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Edible Gelatin and Cosmetic Activated Carbon Powder as Biodegradable and Replaceable Materials in the Production of Supercapacitors 将食用明胶和化妆品活性碳粉作为生产超级电容器的可生物降解和可替代材料
Pub Date : 2024-07-01 DOI: 10.3390/batteries10070237
Rodica Negroiu, C. Marghescu, I. Bacis, M. Burcea, Andrei Drumea, L. Dinca, Ion Razvan Radulescu
Environmental pollution is currently one of the most worrying factors that endangers human health. Therefore, attempts are being made to reduce it by various means. One of the most important sources of pollution in terms of the current RoHS and REACH directives is the pollution caused by the use of chemical products for the production of sources for the storage and generation of electricity. The aim of this article is therefore to develop supercapacitors made of biodegradable materials and to investigate their electrical performance. Among the materials used to make these electrodes, activated carbon was identified as the main material and different combinations of gelatin, calligraphy ink and glycerol were used as the binders. The electrolyte consists of a hydrogel based on gelatin, NaCl 20 wt% solution and glycerol. In the context of this research, the electrolyte, which has the consistency of a gel, fulfills the dual function of the separator in the structure of the manufactured cells. Due to its structure, the electrolyte has good mechanical properties and can easily block the contact between the two electrodes. Most of the materials used for the production of supercapacitor cells are interchangeable materials, which are mainly used in other application fields such as the food or cosmetics industries, but were also successfully used for the investigations carried out in this research. Thus, remarkable results were recorded regarding a specific capacitance between 101.46 F/g and 233.26 F/g and an energy density between 3.52 Wh/kg and 8.09 Wh/kg, with a slightly lower power density between 66.66 W/kg and 85.76 W/kg for the manufactured supercapacitors.
环境污染是目前危害人类健康的最令人担忧的因素之一。因此,人们正试图通过各种手段来减少污染。就目前的 RoHS 和 REACH 指令而言,最重要的污染源之一就是使用化学产品生产用于储存和发电的能源所造成的污染。因此,本文旨在开发由可生物降解材料制成的超级电容器,并研究其电气性能。在用于制造这些电极的材料中,活性炭被确定为主要材料,明胶、书法墨水和甘油的不同组合被用作粘合剂。电解质由基于明胶的水凝胶、20 wt%的氯化钠溶液和甘油组成。在本研究中,电解质具有凝胶的稠度,在制造的电池结构中具有隔膜的双重功能。由于其结构,电解质具有良好的机械性能,可以很容易地阻断两个电极之间的接触。用于生产超级电容器电池的大多数材料都是可互换材料,这些材料主要用于其他应用领域,如食品或化妆品行业,但也成功地用于本研究的调查。因此,所生产的超级电容器的比电容介于 101.46 F/g 和 233.26 F/g 之间,能量密度介于 3.52 Wh/kg 和 8.09 Wh/kg 之间,功率密度稍低,介于 66.66 W/kg 和 85.76 W/kg 之间。
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引用次数: 0
Single-Use Vape Batteries: Investigating Their Potential as Ignition Sources in Waste and Recycling Streams 一次性 Vape 电池:调查其作为废物和回收流中点火源的潜力
Pub Date : 2024-07-01 DOI: 10.3390/batteries10070236
Andrew Gausden, B. Cerik
This study investigates the potential link between the increasing prevalence of single-use vapes (SUVs) and the rising frequency of waste and recycling fires in the UK. Incorrectly discarded Li-ion cells from SUVs can suffer mechanical damage, potentially leading to thermal runaway (TR) depending on the cells’ state of charge (SOC). Industry-standard abuse tests (short-circuit and nail test) and novel impact and crush tests, simulating damage during waste management processes, were conducted on Li-ion cells from two market-leading SUVs. The novel tests created internal short circuits, generating higher temperatures than the short-circuit test required for product safety. The cells in used SUVs had an average SOC ≤ 50% and reached a maximum temperature of 131 °C, below the minimum ignition temperature of common waste materials. The high temperatures were short-lived and had limited heat transfer to adjacent materials. The study concludes that Li-ion cells in used SUVs at ≤50% SOC cannot generate sufficient heat and temperature to ignite common waste and recycling materials. These findings have implications for understanding the fire risk associated with discarded SUVs in waste management facilities.
