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Thermal Runaway Characteristics and Gas Analysis of LiNi0.9Co0.05Mn0.05O2 Batteries LiNi0.9Co0.05Mn0.05O2 电池的热失控特性和气体分析
Pub Date : 2024-03-01 DOI: 10.3390/batteries10030084
Chao Shi, Hewu Wang, Hengjie Shen, Juan Wang, Cheng Li, Yalun Li, Wenqiang Xu, Minghai Li
Layered ternary materials with high nickel content are regarded as the most promising cathode materials for high-energy-density lithium-ion batteries, owing to their advantages of high capacity, low cost, and relatively good safety. However, as the nickel content increases in ternary layered materials, their thermal stability noticeably decreases. It is of paramount importance to explore the characteristics of thermal runaway for lithium-ion batteries. In this study, two high-nickel LiNi0.9Co0.05Mn0.05O2 batteries were laterally heated to thermal runaway in a sealed chamber filled with nitrogen to investigate the thermal characteristics and gas compositions. The temperature of the battery tabs was measured, revealing that both batteries were in a critical state of thermal runaway near 120 degrees Celsius. A quantitative analysis method was employed during the eruption process, dividing it into three stages: ultra-fast, fast, and slow; the corresponding durations for the two batteries were 3, 2, 27 s and 3, 3, 26 s. By comparing the changes in chamber pressure, it was observed that both batteries exhibited a similar continuous venting duration of 32 s. However, the pressure fluctuation ranges of the two samples were 99.5 and 68.2 kPa·m·s−1. Compared to the other sample, the 211 Ah sample exhibited larger chamber pressure fluctuations and reached higher peak pressures, indicating a higher risk of explosion. In the experimental phenomenon captured by a high-speed camera, it took only 1 s for the sample to transition from the opening of the safety valve to filling the experimental chamber with smoke. The battery with higher energy density exhibited more intense eruption during thermal runaway, resulting in more severe mass loss. The mass loss of the two samples is 73% and 64.87%. The electrolyte also reacted more completely, resulting in a reduced number of measured exhaust components. The main components of gaseous ejections are CO, CO2, H2, C2H4, and CH4. For the 211 Ah battery, the vented gases were mainly composed of CO (41.3%), CO2 (24.8%), H2 (21%), C2H4 (7.4%) and CH4 (3.9%), while those for the other 256 Ah battery were mainly CO (30.6%), CO2 (28.5%), H2 (21.7%), C2H4 (12.4%) and CH4 (5.8%). Comparatively, the higher-capacity battery produced more gases. The gas volumes, converted to standard conditions (0 °C, 101 kPa) and normalized, resulted in 1.985 L/Ah and 2.182 L/Ah, respectively. The results provide valuable guidance for the protection of large-capacity, high-energy-density battery systems. The quantitative analysis of the eruption process has provided assistance to fire alarm systems and firefighting strategies.
