This study presents multi-year (2016–2022) results on the spatial and temporal distribution of dissolved organic carbon (DOC) along the eastern Adriatic coast, as well as total organic carbon (TOC) concentrations in surface sediments at the same coastal and transitional stations. Based on DOC concentration thresholds for oligotrophic (<1.440 mg/L), mesotrophic (1.800–2.500 mg/L), and eutrophic (>2.500 mg/L) conditions, the majority of coastal waters along the eastern Adriatic can be classified as oligotrophic.
Episodic mesotrophic to eutrophic conditions were observed primarily during summer and autumn in both surface and bottom layers at specific locations, including the Gulf of Rijeka (including the port of Rijeka), parts of Kvarner Bay (Bay of Bakar), the Port of Pula, and the Lim Channel in the northern Adriatic (NA), as well as Brač–Split Channel, Kaštela Bay, and Pašman–Zadar Channel in the middle Adriatic (MA). Transitional waters of the rivers Rječina, Mirna, Raša (NA), and Krka (MA) also exhibited episodic mesotrophic–eutrophic conditions. According to monitoring data, the Gulf of Rijeka shifted from a “very good” to a “good” trophic status in 2022.
Elevated sediment TOC (>1.5 %) was generally observed at stations where DOC concentrations in the water column were high, including Brač–Split Channel, and the rivers Cetina and Jadro (MA), as well as Raša, Mirna, and Dragonja (NA). The highest sediment TOC (6.3 %) was recorded in the Bay of Bakar and the Port of Pula (NA), reflecting eutrophic conditions in the overlying water column. An exception was observed at station FP-P5b Ploče/Neretva (SA), where relatively high sediment TOC (up to 4.0 %) was recorded in all monitored years, despite DOC concentrations in the water column remaining within oligotrophic levels (≤1.44 mg/L). In light of the continuous intensification of anthropogenic pressures (tourism, maritime traffic, aquaculture and agriculture), these regions are likely to be highly susceptible to ecological degradation under future climate scenarios, underscoring the need to prioritize them in coastal management plans and long-term monitoring initiatives.
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