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Conservative Evaluation of Fault Displacement Hazard for a Nuclear Site in Case of Insufficient Data on the Fault Activity 在断层活动数据不足的情况下对核基地断层位移危害的保守评估
Pub Date : 2024-06-07 DOI: 10.3390/geosciences14060158
Tamás János Katona
The safety regulations require periodic reviews of the site hazards when operating nuclear power plants. If any indications of Quaternary fault activity are revealed, the fault displacement hazard should be evaluated. Signs of paleo-liquefaction were recently found at the nuclear site of Paks, Hungary, indicating the late-Pleistocene activity of the fault crossing the site. Except for this, there are no historical or instrumental records of earthquakes at the fault, and the micro-seismic and GPS monitoring results do not indicate activity either. Despite a thorough site investigation of over 40 years, the indications are uncertain and insufficient for defining the fault activity, as required for a probabilistic fault displacement hazard analysis. This paper develops and applies a simplified conservative hazard evaluation method of average fault displacement that allows an in-time decision regarding the safety relevance of the hazard. Geometrical simplification is possible since the fault crosses the site. The fault’s activity is evaluated using magnitude–frequency relations of the area sources developed for probabilistic seismic hazard analysis. The total probability theorem is applied, and different strike-slip fault scaling relations are considered while calculating the probability of non-zero surface displacement, fault rupture length, and average displacement. The fault displacement hazard curve is defined and compared with earlier studies for the same site. Since the late recognition of active faults cannot be excluded at several operating plant sites, the methodology can be applied in the future beyond a single application for the Paks site in Hungary.
安全法规要求在核电厂运行时定期审查厂址的危险性。如果发现任何第四纪断层活动迹象,则应对断层位移危险进行评估。最近在匈牙利帕克斯核电厂发现了古地震迹象,表明穿越该厂的断层在晚更新世活动。除此之外,该断层没有地震的历史记录或仪器记录,微震和全球定位系统监测结果也未显示有地震活动。尽管对现场进行了 40 多年的彻底调查,但这些迹象并不确定,不足以确定断层的活动性,而这正是进行概率断层位移危害分析所需要的。本文开发并应用了一种简化的、保守的平均断层位移危险性评估方法,可以及时确定危险性的安全相关性。由于断层穿越现场,因此可以进行几何简化。利用为概率地震灾害分析而开发的区域震源震级-频率关系来评估断层的活动性。在计算非零表面位移概率、断层破裂长度和平均位移时,应用了总概率定理,并考虑了不同的走向滑动断层比例关系。定义了断层位移危险曲线,并将其与针对同一地点的早期研究进行了比较。由于不能排除在多个运行厂址中发现活动断层的可能性,因此该方法今后可在匈牙利帕克斯厂址的单一应用之外加以应用。
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引用次数: 0
Identification, Characterization, and Deposit Model of Calcite Mineralization in the Middle Atlas Belts, Morocco 摩洛哥中阿特拉斯带方解石矿化的识别、特征和矿床模型
Pub Date : 2024-06-06 DOI: 10.3390/geosciences14060154
Abdelkhiar Ait Ali, M. Charroud, J. Choukrad, Youssef Ouahzizi, Hicham Si Mhamdi, Nacir El Moutaouakkil, N. Saoud, A. Mechaqrane
The Middle Atlas hosts calcite veins of considerable economic value, being found in the Mahdi and Bou Naceur ridges in the eastern part of the Moroccan Middle Atlas. In this study, we aim to identify the fundamental factors controlling mineralization, which could be essential for the exploration of calcite minerals. Jurassic dolomites and limestones host calcite deposits. Mineralization is controlled by the NE-SW sinistral fault system of the Mahdi Ridge as well as by the NW-SE dextral fault system of the Bou Naceur Ridge. These veins exhibit a Riedel shear system. The edges of the veins display different textures, such as banded and brecciated calcite. At the heart of the veins are deposits of massive, automorphic, pure crystalline calcite. Geochemical analyses revealed carbonate rock dissolution and carbonate fluid infiltration, indicating the presence of a low-temperature hydrothermal system. These mineralizations are a response to the evolution of the geodynamic uplift of the Middle Atlas during the Neogene, which occurred during the Alpine orogeny.