高镍含量的三元层状材料具有高容量、低成本和相对较好的安全性等优点,被认为是最有前途的高能量密度锂离子电池正极材料。然而,随着三元层状材料中镍含量的增加,其热稳定性明显下降。因此,探索锂离子电池的热失控特性至关重要。本研究将两块高镍锂离子电池(LiNi0.9Co0.05Mn0.05O2)在充满氮气的密封室内横向加热至热失控,以研究其热特性和气体成分。对电池片的温度进行了测量,结果表明两种电池都处于接近 120 摄氏度的热失控临界状态。在喷发过程中采用了定量分析方法,将其分为超快、快和慢三个阶段;两个电池的相应持续时间分别为 3、2、27 秒和 3、3、26 秒。与另一个样品相比,211 Ah 样品的腔室压力波动更大,峰值压力更高,表明爆炸风险更高。在高速摄像机捕捉到的实验现象中,样品从打开安全阀到烟雾充满实验箱只用了 1 秒钟。能量密度较高的电池在热失控过程中表现出更强烈的爆发,导致更严重的质量损失。两个样品的质量损失分别为 73% 和 64.87%。电解液的反应也更完全,导致测量到的废气成分数量减少。气体喷出物的主要成分是 CO、CO2、H2、C2H4 和 CH4。容量为 211 Ah 的电池排出的气体主要包括 CO(41.3%)、CO2(24.8%)、H2(21%)、C2H4(7.4%)和 CH4(3.9%),而容量为 256 Ah 的电池排出的气体主要包括 CO(30.6%)、CO2(28.5%)、H2(21.7%)、C2H4(12.4%)和 CH4(5.8%)。相比之下,容量更大的电池产生的气体更多。将气体体积转换为标准条件(0 °C、101 kPa)并归一化后,结果分别为 1.985 L/Ah 和 2.182 L/Ah。这些结果为保护大容量、高能量密度电池系统提供了宝贵的指导。对爆发过程的定量分析为火灾报警系统和消防策略提供了帮助。
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引用次数: 0
Research on Inconsistency Evaluation of Retired Battery Systems in Real-World Vehicles 真实世界车辆中退役电池系统不一致性评估研究
Pub Date : 2024-03-01 DOI: 10.3390/batteries10030082
Jiegang Wang, Kerui Li, Chi Zhang, Zhenpo Wang, Yangjie Zhou, Peng Liu
Inconsistency is a key factor triggering safety problems in battery packs. The inconsistency evaluation of retired batteries is of great significance to ensure the safe and stable operation of batteries during subsequent gradual use. This paper summaries the commonly used diagnostic methods for battery inconsistency assessment. The local outlier factor (LOF) algorithm and the improved Shannon entropy (ImEn) algorithm are selected for validation based on the individual voltage data from real-world vehicles. Then, a comprehensive inconsistency evaluation strategy for retired batteries with many levels and indicators is established based on the three parameters of LOF, ImEn, and cell voltage range. Finally, the evaluation strategy is validated using two real-world vehicle samples of retired batteries. The results show that the proposed method can achieve the inconsistency evaluation of retired batteries quickly and effectively.
不一致性是引发电池组安全问题的关键因素。对报废电池进行不一致性评估,对于确保电池在后续逐步使用过程中的安全稳定运行具有重要意义。本文总结了电池不一致性评估的常用诊断方法。根据实际车辆的单体电压数据,选择局部离群因子(LOF)算法和改进香农熵(ImEn)算法进行验证。然后,根据 LOF、ImEn 和电池电压范围这三个参数,为具有多个级别和指标的退役电池建立了综合不一致性评估策略。最后,使用两个真实世界中的报废电池车辆样本对该评估策略进行了验证。结果表明,所提出的方法可以快速有效地实现报废电池的不一致性评估。
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引用次数: 0
A Low-Cost and High-Efficiency Active Cell-Balancing Circuit for the Reuse of EV Batteries 用于电动汽车电池再利用的低成本、高效率有源电池平衡电路
Pub Date : 2024-02-15 DOI: 10.3390/batteries10020061
M. Dinh, Thi-Tinh Le, Minwon Park
In this paper, a high-efficiency and low-cost active cell-to-cell balancing circuit for the reuse of electric vehicle (EV) batteries is proposed. In the proposed method, a battery string is divided into two legs to transfer the charge from each cell in one leg to that in the other and a bidirectional CLLC resonant converter is used to transfer energy between the selected cells. Thanks to the proposed structure, the number of bidirectional switches and gate drivers can be reduced by half compared to the conventional direct cell-to-cell topologies, thereby achieving lower cost for the system. The CLLC converter is used to transfer the charge, and it is designed to work at resonant frequencies to achieve zero-voltage zero-current switching (ZVZCS) for all the switches and diodes. Consequently, the system’s efficiency can be enhanced, and hence, the fuel economy of the system can also be improved significantly. To verify the performance of the proposed active cell-balancing system, a prototype is implemented for balancing the three EV battery modules that contain twelve lithium-ion batteries from xEV. The maximum efficiency achieved for the charge transfer is 89.4%, and the balancing efficiency is 96.3%.
