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Enhanced denitrification by graphene oxide–modified cathode for the secondary effluent of wastewater treatment plants in three-dimensional biofilm electrode reactors 在三维生物膜电极反应器中利用氧化石墨烯改性阴极增强污水处理厂二级出水的脱硝效果
Pub Date : 2024-06-03 DOI: 10.2166/wst.2024.179
Ying Xue, Chaojie Zhang, Sibo Li, Qi Zhou, Xuefei Zhou, Yalei Zhang
In this study, a novel three-dimensional biofilm electrode reactor (3D-BER) with a graphene oxide (GO)–modified cathode was developed to enhance the denitrification performance of secondary effluent from wastewater treatment plants (SEWTPs). The effects of different HRTs and currents on the 3D-BER were explored. The results indicated that at the optimal HRT of 4 h and current of 350 mA/m2, the 3D-BER with GO-modified cathode had a higher denitrification rate (2.40 ± 0.1 mg TN/L/h) and less accumulation of intermediate products, especially with 3.34% TN molar conversion to N2O. The GO-modified cathode offered a large biocompatible specific surface area and enhanced the conductivity, which favored microbial growth and increased electron transfer efficiency and extracellular enzyme activities. Moreover, the activity of nitrite reductase increased more than that of nitrate reductase to accelerate nitrite reduction, thus facilitating the denitrification process. The proposed 3D-BER provided an effective solution to elevate tertiary denitrification in the SEWTP.
本研究开发了一种新型三维生物膜电极反应器(3D-BER),该反应器采用氧化石墨烯(GO)改性阴极,用于提高污水处理厂(SEWTPs)二级出水的脱硝性能。研究人员探讨了不同的 HRT 和电流对 3D-BER 的影响。结果表明,当最佳 HRT 为 4 小时、电流为 350 mA/m2 时,带有 GO 改性阴极的 3D-BER 具有更高的反硝化率(2.40 ± 0.1 mg TN/L/h)和更少的中间产物积累,尤其是在 TN 摩尔转化为 N2O 的转化率为 3.34% 时。GO 修饰的阴极具有较大的生物相容性比表面积,并增强了导电性,有利于微生物的生长,提高了电子传递效率和细胞外酶活性。此外,亚硝酸盐还原酶的活性比硝酸盐还原酶的活性更高,从而加速了亚硝酸盐的还原,促进了反硝化过程。拟议的 3D-BER 为提高污水处理厂的三级反硝化提供了有效的解决方案。
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引用次数: 0
Flow rate influence on sediment depth estimation in sewers using temperature sensors 流速对使用温度传感器估算下水道沉积深度的影响
Pub Date : 2024-06-03 DOI: 10.2166/wst.2024.193
M. Regueiro-Picallo, Alma Schellart, Henriette Jensen, Jeroen Langeveld, M. Viklander, Lian Lundy
Enhancing sediment accumulation monitoring techniques in sewers will enable a better understanding of the build-up processes to develop improved cleaning strategies. Thermal sensors provide a solution to sediment depth estimation by passively monitoring temperature fluctuations in the wastewater and sediment beds, which allows evaluation of the heat-transfer processes in sewer pipes. This study analyses the influence of the flow conditions on heat-transfer processes at the water–sediment interface during dry weather flow conditions. For this purpose, an experimental campaign was performed by establishing different flow, temperature patterns, and sediment depth conditions in an annular flume, which ensured stable flow and room-temperature conditions. Numerical simulations were also performed to assess the impact of flow conditions on the relationships between sediment depth and harmonic parameters derived from wastewater and sediment-bed temperature patterns. Results show that heat transfer between water and sediment occurred instantaneously for velocities greater than 0.1 m/s, and that sediment depth estimations using temperature-based systems were barely sensitive to velocities between 0.1 and 0.4 m/s. A depth estimation accuracy of ±7 mm was achieved. This confirms the ability of using temperature sensors to monitor sediment build-up in sewers under dry weather conditions, without the need for flow monitoring.
