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Effects of continuous straw and equivalent straw-derived biochar application on soil multifunctionality, crop productivity, and greenhouse gas emissions 连续施用秸秆和等量秸秆生物炭对土壤多功能、作物生产力和温室气体排放的影响
IF 6.8 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-12-23 DOI: 10.1016/j.still.2025.107033
Junsheng Lu , Wei Zhang , Xuezhi Liu , Xinyue Zhu , Penghai Su , Tiantian Hu
Incorporating straw or straw-derived biochar is recognized as a promising strategy to enhance soil quality and promote sustainable agricultural development. However, the sustained effects of straw and biochar amendments on crop productivity, greenhouse gas (GHG) emissions and soil multifunctionality remain controversial, largely due to the lack of comparative studies between raw straw and biochar produced from an equivalent amount of straw. To address this issue, a five-year field experiment was conducted with three treatments—CK (no incorporation), SI (continuous raw straw incorporation), and BI (continuous incorporation of biochar derived from an equivalent amount of straw)—to evaluate whether converting raw straw into biochar for soil application provides greater benefits in mitigating GHG emissions and improving soil quality, crop yield, and water productivity. The results showed that both SI and BI significantly improved soil physical (bulk density, porosity, field capacity), chemical (pH, organic carbon, nutrient levels), and biological (microbial biomass carbon and nitrogen) properties, leading to increases in soil ecosystem multifunctionality by 222.8 % and 251.8 %, respectively, compared with CK. Additionally, SI consistently elevated N2O emissions, whereas BI generally reduced N2O emissions relative to CK. Both SI and BI increased CO2 emissions and significantly enhanced crop yield, with SI and BI increasing grain yield by 8.3 % and 25.6 %, and water productivity by 12.2 % and 24.8 %, respectively, in the maize-wheat rotation system compared to CK. As a consequence, SI and BI increased the global warming potential (GWP) by 22.4 % and 6.1 %, respectively, while SI increased greenhouse gas intensity (GHGI) by 12.6 % and BI reduced it by 16.1 %, relative to CK. Notably, continuous incorporation of straw and biochar resulted in a cumulative effect (residual effect + current-season effect) on N2O and CO2 emissions. The residual effect on N2O and CO2 emissions persisted for 3 and 4 years, respectively, under SI, and extended up to 7 years for both gases under BI. Overall, these findings demonstrate that converting straw into biochar for soil incorporation not only enhances soil quality and sustains high crop productivity but also contributes to mitigating GHG emissions. This study highlights the importance of considering long-term dynamics in straw and biochar management and underscores biochar's potential as a sustainable strategy for climate change mitigation.
秸秆或秸秆衍生生物炭被认为是提高土壤质量和促进农业可持续发展的一种有前景的策略。然而,秸秆和生物炭改性对作物生产力、温室气体(GHG)排放和土壤多功能的持续影响仍然存在争议,主要原因是缺乏原料秸秆和等量秸秆生产的生物炭之间的比较研究。为了解决这一问题,研究人员进行了为期五年的田间试验,采用三种处理——ck(不掺入)、SI(连续掺入原料秸秆)和BI(连续掺入等量秸秆提取的生物炭),以评估将原料秸秆转化为生物炭用于土壤是否在减少温室气体排放、提高土壤质量、作物产量和水分生产力方面有更大的好处。结果表明,SI和BI处理均显著改善了土壤的物理(容重、孔隙度、田间容量)、化学(pH、有机碳、养分水平)和生物(微生物生物量碳和氮)特性,土壤生态系统的多功能性分别比CK提高了222.8 %和251.8 %。此外,相对于对照,SI持续增加N2O排放,而BI通常减少N2O排放。与对照相比,玉米-小麦轮作系统中,SI和BI均增加了二氧化碳排放量,显著提高了作物产量,其中SI和BI分别使玉米-小麦轮作系统的粮食产量提高了8.3 %和25.6 %,水分生产力分别提高了12.2 %和24.8 %。结果表明,相对于对照,SI和BI分别使全球变暖潜势(GWP)提高了22.4% %和6.1 %,而SI使温室气体强度(GHGI)提高了12.6% %,BI使GHGI降低了16.1% %。值得注意的是,秸秆和生物炭的持续掺入导致N2O和CO2排放的累积效应(残余效应+当季效应)。在SI下,对N2O和CO2排放的残余影响分别持续了3年和4年,在BI下,这两种气体的残余影响延长了7年。总的来说,这些发现表明,将秸秆转化为生物炭用于土壤掺入不仅可以提高土壤质量,保持较高的作物生产力,而且有助于减少温室气体排放。这项研究强调了在秸秆和生物炭管理中考虑长期动态的重要性,并强调了生物炭作为减缓气候变化的可持续战略的潜力。
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引用次数: 0
Long-term green manure incorporation increases soil carbon sequestration and improves aggregate stability by changing organic carbon components 长期施用绿肥可通过改变有机碳组分增加土壤固碳,提高团聚体稳定性
IF 6.8 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-12-23 DOI: 10.1016/j.still.2025.107024
Yulu Chen , Li Huang , Shaomin Huang , Tengfei Guo , Shuiqing Zhang , Doudou Guo , Xiao Song , Shijie Ding , Muhammad Mehran , Yongqiang Yang , Ke Yue , Sumiao Su , Mingjian Geng , Huimin Zhang
