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Graphene-cellulose hydrogels: An apt combination 石墨烯-纤维素水凝胶:完美结合
Pub Date : 2024-05-01 DOI: 10.15376/biores.19.3.4050-4052
Zhongfei Yuan
Graphene-cellulose hydrogels have been extensively studied in the field of functional hydrogels. This editorial presents an overview of graphene-based and cellulose-derived materials, highlighting the unique characteristics of these two materials and the synergistic advantages achieved by combining them to construct graphene-cellulose composite hydrogels. The aim is to provide novel insights for developing functional cellulose-based hydrogels enabled by carbon nanomaterials.
石墨烯-纤维素水凝胶在功能性水凝胶领域得到了广泛的研究。这篇社论概述了石墨烯基材料和纤维素衍生材料,强调了这两种材料的独特特性,以及将它们结合起来构建石墨烯-纤维素复合水凝胶所实现的协同优势。其目的是为利用碳纳米材料开发功能性纤维素基水凝胶提供新的见解。
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引用次数: 0
Kudzu: An invasive plant or a sustainable resource 野葛入侵植物还是可持续资源
Pub Date : 2024-05-01 DOI: 10.15376/biores.19.3.4047-4049
Shengrong Zhang, Qi Zhang, Xin Guo, Shengdong Zhu
Kudzu (Pueraria lobata (Willd.) Ohwi) is a fast growing leguminous vine plant that has strong reproductive ability and low requirements on its growing conditions. It has been considered an invasive plant in some places because of its aggressive growth, which can destroy the habitat for native plants and animals. However, its strong environmental adaptability makes it easily cultivated as a sustainable resource. Kudzu can also keep soil from washing away and play an important role in ecological protection. Kudzu has had numerous practical uses in our daily lives since ancient times. For example, its root, stem, flower and pod are used in traditional Chinese medicine. Its root is a healthy food. And its leaf is used as fodder and forage for livestock. Moreover, some recent studies on kudzu have found that it is in rich of bioactive ingredients, especially isoflavones, which further broadens its uses in medicine, healthy food, and cosmetics industries. Its high starch and cellulose content makes it a promising feedstock for biofuel production and paper preparation. This editorial will give a brief discussion on kudzu and its comprehensive utilization.
野葛(Pueraria lobata (Willd.) Ohwi)是一种生长迅速的豆科藤本植物,繁殖能力强,对生长条件要求不高。在一些地方,它被认为是一种入侵植物,因为它的生长具有侵略性,会破坏本地动植物的栖息地。不过,它对环境的适应能力很强,因此很容易作为一种可持续资源进行栽培。野葛还能防止土壤流失,在生态保护方面发挥着重要作用。自古以来,葛根在我们的日常生活中就有许多实际用途。例如,它的根、茎、花和荚果都可用于传统中药。它的根是一种健康食品。它的叶子可用作牲畜的饲料和饲草。此外,最近对葛根的一些研究发现,它含有丰富的生物活性成分,尤其是异黄酮,这进一步拓宽了它在医药、健康食品和化妆品行业的用途。葛根的淀粉和纤维素含量较高,是一种很有前景的生物燃料生产和造纸原料。这篇社论将简要讨论葛根及其综合利用。
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引用次数: 0
Paper drinking straws coated with cellulose acetate and polyhydroxyalkanoates via an entropy-driven approach and natural colorants as alternatives for plastic drinking straws 通过熵驱动法涂覆醋酸纤维素和聚羟基烷酸酯的纸吸管以及天然着色剂作为塑料吸管的替代品
Pub Date : 2024-05-01 DOI: 10.15376/biores.19.3.4043-4046
Jinlong Zhang, Lokendra Pal
As a way to reduce microplastics or nano-plastics in the ocean, it is of interest to develop biodegradable paper-based drinking straws to replace non-degradable plastic drinking straws. Primary questions to be addressed include how to design suitable coatings for paper drinking straws. Such coatings not only need to resist water. In addition, consumers have high expectations for the strength of a drinking straw. It is proposed here to replace non-biodegradable polypropylene, which is presently the main component of straws, with biodegradable and hydrophobic coating components via an entropy-driven approach. It is further proposed to develop colored paper-based drinking straws with cellulose nematic liquid crystal photonic pigments as a way to make the product stand out visibly, while at the same time mediating the usage of toxic chemical pigments.
