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Microstructural and mechanical evolution of sintered nano-silver joints on bare copper substrates during high-temperature storage 裸铜衬底烧结纳米银接头高温贮存过程中的显微组织和力学演化
IF 2 4区 材料科学 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-11-27 DOI: 10.1108/ssmt-12-2022-0061
Meng Jiang, Yang Liu, Ke Li, Zhen Pan, Quan Sun, Yongzhe Xu, Yuan Tao

Purpose

The purpose of this paper is to study the reliability of sintered nano-silver joints on bare copper substrates during high-temperature storage (HTS).

Design/methodology/approach

In this study, HTS at 250 °C was carried out to investigate the reliability of nano-silver sintered joints. Combining the evolution of the microstructure and shear strength of the joints, the degradation mechanisms of joints performance were characterized.

Findings

The results indicated that the degradation of the shear properties of sintered nano-silver joints on copper substrates was attributed to copper oxidation at the silver/copper interface and interdiffusion of interfacial elements. The joints decreased by approximately 57.4% compared to the original joints after aging for 500 h. In addition, severe coarsening of the silver structure was also an important cause for joints failure during HTS.

Originality/value

This paper provides a comparison of quantitative and mechanistic evaluation of sintered silver joints on bare copper substrates during HTS, which is of great importance in promoting the development of sintered silver technology.