Dissolved organic carbon (DOC), the most labile fraction of soil organic carbon (SOC), plays a vital role in ecosystem functioning and soil productivity. However, the influence of long-term green manure application on DOC composition and its role in soil aggregate formation and carbon stabilization remains unclear. This study investigated changes in DOC composition and their effects on aggregate stability and carbon sequestration in two rice-green manure rotation trials long-5 years in Jingzhou (JZ) and 36 years in Qiyang (QY), China. Treatments included rice-winter fallow (WF), rice-Chinese milk vetch (MV), rice-oilseed rape (RP), and rice-ryegrass (RG). At the JZ test site, 5-year MV incorporation slightly improved aggregate stability, measured by mean weight diameter (MWD) and geometric mean diameter (GMD), but without significant changes. In contrast, at QY, 36-year MV and RG incorporation significantly enhanced both MWD and GMD. Green manure addition increased SOC and DOC contents and enhanced the molecular complexity of DOC, reflected by higher molecular weight, aromaticity, and humification degree. DOC was primarily derived from plant residues and microbial metabolites, with green manure application enhancing microbial contributions. Fluorescence spectroscopy identified three DOC components: bioavailable, humic-like, and protein-like. While DOC composition at JZ remained largely unchanged after 5 years of MV incorporation, 36 years of MV and RG incorporation at QY facilitated the transformation of protein-like into humic-like components. SOC, humic-like DOC, and the humification index (HIX), were the key drivers of aggregate stability, showing direct positive effects on aggregate MWD. Humic-like DOC indirectly promoted SOC accumulation through increased DOC aromaticity and enhanced humification. Our findings highlight the central role of humic-like DOC in enhancing SOC sequestration and soil aggregate stabilization, underscoring the long-term benefits of green manure in sustainable agriculture.
溶解有机碳(DOC)是土壤有机碳(SOC)中最不稳定的部分,在生态系统功能和土壤生产力中起着至关重要的作用。然而,长期施用绿肥对土壤DOC组成的影响及其在土壤团聚体形成和碳稳定中的作用尚不清楚。研究了荆州5年和祁阳36年两个水稻-绿肥轮作试验中DOC组成的变化及其对团聚体稳定性和固碳的影响。处理包括水稻-冬休(WF)、水稻-豇豆(MV)、水稻-油菜(RP)和水稻-黑麦草(RG)。在JZ试验场,通过平均重量直径(MWD)和几何平均直径(GMD)测量,5年MV掺入略微改善了骨料稳定性,但没有显著变化。相比之下,在QY, 36年的MV和RG结合显著提高了MWD和GMD。添加绿肥增加了有机碳和DOC含量,提高了DOC的分子复杂性,表现为分子量、芳香性和腐殖化程度的提高。DOC主要来源于植物残体和微生物代谢产物,绿肥的施用增强了微生物的贡献。荧光光谱鉴定出三种DOC成分:生物可利用性、腐殖质样和蛋白质样。经过5年的MV掺入,JZ处的DOC成分基本保持不变,而QY处36年的MV和RG掺入促进了蛋白样成分向腐殖质样成分的转化。SOC、类腐殖质DOC和腐殖质化指数(HIX)是骨料稳定性的关键驱动因素,对骨料MWD有直接的正向影响。腐殖质样DOC通过增加DOC芳香性和增强腐殖化间接促进有机碳积累。我们的研究结果强调了腐殖质类DOC在增强有机碳固存和土壤团聚体稳定方面的核心作用,强调了绿肥在可持续农业中的长期效益。
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引用次数: 0
Unearthing profits: The impact of ripping depth on cost-benefit dynamics in south-eastern Australia's sandy soils 挖掘利润:撕裂深度对澳大利亚东南部沙质土壤成本效益动态的影响
IF 6.8 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-12-23 DOI: 10.1016/j.still.2025.107032
Muhammad Masood Azeem , Therese McBeath , Jackie Ouzman , Chris Saunders , Rick Llewellyn
Deep ripping, a tillage practice that loosens compacted soil layers below 30 cm, has gained traction in south-eastern Australia's sandy soils due to recognition of its ability to overcome constraints to crop production and advances in machinery that allow the operation to be deeper and more effective. While it has the potential to improve productivity, deep ripping requires significant investment and exhibits variable effectiveness across locations, seasons, and timeframes. Despite its growing adoption, robust economic assessments of different ripping depths have been limited. This study evaluates the economic performance of deep ripping at varying depths using data from 162 treatment-site-years collected between 2014 and 2021 across on-farm trials in the southern Australian cropping zone (250–400 mm annual rainfall). Cost–benefit analysis combined with Monte Carlo simulations was used to estimate probabilistic outcomes under different scenarios and uncertainty levels. Results show that 73 % of cases yielded a positive net present value (NPV) and benefit–cost ratio (BCR), with NPV outcomes ranging from –$406 to $1218 per hectare. A cumulative grain yield gain of approximately 1 tonne per hectare was generally required to achieve a positive NPV. Ripping to depths between 40 and 60 cm—targeting the layers most restrictive to root exploration—produced higher economic returns than shallower ripping (e.g., 30 cm).