加强下水道沉积物积聚监测技术将有助于更好地了解沉积物的积聚过程,从而制定更好的清洁策略。热传感器通过被动监测废水和沉积床中的温度波动,为沉积物深度估算提供了解决方案,从而可以评估下水管道中的热传导过程。本研究分析了旱季水流条件对水-沉积物界面传热过程的影响。为此,我们在环形水槽中建立了不同的水流、温度模式和沉积深度条件,以确保稳定的水流和室温条件。此外,还进行了数值模拟,以评估水流条件对沉积深度与根据废水和沉积床温度模式得出的谐波参数之间关系的影响。结果表明,当流速大于 0.1 米/秒时,水与沉积物之间的热量传递是瞬时发生的,使用基于温度的系统估算沉积物深度对 0.1 至 0.4 米/秒之间的流速几乎不敏感。深度估计精度达到 ±7 毫米。这证实了在干燥天气条件下使用温度传感器监测下水道沉积物堆积情况的能力,而无需进行流量监测。
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引用次数: 0
Further treatment of coking wastewater treated in A2O-MBR by the nanofiltration-powder activated carbon hybrid system 纳滤-粉末活性炭混合系统进一步处理 A2O-MBR 处理的焦化废水
Pub Date : 2024-03-20 DOI: 10.2166/wst.2024.091
Elif İnce, M. Ince, Furkan Durmaz, Handenur Yasar, Yasin Abdullah Uslu
Anoxic–oxic membrane bioreactor (A2O-MBR), one of the biological systems requently used for the treatment of coking wastewater, increased under the influence of the growing iron and steel industry; however it cannot meet the discharge standards set by the Ministry of Environment, Urbanization and Climate Change of the Republic of Türkiye (CSB) due to recalcitrant pollutants in the wastewater. Advanced treatment of coking wastewater treated in A2O-MBR to meet the standards of the Ministry; nanofiltration (NF) (two different membranes and different pressures), powder activated carbon-microfiltration (PAC-MF), and PAC-NF (two different membranes and five different PAC concentrations) were investigated. In addition to the parameters determined by the Ministry, other parameters (ammonium, thiocyanate (SCN−), hydrogen cyanide (HCN), dissolved organic carbon (DOC), dissolved inorganic carbon (DIC), color) were also investigated to evaluate the performance of flux and treatment efficiency of the hybrid process. According to the results, chemical oxygen demand (COD) in the NF process, COD, and total cyanide (T-CN) in the PAC-MF process could not meet the discharge standards. In the PAC-NF hybrid system, XN45 met the discharge standards in all parameters (COD = 96 ± 1.88 mg/L, T-CN = <0.02 mg/L, phenol = <0.05 mg/L), with a 78% recovery rate at 0.5 g/L PAC concentration.
缺氧-缺氧膜生物反应器(A2O-MBR)是处理焦化废水所需的生物系统之一,在钢铁工业不断发展的影响下,该系统的使用量有所增加;然而,由于废水中存在难降解的污染物,该系统无法达到土耳其共和国环境、城市化和气候变化部(CSB)规定的排放标准。为使焦化废水经 A2O-MBR 高级处理后达到该部的标准,研究了纳滤(NF)(两种不同的膜和不同的压力)、粉末活性炭-微滤(PAC-MF)和 PAC-NF(两种不同的膜和五种不同的 PAC 浓度)。除了该部确定的参数外,还调查了其他参数(氨、硫氰酸盐(SCN-)、氰化氢(HCN)、溶解有机碳(DOC)、溶解无机碳(DIC)、色度),以评估混合工艺的通量性能和处理效率。结果表明,NF 工艺中的化学需氧量 (COD)、PAC-MF 工艺中的 COD 和总氰化物 (T-CN) 均未达到排放标准。在 PAC-NF 混合系统中,XN45 的所有参数(COD = 96 ± 1.88 mg/L、T-CN = <0.02 mg/L、酚 = <0.05 mg/L)均达到排放标准,在 PAC 浓度为 0.5 g/L 时,回收率为 78%。
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引用次数: 0
Solar desalination system for fresh water production performance estimation in net-zero energy consumption building: a comparative study on various machine learning models 用于净零能耗建筑淡水生产的太阳能海水淡化系统性能评估:各种机器学习模型的比较研究
Pub Date : 2024-03-20 DOI: 10.2166/wst.2024.092
A. Alhamami, Emmanuel Falude, Ahmed Osman Ibrahim, Y. Dodo, Okpakhalu Livingston Daniel, Farruh Atamurotov
This study employs diverse machine learning models, including classic artificial neural network (ANN), hybrid ANN models, and the imperialist competitive algorithm and emotional artificial neural network (EANN), to predict crucial parameters such as fresh water production and vapor temperatures. Evaluation metrics reveal the integrated ANN-ICA model outperforms the classic ANN, achieving a remarkable 20% reduction in mean squared error (MSE). The emotional artificial neural network (EANN) demonstrates superior accuracy, attaining an impressive 99% coefficient of determination (R2) in predicting freshwater production and vapor temperatures. The comprehensive comparative analysis extends to environmental assessments, displaying the solar desalination system's compatibility with renewable energy sources. Results highlight the potential for the proposed system to conserve water resources and reduce environmental impact, with a substantial decrease in total dissolved solids (TDS) from over 6,000 ppm to below 50 ppm. The findings underscore the efficacy of machine learning models in optimizing solar-driven desalination systems, providing valuable insights into their capabilities for addressing water scarcity challenges and contributing to the global shift toward sustainable and environmentally friendly water production methods.
