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Performance of laminated veneer lumber panels from fast-growing species with different layering arrangements 不同分层排列的速生树种层压单板板材的性能
Pub Date : 2024-03-01 DOI: 10.15376/biores.19.2.2546-2561
Mohammad Arabi, Moharam Hazrati, Akbar Rostampour-Haftkhani
This study investigated the effect of various layer arrangements and their impact on the properties of laminated veneer lumber (LVL). Seven different layer arrangements (CCCCCCC, DDDDDDD, PPPPPPP, CDDDDDC, CPPPPPC, CDDCDDC, CPPCPPC, CDCDCDC, CPCPCPC, CCDDDCC, CCPPPCC, CCDCDCC, and CCPCPCC) were used in the manufacturing of the LVL, with each arrangement represented by a combination of the three wood species: hornbeam (C), paulownia (P), and poplar (D). The veneers were bonded with a polyurethane adhesive and pressed under 1 MPa pressure. The physical and mechanical properties of the laminated veneer lumber, including modulus of rupture, modulus of elasticity, block shear, delamination, and swelling, were measured under both dry and cyclic conditions (boil and dry). The modulus of rupture and modulus of elasticity of the LVLs increased when the proportion of hornbeam in the lamination increased. In the cyclic boil-dry condition, the laminated veneer lumbers with the configurations CPCPCPC and CDCDCDC showed the best structural performance. Furthermore, the study found that when one or two upper layers of poplar and paulownia were replaced with hornbeam layers, cracks were observed in the laminated veneer lumber samples. However, when the layers of poplar and paulownia were replaced with hornbeam alternately, no cracks were observed after saturating the laminated veneer lumber with water. The utilization of an alternating arrangement of poplar and paulownia layers with hornbeam in LVL can be used as an effective and cost-efficient approach for enhancing and reinforcing the LVL performance.
本研究调查了各种层状排列的效果及其对层压单板板材(LVL)性能的影响。在制造 LVL 时使用了七种不同的层排列方式(CCCCCCC、DDDDDDD、PPPPP、CDDDDC、CPPPPPC、CDDCDDC、CPPCPPC、CDCDCDC、CPCPCPC、CCDDDCC、CCPPPCC、CCDCDCC 和 CCPCPCC),每种排列方式都代表了三种木材树种的组合:角梁木(C)、泡桐(P)和杨木(D)。单板用聚氨酯粘合剂粘合,并在 1 兆帕压力下压制。在干燥和循环条件(沸腾和干燥)下测量了层压单板木材的物理和机械特性,包括断裂模数、弹性模量、块状剪切、分层和膨胀。当层板中的角梁比例增加时,LVL 的断裂模数和弹性模量也随之增加。在循环煮干条件下,配置为 CPCPCPC 和 CDCDCDC 的层压单板木材显示出最佳的结构性能。此外,研究还发现,当杨木和泡桐的一到两层上层被角梁层取代时,层压单板木材样本中会出现裂缝。然而,当杨木和泡桐层交替替换为黄檀层时,在用水浸泡层压单板木材后没有发现裂缝。在 LVL 中交替使用杨木层和泡桐层与角梁,是提高和增强 LVL 性能的一种有效且经济的方法。
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引用次数: 0
Sustainable thermoplastic road marking paint production from natural modified rosins 利用天然改性松香生产可持续的热塑性道路标线涂料
Pub Date : 2024-02-13 DOI: 10.15376/biores.19.2.2160-2178
Bilge Yılmaz, İlhan Deniz, Hilal Fazlı, O. Bekircan, Andrey Pranovich, E. Karaogul
Modified natural rosins were evaluated as binders in the production of thermoplastic road marking paints (TRMPs). Pine rosin (GR), wood rosin (WR), and tall oil rosin (TOR) were used. Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), matrix-assisted laser desorption/ionization (MALDI-ToF-MS), and gel permeation chromatography-high pressure liquid chromatography (GPC-HPLC) were performed on natural and modified rosins. Acid number (mg KOH/g) ASTM D 465 – 05 and softening point, (°C) ASTM E 28 – 99 standard tests were applied to the samples. For the optimum synthesis condition, the pentaerythritol/rosin mol/mol ratio is 1/1, with the levels of Irganox 1425/rosin w/w, 0.5%, and TBM-6/rosin w/w, 1.0%. Gel permeation chromatography-high pressure analysis revealed that the esterification reaction yield was over 90% for each of the three natural rosins. Moreover, chromaticity coordinates (x,y), gloss factor (β), softening point (°C), and UVB aging test were applied to TRMPs. Modified natural rosins showed better results in the production of TRMPs. This is an important development and crucial step for sustainable TRMP production.