深层撕裂是一种松散30 厘米以下的密实土层的耕作方法,由于人们认识到它能够克服作物生产的限制,并且机器的进步使操作更深更有效,因此在澳大利亚东南部的沙质土壤中得到了推广。虽然它有提高生产率的潜力,但深钻需要大量投资,并且在不同的地点、季节和时间范围内表现出不同的效果。尽管越来越多的人采用它,但对不同撕裂深度的可靠经济评估仍然有限。本研究利用2014年至2021年在澳大利亚南部种植区(250-400 毫米年降雨量)的农场试验中收集的162个处理地点年的数据,评估了不同深度的深撕裂的经济性能。采用成本效益分析与蒙特卡罗模拟相结合的方法对不同情景和不确定性水平下的概率结果进行了估计。结果表明,73% %的案例产生了正的净现值(NPV)和效益成本比(BCR), NPV结果从每公顷- 406美元到1218美元不等。一般需要每公顷粮食产量累计增加约1吨,才能实现正的净现值。在40 ~ 60 cm之间的深度进行抽拔——针对最限制根系勘探的地层——比较浅的抽拔(例如30 cm)产生更高的经济回报。
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引用次数: 0
Effect of construction activities-altered soil bulk density on spoil heap rill erosion and morphological characteristics 建设活动改变土壤容重对矸石堆细沟侵蚀及形态特征的影响
IF 6.8 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-12-22 DOI: 10.1016/j.still.2025.107026
Zhihua Zhang , Yuhui Guo , Li Li , Honghu Liu , Wenfeng Ding , Wenjian Tang , Jigen Liu
Spoil heaps, resulting from excavation and backfilling at construction sites, are highly susceptible to soil detachment and transport, leading to rill development, while large-scale infrastructure activities continually alter the soil bulk density. However, the mechanisms by which soil bulk density affects rill erosion on spoil heaps remain poorly understood. This study aims to investigate how soil bulk density governs rill morphology and hydraulic parameters on spoil heaps by conducting multiple flume tests under different flow discharges (3, 5, and 7 L min−1), slope gradients (10, 20, and 30°), and soil bulk densities (1.2, 1.5, and 1.8 g cm−3). Close-range digital photogrammetry was utilized to obtain surface elevation information, which was used for constructing a digital elevation model (DEM). The results showed: 1) soil bulk density significantly affected the soil erosion resistance of spoil heaps: as it increased from 1.2 to 1.8 g cm−3, soil erodibility decreased, while critical shear stress increased from 4.17 to 6.47 Pa and critical stream power from 1.23 to 2.13 N m−1 s−1; 2) soil bulk density significantly suppressed rill development as it increased from 1.2 to 1.8 g cm−3, reducing the mean rill density by 19.4 %, the mean rill width-depth ratio by 48.2 %, and the mean rill inclination angle by 30.5 %; 3) rill depth was the best morphological predictor of sediment yield (P < 0.01), and among the four derived morphological indicators, the degree of rill dissection was the optimal predictor of rill erosion and morphology, followed by the rill inclination angle, the rill width-depth ratio, and the rill density. This study would enhance understanding of the complicated interactions between soil bulk density and morphological development on spoil heaps, and provides strategic erosion control plans for their management.
在建筑工地开挖和回填产生的矸石堆极易受到土壤剥离和运输的影响,从而导致了细沟的发展,而大规模的基础设施活动不断改变着土壤的容重。然而,土壤容重影响废土堆上细沟侵蚀的机制仍然知之甚少。本研究旨在通过在不同流量(3、5和7 L min−1)、坡度(10、20和30°)和土壤容重(1.2、1.5和1.8 g cm−3)下进行多次水槽试验,研究土壤容重如何影响矸石堆的细沟形态和水力参数。利用近景数字摄影测量技术获取地表高程信息,用于构建数字高程模型(DEM)。结果表明:1)土壤容重对矸石堆土壤抗侵蚀能力有显著影响,当容重从1.2增大到1.8 g cm−3时,土壤可蚀性降低,临界剪应力从4.17增大到6.47 Pa,临界水流功率从1.23增大到2.13 N m−1 s−1;2)土壤容重从1.2 ~ 1.8 g cm−3显著抑制了细沟的发育,使平均细沟密度降低19.4% %,平均细沟宽深比降低48.2 %,平均细沟倾角降低30.5% %;3)细沟深度是产沙量的最佳形态预测因子(P <; 0.01),在4个衍生形态指标中,细沟解剖程度是细沟侵蚀和形态的最佳预测因子,其次是细沟倾角、细沟宽深比和细沟密度。该研究将有助于进一步认识土壤容重与矸石堆形态发育之间的复杂相互作用,并为矸石堆治理提供战略规划。
