolinite surfaces, particularly on the (001) plane, facilitating the efficient extraction of fine kaolinite from coal slime. This research holds significant potential for enhancing the utilization of resources from coal slime in the coal industry, offering both economic and environmental benefits.</p>","PeriodicalId":49237,"journal":{"name":"Asia-Pacific Journal of Chemical Engineering","volume":"19 4","pages":""},"PeriodicalIF":1.4,"publicationDate":"2024-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140577548","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of Ti4O7/h-BN self-supported ceramic photoelectrode and its photoelectrocatalytic performance for water purification Ti4O7/h-BN 自支撑陶瓷光电电极的制备及其用于水净化的光电催化性能
IF 1.4 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-04-02 DOI: 10.1002/apj.3072
Shanshan Li, Yanan Gong, Md Azharul Hossain, Zeqi Jiang, Jiarong Zhang, Guowen Wang, Yinghuan Fu, Pengyuan Wang, Yu Song, Hongchao Ma

The construction of high-efficiency self-supported ceramic photoelectrode based on ideal semiconductor materials is essential for achieving effective degradation of pollutants by photoelectrocatalysis (PEC) technology. Herein, a Ti4O7/h-BN composite ceramic photoelectrode with a unique microstructure was fabricated by a step-by-step calcination process and used in PEC water pollution remediation. The PEC activity of Ti4O7 ceramic photoelectrode could be enhanced by introducing hexagonal boron nitride (h-BN) nanoparticles on the surface. The most optimized Ti4O7/h-BN photoelectrode exhibited the decolorization rate of active brilliant blue KN-R at about 97.79% in 30 min. The PEC activities could remain stable during five degradation cycles. The excellent photoelectrocatalytic performance of Ti4O7/h-BN ceramic photoelectrode could be attributed to the low Tafel slope, low charge transfer resistance, large electrochemical active area, and excellent photo-generated carrier separation efficiency. A type-II heterojunction was formed between the Ti4O7 and h-BN, which caused more effective carrier separation and enhanced the generation of dominant active species •O2− and h+. This work provided a mature synthesis strategy of Ti4O7/h-BN self-supported ceramic photoelectrodes with excellent practical application prospects to achieve superior PEC performance for water purification.

要实现光电催化(PEC)技术对污染物的有效降解,基于理想半导体材料的高效自支撑陶瓷光电电极的构建至关重要。本文通过逐步煅烧工艺制备了具有独特微观结构的 Ti4O7/h-BN 复合陶瓷光电极,并将其用于 PEC 水污染修复。通过在 Ti4O7 陶瓷光电极表面引入六方氮化硼(h-BN)纳米颗粒,可提高其 PEC 活性。最优化的 Ti4O7/h-BN 光电极在 30 分钟内对活性亮蓝 KN-R 的脱色率约为 97.79%。在五个降解周期中,PEC 活性保持稳定。Ti4O7/h-BN 陶瓷光电极优异的光电催化性能可归因于其较低的塔菲尔斜率、较低的电荷转移电阻、较大的电化学活性面积和优异的光生载流子分离效率。Ti4O7 和 h-BN 之间形成了 II 型异质结,从而实现了更有效的载流子分离,并增强了主要活性物种 -O2- 和 h+ 的生成。这项工作提供了一种成熟的 Ti4O7/h-BN 自支撑陶瓷光电极合成策略,具有良好的实际应用前景,可在水净化领域实现优异的 PEC 性能。
{"title":"Preparation of Ti4O7/h-BN self-supported ceramic photoelectrode and its photoelectrocatalytic performance for water purification","authors":"Shanshan Li,&nbsp;Yanan Gong,&nbsp;Md Azharul Hossain,&nbsp;Zeqi Jiang,&nbsp;Jiarong Zhang,&nbsp;Guowen Wang,&nbsp;Yinghuan Fu,&nbsp;Pengyuan Wang,&nbsp;Yu Song,&nbsp;Hongchao Ma","doi":"10.1002/apj.3072","DOIUrl":"10.1002/apj.3072","url":null,"abstract":"<p>The construction of high-efficiency self-supported ceramic photoelectrode based on ideal semiconductor materials is essential for achieving effective degradation of pollutants by photoelectrocatalysis (PEC) technology. Herein, a Ti<sub>4</sub>O<sub>7</sub>/h-BN composite ceramic photoelectrode with a unique microstructure was fabricated by a step-by-step calcination process and used in PEC water pollution remediation. The PEC activity of Ti<sub>4</sub>O<sub>7</sub> ceramic photoelectrode could be enhanced by introducing hexagonal boron nitride (h-BN) nanoparticles on the surface. The most optimized Ti<sub>4</sub>O<sub>7</sub>/h-BN photoelectrode exhibited the decolorization rate of active brilliant blue KN-R at about 97.79% in 30 min. The PEC activities could remain stable during five degradation cycles. The excellent photoelectrocatalytic performance of Ti<sub>4</sub>O<sub>7</sub>/h-BN ceramic photoelectrode could be attributed to the low Tafel slope, low charge transfer resistance, large electrochemical active area, and excellent photo-generated carrier separation efficiency. A type-II heterojunction was formed between the Ti<sub>4</sub>O<sub>7</sub> and h-BN, which caused more effective carrier separation and enhanced the generation of dominant active species •O<sup>2−</sup> and h<sup>+</sup>. This work provided a mature synthesis strategy of Ti<sub>4</sub>O<sub>7</sub>/h-BN self-supported ceramic photoelectrodes with excellent practical application prospects to achieve superior PEC performance for water purification.</p>","PeriodicalId":49237,"journal":{"name":"Asia-Pacific Journal of Chemical Engineering","volume":"19 4","pages":""},"PeriodicalIF":1.4,"publicationDate":"2024-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140577540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Scale inhibition performance of carboxylic acid polymers containing ether groups in artificial seawater: Experiments and MD simulation 含有醚基的羧酸聚合物在人工海水中的阻垢性能:实验与 MD 模拟
IF 1.4 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-04-02 DOI: 10.1002/apj.3071
Jiajia Zhang, Xueni Sun, Hui Shao