作为减少海洋中的微塑料或纳米塑料的一种方法,开发可生物降解的纸质饮管以取代不可降解的塑料饮管令人感兴趣。需要解决的主要问题包括如何为纸质饮管设计合适的涂层。这种涂层不仅需要防水。此外,消费者对吸管的强度也有很高的要求。本文建议通过熵驱动方法,用可生物降解的疏水涂层成分取代目前吸管的主要成分--不可生物降解的聚丙烯。此外,还建议开发使用纤维素向列液晶光子颜料的彩色纸基饮水机吸管,使产品更加醒目,同时减少有毒化学颜料的使用。
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引用次数: 0
Some modeling challenges in dynamic life cycle assessment 动态生命周期评估中的一些建模挑战
Pub Date : 2024-05-01 DOI: 10.15376/biores.19.3.4040-4042
Kai Lan
Life cycle assessment (LCA) has been a mainstream tool to evaluate the environmental impacts of products, services, and systems. Current LCAs inherently rely on the static basis and commonly fail to include temporal considerations. To better assist in the decision-making for sustainable development, dynamic LCA has been initiated to answer more complex and interdisciplinary questions. As in its initial phase, dynamic LCA faces many modeling challenges that at the same time are meaningful research opportunities. In modeling dynamic LCA, there are several key aspects that need more attention for contribution and close collaboration across the first three phases of the LCA framework.
生命周期评估(LCA)一直是评估产品、服务和系统对环境影响的主流工具。目前的生命周期评估固有地依赖于静态基础,通常不包括时间因素。为了更好地协助可持续发展决策,人们开始采用动态生命周期评估来回答更加复杂和跨学科的问题。正如其初始阶段一样,动态生命周期评估面临着许多建模挑战,同时也是有意义的研究机会。在建立动态生命周期评估模型时,有几个关键方面需要更多关注,以促进生命周期评估框架前三个阶段的贡献和密切合作。
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引用次数: 0
Integration of genome-scale metabolic model with biorefinery process model reveals market-competitive carbon-negative sustainable aviation fuel utilizing microbial cell mass lipids and biogenic CO2 基因组尺度代谢模型与生物精炼工艺模型的整合揭示了利用微生物细胞质脂和生物源二氧化碳生产的具有市场竞争力的负碳可持续航空燃料
Pub Date : 2024-05-01 DOI: 10.15376/biores.19.3.4056-4086
Nawa Raj Baral, Deepanwita Banerjee, Aindrila Mukhopadhyay, B. A. Simmons, S. Singer, C. Scown
Producing scalable, economically viable, low-carbon biofuels or biochemicals hinges on more efficient bioconversion processes. While microbial conversion can offer robust solutions, the native microbial growth process often redirects a large fraction of carbon to CO2 and cell mass. By integrating genome-scale metabolic models with techno-economic and life cycle assessment models, this study analyzes the effects of converting cell mass lipids to hydrocarbon fuels, and CO2 to methanol on the facility’s costs and life-cycle carbon footprint. Results show that upgrading microbial lipids or both microbial lipids and CO2 using renewable hydrogen produces carbon-negative bisabolene. Additionally, on-site electrolytic hydrogen production offers a supply of pure oxygen to use in place of air for bioconversion and fuel combustion in the boiler. To reach cost parity with conventional jet fuel, renewable hydrogen needs to be produced at less than $2.2 to $3.1/kg, with a bisabolene yield of 80% of the theoretical yield, along with cell mass and CO2 yields of 22 wt% and 54 wt%, respectively. The economic combination of cell mass, CO2, and bisabolene yields demonstrated in this study provides practical insights for prioritizing research, selecting suitable hosts, and determining necessary engineered production levels.