中阿特拉斯地区拥有具有相当经济价值的方解石矿脉,在摩洛哥中阿特拉斯东部的马赫迪山脊和布纳瑟山脊均有发现。在这项研究中,我们旨在确定控制矿化的基本因素,这些因素可能对方解石矿物的勘探至关重要。侏罗纪白云岩和石灰岩蕴藏着方解石矿床。成矿作用受到马赫迪山脊东北-西南正断层系统以及布纳瑟尔山脊西北-东南正断层系统的控制。这些矿脉呈现出里德尔剪切系统。矿脉边缘显示出不同的纹理,如带状和角砾状方解石。矿脉的中心是块状、自动形成的纯结晶方解石矿床。地球化学分析表明,碳酸盐岩溶解和碳酸盐流体渗入表明存在低温热液系统。这些矿化现象是新近纪阿尔卑斯造山运动期间中阿特拉斯地区地球动力隆升演变的反应。
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引用次数: 0
Prediction of Soil Liquefaction Triggering Using Rule-Based Interpretable Machine Learning 利用基于规则的可解释机器学习预测土壤液化触发情况
Pub Date : 2024-06-06 DOI: 10.3390/geosciences14060156
Emerzon Torres, Jonathan Dungca
Seismic events remain a significant threat, causing loss of life and extensive damage in vulnerable regions. Soil liquefaction, a complex phenomenon where soil particles lose confinement, poses a substantial risk. The existing conventional simplified procedures, and some current machine learning techniques, for liquefaction assessment reveal limitations and disadvantages. Utilizing the publicly available liquefaction case history database, this study aimed to produce a rule-based liquefaction triggering classification model using rough set-based machine learning, which is an interpretable machine learning tool. Following a series of procedures, a set of 32 rules in the form of IF-THEN statements were chosen as the best rule set. While some rules showed the expected outputs, there are several rules that presented attribute threshold values for triggering liquefaction. Rules that govern fine-grained soils emerged and challenged some of the common understandings of soil liquefaction. Additionally, this study also offered a clear flowchart for utilizing the rule-based model, demonstrated through practical examples using a borehole log. Results from the state-of-practice simplified procedures for liquefaction triggering align well with the proposed rule-based model. Recommendations for further evaluations of some rules and the expansion of the liquefaction database are warranted.
地震事件仍然是一个重大威胁,在脆弱地区造成生命损失和广泛破坏。土壤液化是土壤颗粒失去约束的一种复杂现象,会带来巨大风险。现有的用于液化评估的传统简化程序和当前的一些机器学习技术都存在局限性和缺点。本研究旨在利用公开的液化案例数据库,使用基于粗糙集的机器学习(一种可解释的机器学习工具),建立基于规则的液化触发分类模型。经过一系列程序后,以 IF-THEN 语句为形式的 32 条规则被选为最佳规则集。虽然有些规则显示了预期的输出结果,但也有几条规则显示了触发液化的属性阈值。细粒土规则的出现,对土壤液化的一些常见理解提出了挑战。此外,这项研究还提供了使用基于规则的模型的清晰流程图,并通过使用钻孔记录的实际例子进行了演示。液化触发简化程序的实践结果与建议的基于规则的模型非常吻合。建议对某些规则进行进一步评估,并扩大液化数据库。
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引用次数: 0
Dipping Tidal Notch (DTN): Exposed vs. Sheltered Morphometry 潮汐凹槽(DTN):暴露与遮蔽形态测量
Pub Date : 2024-06-06 DOI: 10.3390/geosciences14060157
S. Furlani, Mauro Agate, Eleonora de Sabata, Renato Chemello, V. Vaccher, Giulia Visconti, Fabrizio Antonioli
Tidal notches, long regarded as reliable indicators of mean sea level, have been extensively studied along carbonate coasts in the central Mediterranean Sea. Previous studies revealed a correlation between the genesis of tidal notches and tidal range, lithology, cliff foot depth, and wave energy. In the 2020 Geoswim campaigns at Lampedusa, the southernmost island of the Pelagie archipelago (Italy), and in Gozo Island (Malta), ‘anomalous’ tidal notches were identified. Unlike normal notches observed elsewhere, those in Lampedusa’s southern bays exhibited a particular behaviour —constantly deepening in the inner part of the bays, reaching a maximum depth of approximately 30 cm below sea level and narrowing inwards. Similar phenomena were previously observed near Marseille (France). As confirmed by the literature, all these areas are tectonically stable. Time-lapse images, alongside measurements of morphometric parameters, were collected during the survey. Our hypothesis indicates that a combination of marine factors influenced by local marine conditions driven by the local morphology of the small bays exposed to southern quadrants contribute to the formation of these unique landforms. The latter manifests higher lowering erosion rates slightly below the mean sea level in sheltered areas, challenging conventional notions about tidal notch formation.