The lowered dispersibility of carboxylic acid polymers in the seawater system with high salt content results in reduced scale inhibition efficiency. To solve this problem, a series of carboxylic acid polymers containing ether groups were prepared by free radical polymerization using α-allyl glycerol ether (AG) and vinyl monomers containing different numbers of carboxylic acid groups (acrylic acid [AA], maleic acid [MA], itaconic acid [IA], and aconitic acid [ANA]) as raw materials, and their scale inhibition properties in artificial seawater were studied. The static test results demonstrate that IA-AG outperforms the other three polymers containing ether carboxylic acid in terms of scale inhibition performance, with CaCO3 and CaSO4 having scale inhibition rates of 95.16% and 98.73%, respectively. Furthermore, molecular dynamics (MD) simulation was employed to investigate the mechanism of scale inhibition by simulating the interaction between ether carboxylic acid polymers and the crystal surface. The results show that the order of binding energy between polymers and crystal faces is IA-AG > ANA-AG > MA-AG > AA-AG. The simulation results are in agreement with the experimental phenomena. The polymers can overcome their own deformation and adsorb on the crystal surfaces, thus inhibiting the growth of scale.

羧酸聚合物在含盐量较高的海水系统中分散性较低,导致阻垢效率降低。为解决这一问题,以α-烯丙基甘油醚(AG)和含有不同数量羧基的乙烯基单体(丙烯酸[AA]、马来酸[MA]、衣康酸[IA]和乌头酸[ANA])为原料,通过自由基聚合制备了一系列含有醚基的羧酸聚合物,并研究了它们在人工海水中的阻垢性能。静态测试结果表明,IA-AG 的阻垢性能优于其他三种含醚羧酸聚合物,CaCO3 和 CaSO4 的阻垢率分别为 95.16% 和 98.73%。此外,通过模拟醚羧酸聚合物与晶体表面的相互作用,采用分子动力学(MD)模拟研究了阻垢机理。结果表明,聚合物与晶面的结合能顺序为 IA-AG > ANA-AG > MA-AG > AA-AG。模拟结果与实验现象一致。聚合物可以克服自身变形吸附在晶体表面,从而抑制鳞片的生长。
{"title":"Scale inhibition performance of carboxylic acid polymers containing ether groups in artificial seawater: Experiments and MD simulation","authors":"Jiajia Zhang,&nbsp;Xueni Sun,&nbsp;Hui Shao","doi":"10.1002/apj.3071","DOIUrl":"10.1002/apj.3071","url":null,"abstract":"<p>The lowered dispersibility of carboxylic acid polymers in the seawater system with high salt content results in reduced scale inhibition efficiency. To solve this problem, a series of carboxylic acid polymers containing ether groups were prepared by free radical polymerization using α-allyl glycerol ether (AG) and vinyl monomers containing different numbers of carboxylic acid groups (acrylic acid [AA], maleic acid [MA], itaconic acid [IA], and aconitic acid [ANA]) as raw materials, and their scale inhibition properties in artificial seawater were studied. The static test results demonstrate that IA-AG outperforms the other three polymers containing ether carboxylic acid in terms of scale inhibition performance, with CaCO<sub>3</sub> and CaSO<sub>4</sub> having scale inhibition rates of 95.16% and 98.73%, respectively. Furthermore, molecular dynamics (MD) simulation was employed to investigate the mechanism of scale inhibition by simulating the interaction between ether carboxylic acid polymers and the crystal surface. The results show that the order of binding energy between polymers and crystal faces is IA-AG &gt; ANA-AG &gt; MA-AG &gt; AA-AG. The simulation results are in agreement with the experimental phenomena. The polymers can overcome their own deformation and adsorb on the crystal surfaces, thus inhibiting the growth of scale.</p>","PeriodicalId":49237,"journal":{"name":"Asia-Pacific Journal of Chemical Engineering","volume":"19 4","pages":""},"PeriodicalIF":1.4,"publicationDate":"2024-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140577311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on the influence of aeration manners on the mass transfer characteristics of bubbles in multi-column airlift photobioreactor 曝气方式对多柱气升式光生物反应器中气泡传质特性的影响研究
IF 1.4 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-04-01 DOI: 10.1002/apj.3068
Shuangcheng Fu, Chenxi Liu, Faqi Zhou, Tao Yu, Kewei Li, Yue Zhang, Shenghu Yan, Xiang Zhang