本研究调查了英国一次性吸管(SUV)的日益普及与废物和回收火灾频率上升之间的潜在联系。从 SUV 中不正确丢弃的锂离子电池可能会受到机械损伤,根据电池的充电状态 (SOC),有可能导致热失控 (TR)。我们对两款市场领先的 SUV 的锂离子电池进行了行业标准的滥用测试(短路和钉子测试)以及新颖的冲击和挤压测试,模拟废物管理过程中的损坏情况。新型测试会造成内部短路,产生比产品安全所需的短路测试更高的温度。使用过的 SUV 中的电池平均 SOC ≤ 50%,最高温度达到 131 °C,低于常见废料的最低点火温度。高温持续时间很短,传导到邻近材料的热量有限。研究得出结论,废旧 SUV 中的锂离子电池在 SOC ≤50% 的情况下无法产生足够的热量和温度来点燃普通废料和回收材料。这些研究结果对了解废物管理设施中废弃 SUV 的火灾风险具有重要意义。
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引用次数: 0
State-of-Charge Estimation of Lithium-Ion Battery Based on Convolutional Neural Network Combined with Unscented Kalman Filter 基于卷积神经网络和无符号卡尔曼滤波器的锂离子电池充电状态估计
Pub Date : 2024-06-04 DOI: 10.3390/batteries10060198
Hongli Ma, Xinyuan Bao, António Lopes, Liping Chen, Guoquan Liu, Min Zhu
Estimation of the state-of-charge (SOC) of lithium-ion batteries (LIBs) is fundamental to assure the normal operation of both the battery and battery-powered equipment. This paper derives a new SOC estimation method (CNN-UKF) that combines a convolutional neural network (CNN) and an unscented Kalman filter (UKF). The measured voltage, current and temperature of the LIB are the input of the CNN. The output of the hidden layer feeds the linear layer, whose output corresponds to an initial network-based SOC estimation. The output of the CNN is then used as the input of a UKF, which, using self-correction, yields high-precision SOC estimation results. This method does not require tuning of network hyperparameters, reducing the dependence of the network on hyperparameter adjustment and improving the efficiency of the network. The experimental results show that this method has higher accuracy and robustness compared to SOC estimation methods based on CNN and other advanced methods found in the literature.
估算锂离子电池(LIB)的充电状态(SOC)是确保电池和电池供电设备正常运行的基础。本文提出了一种新的 SOC 估算方法(CNN-UKF),该方法结合了卷积神经网络(CNN)和无香卡尔曼滤波器(UKF)。LIB 的测量电压、电流和温度是 CNN 的输入。隐藏层的输出为线性层提供输入,线性层的输出对应于基于网络的初始 SOC 估算。然后,CNN 的输出被用作 UKF 的输入,UKF 利用自校正功能获得高精度 SOC 估算结果。这种方法无需调整网络超参数,减少了网络对超参数调整的依赖,提高了网络的效率。实验结果表明,与基于 CNN 的 SOC 估算方法和文献中的其他先进方法相比,该方法具有更高的准确性和鲁棒性。
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引用次数: 0
Research on the Human–Robot Collaborative Disassembly Line Balancing of Spent Lithium Batteries with a Human Factor Load 带有人为因素负载的人机协作锂电池拆卸线平衡研究
Pub Date : 2024-06-03 DOI: 10.3390/batteries10060196
Jie Jiao, Guangsheng Feng, Gang Yuan
The disassembly of spent lithium batteries is a prerequisite for efficient product recycling, the first link in remanufacturing, and its operational form has gradually changed from traditional manual disassembly to robot-assisted human–robot cooperative disassembly. Robots exhibit robust load-bearing capacity and perform stable repetitive tasks, while humans possess subjective experiences and tacit knowledge. It makes the disassembly activity more adaptable and ergonomic. However, existing human–robot collaborative disassembly studies have neglected to account for time-varying human conditions, such as safety, cognitive behavior, workload, and human pose shifts. Firstly, in order to overcome the limitations of existing research, we propose a model for balancing human–robot collaborative disassembly lines that take into consideration the load factor related to human involvement. This entails the development of a multi-objective mathematical model aimed at minimizing both the cycle time of the disassembly line and its associated costs while also aiming to reduce the integrated smoothing exponent. Secondly, we propose a modified multi-objective fruit fly optimization algorithm. The proposed algorithm combines chaos theory and the global cooperation mechanism to improve the performance of the algorithm. We add Gaussian mutation and crowding distance to efficiently solve the discrete optimization problem. Finally, we demonstrate the effectiveness and sensitivity of the improved multi-objective fruit fly optimization algorithm by solving and analyzing an example of Mercedes battery pack disassembly.