潮汐缺口一直被视为平均海平面的可靠指标,地中海中部碳酸盐海岸沿线的潮汐缺口已被广泛研究。以往的研究表明,潮汐凹槽的形成与潮差、岩性、崖脚深度和波浪能之间存在相关性。在佩拉吉群岛(意大利)最南端的兰佩杜萨岛和戈佐岛(马耳他)进行的 2020 年 Geoswim 活动中,发现了 "异常 "潮汐缺口。与其他地方观测到的正常缺口不同,兰佩杜萨岛南部海湾的缺口表现出一种特殊的行为--在海湾内部不断加深,最大深度约为海平面以下 30 厘米,然后向内缩小。之前在法国马赛附近也观察到类似现象。文献证实,所有这些地区的构造都很稳定。在勘测过程中,我们收集了延时图像以及形态测量参数。我们的假设表明,受当地海洋条件的影响,以及南四边形小海湾当地形态的驱动,多种海洋因素共同促成了这些独特地貌的形成。后者在遮蔽区域略低于平均海平面的地方表现出较高的下侵蚀率,挑战了关于潮汐凹槽形成的传统观念。
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引用次数: 0
Selection of the Value of the Power Distance Exponent for Mapping with the Inverse Distance Weighting Method—Application in Subsurface Porosity Mapping, Northern Croatia Neogene 使用反距离加权法测绘时功率距离指数值的选择--在克罗地亚北部新近纪地下孔隙度测绘中的应用
Pub Date : 2024-06-06 DOI: 10.3390/geosciences14060155
Uroš Barudžija, Josip Ivšinović, T. Malvić
The correct selection of the value of p is a complex and iterative procedure that requires experience in the interpretation of the obtained interpolated maps. Inverse Distance Weighting is a method applied to the porosities of the K and L hydrocarbon reservoirs discovered in the Neogene (Lower Pontian) subsurface sandstones in northern Croatia (Pannonian Basin System). They represent small and large data samples. Also, a standard statistical analysis of the data was made, followed by a qualitative–quantitative analysis of the maps, based on the selection of different values for the power distance exponent (p-value) for the K and L reservoir maps. According to the qualitative analysis, for a small data set, the p-value could be set at 1 or 2, giving the optimal result, while for a large data set, a p value of 3 or 4 could be applied. For quantitative analysis, in the case of a small data set, p = 2 is recommended, resulting in a root mean square error value of 0.03458, a mean absolute error of 0.02013 and a median absolute deviation of 0.00546. In contrast, a p-value of 3 or 4 is selected as appropriate for a large data set, with root mean square errors of 0.02435 and 0.02437, mean square errors of 0.01582 and 0.01509 and median absolute deviations 0.00896 and 0.00444. Eventually for a small data set, it is recommended to use a p-value of 2, and for a large data set, a p-value of 3 or 4.