Mass transfer of bubbles is important in microalgae cultivation. In this study, aiming to improve the microalgae culturing efficiency, computational fluid dynamics (CFD) was adopted to study the influence of the aeration manners on mass transfer of bubbles within ascending columns in multi-column airlift photobioreactor (PBR) and the hydrodynamic conditions within the PBR under different aeration manners. In addition, the bubble generation time, the detachment diameter, and the average volumetric mass transfer coefficient of bubbles in ascending columns were analyzed. Furthermore, the experimental results were compared with the simulation results obtained from microalgae cultivation. The results showed that the whole aeration manner yields the lowest mixing strength and mass transfer efficiency of bubbles at an aeration rate of 0.2 vvm. Conversely, both the mixing strength of the liquid and mass transfer coefficient of bubbles were enhanced under the half and alternate aeration manners. However, the results demonstrated that the distribution of the flow field was not uniform under the half aeration manner and there were obvious high-speed and low-speed zones. In contrast, the flow field distribution in the PBR was more uniform under the alternate aeration manner, which was suitable for microalgae cultivation at high concentration. This study effectively enhanced the mixing strength and CO2 transfer rate in the PBR.

气泡的传质在微藻培养中非常重要。本研究以提高微藻培养效率为目的,采用计算流体动力学(CFD)方法研究了多柱气升式光生物反应器(PBR)中曝气方式对上升柱内气泡传质的影响,以及不同曝气方式下PBR内的水动力条件。此外,还分析了上升柱中气泡的产生时间、脱离直径和平均体积传质系数。此外,还将实验结果与微藻培养的模拟结果进行了比较。结果表明,当曝气速率为 0.2 vvm 时,整体曝气方式产生的气泡混合强度和传质效率最低。相反,在半曝气和交替曝气方式下,液体的混合强度和气泡的传质系数都有所提高。但结果表明,在半曝气方式下,流场分布并不均匀,存在明显的高速区和低速区。相比之下,交替曝气方式下 PBR 的流场分布更加均匀,适合高浓度微藻培养。这项研究有效地提高了 PBR 的混合强度和二氧化碳转移率。
{"title":"Research on the influence of aeration manners on the mass transfer characteristics of bubbles in multi-column airlift photobioreactor","authors":"Shuangcheng Fu,&nbsp;Chenxi Liu,&nbsp;Faqi Zhou,&nbsp;Tao Yu,&nbsp;Kewei Li,&nbsp;Yue Zhang,&nbsp;Shenghu Yan,&nbsp;Xiang Zhang","doi":"10.1002/apj.3068","DOIUrl":"10.1002/apj.3068","url":null,"abstract":"<p>Mass transfer of bubbles is important in microalgae cultivation. In this study, aiming to improve the microalgae culturing efficiency, computational fluid dynamics (CFD) was adopted to study the influence of the aeration manners on mass transfer of bubbles within ascending columns in multi-column airlift photobioreactor (PBR) and the hydrodynamic conditions within the PBR under different aeration manners. In addition, the bubble generation time, the detachment diameter, and the average volumetric mass transfer coefficient of bubbles in ascending columns were analyzed. Furthermore, the experimental results were compared with the simulation results obtained from microalgae cultivation. The results showed that the whole aeration manner yields the lowest mixing strength and mass transfer efficiency of bubbles at an aeration rate of 0.2 vvm. Conversely, both the mixing strength of the liquid and mass transfer coefficient of bubbles were enhanced under the half and alternate aeration manners. However, the results demonstrated that the distribution of the flow field was not uniform under the half aeration manner and there were obvious high-speed and low-speed zones. In contrast, the flow field distribution in the PBR was more uniform under the alternate aeration manner, which was suitable for microalgae cultivation at high concentration. This study effectively enhanced the mixing strength and CO<sub>2</sub> transfer rate in the PBR.</p>","PeriodicalId":49237,"journal":{"name":"Asia-Pacific Journal of Chemical Engineering","volume":"19 4","pages":""},"PeriodicalIF":1.4,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140577550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental investigation on dynamic characteristics of methane/air combustion in double-layer pellets porous media 双层颗粒多孔介质中甲烷/空气燃烧动态特性的实验研究
IF 1.4 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-04-01 DOI: 10.1002/apj.3059
Hui Wang, Ning Wang, Guangshun Wang, Xiangyu Wang, Xiang Liu, Yuxuan Zhu

