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Effect of sintering temperature on the fabrication of porous titanium by spark plasma sintering for environmental applications 烧结温度对环境用火花等离子烧结制备多孔钛的影响
Pub Date : 2025-11-01 DOI: 10.1088/1755-1315/1565/1/012013
Hao Van Pham, Tam Thanh Thi Dam, Trang Thuy Thi Nguyen, Viet Huy Nguyen, Thang Duc Nguyen, Vuong Hung Pham, Khanh Quoc Dang
Abstract Porous Titanium (Ti) is a leading material applied in the maritime sector due to its durability, high stability, and resistance to seawater corrosion. In this study, highly porous Ti was fabricated using the spark plasma sintering (SPS) process with NaCl as a pore-forming agent. The effects of sintering temperature on the material’s properties were systematically investigated. All samples were sintered under a pressing pressure of 40 MPa for 10 minutes, with sintering temperatures varying from 575 ºC to 675 ºC and a heating rate of 100 ºC /min in a vacuum. The as-sintered samples were characterized for porosity, microstructure, phase composition, elemental distribution, and compressive strength. The results revealed that pore size and porosity gradually decreased as the sintering temperature increased. The sample, sintered at 40 MPa and 575 ºC, demonstrated a high porosity exceeding 60%. The pore size distribution was predominantly within the 50-150 µm range, and the material achieved a compressive strength of approximately 185 MPa. This combination of parameters, along with a uniform, interconnected pore network, provides high mechanical stability, resistance to strong vibrations, and exceptional corrosion resistance. These characteristics make the material a highly promising candidate for filtration applications within Ballast Water Management Systems (BWMS). The structure’s ability to withstand high pressure and minimize deformation enhances its efficacy, allowing it to efficiently filter out microorganisms larger than 150 µm, thereby improving the overall performance of ballast water treatment.
多孔钛(Ti)因其耐久性、高稳定性和耐海水腐蚀而成为海事领域应用的主要材料。本研究以NaCl为成孔剂,采用火花等离子烧结(SPS)法制备了高孔钛。系统地研究了烧结温度对材料性能的影响。在真空条件下,烧结温度为575℃~ 675℃,升温速率为100℃/min,压力为40 MPa,烧结时间为10 min。对烧结试样的孔隙率、微观结构、相组成、元素分布和抗压强度进行了表征。结果表明,随着烧结温度的升高,孔隙率和孔径逐渐减小。试样在40mpa和575℃条件下烧结,孔隙率超过60%。孔径分布主要在50 ~ 150µm范围内,材料抗压强度约为185 MPa。这些参数的组合,以及均匀的、相互连接的孔隙网络,提供了高的机械稳定性、抗强烈振动和卓越的耐腐蚀性。这些特性使该材料成为压载水管理系统(BWMS)中过滤应用的非常有前途的候选者。该结构能够承受高压并最大限度地减少变形,从而提高了其效率,使其能够有效过滤出大于150µm的微生物,从而提高压载水处理的整体性能。
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引用次数: 0
Immunohistochemical Investigation of Prostaglandin E2 During the Healing of Experimentally Gastric Ulceration in Rats 前列腺素E2在大鼠实验性胃溃疡愈合过程中的免疫组化研究
Pub Date : 2025-02-01 DOI: 10.1088/1755-1315/1449/1/012009
Jenan M. Al-Kawaz, Fakir magtoof Al-zubaidy, Hana Alharbi
Abstract The current study attempt to identify the healing activities of esomeprazole, curcumin, chitosan as well as mixture from curcumin and chitosan on gastric ulceration induced by ethanol in female rats. this study included 30 rats, their average weight ranged between (195.600-198.600 gm) separated into 2 control groups and 4 treated groups each group contained 5 rats. all groups treated for 5 days after last dose from ethanol. After the experiment has been over, the body was weighed before and after the end of the experiment. The therapeutic effects of esomeprazole, chitosan, curcumin and mixture were identified by comparing the volume and pH of gastric juice, ulcer index as well as curative index. The results of the current study showed that percentage change in body weight means decreased significantly in treated group with curcumin compared to the positive control group. While in the case of the esomeprazole, chitosan and mixture there was no significant change compared with the positive control group. In addition, the results indicated a significant decreased in the ulcer index values and volume of gastric juice in esomeprazole, curcumin, chitosan and mixture in comparison with the positive control group. By comparing the immunohistochemical investigation of the PGE2 expressions in gastric tissue, the development of gastric ulcers was analyzed.