正确选择 p 值是一个复杂的迭代过程,需要对所获得的插值图进行解释的经验。反距离加权法适用于在克罗地亚北部(潘诺尼亚盆地系统)新近纪(下庞提安)地下砂岩中发现的 K 和 L 油气藏的孔隙度。它们代表了小型和大型数据样本。此外,还对数据进行了标准统计分析,然后根据 K 和 L 储层图选择不同的幂距指数值(p 值),对储层图进行了定性-定量分析。根据定性分析,对于小数据集,可将 p 值设为 1 或 2,以获得最佳结果,而对于大数据集,可将 p 值设为 3 或 4。在定量分析中,如果数据集较小,建议 p = 2,得出的均方根误差值为 0.03458,平均绝对误差为 0.02013,中位绝对偏差为 0.00546。相反,对于大数据集,p 值为 3 或 4 比较合适,均方根误差分别为 0.02435 和 0.02437,均方误差分别为 0.01582 和 0.01509,绝对偏差中值分别为 0.00896 和 0.00444。最终,对于小数据集,建议使用 2 的 p 值,对于大数据集,建议使用 3 或 4 的 p 值。
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引用次数: 0
Geosites and Climate Change—A Review and Conceptual Framework 土工合成材料与气候变化--回顾与概念框架
Pub Date : 2024-06-05 DOI: 10.3390/geosciences14060153
P. Migoń
Geosites are windows into the geological past, which may be recorded in rocks and their properties, the fossil content, and landform produced by processes no longer operating. Since the histories of sedimentation, life, and landscape evolution are to a certain extent controlled by climatic conditions, some geosites may be used as illustrations of various themes linked to the issue of climate change. In this paper, a coherent systematic framework is proposed for how to look at geosites through the lens of climate change. Four major aspects of relevance are recognized: (i) geosites providing evidence of changing climatic conditions in the past; (ii) geosites providing evidence of an environment different than that of today at the place; (iii) geosites providing evidence of extreme weather events; and (iv) dynamic geosites, subject to change as a response to ongoing climate change. The use of geosites to raise awareness and educate the public about climate change faces various interpretation challenges. In particular, linking with ongoing climate change requires caution and balanced presentation as most geosites record changes which occurred without any anthropogenic component. The preferred focus should be on environmental instability in general rather than on any specific reasons for change.
地貌景观是了解地质历史的窗口,岩石及其性质、化石含量以及不再运行的过程所产生的地貌都可能记录了地质历史。由于沉积、生命和地貌演变的历史在一定程度上受气候条件的控制,因此一些地质景观可以用来说明与气候变化问题相关的各种主题。本文提出了一个连贯的系统框架,说明如何通过气候变化的视角来观察地质地貌。本文认识到四个主要相关方面:(i) 提供过去气候条件变化证据的地貌景观;(ii) 提供该地环境不同于当今环境证据的地貌景观;(iii) 提供极端天气事件证据的地貌景观;(iv) 随着持续气候变化而变化的动态地貌景观。利用地质地貌来提高公众对气候变化的认识和教育面临着各种解释方面的挑战。特别是,与正在发生的气候变化联系起来需要谨慎和平衡的表述,因为大多数地 质照片记录的变化都是在没有任何人为因素的情况下发生的。重点应放在环境的总体不稳定性上,而不是变化的任何具体原因上。
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引用次数: 0
Google Earth Engine and Machine Learning for Flash Flood Exposure Mapping—Case Study: Tetouan, Morocco 谷歌地球引擎和机器学习用于山洪暴发绘图--案例研究:摩洛哥泰图安
Pub Date : 2024-06-04 DOI: 10.3390/geosciences14060152
E. Sellami, Hassan Rhinane
Recently, the earth’s climate has changed considerably, leading to several hazards, including flash floods (FFs). This study aims to introduce an innovative approach to mapping and identifying FF exposure in the city of Tetouan, Morocco. To address this problem, the study uses different machine learning methods applied to remote sensing imagery within the Google Earth Engine (GEE) platform. To achieve this, the first phase of this study was to map land use and land cover (LULC) using Random Forest (RF), a Support Vector Machine (SVM), and Classification and Regression Trees (CART). By comparing the results of five composite methods (mode, maximum, minimum, mean, and median) based on Sentinel images, LULC was generated for each method. In the second phase, the precise LULC was used as a related factor to others (Stream Power Index (SPI), Topographic Position Index (TPI), Slope, Profile Curvature, Plan Curvature, Aspect, Elevation, and Topographic Wetness Index (TWI)). In addition to 2024 non-flood and flood points to predict and detect FF susceptibility, 70% of the dataset was used to train the model by comparing different algorithms (RF, SVM, Logistic Regression (LR), Multilayer Perceptron (MLP), and Naive Bayes (NB)); the rest of the dataset (30%) was used for evaluation. Model performance was evaluated by five-fold cross-validation to assess the model’s ability on new data using metrics such as precision, score, kappa index, recall, and the receiver operating characteristic (ROC) curve. In the third phase, the high FF susceptibility areas were analyzed for two-way validation with inundated areas generated from Sentinel-1 SAR imagery with coherent change detection (CDD). Finally, the validated inundation map was intersected with the LULC areas and population density for FF exposure and assessment. The initial results of this study in terms of LULC mapping showed that the most appropriate method in this research region is the use of an SVM trained on a mean composite. Similarly, the results of the FF susceptibility assessment showed that the RF algorithm performed best with an accuracy of 96%. In the final analysis, the FF exposure map showed that 2465 hectares were affected and 198,913 inhabitants were at risk. In conclusion, the proposed approach not only allows us to assess the impact of FF in this study area but also provides a versatile approach that can be applied in different regions around the world and can help decision-makers plan FF mitigation strategies.