{"title":"Effect of construction activities-altered soil bulk density on spoil heap rill erosion and morphological characteristics","authors":"Zhihua Zhang ,&nbsp;Yuhui Guo ,&nbsp;Li Li ,&nbsp;Honghu Liu ,&nbsp;Wenfeng Ding ,&nbsp;Wenjian Tang ,&nbsp;Jigen Liu","doi":"10.1016/j.still.2025.107026","DOIUrl":"10.1016/j.still.2025.107026","url":null,"abstract":"<div><div>Spoil heaps, resulting from excavation and backfilling at construction sites, are highly susceptible to soil detachment and transport, leading to rill development, while large-scale infrastructure activities continually alter the soil bulk density. However, the mechanisms by which soil bulk density affects rill erosion on spoil heaps remain poorly understood. This study aims to investigate how soil bulk density governs rill morphology and hydraulic parameters on spoil heaps by conducting multiple flume tests under different flow discharges (3, 5, and 7 L min<sup>−1</sup>), slope gradients (10, 20, and 30°), and soil bulk densities (1.2, 1.5, and 1.8 g cm<sup>−3</sup>). Close-range digital photogrammetry was utilized to obtain surface elevation information, which was used for constructing a digital elevation model (DEM). The results showed: 1) soil bulk density significantly affected the soil erosion resistance of spoil heaps: as it increased from 1.2 to 1.8 g cm<sup>−3</sup>, soil erodibility decreased, while critical shear stress increased from 4.17 to 6.47 Pa and critical stream power from 1.23 to 2.13 N m<sup>−1</sup> s<sup>−1</sup>; 2) soil bulk density significantly suppressed rill development as it increased from 1.2 to 1.8 g cm<sup>−3</sup>, reducing the mean rill density by 19.4 %, the mean rill width-depth ratio by 48.2 %, and the mean rill inclination angle by 30.5 %; 3) rill depth was the best morphological predictor of sediment yield (<em>P</em> &lt; 0.01), and among the four derived morphological indicators, the degree of rill dissection was the optimal predictor of rill erosion and morphology, followed by the rill inclination angle, the rill width-depth ratio, and the rill density. This study would enhance understanding of the complicated interactions between soil bulk density and morphological development on spoil heaps, and provides strategic erosion control plans for their management.</div></div>","PeriodicalId":49503,"journal":{"name":"Soil & Tillage Research","volume":"258 ","pages":"Article 107026"},"PeriodicalIF":6.8,"publicationDate":"2025-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145813857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Iron-bound organic-carbon dynamics in a fertilized Agriustoll 铁结合有机碳在施肥后的动态
IF 6.8 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-12-19 DOI: 10.1016/j.still.2025.107027
Wen Zhihao, Zhai Bingnian, Jia Hanzhong, Li Ziyan
Iron-bound organic carbon (Fe-OC) is an important form of soil organic carbon (SOC), and understanding the mechanisms that underlie its formation is crucial for elucidating soil carbon cycling processes. Here, multiple inorganic leaching solutions were used to extract different types of iron minerals from soil under different nitrogen application rates. The results show that fertilization drives the activation of soil iron minerals by regulating root growth and microbial community composition. Iron mineral activation was highest under moderate nitrogen supplementation, but manure application also regulates iron mineral form. EEMs (Excitation-Emission-Matrix Spectra) analysis was also used to determine the molecular structure of Fe-OC, revealing that different types of iron minerals have a significant fractionation effect on organic carbon. To investigate the processes mediating this fractionation, FT-ICR MS (Fourier Transform Ion Cyclotron Resonance Mass Spectrometry) was employed to determine Fe-OC structure. This analysis revealed that fractionation was jointly determined by both iron-mineral and organic-carbon structure. This study reveals the mechanisms by which fertilization of regulates the formation of Fe-OC in temperate soils, improving understanding of the relationship between Fe-OC formation and fractionation.