对改性天然松香作为生产热塑性道路标线涂料(TRMP)的粘合剂进行了评估。使用了松香(GR)、木松香(WR)和妥尔油松香(TOR)。对天然松香和改性松香进行了傅立叶变换红外光谱(FT-IR)、热重分析(TGA)、基质辅助激光解吸/电离(MALDI-ToF-MS)和凝胶渗透色谱-高压液相色谱(GPC-HPLC)分析。对样品进行了酸值(毫克 KOH/克)ASTM D 465 - 05 和软化点(°C)ASTM E 28 - 99 标准测试。在最佳合成条件下,季戊四醇与松香的摩尔/摩尔比为 1/1,Irganox 1425 与松香的重量比为 0.5%,TBM-6 与松香的重量比为 1.0%。凝胶渗透色谱-高压分析表明,三种天然松香的酯化反应产率均超过 90%。此外,还对 TRMP 进行了色度坐标(x,y)、光泽系数(β)、软化点(℃)和紫外线老化试验。改性天然松香在 TRMP 的生产中表现出更好的效果。这是可持续 TRMP 生产的重要发展和关键步骤。
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引用次数: 0
Sustainable thermoplastic road marking paint production from natural modified rosins 利用天然改性松香生产可持续的热塑性道路标线涂料
Pub Date : 2024-02-13 DOI: 10.15376/biores.19.2.2160-2178
Bilge Yılmaz, İlhan Deniz, Hilal Fazlı, O. Bekircan, Andrey Pranovich, E. Karaogul
Modified natural rosins were evaluated as binders in the production of thermoplastic road marking paints (TRMPs). Pine rosin (GR), wood rosin (WR), and tall oil rosin (TOR) were used. Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), matrix-assisted laser desorption/ionization (MALDI-ToF-MS), and gel permeation chromatography-high pressure liquid chromatography (GPC-HPLC) were performed on natural and modified rosins. Acid number (mg KOH/g) ASTM D 465 – 05 and softening point, (°C) ASTM E 28 – 99 standard tests were applied to the samples. For the optimum synthesis condition, the pentaerythritol/rosin mol/mol ratio is 1/1, with the levels of Irganox 1425/rosin w/w, 0.5%, and TBM-6/rosin w/w, 1.0%. Gel permeation chromatography-high pressure analysis revealed that the esterification reaction yield was over 90% for each of the three natural rosins. Moreover, chromaticity coordinates (x,y), gloss factor (β), softening point (°C), and UVB aging test were applied to TRMPs. Modified natural rosins showed better results in the production of TRMPs. This is an important development and crucial step for sustainable TRMP production.