近来,地球气候发生了巨大变化,导致了包括山洪在内的多种灾害。本研究旨在介绍一种创新方法,用于绘制和识别摩洛哥泰图安市的山洪暴发风险。为解决这一问题,本研究在谷歌地球引擎(GEE)平台上对遥感图像采用了不同的机器学习方法。为此,本研究的第一阶段是使用随机森林(RF)、支持向量机(SVM)以及分类和回归树(CART)绘制土地利用和土地覆被地图。通过比较基于哨兵图像的五种综合方法(模式、最大值、最小值、平均值和中值)的结果,为每种方法生成了土地利用和土地覆被图。在第二阶段,精确的 LULC 被用作其他相关因子(溪流动力指数 (SPI)、地形位置指数 (TPI)、坡度、剖面曲率、平面曲率、纵向、高程和地形湿润指数 (TWI))。除了 2024 个非洪水点和洪水点用于预测和检测 FF 易感性外,70% 的数据集通过比较不同的算法(RF、SVM、逻辑回归 (LR)、多层感知器 (MLP) 和 Naive Bayes (NB))用于训练模型;其余的数据集(30%)用于评估。通过五倍交叉验证评估模型性能,使用精度、得分、卡帕指数、召回率和接收者操作特征曲线等指标评估模型在新数据上的能力。在第三阶段,对高 FF 易感区进行分析,并与利用相干变化检测(CDD)从 Sentinel-1 SAR 图像生成的淹没区进行双向验证。最后,将经过验证的淹没地图与 LULC 区域和人口密度相交,以进行 FF 暴露和评估。本研究在 LULC 地图绘制方面的初步结果表明,在本研究区域内最合适的方法是使用在平均合成物上训练的 SVM。同样,FF 易感性评估结果表明,RF 算法的准确率为 96%,表现最佳。在最终分析中,FF 暴露图显示有 2465 公顷的土地受到影响,198,913 名居民面临风险。总之,所提出的方法不仅能让我们评估 FF 对该研究区域的影响,还提供了一种可应用于全球不同地区的通用方法,并能帮助决策者规划 FF 缓解战略。
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引用次数: 0
Stabilization of Pavement Subgrade Clay Soil Using Sugarcane Ash and Lime 使用甘蔗灰和石灰稳定路面基层粘土
Pub Date : 2024-06-02 DOI: 10.3390/geosciences14060151
Abrar Ahmed, Magdi El-Emam, Naveed Ahmad, M. Attom
Soft to medium clay soil possesses major sources of damages to the pavement layers overlying them because of their potential failure under moisture changes and external heavy traffic load. In such situations, soil stabilization methods can be used to improve the soil properties and satisfy the desired engineering requirements. This study presents the use of sugarcane bagasse ash (SBA) and lime as chemical stabilizers for a clay soil subbase. Sugarcane bagasse ash and lime are used individually and as mixtures at varying percentages to stabilize a clay soil from Taxila, Pakistan. Various geotechnical laboratory tests such as Atterberg limits, compaction test, and California Bearing Ratio (CBR) are carried out on both pure and stabilized soils. These tests are performed at 2.5%, 5%, and 7.5% of either SBA or lime by weight of dry soil. In addition, mixtures of lime and SBA in ratios of 1:1, 2:1, 3:1, 1:2, and 1:3 are used in 5%, 7.5%, and 10% of dry soil weight, respectively. Results indicate that soil improved with 7.5% SBA showed a 28% increase in the liquid limit, while soil mixed with 2.5% lime in combination with 7.5% SBA showed an increase of 40% in the plastic limit. For the plasticity index, the soil mixed with 7.5% SBA showed an increase of 42%. Moreover, 2.5% lime in combination with 2.5% SBA showed the best improvement in soil consistency as this mixture reduced the soil plasticity from high to low according to the plasticity chart. Furthermore, 2.5% SBA in combination with 5% lime demonstrated the largest improvement on the CBR value, which is about a 69% increase above that of the pure soil. Finally, the cost analysis indicates a promising improvement method that reduces pavement cost, increases design life, and mitigates issues of energy consumption and pollution related to SBA as a solid waste material.