铁结合有机碳(Fe-OC)是土壤有机碳(SOC)的一种重要形式,了解其形成机制对阐明土壤碳循环过程至关重要。在不同施氮量下,采用多种无机浸出溶液从土壤中提取不同类型的铁矿物。结果表明,施肥通过调节根系生长和微生物群落组成来促进土壤中铁矿物的活化。适量补氮条件下铁矿物活性最高,但施用有机肥对铁矿物形态也有调节作用。利用EEMs(激发-发射-矩阵光谱)分析了Fe-OC的分子结构,发现不同类型的铁矿物对有机碳有显著的分馏作用。为了研究介导这种分离的过程,采用傅里叶变换离子回旋共振质谱法(FT-ICR MS)测定Fe-OC的结构。分析表明,分选是由铁矿物结构和有机碳结构共同决定的。本研究揭示了施肥调节温带土壤Fe-OC形成的机制,提高了对Fe-OC形成与分异关系的认识。
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引用次数: 0
Cover cropping and minimum tillage improved microbial functional resilience to compaction stress in an acidic soil 覆盖和少耕提高了酸性土壤微生物功能对压实胁迫的恢复能力
IF 6.8 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-12-19 DOI: 10.1016/j.still.2025.107031
Apsara Amarasinghe , Chengrong Chen , Lukas Van Zwieten , Michael T. Rose , Mehran Rezaei Rashti
Sustainable agriculture requires maintaining soil health, yet conventional management (CM) practices may not protect soils from stresses such as compaction. This study compared microbial resilience to compaction in two soils collected from sugarcane farms under improved management (IM: minimum tillage, cover cropping and stubble retention) and CM (conventional tillage, no cover crop and stubble retention) practices. Samples were placed in 96-well deep-well plates and compacted using a bespoke device to achieve bulk densities of 0.9 (control), 1.1 (low), and 1.2 g cm⁻³ (moderate). Microbial resistance was assessed 14 days after compaction, and resilience 14 days after stress relief. Under low and moderate compaction, IM soils showed 49.5 % and 45.7 % higher CO₂ emission resistance indices (i.e., the ability of soil to maintain microbial respiration under compaction stress) than CM, indicating greater stability. Microbial biomass carbon and nitrogen were 56.2 % and 47.9 % higher in IM soils under low compaction, compared to CM. Soil microbial metabolic quotient (qCO₂) was similar across compaction levels within each system, but was 19.5 %–36.3 % lower in IM soils than CM at equivalent compaction, indicating lower microbial stress under IM. Fourteen days after stress relief, qCO₂ in moderately compacted CM soil increased by 41.1 % and 25.0 % compared to control and low compaction. In contrast, IM soil under moderate compaction had 40.6 % lower qCO₂ than CM. The CM showed no effects of compaction on hot water extractable organic carbon content, while compaction of IM showed a 13 % decline compared to its control. Hot water extractable total nitrogen did not vary with compaction within the management systems but was 12 %–15 % higher in IM than CM under the same compaction during the resistance phase. Total mineral nitrogen was unaffected by compaction treatments under each system but was 11 %–13 % higher in IM than CM during resistance phase. These findings highlight the potential of improved management practices to sustain soil health and resilience under compaction stress.
可持续农业需要保持土壤健康,但传统的管理方法可能无法保护土壤免受压实等压力的影响。本研究比较了从改良管理(IM:最少耕作、覆盖种植和留茬)和CM(传统耕作、不覆盖种植和留茬)的甘蔗农场收集的两种土壤的微生物对压实的恢复力。样品被放置在96孔深孔板中,并使用定制的设备进行压实,以达到0.9(对照),1.1(低)和1.2 g cm⁻³ (中等)的体积密度。压实后14 d评估微生物耐药性,缓解胁迫后14 d评估恢复力。在低压实和中等压实条件下,IM土壤的CO₂排放阻力指数(即土壤在压实胁迫下维持微生物呼吸的能力)比CM土壤高49.5 %和45.7 %,表现出更强的稳定性。低压实条件下IM土壤微生物量碳和氮分别比CM土壤高56.2% %和47.9 %。土壤微生物代谢商(qCO₂)在不同压实水平下相似,但在相同压实度下,IM土壤比CM土壤低19.5 % -36.3 %,表明IM土壤的微生物胁迫较低。应力解除14 d后,中等压实CM土的qCO₂比对照和低压实分别增加了41.1% %和25.0% %。中等压实条件下IM土壤的qCO₂含量比CM土壤低40.6 %。压实处理对有机碳含量无显著影响,而压实处理的有机碳含量比对照降低13 %。在不同的管理体系中,热水可提取的总氮不随压实度的变化而变化,但在相同压实度下,在抵抗阶段,IM比CM高12 % -15 %。各体系下的总矿物氮不受压实处理的影响,但在抗性阶段,IM比CM高11 % ~ 13 %。这些发现强调了改善管理措施在压实压力下维持土壤健康和恢复力的潜力。
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引用次数: 0
Iron fractionation-directed mechanisms of soil organic carbon: A geochemically-grounded hypothesis and validation 土壤有机碳的铁分馏导向机制:基于地球化学的假设与验证
IF 6.8 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-12-19 DOI: 10.1016/j.still.2025.107029
Fei Xie , Yuanqing Tang , Jin-E. Wei , Yangzheng Liu , Weifang Chen , Chengmei Liao , Changwei Lü
The stabilization of soil organic carbon (SOC) by reactive iron (Fe) minerals is a critical yet poorly quantified process in the global carbon cycle. To elucidate the specific mechanisms of Fe-mediated OC (organic carbon) fractionation, we employed a sequential chemical extraction protocol on < 53 μm soil fractions to isolate distinct Fe phases. This method was rigorously validated using X-ray diffraction (XRD) to correlate the extracted Fe species with specific mineral phases. A key methodological advancement was the developmen of a novel approach to quantify OC co-extracted with each Fe phase, enabling the first direct assessment of MAOC (mineral-associated organic carbon) partitioning to specific mineral hosts. Operationally, citrate-bicarbonate-dithionite (CBD) extraction targeted reactive Fe (FeHR) minerals (e.g., lepidocrocite, goethite, maghemite), while 12 M HCl dissolved poorly reactive Fe (FePR) phases (e.g., ankerite, magnetite, illite, montmorillonite). The residual silicate-bound Fe (FeU), such as grossular, riebeckite, mica, and orthoclase remained in the final residue. Our results revealed a quantitative partitioning of MAOC: FeU-OC dominated (47.9 %), indicative of long-term geological inheritance via physical occlusion within silicate matrices. FePR-OC (36.3 %) was stabilized predominantly by micropore confinement in low-activity minerals and cation bridging, effectively shielding OC from redox-driven dissolution. In contrast, FeHR-OC constituted the smallest fraction (15.8 %) but was the most dynamic, with its concentration strongly correlated with precipitation-induced Fe (oxyhydr)oxide transformation and vegetation diversity, leading to the formation of mineral-organic complexes. Mechanistically, we identified three distinct stabilization pathways: (1) reactive Fe/Al-(hydr)oxides bound OC mainly through chemical complexation or co-precipitation at high-surface-area mineral surfaces; (2) low-activity Fe/Al-(hydr)oxides associated with OC via physical adsorption; and (3) FeU-OC through physical encapsulation within silicate mineral frameworks and lattice-defects. These findings provide a mechanistic and quantitative framework for predicting the persistence of Fe-OC associations under changing environmental conditions.