对改性天然松香作为生产热塑性道路标线涂料(TRMP)的粘合剂进行了评估。使用了松香(GR)、木松香(WR)和妥尔油松香(TOR)。对天然松香和改性松香进行了傅立叶变换红外光谱(FT-IR)、热重分析(TGA)、基质辅助激光解吸/电离(MALDI-ToF-MS)和凝胶渗透色谱-高压液相色谱(GPC-HPLC)分析。对样品进行了酸值(毫克 KOH/克)ASTM D 465 - 05 和软化点(°C)ASTM E 28 - 99 标准测试。在最佳合成条件下,季戊四醇与松香的摩尔/摩尔比为 1/1,Irganox 1425 与松香的重量比为 0.5%,TBM-6 与松香的重量比为 1.0%。凝胶渗透色谱-高压分析表明,三种天然松香的酯化反应产率均超过 90%。此外,还对 TRMP 进行了色度坐标(x,y)、光泽系数(β)、软化点(℃)和紫外线老化试验。改性天然松香在 TRMP 的生产中表现出更好的效果。这是可持续 TRMP 生产的重要发展和关键步骤。
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引用次数: 0
Effects of silver nanoparticles on germination and seedling characteristics of Oriental beech (Fagus orientalis) seeds 纳米银颗粒对东方山毛榉(Fagus orientalis)种子萌发和幼苗特性的影响
Pub Date : 2024-02-12 DOI: 10.15376/biores.19.2.2135-2148
H. Özel, H. Sevik, Yafes Yıldız, H. Çobanoğlu
Nowadays, the applications of nanotechnology are increasing in various fields such as information technology, energy, the medical sector, and agriculture. Nanotechnology has proved its ability to solve problems in agriculture and related industries. Establishing the impact of nanoparticles on various ecosystems has become a primary research topic, but studies on forest ecosystems and trees are quite limited. This study examined the effects of silver nanoparticles on the germination parameters of oriental beech seeds and established their toxic threshold values. Silver nanoparticles were applied at concentrations of 200, 400, 600, 800, and 1000 mg/L to oriental beech (Fagus orientalis) seeds collected from 10 different populations in order to identify the germination rate, germination percentage, seedling height, root collar diameter, plumula length, radicle thickness, and radicle length parameters. The results revealed that silver nanoparticles have a negative effect on germination and seedling parameters of oriental beech seeds, and that this effect is clearly seen in the germination rate at 20 mg/L levels and in seedling characters starting from 60 mg/L dose, causing a decrease of 13% in germination rate, 24% in germination percentage, 40% in plumula length, and 30% in radicle length. The Kahramanmaras-Andirin population was found to be the most affected by nanoparticles, while the Bursa-Inegol and Ordu-Akkus populations were the least affected.
如今,纳米技术在信息技术、能源、医疗和农业等各个领域的应用日益增多。事实证明,纳米技术有能力解决农业及相关行业的问题。确定纳米粒子对各种生态系统的影响已成为一个主要研究课题,但对森林生态系统和树木的研究却相当有限。本研究考察了银纳米粒子对东方山毛榉种子萌发参数的影响,并确定了其毒性阈值。将纳米银粒子以 200、400、600、800 和 1000 mg/L 的浓度施用于从 10 个不同种群中采集的东方山毛榉(Fagus orientalis)种子,以确定其发芽率、发芽率、苗高、根颈直径、羽叶长度、胚根厚度和胚根长度等参数。结果表明,纳米银对东方山毛榉种子的发芽率和幼苗参数有负面影响,这种影响在 20 毫克/升水平的发芽率和从 60 毫克/升剂量开始的幼苗特征中明显可见,导致发芽率下降 13%,发芽率下降 24%,羽叶长度下降 40%,胚根长度下降 30%。研究发现,纳米粒子对 Kahramanmaras-Andirin 种群的影响最大,而对 Bursa-Inegol 和 Ordu-Akkus 种群的影响最小。
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引用次数: 0
Preparation of antibacterial and strong regenerated cellulose film via crosslinking with polymeric quaternary ammonium salt containing epoxy/ZnO 通过与含环氧树脂/氧化锌的聚合物季铵盐交联制备抗菌强力再生纤维素薄膜
Pub Date : 2024-02-12 DOI: 10.15376/biores.19.2.2149-2159
Meng Zhang, Xiaoning Tang, Tian Si, Xueping Wang, Xue Wu
Particulate matter (PM), usually formed as aerosols suspended in atmosphere, is becoming a carrier of viruses and bacteria, accelerating the spread of respiratory diseases. Hence, air filtration devices are widely utilized for removing PM. In this study, a regenerated cellulose (RC) film was prepared with the properties of good mechanical strength, antibacterial, and highly efficient filtration (EF) properties, through cellulose dissolution and further crosslinking with P(AGE-DMDAAC)/ZnO. Results exhibited that the Young’s modulus of the composite membrane was nearly 4.3 GPa. Additionally, the antibacterial performance against Escherichia coli and Staphylococcus aureus, was up to 99.89% and 99.67%, respectively. Meanwhile, RC composite filter exhibited a high PM 2.5 capture efficiency (over 99.91%). This study introduces an interesting approach to produce antibacterial films with the characteristics of notably good mechanical performance and high fine particle EF that can be utilized in a high humidity environment.