目的研究裸铜衬底烧结纳米银接头在高温储存过程中的可靠性。设计/方法/方法在本研究中,采用250°C高温超导(HTS)来研究纳米银烧结接头的可靠性。结合节理的微观结构演变和抗剪强度,分析了节理性能的退化机理。结果表明:铜基体上烧结纳米银接头剪切性能的下降主要是由于铜在银/铜界面上的氧化和界面元素的相互扩散。时效500h后,接头与原接头相比减少了约57.4%。此外,银组织的严重粗化也是高温超导过程中接头失效的重要原因。本文对裸铜衬底烧结银接头进行了定量评价和机理评价的比较,对促进烧结银技术的发展具有重要意义。
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引用次数: 0
Deep learning and analytical study of void regional formation in flip-chip underfilling process 倒装下填过程中空洞区域形成的深度学习与分析研究
4区 材料科学 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-10-24 DOI: 10.1108/ssmt-06-2023-0028
Calvin Ling, Muhammad Taufik Azahari, Mohamad Aizat Abas, Fei Chong Ng
Purpose This paper aims to study the relationship between the ball grid array (BGA) flip-chip underfilling process parameter and its void formation region. Design/methodology/approach A set of top-down scanning acoustic microscope images of BGA underfill is collected and void labelled. The labelled images are trained with a convolutional neural network model, and the performance is evaluated. The model is tested with new images, and the void area with its region is analysed with its dispensing parameter. Findings All findings were well-validated with reference to the past experimental results regarding dispensing parameters and their quantitative regional formation. As the BGA is non-uniform, 85% of the test samples have void(s) formed in the emptier region. Furthermore, the highest rating factor, valve dispensing pressure with a Gini index of 0.219 and U-type dispensing pattern set of parameters generally form a lower void percentage within the underfilling, although its consistency is difficult to maintain. Practical implications This study enabled manufacturers to forecast the void regional formation from its filling parameters and array pattern. The filling pressure, dispensing pattern and BGA relations could provide qualitative insights to understand the void formation region in a flip-chip, enabling the prompt to formulate countermeasures to optimise voiding in a specific area in the underfill. Originality/value The void regional formation in a flip-chip underfilling process can be explained quantitatively with indicative parameters such as valve pressure, dispensing pattern and BGA arrangement.
目的研究球栅阵列(BGA)倒装芯片下填充工艺参数与其孔隙形成区域的关系。设计/方法/方法收集BGA底填体的一组自上而下扫描声学显微镜图像并标记空隙。用卷积神经网络模型对标记后的图像进行训练,并对其性能进行评价。利用新图像对模型进行了测试,并对空洞区域及其分布参数进行了分析。结果与以往的实验结果相比较,均得到了较好的验证。由于BGA是不均匀的,85%的测试样品在较空的区域形成了空洞。此外,评级因子最高、阀点胶压力(基尼系数为0.219)和u型点胶模式组参数总体上形成了较低的下填充空隙率,但其一致性难以保持。实际意义本研究使制造商能够根据其填充参数和阵列模式预测空洞的区域形成。充填压力、配胶模式和BGA关系可以为了解倒装芯片中的空隙形成区域提供定性的见解,从而能够及时制定对策,以优化下填体中特定区域的空隙。用阀门压力、点胶方式、BGA排列等指示性参数,可以定量地解释倒装下填充过程中空洞区域的形成。
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引用次数: 0
Low-cycle fatigue life assessment of SAC solder alloy through a FEM-data driven machine learning approach 基于有限元数据驱动机器学习方法的SAC焊料合金低周疲劳寿命评估
4区 材料科学 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-09-28 DOI: 10.1108/ssmt-08-2023-0045
Vicente-Segundo Ruiz-Jacinto, Karina-Silvana Gutiérrez-Valverde, Abrahan-Pablo Aslla-Quispe, José-Manuel Burga-Falla, Aldo Alarcón-Sucasaca, Yersi-Luis Huamán-Romaní
Purpose This paper aims to present the novel stacked machine learning approach (SMLA) to estimate low-cycle fatigue (LCF) life of SAC305 solder across structural parts. Using the finite element simulation (FEM) and continuous damage mechanics (CDM) model, a fatigue life database is built. The stacked machine learning (ML) model's iterative optimization during training enables precise fatigue predictions (2.41% root mean square error [RMSE], R 2 = 0.975) for diverse structural components. Outliers are found in regression analysis, indicating potential overestimation for thickness transition specimens with extended lifetimes and underestimation for open-hole specimens. Correlations between fatigue life, stress factors, nominal stress and temperature are unveiled, enriching comprehension of LCF, thus enhancing solder behavior predictions. Design/methodology/approach This paper introduces stacked ML as a novel approach for estimating LCF life of SAC305 solder in various structural parts. It builds a fatigue life database using FEM and CDM model. The stacked ML model iteratively optimizes its structure, yielding accurate fatigue predictions (2.41% RMSE, R 2 = 0.975). Outliers are observed: overestimation for thickness transition specimens