The double-layer porous media burner is considered as an effective way to realize stable lean-burn. In order to quickly achieve a stable combustion state in a double-layer porous media burner, this work investigated the dynamic characteristics of methane/air premixed combustion in a bench-scale double-layer porous media burnspanning from ignition to stable combustion and ultimately flameout. The experimental results indicate that regulating the equivalence ratio and the inlet velocity enables the establishment of a stable flame front and the φ = 0.75 and the Vin = 0.20 m/s are the appropriate start-up conditions. The average propagation velocity of the combustion wave variation along the axial direction and ranged approximately from −0.022 to −0.078 mm/s. Moreover, the transition time to a stable combustion state is reduced by nearly 47.14% as the equivalence ratio increases from 0.60 to 0.70. During start-up stage, there are significant fluctuations in CO and NOx concentrations, but both emissions remain low during steady combustion state, with the maximum concentrations of 37.5 and 40.2 mg/m3, respectively. Furthermore, the porous media combustion exhibits a pronounced re-ignition capacity. At higher equivalence ratios, longer interruptions of premixed gas are allowed.

双层多孔介质燃烧器被认为是实现稳定贫燃烧的有效方法。为了在双层多孔介质燃烧器中快速实现稳定燃烧状态,本研究对甲烷/空气预混合燃烧在台式双层多孔介质燃烧器中从点火到稳定燃烧再到最终熄火的动态特性进行了研究。实验结果表明,调节当量比和入口速度可建立稳定的火焰前沿,φ = 0.75 和 Vin = 0.20 m/s 是合适的启动条件。燃烧波的平均传播速度沿轴向变化,大约在 -0.022 至 -0.078 mm/s 之间。此外,当当量比从 0.60 增加到 0.70 时,过渡到稳定燃烧状态的时间缩短了近 47.14%。在启动阶段,一氧化碳和氮氧化物的浓度有明显的波动,但在稳定燃烧状态下,这两种气体的排放量仍然很低,最大浓度分别为 37.5 和 40.2 mg/m3。此外,多孔介质燃烧还表现出明显的复燃能力。当量比越高,预混合气体的中断时间就越长。
{"title":"Experimental investigation on dynamic characteristics of methane/air combustion in double-layer pellets porous media","authors":"Hui Wang,&nbsp;Ning Wang,&nbsp;Guangshun Wang,&nbsp;Xiangyu Wang,&nbsp;Xiang Liu,&nbsp;Yuxuan Zhu","doi":"10.1002/apj.3059","DOIUrl":"10.1002/apj.3059","url":null,"abstract":"<p>The double-layer porous media burner is considered as an effective way to realize stable lean-burn. In order to quickly achieve a stable combustion state in a double-layer porous media burner, this work investigated the dynamic characteristics of methane/air premixed combustion in a bench-scale double-layer porous media burnspanning from ignition to stable combustion and ultimately flameout. The experimental results indicate that regulating the equivalence ratio and the inlet velocity enables the establishment of a stable flame front and the φ = 0.75 and the <i>V</i><sub>in</sub> = 0.20 m/s are the appropriate start-up conditions. The average propagation velocity of the combustion wave variation along the axial direction and ranged approximately from −0.022 to −0.078 mm/s. Moreover, the transition time to a stable combustion state is reduced by nearly 47.14% as the equivalence ratio increases from 0.60 to 0.70. During start-up stage, there are significant fluctuations in CO and NOx concentrations, but both emissions remain low during steady combustion state, with the maximum concentrations of 37.5 and 40.2 mg/m<sup>3</sup>, respectively. Furthermore, the porous media combustion exhibits a pronounced re-ignition capacity. At higher equivalence ratios, longer interruptions of premixed gas are allowed.</p>","PeriodicalId":49237,"journal":{"name":"Asia-Pacific Journal of Chemical Engineering","volume":"19 4","pages":""},"PeriodicalIF":1.4,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140577636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design and hydraulic study of double-partition dividing-wall column 双隔墙分隔柱的设计与水力研究
IF 1.4 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-03-28 DOI: 10.1002/apj.3063
Shengyi Guan, Yongshuai Li, Gaoyang Li, Litao Zhu, Hui Pan, Hao Ling

Dividing-wall column (DWC) provides tremendous advantages in terms of energy savings and capital costs for three-component and even multi-component separations. With increasing industrial application of three-component DWCs, DWCs for separation of four-component have received considerable research attention. The aim of this work is to investigate the design of the two-staggered wall region and gas–liquid two-phase flow behavior on the tray in a double-partition DWC (DPDWC). The Aspen Plus was applied to simulate the steady state to obtain the gas–liquid-phase flow rate in each region to serve as the basis for the tray design. In different task regions, the gas- and liquid-phase flow varied in some ways. The drag models have variability for the study of fluid flow, and the Tomiyama model is more appropriate. Moreover, high-velocity gradients and recirculating phenomenon can be discovered owing to the existence of multiple partitions in DPDWC.