生产可扩展、经济上可行的低碳生物燃料或生物化学品取决于更高效的生物转化过程。虽然微生物转化可以提供稳健的解决方案,但原生微生物的生长过程通常会将大部分碳转化为二氧化碳和细胞质量。通过将基因组尺度代谢模型与技术经济和生命周期评估模型相结合,本研究分析了将细胞质量脂质转化为碳氢化合物燃料以及将二氧化碳转化为甲醇对设施成本和生命周期碳足迹的影响。结果表明,利用可再生氢气提升微生物脂质或微生物脂质和二氧化碳可产生负碳双酚。此外,现场电解制氢还可提供纯氧,代替空气用于生物转化和锅炉燃料燃烧。要达到与传统喷气燃料持平的成本,可再生氢的生产成本需低于 2.2 美元至 3.1 美元/千克,双酚产量为理论产量的 80%,电池质量和二氧化碳产量分别为 22 wt% 和 54 wt%。本研究中展示的细胞质量、二氧化碳和双酚产量的经济组合为确定研究的优先次序、选择合适的宿主和确定必要的工程生产水平提供了实用的见解。
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引用次数: 0
Artists, papermakers, and the future 艺术家、造纸者与未来
Pub Date : 2024-05-01 DOI: 10.15376/biores.19.3.4053-4055
M. Hubbe
This editorial considers three groups of individuals and how they often find themselves following common ways of thinking. Artists, especially those who become well known, are hard workers and somewhat stubborn. Once they have found a type of paper that works well for them, they tend to develop loyalty to it, regardless of what the label on the ream wrap may say. Papermakers, ancient and modern, likewise have tended to stick with practices that are convenient to them at the moment, whether or not they contribute to archival quality. Fortunately, the transition to alkaline papermaking practices means that modern printing papers tend to last a lot longer. Increasing knowledge of the importance of acid-free paper, as well as the principles of sustainability, are making positive contributions to our ongoing cultural heritage, at least to the part of that heritage that is related to cellulosic materials.
这篇社论探讨了三类人,以及他们如何经常发现自己遵循着共同的思维方式。艺术家,尤其是那些声名显赫的艺术家,工作勤奋,而且有些固执。一旦他们找到了一种适合自己的纸张,不管包装纸上的标签如何标注,他们都会忠于这种纸张。古今中外的造纸工人也是如此,他们往往会坚持使用对他们目前来说比较方便的做法,无论这些做法是否有助于提高档案质量。幸运的是,向碱性造纸法的过渡意味着现代印刷纸的使用寿命更长。人们对无酸纸的重要性以及可持续发展原则的认识不断提高,这对我们正在进行的文化遗产保护工作做出了积极贡献,至少对与纤维素材料有关的那部分遗产来说是如此。
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引用次数: 0
Quantifying and predicting the tensile properties of silicone reinforced with Moringa oleifera bark fibers, 量化和预测用油辣木树皮纤维增强的硅树脂的拉伸性能、
Pub Date : 2024-04-17 DOI: 10.15376/biores.19.2.3461-3474
Mohd Nor Azmi Ab Patar, N. A. S. Manssor, Mohd Rashdan Isa, Nur Auni Izzati Jusoh, M. J. Abd Latif, P. N. Sivasankaran, Jamaluddin Mahmud
To obtain a better understanding of using Moringa oleifera bark (MOB) as a reinforcement in a silicone matrix, this study aimed to define the mechanical properties of this new material under uniaxial tension. Composite samples of 0 wt%, 4 wt%, 8 wt%, 12 wt%, and 16 wt% MOB powder were produced. The tensile properties were quantified mathematically using the neo-Hookean hyperelastic model. The collected data were employed to establish multiple inputs of an artificial neural network (ANN) to predict its material constant via MATLAB. The result showed that the material constant for the 16 wt% fiber content sample was 63.9% higher than pure silicone. This was supported by the tensile modulus testing, which indicated that the modulus increased as the fiber content increased. However, the elongation ratio (λ) of the MOB-silicone biocomposite decreased slightly compared to the pure silicone. Lastly, the prediction of the material constant using an ANN recorded a 2.03% percentage error, which showed that it was comparable to the mathematical modelling. Therefore, the inclusion of MOB fibers into silicone produced a stiffer material and gradually improved the composite. Furthermore, the network that had multiple inputs (weighting, load, and elongation) was more reliable to produce precise predictions.