and underestimation for open-hole ones. Correlations between fatigue life, stress factors, nominal stress and temperature enhance predictions, deepening understanding of solder behavior. Findings The findings of this paper highlight the successful application of the SMLA in accurately estimating the LCF life of SAC305 solder across diverse structural components. The stacked ML model, trained iteratively, demonstrates its effectiveness by producing precise fatigue lifetime predictions with a RMSE of 2.41% and an “ R 2 ” value of 0.975. The study also identifies distinct outlier behaviors associated with different structural parts: overestimations for thickness transition specimens with extended fatigue lifetimes and underestimations for open-hole specimens. The research further establishes correlations between fatigue life, stress concentration factors, nominal stress and temperature, enriching the understanding of solder behavior prediction. Originality/value The authors confirm the originality of this paper.
本文旨在提出一种新的堆叠机器学习方法(SMLA)来估计SAC305结构件焊料的低周疲劳(LCF)寿命。采用有限元模拟(FEM)和连续损伤力学(CDM)模型,建立了疲劳寿命数据库。堆叠机器学习(ML)模型在训练过程中的迭代优化可以精确预测不同结构部件的疲劳(2.41%的均方根误差[RMSE], r2 = 0.975)。在回归分析中发现异常值,表明对寿命延长的厚度过渡样品可能高估,而对裸眼样品可能低估。揭示了疲劳寿命、应力因子、名义应力和温度之间的相关性,丰富了对LCF的理解,从而增强了焊料行为的预测。设计/方法/方法本文介绍了堆叠ML作为一种估算各种结构件中SAC305焊料LCF寿命的新方法。采用有限元模型和CDM模型建立了疲劳寿命数据库。叠置ML模型对其结构进行了迭代优化,得到了准确的疲劳预测(RMSE 2.41%, r2 = 0.975)。观察到异常值:厚度过渡样品高估,裸眼样品低估。疲劳寿命、应力因素、名义应力和温度之间的相关性增强了预测,加深了对焊料行为的理解。本文的研究结果突出了SMLA在准确估计SAC305焊料跨不同结构部件LCF寿命方面的成功应用。经过迭代训练的堆叠ML模型通过产生精确的疲劳寿命预测(RMSE为2.41%,r2为0.975)证明了其有效性。该研究还确定了与不同结构部件相关的不同异常行为:对具有延长疲劳寿命的厚度过渡试件的高估和对裸眼试件的低估。该研究进一步建立了疲劳寿命、应力集中系数、名义应力和温度之间的相关性,丰富了对焊料行为预测的理解。原创性/价值作者确认本文的原创性。
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引用次数: 0
Effect of PVD-coated wall aperture roughness on the life span of fine-pitch stencil printing pvd涂层壁孔粗糙度对细间距模板印刷寿命的影响
4区 材料科学 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-09-22 DOI: 10.1108/ssmt-05-2023-0025
Mohamad Solehin Mohamed Sunar, Maria Abu Bakar, Atiqah A., Azman Jalar, Muhamed Abdul Fatah Muhamed Mukhtar, Fakhrozi Che Ani
Purpose This paper aims to investigate the effect of physical vapor deposition (PVD)-coated stencil wall aperture on the life span of fine-pitch stencil printing. Design/methodology/approach The fine-pitch stencil used in this work is fabricated by electroform process and subsequently nano-coated using the PVD process. Stencil printing process was then performed to print the solder paste onto the printed circuit board (PCB) pad. The solder paste release was observed by solder paste inspection (SPI) and analyzed qualitatively and quantitatively. The printing cycle of up to 80,000 cycles was used to investigate the life span of stencil printing. Findings The finding shows that the performance of stencil printing in terms of solder printing quality is highly dependent on the surface roughness of the stencil aperture. PVD-coated stencil aperture can prolong the life span of stencil printing with an acceptable performance rate of about 60%. Originality/value Stencil printing is one of the important processes in surface mount technology to apply solder paste on the PCB. The stencil’s life span greatly depends on the type of solder paste, stencil printing cycles involved and stencil conditions such as the shape of the aperture, size and thickness of the stencil. This study will provide valuable insight into the relationship between the coated stencil wall aperture via PVD process on the life span of fine-pitch stencil printing.
目的研究物理气相沉积(PVD)涂层模板壁孔径对细间距模板印刷寿命的影响。设计/方法/方法在这项工作中使用的细间距模板是由电铸工艺制造的,随后使用PVD工艺进行纳米涂层。然后进行模板印刷过程,将锡膏印刷到印刷电路板(PCB)衬垫上。通过锡膏检测(SPI)观察锡膏释放情况,并对其进行定性和定量分析。使用高达80,000次的印刷周期来研究模板印刷的寿命。研究结果表明,从焊锡印刷质量的角度来看,网版印刷的性能高度依赖于网版孔径的表面粗糙度。pvd涂层的网孔可以延长网孔印刷的寿命,其可接受的性能率约为60%。原创性/价值模板印刷是在PCB表面贴装技术中应用锡膏的重要工艺之一。模板的寿命在很大程度上取决于锡膏的类型、所涉及的模板印刷周期和模板条件,如孔径的形状、模板的尺寸和厚度。该研究将为PVD工艺涂层模板壁孔径与细间距模板印刷寿命之间的关系提供有价值的见解。
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引用次数: 0
Effect of Si3N4 nanowires doping on microstructure and properties of Sn58Bi solder for Cu bonding Si3N4纳米线掺杂对Sn58Bi铜键合焊料组织和性能的影响
4区 材料科学 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-09-22 DOI: 10.1108/ssmt-07-2023-0037
Chen Chen, Liang Zhang, Xi Huang, Xiao Lu
