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A method for fast and accurate prediction of wind turbine thrust coefficients using classical momentum theory and power curve 利用经典动量理论和功率曲线快速准确预测风力涡轮机推力系数的方法
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012021
V. Tai, Yong Chai Tan, L. K. Moey, Norzaura Abd Rahman, David Baglee, L. Saw
The planning and development of windfarms require accurate prediction of the thrust coefficient (cT ) of wind turbines, which significantly affects the downstream wake. Traditional methods, such as blade element momentum theory (BEMT), often necessitate detailed geometric information of wind turbines for cT computation, information that is not frequently available, especially in the early stages of windfarm planning. This paper aims to address this challenge by presenting a novel and efficient approach to predict cT for horizontal-axis wind turbines (HAWTs). The proposed method integrates classical momentum theory with power curve data to estimate the average axial induction factor (a), thereby enabling the calculation of cT without requiring detailed geometric information of HAWTs. The method was validated against thirty-five existing pitch-controlled HAWTs, with R2 values ranging from 0.9604 to 0.9989. This validation confirms the accuracy of the method, making it a viable alternative to traditional techniques that demand comprehensive wind turbine geometric details. The method has demonstrated both rapidity and precision in cT computation for turbine wake analysis, ensuring high levels of prediction accuracy and potentially lowering the barrier to entry for windfarm development. Unlike existing models predominantly focused on wind turbine power curves, cT modelling has largely been overlooked. This study makes a unique contribution to the field by proposing a novel method for cT prediction, thereby filling a critical gap in windfarm planning and development. However, while the study shows promising results, further research is warranted to explore its applicability in diverse windfarm scenarios and turbine configurations.
风力发电场的规划和开发需要对风力涡轮机的推力系数(cT)进行精确预测,因为推力系数对下游尾流有很大影响。传统方法(如叶片动量理论 (BEMT))通常需要风力涡轮机的详细几何信息来计算推力系数,而这些信息并不常见,尤其是在风场规划的早期阶段。本文旨在通过提出一种新颖高效的方法来预测水平轴风力涡轮机(HAWT)的 cT,从而应对这一挑战。所提出的方法将经典动量理论与功率曲线数据相结合,估算出平均轴向感应系数 (a),从而无需 HAWT 的详细几何信息即可计算 cT。该方法通过对 35 台现有变桨控制 HAWT 进行验证,R2 值在 0.9604 到 0.9989 之间。这一验证证实了该方法的准确性,使其成为需要全面风力涡轮机几何细节的传统技术的可行替代方法。该方法证明了涡轮机尾流分析 cT 计算的快速性和精确性,确保了高水平的预测精度,并有可能降低风电场开发的准入门槛。与主要关注风机功率曲线的现有模型不同,cT 建模在很大程度上被忽视了。本研究提出了一种新的 cT 预测方法,从而填补了风场规划和开发中的一个重要空白,为该领域做出了独特的贡献。不过,虽然研究结果很有希望,但仍需进一步研究,以探索其在不同风场场景和风机配置中的适用性。
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引用次数: 0
On application of molecular dynamics simulation for studying the effect of temperature and heating rate on HTL of biomass 应用分子动力学模拟研究温度和加热速率对生物质热液化的影响
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012051
Thuat T. Trinh, Khanh-Quang Tran
Hydrothermal liquefaction (HTL) of biomass has garnered increasing attention as a promising pathway for converting solid biomass to liquid biofuels and valuable chemical products. HTL involves processing of biomass in water at high-temperature and high-pressure conditions. The heating rate during this process plays a critical role in determining the yield and composition of the liquefied products. To probe the impact of heating rate, we develop a detailed atomistic model biomass by using cellulose as model compound and place it in a simulated HTL reactor. Our Reactive molecular dynamics simulations are capable of capturing the dynamic chemical reactions and structural changes during HTL. The effect of reaction temperature and heating rates on reaction pathways, product distributions, and reaction kinetics is rigorously analyzed. Our findings reveal that the reaction temperature and heating rate significantly influences the extent of cellulose degradation and the composition of bio-oil product.