废旧锂电池的拆解是实现产品高效回收的前提,是再制造的第一个环节,其操作形式已从传统的人工拆解逐渐转变为机器人辅助的人机协同拆解。机器人具有强大的承载能力,能稳定地完成重复性任务,而人类则拥有主观经验和隐性知识。这使得拆卸活动更具适应性和人性化。然而,现有的人机协作拆卸研究忽略了随时间变化的人类条件,如安全、认知行为、工作量和人类姿势变化。首先,为了克服现有研究的局限性,我们提出了一种平衡人机协作拆卸线的模型,该模型考虑了与人的参与相关的负载因素。这就需要开发一个多目标数学模型,旨在最大限度地减少拆卸线的周期时间及其相关成本,同时降低综合平滑指数。其次,我们提出了一种改进的多目标果蝇优化算法。该算法结合了混沌理论和全局合作机制,以提高算法的性能。我们添加了高斯突变和拥挤距离,以高效解决离散优化问题。最后,我们通过求解和分析梅赛德斯电池组拆卸的实例,证明了改进的多目标果蝇优化算法的有效性和灵敏度。
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引用次数: 0
Transition Metal-Based Polyoxometalates for Oxygen Electrode Bifunctional Electrocatalysis 用于氧电极双功能电催化的过渡金属基多氧金属盐
Pub Date : 2024-06-03 DOI: 10.3390/batteries10060197
Jadranka Milikić, Filipe Gusmão, S. Knežević, N. Gavrilov, Anup Paul, Diogo M. F. Santos, Biljana Šljukić
Polyoxometalates (POMs) with transition metals (Co, Cu, Fe, Mn, Ni) of Keggin structure and lamellar-stacked multi-layer morphology were synthesized. They were subsequently explored as bifunctional electrocatalysts for oxygen electrodes, i.e., oxygen reduction (ORR) and evolution (OER) reaction, for aqueous rechargeable metal-air batteries in alkaline media. The lowest Tafel slope (85 mV dec−1) value and the highest OER current density of 93.8 mA cm−2 were obtained for the Fe-POM electrocatalyst. Similar OER electrochemical catalytic activity was noticed for the Co-POM electrocatalyst. This behavior was confirmed by electrochemical impedance spectroscopy, where Fe-POM gave the lowest charge transfer resistance of 3.35 Ω, followed by Co-POM with Rct of 15.04 Ω, during the OER. Additionally, Tafel slope values of 85 and 109 mV dec−1 were calculated for Fe-POM and Co-POM, respectively, during the ORR. The ORR at Fe-POM proceeded by mixed two- and four-electron pathways, while ORR at Co-POM proceeded exclusively by the four-electron pathway. Finally, capacitance studies were conducted on the synthesized POMs.