Purpose The purpose of this study is to delve into the mechanism of Si3N4 nanowires (NWs) in Sn-based solder, thereby furnishing a theoretical foundation for the expeditious design and practical implementation of innovative lead-free solder materials in the electronic packaging industry. Design/methodology/approach This study investigates the effect of adding Si 3 N 4 NWs to Sn58Bi solder in various mass fractions (0, 0.1, 0.2, 0.4, 0.6 and 0.8 Wt.%) for modifying the solder and joining the Cu substrate. Meanwhile, the melting characteristics and wettability of solder, as well as the microstructure, interfacial intermetallic compound (IMC) and mechanical properties of joint were evaluated. Findings The crystal plane spacing and lattice constant of Sn and Bi phase increase slightly. A minor variation in the Sn58Bi solder melting point was caused, while it does not impact its functionality. An appropriate Si 3 N 4 NWs content (0.2∼0.4 Wt.%) significantly improves its wettability, and modifies the microstructure and interfacial IMC layer. The shear strength increases by up to 10.74% when adding 0.4 Wt.% Si 3 N 4 NWs, and the failure mode observed is brittle fracture mainly. However, excessive Si 3 N 4 will cause aggregation at the junction between the solder matrix and IMC layer, this will be detrimental to the joint. Originality/value The Si 3 N 4 NWs were first used for the modification of lead-free solder materials. The relative properties of composite solder and joints were evaluated from different aspects, and the optimal ratio was obtained.
目的探讨氮化硅纳米线(NWs)在锡基钎料中的作用机理,为电子封装行业创新无铅钎料的快速设计和实际应用提供理论基础。本研究考察了在Sn58Bi焊料中以不同质量分数(0、0.1、0.2、0.4、0.6和0.8 Wt.%)添加Si 3n4nws对焊料的改性和与Cu衬底的连接的影响。同时,对焊料的熔化特性、润湿性、接头的显微组织、界面金属间化合物(IMC)和力学性能进行了评价。发现Sn相和Bi相的晶面间距和晶格常数略有增大。造成Sn58Bi焊料熔点的微小变化,但不影响其功能。适当的si3n4nws含量(0.2 ~ 0.4 Wt.%)可显著改善其润湿性,改变其微观结构和界面IMC层。添加0.4 Wt.% si3n4nws时,抗剪强度可提高10.74%,破坏模式以脆性断裂为主。然而,过量的si3n4会在钎料基体和IMC层之间的连接处引起聚集,这将对接头有害。原创性/价值si3n4nws最初用于无铅焊料的改性。从不同方面评价了复合焊料与焊点的相对性能,得到了最佳配比。
{"title":"Effect of Si<sub>3</sub>N<sub>4</sub> nanowires doping on microstructure and properties of Sn58Bi solder for Cu bonding","authors":"Chen Chen, Liang Zhang, Xi Huang, Xiao Lu","doi":"10.1108/ssmt-07-2023-0037","DOIUrl":"https://doi.org/10.1108/ssmt-07-2023-0037","url":null,"abstract":"Purpose The purpose of this study is to delve into the mechanism of Si3N4 nanowires (NWs) in Sn-based solder, thereby furnishing a theoretical foundation for the expeditious design and practical implementation of innovative lead-free solder materials in the electronic packaging industry. Design/methodology/approach This study investigates the effect of adding Si 3 N 4 NWs to Sn58Bi solder in various mass fractions (0, 0.1, 0.2, 0.4, 0.6 and 0.8 Wt.%) for modifying the solder and joining the Cu substrate. Meanwhile, the melting characteristics and wettability of solder, as well as the microstructure, interfacial intermetallic compound (IMC) and mechanical properties of joint were evaluated. Findings The crystal plane spacing and lattice constant of Sn and Bi phase increase slightly. A minor variation in the Sn58Bi solder melting point was caused, while it does not impact its functionality. An appropriate Si 3 N 4 NWs content (0.2∼0.4 Wt.%) significantly improves its wettability, and modifies the microstructure and interfacial IMC layer. The shear strength increases by up to 10.74% when adding 0.4 Wt.% Si 3 N 4 NWs, and the failure mode observed is brittle fracture mainly. However, excessive Si 3 N 4 will cause aggregation at the junction between the solder matrix and IMC layer, this will be detrimental to the joint. Originality/value The Si 3 N 4 NWs were first used for the modification of lead-free solder materials. The relative properties of composite solder and joints were evaluated from different aspects, and the optimal ratio was obtained.","PeriodicalId":49499,"journal":{"name":"Soldering & Surface Mount Technology","volume":"19 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136010970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Interfacial reactions in the Sn-9.0 wt.% Zn/Cu-Ti alloy (C1990 HP) couple Sn-9.0 wt.% Zn/Cu-Ti合金(C1990 HP)偶联界面反应
4区 材料科学 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-09-19 DOI: 10.1108/ssmt-05-2023-0027
Andromeda Dwi Laksono, Chih-Ming Chen, Yee-Wen Yen