本文提出了一种用于电动汽车(EV)电池再利用的高效率、低成本有源电池间平衡电路。在所提出的方法中,电池串被分为两条腿,将一条腿上的每个电池的电荷转移到另一条腿上的电池上,并使用双向 CLLC 谐振转换器在所选电池之间传输能量。由于采用了所提出的结构,双向开关和栅极驱动器的数量比传统的直接电池到电池拓扑结构减少了一半,从而降低了系统成本。CLLC 转换器用于传输电荷,其设计工作在谐振频率下,以实现所有开关和二极管的零电压零电流开关(ZVZCS)。因此,系统的效率可以得到提高,从而显著改善系统的燃油经济性。为了验证所提出的主动式电池平衡系统的性能,实施了一个原型,用于平衡三个电动汽车电池模块,其中包含 xEV 的十二个锂离子电池。电荷转移的最高效率为 89.4%,平衡效率为 96.3%。
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引用次数: 0
Charge Scheduling of Electric Vehicle Fleets: Maximizing Battery Remaining Useful Life Using Machine Learning Models 电动汽车车队的充电调度:利用机器学习模型最大化电池剩余使用寿命
Pub Date : 2024-02-15 DOI: 10.3390/batteries10020060
David Geerts, R. Medina, W. V. van Sark, Steven Wilkins
Reducing greenhouse emissions can be done via the electrification of the transport industry. However, there are challenges related to the electrification such as the lifetime of vehicle batteries as well as limitations on the charging possibilities. To cope with some of these challenges, a charge scheduling method for fleets of electric vehicles is presented. Such a method assigns the charging moments (i.e., schedules) of fleets that have more vehicles than chargers. While doing the assignation, the method also maximizes the total Remaining Useful Life (RUL) of all the vehicle batteries. The method consists of two optimization algorithms. The first optimization algorithm determines charging profiles (i.e., charging current vs time) for individual vehicles. The second algorithm finds the charging schedule (i.e. the order in which vehicles are connected to a charger) that maximizes the RUL in the batteries of the entire fleet. To reduce the computational effort of predicting the battery RUL, the method uses a Machine Learning (ML) model. Such a model predicts the RUL of an individual battery while taking into account common stress factors and fabrication-related differences per battery. Simulation results show that charging a single vehicle as late as possible maximizes the RUL of that single vehicle, due to the lower battery degradation. Simulations also show that the ML model accurately predicts the RUL, while taking into account fabrication-related variability in the battery. Additionally, it was shown that this method schedules the charging moments of a fleet, leading to an increased total RUL of all the batteries in the vehicle fleet.
减少温室气体排放可以通过运输业电气化来实现。然而,电气化也面临着一些挑战,例如车辆电池的使用寿命以及充电可能性的限制。为了应对其中的一些挑战,本文提出了一种电动汽车车队充电调度方法。这种方法可以为车辆数量多于充电器数量的车队分配充电时间(即时间表)。在进行分配的同时,该方法还能最大限度地延长所有车辆电池的总剩余使用寿命(RUL)。该方法由两种优化算法组成。第一种优化算法确定每辆车的充电曲线(即充电电流与时间)。第二种算法确定充电时间表(即车辆连接到充电器的顺序),使整个车队电池的 RUL 达到最大值。为了减少预测电池 RUL 的计算量,该方法使用了机器学习 (ML) 模型。该模型可预测单个电池的有效使用时间,同时考虑到常见的应力因素和每个电池在制造方面的差异。仿真结果表明,由于电池退化程度较低,尽可能晚地为单个车辆充电可使该单个车辆的 RUL 达到最大值。仿真结果还表明,ML 模型能准确预测 RUL,同时考虑到电池制造相关的差异。此外,研究还表明,这种方法可以安排车队的充电时间,从而提高车队所有电池的总有效使用时间。
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引用次数: 0
A Low-Cost and High-Efficiency Active Cell-Balancing Circuit for the Reuse of EV Batteries 用于电动汽车电池再利用的低成本、高效率有源电池平衡电路
Pub Date : 2024-02-15 DOI: 10.3390/batteries10020061
M. Dinh, Thi-Tinh Le, Minwon Park
In this paper, a high-efficiency and low-cost active cell-to-cell balancing circuit for the reuse of electric vehicle (EV) batteries is proposed. In the proposed method, a battery string is divided into two legs to transfer the charge from each cell in one leg to that in the other and a bidirectional CLLC resonant converter is used to transfer energy between the selected cells. Thanks to the proposed structure, the number of bidirectional switches and gate drivers can be reduced by half compared to the conventional direct cell-to-cell topologies, thereby achieving lower cost for the system. The CLLC converter is used to transfer the charge, and it is designed to work at resonant frequencies to achieve zero-voltage zero-current switching (ZVZCS) for all the switches and diodes. Consequently, the system’s efficiency can be enhanced, and hence, the fuel economy of the system can also be improved significantly. To verify the performance of the proposed active cell-balancing system, a prototype is implemented for balancing the three EV battery modules that contain twelve lithium-ion batteries from xEV. The maximum efficiency achieved for the charge transfer is 89.4%, and the balancing efficiency is 96.3%.