生物质水热液化(HTL)作为一种将固体生物质转化为液态生物燃料和有价值化学产品的有效途径,已引起越来越多的关注。热液化涉及在高温高压条件下在水中处理生物质。在此过程中,加热速率对液化产品的产量和成分起着至关重要的作用。为了探究加热速率的影响,我们以纤维素为模型化合物,建立了详细的原子模型生物质,并将其置于模拟 HTL 反应器中。我们的反应分子动力学模拟能够捕捉 HTL 过程中的动态化学反应和结构变化。我们严格分析了反应温度和加热速率对反应路径、产物分布和反应动力学的影响。我们的研究结果表明,反应温度和加热速率对纤维素降解程度和生物油产品成分有显著影响。
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引用次数: 0
CO2 emission mitigation of a hybrid photovoltaic and cogeneration system in computer hardware manufacturing industry: A case study in Thailand 计算机硬件制造业中光伏与热电联产混合系统的二氧化碳减排:泰国案例研究
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012063
D. Manirampa, P. Chaiwiwatworakul
In the wake of COP26 and the growing urgency of addressing climate change, achieving carbon neutrality by 2050 has become a central global objective. This imperative extends to industries like computer hardware manufacturing, which are now actively pursuing decarbonization strategies through the strategic adoption of renewable energy sources and energy efficiency enhancements. This research paper assessed the CO2 emission mitigation potential of a hybrid system of photovoltaic (PV) roof and cogeneration where a large factory of computer hardware manufacturing in tropical Thailand was selected as a study site. On one hand, a one-Megawatt photovoltaic system was installed over the roof of the production building to generate electricity from solar radiation to serve the building. On the other hand, a twenty-four-Megawatt cogeneration system of gas engines as the prime mover was used to supply power to meet the building’s electricity demand. Waste heat from the gas engine was used by the absorption chiller to generate chilled water for cooling inside the building. Based on the system equipment specifications, the annual simulation using Thailand’s solar radiation showed that the installed photovoltaic system could generate electricity of 1,412.4 MWhelec/year while the implementation of the absorption chillers for cooling helped to reduce the electrical energy consumed by the traditional electric chiller by 10,211.4 MWhelec/year. In our study case where the CO2 emission of the grid power was 0.4758 kgCO2/kWhelec in the year 2022 and was reduced to 0.350 kgCO2/kWhelec in the year 2050, the total CO2 emission mitigation from the hybrid photovoltaic and cogeneration system with the genset efficiency of 50% and the waste heat recovery of 60% could reduce approximately 207,388.5TonCO2 for over 20 years as compared to the scenario where the grid electricity alone powered the building. These findings underscored the critical role of the proposed hybrid system in addressing the climate crisis and exemplified how the industry could make meaningful strides toward more environmental sustainability.
随着 COP26 的召开以及应对气候变化的日益紧迫性,到 2050 年实现碳中和已成为全球的核心目标。计算机硬件制造等行业也面临着这一紧迫性,这些行业目前正通过战略性地采用可再生能源和提高能效来积极推行去碳化战略。本文以泰国热带地区的一家大型计算机硬件制造厂为研究对象,评估了光伏屋顶和热电联产混合系统的二氧化碳减排潜力。一方面,在生产大楼的屋顶上安装了一个一兆瓦的光伏系统,利用太阳辐射发电,为大楼提供服务。另一方面,以燃气发动机为原动机的 24 兆瓦热电联产系统提供电力,以满足大楼的用电需求。吸收式冷却器利用燃气发动机的余热产生冷冻水,用于大楼内部的冷却。根据系统设备规格,利用泰国的太阳辐射进行的年度模拟显示,安装的光伏系统每年可产生 1,412.4 兆瓦电能,而吸收式冷水机组的使用则有助于将传统电冷水机组的电能消耗减少 10,211.4 兆瓦电能/年。在我们的研究案例中,2022 年电网电力的二氧化碳排放量为 0.4758 kgCO2/kWhelec,到 2050 年降至 0.350 kgCO2/kWhelec,与仅由电网电力驱动建筑的情景相比,在发电机组效率为 50%、余热回收率为 60% 的情况下,光伏和热电联产混合系统在 20 多年内可减少约 207388.5 吨二氧化碳排放。这些研究结果突显了拟议的混合动力系统在应对气候危机方面的关键作用,并体现了该行业如何在环境可持续发展方面取得有意义的进步。
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引用次数: 0