本研究采用了多种机器学习模型,包括经典人工神经网络(ANN)、混合ANN模型以及帝国主义竞争算法和情感人工神经网络(EANN),来预测淡水产量和水汽温度等关键参数。评估指标显示,综合 ANN-ICA 模型优于传统 ANN,显著降低了 20% 的均方误差 (MSE)。情感人工神经网络(EANN)在预测淡水产量和水蒸气温度方面表现出更高的准确性,达到了令人印象深刻的 99% 的决定系数 (R2)。综合比较分析扩展到环境评估,显示了太阳能海水淡化系统与可再生能源的兼容性。结果凸显了拟议系统在节约水资源和减少环境影响方面的潜力,总溶解固体(TDS)从 6,000 ppm 以上大幅降至 50 ppm 以下。研究结果凸显了机器学习模型在优化太阳能驱动的海水淡化系统方面的功效,为了解这些系统在应对水资源短缺挑战方面的能力提供了宝贵的见解,并有助于全球向可持续的环保型水生产方法转变。
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引用次数: 0
Algal-bacterial shortcut nitrogen removal model with seasonal light variations 具有季节性光照变化的藻类-细菌捷径脱氮模型
Pub Date : 2024-03-20 DOI: 10.2166/wst.2024.090
Sahand Iman Shayan, Steve Youssef, P. van der Steen, Qiong Zhang, S. Ergas
The algal–bacterial shortcut nitrogen removal (ABSNR) process can be used to treat high ammonia strength wastewaters without external aeration. However, prior algal–bacterial SNR studies have been conducted under fixed light/dark periods that were not representative of natural light conditions. In this study, laboratory-scale photo-sequencing batch reactors (PSBRs) were used to treat anaerobic digester sidestream under varying light intensities that mimicked summer and winter conditions in Tampa, FL (USA). A dynamic mathematical model was developed for the ABSNR process, which was calibrated and validated using data sets from the laboratory PSBRs. The model elucidated the dynamics of algal and bacterial biomass growth under natural illumination conditions as well as transformation processes for nitrogen species, oxygen, organic and inorganic carbon. A full-scale PSBR with a 1.2 m depth, a 6-day hydraulic retention time (HRT) and a 10-day solids retention time (SRT) was simulated for treatment of anaerobic digester sidestream. The full-scale PSBR could achieve >90% ammonia removal, significantly reducing the nitrogen load to the mainstream wastewater treatment plant. The dynamic simulation showed that ABSNR process can help wastewater treatment facilities meet stringent nitrogen removal standards with low energy inputs.
藻类-细菌短程脱氮(ABSNR)工艺可用于处理高氨氮废水,而无需外部曝气。然而,之前的藻类-细菌短程脱氮研究都是在固定的光照/黑暗时间段内进行的,并不能代表自然光照条件。在本研究中,实验室规模的光序批式反应器(PSBRs)被用来处理厌氧消化池的侧流,光照强度的变化模拟了美国佛罗里达州坦帕市夏季和冬季的光照条件。针对 ABSNR 过程开发了一个动态数学模型,并利用实验室 PSBR 的数据集对该模型进行了校准和验证。该模型阐明了自然光照条件下藻类和细菌生物量的动态生长过程,以及氮物种、氧气、有机碳和无机碳的转化过程。模拟了一个深度为 1.2 米、水力停留时间(HRT)为 6 天、固体停留时间(SRT)为 10 天的全规模 PSBR,用于处理厌氧消化池的侧流。全规模 PSBR 的氨氮去除率大于 90%,大大降低了主流污水处理厂的氮负荷。动态模拟结果表明,ABSNR 工艺可以帮助污水处理设施以较低的能源投入达到严格的脱氮标准。
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引用次数: 0
Withdrawn: Emerging progress of carbon nanomaterials in wastewater treatment: synthesis and utilization 撤回:碳纳米材料在废水处理中的新进展:合成与利用
Pub Date : 2024-03-20 DOI: 10.2166/wst.2024.085
Yuansha Xie, Wu Chen, Jie Dai
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引用次数: 0
Influence and mechanism of solids on the air pressure fluctuations on the building drainage system 固体物质对建筑排水系统气压波动的影响和机理
Pub Date : 2024-03-20 DOI: 10.2166/wst.2024.088
Ping Xu, Ke Wang, Xue Fu, Zhuangzhuang Liu, Yilin Song
The conventional building drainage system was constructed based on the theory of two-phase flow involving water and air. However, the drainage system contained a more intricate three-phase flow, encompassing water, air, and solids, which was relatively overlooked in research. This study addressed the impact of solids on pressure fluctuations, air flow rates, and hydraulic jump fullness within the drainage system, considering three factors: the mass factor, cross-section factor, and viscosity. The investigation was conducted within a single-stack system using both experimental methods and CFD simulations. The findings revealed a positive correlation between both positive and negative pressures and above three factors. The mass factor and the cross-section factor had a more significant impact on the negative pressure of the system. The maximum growth rates of negative pressure extremes under different mass and cross-section factors reached 7.72 and 16.52%, respectively. In contrast, the viscosity of fecal sludge had a slightly higher effect on the positive pressure fluctuation of the drainage system, with the maximum growth rate of positive pressure extremes at 3.41%.