摘要本研究旨在探讨艾索美拉唑、姜黄素、壳聚糖及姜黄素壳聚糖混合物对乙醇诱导的雌性大鼠胃溃疡的愈合作用。实验选用30只平均体重为(195.600 ~ 198.600 gm)的大鼠,随机分为2个对照组和4个治疗组,每组5只。各组均在末次给药后给药5 d。实验结束后,在实验结束前后对实验体进行称重。通过比较胃液体积、pH值、溃疡指数和治愈指数,确定埃索美拉唑、壳聚糖、姜黄素及其合剂的治疗效果。目前的研究结果表明,姜黄素治疗组与阳性对照组相比,体重变化百分比显著下降。而在埃索美拉唑、壳聚糖和混合物的情况下,与阳性对照组相比,无显著变化。此外,与阳性对照组相比,埃索美拉唑、姜黄素、壳聚糖和混合物的溃疡指数值和胃液体积均显著降低。通过比较胃组织中PGE2表达的免疫组化研究,分析胃溃疡的发生发展。
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引用次数: 0
Green stock investment preferences among adult investors in east Malaysia 马来西亚东部成年投资者的绿色股票投资偏好
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012086
H. C. Eaw, I. Y. Loebiantoro, K. P. Jap, E. S. A. Shakur, A. Voon
In light of increasing concerns about environmental issues and a heightened focus on green stocks prompted by global warming and the COVID-19 pandemic, this research study aims to analyse the determinants influencing the investment intentions of working adults in Sarawak, Malaysia, regarding green stocks. This study emphasises comprehending how factors such as attitudes, social influences, affect, and perceived customer effectiveness impact the investment intentions of working adults in green stocks. This research adopts a quantitative methodology, employing hypothesis testing to analyse data obtained from 150 respondents in East Malaysia, who were selected using a convenience sampling technique and responded through a Google Form. Data analysis was conducted using SPSS version 27, with a comprehensive assessment of variable validity and reliability through various tests. Six hypotheses were formulated to establish a significant correlation between the dependent variable intention to invest in green stocks and the independent variables’ social factors, attitude, affect, perceived customer effectiveness, and financial literacy. Four independent variables significantly influence the dependent variable when investing in green stocks. Further, perceived customer effectiveness directly impacts investors’ intentions. Thus, financial literacy indirectly influences the intention to invest in green stocks through its mediation with attitude. The findings result in practical implications related to the determinants of green stock investment intention among working-age adults in Sarawak. To begin with, this study contributes to the body of knowledge concerning green investments by investigating the factors influencing the Sarawak residents’ intention to invest in green stocks, utilising the theory of interpersonal behaviour. Previous research has predominantly relied on the theory of reasoned action and the “theory of planned behaviour” to elucidate the factors impacting green investment intention. Therefore, this study’s adoption of the theory of interpersonal behaviour offers a special perspective and potential reference for future researchers. The knowledge gained from this study is pertinent to a broad spectrum of stakeholders, encompassing policymakers, government, professionals, and educators. It offers valuable insights that can shape decision-making and the development of strategic initiatives within green investments.