Simulation on solidification process of molten salt-based phase change material as thermal energy storage medium for application in Stirling engine 模拟作为斯特林发动机热能储存介质的熔盐相变材料的凝固过程
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012012
G. Putra, N. Putra
Thermal energy storage technologies have been widely used to mitigate intermittency from renewable energy such as solar energy. Phase change material (PCM) is a certain material that can be used as a heat storage medium and is available in a wide range of operating temperatures. Molten salt is one of the PCMs that has the advantage of a very high operating temperature. The PCM solidification simulation based on HitecXL molten salt using COMSOL Multiphysics software will be carried out with variations in heat absorption of 1 - 5 kW/m2, assuming constant heat absorption. The results show that the PCM solidification process starts from the surface of the Stirling engine heat exchanger pipe. The part of the PCM that has been solidified will fall following the direction of gravity and cause a phenomenon such as a droplet. The flow that occurs is a natural flow caused by the buoyancy force due to changes in density due to temperature gradients in the solidification process. The time required for the PCM to completely solidify is closely related to the amount of heat absorption. The greater the heat absorption from the pipe, the faster the PCM to fully solidified.
热能储存技术已被广泛用于缓解太阳能等可再生能源的间歇性。相变材料(PCM)是一种可用作储热介质的特定材料,其工作温度范围很广。熔盐是 PCM 的一种,具有工作温度极高的优点。将使用 COMSOL Multiphysics 软件对基于 HitecXL 熔盐的 PCM 固化进行模拟,在假设吸热恒定的情况下,吸热变化范围为 1 - 5 kW/m2。结果表明,PCM 的凝固过程从斯特林发动机热交换器管道表面开始。已凝固的 PCM 部分会顺着重力方向落下,形成液滴等现象。在凝固过程中,由于温度梯度导致密度发生变化,从而产生浮力,形成自然流动。PCM 完全凝固所需的时间与吸热量密切相关。管道吸热越多,PCM 完全凝固的速度就越快。
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引用次数: 0
Strategies and models for optimal EV charging station site selection 优化电动汽车充电站选址的策略和模型
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012106
B. Harshil, G. Nagababu
In numerous countries worldwide, adopting electric vehicles (EVs) is gaining momentum as a proactive measure to mitigate the detrimental environmental impacts of traditional fuel-powered automobiles. This shift drives exponential growth in the adoption of EVs, prompting the need for comprehensive analysis to optimize charging infrastructure requirements. Developing reliable and sustainable charging infrastructure depends on practical and strategic site selection of EV charging stations. The main challenge is finding a charging solution that maximizes efficiency within limited financial resources. The present review critically assesses methodologies for selecting optimal EV charging station sites, considering technical, environmental, social, and economic factors. Special emphasis is given to social factors such as population density and service accessibility, as well as technical factors like vehicle battery life, charging time, and grid capacity. Environmental impact and feasibility are also vital criteria under evaluation. Through a synthesis of insights from various studies, this review provides a comprehensive overview of the existing models used in EV charging infrastructure site selection. The findings contribute valuable insights for decision-makers, city planners, and other stakeholders in creating sustainable EV charging networks amidst the dynamic landscape of electric mobility.