分壁柱(DWC)在三组分甚至多组分分离的节能和资金成本方面具有巨大优势。随着三组份 DWC 在工业上的应用越来越多,用于四组份分离的 DWC 也受到了相当多的研究关注。这项工作旨在研究双分区 DWC(DPDWC)中双层交错壁区的设计以及托盘上的气液两相流行为。应用 Aspen Plus 进行稳态模拟,以获得各区域的气液相流量,作为托盘设计的基础。在不同的任务区域,气相和液相流动有一定的差异。在研究流体流动时,阻力模型具有可变性,而富山模型更为合适。此外,由于 DPDWC 中存在多个分区,因此可以发现高速梯度和再循环现象。
{"title":"Design and hydraulic study of double-partition dividing-wall column","authors":"Shengyi Guan,&nbsp;Yongshuai Li,&nbsp;Gaoyang Li,&nbsp;Litao Zhu,&nbsp;Hui Pan,&nbsp;Hao Ling","doi":"10.1002/apj.3063","DOIUrl":"10.1002/apj.3063","url":null,"abstract":"<p>Dividing-wall column (DWC) provides tremendous advantages in terms of energy savings and capital costs for three-component and even multi-component separations. With increasing industrial application of three-component DWCs, DWCs for separation of four-component have received considerable research attention. The aim of this work is to investigate the design of the two-staggered wall region and gas–liquid two-phase flow behavior on the tray in a double-partition DWC (DPDWC). The Aspen Plus was applied to simulate the steady state to obtain the gas–liquid-phase flow rate in each region to serve as the basis for the tray design. In different task regions, the gas- and liquid-phase flow varied in some ways. The drag models have variability for the study of fluid flow, and the Tomiyama model is more appropriate. Moreover, high-velocity gradients and recirculating phenomenon can be discovered owing to the existence of multiple partitions in DPDWC.</p>","PeriodicalId":49237,"journal":{"name":"Asia-Pacific Journal of Chemical Engineering","volume":"19 4","pages":""},"PeriodicalIF":1.4,"publicationDate":"2024-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140323377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Laminar flame speed measurement and combustion mechanism optimization for ethylene–air mixtures 乙烯-空气混合物的层流火焰速度测量和燃烧机理优化
IF 1.4 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-03-26 DOI: 10.1002/apj.3060
Lei Wang, Ruida Hou, Zixing Zhang, Yindong Song

Ethylene plays a crucial role as an intermediate component in the cracking and combustion processes of large molecular alkane and olefins. In this article, the laminar flame speed of ethylene–air mixtures was measured using the heat flux method. The mechanism of ethylene was simplified by utilizing the error propagation directed relationship graph (DRGEP) and sensitivity analysis (SA), and the Arrhenius pre-exponential factors for 20 selected reactions in the skeletal mechanism were optimized using the particle swarm optimization (PSO) algorithm. Finally, an ethylene optimization mechanism including 39 species and 85 reactions was obtained. The prediction results for flame speed, ignition delay time, and species concentration were compared with experimental data and other mechanisms, covering a wide range of temperatures (298–1725 K), pressures (1–22.8 atm), and equivalence ratios (0.5–2.0). The findings demonstrate that the optimization mechanism not only improves the prediction results of laminar flame speed in the rich combustion zone and low oxygen environment but also enhances the prediction accuracy of the ignition delay time at high pressure and in the lean combustion zone, as well as the prediction accuracy of C2H4 and H2O radicals. In conclusion, the optimized mechanism exhibits higher accuracy and broader applicability.