颗粒物(PM)通常以悬浮在大气中的气溶胶形式形成,正在成为病毒和细菌的载体,加速了呼吸道疾病的传播。因此,空气过滤设备被广泛用于去除可吸入颗粒物。本研究通过纤维素溶解并与 P(AGE-DMDAAC)/ZnO 进一步交联,制备了一种具有良好机械强度、抗菌和高效过滤(EF)性能的再生纤维素(RC)薄膜。结果表明,复合膜的杨氏模量接近 4.3 GPa。此外,对大肠杆菌和金黄色葡萄球菌的抗菌性能分别高达 99.89% 和 99.67%。同时,RC 复合过滤器还具有较高的 PM 2.5 捕获效率(超过 99.91%)。这项研究提出了一种有趣的方法来生产抗菌薄膜,这种薄膜具有显著的机械性能和高微粒 EF 值,可在高湿度环境中使用。
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引用次数: 0
Preparation of antibacterial and strong regenerated cellulose film via crosslinking with polymeric quaternary ammonium salt containing epoxy/ZnO 通过与含环氧树脂/氧化锌的聚合物季铵盐交联制备抗菌强力再生纤维素薄膜
Pub Date : 2024-02-12 DOI: 10.15376/biores.19.2.2149-2159
Meng Zhang, Xiaoning Tang, Tian Si, Xueping Wang, Xue Wu
Particulate matter (PM), usually formed as aerosols suspended in atmosphere, is becoming a carrier of viruses and bacteria, accelerating the spread of respiratory diseases. Hence, air filtration devices are widely utilized for removing PM. In this study, a regenerated cellulose (RC) film was prepared with the properties of good mechanical strength, antibacterial, and highly efficient filtration (EF) properties, through cellulose dissolution and further crosslinking with P(AGE-DMDAAC)/ZnO. Results exhibited that the Young’s modulus of the composite membrane was nearly 4.3 GPa. Additionally, the antibacterial performance against Escherichia coli and Staphylococcus aureus, was up to 99.89% and 99.67%, respectively. Meanwhile, RC composite filter exhibited a high PM 2.5 capture efficiency (over 99.91%). This study introduces an interesting approach to produce antibacterial films with the characteristics of notably good mechanical performance and high fine particle EF that can be utilized in a high humidity environment.
颗粒物(PM)通常以悬浮在大气中的气溶胶形式形成,正在成为病毒和细菌的载体,加速了呼吸道疾病的传播。因此,空气过滤设备被广泛用于去除可吸入颗粒物。本研究通过纤维素溶解并与 P(AGE-DMDAAC)/ZnO 进一步交联,制备了一种具有良好机械强度、抗菌和高效过滤(EF)性能的再生纤维素(RC)薄膜。结果表明,复合膜的杨氏模量接近 4.3 GPa。此外,对大肠杆菌和金黄色葡萄球菌的抗菌性能分别高达 99.89% 和 99.67%。同时,RC 复合过滤器还具有较高的 PM 2.5 捕获效率(超过 99.91%)。这项研究提出了一种有趣的方法来生产抗菌薄膜,这种薄膜具有显著的机械性能和高微粒 EF 值,可在高湿度环境中使用。
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引用次数: 0
Effects of silver nanoparticles on germination and seedling characteristics of Oriental beech (Fagus orientalis) seeds 纳米银颗粒对东方山毛榉(Fagus orientalis)种子萌发和幼苗特性的影响
Pub Date : 2024-02-12 DOI: 10.15376/biores.19.2.2135-2148
H. Özel, H. Sevik, Yafes Yıldız, H. Çobanoğlu
Nowadays, the applications of nanotechnology are increasing in various fields such as information technology, energy, the medical sector, and agriculture. Nanotechnology has proved its ability to solve problems in agriculture and related industries. Establishing the impact of nanoparticles on various ecosystems has become a primary research topic, but studies on forest ecosystems and trees are quite limited. This study examined the effects of silver nanoparticles on the germination parameters of oriental beech seeds and established their toxic threshold values. Silver nanoparticles were applied at concentrations of 200, 400, 600, 800, and 1000 mg/L to oriental beech (Fagus orientalis) seeds collected from 10 different populations in order to identify the germination rate, germination percentage, seedling height, root collar diameter, plumula length, radicle thickness, and radicle length parameters. The results revealed that silver nanoparticles have a negative effect on germination and seedling parameters of oriental beech seeds, and that this effect is clearly seen in the germination rate at 20 mg/L levels and in seedling characters starting from 60 mg/L dose, causing a decrease of 13% in germination rate, 24% in germination percentage, 40% in plumula length, and 30% in radicle length. The Kahramanmaras-Andirin population was found to be the most affected by nanoparticles, while the Bursa-Inegol and Ordu-Akkus populations were the least affected.