研究人员合成了具有凯金结构和层状堆叠多层形态的过渡金属(钴、铜、铁、锰、镍)聚氧化金属盐(POMs)。随后,研究人员将它们作为氧气电极的双功能电催化剂进行了探索,即在碱性介质中用于水性可充电金属空气电池的氧气还原(ORR)和进化(OER)反应。Fe-POM 电催化剂的塔菲尔斜率(85 mV dec-1)值最低,OER 电流密度最高,为 93.8 mA cm-2。Co-POM 电催化剂也具有类似的 OER 电化学催化活性。电化学阻抗谱证实了这一行为,在 OER 过程中,Fe-POM 的电荷转移电阻最低,为 3.35 Ω,其次是 Co-POM,Rct 为 15.04 Ω。此外,在 ORR 期间,Fe-POM 和 Co-POM 的塔菲尔斜率值分别为 85 和 109 mV dec-1。Fe-POM 的 ORR 是通过双电子和四电子混合途径进行的,而 Co-POM 的 ORR 完全是通过四电子途径进行的。最后,对合成的 POM 进行了电容研究。
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引用次数: 0
High-Performance Supercapacitors Based on Graphene/Activated Carbon Hybrid Electrodes Prepared via Dry Processing 基于干法制备的石墨烯/活性碳混合电极的高性能超级电容器
Pub Date : 2024-06-03 DOI: 10.3390/batteries10060195
Shengjun Chen, Wenrui Wang, Xinyue Zhang, Xiaofeng Wang
Graphene has a high specific surface area and high electrical conductivity, and its addition to activated carbon electrodes should theoretically significantly improve the energy storage performance of supercapacitors. Unfortunately, such an ideal outcome is seldom verified in practical commercial supercapacitor design and production. In this paper, the oxygen-containing functional groups in graphene/activated carbon hybrids, which are prone to induce side reactions, are removed in the material synthesis stage by a special process design, and electrodes with high densities and low internal resistances are prepared by a dry process. On this basis, a carbon-coated aluminum foil collector with a full tab structure is designed and assembled with graphene/activated carbon hybrid electrodes to form a commercial supercapacitor in cylindrical configuration. The experimental tests confirmed that such supercapacitors have high capacity density, power density, low internal resistance (about 0.06 mΩ), good high-current charging/discharging characteristics, and a long lifetime, with more than 80% capacity retention after 10 W cycles.
石墨烯具有高比表面积和高导电性,理论上将其添加到活性炭电极中应能显著提高超级电容器的储能性能。遗憾的是,这种理想结果在实际商业超级电容器的设计和生产中很少得到验证。本文通过特殊的工艺设计,在材料合成阶段去除石墨烯/活性碳杂化物中容易诱发副反应的含氧官能团,并通过干法工艺制备出高密度、低内阻的电极。在此基础上,设计了具有全片结构的碳涂层铝箔集电体,并将其与石墨烯/活性炭混合电极组装在一起,形成了圆柱形结构的商用超级电容器。实验测试证实,这种超级电容器具有高容量密度、功率密度、低内阻(约 0.06 mΩ)、良好的大电流充放电特性和较长的使用寿命,10 W 循环后容量保持率超过 80%。
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引用次数: 0
An Investigation into the Viability of Battery Technologies for Electric Buses in the UK 英国电动巴士电池技术可行性调查
Pub Date : 2024-03-04 DOI: 10.3390/batteries10030091
Tahmid Muhith, Santosh Behara, Munnangi Anji Reddy
This study explores the feasibility of integrating battery technology into electric buses, addressing the imperative to reduce carbon emissions within the transport sector. A comprehensive review and analysis of diverse literature sources establish the present and prospective landscape of battery electric buses within the public transportation domain. Existing battery technology and infrastructure constraints hinder the comprehensive deployment of electric buses across all routes currently served by internal combustion engine counterparts. However, forward-looking insights indicate a promising trajectory with the potential for substantial advancements in battery technology coupled with significant investments in charging infrastructure. Such developments hold promise for electric buses to fulfill a considerable portion of a nation’s public transit requirements. Significant findings emphasize that electric buses showcase considerably lower emissions than fossil-fuel-driven counterparts, especially when operated with zero-carbon electricity sources, thereby significantly mitigating the perils of climate change.