在大分子烷烃和烯烃的裂解和燃烧过程中,乙烯作为中间组分起着至关重要的作用。本文采用热通量法测量了乙烯-空气混合物的层燃速度。利用误差传播有向关系图(DRGEP)和敏感性分析(SA)简化了乙烯的机理,并利用粒子群优化(PSO)算法优化了骨架机理中选定的 20 个反应的阿伦尼斯预指数因子。最后得到了包括 39 个物种和 85 个反应的乙烯优化机理。火焰速度、点火延迟时间和物种浓度的预测结果与实验数据和其他机理进行了比较,涵盖的温度(298-1725 K)、压力(1-22.8 atm)和当量比(0.5-2.0)范围很广。研究结果表明,优化机制不仅改善了富燃区和低氧环境下层流火焰速度的预测结果,还提高了高压和贫燃区点火延迟时间的预测精度,以及 C2H4 和 H2O 自由基的预测精度。总之,优化后的机制具有更高的准确性和更广泛的适用性。
{"title":"Laminar flame speed measurement and combustion mechanism optimization for ethylene–air mixtures","authors":"Lei Wang,&nbsp;Ruida Hou,&nbsp;Zixing Zhang,&nbsp;Yindong Song","doi":"10.1002/apj.3060","DOIUrl":"10.1002/apj.3060","url":null,"abstract":"<p>Ethylene plays a crucial role as an intermediate component in the cracking and combustion processes of large molecular alkane and olefins. In this article, the laminar flame speed of ethylene–air mixtures was measured using the heat flux method. The mechanism of ethylene was simplified by utilizing the error propagation directed relationship graph (DRGEP) and sensitivity analysis (SA), and the Arrhenius pre-exponential factors for 20 selected reactions in the skeletal mechanism were optimized using the particle swarm optimization (PSO) algorithm. Finally, an ethylene optimization mechanism including 39 species and 85 reactions was obtained. The prediction results for flame speed, ignition delay time, and species concentration were compared with experimental data and other mechanisms, covering a wide range of temperatures (298–1725 K), pressures (1–22.8 atm), and equivalence ratios (0.5–2.0). The findings demonstrate that the optimization mechanism not only improves the prediction results of laminar flame speed in the rich combustion zone and low oxygen environment but also enhances the prediction accuracy of the ignition delay time at high pressure and in the lean combustion zone, as well as the prediction accuracy of C<sub>2</sub>H<sub>4</sub> and H<sub>2</sub>O radicals. In conclusion, the optimized mechanism exhibits higher accuracy and broader applicability.</p>","PeriodicalId":49237,"journal":{"name":"Asia-Pacific Journal of Chemical Engineering","volume":"19 4","pages":""},"PeriodicalIF":1.4,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140315897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Controllable synthesis of snowflake-like α-calcium sulfate hemihydrate microstructures using Na2EDTA as morphology modifier 使用 Na2EDTA 作为形态改性剂可控合成雪花状 α-硫酸钙半水合物微结构
IF 1.4 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-03-25 DOI: 10.1002/apj.3064
Lingling Lv, Yang Gao, Ming Guo, Minfu Liu, Baocun Zhang, Han Lin, Xingong Zhang, Chenguang Liu

In this work, snowflake-like α-CaSO4·0.5H2O (α-CSH) hierarchical architectures were successfully synthesized by a facile one-pot method in an ethylene glycol-water system using Na2EDTA as a crystal morphology modifier. Characterization techniques including X-ray diffraction (XRD), thermogravimetric (TG) analysis, differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR) confirmed the progressive morphological evolution of α-CSH from rods to snowflake-like structures ultimately to hexagonal plates with increased Na2EDTA concentrations. The results revealed that Na2EDTA concentration played a critical role in directing the crystallization and self-assembly of α-CSH, and a mechanism is proposed where Na2EDTA modulated crystal orientation through preferential adsorption and regulated the driving forces between ion-mediated crystallization and particle-mediated assembly. This work puts forward a simple yet effective strategy for facilely regulating the morphology of α-CSH microstructures, which could potentially expand their applications across diverse fields such as composites, construction, biomedicine, and drug delivery.