Purpose The purpose of this study was to examine the influence of adding a small amount of Ti to a Cu-based alloy, specifically the commercial Hyper Titanium Copper alloy (C1990 HP), which contains Cu-3.28 wt.% Ti, on its interfacial reaction with Sn-9.0 wt.% Zn (SnZn) solder, using the liquid/solid reaction couple technique. Design/methodology/approach The SnZn/C1990 HP couples were subjected to a reaction temperature of 240–270°C for a duration of 0.5–5 h. The resulting reaction couple was characterized using a scanning electron microscope, energy dispersive spectrometer, electron probe microanalyzer and X-ray diffractometer. Findings It was observed that the scallop-shaped CuZn5 and planar Cu5Zn8 phases were formed in almost all SnZn/C1990 HP couples. With increased reaction duration and temperature, the Cu-rich intermetallic compound (IMC)-Cu5Zn8 phase became a dominant IMC formed at the interface. The total thickness of the IMCs was increased with the increase in the reaction duration and temperature. The IMC growth obeyed the parabolic law, and the IMC growth mechanism was diffusion controlled. The activation energy of the SnZn/C1990 HP couple was 64.71 kJ/mol. Originality/value This article presents an analysis of the IMC thickness in each sample using ImageJ software, followed by kinetic analysis using Origin software at various reaction temperatures of SnZn/C1990 HP in liquid/solid couples. The study also includes detailed reports on the morphology, interface composition and X-ray diffraction analysis, as well as the activation energy. The findings can serve as a valuable reference for electronic packaging companies that utilize C1990 HP substrates.
本研究的目的是利用液固反应偶联技术,研究在cu基合金中加入少量Ti对其与Sn-9.0 wt.% Zn (SnZn)焊料界面反应的影响,特别是在含有Cu-3.28 wt.% Ti的商用超钛铜合金(C1990 HP)中。设计/方法/方法将SnZn/C1990 HP偶体在240 ~ 270℃的反应温度下反应0.5 ~ 5 h,利用扫描电镜、能谱仪、电子探针微量分析仪和x射线衍射仪对反应偶体进行表征。发现几乎所有SnZn/C1990 HP对均形成扇形CuZn5和平面Cu5Zn8相。随着反应时间的延长和反应温度的升高,富cu金属间化合物(IMC)-Cu5Zn8相成为界面形成的主要IMC相。随着反应时间和温度的增加,IMCs的总厚度增加。IMC生长服从抛物线规律,IMC生长机制受扩散控制。SnZn/C1990 HP对的活化能为64.71 kJ/mol。本文利用ImageJ软件分析了每个样品的IMC厚度,然后用Origin软件分析了SnZn/C1990 HP在不同反应温度下的液/固耦合动力学。该研究还包括详细的形貌报告,界面组成和x射线衍射分析,以及活化能。研究结果可为使用C1990 HP基板的电子封装公司提供有价值的参考。
{"title":"Interfacial reactions in the Sn-9.0 wt.% Zn/Cu-Ti alloy (C1990 HP) couple","authors":"Andromeda Dwi Laksono, Chih-Ming Chen, Yee-Wen Yen","doi":"10.1108/ssmt-05-2023-0027","DOIUrl":"https://doi.org/10.1108/ssmt-05-2023-0027","url":null,"abstract":"Purpose The purpose of this study was to examine the influence of adding a small amount of Ti to a Cu-based alloy, specifically the commercial Hyper Titanium Copper alloy (C1990 HP), which contains Cu-3.28 wt.% Ti, on its interfacial reaction with Sn-9.0 wt.% Zn (SnZn) solder, using the liquid/solid reaction couple technique. Design/methodology/approach The SnZn/C1990 HP couples were subjected to a reaction temperature of 240–270°C for a duration of 0.5–5 h. The resulting reaction couple was characterized using a scanning electron microscope, energy dispersive spectrometer, electron probe microanalyzer and X-ray diffractometer. Findings It was observed that the scallop-shaped CuZn5 and planar Cu5Zn8 phases were formed in almost all SnZn/C1990 HP couples. With increased reaction duration and temperature, the Cu-rich intermetallic compound (IMC)-Cu5Zn8 phase became a dominant IMC formed at the interface. The total thickness of the IMCs was increased with the increase in the reaction duration and temperature. The IMC growth obeyed the parabolic law, and the IMC growth mechanism was diffusion controlled. The activation energy of the SnZn/C1990 HP couple was 64.71 kJ/mol. Originality/value This article presents an analysis of the IMC thickness in each sample using ImageJ software, followed by kinetic analysis using Origin software at various reaction temperatures of SnZn/C1990 HP in liquid/solid couples. The study also includes detailed reports on the morphology, interface composition and X-ray diffraction analysis, as well as the activation energy. The findings can serve as a valuable reference for electronic packaging companies that utilize C1990 HP substrates.","PeriodicalId":49499,"journal":{"name":"Soldering & Surface Mount Technology","volume":"48 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135011558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cu-Cu joint with Sn-58Bi/Porous Cu/Sn-58Bi transient liquid phase bonding under formic acid atmosphere 甲酸气氛下Sn-58Bi/多孔Cu/Sn-58Bi瞬态液相键合Cu-Cu接头