在全球碳循环中,活性铁(Fe)矿物对土壤有机碳(SOC)的稳定作用是一个关键的但缺乏量化的过程。为了阐明铁介导OC(有机碳)分馏的具体机制,我们采用顺序化学萃取方案在<; 53 μm土壤组分上分离不同的铁相。用x射线衍射(XRD)对该方法进行了严格的验证,以确定提取的铁与特定矿物相的相关性。一个关键的方法进步是开发了一种新的方法来量化与每个Fe相共萃取的OC,从而首次直接评估MAOC(矿物相关有机碳)与特定矿物宿主的分配。在操作上,柠檬酸盐-碳酸氢盐-二硫代矿(CBD)萃取的目标是活性铁(FeHR)矿物(如绢云母、针铁矿、磁铁矿),而12 M HCl溶解的是活性较差的铁(FePR)相(如铁云母、磁铁矿、伊利石、蒙脱石)。残余的硅酸结合铁(FeU),如粗晶铁、辉贝克石、云母和正长石在最终残渣中残留。我们的研究结果揭示了MAOC的定量划分:FeU-OC占主导地位(47.9 %),表明在硅酸盐基质中通过物理遮挡进行了长期的地质继承。FePR-OC(36.3% %)主要通过低活性矿物的微孔限制和阳离子桥接来稳定,有效地屏蔽了氧化还原驱动的OC溶解。FeHR-OC占比最小(15.8 %),但其浓度与降水诱导的铁(氧)氧化物转化和植被多样性密切相关,导致矿物-有机复合物的形成。在机理上,我们确定了三种不同的稳定途径:(1)活性Fe/Al-(水合)氧化物结合OC主要通过化学络合或在高表面积矿物表面共沉淀;(2)低活性Fe/Al-(水合)氧化物通过物理吸附与OC结合;(3) FeU-OC通过硅酸盐矿物框架和晶格缺陷的物理封装。这些发现为预测在变化的环境条件下Fe-OC关联的持久性提供了一个机制和定量框架。
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引用次数: 0
Benchmarking soil potassium extraction methods and establishing critical thresholds for wheat production in Inceptisols 对土壤钾提取方法和建立小麦生产的临界阈值进行基准分析
IF 6.8 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-12-16 DOI: 10.1016/j.still.2025.107017
Shubhadip Dasgupta , Rajat Pandit , Sudip Sengupta , Arup Dey , Kallol Bhattacharyya , Sanjay Srivastava , Owais Bashir , Kiran Lata , Somsubhra Chakraborty , Nicola Senesi , Abdessalam Ouallali , Mohamed Beroho , Shuraik Kader
Accurate assessment of plant-available potassium (K) in soils is crucial for optimizing crop nutrition and enhancing the efficiency of fertilizer use. This study systematically benchmarked ten widely used soil K extractants, Calcium Chloride (CaCl2), Ammonium Acetate (NH4OAc), Ammonium Bicarbonate-Diethylenetriaminepentaacetic Acid (AB-DTPA), Morgan's extractant (Morgan), Calcium acetate lactate extractant (Ca-AL), Kelowna extractant (Kelowna), Olsen extractant (Olsen), Modified Kelowna extractant (Kelowna-2), Nitric Acid (HNO₃), and Sodium Tetraphenylborate (NaTPB) to identify the most effective method for quantifying available K and defining critical thresholds for wheat production in Inceptisols. Pot trials were conducted on soils from twenty Inceptisol series in the Gangetic alluvial plains of Eastern India using five K fertilizer rates that simulates the wide K variability in real field situations. Among the tested methods, NaTPB emerged as the most reliable extractant, showing the strongest correlation (R2 = 0.83, P < 0.05) with Bray’s percent yield (BPY) and a critical K threshold of 1110.3 kg ha−1. CaCl2 also demonstrated high accuracy (R² = 0.82). Multivariate analysis revealed that NaTPB-extractable K was significantly influenced by soil clay content and electrical conductivity, which together explained 76.9 % of its variability. Furthermore, NaTPB effectively captured K from multiple pools, including water-soluble, exchangeable, and non-exchangeable pools, providing a more comprehensive index of plant-available K. A critical K concentration of 0.35 % in wheat grain was identified as the threshold for optimal yield, offering a practical benchmark for site-specific K management. By integrating chemical extraction, crop response modeling, and soil property analysis, this research presents a novel and scientifically robust framework for assessing K fertility. With the successful implementation in Eastern India, the findings have benchmarked broader applicability to Inceptisols in other agroecological regions, providing a scalable diagnostic approach for sustainable nutrient management. This study makes a significant contribution to precision agriculture and global efforts to optimize fertilizer recommendations through the development of improved soil testing methodologies.