鉴于人们对环境问题的日益关注,以及全球变暖和 COVID-19 大流行所引发的对绿色股票的高度关注,本研究旨在分析影响马来西亚沙捞越州在职成年人对绿色股票投资意向的决定因素。本研究强调理解诸如态度、社会影响、情感和感知到的客户有效性等因素如何影响在职成年人对绿色股票的投资意向。本研究采用定量方法,通过假设检验来分析从马来西亚东部 150 名受访者那里获得的数据,这些受访者是通过方便抽样技术选出的,并通过谷歌表格进行了回复。数据分析采用 SPSS 27 版本,并通过各种测试对变量的有效性和可靠性进行了全面评估。研究提出了六个假设,以确定因变量绿色股票投资意向与自变量社会因素、态度、情感、感知客户有效性和金融知识之间的显著相关性。在投资绿色股票时,四个自变量会对因变量产生重大影响。此外,感知到的客户有效性直接影响投资者的投资意向。因此,金融知识通过与态度的中介作用间接影响了投资绿色股票的意向。研究结果对砂拉越适龄成年人投资绿色股票意向的决定因素产生了实际影响。首先,本研究利用人际行为理论调查了影响砂拉越居民绿色股票投资意向的因素,为有关绿色投资的知识体系做出了贡献。以往的研究主要依靠 "理性行动理论 "和 "计划行为理论 "来阐明影响绿色投资意向的因素。因此,本研究采用的人际行为理论为未来的研究人员提供了一个特殊的视角和潜在的参考。本研究获得的知识与政策制定者、政府、专业人士和教育工作者等广泛的利益相关者息息相关。它提供了宝贵的见解,可以影响绿色投资方面的决策和战略举措的制定。
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引用次数: 0
Evaluating Lean Combustion Cycle Stability and Emissions in Spark Ignition Engines with Gasoline, Ethanol, and Methanol Blends 评估使用汽油、乙醇和甲醇混合物的火花点火发动机的稀薄燃烧循环稳定性和排放情况
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012042
A. A. Agama, B. Sugiarto, Mokhtar, A. Kurniawan, A. S. Auzani, M. A. Wisnugraha, Z. B. Rahatwan, D. Prasetyo
Fuels for vehicles account for a large portion of the world’s total energy demand, which in turn leads to increased carbon emissions. Ethanol and methanol are a fuel with a simple carbon chain and OH- bonds. It has similar properties to gasoline, and ethanol can be made from the fermentation of plant carbohydrates, called bioethanol. The advantage of using bioethanol is that it contributes to carbon neutrality. This paper will investigate the use of three manually blended gasoline ethanol and methanol (GEM) fuels in a spark ignition engine to address cycle-to-cycle variation (CCV), knock potential, and emissions with lean blend conditions. In the experiments conducted, the air-fuel ratio was conditioned lean by utilizing an electronic control unit to adjust the injector spray duration. This experiment provides results that there is a potential for mild knocking on the use of alcohol fuel with lean fuel mixture conditions at engine speed 4000 RPM, while at engine speed 6000 RPM and 8000 RPM the use of GEM tends to be stable, but in the CCV results the increase in COV (coefficient of variation) value using GEM fuel tends to be more sloping, especially with the addition of more methanol. Emission results from the use of GEM produce top emission CO2 value obtained by the E5M15 mixture at λ=1.2 and an engine speed of 8000 RPM, with a value of 13.75% and then peak CO2 emissions at a value of λ = 1.2 whereas in the use of pure gasoline peak CO2 is at a value of λ = 1.1.