本文提出了一种用于电动汽车(EV)电池再利用的高效率、低成本有源电池间平衡电路。在所提出的方法中,电池串被分为两条腿,将一条腿上的每个电池的电荷转移到另一条腿上的电池上,并使用双向 CLLC 谐振转换器在所选电池之间传输能量。由于采用了所提出的结构,双向开关和栅极驱动器的数量比传统的直接电池到电池拓扑结构减少了一半,从而降低了系统成本。CLLC 转换器用于传输电荷,其设计工作在谐振频率下,以实现所有开关和二极管的零电压零电流开关(ZVZCS)。因此,系统的效率可以得到提高,从而显著改善系统的燃油经济性。为了验证所提出的主动式电池平衡系统的性能,实施了一个原型,用于平衡三个电动汽车电池模块,其中包含 xEV 的十二个锂离子电池。电荷转移的最高效率为 89.4%,平衡效率为 96.3%。
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引用次数: 0
Adaptive Integrated Thermal Management System for a Stable Driving Environment in Battery Electric Vehicles 为电池电动汽车提供稳定驾驶环境的自适应集成热管理系统
Pub Date : 2024-02-15 DOI: 10.3390/batteries10020059
Jaehyun Bae, D. Hyun, Jaeyoung Han
With an increase in global warming, battery electric vehicles (BEVs), which are environmentally friendly, have been rapidly commercialized to replace conventional vehicles with internal combustion engines. Unlike traditional internal combustion engine vehicles, the powertrain system of BEVs operates with high efficiency, resulting in lower heat generation. This poses a challenge for cabin heating under low-temperature conditions. Conversely, under high-temperature conditions, the operating temperature of a high-voltage battery (HVB) is lower than the ambient air temperature, which makes cooling through ambient air challenging. To overcome these challenges, in this study, we proposed an integrated thermal management system (ITMS) based on a heat pump system capable of stable thermal management under diverse climatic conditions. Furthermore, to assess the ability of the proposed ITMS to perform thermal management under various climatic conditions, we integrated a detailed powertrain system model incorporating BEV specifications and the proposed ITMS model based on the heat pump system. The ITMS model was evaluated under high-load-driving conditions, specifically the HWFET scenario, demonstrating its capability to perform stable thermal management not only under high-temperature conditions, such as at 36 °C, but also under low-temperature conditions, such as at −10 °C, through the designated thermal management modes.
随着全球变暖的加剧,环保型电池电动汽车(BEV)已迅速商业化,以取代传统的内燃机汽车。与传统内燃机汽车不同,BEV 的动力总成系统运行效率高,发热量低。这给低温条件下的车厢加热带来了挑战。相反,在高温条件下,高压电池(HVB)的工作温度低于环境空气温度,这给通过环境空气降温带来了挑战。为了克服这些挑战,我们在本研究中提出了一种基于热泵系统的集成热管理系统(ITMS),该系统能够在不同气候条件下实现稳定的热管理。此外,为了评估所提出的 ITMS 在各种气候条件下执行热管理的能力,我们整合了一个包含 BEV 规格的详细动力总成系统模型和所提出的基于热泵系统的 ITMS 模型。在高负荷驱动条件下,特别是在 HWFET 情景下,对 ITMS 模型进行了评估,结果表明该模型不仅能够在 36 °C 等高温条件下执行稳定的热管理,而且还能在 -10 °C 等低温条件下通过指定的热管理模式执行稳定的热管理。
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引用次数: 0
Intrinsic Safety Risk Control and Early Warning Methods for Lithium-Ion Power Batteries 锂离子动力电池的本质安全风险控制和预警方法
Pub Date : 2024-02-15 DOI: 10.3390/batteries10020062
Yi Cui, Xueling Shen, Hang Zhang, Yanping Yin, Zhanglong Yu, Dong Shi, Yanyan Fang, Ran Xu
Since 2014, the electric vehicle industry in China has flourished and has been accompanied by rapid growth in the power battery industry led by lithium-ion battery (LIB) development. Due to a variety of factors, LIBs have been widely used, but user abuse and battery quality issues have led to explosion accidents that have caused loss of life and property. Current strategies to address battery safety concerns mainly involve enhancing the intrinsic safety of batteries and strengthening safety controls with approaches such as early warning systems to alert users before thermal runaway and ensure user safety. In this paper, we discuss the current research status and trends in two areas, intrinsic battery safety risk control and early warning methods, with the goal of promoting the development of safe LIB solutions in new energy applications.