为了更好地了解如何使用辣木树皮(MOB)作为有机硅基体的增强材料,本研究旨在确定这种新材料在单轴拉伸下的机械性能。研究人员制作了 MOB 粉含量分别为 0 wt%、4 wt%、8 wt%、12 wt% 和 16 wt% 的复合样品。使用新胡克安超弹性模型对拉伸性能进行了数学量化。收集到的数据被用于建立人工神经网络(ANN)的多个输入,通过 MATLAB 预测其材料常数。结果表明,纤维含量为 16 wt% 的样品的材料常数比纯硅胶高 63.9%。拉伸模量测试也证明了这一点,测试结果表明,随着纤维含量的增加,模量也随之增加。不过,与纯硅胶相比,MOB-硅胶生物复合材料的伸长率(λ)略有下降。最后,使用 ANN 对材料常数进行预测的百分比误差为 2.03%,这表明它与数学模型相当。因此,在有机硅中加入 MOB 纤维可产生更硬的材料,并逐步改善复合材料。此外,具有多重输入(加权、载荷和伸长率)的网络在进行精确预测方面更为可靠。
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引用次数: 0
Effects of membrane covers and biochar on compost quality and greenhouse gas reduction in aerobic composting 膜覆盖物和生物炭对好氧堆肥中堆肥质量和温室气体减排的影响
Pub Date : 2024-04-17 DOI: 10.15376/biores.19.2.3475-3488
Jie Cao, H. Qu, Ruirong Li, Pengjun Wang, Jingjing Fu, Mingjiang Chen
The addition of biochar and the use of membrane coverings are two methods used in aerobic composting of agricultural waste. The effectiveness of each of these two methods on compost quality and reduction of greenhouse gas emissions was tested in the laboratory. The results showed that both methods increased the maximum composting temperature and extended the thermophilic period. The germination index of biochar-treated compost and membrane-covered compost reached 70% on the 18th day, which was 12 days earlier than the corresponding value in the control group. The products from the biochar-treated compost had higher pH and lower electrical conductivity, compared with the product of the control group, indicating that these products are more suitable for acidic soils. In terms of greenhouse gas reduction, both methods were found to reduce the emissions of CH4 and N2O from composting. The addition of biochar had a better emission reduction effect on N2O, whereas the membrane covering technique yielded a better effect on CH4 emission reduction. The results of this study provide technical support for managed aerobic composting to reduce greenhouse gas emissions.
添加生物炭和使用膜覆盖物是农业废弃物好氧堆肥的两种方法。这两种方法分别对堆肥质量和减少温室气体排放的效果进行了实验室测试。结果表明,这两种方法都提高了堆肥的最高温度,延长了嗜热期。生物炭处理堆肥和膜覆盖堆肥的发芽指数在第 18 天达到 70%,比对照组的相应值提前了 12 天。与对照组的产品相比,生物炭处理堆肥的产品具有更高的 pH 值和更低的电导率,这表明这些产品更适合酸性土壤。在减少温室气体排放方面,两种方法都能减少堆肥产生的甲烷和氧化亚氮的排放。添加生物炭对 N2O 的减排效果更好,而膜覆盖技术对 CH4 的减排效果更好。这项研究的结果为有管理的好氧堆肥减少温室气体排放提供了技术支持。
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引用次数: 0
Relationship between mechanical properties and height-diameter ratio of moso bamboo 毛竹机械性能与高径比之间的关系
Pub Date : 2024-04-16 DOI: 10.15376/biores.19.2.3409-3420
Liming Yang, Yan Yuan, Xiaoming Lu
Systematic tests of longitudinal compression, bending, longitudinal shear, and longitudinal tensile strength of bamboo were conducted to study the variation of mechanical properties and the height-diameter ratio of bamboo. The predictive relations of mechanical properties and height-diameter ratio were fitted by linear regression analysis. The results showed that the mechanical properties of longitudinal compression, bending, longitudinal shear, and longitudinal tensile strength of bamboo increased with the increase of the height-diameter ratio. In this paper, the method of deducing the relationship between mechanical properties and height-diameter ratio of bamboo through the linear fitting relationship between mechanical properties and height-diameter ratio was shown to have high applicability and accuracy for bamboo. This paper has a certain reference value for the evaluation of mechanical properties of bamboo and has a certain practical value for reducing the testing cost.