本研究以 Na2EDTA 为晶体形态改性剂,在乙二醇-水体系中采用简便的一锅法成功合成了雪花状 α-CaSO4-0.5H2O (α-CSH)分层结构。包括 X 射线衍射 (XRD)、热重分析 (TG)、差示扫描量热法 (DSC)、扫描电子显微镜 (SEM) 和傅立叶变换红外光谱 (FTIR) 在内的表征技术证实,随着 Na2EDTA 浓度的增加,α-CSH 的形态从棒状结构逐渐演变为雪花状结构,并最终演变为六方板状结构。研究结果表明,Na2EDTA 浓度在引导 α-CSH 结晶和自组装方面起着关键作用,并提出了一种机制,即 Na2EDTA 通过优先吸附调节晶体取向,并调节离子介导的结晶和颗粒介导的组装之间的驱动力。这项研究提出了一种简单而有效的策略,可以方便地调节 α-CSH 微结构的形态,从而有可能扩大其在复合材料、建筑、生物医学和药物输送等不同领域的应用。
{"title":"Controllable synthesis of snowflake-like α-calcium sulfate hemihydrate microstructures using Na2EDTA as morphology modifier","authors":"Lingling Lv,&nbsp;Yang Gao,&nbsp;Ming Guo,&nbsp;Minfu Liu,&nbsp;Baocun Zhang,&nbsp;Han Lin,&nbsp;Xingong Zhang,&nbsp;Chenguang Liu","doi":"10.1002/apj.3064","DOIUrl":"10.1002/apj.3064","url":null,"abstract":"<p>In this work, snowflake-like α-CaSO<sub>4</sub>·0.5H<sub>2</sub>O (α-CSH) hierarchical architectures were successfully synthesized by a facile one-pot method in an ethylene glycol-water system using Na<sub>2</sub>EDTA as a crystal morphology modifier. Characterization techniques including X-ray diffraction (XRD), thermogravimetric (TG) analysis, differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR) confirmed the progressive morphological evolution of α-CSH from rods to snowflake-like structures ultimately to hexagonal plates with increased Na<sub>2</sub>EDTA concentrations. The results revealed that Na<sub>2</sub>EDTA concentration played a critical role in directing the crystallization and self-assembly of α-CSH, and a mechanism is proposed where Na<sub>2</sub>EDTA modulated crystal orientation through preferential adsorption and regulated the driving forces between ion-mediated crystallization and particle-mediated assembly. This work puts forward a simple yet effective strategy for facilely regulating the morphology of α-CSH microstructures, which could potentially expand their applications across diverse fields such as composites, construction, biomedicine, and drug delivery.</p>","PeriodicalId":49237,"journal":{"name":"Asia-Pacific Journal of Chemical Engineering","volume":"19 4","pages":""},"PeriodicalIF":1.4,"publicationDate":"2024-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140301399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Utilization of industrial by-product gypsum to prepare urea gypsum cocrystals as a sustained release fertilizer: A review 利用工业副产品石膏制备尿素石膏茧晶作为缓释肥料:综述
IF 1.4 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-03-24 DOI: 10.1002/apj.3066
Jiang Zhao, Caiyun Jia, Xiaoxia Fang, Anni Xiao, Haijun Zhang

The large-scale accumulation of industrial by-product gypsum has led to land embezzlement and serious environmental pollution. Meanwhile, as a predominantly used nitrogen fertilizer, urea shows a disadvantage of high solubility in soil. Therefore, it can hydrolyze into large amounts of ammonium salts so rapidly that cannot be absorbed efficiently by crops. The sustainable method of using industrial by-product gypsum to synthesize urea gypsum cocrystals is a promising way to solve above challenges. The synthesized urea gypsum shows low aqueous solubility and hygroscopicity, which can be used as sustained release fertilizer. In this review, the present status regarding urea gypsum is systematically reviewed, including its development history, preparation methods, impact of different raw materials, evaluation of products performance, and large-scale trials. This review aims to reveal the current situation, identify current gaps, and provide suggestions for future investigations concerning urea gypsum.

工业副产品石膏的大量堆积导致了土地侵占和严重的环境污染。同时,尿素作为一种主要的氮肥,在土壤中具有高溶解性的缺点。因此,它会迅速水解成大量铵盐,无法被作物有效吸收。利用工业副产品石膏合成尿素石膏茧晶的可持续方法是解决上述难题的一个可行途径。合成的尿素石膏具有低水溶性和吸湿性,可用作缓释肥料。本综述系统回顾了尿素石膏的现状,包括其发展历史、制备方法、不同原料的影响、产品性能评估和大规模试验。本综述旨在揭示尿素石膏的现状,找出目前存在的差距,并为今后的研究提供建议。
{"title":"Utilization of industrial by-product gypsum to prepare urea gypsum cocrystals as a sustained release fertilizer: A review","authors":"Jiang Zhao,&nbsp;Caiyun Jia,&nbsp;Xiaoxia Fang,&nbsp;Anni Xiao,&nbsp;Haijun Zhang","doi":"10.1002/apj.3066","DOIUrl":"10.1002/apj.3066","url":null,"abstract":"<p>The large-scale accumulation of industrial by-product gypsum has led to land embezzlement and serious environmental pollution. Meanwhile, as a predominantly used nitrogen fertilizer, urea shows a disadvantage of high solubility in soil. Therefore, it can hydrolyze into large amounts of ammonium salts so rapidly that cannot be absorbed efficiently by crops. The sustainable method of using industrial by-product gypsum to synthesize urea gypsum cocrystals is a promising way to solve above challenges. The synthesized urea gypsum shows low aqueous solubility and hygroscopicity, which can be used as sustained release fertilizer. In this review, the present status regarding urea gypsum is systematically reviewed, including its development history, preparation methods, impact of different raw materials, evaluation of products performance, and large-scale trials. This review aims to reveal the current situation, identify current gaps, and provide suggestions for future investigations concerning urea gypsum.</p>","PeriodicalId":49237,"journal":{"name":"Asia-Pacific Journal of Chemical Engineering","volume":"19 4","pages":""},"PeriodicalIF":1.4,"publicationDate":"2024-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140301325","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dividing-wall column for separating wide boiling mixture: Optimal design and servo control strategy 用于分离宽沸程混合物的分壁柱:优化设计和伺服控制策略
IF 1.4 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-03-21 DOI: 10.1002/apj.3065
Md Aurangzeb, Sudip Banerjee, Subhankar Roy, Ravi Tejasvi