4区 材料科学 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-09-13 DOI: 10.1108/ssmt-07-2023-0034
Bifu Xiong, Siliang He, Jinguo Ge, Quantong Li, Chuan Hu, Haidong Yan, Yu-An Shen
Purpose This paper aims to examine the effects of bonding temperature, bonding time, bonding pressure and the presence of a Pt catalyst on the bonding strength of Cu/SB/P-Cu/SB/Cu joints by transient liquid phase bonding (TLPB). Design/methodology/approach TLPB is promising to assemble die-attaching packaging for power devices. In this study, porous Cu (P-Cu) foil with a distinctive porous structure and Sn-58Bi solder (SB) serve as the bonding materials for TLPB under a formic acid atmosphere (FA). The high surface area of P-Cu enables efficient diffusion of the liquid phase of SB, stimulating the wetting, spreading and formation of intermetallic compounds (IMCs). Findings The higher bonding temperature decreased strength due to the coarsening of IMCs. The longer bonding time reduced the bonding strength owing to the coarsened Bi and thickened IMC. Applying optimal bonding pressure improved bonding strength, whereas excessive pressure caused damage. The presence of a Pt catalyst enhanced bonding efficiency and strength by facilitating reduction–oxidation reactions and oxide film removal. Originality/value Overall, this study demonstrates the feasibility of low-temperature TLPB for Cu/SB/P-Cu/SB/Cu joints and provides insights into optimizing bonding strength for the interconnecting materials in the applications of power devices.
目的研究键合温度、键合时间、键合压力和Pt催化剂的存在对瞬态液相键合Cu/SB/P-Cu/SB/Cu接头键合强度的影响。TLPB有望为功率器件组装贴装封装。在甲酸气氛(FA)下,采用具有独特多孔结构的多孔Cu (P-Cu)箔和Sn-58Bi焊料(SB)作为TLPB的键合材料。P-Cu的高表面积使得SB液相的有效扩散,刺激了金属间化合物(IMCs)的润湿、扩散和形成。发现较高的结合温度会导致IMCs的强度降低。由于Bi粗化和IMC增厚,较长的结合时间降低了结合强度。施加最佳的粘接压力可提高粘接强度,而压力过大则会造成损伤。Pt催化剂的存在通过促进还原氧化反应和氧化膜的去除提高了键合效率和强度。总体而言,本研究证明了低温TLPB用于Cu/SB/P-Cu/SB/Cu接头的可行性,并为优化功率器件中互连材料的结合强度提供了见解。
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引用次数: 1
Flow behavior during solder/Cu column friction plunge micro-welding 焊料/铜柱摩擦微焊接流动特性研究
4区 材料科学 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-09-12 DOI: 10.1108/ssmt-07-2023-0039
Zhili Zhao, Mingqiang Zhang, Xi Meng, Zhenkun Li, Jiazhe Li, Luying Qiu, Zeyu Ren
Purpose The author proposed a friction plunge micro-welding (FPMW) method and applied it to column grid array packaging to realize the connection of copper columns without precision molds assisted positioning. The purpose of this paper is to study the flow behavior of the solder undergoing frictional thermo-mechanical action during the FPMW and to determine the source of the solders in the micro-zones with different microstructure characteristics near the solder/Cu column friction interface. Design/methodology/approach Three kinds of Sn58Bi/SAC305 and SAC305/Pb90Sn composite solder samples were designed to study the flow behavior of the solder during FPMW using Bi and Pb as tracer elements. Findings The results show that most of the solders in the position occupied by the copper column was softened and plasticized during the welding process and was extruded to side of the copper column, flowing axially, circumferentially and radially along a trajectory similar to a conical spiral line. Under the drive of the tangential friction force and the radial hold-tight force, the extruded out visco-plastic solders fully mixed with the visco-plastic solders on the sides of the copper column, and bonded with the solders that deformed plastically on the periphery, so that a stir zone and a dynamic recrystallization zone finally evolved. The outside plastically deformed solders evolved into a thermo-mechanical affected zone. Originality/value The flow behavior of the solder during the FPMW was determined, as well as the source of the solders in micro-zones with different microstructure characteristics.
目的提出一种摩擦骤降微焊接(FPMW)方法,并将其应用于柱栅阵列封装中,实现铜柱的连接,无需精密模具辅助定位。本文的目的是研究FPMW过程中受摩擦热机械作用的焊料的流动行为,并确定焊料/铜柱摩擦界面附近具有不同微观结构特征的微区中焊料的来源。设计了3种Sn58Bi/SAC305和SAC305/Pb90Sn复合焊料样品,以Bi和Pb为示踪元素,研究了FPMW过程中焊料的流动行为。结果表明:铜柱所占位置的焊料在焊接过程中大部分被软化塑化,并被挤压到铜柱侧面,沿类似锥形螺旋线的轨迹向轴向、向周向和向径向流动;在切向摩擦力和径向抱紧力的驱动下,挤出的粘塑性焊料与铜柱两侧的粘塑性焊料充分混合,并与外围发生塑性变形的焊料结合,最终形成搅拌区和动态再结晶区。外部塑性变形的焊料演变成热机械影响区。确定了FPMW过程中焊料的流动行为,以及具有不同微观结构特征的微区焊料的来源。
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引用次数: 0
Early wetting and interfacial behavior of Sn-based solder on copper substrates with different roughness 不同粗糙度铜基锡基焊料的早期润湿及界面行为