准确评估土壤植物速效钾对优化作物营养和提高肥料利用效率至关重要。本研究系统地对十种广泛使用的土壤K萃取剂:氯化钙(CaCl2)、乙酸铵(NH4OAc)、碳酸氢铵-二乙烯三胺五乙酸(AB-DTPA)、摩根萃取剂(Morgan)、醋酸钙乳酸萃取剂(Ca-AL)、基洛纳萃取剂(Kelowna)、奥尔森萃取剂(Olsen)、改性基洛纳萃取剂(Kelowna-2)、硝酸(HNO₃)、和四苯基硼酸钠(NaTPB),以确定最有效的方法来量化有效钾和确定Inceptisols小麦生产的临界阈值。在印度东部恒河冲积平原的20个Inceptisol系列土壤上进行了盆栽试验,使用了5种钾肥率,模拟了实际现场情况下钾的广泛变化。在试验方法中,NaTPB是最可靠的萃取剂,与Bray产率(BPY)的相关性最强(R2 = 0.83, P <; 0.05),临界K阈值为1110.3 kg ha−1。CaCl2也显示出较高的准确性(R²= 0.82)。多变量分析表明,土壤粘土含量和电导率对natpb可提取钾的影响显著,两者共同解释了其变异率的76.9% %。此外,NaTPB有效地捕获了包括水溶性、交换性和非交换性在内的多个钾库,提供了更全面的植物速效钾指数。小麦籽粒中钾的临界浓度为0.35 %,是最佳产量的阈值,为特定地点的钾管理提供了实用基准。通过综合化学提取、作物响应模型和土壤性质分析,本研究提出了一个新的、科学可靠的评估钾肥力的框架。随着在印度东部的成功实施,研究结果为Inceptisols在其他农业生态区域的广泛适用性提供了基准,为可持续营养管理提供了可扩展的诊断方法。本研究通过改进土壤测试方法的发展,为精准农业和优化肥料建议的全球努力做出了重大贡献。
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引用次数: 0
The improved integral suspension pressure method for particle size analysis agrees well with the standard hydrometer method 改进的积分悬浮压力法与标准比重计法具有较好的一致性
IF 6.8 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-12-16 DOI: 10.1016/j.still.2025.107021
Sára Poláchová, Martin Kovář, Lukáš Jačka
Particle size distribution (PSD) is a fundamental property of soil, influencing its physical and chemical properties. Consequently, PSD is commonly used to estimate other critical but harder-to-measure soil properties, such as hydraulic conductivity and soil water retention characteristics. Traditionally, PSD is determined using standard sedimentation methods, such as the pipette or hydrometer method. These conventional methods are, however, currently being replaced by innovative automated techniques, including approaches that measure pressure changes in suspensions. This study compares the standard hydrometer method (HM) with the improved integral suspension pressure method (ISP+), both of which operate on the same physical principle. Measurements were performed on fourteen soil types of varying texture, with identical sample pretreatment. For each type, four PSD analyses were carried out by the HM and four by the ISP+, yielding 112 analyses in total. The two methods showed strong agreement for clay fraction (R2 = 0.987; RMSE = 1.62 %) as well as the sand (R2 = 0.996; RMSE = 1.65 %) and silt fraction (R2 = 0.987; RMSE = 2.11 %). The strong correspondence in clay is particularly important, as it is corrected by oven-drying in ISP+ and represents a direct rather than an indirect estimate as in the case of silt. According to paired t-tests, there is no statistically significant difference between the methods. Although pretreatment and handling are similar to HM, ISP+ provides more detailed PSD data and can support more efficient laboratory workflows than standardized methods, representing a reliable alternative for routine soil texture determination.