本研究探讨了将电池技术整合到电动公交车中的可行性,以解决交通部门减少碳排放的当务之急。通过对各种文献资料的全面审查和分析,确定了电池电动公交车在公共交通领域的现状和前景。现有的电池技术和基础设施限制阻碍了电动公交车在目前由内燃机公交车提供服务的所有线路上的全面部署。不过,前瞻性的洞察力表明,电动公交车的发展前景广阔,电池技术有可能取得长足进步,充电基础设施也将获得重大投资。这些发展有望使电动公交车满足国家公共交通的大部分需求。重要研究结果强调,电动公交车的排放量大大低于化石燃料驱动的公交车,尤其是在使用零碳电力的情况下,从而大大减轻了气候变化的危害。
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引用次数: 0
A State-of-Health Estimation Method for Lithium Batteries Based on Fennec Fox Optimization Algorithm–Mixed Extreme Learning Machine 基于 Fennec Fox 优化算法-混合极端学习机的锂电池健康状况评估方法
Pub Date : 2024-03-02 DOI: 10.3390/batteries10030087
Chongbin Sun, Wenhu Qin, Zhonghua Yun
A reliable and accurate estimation of the state-of-health (SOH) of lithium batteries is critical to safely operating electric vehicles and other equipment. This paper proposes a state-of-health estimation method based on fennec fox optimization algorithm–mixed extreme learning machine (FFA-MELM). Firstly, health indicators are extracted from lithium-battery-charging data, and grey relational analysis (GRA) is employed to identify highly correlated features with the state-of-health of the battery. Subsequently, a state-of-health estimation model based on mixed extreme learning machine is constructed, and the hyperparameters of the model are optimized using the fennec fox optimization algorithm to improve estimation accuracy and convergence speed. The experimental results demonstrate that the proposed method has significantly improved the accuracy of the state-of-health estimation for lithium batteries compared to the extreme learning machine. Furthermore, it can achieve precise state-of-health estimation results for multiple batteries, even under complex operating conditions and with limited charge/discharge cycle data.
可靠而准确地估算锂电池的健康状况(SOH)对于安全运行电动汽车和其他设备至关重要。本文提出了一种基于狐狸优化算法-混合极端学习机(FFA-MELM)的健康状况估计方法。首先,从锂电池充电数据中提取健康指标,并采用灰色关系分析(GRA)找出与电池健康状况高度相关的特征。随后,构建了基于混合极端学习机的电池健康状况估计模型,并利用狐狸优化算法对模型的超参数进行了优化,以提高估计精度和收敛速度。实验结果表明,与极端学习机相比,所提出的方法显著提高了锂电池健康状态估计的准确性。此外,即使在复杂的运行条件下和充放电循环数据有限的情况下,它也能对多个电池得出精确的健康状况估计结果。
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引用次数: 0
Battery Temperature Prediction Using an Adaptive Neuro-Fuzzy Inference System 使用自适应神经模糊推理系统预测电池温度
Pub Date : 2024-03-01 DOI: 10.3390/batteries10030085
Hanwen Zhang, A. Fotouhi, D. Auger, Matt Lowe
Maintaining batteries within a specific temperature range is vital for safety and efficiency, as extreme temperatures can degrade a battery’s performance and lifespan. In addition, battery temperature is the key parameter in battery safety regulations. Battery thermal management systems (BTMSs) are pivotal in regulating battery temperature. While current BTMSs offer real-time temperature monitoring, their lack of predictive capability poses a limitation. This study introduces a novel hybrid system that combines a machine learning-based battery temperature prediction model with an online battery parameter identification unit. The identification unit continuously updates the battery’s electrical parameters in real time, enhancing the prediction model’s accuracy. The prediction model employs an Adaptive Neuro-Fuzzy Inference System (ANFIS) and considers various input parameters, such as ambient temperature, the battery’s current temperature, internal resistance, and open-circuit voltage. The model accurately predicts the battery’s future temperature in a finite time horizon by dynamically adjusting thermal and electrical parameters based on real-time data. Experimental tests are conducted on Li-ion (NCA and LFP) cylindrical cells across a range of ambient temperatures to validate the system’s accuracy under varying conditions, including state of charge and a dynamic load current. The proposed models prioritise simplicity to ensure real-time industrial applicability.