4区 材料科学 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-09-12 DOI: 10.1108/ssmt-07-2023-0041
Yuzhu Han, Jieshi Chen, Shuye Zhang, Zhishui Yu
Purpose This paper aims to investigate the effect of solder composition and roughness on early wetting behavior and interfacial reaction under atmospheric conditions. Design/methodology/approach High-speed photography is used to observe the early wetting and spreading process of the solder on the substrate in real time. The morphology of intermetallic compounds (IMCs) was observed by scanning electron microscopy, and the composition of IMCs micro bumps was determined by energy dispersive spectroscopy. Findings With a roughness range of 0.320–0.539 µm, the solder is distributed in an elliptical trilinear pattern along the grinding direction. With a roughness range of 0.029–0.031 µm, the solder spreads in the direction of grinding and perpendicular, forming a perfect circle (except in the case of Sn63Pb37 solder). The effect of three types of solder on early wettability is Sn63Pb37 > Sn96.5Ag3Cu0.5 > Sn. The wetting behavior is consistent with the Rn∼t model. The rapid spreading stage (Stage I) is controlled by the interfacial reaction with n1 values between 2.4 and 4. The slow spreading stage (stage II) is controlled by diffusion with n2 values between 4 and 6.7. The size of Cu6Sn5 formed on a rough substrate is greater than that produced on a smooth substrate. Originality/value Investigating the effect of solder composition and roughness on early wettability. This will provide a powerful guide in the field of soft brazing.
目的研究常压条件下焊料成分和粗糙度对早期润湿行为和界面反应的影响。设计/方法/方法高速摄影用于实时观察衬底上焊料的早期润湿和扩散过程。用扫描电镜观察了金属间化合物(IMCs)的形貌,用能量色散光谱测定了IMCs微凸起的组成。在0.320 ~ 0.539µm的粗糙度范围内,焊料沿磨削方向呈椭圆型三线性分布;焊料的粗糙度范围为0.029-0.031µm,沿磨削方向和垂直方向扩散,形成一个完美的圆(Sn63Pb37焊料除外)。三种焊料对早期润湿性的影响分别为:Sn63Pb37 >Sn96.5Ag3Cu0.5祝辞Sn。润湿行为与Rn ~ t模型一致。快速扩散阶段(ⅰ阶段)受界面反应控制,n1值在2.4 ~ 4之间。缓慢扩散阶段(II期)由扩散控制,n2值在4 ~ 6.7之间。在粗糙基体上形成的Cu6Sn5晶粒尺寸大于在光滑基体上形成的Cu6Sn5晶粒尺寸。研究焊料成分和粗糙度对早期润湿性的影响。这将为软钎焊领域提供有力的指导。
{"title":"Early wetting and interfacial behavior of Sn-based solder on copper substrates with different roughness","authors":"Yuzhu Han, Jieshi Chen, Shuye Zhang, Zhishui Yu","doi":"10.1108/ssmt-07-2023-0041","DOIUrl":"https://doi.org/10.1108/ssmt-07-2023-0041","url":null,"abstract":"Purpose This paper aims to investigate the effect of solder composition and roughness on early wetting behavior and interfacial reaction under atmospheric conditions. Design/methodology/approach High-speed photography is used to observe the early wetting and spreading process of the solder on the substrate in real time. The morphology of intermetallic compounds (IMCs) was observed by scanning electron microscopy, and the composition of IMCs micro bumps was determined by energy dispersive spectroscopy. Findings With a roughness range of 0.320–0.539 µm, the solder is distributed in an elliptical trilinear pattern along the grinding direction. With a roughness range of 0.029–0.031 µm, the solder spreads in the direction of grinding and perpendicular, forming a perfect circle (except in the case of Sn63Pb37 solder). The effect of three types of solder on early wettability is Sn63Pb37 &gt; Sn96.5Ag3Cu0.5 &gt; Sn. The wetting behavior is consistent with the Rn∼t model. The rapid spreading stage (Stage I) is controlled by the interfacial reaction with n1 values between 2.4 and 4. The slow spreading stage (stage II) is controlled by diffusion with n2 values between 4 and 6.7. The size of Cu6Sn5 formed on a rough substrate is greater than that produced on a smooth substrate. Originality/value Investigating the effect of solder composition and roughness on early wettability. This will provide a powerful guide in the field of soft brazing.","PeriodicalId":49499,"journal":{"name":"Soldering & Surface Mount Technology","volume":"33 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135824532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal and mechanical analysis of low-temperature and low-pressure silver-based sintered thermal joints 低温低压银基烧结热接头的热力学分析
IF 2 4区 材料科学 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2022-04-28 DOI: 10.1108/ssmt-06-2021-0042
Krzysztof Jakub Stojek, Jan Felba, Damian Nowak, Karol Malecha, Szymon Kaczmarek, Patryk Tomasz Tomasz Andrzejak