2014 年以来,中国电动汽车产业蓬勃发展,以锂离子电池(LIB)发展为龙头的动力电池产业也随之快速增长。由于多种因素,锂离子电池得到了广泛应用,但用户滥用和电池质量问题导致的爆炸事故也造成了生命和财产损失。目前解决电池安全问题的策略主要涉及提高电池的内在安全性,并通过预警系统等方法加强安全控制,在热失控前提醒用户,确保用户安全。本文探讨了电池本质安全风险控制和预警方法两个领域的研究现状和趋势,旨在推动新能源应用领域安全电池组解决方案的发展。
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引用次数: 0
Intrinsic Safety Risk Control and Early Warning Methods for Lithium-Ion Power Batteries 锂离子动力电池的本质安全风险控制和预警方法
Pub Date : 2024-02-15 DOI: 10.3390/batteries10020062
Yi Cui, Xueling Shen, Hang Zhang, Yanping Yin, Zhanglong Yu, Dong Shi, Yanyan Fang, Ran Xu
Since 2014, the electric vehicle industry in China has flourished and has been accompanied by rapid growth in the power battery industry led by lithium-ion battery (LIB) development. Due to a variety of factors, LIBs have been widely used, but user abuse and battery quality issues have led to explosion accidents that have caused loss of life and property. Current strategies to address battery safety concerns mainly involve enhancing the intrinsic safety of batteries and strengthening safety controls with approaches such as early warning systems to alert users before thermal runaway and ensure user safety. In this paper, we discuss the current research status and trends in two areas, intrinsic battery safety risk control and early warning methods, with the goal of promoting the development of safe LIB solutions in new energy applications.
2014 年以来,中国电动汽车产业蓬勃发展,以锂离子电池(LIB)发展为龙头的动力电池产业也随之快速增长。由于多种因素,锂离子电池得到了广泛应用,但用户滥用和电池质量问题导致的爆炸事故也造成了生命和财产损失。目前解决电池安全问题的策略主要涉及提高电池的内在安全性,并通过预警系统等方法加强安全控制,在热失控前提醒用户,确保用户安全。本文探讨了电池本质安全风险控制和预警方法两个领域的研究现状和趋势,旨在推动新能源应用领域安全电池组解决方案的发展。
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引用次数: 0
Charge Scheduling of Electric Vehicle Fleets: Maximizing Battery Remaining Useful Life Using Machine Learning Models 电动汽车车队的充电调度:利用机器学习模型最大化电池剩余使用寿命
Pub Date : 2024-02-15 DOI: 10.3390/batteries10020060
David Geerts, R. Medina, W. V. van Sark, Steven Wilkins
Reducing greenhouse emissions can be done via the electrification of the transport industry. However, there are challenges related to the electrification such as the lifetime of vehicle batteries as well as limitations on the charging possibilities. To cope with some of these challenges, a charge scheduling method for fleets of electric vehicles is presented. Such a method assigns the charging moments (i.e., schedules) of fleets that have more vehicles than chargers. While doing the assignation, the method also maximizes the total Remaining Useful Life (RUL) of all the vehicle batteries. The method consists of two optimization algorithms. The first optimization algorithm determines charging profiles (i.e., charging current vs time) for individual vehicles. The second algorithm finds the charging schedule (i.e. the order in which vehicles are connected to a charger) that maximizes the RUL in the batteries of the entire fleet. To reduce the computational effort of predicting the battery RUL, the method uses a Machine Learning (ML) model. Such a model predicts the RUL of an individual battery while taking into account common stress factors and fabrication-related differences per battery. Simulation results show that charging a single vehicle as late as possible maximizes the RUL of that single vehicle, due to the lower battery degradation. Simulations also show that the ML model accurately predicts the RUL, while taking into account fabrication-related variability in the battery. Additionally, it was shown that this method schedules the charging moments of a fleet, leading to an increased total RUL of all the batteries in the vehicle fleet.