将电池保持在特定的温度范围内对安全和效率至关重要,因为极端温度会降低电池的性能和使用寿命。此外,电池温度也是电池安全法规中的关键参数。电池热管理系统(BTMS)是调节电池温度的关键。虽然目前的 BTMS 可提供实时温度监控,但其缺乏预测能力,这也是其局限性所在。本研究介绍了一种新型混合系统,它将基于机器学习的电池温度预测模型与在线电池参数识别单元相结合。识别单元可持续实时更新电池的电气参数,从而提高预测模型的准确性。预测模型采用了自适应神经模糊推理系统(ANFIS),并考虑了各种输入参数,如环境温度、电池当前温度、内阻和开路电压。该模型根据实时数据动态调整热参数和电参数,从而在有限的时间范围内准确预测电池的未来温度。在不同环境温度下对锂离子(NCA 和 LFP)圆柱形电池进行了实验测试,以验证系统在不同条件下(包括充电状态和动态负载电流)的准确性。建议的模型以简洁为优先,以确保实时的工业适用性。
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引用次数: 0
Recent Advances in Thermal Management Strategies for Lithium-Ion Batteries: A Comprehensive Review 锂离子电池热管理策略的最新进展:全面回顾
Pub Date : 2024-03-01 DOI: 10.3390/batteries10030083
Yadyra Ortiz, Paul Arévalo, Diego Peña, F. Jurado
Effective thermal management is essential for ensuring the safety, performance, and longevity of lithium-ion batteries across diverse applications, from electric vehicles to energy storage systems. This paper presents a thorough review of thermal management strategies, emphasizing recent advancements and future prospects. The analysis begins with an evaluation of industry-standard practices and their limitations, followed by a detailed examination of single-phase and multi-phase cooling approaches. Successful implementations and challenges are discussed through relevant examples. The exploration extends to innovative materials and structures that augment thermal efficiency, along with advanced sensors and thermal control systems for real-time monitoring. The paper addresses strategies for mitigating the risks of overheating and propagation. Furthermore, it highlights the significance of advanced models and numerical simulations in comprehending long-term thermal degradation. The integration of machine learning algorithms is explored to enhance precision in detecting and predicting thermal issues. The review concludes with an analysis of challenges and solutions in thermal management under extreme conditions, including ultra-fast charging and low temperatures. In summary, this comprehensive review offers insights into current and future strategies for lithium-ion battery thermal management, with a dedicated focus on improving the safety, performance, and durability of these vital energy sources.
有效的热管理对于确保从电动汽车到储能系统等各种应用中的锂离子电池的安全性、性能和寿命至关重要。本文全面回顾了热管理策略,重点介绍了最新进展和未来前景。分析首先评估了行业标准做法及其局限性,然后详细研究了单相和多相冷却方法。通过相关实例讨论了成功的实施方法和面临的挑战。论文还探讨了提高热效率的创新材料和结构,以及用于实时监控的先进传感器和热控制系统。论文探讨了降低过热和传播风险的策略。此外,论文还强调了先进模型和数值模拟在理解长期热退化方面的重要性。文章还探讨了机器学习算法的整合,以提高检测和预测热问题的精度。综述最后分析了极端条件(包括超快速充电和低温)下热管理的挑战和解决方案。总之,本综述深入探讨了当前和未来的锂离子电池热管理策略,重点关注如何提高这些重要能源的安全性、性能和耐用性。
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引用次数: 0
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