Purpose

This paper aims to perform thermal and mechanical characterization for silver-based sintered thermal joints. Layer quality affects thermal and mechanical performance, and it is important to achieve information about how materials and process parameters influence them.

Design/methodology/approach

Thermal investigation of the thermal joints analysis method was focused on determination of thermal resistance, where temperature measurements were performed using infrared camera. They were performed in two modes: steady-state analysis and dynamic analysis. Mechanical analysis based on measurements of mechanical shear force. Additional characterizations based on X-ray image analysis (image thresholding), optical microscope of polished cross-section and scanning electron microscope image analysis were proposed.

Findings

Sample surface modification affects thermal resistance. Silver metallization exhibits the lowest thermal resistance and the highest mechanical strength compared to the pure Si surface. The type of dynamic analysis affects the results of the thermal resistance.

Originality/value

Investigation of the layer quality influence on mechanical and thermal performance provided information about different joint types.

目的对银基烧结热接头进行热力学表征。层的质量影响热性能和机械性能,获得有关材料和工艺参数如何影响它们的信息非常重要。设计/方法学/方法热接头分析方法的热调查主要集中在热阻的确定上,其中使用红外摄像机进行温度测量。它们以两种模式进行:稳态分析和动态分析。基于机械剪切力测量的力学分析。提出了基于x射线图像分析(图像阈值化)、抛光截面光学显微镜和扫描电镜图像分析的附加表征方法。结果:样品表面改性影响热阻。与纯硅表面相比,银金属化表现出最低的热阻和最高的机械强度。动态分析的类型影响热阻的结果。独创性/价值层质量对力学和热工性能影响的研究提供了不同接头类型的信息。
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Soldering & Surface Mount Technology
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