软土和中粘土是上覆路面层的主要破坏源,因为它们在湿度变化和外部重交通荷载的作用下有可能失效。在这种情况下,可以采用土壤稳定方法来改善土壤性质,满足所需的工程要求。本研究介绍了使用甘蔗渣灰(SBA)和石灰作为粘土路基的化学稳定剂。甘蔗渣灰和石灰以不同的比例单独或混合使用,用于稳定巴基斯坦塔克西拉的粘土。对纯土和稳定土进行了各种土工实验室测试,如阿特伯格极限、压实试验和加州承载比(CBR)。这些测试是按干土重量的 2.5%、5% 和 7.5% 的 SBA 或石灰含量进行的。此外,石灰和 SBA 的混合物比例分别为 1:1、2:1、3:1、1:2 和 1:3,分别占干土重量的 5%、7.5% 和 10%。结果表明,使用 7.5% SBA 改良土壤的液限提高了 28%,而混合了 2.5% 石灰和 7.5% SBA 的土壤的塑限提高了 40%。在塑性指数方面,混有 7.5% SBA 的土壤增加了 42%。此外,2.5% 的石灰与 2.5% 的 SBA 混合物对土壤稠度的改善效果最好,因为根据塑性图,这种混合物能将土壤塑性从高降到低。此外,2.5% 的 SBA 与 5%的石灰混合使用对 CBR 值的改善最大,比纯土壤的 CBR 值提高了约 69%。最后,成本分析表明,这是一种很有前景的改良方法,它可以降低路面成本、延长设计寿命,还能减少与固体废弃物 SBA 相关的能源消耗和污染问题。
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引用次数: 0
Innovative Assessment of Mun River Flow Components through ANN and Isotopic End-Member Mixing Analysis 通过 ANN 和同位素末端分子混合分析创新性地评估濛河流量成分
Pub Date : 2024-06-01 DOI: 10.3390/geosciences14060150
Phornsuda Chomcheawchan, Veeraphat Pawana, P. Julphunthong, K. Kamdee, J. Laonamsai
This study innovatively assesses the Mun River flow components in Thailand, integrating artificial neural networks (ANNs) and isotopic (δ18O) end-member mixing analysis (IEMMA). It quantifies the contributions of the Upper Mun River (UMR) and Chi River (CR) to the overall flow, revealing a discrepancy in their estimated contributions. The ANN method predicts that the UMR and CR contribute approximately 70.5% and 29.5% respectively, while IEMMA indicates a more pronounced disparity with 84% from UMR and 16% from CR. This divergence highlights the distinct perspectives of ANN, focusing on hydrological data patterns, and IEMMA, emphasizing isotopic signatures. Despite discrepancies, both methods validate UMR as a significant contributor to the overall flow, highlighting their utility in hydrological research. The findings emphasize the complexity of river systems and advocate for an integrated approach of river flow analysis for a comprehensive understanding, crucial for effective water resource management and planning.