汽车燃料占世界能源需求总量的很大一部分,这反过来又导致了碳排放量的增加。乙醇和甲醇是一种具有简单碳链和 OH 键的燃料。它的性质与汽油相似,乙醇可由植物碳水化合物发酵制成,称为生物乙醇。使用生物乙醇的好处是有助于实现碳中和。本文将研究在火花点火发动机中使用三种手动混合的汽油乙醇和甲醇(GEM)燃料,以解决贫混合条件下的循环周期变化(CCV)、爆震可能性和排放问题。在实验中,通过使用电子控制装置调节喷油器喷油时间来调节空燃比。实验结果表明,在发动机转速为 4000 转/分时,使用酒精燃料和贫油混合燃料可能会产生轻微的爆震,而在发动机转速为 6000 转/分和 8000 转/分时,使用 GEM 燃料则趋于稳定,但在 CCV 结果中,使用 GEM 燃料的 COV(变异系数)值的增加趋于倾斜,特别是在添加更多甲醇时。使用 GEM 的排放结果显示,在 λ=1.2 和发动机转速为 8000 转/分时,E5M15 混合燃料的二氧化碳排放值最高,达到 13.75%,然后在 λ=1.2 时达到二氧化碳排放峰值,而使用纯汽油时,二氧化碳排放峰值为 λ=1.1。
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引用次数: 0
Enhancing efficiency in closed agricultural greenhouses: A data-driven predictive model for energy consumption 提高封闭式农业温室的效率:数据驱动的能耗预测模型
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012084
Ikhlas Ghiat, T. Al-Ansari
Predicting energy consumption in agricultural greenhouses is essential to effectively allocate resources, enhance plant growth, and minimize energy inefficiencies. Various factors affect the energy consumption inside the greenhouse including external climate conditions and internal microclimate. Proper understanding of these factors is crucial for maintaining an ideal growing environment and optimizing energy efficiency. This drives the need to investigate the interaction between these factors and greenhouse energy consumption, encompassing the energy needed for cooling and the supply of water and nutrients. This work aims at developing a dynamic model that predicts the total energy consumption of a closed agricultural greenhouse to improve microclimate control and energy efficiency. The study is conducted within a closed-loop agricultural greenhouse with no natural ventilation. Inside, the air is cooled and continuously circulated without being exchanged with ambient air through a heating, ventilation, and air conditioning (HVAC) system. The data-driven model encompasses external climate parameters such solar radiation, ambient temperature, and relative humidity; along with microclimate parameters such as internal temperature, humidity, and CO2 concentration to predict overall energy consumption. The study examines two machine learning models, deep neural networks (DNN) and extreme gradient boosting (XGBoost), for forecasting energy consumption, and assesses their performance using the coefficient of determination (R2), the root mean square error (RMSE), and the mean absolute error (MAE). Results reveal that the DNN model surpasses the XGBoost model, exhibiting a superior predictive performance with an R2 of 80.9%, RMSE of 171.1 kWh and MAE of 130.3 kWh. This study demonstrates its practicality in assisting with energy consumption analyses and identifying inefficient energy usage patterns within closed agricultural greenhouses.
预测农业温室的能耗对于有效分配资源、促进植物生长以及最大限度地降低能源效率至关重要。影响温室能耗的因素有很多,包括外部气候条件和内部小气候。正确理解这些因素对于保持理想的生长环境和优化能源效率至关重要。因此,有必要研究这些因素与温室能耗之间的相互作用,包括降温所需的能量以及水和养分的供应。这项工作旨在开发一个动态模型,预测封闭式农业温室的总能耗,以改善微气候控制和提高能效。研究在一个没有自然通风的封闭式农业温室内进行。在温室内部,空气通过加热、通风和空调(HVAC)系统进行冷却和持续循环,而不与环境空气交换。数据驱动模型包括外部气候参数,如太阳辐射、环境温度和相对湿度;以及微气候参数,如内部温度、湿度和二氧化碳浓度,以预测总体能耗。研究考察了两种预测能源消耗的机器学习模型:深度神经网络(DNN)和极端梯度提升(XGBoost),并使用决定系数(R2)、均方根误差(RMSE)和平均绝对误差(MAE)评估了它们的性能。结果显示,DNN 模型超过了 XGBoost 模型,表现出更优越的预测性能,R2 为 80.9%,RMSE 为 171.1 千瓦时,MAE 为 130.3 千瓦时。这项研究证明了 DNN 在协助能耗分析和识别封闭式农业温室内低效能源使用模式方面的实用性。
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引用次数: 0
Analysing type of plants for reducing noise pollution in climate change adaptation 分析在适应气候变化过程中减少噪音污染的植物类型
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012056
W. Hashim, S. M. Jamaludin, R. M. A. R. Mohamed, S. S. Gunasekaran, R. Thabit, H. Gohel