传统的建筑排水系统是根据水和空气两相流动的理论构建的。然而,排水系统包含更为复杂的三相流,包括水、空气和固体,这一点在研究中相对被忽视。本研究探讨了固体对排水系统内压力波动、空气流速和水力跃层饱满度的影响,考虑了三个因素:质量因素、横截面因素和粘度。研究采用实验方法和 CFD 模拟在单层系统内进行。研究结果表明,正压和负压与上述三个因素之间存在正相关。质量因子和横截面因子对系统负压的影响更为显著。不同质量系数和截面系数下负压极值的最大增长率分别达到 7.72% 和 16.52%。相比之下,粪便污泥的粘度对排水系统正压波动的影响稍大,正压极值的最大增长率为 3.41%。
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引用次数: 0
Using unsupervised learning to classify inlet water for more stable design of water reuse in industrial parks 利用无监督学习对进水进行分类,以更稳定地设计工业园区的中水回用系统
Pub Date : 2024-03-19 DOI: 10.2166/wst.2024.087
Kan Chen, Xiaofei Shi, Zhihao Zhang, Shijun Chen, Ji Ma, Tong Zheng, Leonardo Alfonso
The water reuse facilities of industrial parks face the challenge of managing a growing variety of wastewater sources as their inlet water. Typically, this clustering outcome is designed by engineers with extensive expertise. This paper presents an innovative application of unsupervised learning methods to classify inlet water in Chinese water reuse stations, aiming to reduce reliance on engineer experience. The concept of ‘water quality distance’ was incorporated into three unsupervised learning clustering algorithms (K-means, DBSCAN, and AGNES), which were validated through six case studies. Of the six cases, three were employed to illustrate the feasibility of the unsupervised learning clustering algorithm. The results indicated that the clustering algorithm exhibited greater stability and excellence compared to both artificial clustering and ChatGPT-based clustering. The remaining three cases were utilized to showcase the reliability of the three clustering algorithms. The findings revealed that the AGNES algorithm demonstrated superior potential application ability. The average purity in six cases of K-means, DBSCAN, and AGNES were 0.947, 0.852, and 0.955, respectively.