在全球许多国家,采用电动汽车(EV)作为减轻传统燃油汽车对环境造成的有害影响的积极措施,正获得越来越大的发展势头。这种转变推动了电动汽车采用率的指数级增长,促使人们需要进行全面分析,以优化充电基础设施需求。开发可靠、可持续的充电基础设施取决于对电动汽车充电站进行切实可行的战略选址。主要的挑战在于找到一种充电解决方案,在有限的财政资源内实现效率最大化。本综述结合技术、环境、社会和经济因素,对电动汽车充电站最佳选址方法进行了严格评估。其中特别强调了人口密度和服务可达性等社会因素,以及车辆电池寿命、充电时间和电网容量等技术因素。环境影响和可行性也是评估的重要标准。本综述综合了各种研究的观点,全面概述了电动汽车充电基础设施选址中使用的现有模型。研究结果为决策者、城市规划者和其他利益相关者提供了宝贵的见解,帮助他们在电动交通的动态环境中创建可持续的电动汽车充电网络。
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引用次数: 0
Experimental soil matrix, vortex and oil skimming technology as a tertiary treatment of wastewater effluent 试验性土壤基质、涡流和撇油技术作为废水三级处理技术
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012043
C. Tugade, C. Pescos, C.A.L. Caliwag, C.D.V. Centeno, J.D.C. Tan, Q.M.D Malveda, R.C. Olivares, R.M. Chavez, L. Carrillo
Water is a necessary resource that must be carefully managed. Hazardous chemicals are produced with increased industrial activities and contamination has been detrimental to both people and the environment. An experimental investigation was performed to evaluate the efficiency of vortex technology, soil matrices, and oil skimmer separately for combination as a tertiary wastewater treatment in the design of a phytoremediation system. The objective of the study is to evaluate the performance of each component in removing oil and grease, reducing the concentration of ammonia, nitrate, and phosphate; quality control measures for dissolved oxygen, total dissolved solids, and chemical oxygen demand. One-way ANOVA, kinetics analysis, and adoption isotherm analysis were applied to determine the significance of the parameters. Analysis of results for the oil skimmer exhibited an efficiency of 96% in removing oil and grease after 5 hours of treatment. The vortex technology results were fluctuating with percentage removal of nitrates at 11% while ammonia with an initial concentration of 5.24 mg/L was reduced to 4.12 mg/L. Phosphate decreased after treatment from an initial of 0.87 mg/L to 0.809 mg/L. The analysis of pollutant concentration in the soil matrix after a 5-day period indicated a greater efficiency compared to the vortex technology in the removal of ammonia and phosphate. The ammonia concentration decreased from 18.7 mg/L and 21.4 mg/L to <0.1 mg/L. Similarly, phosphate concentration decreased from 15.5 mg/L to 1.13 mg/L and from 32.5 mg/L to 0.948 mg/L. The research finding underscores the efficiency of the soil matrix in removing ammonia and phosphate but recommends the need for additional intervention to lower nitrate. Overall, the three technologies showed potential and greater efficiencies in mitigating wastewater streams resulting in a notable reduction in oil and pollutant concentrations.
水是一种必须谨慎管理的必要资源。随着工业活动的增加,产生了有害的化学物质,污染对人类和环境都造成了危害。我们进行了一项实验调查,以评估涡流技术、土壤基质和撇油器在植物修复系统设计中分别用作三级废水处理的组合效率。研究的目的是评估各组成部分在去除油脂、降低氨氮、硝酸盐和磷酸盐浓度方面的性能,以及溶解氧、溶解固体总量和化学需氧量的质量控制措施。采用单因素方差分析、动力学分析和采用等温线分析来确定参数的重要性。对撇油机的结果分析表明,经过 5 小时的处理,其去除油脂的效率为 96%。涡流技术的结果是波动的,硝酸盐的去除率为 11%,而氨氮从初始浓度 5.24 毫克/升降至 4.12 毫克/升。磷酸盐在处理后从最初的 0.87 毫克/升降至 0.809 毫克/升。5 天后对土壤基质中污染物浓度的分析表明,与涡流技术相比,涡流技术去除氨氮和磷酸盐的效率更高。氨浓度分别从 18.7 毫克/升和 21.4 毫克/升降至小于 0.1 毫克/升。同样,磷酸盐浓度从 15.5 毫克/升降至 1.13 毫克/升,从 32.5 毫克/升降至 0.948 毫克/升。这项研究成果强调了土壤基质在去除氨氮和磷酸盐方面的效率,但建议需要采取更多干预措施来降低硝酸盐。总体而言,这三种技术在缓解废水流方面显示出了潜力和更高的效率,从而显著降低了油类和污染物的浓度。
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引用次数: 0
Performance of tube heat pipe solar collector with phase change material for seawater desalination system 海水淡化系统中使用相变材料的管式热管太阳能集热器的性能
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012014
R.A. Kusumadewi, N. Putra, S. Moersidik, S. Laksono, G. Putra, A.J.P. Utomo