The dividing-wall column (DWC) stands as an energy-efficient distillation technology designed to efficiently separate ternary systems into their pure components within a single column. Despite its efficiency, integrating two towers into a DWC poses challenges in controllability. Published studies have focused on developing controllers for disturbance rejection but have not addressed the issue of servo control. Addressing this, our study proposes a servo controller problem and a methodical approach to strategically select controlled variables that undergo consecutive set point step changes, aiming to track the purity of key products obtained from the DWC. To achieve this goal, we developed a dynamic model specifically tailored to the DWC. Determining the design parameters involved employing a genetic algorithm optimization technique, minimizing the total annual cost. Subsequently, we implemented three servo parallel proportional-integral (PI) feedback controllers for three distinct product streams. The fine-tuning of their controller gain and reset time is carried out by minimizing the integrated square error while adhering to valve opening constraints. Our investigation revealed a limitation: the introduction of simultaneous step changes in all three controlled variables proved unfeasible with the three active PI controllers. As an alternative, our findings recommend prioritizing two variables: the lightest (distillate) and heaviest (bottom) key components, alongside the middle component (side stream) and either the lightest or heaviest key component. This research underscores the complexities of implementing step changes in multiple controlled variables within a DWC, offering insights into optimal control strategies for enhancing the efficiency of this innovative distillation technology.

隔墙蒸馏塔(DWC)是一种高效节能的蒸馏技术,其设计目的是在单个塔内将三元系统有效地分离成纯组分。尽管效率很高,但将两个塔集成到 DWC 中会给可控性带来挑战。已发表的研究主要集中于开发干扰抑制控制器,但并未涉及伺服控制问题。针对这一问题,我们的研究提出了一个伺服控制器问题和一种有条不紊的方法,以战略性地选择经过连续设定点阶跃变化的受控变量,从而跟踪从 DWC 中获得的关键产品的纯度。为实现这一目标,我们开发了一个专门针对 DWC 的动态模型。在确定设计参数时,我们采用了遗传算法优化技术,最大限度地降低了年度总成本。随后,我们为三个不同的产品流实施了三个伺服并行比例积分(PI)反馈控制器。控制器增益和复位时间的微调是在遵守阀门开度限制的前提下,通过最小化综合平方误差来实现的。我们的研究发现了一个局限性:在所有三个受控变量中同时引入阶跃变化在三个主动 PI 控制器中证明是不可行的。作为替代方案,我们的研究结果建议优先考虑两个变量:最轻(馏分)和最重(底部)的关键组分,以及中间组分(侧流)和最轻或最重的关键组分。这项研究强调了在 DWC 中对多个受控变量实施阶跃变化的复杂性,为提高这种创新蒸馏技术的效率提供了最佳控制策略。
{"title":"Dividing-wall column for separating wide boiling mixture: Optimal design and servo control strategy","authors":"Md Aurangzeb,&nbsp;Sudip Banerjee,&nbsp;Subhankar Roy,&nbsp;Ravi Tejasvi","doi":"10.1002/apj.3065","DOIUrl":"10.1002/apj.3065","url":null,"abstract":"<p>The dividing-wall column (DWC) stands as an energy-efficient distillation technology designed to efficiently separate ternary systems into their pure components within a single column. Despite its efficiency, integrating two towers into a DWC poses challenges in controllability. Published studies have focused on developing controllers for disturbance rejection but have not addressed the issue of servo control. Addressing this, our study proposes a servo controller problem and a methodical approach to strategically select controlled variables that undergo consecutive set point step changes, aiming to track the purity of key products obtained from the DWC. To achieve this goal, we developed a dynamic model specifically tailored to the DWC. Determining the design parameters involved employing a genetic algorithm optimization technique, minimizing the total annual cost. Subsequently, we implemented three servo parallel proportional-integral (PI) feedback controllers for three distinct product streams. The fine-tuning of their controller gain and reset time is carried out by minimizing the integrated square error while adhering to valve opening constraints. Our investigation revealed a limitation: the introduction of simultaneous step changes in all three controlled variables proved unfeasible with the three active PI controllers. As an alternative, our findings recommend prioritizing two variables: the lightest (distillate) and heaviest (bottom) key components, alongside the middle component (side stream) and either the lightest or heaviest key component. This research underscores the complexities of implementing step changes in multiple controlled variables within a DWC, offering insights into optimal control strategies for enhancing the efficiency of this innovative distillation technology.</p>","PeriodicalId":49237,"journal":{"name":"Asia-Pacific Journal of Chemical Engineering","volume":"19 4","pages":""},"PeriodicalIF":1.4,"publicationDate":"2024-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140197500","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Asia-Pacific Journal of Chemical Engineering
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1