The noisier a region or city is, the faster the rate of global warming. Noise is not a substance. However, most sources of carbon dioxide and other greenhouse gases are also sources of noise; for example, busy highways in cities can occasionally see as many as 100 cars per hour. Planting trees to mitigate noise pollution has been identified as one of the most sustainable methods to employ, since plants may function as a buffer and absorb sounds. Several plant species were chosen to assess noise absorption based on parameters such as leaf thickness, breadth, surface area, and length. The initial goal of this study is to estimate the noise absorption on the selected flora native to the Malaysian environment, where the noise was measured using an in-house developed impedance tube to discover the effective acoustic characteristics of leaves. The investigation was then carried on by assessing the data on the correlation coefficient parameter in order to determine the link between noise absorption and leaf features. Because of the freshness and perishability of the materials, measurements were repeated twice. Only 100% and 50% vegetation quantity size were measured for 10 sample species during the initial data collection. According to the findings, half of the leaves’ features were connected with noise absorption. This might be owing to the freshness state, which cannot be maintained for an extended period of time. To acquire a better value, the experiment was repeated within the permissible freshness time. The findings are as predicted, with the maximum noise absorption and features correlation at 100% plant density including twigs. When the vegetation amount is lowered to 50%, this will progressively diminish. The notion is confirmed by the fact that a tube packed with thicker samples absorbs more noise. The correlation study identifies that each leaf has its unique capacity for noise absorption dependent on its properties and freshness level.
一个地区或城市越嘈杂,全球变暖的速度就越快。噪音不是一种物质。然而,大多数二氧化碳和其他温室气体的来源也是噪音的来源;例如,城市中繁忙的高速公路上偶尔会出现每小时多达 100 辆汽车的情况。种植树木来减轻噪音污染被认为是最可持续的方法之一,因为植物可以起到缓冲和吸收声音的作用。我们选择了几种植物,根据叶片厚度、宽度、表面积和长度等参数来评估噪音吸收能力。这项研究的最初目标是估算所选的马来西亚本土植物的噪音吸收能力,使用内部开发的阻抗管测量噪音,以发现叶子的有效声学特性。然后,通过评估相关系数参数数据进行调查,以确定噪音吸收与叶片特征之间的联系。由于材料的新鲜度和易腐性,测量重复了两次。在最初的数据收集过程中,只对 10 个样本物种的 100%和 50%植被数量大小进行了测量。结果显示,一半的叶片特征与噪声吸收有关。这可能是由于新鲜状态无法长时间保持。为了获得更好的数值,在允许的保鲜时间内重复了实验。实验结果与预测一致,当植物密度为 100%(包括树枝)时,噪声吸收和特征相关性最大。当植被数量降低到 50% 时,噪音吸收和特征相关性将逐渐减弱。装有较厚样本的试管能吸收更多噪声的事实也证实了这一观点。相关性研究表明,每片叶子都有其独特的噪音吸收能力,这取决于其特性和新鲜程度。
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引用次数: 0
Assessment of energy saving and CO2 emission mitigation of low-lift cooling in computer hardware manufacturing industry: A case study in Thailand 计算机硬件制造业低扬程冷却的节能和二氧化碳减排评估:泰国案例研究
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012062
J. Nizigiyimana, P. Chaiwiwatworakul
Released heat from production process contributes the largest proportion of cooling load in computer hardware manufacturing industry. According to traditional design practice, chiller plant produces chilled water at a temperature of 7°C to treat the entire load from the production process and from the comfort air-conditioning in buildings. However, the heat from the process is solely the sensible component where high-temperature chilled water (e.g., 15°C) can be used for the heat removal, the chillers equipped with low temperature-lift technology thus offer a great opportunity to improve the plant’s cooling performance. Under the critical global warming situation and the need of decarbonizing industry, this paper investigated the energy saving and CO2 emission mitigation potential of the low-lift technology by which the chiller plant of high-temperature chilled water (15°C) is