Unlimited seawater resources resulted for utilization of desalination systems using seawater treatment process emerges as a promising technology for addressing the continually escalating need for freshwater. At present, the most notable desalination processes that are reverse osmosis, membrane distillation, multistage desalination, multiple-effect distillation, and electrodialysis, require energy generated by fossil fuels to obtain fresh water. Among the noteworthy sources of renewable energy, solar energy stands out with its manifold applications. The use of solar energy has strong advantages, such as a low maintenance and operation costs. In this study, a novel solar desalination system is introduced, which integrates tube heat pipe solar collector (THP-SC) equipped with phase change material (PCM). The aim of this research is to evaluate the performance of THP-SC equipped with PCM and without PCM. The feedwater sample used is water. Parameters measured for 24 hours were temperature, solar radiation, ambient air temperature, relative humidity, and wind speed. The greatest recorded solar radiation at noon (11.52 a.m.) is 900 W/m2 while the maximum recorded ambient temperature at 12.45 p.m. is 35.2°C. The experimental study showed that from morning to afternoon (06.00-15.00), the temperature of the evaporator section of the heat pipe on the THP-SC without PCM (46.70-56.21°C) was higher than the temperature of the evaporator section of the heat pipe on the THP-SC with PCM (33.18-44.43°C). This is because solar radiation will heat the PCM first before heating the heat pipe. PCM can store heat energy and release it at night. This can be seen from the water temperature in THP-SC with PCM (28.39-36.03) which is higher than the water temperature in THP-SC without PCM (27.17-34.01) at night, but the temperature difference is not significant. This can be caused by the large amount of heat lost to the environment in THP-SC with PCM, it is best to coat the heat pipe tube with insulation and create a vacuum to reduce heat loss.
由于海水资源无限,利用海水处理工艺的海水淡化系统成为解决淡水需求持续增长的一项前景广阔的技术。目前,最著名的海水淡化工艺包括反渗透、膜蒸馏、多级海水淡化、多效蒸馏和电渗析,这些工艺都需要化石燃料产生的能量来获取淡水。在值得注意的可再生能源中,太阳能以其多方面的应用脱颖而出。太阳能的使用具有很强的优势,如维护和运行成本低。本研究介绍了一种新型太阳能海水淡化系统,该系统集成了配备相变材料(PCM)的管式热管太阳能集热器(THP-SC)。本研究的目的是评估配备 PCM 和不配备 PCM 的 THP-SC 的性能。使用的给水样品是水。24 小时测量的参数包括温度、太阳辐射、环境空气温度、相对湿度和风速。中午(上午 11:52)记录到的最大太阳辐射为 900 W/m2,中午 12:45 记录到的最高环境温度为 35.2°C。实验研究表明,从上午到下午(06.00-15.00),不含 PCM 的 THP-SC 热管蒸发器部分的温度(46.70-56.21°C)高于含 PCM 的 THP-SC 热管蒸发器部分的温度(33.18-44.43°C)。这是因为太阳辐射会先加热 PCM,然后再加热热管。PCM 可以储存热能并在夜间释放。有 PCM 的 THP-SC 中的水温(28.39-36.03)高于无 PCM 的 THP-SC 中夜间的水温(27.17-34.01),但温差不大。这可能是由于带 PCM 的 THP-SC 向环境中散失了大量热量,因此最好在热管上涂上隔热材料并形成真空,以减少热量散失。
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引用次数: 0
The influence of variations in salinity levels on the biocementing process on soil improvement of liquefaction potential 盐度变化对生物固结法改良土壤液化潜力的影响
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012071
N. A. Diana, R. A. A. Soemitro, J. J. Ekaputri, T. R. Satrya, D. Warnana
This article presents an innovative method of soil improvement cementing to increase the shearing strength of very loose sand with 10% relative density (Dr) in saline conditions. Salt in saline soils destroys the stability of stable soils. In contrast, the salt content reduces the level of homogenization of unstable soils, causes technical problems in calcareous soils, and affects their stability, especially if the salt content is more than 3.0%. The variations in salinity levels can determine the optimal percentage of salt levels in the stabilized soil. The application of biocementation to saline soil can drastically increase the shear strength of soil in soil with potential liquefaction in coastal areas due to earthquakes. Calcium carbonate deposition (MICP) in the microbial-induced biocementing process is a new method that utilizes the metabolic processes of microorganisms in this study using Bacillus sp. In the MICP process, microbes need Ca2+ ions obtained from fly ash, which can produce SiO2 and CaO to produce CaCO3 for binding between particles. Soil improvement was carried out by combining initial soil, fly ash, mycobacteria, and variations in salinity obtained from NaCl with varying percentages of 0%, 1%, 2%, and 3,4% after testing at curing times 7, 14, 21, and 28 days. The research samples from the UCS and direct shear tests showed that the shear and UC strength that were treated increased. The highest increase in shear strength was at 3,4% salinity at 28 days of 80.9°. CaCO3 production resulting from the binding between particles in the biocementing reaction can be seen from the results of SEM tests. Soil improvement using biocementing in this study resulted in an effective increase in the strength of loose sand soil in salinity condition.