如今,纳米技术在信息技术、能源、医疗和农业等各个领域的应用日益增多。事实证明,纳米技术有能力解决农业及相关行业的问题。确定纳米粒子对各种生态系统的影响已成为一个主要研究课题,但对森林生态系统和树木的研究却相当有限。本研究考察了银纳米粒子对东方山毛榉种子萌发参数的影响,并确定了其毒性阈值。将纳米银粒子以 200、400、600、800 和 1000 mg/L 的浓度施用于从 10 个不同种群中采集的东方山毛榉(Fagus orientalis)种子,以确定其发芽率、发芽率、苗高、根颈直径、羽叶长度、胚根厚度和胚根长度等参数。结果表明,纳米银对东方山毛榉种子的发芽率和幼苗参数有负面影响,这种影响在 20 毫克/升水平的发芽率和从 60 毫克/升剂量开始的幼苗特征中明显可见,导致发芽率下降 13%,发芽率下降 24%,羽叶长度下降 40%,胚根长度下降 30%。研究发现,纳米粒子对 Kahramanmaras-Andirin 种群的影响最大,而对 Bursa-Inegol 和 Ordu-Akkus 种群的影响最小。
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引用次数: 0
Modeling of the thermoforming process of paperboard composites for packaging 包装用纸板复合材料热成型工艺建模
Pub Date : 2024-02-09 DOI: 10.15376/biores.19.2.2120-2134
Moaaz Safwa, Hemantha Kumar Yeddu, Ville Leminen
The quest to reduce global plastic consumption has led to the emergence of biodegradable fiber-based composites as a promising sustainable replacement to conventional plastics in the food packaging industry. As the packaging sector is shifting more towards fiber-centric materials, thermoforming techniques for the 3D forming of the fiber-based materials, especially using complex mold designs, should be thoroughly researched to replace the conventional plastics in the industry. Finite element analysis of the deformation behavior of the paperboard during the thermoforming process and the factors that trigger the fracture of the composite layers were studied in the present work. The results show that 90° fiber orientation, 0.3 mm sheet thicknesses, and specific mold geometries can result in better forming results, thereby maximizing the potential of fiber-based materials in thermoforming.