减少温室气体排放可以通过运输业电气化来实现。然而,电气化也面临着一些挑战,例如车辆电池的使用寿命以及充电可能性的限制。为了应对其中的一些挑战,本文提出了一种电动汽车车队充电调度方法。这种方法可以为车辆数量多于充电器数量的车队分配充电时间(即时间表)。在进行分配的同时,该方法还能最大限度地延长所有车辆电池的总剩余使用寿命(RUL)。该方法由两种优化算法组成。第一种优化算法确定每辆车的充电曲线(即充电电流与时间)。第二种算法确定充电时间表(即车辆连接到充电器的顺序),使整个车队电池的 RUL 达到最大值。为了减少预测电池 RUL 的计算量,该方法使用了机器学习 (ML) 模型。该模型可预测单个电池的有效使用时间,同时考虑到常见的应力因素和每个电池在制造方面的差异。仿真结果表明,由于电池退化程度较低,尽可能晚地为单个车辆充电可使该单个车辆的 RUL 达到最大值。仿真结果还表明,ML 模型能准确预测 RUL,同时考虑到电池制造相关的差异。此外,研究还表明,这种方法可以安排车队的充电时间,从而提高车队所有电池的总有效使用时间。
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引用次数: 0
Adaptive Integrated Thermal Management System for a Stable Driving Environment in Battery Electric Vehicles 为电池电动汽车提供稳定驾驶环境的自适应集成热管理系统
Pub Date : 2024-02-15 DOI: 10.3390/batteries10020059
Jaehyun Bae, D. Hyun, Jaeyoung Han
With an increase in global warming, battery electric vehicles (BEVs), which are environmentally friendly, have been rapidly commercialized to replace conventional vehicles with internal combustion engines. Unlike traditional internal combustion engine vehicles, the powertrain system of BEVs operates with high efficiency, resulting in lower heat generation. This poses a challenge for cabin heating under low-temperature conditions. Conversely, under high-temperature conditions, the operating temperature of a high-voltage battery (HVB) is lower than the ambient air temperature, which makes cooling through ambient air challenging. To overcome these challenges, in this study, we proposed an integrated thermal management system (ITMS) based on a heat pump system capable of stable thermal management under diverse climatic conditions. Furthermore, to assess the ability of the proposed ITMS to perform thermal management under various climatic conditions, we integrated a detailed powertrain system model incorporating BEV specifications and the proposed ITMS model based on the heat pump system. The ITMS model was evaluated under high-load-driving conditions, specifically the HWFET scenario, demonstrating its capability to perform stable thermal management not only under high-temperature conditions, such as at 36 °C, but also under low-temperature conditions, such as at −10 °C, through the designated thermal management modes.
随着全球变暖的加剧,环保型电池电动汽车(BEV)已迅速商业化,以取代传统的内燃机汽车。与传统内燃机汽车不同,BEV 的动力总成系统运行效率高,发热量低。这给低温条件下的车厢加热带来了挑战。相反,在高温条件下,高压电池(HVB)的工作温度低于环境空气温度,这给通过环境空气降温带来了挑战。为了克服这些挑战,我们在本研究中提出了一种基于热泵系统的集成热管理系统(ITMS),该系统能够在不同气候条件下实现稳定的热管理。此外,为了评估所提出的 ITMS 在各种气候条件下执行热管理的能力,我们整合了一个包含 BEV 规格的详细动力总成系统模型和所提出的基于热泵系统的 ITMS 模型。在高负荷驱动条件下,特别是在 HWFET 情景下,对 ITMS 模型进行了评估,结果表明该模型不仅能够在 36 °C 等高温条件下执行稳定的热管理,而且还能在 -10 °C 等低温条件下通过指定的热管理模式执行稳定的热管理。
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引用次数: 0
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Batteries
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