对竹材的纵向压缩、弯曲、纵向剪切和纵向拉伸强度进行了系统试验,以研究竹材力学性能和高径比的变化。通过线性回归分析拟合了力学性能和高径比的预测关系。结果表明,竹材的纵向压缩、弯曲、纵向剪切和纵向抗拉强度等力学性能随高径比的增加而增加。本文通过竹材力学性能与高径比的线性拟合关系推导出竹材力学性能与高径比关系的方法,表明该方法对竹材具有较高的适用性和准确性。本文对竹材力学性能的评价具有一定的参考价值,对降低试验成本具有一定的实用价值。
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引用次数: 0
Properties of poplar veneer modified by Acid Red 3R dye in combination with ammonium dihydrogen phosphate 酸性红 3R 染料结合磷酸二氢铵改性杨木单板的性能
Pub Date : 2024-04-16 DOI: 10.15376/biores.19.2.3436-3460
Xin Shi, Hao Shen, Shenglei Qin, Yangguang Liu, Xiaoshuang Shen, Demiao Chu, Shengquan Liu
Ammonium dihydrogen phosphate (ADP) is a nitrogen-phosphorus-based inorganic flame retardant that is environmentally friendly and non-toxic. Wood treated with ADP has enhanced thermal stability and flame retardancy. Compounding ADP with Acid Red 3R dye further improves the decorative effect of the wood on the basis of excellent flame retardancy, resulting in a kind of dyeing and flame retardant multifunctionalized wood. Single-factor tests were designed to investigate the effects of flame retardant concentration, dye concentration, temperature, and time on three evaluation indexes: dye-uptake, color difference, and oxygen index, respectively. Through SEM and FTIR analysis, it was found that after the wood was simultaneously treated with flame retardant and dye, the two additives were aggregated in the grain pores of the cell wall by a simple physical combination. They did not undergo a chemical reaction. TG analysis showed that fire-retardant dyed wood had good thermal stability, which can delay the thermal degradation of wood and increase the residual charcoal rate of wood. XRD showed that the crystallinity of fire-retardant dyed wood increased compared to untreated wood. Through cone calorimetric test, it is found that flame retardant dyed veneer had excellent flame retardancy.
磷酸二氢铵(ADP)是一种氮磷基无机阻燃剂,环保无毒。经过 ADP 处理的木材具有更高的热稳定性和阻燃性。将 ADP 与酸性红 3R 染料复配,在优异阻燃性的基础上进一步提高了木材的装饰效果,形成了一种染色阻燃多功能木材。设计了单因素试验,分别考察阻燃剂浓度、染料浓度、温度和时间对染料吸收率、色差和氧指数三项评价指标的影响。通过扫描电子显微镜和傅立叶变换红外光谱分析发现,木材经阻燃剂和染料同时处理后,两种添加剂通过简单的物理结合聚集在细胞壁的晶粒孔隙中。它们没有发生化学反应。TG 分析表明,阻燃剂染色木材具有良好的热稳定性,可延缓木材的热降解,提高木材的残炭率。XRD 显示,与未处理的木材相比,阻燃染色木材的结晶度有所增加。通过锥量热试验发现,阻燃染色单板具有优异的阻燃性。
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引用次数: 0
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