为减少全球塑料消耗,可生物降解纤维基复合材料应运而生,有望成为食品包装行业传统塑料的可持续替代品。由于包装行业正在更多地转向以纤维为中心的材料,因此应深入研究用于纤维材料三维成型的热成型技术,特别是使用复杂模具设计的技术,以取代行业中的传统塑料。本研究对纸板在热成型过程中的变形行为以及引发复合材料层断裂的因素进行了有限元分析。研究结果表明,90° 纤维取向、0.3 毫米的纸板厚度和特定的模具几何形状可获得更好的成型效果,从而最大限度地发挥纤维基材料在热成型中的潜力。
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引用次数: 0
Impact of green synthesized zinc oxide nanoparticles for treating dry rot in potato tubers 绿色合成氧化锌纳米粒子对处理马铃薯块茎干腐病的影响
Pub Date : 2024-02-09 DOI: 10.15376/biores.19.2.2106-2119
Mohamed A. Abdelhady, Tarek M. Abdelghany, Sonya H. Mohamed, Salah A. Abdelbary
Potato (Solanum tuberosum) crops have experienced a 22% reduction due to attacks from microbial pathogens and pests. Dry rot disease occurred from risks in El-Minya governorate, Egypt, where potato is the major cultivated crop. Potato cultivar ‘Cara’ samples were collected from the markets of six regions in El-Minya for isolation. They were also tested for the application of biosynthesized zinc oxide nanoparticles (ZnONPs) for disease management. The ability of Exserohilum rostratum to synthesize ZnONPs was documented via UV-visible, X-ray diffraction, Fourier transform infrared spectrum, and transmission and scanning electron microscopy. Spherical shape and crystallite small size (51.0 ± 3.0 nm) were attributed to the created ZnONPs. The ZnONPs were applied in the bio-control of the causative agent (Fusarium nygamai) of dry rot disease and large economic loss of potato cv. ‘Cara’ productivity. The mycosynthesized ZnONPs by E. rostratum at 100 μg/ mL (3 mM) showed antifungal activity against F. nygamai with higher reducing value of mycelium growth diameter 2.0 ± 0.14 cm compared to Revanol 50%, traditional product with a diameter of 3.85 ± 0.10 cm. Overall, ZnONPs are an excellent agent that can be applied to repress the most common fungal disease of potato.
由于微生物病原体和害虫的侵袭,马铃薯(Solanum tuberosum)作物产量减少了 22%。马铃薯是埃及 El-Minya 省的主要种植作物,该省的干腐病发生风险较高。从 El-Minya 六个地区的市场上收集了马铃薯栽培品种 "Cara "的样本进行分离。还对生物合成的氧化锌纳米粒子(ZnONPs)在病害防治中的应用进行了测试。通过紫外可见光、X 射线衍射、傅立叶变换红外光谱以及透射和扫描电子显微镜,证明了 Exserohilum rostratum 合成 ZnONPs 的能力。合成的 ZnONPs 呈球形,结晶尺寸较小(51.0 ± 3.0 nm)。这些 ZnONPs 被应用于生物防治干腐病的病原菌(镰刀菌),对马铃薯品种 "Cara "的产量造成了巨大的经济损失。E. rostratum 真菌合成的 ZnONPs 在 100 μg/ mL (3 mM) 的浓度下对 F. nygamai 具有抗真菌活性,与传统产品 Revanol 50%(直径为 3.85 ± 0.10 厘米)相比,其菌丝生长直径减少值更高,为 2.0 ± 0.14 厘米。总之,ZnONPs 是一种可用于抑制马铃薯最常见真菌病害的优良制剂。
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引用次数: 0
Modeling of the thermoforming process of paperboard composites for packaging 包装用纸板复合材料热成型工艺建模
Pub Date : 2024-02-09 DOI: 10.15376/biores.19.2.2120-2134
Moaaz Safwa, Hemantha Kumar Yeddu, Ville Leminen
The quest to reduce global plastic consumption has led to the emergence of biodegradable fiber-based composites as a promising sustainable replacement to conventional plastics in the food packaging industry. As the packaging sector is shifting more towards fiber-centric materials, thermoforming techniques for the 3D forming of the fiber-based materials, especially using complex mold designs, should be thoroughly researched to replace the conventional plastics in the industry. Finite element analysis of the deformation behavior of the paperboard during the thermoforming process and the factors that trigger the fracture of the composite layers were studied in the present work. The results show that 90° fiber orientation, 0.3 mm sheet thicknesses, and specific mold geometries can result in better forming results, thereby maximizing the potential of fiber-based materials in thermoforming.
为减少全球塑料消耗,可生物降解纤维基复合材料应运而生,有望成为食品包装行业传统塑料的可持续替代品。由于包装行业正在更多地转向以纤维为中心的材料,因此应深入研究用于纤维材料三维成型的热成型技术,特别是使用复杂模具设计的技术,以取代行业中的传统塑料。本研究对纸板在热成型过程中的变形行为以及引发复合材料层断裂的因素进行了有限元分析。研究结果表明,90° 纤维取向、0.3 毫米的纸板厚度和特定的模具几何形状可获得更好的成型效果,从而最大限度地发挥纤维基材料在热成型中的潜力。
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引用次数: 0
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