dedicated for the production process cooling, and the traditional chiller plant of the low-temperature chilled water is used to serve the building air-conditioning. The study site was a large factory of computer hardware manufacturing in Thailand. Through detailed energy auditing, the cooling load profile of the production process was established, and it was used to design the low-lift chiller plant. The annual simulation results showed that in our study case the low-lift chiller plant together with variable motor speed control had 31.6% higher cooling performance than the traditional chiller plant. The plant could reduce the energy consumption by 5,550 MWhelec/year. As the CO2 emission of the grid power in Thailand was 0.47 kgCO2/kWh in 2023 and it was expected to reduce to 0.35 kgCO2/kWh in 2050, the CO2 emissions from implementing the low-lift cooling could be reduced by 49,400 TonCO2 over a course of the 20-year project lifetime. The study results encouraged the low-lift cooling technology as a practical energy efficiency measure in computer hardware manufacturing industry. To our knowledge, while past research focused on the low-lift cooling in building air-conditioning, the study was the first potential assessment project of the low-lift cooling as a deep decarbonization technology for the computer hardware manufacturing industry in Thailand.
生产过程中释放的热量在计算机硬件制造业的冷却负荷中所占比例最大。根据传统设计惯例,冷水机组生产的冷冻水温度为 7°C,用于处理来自生产过程和楼宇舒适空调的全部负荷。然而,生产过程中产生的热量仅仅是显热部分,而高温冷冻水(例如 15°C)可用于去除热量,因此,配备低温升技术的冷水机组为提高工厂的冷却性能提供了一个绝佳的机会。在全球变暖的严峻形势和工业去碳化的需要下,本文研究了低温升技术的节能和二氧化碳减排潜力,即高温冷冻水(15°C)冷水机组专用于生产工艺冷却,而传统的低温冷冻水冷水机组则用于建筑空调。研究地点是泰国的一家大型计算机硬件制造工厂。通过详细的能源审计,确定了生产过程的冷负荷曲线,并以此为基础设计了低扬程冷水机组。年度模拟结果表明,在我们的研究案例中,与传统冷水机组相比,低扬程冷水机组加上变频电机速度控制的冷却性能提高了 31.6%。该设备每年可减少 5,550 兆瓦电能消耗。由于 2023 年泰国电网电力的二氧化碳排放量为 0.47 kgCO2/kWh,预计到 2050 年将降至 0.35 kgCO2/kWh,因此在 20 年的项目生命周期内,采用低扬程冷却技术可减少 49,400 吨二氧化碳排放量。研究结果鼓励将低扬程冷却技术作为计算机硬件制造业的一项实用节能措施。据我们所知,过去的研究主要集中在建筑空调的低扬程冷却方面,而这项研究是泰国首个将低扬程冷却作为计算机硬件制造业深度脱碳技术的潜在评估项目。
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引用次数: 0
Thermal performance of the photovoltaic module with evaporative cooling ventilated cavity 带有蒸发冷却通风腔的光伏组件的热性能
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012061
Y H Liu, W. C. Yan, C J Yang, Y Zhang, C. W. He, X Cui, L W Jin
Energy is indispensable in modern life, and solar photovoltaic technology stands out for its substantial advantages. However, the current conversion rate remains suboptimal, ranging from 15% to 20%. Compounding this, a portion of solar energy undergoes conversion into thermal energy, resulting in an elevation of the PV (photovoltaic) module’s temperature and a subsequent reduction in electricity generation efficiency. In response to this challenge, a solution was conceived—a design featuring an evaporative cooling ventilated cavity crafted to alleviate the operating temperature of the photovoltaic module. This innovative system integrates a photovoltaic facade with an evaporative cooling ventilation cavity, encompassing crucial components such as solar photovoltaic panels, an evaporative cooling layer, and a ventilated cavity equipped with thermal regulation. An experimental system was meticulously developed. The results illuminate the system’s efficacy in temperature reduction: approximately 5°C for the PV back sheet, 5°C for the cavity back sheet, and 5.2°C inside the cavity. Furthermore, the system achieves a noteworthy average operating temperature reduction of about 14.1%, 20.2%, and 20.4%, respectively. These findings underscore the substantial impact of the evaporative cooling system on regulating and enhancing the thermal performance of PV modules.