本研究结合人工神经网络(ANN)和同位素(δ18O)末端分子混合分析(IEMMA),对泰国濛江的流量成分进行了创新性评估。它量化了濛河上游(UMR)和池河(CR)对总流量的贡献,揭示了它们在估计贡献方面的差异。根据方差分析方法的预测,濛江上游和赤水河的贡献率分别约为 70.5%和 29.5%,而 IEMMA 显示的差异更为明显,濛江上游和赤水河的贡献率分别为 84%和 16%。这种差异凸显了 ANN 和 IEMMA 的不同视角,前者侧重于水文数据模式,后者则强调同位素特征。尽管存在差异,但这两种方法都验证了 UMR 对总流量的重要贡献,突出了它们在水文研究中的实用性。研究结果强调了河流系统的复杂性,提倡采用综合方法对河流流量进行分析,以获得全面的理解,这对有效的水资源管理和规划至关重要。
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引用次数: 0
Trace Elements Distribution in the k7 Seam of the Karaganda Coal Basin, Kazakhstan 哈萨克斯坦卡拉干达煤盆地 k7 煤层中的微量元素分布
Pub Date : 2024-05-24 DOI: 10.3390/geosciences14060143
Aiman Kopobayeva, Irina Baidauletova, Altynay Amangeldikyzy, Nazym Askarova
We investigated the distribution patterns and evaluated the average contents of trace elements in the k7 seam of the Karaganda coal basin in Central Kazakhstan. This paper presents the results of studying the geochemistry of 34 elements in 85 samples of the k7 seam. The study employed a suite of advanced high-resolution analytical methods, including atomic emission spectrometry with inductively coupled plasma (ICP–OES) and mass spectrometry with inductively coupled plasma (ICP–MS), along with their processing and interpretation. It was determined that the concentrations of trace elements in the k7 seam are primarily associated with lithophile elements, revealing high concentrations of Li, V, Sc, Zr, Hf, and Ba. Additionally, increased concentrations of Nb, Ta, Se, Te, Ag, and Th were observed compared to the coal Clarke. Specific Nb(Ta)–Zr(Hf)–Li mineralization accompanied by a group of associated metals (Ba, V, Sc, etc.) was identified. The study revealed lateral and vertical heterogeneity of the rare elements’ distributions in coals, attributed to the formation dynamics of the coal basin. A correlation between Li and Al2O3 with a less positive relationship with K2O suggests the affinity of certain elements (Li, Ta, Nb, and Ba) to kaolinite. Clay layers showed increased radioactivity, with Th—13.2 ppm and U—2.6 ppm, indicating the possible presence of volcanogenic pyroclastic rocks characterized by radioactivity. Taken together, these data reveal the features of the rock composition of the source area, which is considered a mineralization source. According to geochemical data, it was found that the source area mainly consists of igneous felsic rocks, indicating that the formation occurred under conditions of a volcanic arc. This study’s novelty lies in estimating the average trace elements in the k7 seam, with elevated concentrations of certain elements that suggest promising prospects for industrial extraction from coals and coal wastes. These findings offer insights into considering coal as a potential source of raw material for rare metal production, guiding the industrial processing of key elements within coal. The potential extraction of metals from coal deposits, including from dumps, holds significance for industrial and commercial technologies, as processing critical coal elements can reduce disposal costs and mitigate their environmental impact.
我们研究了哈萨克斯坦中部卡拉干达煤盆地 k7 煤层中微量元素的分布规律,并评估了其平均含量。本文介绍了对 k7 煤层 85 个样本中 34 种元素的地球化学研究结果。研究采用了一整套先进的高分辨率分析方法,包括电感耦合等离子体原子发射光谱法(ICP-OES)和电感耦合等离子体质谱法(ICP-MS),以及对这些方法的处理和解释。经测定,k7 煤层中的痕量元素浓度主要与亲岩元素有关,显示出 Li、V、Sc、Zr、Hf 和 Ba 的高浓度。此外,与 Clarke 煤层相比,Nb、Ta、Se、Te、Ag 和 Th 的浓度也有所增加。发现了特定的 Nb(Ta)-Zr(Hf)-Li 矿化,并伴有一组伴生金属(Ba、V、Sc 等)。研究揭示了煤中稀有元素分布的横向和纵向异质性,这归因于煤盆地的形成动力学。锂与 Al2O3 之间存在相关性,而与 K2O 之间的正相关性较小,这表明某些元素(锂、钽、铌和钡)与高岭石具有亲和性。粘土层显示出更高的放射性,钍含量为 13.2 ppm,铀含量为 2.6 ppm,表明可能存在以放射性为特征的火山成因火成碎屑岩。综合来看,这些数据揭示了被认为是矿化源的矿源区的岩石成分特征。根据地球化学数据,发现矿源区主要由火成岩长英岩组成,表明其形成是在火山弧条件下进行的。这项研究的新颖之处在于估算了 k7 煤层中的平均微量元素含量,其中某些元素的浓度较高,表明从煤炭和煤炭废料中进行工业提取的前景广阔。这些发现为将煤炭视为稀有金属生产的潜在原料来源提供了启示,指导了煤炭中关键元素的工业加工。从煤炭矿藏(包括垃圾场)中提取金属的可能性对工业和商业技术具有重要意义,因为对关键煤炭元素进行加工可以降低处理成本,减轻对环境的影响。
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