本文介绍了一种创新的土壤改良固结方法,用于提高盐碱条件下相对密度为 10%(Dr)的极松散砂土的抗剪强度。盐碱土中的盐分会破坏稳定土壤的稳定性。相反,含盐量会降低不稳定土壤的均质化水平,造成石灰性土壤的技术问题,并影响其稳定性,尤其是当含盐量超过 3.0% 时。盐度的变化可以决定稳定土壤中盐含量的最佳比例。在盐碱土壤中应用生物固化技术,可大幅提高沿海地区因地震可能发生液化的土壤的抗剪强度。在微生物诱导生物固结过程中的碳酸钙沉积(MICP)是一种利用微生物代谢过程的新方法,本研究利用芽孢杆菌(Bacillus sp.)在 MICP 过程中,微生物需要从粉煤灰中获得 Ca2+ 离子,从而产生 SiO2 和 CaO,生成 CaCO3,用于颗粒之间的结合。土壤改良是通过将初始土壤、粉煤灰、霉菌和盐度变化(从氯化钠中获取)结合起来进行的,盐度变化的百分比分别为 0%、1%、2% 和 3.4%,在固化 7、14、21 和 28 天后进行测试。UCS 和直接剪切试验的研究样本表明,经过处理的剪切强度和 UC 强度都有所提高。在盐度为 3.4% 的情况下,剪切强度的提高幅度最大,28 天时的剪切强度为 80.9°。从扫描电镜测试结果可以看出,生物固结反应中颗粒之间的结合产生了 CaCO3。在这项研究中,使用生物固结法改良土壤可有效提高松散砂土在盐度条件下的强度。
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引用次数: 0
Life cycle analysis of a network of small modular reactors 小型模块化反应堆网络的生命周期分析
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012059
Carlo L. Vinoya, A. Ubando, A. Culaba
Small modular reactors are highly-touted as the next-generation nuclear reactors that can provide alternatives to baseload energy sources such as coal and gas. Lesser dependence on these energy resources may enable faster development in poorer countries. The small modular reactors’ modularity allows for faster construction times vis-à-vis large reactors. Together with this, as more of the same reactors are constructed, costs are expected to decrease with learnings made from the experience of producing the previous one. From a technological point of view, Small modular reactors are capable of generating energy at a lower cost compared to large reactors due to the lesser capital costs that arise from faster construction times. However, it is important to understand the overall environmental impact of small modular reactors when used as a network of reactors to generate energy. Life-cycle analysis is an accepted methodology to assess various environmental impacts of technology from cradle to grave. In this work, a case study of the development of a network of small modular reactors with a unique supply chain is presented. Since small modular reactors can be sited separately, and with its comparatively higher number of reactors and plants, the same network of small modular reactors has a higher carbon footprint than a single large reactor. However, this result should be carefully considered together with other criteria that affect the decision-making in the construction and development of small modular reactors or large reactors as these may outweigh marginally higher carbon footprints, such as economic, social, and political benefits.