能源在现代生活中不可或缺,而太阳能光伏技术因其巨大优势而脱颖而出。然而,目前的转换率仍不理想,在 15%至 20%之间。此外,部分太阳能会转化为热能,导致光伏组件温度升高,发电效率随之降低。为了应对这一挑战,我们构思出了一种解决方案--采用蒸发冷却通风腔设计,以降低光伏组件的工作温度。这一创新系统集成了光伏外墙和蒸发冷却通风腔,包括太阳能光伏板、蒸发冷却层和配备热调节功能的通风腔等关键部件。我们精心开发了一个实验系统。实验结果表明了该系统的降温效果:光伏背板降温约 5°C,空腔背板降温约 5°C,空腔内降温约 5.2°C。此外,该系统的平均工作温度分别降低了约 14.1%、20.2% 和 20.4%。这些发现强调了蒸发冷却系统对调节和提高光伏组件热性能的重大影响。
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引用次数: 0
Bio-oil production from the catalytic pyrolysis of raw and torrefied corn waste by using MgO and CaO catalysts 使用氧化镁和氧化钙催化剂催化热解生玉米废料和干玉米废料生产生物油
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012027
K. Thu, S. Fukuda, S. Krerkkaiwan
This research investigates the influence of torrefaction and catalytic pyrolysis of raw corn waste (RCW) to upgrade the quality of bio-oil. RCW was torrefied at 280°C for 16 mins to produce torrefied corn waste (TCW). Natural basic oxides (CaO and MgO) catalysts were selected because of inexpensive and high catalytic performance. Pyrolysis experiments were conducted in a bench-scaled bubbling fluidized bed reactor at 500°C. The effects of torrefaction and the presence of a catalyst on the pyrolysis product both yield and composition were investigated. The results from non-catalytic pyrolysis revealed that TCW pyrolysis gave 15 wt.% lower in oil yield, and about 6.8 wt.% lower in gas yield but the char yield was approximately 22 wt.% higher compared to the pyrolysis of RCW. Considering the effect of catalyst, the yield of bio-oil reduced slightly, while the yield of char and gas increased compared to non-catalytic pyrolysis for both RCW and TCW. The bio-oil composition derived from TCW pyrolysis contained more phenolic and aromatic compounds and significantly lower oxygenated compounds when compared to that of RCW pyrolysis. Moreover, with the presence of the catalysts, the bio-oil composition and HHVs of bio-oil was also improved.