工业园区的中水回用设施面临着管理越来越多的废水源的挑战。通常情况下,这种聚类结果是由具有丰富专业知识的工程师设计的。本文介绍了无监督学习方法在中国中水回用站进水分类中的创新应用,旨在减少对工程师经验的依赖。本文将 "水质距离 "的概念纳入三种无监督学习聚类算法(K-means、DBSCAN 和 AGNES),并通过六个案例研究对这些算法进行了验证。在这六个案例中,有三个案例用于说明无监督学习聚类算法的可行性。结果表明,与人工聚类和基于 ChatGPT 的聚类相比,该聚类算法表现出更高的稳定性和卓越性。其余三个案例用于展示三种聚类算法的可靠性。研究结果表明,AGNES 算法表现出了卓越的潜在应用能力。在六个案例中,K-means、DBSCAN 和 AGNES 的平均纯度分别为 0.947、0.852 和 0.955。
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引用次数: 0
Valorization of fat balls and primary scum from wastewater treatment: a promising renewable lipid feedstock for biodiesel production 废水处理产生的脂肪球和初级浮渣的价值化:一种用于生产生物柴油的前景广阔的可再生脂质原料
Pub Date : 2024-03-19 DOI: 10.2166/wst.2024.089
Febrian Rizkianto, K. Oshita, Masaki Takaoka
We investigated the potential of waste materials from wastewater treatment plants (WWTPs) to serve as an alternative lipid feedstock for biodiesel production. The average lipid recoveries from fat balls (46.4%) and primary scum (49.5–54.5%) were higher than the lipid recovery of primary sludge (15.8–16.4%). The yield of biodiesel produced from the extracted lipids ranged from 5.7 to 20.1%. There were considerable site- and season-dependent variations in the characteristics of the lipid waste materials. Radiocarbon analysis indicated the presence of fossil-derived carbon (26.0–42.0%) in the biodiesel obtained from wastewater lipids. Finally, we estimated the potential for biodiesel production from WWTP-derived lipids; about 9,053.0 metric tons of biodiesel per year could be produced from fat balls and primary scum in Japan, potentially satisfying 32% of Japan's current biodiesel demand. The results indicate that lipid-rich materials from WWTPs represent a valuable alternative feedstock for biodiesel production.
我们研究了污水处理厂(WWTPs)的废料作为生物柴油生产的替代脂质原料的潜力。脂肪球(46.4%)和初级浮渣(49.5%-54.5%)的平均脂质回收率高于初级污泥(15.8%-16.4%)的脂质回收率。从提取的脂质中生产的生物柴油产量在 5.7% 到 20.1% 之间。脂质废料的特性与地点和季节有很大的关系。放射性碳分析表明,从废脂中提取的生物柴油中含有化石衍生碳(26.0-42.0%)。最后,我们估算了利用污水处理厂产生的脂类生产生物柴油的潜力;在日本,每年可利用脂肪球和原生浮渣生产约 9053.0 公吨生物柴油,可满足日本目前 32% 的生物柴油需求。研究结果表明,污水处理厂中富含脂质的材料是生物柴油生产的重要替代原料。
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引用次数: 0
A comparative study of satellite altimetry-based and DEM-based methods for estimating lake water volume changes 基于卫星测高法和基于 DEM 法估算湖泊水量变化的比较研究
Pub Date : 2024-03-19 DOI: 10.2166/wst.2024.086
Haotian Li, Jun Chen, Liguo Cao, Wei Liu, Zheng Duan
This study compared two different methods, the satellite altimetry-based and DEM (digital elevation model)-based, for estimating lake water volume changes. We focused on 34 lakes in China as the testing sites to compare the two methods for lake water volume changes from 2005 to 2020. The satellite altimetry-based method used water levels provided by the DAHITI (Database for Hydrological Time Series of Inland Waters) data and surface areas derived from Landsat imagery. The DEM-based method used the SRTM DEM data in combination with Landsat-derived lake extents. Our results showed a high degree of consistency in lake water volume changes estimated between the two methods (R2 < 0.90), but each method has its limitations. In terms of temporal coverage, the satellite altimetry-based method with the DAHITI data is limited by missing water level data in certain periods. The performance of the DEM-based method in extracting lake shore boundaries in regions with flat terrains (slope <1.5°) is not satisfactory. The DEM-based method has complete regional applicability (100%) in the Tibetan Plateau (TP) Lake Region, yet its effectiveness drops significantly in the Xinjiang and Eastern China Plain Lake Regions, with applicability rates of 50 and 40%, respectively.
本研究比较了基于卫星测高和基于 DEM(数字高程模型)的两种估算湖泊水量变化的不同方法。我们以中国的 34 个湖泊为测试点,比较了这两种方法对 2005 年至 2020 年湖泊水量变化的影响。基于卫星测高法的方法使用了由 DAHITI(内陆水域水文时间序列数据库)数据提供的水位和大地卫星图像得出的湖面面积。基于 DEM 的方法使用了 SRTM DEM 数据和 Landsat 导出的湖泊面积。结果表明,两种方法估算的湖泊水量变化高度一致(R2 < 0.90),但每种方法都有其局限性。就时间覆盖范围而言,基于卫星测高法的 DAHITI 数据因某些时段的水位数据缺失而受到限制。基于 DEM 的方法在提取地形平坦地区(坡度小于 1.5°)的湖岸边界时性能不尽人意。基于 DEM 的方法在青藏高原(TP)湖区具有完全的区域适用性(100%),但在新疆和华东平原湖区的有效性明显下降,适用率分别为 50%和 40%。
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引用次数: 0
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Water Science &amp; Technology
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