小型模块化反应堆是备受推崇的下一代核反应堆,可以替代煤炭和天然气等基荷能源。减少对这些能源资源的依赖,可以加快贫穷国家的发展。与大型反应堆相比,小型模块化反应堆的模块化设计可以加快建造时间。此外,随着更多相同反应堆的建造,从上一个反应堆的生产经验中吸取的教训有望降低成本。从技术角度来看,小型模块化反应堆能够以低于大型反应堆的成本生产能源,因为建造时间越短,资本成本越低。然而,当小型模块化反应堆作为一个反应堆网络用于生产能源时,了解其对环境的总体影响非常重要。生命周期分析是评估技术从摇篮到坟墓的各种环境影响的公认方法。在这项工作中,介绍了一项关于开发具有独特供应链的小型模块化反应堆网络的案例研究。由于小型模块化反应堆可以单独选址,而且反应堆和工厂的数量相对较多,因此同一小型模块化反应堆网络的碳足迹高于单一大型反应堆。然而,在考虑这一结果的同时,还应仔细考虑影响小型模块化反应堆或大型反应堆建设和开发决策的其他标准,因为这些标准可能会超过碳足迹略高的标准,如经济、社会和政治利益。
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引用次数: 0
Effect of alkali metal cations in alkaline iron battery electrodes 碱金属阳离子对碱性铁电池电极的影响
Pub Date : 2024-07-01 DOI: 10.1088/1755-1315/1372/1/012015
D. E. D. Loresca, J. A. Paraggua
Rechargeable alkaline iron batteries (e.g. Ni-Fe and Fe-air) have been extensively studied recently as viable energy storage systems for renewable energy sources. However, inherent issues such as passivation of the iron and parasitic hydrogen evolution reaction (HER) on the electrode surface limit their full capability. Multiple approaches to improving iron electrode performance have been conducted, few of which focused on electrolyte composition. While alkali metal (AM) cations on the electrolyte do not directly participate in the electrochemical reactions, their intrinsic characteristics can dictate the performance of the electrode. Investigating the interface interactions and electrical double layer (EDL) structure can provide a deeper insight into the operation of iron electrodes in an alkaline solution. In this work, we investigated the effect of alkali metal cations (Li+, Na+, K+, Cs+) in the electrolyte solution in inhibiting passivation and HER on electrodeposited iron on carbon paper (Fe/CP) electrodes. The electrochemical measurements show that the iron redox and HER activities of the electrode increased with increasing cation size in the electrolyte. The non-covalent interactions between hydrated alkali metal cations and adsorbed OH species resulted to the formation of quasi-adsorbed clusters which can block active sites on the electrode surface. Furthermore, the concentration of these clusters decreases with increasing cation size which resulted to higher EDL capacitance and ECSA values of the electrode. The results of this work provide a better understanding of the surface reactions on iron electrodes and can help in developing novel techniques for suppressing passivation and parasitic HER on rechargeable alkaline iron batteries.
作为可再生能源的可行储能系统,可充电碱铁电池(如镍铁电池和铁-空气电池)最近得到了广泛的研究。然而,铁的钝化和电极表面的寄生氢进化反应(HER)等固有问题限制了它们的全部能力。目前已采用多种方法来提高铁电极的性能,其中少数方法侧重于电解质成分。虽然电解质上的碱金属(AM)阳离子并不直接参与电化学反应,但其内在特性却能决定电极的性能。对界面相互作用和电双层(EDL)结构的研究可以更深入地了解铁电极在碱性溶液中的运行情况。在这项工作中,我们研究了电解质溶液中碱金属阳离子(Li+、Na+、K+、Cs+)对电沉积铁碳纸(Fe/CP)电极钝化和 HER 的抑制作用。电化学测量结果表明,电极的铁氧化还原和氢化还原活性随着电解液中阳离子大小的增加而增加。水合碱金属阳离子与吸附的 OH 物种之间的非共价相互作用形成了准吸附簇,这些簇会阻塞电极表面的活性位点。此外,这些团簇的浓度随着阳离子大小的增加而降低,从而导致电极的 EDL 电容值和 ECSA 值升高。这项工作的结果让人们更好地了解了铁电极的表面反应,有助于开发新技术,抑制可充电碱性铁电池的钝化和寄生 HER。
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IOP Conference Series: Earth and Environmental Science
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