本研究探讨了生玉米废料(RCW)的热解和催化热解对提高生物油质量的影响。将 RCW 在 280°C 高温下烘烤 16 分钟,生成烘烤玉米废料(TCW)。天然碱性氧化物(CaO 和 MgO)催化剂价格低廉,催化性能高,因此被选中。热解实验在 500°C 的台式鼓泡流化床反应器中进行。研究了热解产物的产量和成分受热分解和催化剂存在的影响。非催化热解的结果表明,与热解 RCW 相比,TCW 的产油量低 15 重量%,产气量低约 6.8 重量%,但产炭量高出约 22 重量%。考虑到催化剂的影响,与非催化热解相比,RCW 和 TCW 的生物油产率略有降低,而炭和气体产率则有所提高。与 RCW 高温分解相比,TCW 高温分解产生的生物油成分含有更多的酚类和芳香族化合物,含氧化合物则明显较少。此外,在催化剂的作用下,生物油的成分和 HHVs 也得到了改善。
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引用次数: 0
The determination of elements influencing successful collaboration factors in preventing oil spills during bunkering at port 确定影响在港口加油期间成功防止石油泄漏的合作因素
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012064
I. C. Ishak, I. Charles, M. K. Ramli, A. M. Arof, H. S. Salleh, A. S. N. Isha
This study is concerned with the factors that could concern the successful collaboration in preventing oil spills during bunkering operations. This study encompasses individual staff at port and bunkering companies in Sabah, Malaysia. The oil spill incidents from bunkering activities are possible to occur while the ships are moving. The primary causes of bunker activities that could lead to the oil spill are overflow, leak incidents, inadequate planning, and human error. This study aims to validate the factors of successful collaboration toward preventing oil spills during bunkering operations. This study utilized a Delphi questionnaire survey distributed to respondents with working experiences between two years and more than 10 years of working experience. The data has been accumulated from the related departments within the individual staff at Jabatan Pelabuhan dan Dermaga Sabah (JPDS) and Kota Kinabalu Port. This study applied an online Delphi questionnaire survey from the required purposive sampling. The Delphi questionnaire survey assembles information about respondents and the importance of and factors influencing successful collaboration by applying Likert scale point of 5 ranging from not important to extremely important. This study has included 59 respondents from JPDS and related bunkering companies and bunkering operators. The data have been analysed using SPSS analysis tools such as Cronbach alpha and Correlation analysis. The result revealed that the Cronbach alpha value shows a high value of 0.960. Meanwhile, the correlation coefficient (r) shows at 0.775. It has shown a positive and strong relationship between the importance of successful collaboration and the factors influencing successful collaboration to prevent oil spills during bunkering. The recommendation of this study could facilitate other port authorities to collaborate or coordinate with other sectors or companies in bunkering operations to gain a successful collaboration in preventing oil spills during bunkering activities. It is also anticipated to contribute to the deficiency of literature on the determination of elements influencing successful collaboration factors in preventing oil spills during bunkering at port.
本研究关注的是在加油作业期间成功合作防止石油泄漏的因素。研究对象包括马来西亚沙巴州港口和加油公司的员工。船舶在行驶过程中可能会发生加油活动导致的溢油事故。加油活动可能导致溢油的主要原因是溢出、泄漏事故、计划不当和人为错误。本研究旨在验证在加油操作过程中防止溢油的成功合作因素。本研究采用德尔菲问卷调查法,向工作经验在两年至十年以上的受访者发放问卷。这些数据来自于沙巴州船舶和港口管理局(Jabatan Pelabuhan dan Dermaga Sabah,JPDS)和亚庇港口的相关部门员工。本研究从所需的目的性抽样中采用了在线德尔菲问卷调查法。德尔菲问卷调查收集了受访者的相关信息,并通过从不重要到极其重要的 5 级李克特量表,对成功合作的重要性和影响因素进行了评估。这项研究包括了来自 JPDS 和相关加油公司及加油运营商的 59 名受访者。使用 SPSS 分析工具对数据进行了分析,如 Cronbach alpha 和相关分析。结果显示,Cronbach alpha 值高达 0.960。同时,相关系数(r)为 0.775。这表明,成功合作的重要性与影响成功合作的因素之间存在着积极而紧密的关系,以防止加油过程中的溢油事故。本研究的建议有助于其他港务局在加油作业中与其他部门或公司进行合作或协调,从而在防止加油活动中的溢油方面获得成功合作。预计本研究还将有助于弥补在确定影响成功合作的因素以防止港口加油期间溢油泄漏方面的文献不足。
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引用次数: 0
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IOP Conference Series: Earth and Environmental Science
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