土壤粒度分布是土壤的基本性质,影响土壤的理化性质。因此,PSD通常用于估计其他关键但难以测量的土壤特性,如水力导电性和土壤保水特性。传统上,PSD是用标准沉淀方法测定的,如移液器或比重计法。然而,这些传统的方法目前正在被创新的自动化技术所取代,包括测量悬架压力变化的方法。本研究比较了标准比重计法(HM)和改进的积分悬浮压力法(ISP+),两者在相同的物理原理下工作。在相同的样品预处理条件下,对14种不同质地的土壤进行了测量。对于每种类型,HM进行了4次PSD分析,ISP+进行了4次分析,总共进行了112次分析。两种方法对粘土组分(R2 = 0.987, RMSE = 1.62 %)、砂土组分(R2 = 0.996, RMSE = 1.65 %)和粉砂组分(R2 = 0.987, RMSE = 2.11 %)的测定结果吻合较好。粘土中的强对应关系尤其重要,因为它是通过ISP+ 的烘箱干燥来纠正的,并且代表了直接而不是像淤泥那样的间接估计。根据配对t检验,两种方法之间没有统计学上的显著差异。虽然预处理和处理类似于HM, ISP+ 提供更详细的PSD数据,可以支持比标准化方法更有效的实验室工作流程,代表常规土壤质地测定的可靠替代方案。
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引用次数: 0
Rainfall simulations on granite-derived red soils: How jute geotextile mulching regulates erosion dynamics and sediment sorting 花岗岩红壤的降雨模拟:黄麻土工织物覆盖物如何调节侵蚀动力学和沉积物分选
IF 6.8 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-12-16 DOI: 10.1016/j.still.2025.107023
Shimin Ni , Yang Zhou , Chongfa Cai , Junguang Wang , Ziqiang Zou
Water-induced soil erosion severely endangers the sustainability of granite-derived red soil regions in southern China, where jute geotextiles hold promise for erosion control—yet their mechanisms in regulating erosion dynamics and sediment sorting remain poorly understood. This study investigated the erosion mitigation performance and underlying mechanisms of jute geotextile mulching through rainfall simulations, employing a 2 m × 1.2 m soil plot with four soil horizons (eluvium-A, illuvium-B, transitional-BC, parent material-C), two rainfall intensities (60 and 90 mm h−1), two slope gradients (5.56 % and 16.67 %), and three mulching treatments (bare control-CK, low-coverage-6.54 % and high-coverage-13.08 % jute geotextiles). Runoff, soil loss, flow hydrodynamics, and sediment sorting characteristics were analyzed to quantify treatment effects. High-coverage geotextiles could significantly reduce runoff coefficients by an average of 22.75 % and sediment loss by 50.01 % relative to CK. Hydrodynamically, jute geotextile could reduce mean flow velocity by 36.30 % and stream power by 22.75 %, facilitating a laminar-dominated flow regime (Re < 800) and suppressing transitions to supercritical flow. Sediment particle-size distribution (PSD) analysis revealed that clay-silt fractions (< 0.05 mm) were preferentially transported (enrichment ratio > 1), while sand-gravel fractions (> 0.05 mm) were retained in place (enrichment ratio < 1). This selectivity was amplified by high-coverage geotextiles, enabling an increase of clay enrichment ratio by 0.27–0.51 and a reduction of sediment mean weight diameter (MWD) by 0.09–0.17 mm, thereby promoting fine-particle enrichment and delaying sediment coarsening. Additionally, as rainfall progressed, a potential sediment transport mechanism was observed, namely the shift of sediment transport mode from initial suspension-saltation (fine-particle-domination) to later saltation-rolling (coarse-particle-domination). Importantly, this transition was delayed by jute geotextiles via intercepting coarse particles and sustaining fine-particle production. In conclusion, jute geotextiles can effectively mitigate sheet erosion in granite-derived red soils by regulating runoff energy and enhancing sediment sorting. Further research should prioritize optimization of geotextile grid density and synergies between geotextile mulching and local quartz gravels to balance erosion control efficacy, ecological benefits, and economic feasibility.
水致土壤侵蚀严重危及中国南方花岗岩红壤地区的可持续性,黄麻土工布有望控制侵蚀,但其调节侵蚀动力学和沉积物分选的机制尚不清楚。这项研究调查了减缓侵蚀性能和潜在机制的黄麻土工布覆盖通过降雨模拟,采用2 m×1.2  m土壤图有四个视野(eluvium-A、illuvium-B transitional-BC,父material-C),两个降雨强度(60和90年 mm h−1),两个坡渐变(5.56 % 16.67 %),和三个覆盖治疗(裸control-CK、低覆盖13.08 - 6.54 %和高覆盖率 %黄麻土工布)。径流、土壤流失、水流动力学和泥沙分选特性进行了分析,以量化处理效果。与对照相比,高盖度土工布可显著降低径流系数22.75% %,显著降低泥沙损失量50.01 %。在流体动力学上,黄麻土工布可以使平均流速降低36.30 %,水流功率降低22.75 %,促进层流主导的流动状态(Re < 800),并抑制向超临界流动的过渡。沉积物粒径分布(PSD)分析显示,粘土粉砂组分(< 0.05 mm)被优先搬运(富集比>; 1),砂砾组分(> 0.05 mm)被保留(富集比<; 1)。高覆盖度土工布放大了这种选择性,使粘土富集比提高了0.27-0.51,沉积物平均重径(MWD)降低了0.09-0.17 mm,从而促进了细颗粒富集,延缓了沉积物粗化。此外,随着降雨的增加,还发现了一种潜在的输沙机制,即输沙模式从最初的悬浮-跳跃(细颗粒为主)向后期的跳跃-滚动(粗颗粒为主)转变。重要的是,黄麻土工布通过拦截粗颗粒和维持细颗粒的生产,延缓了这种过渡。综上所述,黄麻土工布可以通过调节径流能量和加强沉积物分选来有效缓解花岗岩红壤的片层侵蚀。进一步的研究应优先考虑优化土工布网格密度以及土工布覆盖与当地石英石之间的协同作用,以平衡侵蚀控制效果、生态效益和经济可行性。
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